CN103283738B - A kind of Pesticidal combination containing spiral shell worm ethyl ester - Google Patents
A kind of Pesticidal combination containing spiral shell worm ethyl ester Download PDFInfo
- Publication number
- CN103283738B CN103283738B CN201210053621.7A CN201210053621A CN103283738B CN 103283738 B CN103283738 B CN 103283738B CN 201210053621 A CN201210053621 A CN 201210053621A CN 103283738 B CN103283738 B CN 103283738B
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- CN
- China
- Prior art keywords
- ethyl ester
- spiral shell
- shell worm
- worm ethyl
- methoxyfenozide
- Prior art date
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- 239000003292 glue Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
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- 159000000003 magnesium salts Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
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- 238000002703 mutagenesis Methods 0.000 description 1
- 231100000350 mutagenesis Toxicity 0.000 description 1
- PEQJBOMPGWYIRO-UHFFFAOYSA-N n-ethyl-3,4-dimethoxyaniline Chemical group CCNC1=CC=C(OC)C(OC)=C1 PEQJBOMPGWYIRO-UHFFFAOYSA-N 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
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- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 description 1
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- DTDSAWVUFPGDMX-UHFFFAOYSA-N spirodiclofen Chemical compound CCC(C)(C)C(=O)OC1=C(C=2C(=CC(Cl)=CC=2)Cl)C(=O)OC11CCCCC1 DTDSAWVUFPGDMX-UHFFFAOYSA-N 0.000 description 1
- CLSVJBIHYWPGQY-GGYDESQDSA-N spirotetramat Chemical compound CCOC(=O)OC1=C(C=2C(=CC=C(C)C=2)C)C(=O)N[C@@]11CC[C@H](OC)CC1 CLSVJBIHYWPGQY-GGYDESQDSA-N 0.000 description 1
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- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
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- HTSABYAWKQAHBT-UHFFFAOYSA-N trans 3-methylcyclohexanol Natural products CC1CCCC(O)C1 HTSABYAWKQAHBT-UHFFFAOYSA-N 0.000 description 1
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- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of Pesticidal combination containing spiral shell worm ethyl ester, the principal character of said composition is: containing active components A, active component B, wherein active components A is spiral shell worm ethyl ester, active component B is arbitrary a kind of in methoxyfenozide, worm hydrazides, and the weight ratio 1: 60 ~ 60: 1 of active components A and active component B, composition makes wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, micro-capsule suspension, microcapsule suspension-suspendinagent agent.The present composition can prevent and treat various pests, and has obvious synergistic effect, expands insecticidal spectrum, has greater activity to the insect on paddy rice, wheat, cotton, fruit tree, brassicaceous vegetable; And decrease pesticide usage amount, to person poultry safety, without poisoning, Environmental compatibility is good; Preparation adhesion strength strengthens, resistance of rainwater washing against.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of Pesticidal combination containing spiral shell worm ethyl ester.
Background technology
Spiral shell worm ethyl ester (spirotetramat) chemical name: 4-(ethoxy carbonyl oxygen base)-8-methoxyl group-3-(2,5-xylyl)-1-azaspiro [4, the 5]-last of the ten Heavenly stems-3-alkene-2-ketone, molecular formula: C
21h
27nO
5, new pesticides spiral shell worm ethyl ester is tetronic acid compounds, belongs to similar compound with insecticidal/acaricidal agent spiral shell mite ester (spirodiclofen) of Bayer company and Spiromesifen (spiromesifen).Spiral shell worm ethyl ester has unique function Characteristics, is the modern pesticides uniquely so far with two-way Uptake and translocation performance.This compound upwards can move down in whole plant corpus, arrives at blade face and bark, thus control is as on romaine lettuce and Chinese cabbage internal lobe, and the corticole insect of fruit.The interior absorption of this uniqueness can protect newborn stem, leaf and root, prevents ovum and the larval growth of insect.Its another feature is that the lasting period is long, can provide the effective control reaching 8 weeks.
Methoxyfenozide (methoxyfenozide); chemical name: the N-tert-butyl group-N'-(3-methyl-2-toluyl groups)-3; 5-dimethylbenzohydrazide; for the one of insect growth regulator, IGR; mainly the normal growth of interference insect is grown; even if insect molting and dead, and can suppress to ingest.This product water controlling object selectivity is strong, has special efficacy to lepidopterous larvae.
Worm hydrazides (tebufenozide), chemical name: 1-(1,1-dimethyl ethyl)-1-(4-ethylamino benzonitrile acyl group)-3,5 ,-dimethylbenzohydrazide, chemical molecular formula: C
22h
23n
2o
2, worm hydrazides is on-steroidal Novel insect growth regulator, is the insect hormone insecticides of up-to-date research and development.Tebufenozide pesticide activity is high, and selectivity is strong, and all effective to all lepidopterous larvaes, antagonism insect cotton bollworm, cabbage caterpillar, diamond-back moth, beet armyworm etc. have special efficacy.And have extremely strong ovicidal activity, safer to non-target organism.Worm hydrazides is to eyes and no skin irritation, to higher mammal without teratogenesis, carcinogenic, mutagenesis, all fool proof to mammal, birds, natural enemy.
