CN103355300A - High-efficiency insecticide composition - Google Patents
High-efficiency insecticide composition Download PDFInfo
- Publication number
- CN103355300A CN103355300A CN2012100949756A CN201210094975A CN103355300A CN 103355300 A CN103355300 A CN 103355300A CN 2012100949756 A CN2012100949756 A CN 2012100949756A CN 201210094975 A CN201210094975 A CN 201210094975A CN 103355300 A CN103355300 A CN 103355300A
- Authority
- CN
- China
- Prior art keywords
- pyridalyl
- worm hydrazides
- methoxyfenozide
- furan tebufenozide
- chlorine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000203 mixture Substances 0.000 title claims abstract description 67
- 239000002917 insecticide Substances 0.000 title claims abstract description 23
- 239000005926 Pyridalyl Substances 0.000 claims abstract description 191
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- 239000005917 Methoxyfenozide Substances 0.000 claims abstract description 130
- QCAWEPFNJXQPAN-UHFFFAOYSA-N methoxyfenozide Chemical compound COC1=CC=CC(C(=O)NN(C(=O)C=2C=C(C)C=C(C)C=2)C(C)(C)C)=C1C QCAWEPFNJXQPAN-UHFFFAOYSA-N 0.000 claims abstract description 102
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Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a high-efficiency insecticide composition which is mainly characterized by comprising an active constituent A and an active constituent B, wherein the active constituent A is pyridalyl, and the active constituent B is any one of methoxyfenozide, fufenozide, halofenozide and chromafenozide; the weight ratio of the active constituent A to the active constituent B is 1:80-80:1; the composition can be prepared into wettable powder, water dispersible granules, suspension, suspoemulsion, emulsion in water, microemulsion, microcapsule suspension or aqueous capsule suspension. The composition can be used for preventing and treating multiple insects on rice, wheat, cotton, fruit trees, vegetables, flowers and corns and has an obvious synergism effect; the using amount of insecticides is reduced; the composition is safe to human and livestock, does not have phytotoxicity and is high in environmental compatibility, high in bonding strength and high in rain-wash resistance.
Description
Technical field
The invention belongs to technical field of pesticide, relate to the application that a kind of efficient pesticides composition is used for the control crop pest.
Background technology
Pyridalyl (pyridalyl) chemical name: 2-[3-[2,6-two chloro-4-[(3,3-two chloro-2-acrylic) the oxygen base] phenoxy group] propoxyl group]-5-(trifluoromethyl) pyrimidine, molecular formula: C
32H
14F
3NO
3Pyridalyl has and has the diverse structure of insecticide now, and the many lepidoptera pests on vegetables and the cotton are had remarkable insecticidal activity.Have simultaneously the effect of tagging with stomach toxicity, lepidoptera pest is had original preventive effect, thrips is also demonstrated certain activity, and pyridalyl is very little on various arthropodan impacts, so it is expected to become an effective instrument in integrated pest management.
Methoxyfenozide (methoxyfenozide), chemical name: the N-tert-butyl group-N'-(3-methyl-2-toluyl groups)-3,5-dimethyl benzene formylhydrazine.Methoxyfenozide is a kind of macrolide disaccharide compounds.Insect growth regulator, IGR a kind of.The moulting hormone insecticides suppresses to ingest.Even mainly be that the normal growth of interference insect grows that insect casts off a skin and dead.
