CN102428948A - Insecticidal composition containing clothianidin and acetamiprid - Google Patents
Insecticidal composition containing clothianidin and acetamiprid Download PDFInfo
- Publication number
- CN102428948A CN102428948A CN2011103830867A CN201110383086A CN102428948A CN 102428948 A CN102428948 A CN 102428948A CN 2011103830867 A CN2011103830867 A CN 2011103830867A CN 201110383086 A CN201110383086 A CN 201110383086A CN 102428948 A CN102428948 A CN 102428948A
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- CN
- China
- Prior art keywords
- acetamiprid
- thiophene worm
- worm amine
- medicine
- pesticidal combination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims abstract description 31
- PGOOBECODWQEAB-UHFFFAOYSA-N (E)-clothianidin Chemical compound [O-][N+](=O)\N=C(/NC)NCC1=CN=C(Cl)S1 PGOOBECODWQEAB-UHFFFAOYSA-N 0.000 title claims abstract description 10
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an insecticidal composition containing clothianidin and acetamiprid, which contains active components clothianidin and acetamiprid, and a proper amount of auxiliary agent is added into the composition to prepare wettable powder, water dispersible granules, suspending agent, suspending emulsion, emulsion in water and microemulsion, and is characterized in that: the weight ratio of the clothianidin to the acetamiprid serving as the effective active ingredients is 80: 1-1: 60. After the clothianidin and the acetamiprid are compounded, the composition has obvious synergistic action and continuous control effect, and has higher activity on pests on cereals, fruits, vegetables and cotton.
Description
Technical field
The invention belongs to technical field of pesticide, the Pesticidal combination that relates to a kind of clothianidin-containing and Acetamiprid is used to prevent and treat the application of crop pest.
Technical background
Thiophene worm amine (clothianidin), molecular formula: C
6H
8ClN
5O
2S, chemical name: (E)-1-(2-chloro-1,3-thiazoles-5-ylmethyl)-3-methyl-2-2-nitroguanidine.Thiophene worm amine is to carry out the world market exploitation jointly by Beyer Co., Ltd and Japanese Takeda Wu Tian company.Thiophene worm amine is a kind of insecticide in the anabasine, is the novel pesticide of one type of highly effective and safe, high selectivity, and its effect is similar with nAChR, have tag, stomach toxicity and systemic activity.Be mainly used on paddy rice, vegetables, fruit tree and other crops anti-ly eliminate aphis, the insecticide of Semiptera, coleoptera, diptera and some Lepidoptera class pest such as leafhopper, thrips, plant hopper; Have efficient, wide spectrum, consumption is few, toxicity is low, the drug effect lasting period long, to crop do not have poisoning, safe in utilization, do not have advantages such as cross resistance with conventional pesticide; Remarkable interior suction and osmosis are arranged, and are the another kinds that substitutes high malicious organophosphorous pesticide.Its novel structure, special, performance is compared more excellent with traditional nicotinic insecticide.
Acetamiprid (acetamiprid), molecular formula: C
10H
11ClN
4, chemical name: N-(N-cyanic acid-ethyleneimine base)-N-methyl-2-chloropyridine-5-methylamine, Acetamiprid belongs to the Nitromethylene heterocycle compound; Be a kind of novel pesticide, act on the nAChR at insect nervous system cynapse position, the neural stimulation conduction of interference insect; Cause the nervous system path blockade; Cause the accumulation of neurotransmitter acetylcholine, thereby cause the insect paralysis at the cynapse position, final dead.Have tag, stomach toxicity and stronger osmosis, desinsection is quick-acting, consumption is few, activity is high, insecticidal spectrum is wide, good with Environmental compatibility.Because its mechanism of action is different with common insecticides, so the insect of organic phosphor, carbamates and pyrethroid generation resistance is had special efficacy.To people and animals' low toxicity, little to natural enemy lethality, lower to fish toxicity, little to the honeybee influence, be applicable to the Semiptera insect on the various crop such as control fruit tree, vegetables; Do soil treatment with granule, can prevent and treat soil insect.
At present, thiophene worm amine and Acetamiprid composite and be applied in still unexposed mistake both at home and abroad.
Summary of the invention
Goal of the invention: in order to satisfy the needs of agricultural chemicals on producing; Make full use of two kinds of active components be mixed the synergistic effect that produced, improve preventive effect, reduce pesticide cost and delay the generation of pest resistance to insecticide, the present invention proposes the composite thiophene worm amine and the Pesticidal combination of Acetamiprid.The use of single agent in cultural control tends to exist a lot of defectives, and long-term a large amount of single uses can make the plant insects that medicament is produced resistance unavoidably, cause preventive effect reduction, dosage increasing, cost height, contaminated environment etc.And that the different activities composition carries out is composite, can effectively overcome above shortcoming.Simultaneously, the synergistic effect that utilizes two kinds of active components to be mixed to produce, can improve preventive effect, reduce active ingredient consumption, practice thrift drug cost, delay pest resistance to insecticide generation, reduce environmental pollution, be the important means of integrated control insect.