In the real process of agricultural production, the problem that pest control the most easily produces is the generation of pest resistance to insecticide.Different cultivars composition carries out composite, is to prevent and treat the very common method of resistant insect.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals is all additive effect, really has the seldom composite of synergistic effect, especially synergistic effect clearly, very high composite just less of co-toxicity coefficient.Find through inventor's lot of experiments, after spiral shell worm ethyl ester and worm hydrazides, methoxyfenozide are composite, synergistic effect is remarkable, and Environmental compatibility is fabulous, considerably reduces pesticide usage amount.
Summary of the invention
The Pesticidal combination that the present invention proposes to contain in spiral shell worm ethyl ester and methoxyfenozide, worm hydrazides any one two kinds of active components, and appropriate surfactant and carrier.
A kind of Pesticidal combination containing spiral shell worm ethyl ester, comprise active components A, active component B, it is characterized in that: active components A is spiral shell worm ethyl ester, active component B is arbitrary a kind of in methoxyfenozide, worm hydrazides, and the weight ratio of active components A and active component B is 1:60 ~ 60:1.
Described Pesticidal combination, is characterized in that: the weight ratio of active components A and active component B is 1:40 ~ 20:1.
Described Pesticidal combination, is characterized in that: the weight ratio of spiral shell worm ethyl ester and methoxyfenozide is 1:10 ~ 10:1.
Described Pesticidal combination, is characterized in that: the weight ratio of spiral shell worm ethyl ester and worm hydrazides is 1:20 ~ 10:1.
Described Pesticidal combination, is characterized in that: composition makes wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent.
Described Pesticidal combination is for preventing and treating the application of insect on paddy rice, wheat, cotton, fruit tree, brassicaceous vegetable.
Described application, pest control comprises: rice leaf roller, striped rice borer, paddy stem borer, cabbage caterpillar, prodenia litura, beet armyworm, cotton bollworm, pink bollworm, small brown rice planthopper, brown planthopper, white-backed planthopper, scale insect, Bemisia tabaci, pear sucker, apple leaf miner.
At least containing a kind of surfactant in Pesticidal combination of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 5% ~ 30% of total formulation weight amount, and surplus is solid or liquid diluent.Surfactant selected by Pesticidal combination of the present invention is known in those skilled in the art: can be selected from one or more in dispersant, wetting agent, emulsifier or defoamer.
Following constituent content is comprised: active components A 1% ~ 60%, active component B1% ~ 60%, dispersant 5% ~ 10%, wetting agent 2% ~ 10%, filler surplus when making wetting powder.
By active components A, active component B, dispersant, wetting agent, filler mixing, mix in mixed cylinder, mix again after airslide disintegrating mill is pulverized, namely can be made into wetting powder product of the present invention.
Composition comprises following constituent content when making water dispersible granules: active components A 1% ~ 60%, active component B1% ~ 60%, dispersant 3% ~ 12%, wetting agent 1% ~ 8%, disintegrant 1% ~ 10%, filler surplus.
Active components A, active component B, dispersant, wetting agent, disintegrant, filler etc. are obtained together the particle diameter needed through air-flow crushing, obtain granulation materials.Item is quantitatively sent in fluidized bed granulating dryer through granulating and after drying, obtaining water dispersible granules product of the present invention.
Composition comprises following constituent content when making suspending agent: active components A 1% ~ 60%, active component B1% ~ 60%, dispersant 2 ~ 10%, wetting agent 2 ~ 10%, defoamer 1 ~ 1%, thickener 1 ~ 2%, antifreeze 1 ~ 8%, deionized water add to 100%.
Dispersant, wetting agent, defoamer, thickener, antifreeze, emulsifier in above-mentioned formulation material are mixed through high speed shear, add active components A, active component B ball milling 2 ~ 3 hours in ball mill, make diameter of particle all below 5 μm, obtained suspending agent product of the present invention.
Composition comprises following constituent content when making suspension emulsion: active components A 1% ~ 60%, active component B1% ~ 60%, emulsifier 2% ~ 12%, and dispersant 2% ~ 10%, defoamer 1% ~ 2%, thickener 1% ~ 2%, antifreeze 1% ~ 8%, stabilizing agent 0.05% ~ 3%, deionized water add to 100%.
Dispersant, defoamer, thickener, antifreeze, stabilizing agent in above-mentioned formulation material are mixed through high speed shear, add the former medicine of active components A, ball milling 2 ~ 3 hours in ball mill, make diameter of particle all below 5 μm, obtained active components A suspending agent, then by former for active component B medicine, emulsifier and the direct emulsification of various auxiliary agent high speed agitators in suspending agent, obtained suspension emulsion product of the present invention.