Furan tebufenozide; chemistry N-(2 by name; 3-7-hydrogen 1; the 7-dimethyl. benzofuran .6 one formoxyl) a N ' tertiary butyl .N '. (3; 5 dimethylbenzoyls) hydrazine; furan tebufenozide has the moulting hormone regulating and controlling effect that bishydrazide compounds generally has as the N one tertiary butyl bishydrazide compounds that contains the benzofuran ring.The Main Ingredients and Appearance of insect moulting hormones is steroid hormone 20-hydroxyl ecdysone, and this is peculiar a kind of somatotropin in the arthropods body.When 20-hydroxyl ecdysone concentration raises, larva enters the stage of casting off a skin, this moment, larva stopped feed, epidermal cell is recombinated, by combining closely with ecdysone receptor albumen, activated receptor albumen, the ecdysial fluid that contains the multiple protein hydrolase enters the space of casting off a skin, it is synthetic that epidermal cell increases protein, generates new epicuticle and cuticula.When 20-hydroxyl ecdysone concentration reduced, insect grew and enters next stage, comprises the activation of enzyme in the ecdysial fluid, the digestion of procuticle and the again absorption of ecdysial fluid.Along with the further reduction of its concentration, finish needed other hormone of the process of casting off a skin and be released, insect recovers feed thereupon.
Chlorine worm hydrazides (halofenozide), chemical molecular formula: C
18H
19CLN
2O
2, chlorine worm hydrazides Main Function limits casting off a skin in the ecdysone receptor of insect.Absorption in having well, Main Function causes too early casting off a skin in the larva of insect; Adult is processed, can reduce fertility; Also has certain ovicidal activity.
Ring worm hydrazides (chromafenozid), molecular formula: C
24H
30N
2O
3, ring worm hydrazides is the bishydrazide insecticide, insect takes food and suppresses feed in rear several hours, causes simultaneously that insect casts off a skin in advance to cause death.It causes the death of casting off a skin too early of insect by regulating the process of casting off a skin of young hormone and moulting hormone moving obstacle insect.Because it can suppress the feed of insect fast, with respect to other similar medicaments commonly used, can reduce the harm to crop.To the caterpillar of noctuid and other, no matter in which, ring worm hydrazides has very strong insecticidal activity in period.
In the real process of agricultural production, pest control, evil the mite problem of easy generation are drug-fast generations.The different cultivars composition carries out composite, is control resistant insect, the very common method of evil mite.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals all is additive effect, and the seldom composite of synergistic effect really arranged, especially synergistic effect very obviously, co-toxicity coefficient very high composite just still less.Find that through inventor's lot of experiments after pyridalyl and methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides were composite, synergistic effect was remarkable, Environmental compatibility is fabulous, has greatly reduced the agricultural chemicals dosage.
Summary of the invention
The insecticides that the present invention proposes any one two kinds of active components, also comprises an amount of surfactant and carrier in comprising pyridalyl and methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides.
A kind of efficient pesticides composition, comprise active components A, active component B, it is characterized in that: active components A is pyridalyl, active component B is a kind of arbitrarily in methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, the ring worm hydrazides, and the weight ratio of active components A and active component B is 1:80 ~ 80:1.
Described insecticides is characterized in that: the weight ratio of active components A and active component B is 1:40 ~ 40:1.
Described insecticides is characterized in that: the weight ratio of pyridalyl and methoxyfenozide is 1:10 ~ 10:1.
Described insecticides is characterized in that: the weight ratio of pyridalyl and furan tebufenozide is 1:10 ~ 10:1.
Described insecticides is characterized in that: the weight ratio of pyridalyl and chlorine worm hydrazides is 1:20 ~ 10:1.
Described insecticides is characterized in that: the weight ratio of pyridalyl and ring worm hydrazides is 1:10 ~ 10:1.
Described insecticides is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, micro-capsule suspension, microcapsule suspension-suspending agent.
Described insecticides is used for the application of control crop pests, and described crops comprise paddy rice, wheat, cotton, fruit tree, vegetables, tea tree, flowers, corn.
Described application, pest control comprises: rice leaf roller, striped rice borer, paddy stem borer, pink rice borer, rice fulgorid, diamond-back moth, cabbage caterpillar, prodenia litura, beet armyworm, 2 entrust noctuid, cotton bollworm, pink bollworm, thrips.
At least comprise a kind of surfactant in the insecticides of the present invention, the dispersion of active component in water when being beneficial to use.Surface-active contents is 5%～30% of total formulation weight amount, and surplus is solid or liquid diluent.The selected surfactant of insecticides of the present invention is known in those skilled in the art: can be selected from one or more in dispersant, wetting agent, emulsifier or the defoamer.