The objective of the invention is to realize like this: the Pesticidal combination of a kind of clothianidin-containing and Acetamiprid, comprise effective active component, auxiliary agent, it is characterized in that: active component thiophene worm amine, Acetamiprid weight ratio are 80: 1～1: 60.
Described Pesticidal combination is characterized in that: the weight ratio of thiophene worm amine and Acetamiprid is 60: 1～1: 40, is preferably 30: 1～1: 20.
Described Pesticidal combination is characterized in that: the weight ratio of thiophene worm amine and Acetamiprid is 20: 1～1: 15, is preferably 15: 1～1: 10, more preferably 8: 1～1: 5.
The described Pesticidal combination that contains thiophene worm amine is characterized in that: composition is processed wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion.
Composition is processed wetting powder and is comprised following constituent content: thiophene worm amine 1～80%, Acetamiprid 1～60%, dispersant 5～10%, wetting agent 2～10%, filler surplus.
The former medicine of thiophene worm amine, the former medicine of Acetamiprid, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, promptly can be made into present composition wetting powder.
Composition is processed water dispersible granules and is comprised following constituent content: thiophene worm amine 1～80%, Acetamiprid 1～60%, dispersant 3～12%, wetting agent 1～8%, disintegrant 1～10%, binding agent 1～8%, filler surplus.
The former medicine of thiophene worm amine, the former medicine of Acetamiprid, dispersant, wetting agent, disintegrant, filler etc. are obtained the particle diameter that needs through comminution by gas stream together, add other auxiliary agents such as binding agent again, obtain the materials of granulating.It is interior through after granulation and the drying to expect that article are quantitatively sent the fluidized bed granulation dryer to, makes present composition water dispersible granules.
When processing suspending agent, composition comprises following constituent content: thiophene worm amine 1～50%, Acetamiprid 1～40%, dispersant 2～10%; Wetting agent 2～10%, antifoaming agent 0.1～1%, thickener 0.1～2%; Antifreeze 0.1～8%, stabilizing agent 0.05～3%, deionized water adds to 100%.
Dispersant, wetting agent, antifoaming agent, thickener, antifreeze in the above-mentioned formulation material are mixed through high speed shear; Add the former medicine of thiophene worm amine, the former medicine of Acetamiprid; Ball milling is 2～3 hours in ball mill, makes diameter of particle all below 5 μ m, makes present composition suspending agent product.
Comprise following constituent content when composition is processed suspension emulsion: thiophene worm amine 1～50%, Acetamiprid 1～40%, emulsifier 2～12%, dispersant 2～10%, antifoaming agent 0.1～2%, thickener 0.1～2%, antifreeze 0.1～8%, stabilizing agent 0.05～3%, water add to 100%.
Dispersant, antifoaming agent, thickener, antifreeze, stabilizing agent in the above-mentioned formulation material are mixed through high speed shear; Add the former medicine of thiophene worm amine; Ball milling is 2～3 hours in ball mill, makes diameter of particle all below 5 μ m, makes thiophene worm amine suspending agent; Then with the former medicine of Acetamiprid, emulsifier and various auxiliary agent with the direct emulsification of high speed agitator in suspending agent, make the suspension emulsion product of the present composition.
When processing aqueous emulsion, composition comprises following constituent content: thiophene worm amine 1%～50%, Acetamiprid 1%～40%, solvent 2%～10%, emulsifier 2%～12%; Dispersant 2%～10%, co-emulsifier 0.2%～5%, antifreeze 0.1%～8%, antifoaming agent 0.1%～2%, thickener 0.1%～2%, deionized water adds to 100%.
Be dissolved into even oil phase with having former medicine, solvent, emulsifier, co-emulsifier to add together in the above-mentioned prescription, making.With deionized water, dispersant, antifreeze,, antifoaming agent, thickener mix, and becomes the homogeneous water, under high-speed stirred, water slowly splashed into oil phase, processes the finely disseminated aqueous emulsion product of the present composition.
When processing microemulsion, composition comprises following constituent content: thiophene worm amine 1%～50%, Acetamiprid 1%～40%, emulsifier 5%～15%, and solvent 2%～10%, antifreeze 5%～10%, stabilizing agent 0.5%～3%, deionized water adds to 100%.