Composition comprises following constituent content when making aqueous emulsion: activity composition A1% ~ 60%, active component B1% ~ 60%, solvent 0% ~ 30%, emulsifier 1% ~ 15%, co-emulsifier 0% ~ 8%, antifreeze 0% ~ 10%, thickener 1% ~ 2%, defoamer 0.01% ~ 2%, deionized water supply surplus.
Above-mentioned formula is mixed, active ingredient, solvent, emulsifier, co-emulsifier are added together, make to be dissolved into homogeneous oil phase; Water, antifreeze, thickener, defoamer are mixed, becomes homogeneous aqueous phase.Under high velocity agitation, aqueous phase is added oil phase, obtained aqueous emulsion product of the present invention.
Composition comprises following constituent content active components A 1% ~ 60%, active component B1% ~ 60%, solvent 0% ~ 30%, emulsifier 3% ~ 20%, co-emulsifier 0% ~ 12%, antifreeze 0% ~ 10%, thickener 1% ~ 2%, defoamer 0.01% ~ 2%, stabilizing agent 0% ~ 4% when making microemulsion, deionized water supplies surplus.
Active components A and the former medicine of active component B are dissolved in the homogenizer that solvent and cosolvent are housed; Emulsifier, stabilizing agent and antifreeze, water are joined after in the homogenizer that above-mentioned solution is housed and gives strong mixing and homogenize, finally obtains the microemulsion product of the present invention that clear appearance is transparent.
Composition is made micro-capsule suspension and is comprised following constituent content: active components A 1% ~ 60%, active component B1% ~ 60%, macromolecule cyst material 1% ~ 12%, surfactant 2% ~ 10%, organic solvent 1% ~ 15%, emulsifier 1% ~ 8%, pH adjusting agent 1% ~ 5%, deionized water adds to 100%.
Macromolecule cyst material is added PH conditioning agent and is heated to uniform temperature, obtain thick liquid, then thin up, form stable prepolymer solution, active component B, active components A are dissolved in organic solvent, be added to again in prepolymer solution, add emulsifier, surfactant, and fully shear agitation is dispersed into superfine microgranular, add PH conditioning agent again, and heat up, catalyzed polycondensation forms the firm microcapsules not easily permeated, obtained micro-capsule suspension of the present invention.
When the formulation of composition is microcapsules suspension-suspending agent, the auxiliary agent of interpolation is surfactant, emulsifier, solvent, PH conditioning agent, macromolecule cyst material, defoamer, thickener, water add to 100%.
Composition comprises following constituent content when making microcapsule suspension-suspendinagent agent: active components A 1% ~ 60%, active component B1% ~ 60%, macromolecule cyst material 2% ~ 12%, surfactant 3% ~ 15%, organic solvent 1% ~ 5%, emulsifier 1% ~ 6%, defoamer 0.2% ~ 5%, thickener 0.2% ~ 5%, pH adjusting agent 1% ~ 5%, water add to 100%.
Adopt interfacial polymerization, mix having active component B, macromolecule cyst material, organic solvent in above-mentioned formula, make to be dissolved into homogeneous oil phase, oil phase is joined in a shear condition in the aqueous phase solution containing emulsifier, pH adjusting agent, bi-material reacts at oil-water interfaces, form macromolecule cyst wall around the drop containing chemical substance, make active component B micro-capsule suspension.Surfactant, defoamer, thickener, antifreeze are mixed through high speed shear, add the former medicine of active components A, ball milling 2 ~ 3 hours in ball mill, make diameter of particle all below 5 μm, obtained active components A suspending agent, then joining being dissolved in active components A suspending agent stable in water in the aqueous phase solution of active component B micro-capsule suspension, making the finely disseminated microcapsule suspension-suspendinagent agent product of the present composition.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, one or more during ester polyoxyethylene is phonetic.
Described wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, washing powder, agriculture breast 2000
#series, sldium lauryl sulfate, wetting and penetrating agent F, wetting agent T, spaonin powder, tea are withered, one or more in silkworm excrement, soapberry powder.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, glucose.
Described emulsifier is selected from: agriculture breast 500
#(alkyl benzene calcium sulfonate), OP series phosphate (thermally coupled distillation columns), 600
#phosphate (phenyl phenol polyoxyethanyl ether phosphate), styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, agriculture breast 400
#(benzyl dimethyl phenol polyoxyethyl ether), agriculture breast 600
#(phenyl phenol polyoxyethyl ether), Nongru-700
#(alkylphenol-formaldehyde resin polyoxyethyl ether), agriculture breast 36
#(phenethyl fluosite polyoxyethyl ether), agriculture breast 1600
#(phenethyl phenol polyoxyethanyl polypropylene-base ether), ethylene oxide-propylene oxide block copolymer, OP series (polyoxyethylene nonylphenol ether), By series (castor oil polyoxyethylene ether), agriculture breast 33
#(alkylaryl polyoxyethylene polyoxypropylene ether), agriculture breast 34
#one or more in (alkylaryl polyoxyethylene poly-oxygen propylene aether), Span series (sorbitan monostearate), TWEEN Series (sorbitan fatty acid ester APEO), EO series (fat alcohol alcohol APEO).