Comprise following constituent content when making wetting powder: active components A 1% ~ 80%, active component B 1% ~ 80%, dispersant 3% ~ 15%, wetting agent 2% ~ 10%, filler surplus.
When making water dispersible granules, composition comprises following constituent content: active components A 1% ~ 80%, active component B 1% ~ 80%, dispersant 3% ~ 12%, wetting agent 1% ~ 10%, disintegrant 1% ~ 10%, binding agent 0 ~ 8%, filler surplus.
Comprise following constituent content when composition is made suspending agent: active components A 1% ~ 60%, active component B 1% ~ 60%, dispersant 2 ~ 10%, wetting agent 2 ~ 10%, defoamer 0.1 ~ 2%, thickener 0.05 ~ 2%, antifreeze 0 ~ 8%, deionized water add to 100%.
Comprise following constituent content when composition is made suspension emulsion: active components A 1% ~ 60%, active component B 1% ~ 60%, emulsifier 2% ~ 12%, dispersant 2% ~ 10%, defoamer 0.1% ~ 2%, thickener 0.05% ~ 2%, antifreeze 0% ~ 8%, stabilizing agent 0% ~ 5%, solvent 0% ~ 15%, deionized water add to 100%.
Comprise following constituent content when composition is made aqueous emulsion: active components A 1% ~ 60%, active component B 1% ~ 60%, solvent 0% ~ 30%, emulsifier 1% ~ 15%, antifreeze 0% ~ 10%, thickener 0.05% ~ 2%, defoamer 0.01% ~ 2%, deionized water are supplied surplus.
When making microemulsion, composition comprises following constituent content active components A 1% ~ 60%, active component B 1% ~ 60%, solvent 0% ~ 30%, emulsifier 3% ~ 20%, antifreeze 0% ~ 10%, thickener 0% ~ 2%, defoamer 0.01% ~ 2%, stabilizing agent 0% ~ 4%, the deionized water surplus.
Composition is made micro-capsule suspension and is comprised following constituent content: active components A 1% ~ 60%, active component B 1% ~ 60%, macromolecule cyst material 1% ~ 12%, surfactant 2% ~ 10%, organic solvent 1% ~ 15%, emulsifier 1% ~ 8%, pH adjusting agent 0.1% ~ 5%, deionized water adds to 100%.
Composition comprises following constituent content when making microcapsule suspension-suspending agent: active components A 1% ~ 60%, active component B1% ~ 60%, macromolecule cyst material 2% ~ 12%, surfactant 3% ~ 15%, organic solvent 1% ~ 5%, emulsifier 1% ~ 6%, defoamer 0.1% ~ 5%, thickener 0.05% ~ 2%, pH adjusting agent 0.1% ~ 5%, water add to 100%.
Wetting powder the key technical indexes of the present invention:
| Technical indicator | Dispersed | Suspensibility | The moistening time | Fineness (by 45 μ m testing sieves) | Water content |
| All examples of the present invention | ≥90% | ≥90% | ≤ 90 seconds | ≥98% | ≤2% |
| The Pesticidal products specification requirement | ≥80% | ≥60% | ≤ 120 seconds | ≥5% | ≤3% |
Water dispersible granules the key technical indexes of the present invention:
| Technical indicator | Dispersed | Suspensibility | The moistening time | Fineness (by 55 μ m testing sieves) | Water content |
| All examples of the present invention | ≥90% | ≥90% | ≤ 60 seconds | ≥99% | ≤1.5% |
| The Pesticidal products specification requirement | ≥80% | ≥60% | ≤ 120 seconds | ≥95% | ≤3% |
Suspending agent the key technical indexes of the present invention:
Suspension emulsion the key technical indexes of the present invention:
Aqueous emulsion the key technical indexes of the present invention:
Microemulsion the key technical indexes of the present invention:
Microcapsule suspending agent the key technical indexes of the present invention:
Microcapsule suspension of the present invention-suspending agent the key technical indexes:
The invention has the advantages that:
(1) pyridalyl and methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides composite after, have notable synergistic and lasting effect;
(2) enlarged the control spectrum, the rice leaf roller on paddy rice, wheat, cotton, fruit tree, vegetables, tea tree, flowers, the corn, striped rice borer, paddy stem borer, pink rice borer, rice fulgorid, diamond-back moth, cabbage caterpillar, prodenia litura, beet armyworm, 2 various pests such as noctuid, cotton bollworm, pink bollworm, thrips of entrusting have been had good preventive effect.