Above-mentioned prescription Central Plains medicine, solvent, emulsifier are added in the mother liquor modulation kettle; Make even oil phase; Deionized water, antifreeze etc. is mixed injection product modulation kettle,, mix and process the transparent or semitransparent microemulsion product of the present composition through high-speed stirred.
Described dispersant is selected from alkylnaphthalene sulfonate; Two (alkyl) naphthalenesulfonate formaldehyde condensation compound; Naphthalene sulfonic acid-formaldehyde condensation product; Aryl phenol polyoxyethylene succinate sulfonate; Octylphenol polyethylene oxyethylene group ether sulfate; Polycarboxylate; Lignosulfonates; The alkylaryl APEO; Aliphatic alcohol polyethenoxy base ether; The phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy; Alkyl benzene sulfonate calcium salt; The naphthalene sulfonic acid-formaldehyde condensation product sodium salt; Alkylphenol-polyethenoxy is phonetic; Aliphatic amine polyoxyethylene is phonetic; Polyoxyethylene carboxylate; During the ester polyoxyethylene is phonetic one or more.
Described wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, sldium lauryl sulfate, tea are withered, in the silkworm excrement, soapberry powder one or more.
Described disintegrant is selected from: one or more in sodium bicarbonate, sodium carbonate, bentonite, urea, ammonium sulfate, glucose, the aluminium chloride.
Described thickener is selected from: one or more in CMC, hydroxyethylcellulose, Magnesiumaluminumsilicate, gelatin, melon glue, gum Arabic, xanthans, sodium phosphate trimer, phenolic resins, sodium alginate, white dextrin, methylcellulose, PAA, polyvinylpyrrolidone, PVPP, polyethylene glycol, the polyvinyl alcohol.
Described antifreeze is selected from: one or more in glycerine, ethylene glycol, propane diols, glycerine, diethylene glycol (DEG), triethylene glycol, the polyethylene glycol.
Described solvent is selected from: N, dinethylformamide, 3-methyl cyclohexanol ketenes, N-octylpyrrolidone, N-pyrrolidones, toluene, propyl alcohol, cyclohexanone, acetone, methyl alcohol, ethanol, butanols, EGME, butyl ether, ethyl acetate, vegetable oil, acetonitrile one or more.
Described antifoaming agent is selected from: silicone, C
8～10Aliphatic alcohols, C
10～20In saturated fat acids (like capric acid) and acid amides, silicone oil, the silicone compound one or more.
Described emulsifier is selected from: agricultural newborn 500# (alkyl benzene calcium sulfonate); OP series phosphate (NPE phosphate); 600# phosphate (phenyl phenol polyoxy ethyl ether phosphate); Styrene polyoxyethylene ether ammonium sulfate salt; Alkyl biphenyl ether disulfonic acid magnesium salts; Triethanolamine salt; Farming newborn 400# (benzyl dimethyl phenol polyoxy ethyl ether); Farming newborn 600# (phenyl phenol polyoxy ethyl ether); Nongru-700 # (alkylphenol-formaldehyde resin polyoxy ethyl ether); Farming newborn 36# (phenethyl fluosite polyoxy ethyl ether); Farming newborn 1600# (phenethyl phenol polyoxy ethyl polypropylene-base ether); Ethylene oxide-propylene oxide block copolymer; OP series (NPE); By series (castor oil polyoxyethylene ether); Farming newborn 33# (alkylaryl polyoxyethylene polyoxypropylene ether); Farming newborn 34# (alkylaryl polyoxyethylene poly-oxygen propylene aether); Sapn series (sorbitan monostearate); Tween series (sorbitan fatty acid ester APEO); In the AEO series (AEO) one or more.
Described stabilizing agent is selected from: one or more in BHT, triphenyl phosphite, epoxychloropropane, organic acid, organic base, ester class, alcohols, antioxidant, surface-active substance, tributyl phosphate, triethanolamine, diethanol amine, the monoethanolamine.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
Described Pesticidal combination is used for rice fulgorid, Lissorhoptrus oryzophilus Kuschel, various aphid, thrips, Bemisia tabaci, trialeurodes vaporariorum, light lyonetid, tangerine lyonetid, oriental fruit moth, peach fruit borer, diamond-back moth, cabbage caterpillar, beet armyworm, prodenia litura, cotton bollworm, cigarette beetle, pink bollworm, corn borer, pink rice borer.
The invention has the advantages that: (1) thiophene worm amine is different fully to the mechanism of action of target pest with Acetamiprid, and both are composite to have notable synergistic and lasting effect; (2) enlarged insecticidal spectrum; Insect on cereal class, fruits and vegetables, the cotton all there is greater activity, like rice fulgorid, Lissorhoptrus oryzophilus Kuschel, various aphid, thrips, Bemisia tabaci, trialeurodes vaporariorum, light lyonetid, tangerine lyonetid, oriental fruit moth, peach fruit borer, diamond-back moth, cabbage caterpillar, beet armyworm, prodenia litura, cotton bollworm, cigarette beetle, pink bollworm, corn borer, pink rice borer; (3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution; (4) not with an organic solvent, to the person poultry safety, Environmental compatibility is good, and insect is difficult for developing immunity to drugs.