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, glycerine, polyethylene glycol.
Described defoamer is selected from: silicone, C
8 ~ 10aliphatic alcohols, C
10 ~ 20one or more in saturated fat acids (as capric acid) and acid amides, silicone oil, silicone compound.
Described thickener is selected from: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol.
Macromolecule cyst material be selected from urea, formaldehyde, PIC, polyfunctional group acyl halide polyamines, polyfunctional group acyl halide dihydroxylic alcohols, sodium alginate, polyvinyl alcohol, gelatin, gum Arabic, sucrose, modified starch, maltose, distortion milk protein, glycerine, calcium chloride, carboxymethyl cellulose, beta-schardinger dextrin-one or more.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate, vegetable oil.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension-suspendinagent agent the key technical indexes of the present invention:
The invention has the advantages that:
(1) spiral shell worm ethyl ester and methoxyfenozide, worm hydrazides composite after, there is notable synergistic and lasting effect;
(2) expand insecticidal spectrum, all have greater activity to the rice leaf roller, striped rice borer, paddy stem borer, cabbage caterpillar, prodenia litura, beet armyworm, cotton bollworm, pink bollworm, small brown rice planthopper, brown planthopper, white-backed planthopper, scale insect, Bemisia tabaci, pear sucker, apple leaf miner etc. of paddy rice, wheat, cotton, fruit tree, brassicaceous vegetable;
(3) decrease the dosage of agricultural chemicals, reduce the residual quantity of agricultural chemicals on crop, alleviate environmental pollution;
(4) to person poultry safety, Environmental compatibility is good, and insect not easily develops immunity to drugs.
Embodiment
Below in conjunction with embodiment to further instruction of the present invention, the percentage in embodiment is all weight percentage, but the present invention is not limited thereto.
Application Example one
Embodiment 180% spiral shell worm ethyl ester methoxyfenozide wetting powder
Spiral shell worm ethyl ester 40%, methoxyfenozide 40%, alkylphenol-polyethenoxy phonetic formaldehyde condensation products sulphate 7%, tea are withered 5%, bentonite adds to 100%, and mixture carries out air-flow crushing, obtained 80% spiral shell worm ethyl ester methoxyfenozide wetting powder.
Effective active composition methoxyfenozide is changed to worm hydrazides and forms new embodiment.
Embodiment 270% spiral shell worm ethyl ester worm hydrazides wetting powder
Spiral shell worm ethyl ester 20%, worm hydrazides 50%, alkylphenol-polyethenoxy are phonetic 6%, silkworm excrement 4%, attapulgite add to 100%, and mixture carries out air-flow crushing, obtained 70% spiral shell worm ethyl ester worm hydrazides wetting powder.
Effective active composition worm hydrazides is changed to methoxyfenozide and forms new embodiment.
Embodiment 361% spiral shell worm ethyl ester methoxyfenozide wetting powder
Spiral shell worm ethyl ester 1%, methoxyfenozide 60%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, tea are withered 4%, kaolin adds to 100%, and mixture carries out air-flow crushing, obtained 61% spiral shell worm ethyl ester methoxyfenozide wetting powder.
Effective active composition methoxyfenozide is changed to worm hydrazides and forms new embodiment.
Embodiment 470% spiral shell worm ethyl ester methoxyfenozide water dispersible granules
Spiral shell worm ethyl ester 30%, methoxyfenozide 40%, polycarboxylate 6%, soapberry powder 5%, sodium bicarbonate 2%, white carbon add to 100%, the obtained 70% spiral shell worm ethyl ester methoxyfenozide water dispersible granules of mixing.
Effective active composition methoxyfenozide is changed to worm hydrazides and forms new embodiment.
Embodiment 561% spiral shell worm ethyl ester methoxyfenozide water dispersible granules
Spiral shell worm ethyl ester 60%, methoxyfenozide 1%, spaonin powder 4%, naphthalene sulfonic acid-formaldehyde condensation product 7%, aluminium chloride 2%, bentonite add to 100%, the obtained 61% spiral shell worm ethyl ester methoxyfenozide water dispersible granules of mixing.
Effective active composition methoxyfenozide is changed to worm hydrazides and forms new embodiment.
Embodiment 645% spiral shell worm ethyl ester worm hydrazides water dispersible granules
Spiral shell worm ethyl ester 15%, worm hydrazides 30%, neopelex 6%, aryl phenol polyoxyethylene succinate sulfonate 7%, sodium bicarbonate 2%, diatomite add to 100%, the obtained 45% spiral shell worm ethyl ester worm hydrazides water dispersible granules of mixing.