(3) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution;
(4) to the person poultry safety, Environmental compatibility is good, is difficult for developing immunity to drugs.
Embodiment
To further instruction of the present invention, the percentage among the embodiment all is weight percentage below in conjunction with embodiment, but the present invention is not limited thereto.
Application Example one
Embodiment 181% pyridalyl methoxyfenozide wetting powder
Pyridalyl 1%, methoxyfenozide 80%, aryl phenol polyoxyethylene succinate sulfonate 6%, soapberry powder 4%, kaolin add to 100%, and mixture carries out air-flow crushing, make 81% pyridalyl methoxyfenozide wetting powder.
Methoxyfenozide is changed to furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 260% pyridalyl methoxyfenozide wetting powder
Pyridalyl 30%, methoxyfenozide 30%, aryl phenol polyoxyethylene succinate sulfonate 5%, silkworm excrement 5%, attapulgite add to 100%, and mixture carries out air-flow crushing, make 60% pyridalyl methoxyfenozide wetting powder.
Methoxyfenozide is changed to furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 380% pyridalyl methoxyfenozide water dispersible granules
Pyridalyl 20%, methoxyfenozide 60%, lignosulfonates 6%, wetting and penetrating agent F 5%, sodium carbonate 2%, white carbon add to 100%, mix to make 80% pyridalyl methoxyfenozide water dispersible granules.
Methoxyfenozide is changed to furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 460% pyridalyl methoxyfenozide water dispersible granules
Pyridalyl 20%, methoxyfenozide 40%, lauryl sodium sulfate 6%, lignosulfonates 5%, bentonite 2%, kaolin add to 100%, mix to make 60% pyridalyl methoxyfenozide water dispersible granules.
Methoxyfenozide is changed to furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 540% pyridalyl methoxyfenozide suspending agent
Pyridalyl 10%, methoxyfenozide 30%, alkylaryl APEO 5%, silkworm excrement 4%, C
8 ~ 10Aliphatic alcohols 0.12%, hydroxyethylcellulose 0.16%, propane diols 3.8%, deionized water add to 100%, mix to make 40% pyridalyl methoxyfenozide suspending agent.
Methoxyfenozide is changed to furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 630% pyridalyl methoxyfenozide suspending agent
Pyridalyl 15%, methoxyfenozide 15%, octylphenol polyethylene oxyethylene group ether sulfate 5%, Nekal BX 5%, C
8 ~ 10Aliphatic alcohols 0.13%, xanthans 0.16%, glycerine 3.2%, deionized water add to 100%, mix to make 30% pyridalyl methoxyfenozide suspending agent.
Methoxyfenozide is changed to furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 725% pyridalyl methoxyfenozide suspension emulsion
Pyridalyl 20%, methoxyfenozide 5%, the phonetic formaldehyde condensation products sulphate 6% of alkylphenol-polyethenoxy, sldium lauryl sulfate 5%, triethanolamine salt 4%, propyl alcohol 8%, silicone compound 0.1%, sodium phosphate trimer 0.08%, glycerine 4.2%, deionized water add to 100%, mix to make 25% pyridalyl methoxyfenozide suspension emulsion.