Embodiment
The present invention is explained further that the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
The embodiment of the invention is the method that adopts Toxicity Determination and field control effectiveness test to combine.Pass through Toxicity Determination earlier, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80≤CTC≤120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field control effectiveness test again.
Experimental scheme: adopt and to soak the method that connects worm behind the leaf earlier, the of the same size fresh blade that does not contact any medicament is soaked taking-up behind the 5s, dries naturally in the soup that configures, put into insect box; Connect then and supply examination 3 instar larvaes, under 25 ℃ of conditions, raise, every processing repeats for 3 times; Every to repeat used examination borer population be 20, establishes blank simultaneously, checks dead borer population in 72h; Calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50Value.If the contrast lethality then is regarded as invalid test greater than 10%.Computing formula is following:
The insect corrected mortality is converted into probit value (y), and concentration of treatment (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates the value of every kind of medicament thus.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula is (with thiophene worm amine is the standard medicament, and its toxicity index is 100) as follows:
TI * the P of the theoretical toxicity index (TTI) of M=thiophene worm amine
Thiophene worm amineTI * the P of+Acetamiprid
Acetamiprid
In the formula: M is the mixture of different proportionings
P
AcetamipridBe Acetamiprid shared ratio in composition
P
Thiophene worm amineBe thiophene worm amine shared ratio in composition
A is selected from thiophene worm amine;
B is selected from Acetamiprid.
Practice example one:
Supply the examination insect: beet armyworm.
Test medicine: Shaanxi agricultural chemicals Co., Ltd of U.S. nation provides.
Experimental scheme: effective lethal concentration scope of confirming thiophene worm amine, the former medicine of Acetamiprid and the two different proportioning mixture through preliminary experiment.
The different proportionings with Acetamiprid of table 1 thiophene worm amine are to the toxicity test of beet armyworm
Can know by table 1; Thiophene worm amine and Acetamiprid and composite to beet armyworm Toxicity Determination experiment discovery; Co-toxicity coefficient is all greater than 120 when thiophene worm amine and Acetamiprid proportioning are 80: 1 to 1: 60; Show obvious synergistic effect; Especially when thiophene worm amine and Acetamiprid proportioning during at 3: 1 to 1: 3; Synergistic effect is obviously outstanding; So when thiophene worm amine: Acetamiprid all had synergistic function between 80: 1 to 1: 60, especially when thiophene worm amine: during Acetamiprid=2: 1, the co-toxicity coefficient maximum; Synergistic effect is the most obvious; The applicant to paddy rice small brown rice planthopper, rice white-backed planthopper, brown plant-hopper, Lissorhoptrus oryzophilus Kuschel, cabbage caterpillar, diamond-back moth, various aphid, prodenia litura, thrips, cotton bollworm, cigarette beetle, pink bollworm, corn borer, pink rice borer, trialeurodes vaporariorum, Bemisia tabaci also had good synergistic effect at 80: 1～1: 60 in the scope when the weight ratio of thiophene worm amine and Acetamiprid through overtesting, and co-toxicity coefficient is all greater than 120, and it is obvious synergistic effect in 15: 1,14: 1,13: 1,12: 1,11: 1,10: 1,9: 1,8: 1,7: 1,6: 1,5: 1,4: 1,3: 1,2: 1,1: 1,1: 2,1: 3,1: 4,1: 5,1: 6,1: 7,1: 8,1: 9,1: 10 particularly to work as thiophene worm amine and Acetamiprid proportioning.
Application implementation example two
The 81% thiophene worm amine Acetamiprid wetting powder control cabbage pieris test of pesticide effectiveness
Thiophene worm amine 75%, Acetamiprid 6%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%; Tea is withered 3%, and kaolin adds to 100%, and the aforementioned formula material is mixed; In stirred tank, evenly stir, behind airslide disintegrating mill, mix again, promptly make 81% thiophene worm amine Acetamiprid wetting powder.This prescription is pressed preparation dosage 12 gram/mus dilution spraying; 72 hours control cabbage pieris effects are 99.53% behind the medicine; And 50% thiophene worm amine water dispersible granules and 20% Acetamiprid wetting powder are according to same quadrat method; Press the dilution of preparation dosage 10 gram/mus and 12.5 gram/mus respectively and use, 72 hours control efficiency are respectively 68.57% and 69.87% behind the medicine.