Effective active composition worm hydrazides is changed to methoxyfenozide and forms new embodiment.
Embodiment 741% spiral shell worm ethyl ester methoxyfenozide suspending agent
The phonetic formaldehyde condensation products sulphate 5% of spiral shell worm ethyl ester 1%, methoxyfenozide 40%, alkylphenol-polyethenoxy, soapberry powder 4%, C
8 ~ 10aliphatic alcohols 2%, xanthans 1.2%, glycerine 0.8%, deionized water add to 100%, the obtained 41% spiral shell worm ethyl ester methoxyfenozide suspending agent of mixing.
Effective active composition methoxyfenozide is changed to worm hydrazides and forms new embodiment.
Embodiment 830% spiral shell worm ethyl ester methoxyfenozide suspending agent
The phonetic formaldehyde condensation products sulphate 6% of spiral shell worm ethyl ester 20%, methoxyfenozide 10%, alkylphenol-polyethenoxy, sldium lauryl sulfate 4%, C
10 ~ 20saturated fat acids 1%, phenolic resins 2%, deionized water add to 100%, the obtained 30% spiral shell worm ethyl ester methoxyfenozide suspending agent of mixing.
Effective active composition methoxyfenozide is changed to worm hydrazides and forms new embodiment.
Embodiment 925% spiral shell worm ethyl ester Tebufenozide suspending agent
Spiral shell worm ethyl ester 15%, worm hydrazides 10%, alkylaryl APEO 6%, soapberry powder 5%, C
10 ~ 20saturated fat acids 1.2%, polyvinylpyrrolidone 2%, deionized water add to 100%, the obtained 25% spiral shell worm ethyl ester Tebufenozide suspending agent of mixing.
Effective active composition worm hydrazides is changed to methoxyfenozide and forms new embodiment.
Embodiment 1040% spiral shell worm ethyl ester methoxyfenozide suspension emulsion
Spiral shell worm ethyl ester 10%, methoxyfenozide 30%, aryl phenol polyoxyethylene succinate sulfonate 7%, neopelex 6%, phenethyl phenol polyoxyethanyl polypropylene-base ether 6%, cyclohexanone 5%, C
8 ~ 10aliphatic alcohols 1%, melon glue 2%, diethylene glycol (DEG) 1.8%, deionized water add to 100%, the obtained 40% spiral shell worm ethyl ester methoxyfenozide suspension emulsion of mixing.
Effective active composition methoxyfenozide is changed to worm hydrazides and forms new embodiment.
Embodiment 1130% spiral shell worm ethyl ester worm hydrazides suspension emulsion
Spiral shell worm ethyl ester 5%, worm hydrazides 25%, alkylaryl APEO 7%, wetting and penetrating agent F4%, sorbitan fatty acid ester APEO 2%, C
8 ~ 10aliphatic alcohols 0.8%, sodium phosphate trimer 1.5%, PAA 2%, deionized water add to 100%, the obtained 30% spiral shell worm ethyl ester worm hydrazides suspension emulsion of mixing.
Effective active composition worm hydrazides is changed to methoxyfenozide and forms new embodiment.
Embodiment 1211% spiral shell worm ethyl ester methoxyfenozide suspension emulsion
Spiral shell worm ethyl ester 10%, methoxyfenozide 1%, aryl phenol polyoxyethylene succinate sulfonate 6%, tea are withered 4%, phenethyl fluosite polyoxyethyl ether 5%, C
10 ~ 20saturated fat acids 0.5%, xanthans 1.5%, polyethylene glycol 1.2%, deionized water add to 100%, the obtained 11% spiral shell worm ethyl ester methoxyfenozide suspension emulsion of mixing.
Effective active composition methoxyfenozide is changed to worm hydrazides and forms new embodiment.
Embodiment 1342% spiral shell worm ethyl ester methoxyfenozide microemulsion
Spiral shell worm ethyl ester 40%, methoxyfenozide 2%, benzyl dimethyl phenol polyoxyethyl ether 7%, vegetable oil 4%, glycerine 1%, polyvinylpyrrolidone 1%, silicone oil 0.9%, epoxychloropropane 2%, deionized water supplies 100%, the obtained 42% spiral shell worm ethyl ester methoxyfenozide microemulsion of mixing.
Effective active composition methoxyfenozide is changed to worm hydrazides and forms new embodiment.
Embodiment 1435% spiral shell worm ethyl ester methoxyfenozide microemulsion
Spiral shell worm ethyl ester 5%, methoxyfenozide 30%, ethyl acetate 7%, sodium phosphate trimer 5%, gum Arabic 1.6%, alkylaryl polyoxyethylene poly-oxygen propylene aether 7%, C
8 ~ 10aliphatic alcohols 1.4%, tributyl phosphate 1.5%, deionized water supplies 100%, obtained 35% spiral shell worm ethyl ester methoxyfenozide microemulsion.