The application implementation example 3 55% thiophene worm amine Acetamiprid wetting powders control brassicaceous vegetable beet armyworm test of pesticide effectiveness
Thiophene worm amine 22.5%, Acetamiprid 22.5%, aliphatic amine polyoxyethylene phonetic 6%; Sldium lauryl sulfate 5%, diatomite adds to 100%, and the aforementioned formula material is mixed; In stirred tank, evenly stir, after airslide disintegrating mill is pulverized, mixing, make 55% thiophene worm amine Acetamiprid wetting powder.This prescription is pressed preparation dosage 11 gram/mus dilution spraying; 72 hours control brassicaceous vegetable beet armyworm effects are 98.84% behind the medicine; 50% thiophene worm amine water dispersible granules and 20% Acetamiprid wetting powder are according to same quadrat method; Press the dilution of preparation dosage 12 gram/mus and 13 gram/mus respectively and use, 72 hours preventive effects are respectively 67.85% and 65.78% behind the medicine.
Application implementation example four
The 61% thiophene worm amine Acetamiprid wetting powder control paddy rice thrips test of pesticide effectiveness
Thiophene worm amine 60%, Acetamiprid 1%, alkylphenol-polyethenoxy phonetic 5%; Wetting and penetrating agent F4%, bentonite adds to 100%, and the aforementioned formula material is mixed; In stirred tank, evenly stir, behind airslide disintegrating mill, mixing, make 61% thiophene worm amine Acetamiprid wetting powder.This prescription is pressed preparation dosage 8 gram/mus dilution spraying; 72 hours control paddy rice thrips effects are 98.88% behind the medicine; 50% thiophene worm amine water dispersible granules and 20% Acetamiprid wetting powder are according to same quadrat method; Press the dilution of preparation dosage 15 gram/mus and 10 gram/mus respectively and use, 72 hours preventive effects are respectively 68.75% and 65.24% behind the medicine.
Application implementation example five
The 35% thiophene worm amine acetamiprid water dispersible granules control brassicaceous vegetable cabbage caterpillar test of pesticide effectiveness
Thiophene worm amine 25%, Acetamiprid 10%, lignosulfonates 8%; Lauryl sodium sulfate 6%, sodium carbonate 2%, methylcellulose 5%; Bentonite adds to 100%; The aforementioned formula material is evenly mixed, use micro jet, carry out granulation, drying, screening in the fluidized bed prilling dryer after the mixed 35% thiophene worm amine acetamiprid water dispersible granules that gets of sample analysis through mediating, adding then.This proportioning is pressed preparation dosage 10 gram/mus dilution spraying; 72 hours control efficiency are 98.57% behind the medicine; 50% thiophene worm amine water dispersible granules and 20% Acetamiprid wetting powder are according to same quadrat method; Press the dilution of preparation dosage 15 gram/mus and 12 gram/mus respectively and use, 72 hours preventive effects are respectively 68.13% and 64.24% behind the medicine.
Application implementation example six
The 60% thiophene worm amine acetamiprid water dispersible granules control paddy rice small brown rice planthopper test of pesticide effectiveness
Thiophene worm amine 30%, Acetamiprid 30%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%; Nekal BX 5%, aluminium chloride 2.8%, PAA 2%; Kaolin adds to 100%; The aforementioned formula material is evenly mixed, use micro jet, carry out granulation, drying, screening in the fluidized bed prilling dryer after the mixed 60% thiophene worm amine acetamiprid water dispersible granules that gets of sample analysis through mediating, adding then.This proportioning is pressed preparation dosage 9 gram/mus dilution spraying; 72 hours control efficiency are 98.35% behind the medicine; 50% thiophene worm amine water dispersible granules and 20% Acetamiprid wetting powder are according to same quadrat method; Press the dilution of preparation dosage 18 gram/mus and 15 gram/mus respectively and use, 72 hours preventive effects are respectively 68.65% and 67.24% behind the medicine.
Application implementation example seven
The 75% thiophene worm amine acetamiprid water dispersible granules control cotton cotton bollworm test of pesticide effectiveness
Thiophene worm amine 25%, Acetamiprid 50%, ester polyoxyethylene phonetic 7.8%; Sldium lauryl sulfate 4.2%, urea 3%, gum Arabic 3%; White carbon adds to 100%; The aforementioned formula material is evenly mixed, use micro jet, through mediating, adding then and carry out granulation, drying, screening in the fluidized bed prilling dryer after sample analysis promptly makes 75% thiophene worm amine acetamiprid water dispersible granules.This prescription is pressed preparation dosage 8.5 gram/mu liquid dilution spraying; 72 hours control efficiency are 99.35% behind the medicine; And 50% thiophene worm amine water dispersible granules and 20% Acetamiprid wetting powder are according to same quadrat method; Press the dilution of preparation dosage 15 gram/mus and 13 gram/mu liquid respectively and use, 72 hours control efficiency are respectively 66.24% and 65.88% behind the medicine.
Application implementation example eight
The 25% thiophene worm amine acetamiprid suspending agent control wild cabbage diamond-back moth test of pesticide effectiveness
Thiophene worm amine 15%, Acetamiprid 10%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, C
8～10Aliphatic alcohols 0.3%, methylcellulose 0.9%, glycerine 2.5%; Deionized water adds to 100%, and thickener and antifreezing agent are mixed back all the other components except that crossing active ingredient, mixes through high speed shear; Add active ingredient; Ball milling is 2～3 hours in ball mill, makes particle diameter all below 5 μ m, promptly makes 25% thiophene worm amine acetamiprid suspending agent.This proportioning is pressed preparation dosage 15g/ mu dilution spraying; 72 hours control efficiency are 98.72% behind the medicine; 50% thiophene worm amine water dispersible granules and 20% Acetamiprid wetting powder are according to same quadrat method; Press preparation dosage 18g/ mu and 15g/ mu respectively and use, 72 hours preventive effects are respectively 68.85% and 66.27% behind the medicine.
Application implementation example nine
The 20% thiophene worm amine acetamiprid suspending agent control paddy rice brown planthopper test of pesticide effectiveness
Thiophene worm amine 15%, Acetamiprid 5%, aryl phenol polyoxyethylene succinate sulfonate 7%, lauryl sodium sulfate 3%; Silicone compound 0.1%, monoethanolamine 1.5%, deionized water adds to 100%; Thickener and antifreezing agent are mixed back all the other components except that crossing active ingredient, mix, add active ingredient through high speed shear; Ball milling is 2～3 hours in ball mill, makes particle diameter all below 5 μ m, promptly makes 20% thiophene worm amine acetamiprid suspending agent.This proportioning is pressed preparation dosage 17g/ mu dilution spraying; 72 hours control efficiency are 98.75% behind the medicine; 50% thiophene worm amine water dispersible granules and 20% Acetamiprid wetting powder are according to same quadrat method; Press preparation dosage 16g/ mu and 12g/ mu respectively and use, 72 hours preventive effects are respectively 67.68% and 68.24% behind the medicine.
Application implementation example ten
The 35% thiophene worm amine acetamiprid suspending agent control beet armyworm test of pesticide effectiveness
Thiophene worm amine 20%, Acetamiprid 15%, lignosulfonates 7%, wetting agent T6%, silicone 0.8%, glycerine 2.5%, monoethanolamine 1.5%, deionized water adds to 100%, the mixed 35% thiophene worm amine acetamiprid suspending agent that gets.This proportioning is pressed preparation dosage 13g/ mu dilution spraying; 72 hours control efficiency are 98.21% behind the medicine; 50% thiophene worm amine water dispersible granules and 20% Acetamiprid wetting powder are according to same quadrat method; Press preparation dosage 15g/ mu and 12g/ mu respectively and use, 72 hours preventive effects are respectively 67.62% and 65.18% behind the medicine.
Application implementation example 11
The 10% thiophene worm amine Acetamiprid suspension emulsion control tangerine lyonetid test of pesticide effectiveness
Thiophene worm amine 8%, Acetamiprid 2%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, alkyl biphenyl ether disulfonic acid magnesium salts 1.2%, ethylene glycol 2.8%, C
8～10Aliphatic alcohols 0.8%, monoethanolamine 1.8%, water adds to 100%, the mixed 10% thiophene worm amine Acetamiprid suspension emulsion that gets.This prescription is pressed preparation dosage 15g/ mu dilution spraying; 72 hours control tangerine lyonetid effects are 97.45% behind the medicine; And 50% thiophene worm amine water dispersible granules and 20% Acetamiprid wetting powder are according to same quadrat method; Press preparation dosage 25g/ mu and 18g/ mu respectively and use, 72 hours control efficiency are respectively 69.14% and 63.43% behind the medicine.
Application implementation example 12
The 20% thiophene worm amine Acetamiprid suspension emulsion control of maize striped rice borer test of pesticide effectiveness
Thiophene worm amine 5%, Acetamiprid 15%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, tween series 5%, gum Arabic 1%, glycerine 2.5%, monoethanolamine 1.5%, silicone oil 0.8%, water adds to 100%, the mixed 20% thiophene worm amine Acetamiprid suspension emulsion that gets.This prescription is pressed preparation dosage 18g/ mu dilution spraying; 72 hours control of maize snout moth's larva effects 98.36% behind the medicine; And 50% thiophene worm amine water dispersible granules and 20% Acetamiprid wetting powder be according to using with quadrat method preparation dosage 20g/ mu and 16g/ mu, and 72 hours control efficiency are respectively 65.57% and 68.35% behind the medicine.