Effective active composition methoxyfenozide is changed to worm hydrazides and forms new embodiment.
Embodiment 1511% spiral shell worm ethyl ester worm hydrazides microemulsion
Spiral shell worm ethyl ester 1%, worm hydrazides 10%, ethyl acetate 7%, phenethyl fluosite polyoxyethyl ether 6%, sodium phosphate trimer 1.5%, propane diols 2%, C
10 ~ 20saturated fat acids 1.4%, triethanolamine 1%, deionized water supplies 100%, the obtained 11% spiral shell worm ethyl ester worm hydrazides microemulsion of mixing.
Effective active composition worm hydrazides is changed to methoxyfenozide and forms new embodiment.
Embodiment 1650% spiral shell worm ethyl ester methoxyfenozide aqueous emulsion
Spiral shell worm ethyl ester 10%, methoxyfenozide 40%, N, dinethylformamide 5%, ethyl acetate 5%, alkylaryl polyoxyethylene polyoxypropylene ether 6%, propane diols 2%, silicone oil 0.8%, deionized water adds to 100%, the obtained 50% spiral shell worm ethyl ester methoxyfenozide aqueous emulsion of mixing.
Effective active composition methoxyfenozide is changed to worm hydrazides and forms new embodiment.
Embodiment 1725% spiral shell worm ethyl ester worm hydrazides aqueous emulsion
Spiral shell worm ethyl ester 10%, worm hydrazides 15%, toluene 8%, butyl ether 2%, thermally coupled distillation columns 8%, sodium alginate 1.6%, C
10 ~ 20saturated fat acids 1.5%, deionized water adds to 100%, through mixing obtained 25% spiral shell worm ethyl ester worm hydrazides aqueous emulsion.
Effective active composition worm hydrazides is changed to methoxyfenozide and forms new embodiment.
Embodiment 1820% spiral shell worm ethyl ester methoxyfenozide aqueous emulsion
Spiral shell worm ethyl ester 10%, methoxyfenozide 10%, N-pyrrolidones 4%, acetone 5%, alkylphenol-formaldehyde resin polyoxyethyl ether 8%, polyvinylpyrrolidone 1.8%, C
8 ~ 10aliphatic alcohols 0.8%, deionized water adds to 100%, through mixing obtained 20% spiral shell worm ethyl ester methoxyfenozide aqueous emulsion.
Effective active composition methoxyfenozide is changed to worm hydrazides and forms new embodiment.
Embodiment 1945% spiral shell worm ethyl ester methoxyfenozide micro-capsule suspension
Spiral shell worm ethyl ester 30%, methoxyfenozide 15%, polyfunctional group acyl halide dihydroxylic alcohols 3%, calcium chloride 2%, silkworm excrement 5%, alkylphenol-polyethenoxy are phonetic 2.4%, 3-methyl cyclohexanol ketenes 6%, sorbitan fatty acid ester APEO 5%; citric acid 0.9%, sodium hydroxide 0.6%, deionized water add to 100% weight portion, obtained 45% spiral shell worm ethyl ester methoxyfenozide micro-capsule suspension.
Effective active composition methoxyfenozide is changed to worm hydrazides and forms new embodiment.
Embodiment 2050% spiral shell worm ethyl ester methoxyfenozide microcapsule suspension-suspendinagent agent
Spiral shell worm ethyl ester 25%, methoxyfenozide 25%, maltose 3%, PIC 4%, fatty acyl amido are withered 2.5% to methoxy benzenesulfonic acid sodium 6%, tea, ethyl acetate 7%, phenyl phenol polyoxyethyl ether 5%, alkylaryl polyoxyethylene poly-oxygen propylene aether 3%, silicone oil 0.6%, xanthans 1.2%, pH adjusting agent sodium hydroxide and citric acid amount to 3.8%, water adds to 100% weight portion, obtained 50% spiral shell worm ethyl ester methoxyfenozide microcapsule suspension-suspendinagent agent.
Effective active composition methoxyfenozide is changed to worm hydrazides and forms new embodiment.
The embodiment of the present invention is the method adopting Toxicity Determination and field trial to combine.First pass through Toxicity Determination, co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC < 80 is antagonism, 80≤CTC≤120 are summation action, CTC > 120 is synergistic effect, on this basis, then carry out field trial.