Application implementation example 13
30% thiophene worm amine Acetamiprid suspension emulsion control brassicaceous vegetable diamond-back moth test of pesticide effectiveness thiophene worm amine 10%, Acetamiprid 20%, NPE 7%, lignosulfonates 3%, C
8～10Aliphatic alcohols 1.5%, methylcellulose 1.5%, triethylene glycol 2%, silicone 0.5%, water adds to 100%, the mixed 30% thiophene worm amine Acetamiprid suspension emulsion that gets.This prescription is pressed preparation dosage 13g/ mu dilution spraying; 72 hours control brassicaceous vegetable diamond-back moth effects are 99.47% behind the medicine; And 50% thiophene worm amine water dispersible granules and 20% Acetamiprid wetting powder be according to using with quadrat method preparation dosage 20g/ mu and 15g/ mu, and 72 hours control efficiency are respectively 68.15% and 65.83% behind the medicine.
Application example 14
The 20% thiophene worm amine acetamiprid micro emulsion agent control eggplant thrips test of pesticide effectiveness
Thiophene worm amine 10%, Acetamiprid 10%, phenyl phenol polyoxy ethyl ether phosphate 10%; N; Dinethylformamide 6%, ethylene oxide-propylene oxide block copolymer 4%, propane diols 6%, monoethanolamine 2%, deionized water add to 100%, process 20% thiophene worm amine acetamiprid micro emulsion agent.This proportioning is by 15 gram/mus dilution spraying; 72 hours control eggplant thrips effects are 98.79% behind the medicine; 50% thiophene worm amine water dispersible granules and 20% Acetamiprid wetting powder are according to using by 18 gram/mus and the dilution of 20 gram/mus respectively with quadrat method, and 72 hours preventive effects are respectively 65.51% and 66.48% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example 15
The 25% thiophene worm amine acetamiprid micro emulsion agent control Chinese cabbage diamond-back moth test of pesticide effectiveness
Thiophene worm amine 15%, Acetamiprid 10%, 3-methyl cyclohexanol ketenes 5%, phenyl phenol polyoxy ethyl ether phosphate 4%, C
8～10Aliphatic alcohols 0.2%, BHT 2.5%, polyethylene glycol 2%, deionized water add to 100%, process 25% thiophene worm amine acetamiprid micro emulsion agent.This proportioning is by 8 gram/mus dilution spraying; 72 hours control Chinese cabbage diamond-back moth effects are 99.23% behind the medicine; 50% thiophene worm amine water dispersible granules and 20% Acetamiprid wetting powder are according to using by 15 gram/mus and the dilution of 13 gram/mus respectively with quadrat method, and 72 hours preventive effects are respectively 68.47% and 65.26% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.Application example 16
The 36% thiophene worm amine acetamiprid micro emulsion agent control paddy rice small brown rice planthopper test of pesticide effectiveness
Thiophene worm amine 6%, Acetamiprid 30%, N-octylpyrrolidone 5%, phenyl phenol polyoxy ethyl ether 7%, AEO series 3%, silicone oil 0.2%, xanthans 1.8%, ethanol 3%, deionized water add to 100%, process 36% thiophene worm amine acetamiprid micro emulsion agent.This proportioning is by 13 gram/mus dilution spraying; 72 hours control paddy rice small brown rice planthopper effects are 98.37% behind the medicine; 50% thiophene worm amine water dispersible granules and 20% Acetamiprid wetting powder are according to using by 18 gram/mus and the dilution of 15 gram/mus respectively with quadrat method, and 72 hours preventive effects are respectively 64.97% and 67.45% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example 17
The 18% thiophene worm amine Acetamiprid aqueous emulsion control cotton pink bollworm test of pesticide effectiveness
Thiophene worm amine 6%, Acetamiprid 12%, OP series 4%, propyl alcohol 7%, agricultural newborn 600#3%, xanthans 0.7%, propane diols 2.4%, toluene 4%, deionized water add to 100%, process 18% thiophene worm amine Acetamiprid aqueous emulsion.This proportioning is by 12 gram/mus dilution spraying; 72 hours control cotton pink bollworm effects are 98.68% behind the medicine; 50% thiophene worm amine water dispersible granules and 20% Acetamiprid wetting powder are according to using by 15 gram/mus and the dilution of 10 gram/mus respectively with quadrat method, and 72 hours preventive effects are respectively 67.31% and 65.42% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example 18
The 25% thiophene worm amine Acetamiprid aqueous emulsion control Lissorhoptrus oryzophilus Kuschel test of pesticide effectiveness