Test method: respectively the mother liquor of each mixed agent is diluted to five series concentration during test, is placed in beaker respectively for subsequent use.Adopt the method connecing worm after first soaking leaf, take out after the blade of the same size not contacting any medicament is soaked 5s in the liquid configured, naturally dry, put into insect box, then connect for examination larva, raise under 25 DEG C of conditions, often process and repeat for 3 times, often repeating examination borer population used is 50, establishes blank simultaneously, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50value.If contrast lethality is greater than 10%, be then considered as invalid test.Computing formula is as follows:
Insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value (x) to, draws virulence regression equation, and calculate the value of often kind of medicament thus with method of least squares.Co-toxicity coefficient CTC is calculated according to the abundant equation of Sun Yun.Computing formula following (with spiral shell worm ethyl ester for standard agent, its toxicity index is 100):
TI × the P of theoretical toxicity index (the TTI)=spiral shell worm ethyl ester of M
spiral shell worm ethyl estertI × the P of+active component B
active component B
In formula: M is the mixture of different ratio;
P
active component Bfor the ratio that active component B is shared in the composition;
P
spiral shell worm ethyl esterfor the ratio that spiral shell worm ethyl ester is shared in the composition.
Note: active component B is arbitrary a kind of in worm hydrazides, methoxyfenozide.
Application Example two:
For examination insect: trialeurodes vaporariorum.
Experimental scheme: through effective lethal concentration scope of preliminary experiment determination spiral shell worm ethyl ester, the former medicine of methoxyfenozide and the two different ratio mixture.
Toxicity test result one
Table 1 spiral shell worm ethyl ester and methoxyfenozide different ratio are to the toxicity test of trialeurodes vaporariorum
As shown in Table 1, spiral shell worm ethyl ester and the composite control trialeurodes vaporariorum of methoxyfenozide fit over 60:1 to 1:60 time, co-toxicity coefficient is all greater than 120, both explanations mixture in 60:1 to 1:60 scope all shows synergistic effect, especially when spiral shell worm ethyl ester and methoxyfenozide obtain proportioning at 10:1 to 1:10, synergistic effect is more obviously given prominence to, wherein when spiral shell worm ethyl ester and methoxyfenozide weight ratio are 1:1, co-toxicity coefficient is maximum, synergistic effect is the most obvious, find simultaneously, spiral shell worm ethyl ester and methoxyfenozide proportioning are at 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, composite to rice leaf roller during 1:10, striped rice borer, paddy stem borer, cabbage caterpillar, prodenia litura, beet armyworm, cotton bollworm, pink bollworm, small brown rice planthopper, brown planthopper, white-backed planthopper, scale insect, Bemisia tabaci, pear sucker, the insects such as apple leaf miner also have good synergistic effect, co-toxicity coefficient is all greater than 260.
Application Example three:
For examination insect: rice leaf roller.
Experimental scheme: through effective lethal concentration scope of preliminary experiment determination spiral shell worm ethyl ester, the former medicine of worm hydrazides and the two different ratio mixture.
Toxicity test result two
Table 2 spiral shell worm ethyl ester and worm hydrazides different ratio are to the toxicity test of rice leaf roller
As shown in Table 2, spiral shell worm ethyl ester and the composite proportioning of preventing and treating rice leaf roller of worm hydrazides are when 60:1 to 1:60, co-toxicity coefficient is all greater than 120, both explanations mixture in 60:1 to 1:60 scope all shows synergistic effect, and especially when the proportioning of spiral shell worm ethyl ester and worm hydrazides is at 10:1 to 1:20, synergistic effect is more obviously given prominence to, wherein when spiral shell worm ethyl ester and worm hydrazides weight ratio are 1:1, co-toxicity coefficient is maximum, synergistic effect is the most obvious, and find, spiral shell worm ethyl ester and worm hydrazides proportioning are at 10:1 simultaneously, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:11, 1:12, 1:13, 1:14, 1:15, 1:16, 1:17, 1:18, 1:19, composite to rice leaf roller during 1:20, striped rice borer, paddy stem borer, cabbage caterpillar, prodenia litura, beet armyworm, cotton bollworm, pink bollworm, small brown rice planthopper, brown planthopper, white-backed planthopper, scale insect, Bemisia tabaci, pear sucker, the insects such as apple leaf miner also have good synergistic effect, and co-toxicity coefficient is all greater than 200.
Application Example four spiral shell worm ethyl ester and methoxyfenozide and composite control paddy rice rice leaf roller thereof are imitated and test
This experimental establishment is in Linan City of Hangzhou, Zhejiang province city, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 240 grams per liter spiral shell worm ethyl ester suspending agent (commercial), 240 grams per liter methoxyfenozide suspending agents (commercial).
Test adopts conventional spray-on process, and investigation paddy rice rice leaf roller insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 3 days, 7 days, 14 days investigation insect pest indexes after dispenser also calculate preventive effect.Experimental result is as follows:
Table 3 spiral shell worm ethyl ester, methoxyfenozide and the composite control paddy rice rice leaf roller test of pesticide effectiveness thereof
As can be seen from Table 3, spiral shell worm ethyl ester and methoxyfenozide composite after can effectively prevent and treat paddy rice rice leaf roller, control efficiency is all better than the preventive effect of single dose, and the preventive effect time is long.In test scope of medication, target crop is had no adverse effects.