Thiophene worm amine 12.5%, Acetamiprid 12.5%, agricultural newborn 33#4%, 600# phosphate 6%, acetone 5%, propane diols 2.5%, xanthans 0.9%, vegetable oil 3%, deionized water add to 100%, process 25% thiophene worm amine Acetamiprid aqueous emulsion.This proportioning is by 20 gram/mus dilution spraying; 72 hours control Lissorhoptrus oryzophilus Kuschel effects are 97.84% behind the medicine; 50% thiophene worm amine water dispersible granules and 20% Acetamiprid wetting powder are according to using by 25 gram/mus and the dilution of 18 gram/mus respectively with quadrat method, and 72 hours preventive effects are respectively 70.27% and 69.75% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Application example 19
The 30% thiophene worm amine Acetamiprid aqueous emulsion control wild cabbage diamond-back moth test of pesticide effectiveness
Thiophene worm amine 20%, Acetamiprid 10%, agricultural newborn 1600#6%, By series 3%, toluene 6%, propane diols 2.5%, polyvinyl alcohol 1%, acetonitrile 2%, deionized water add to 100%, process 30% thiophene worm amine Acetamiprid aqueous emulsion.This proportioning is by 15 gram/mus dilution spraying; 72 hours control wild cabbage diamond-back moth effects are 97.89% behind the medicine; 50% thiophene worm amine water dispersible granules and 20% Acetamiprid wetting powder are according to using by 18 gram/mus and the dilution of 15 gram/mus respectively with quadrat method, and 72 hours preventive effects are respectively 65.54% and 63.27% behind the medicine.In experiment, the inventor does not find that test medicine has harmful effect to crop, to beneficial insect safety.
Wetting powder the key technical indexes of the present invention:
Water dispersible granules the key technical indexes of the present invention:
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Claims (6)
1. the Pesticidal combination of clothianidin-containing and Acetamiprid comprises effective active component, auxiliary agent and filler, and it is characterized in that: active component thiophene worm amine, Acetamiprid weight ratio are 80: 1～1: 60.
2. Pesticidal combination according to claim 1 is characterized in that: the weight ratio of thiophene worm amine and Acetamiprid is 60: 1～1: 40.
3. Pesticidal combination according to claim 2 is characterized in that: the weight ratio of thiophene worm amine and Acetamiprid is 30: 1～1: 20.
4. Pesticidal combination according to claim 1 is characterized in that: composition is processed wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion.
5. the Pesticidal combination that contains thiophene worm amine according to claim 1 is used to prevent and treat the purposes on cereal class, fruits and vegetables, the cotton-plant pest-insects.
6. purposes according to claim 5 is characterized in that: described insect comprises rice fulgorid, Lissorhoptrus oryzophilus Kuschel, aphid, thrips, Bemisia tabaci, trialeurodes vaporariorum, light lyonetid, tangerine lyonetid, oriental fruit moth, peach fruit borer, diamond-back moth, cabbage caterpillar, beet armyworm, prodenia litura, cotton bollworm, cigarette beetle, pink bollworm, corn borer, pink rice borer.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103621544A (en) * | 2012-08-29 | 2014-03-12 | 南京华洲药业有限公司 | Synergistic insecticidal composition containing clothianidin and acetamiprid and applications thereof |
| CN116058366A (en) * | 2022-12-28 | 2023-05-05 | 山东潍坊润丰化工股份有限公司 | Acetamiprid and lambda-cyhalothrin-containing aqueous emulsion and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005036966A1 (en) * | 2003-10-13 | 2005-04-28 | Bayer Cropscience Aktiengesellschaft | Synergistic insecticide mixtures |
| CN101304659A (en) * | 2005-11-10 | 2008-11-12 | 拜尔农作物科学股份公司 | Synergistic insecticidal mixtures for seed treatment |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005036966A1 (en) * | 2003-10-13 | 2005-04-28 | Bayer Cropscience Aktiengesellschaft | Synergistic insecticide mixtures |
| CN101304659A (en) * | 2005-11-10 | 2008-11-12 | 拜尔农作物科学股份公司 | Synergistic insecticidal mixtures for seed treatment |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103621544A (en) * | 2012-08-29 | 2014-03-12 | 南京华洲药业有限公司 | Synergistic insecticidal composition containing clothianidin and acetamiprid and applications thereof |
| CN116058366A (en) * | 2022-12-28 | 2023-05-05 | 山东潍坊润丰化工股份有限公司 | Acetamiprid and lambda-cyhalothrin-containing aqueous emulsion and preparation method thereof |
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Application publication date: 20120502 |