Application Example five spiral shell worm ethyl ester and methoxyfenozide and the composite control cotton cotton bollworm test of pesticide effectiveness thereof
This experimental establishment is in Weinan City Dali County, Shaanxi Province, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 240 grams per liter spiral shell worm ethyl ester suspending agent (commercial), 240 grams per liter methoxyfenozide suspending agents (commercial).
Test adopts conventional spray-on process, and investigation cotton cotton bollworm insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 3 days, 7 days, 14 days investigation insect pest indexes after dispenser also calculate preventive effect.Experimental result is as follows:
Table 4 spiral shell worm ethyl ester, methoxyfenozide and the composite control cotton cotton bollworm test of pesticide effectiveness thereof
As can be seen from Table 4, spiral shell worm ethyl ester and methoxyfenozide composite after can effectively prevent and treat cotton cotton bollworm, control efficiency is all better than the preventive effect of single dose, and the preventive effect time is long.In test scope of medication, target crop is had no adverse effects.
Application Example six spiral shell worm ethyl ester and methoxyfenozide and the composite control eggplant trialeurodes vaporariorum test of pesticide effectiveness thereof
This experimental establishment is in Fengxiang County, Baoji, Shaanxi province city, and test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd., contrast medicament 240 grams per liter spiral shell worm ethyl ester suspending agent (commercial), 240 grams per liter methoxyfenozide suspending agents (commercial).
Test adopts conventional spray-on process, and investigation eggplant trialeurodes vaporariorum insect pest index before medicine, in the dispenser of insect pest initial stage of origination, 3 days, 7 days, 14 days investigation insect pest indexes after dispenser also calculate preventive effect.Experimental result is as follows:
Table 5 spiral shell worm ethyl ester, methoxyfenozide and the composite control eggplant trialeurodes vaporariorum test of pesticide effectiveness thereof
As can be seen from Table 5, spiral shell worm ethyl ester and methoxyfenozide composite after can effectively prevent and treat eggplant trialeurodes vaporariorum, control efficiency is all better than the preventive effect of single dose, and the preventive effect time is long.In test scope of medication, target crop is had no adverse effects.
After draw through tests different local throughout the country, spiral shell worm ethyl ester and methoxyfenozide, worm hydrazides is composite makes wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, to the rice leaf roller of all kinds of crop after microcapsule suspension-suspendinagent agent, striped rice borer, paddy stem borer, cabbage caterpillar, prodenia litura, beet armyworm, cotton bollworm, pink bollworm, small brown rice planthopper, brown planthopper, white-backed planthopper, scale insect, Bemisia tabaci, pear sucker, the preventive effect of the common insect pests such as apple leaf miner is all more than 95%, be better than single dose preventive effect, synergistic effect is obvious.
Claims (6)
1., containing a Pesticidal combination for spiral shell worm ethyl ester, active ingredient is active components A, active component B, it is characterized in that: active components A is spiral shell worm ethyl ester, and active component B is methoxyfenozide, and the weight ratio of spiral shell worm ethyl ester and methoxyfenozide is 1:60 ~ 60:1.
2. the Pesticidal combination containing spiral shell worm ethyl ester according to claim 1, is characterized in that: the weight ratio of spiral shell worm ethyl ester and methoxyfenozide is 1:40 ~ 20:1.
3. the Pesticidal combination containing spiral shell worm ethyl ester according to claim 2, is characterized in that: the weight ratio of spiral shell worm ethyl ester and methoxyfenozide is 1:10 ~ 10:1.
4., according to the Pesticidal combination containing spiral shell worm ethyl ester in claims 1 to 3 described in any one, it is characterized in that: composition makes wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, microcapsule suspension-suspending agent.
5. the Pesticidal combination containing spiral shell worm ethyl ester according to claim 4 is for preventing and treating the application of insect on paddy rice, wheat, cotton, fruit tree, brassicaceous vegetable.
6. application according to claim 5, is characterized in that institute's pest control is rice leaf roller, striped rice borer, paddy stem borer, cabbage caterpillar, prodenia litura, beet armyworm, cotton bollworm, pink bollworm, small brown rice planthopper, brown planthopper, white-backed planthopper, scale insect, Bemisia tabaci, pear sucker, apple leaf miner.
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| CN1232450A (en) * | 1996-08-05 | 1999-10-20 | 拜尔公司 | 2- and 2,5-substd. phenylketoenols |
| WO2008006514A1 (en) * | 2006-07-11 | 2008-01-17 | Bayer Cropscience Ag | Active ingredient combinations with insecticidal and acaricidal properties |
| CN102379299A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Ultralow volume liquid containing spirotetramat |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1232450A (en) * | 1996-08-05 | 1999-10-20 | 拜尔公司 | 2- and 2,5-substd. phenylketoenols |
| WO2008006514A1 (en) * | 2006-07-11 | 2008-01-17 | Bayer Cropscience Ag | Active ingredient combinations with insecticidal and acaricidal properties |
| CN102379299A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Ultralow volume liquid containing spirotetramat |
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