Methoxyfenozide is changed to furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 820% pyridalyl methoxyfenozide suspension emulsion
Pyridalyl 8%, methoxyfenozide 12%, alkylphenol-polyethenoxy are phonetic 5%, neopelex 4%, benzyl dimethyl phenol polyoxy ethyl ether 6%, vegetable oil 5%, silicone 0.14%, Magnesiumaluminumsilicate 0.15%, glycerine 4.1%, deionized water add to 100%, mix making 20% pyridalyl methoxyfenozide suspension emulsion.
Methoxyfenozide is changed to furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 941% pyridalyl methoxyfenozide microemulsion
Pyridalyl 1%, methoxyfenozide 40%, benzyl dimethyl phenol polyoxy ethyl ether 6%, DMF 8%, ethylene glycol 3%, crospolyvinylpyrrolidone 0.18%, C
10 ~ 20Saturated fat acids 0.08%, deionized water supplies 100%, mixes to make 41% pyridalyl methoxyfenozide microemulsion.
Methoxyfenozide is changed to furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 1033% pyridalyl methoxyfenozide microemulsion
Pyridalyl 30%, methoxyfenozide 3%, 3-methyl cyclohexanol ketenes 6%, phenolic resins 0.2%, alkyl biphenyl ether disulfonic acid magnesium salts 7%, silicone oil 0.09%, deionized water supplies 100%, makes 33% pyridalyl methoxyfenozide microemulsion.
Methoxyfenozide is changed to furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 1130% pyridalyl methoxyfenozide aqueous emulsion
Pyridalyl 5%, methoxyfenozide 25%, propyl alcohol 6%, butyl ether 6%, phenethyl phenol polyoxy ethyl polypropylene-base ether 6%, Magnesiumaluminumsilicate 0.2%, C
8 ~ 10Aliphatic alcohols 0.08%, deionized water adds to 100%, mixes to make 30% pyridalyl methoxyfenozide aqueous emulsion.
Methoxyfenozide is changed to furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 1240% pyridalyl methoxyfenozide aqueous emulsion
Pyridalyl 30%, methoxyfenozide 10%, N, dinethylformamide 5%, N-octylpyrrolidone 6%, sorbitan fatty acid ester APEO 6.5%, sodium phosphate trimer 0.13%, capric acid 0.13%, deionized water adds to 100%, makes 40% pyridalyl methoxyfenozide aqueous emulsion through mixing.
Methoxyfenozide is changed to furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 1311% pyridalyl methoxyfenozide micro-capsule suspension
Pyridalyl 1%, methoxyfenozide 10%, PIC 3.5%, polyfunctional group acyl halide polyamines 4%, neopelex 4.5%, the phonetic formaldehyde condensation products sulphate 4% of alkylphenol-polyethenoxy, vegetable oil 4%, fatty alcohol-polyoxyethylene ether 5%; hydrochloric acid 1.5%, sodium hydroxide 1.0%, deionized water add to 100% weight portion, make 11% pyridalyl methoxyfenozide micro-capsule suspension.
Methoxyfenozide is changed to furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 1420% pyridalyl methoxyfenozide microcapsule suspension-suspending agent
Pyridalyl 15%, methoxyfenozide 5%, polyfunctional group acyl halide dihydroxylic alcohols 5%, maltose 4%, silkworm excrement 5%, ethyl acetate 6.5%, alkylphenol-formaldehyde resin polyoxy ethyl ether 7%, alkylaryl polyoxyethylene polyoxypropylene ether 1%, C
8 ~ 10Aliphatic alcohols 0.10%, phenolic resins 0.11%, sodium hydroxide 1.2%, citric acid 1.2%, water add to 100% weight portion, make 20% pyridalyl methoxyfenozide microcapsule suspension-suspending agent.
Methoxyfenozide is changed to furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 1581% pyridalyl furan tebufenozide wetting powder
Pyridalyl 80%, furan tebufenozide 1%, alkylphenol-polyethenoxy are phonetic 6%, lauryl sodium sulfate 5%, kaolin add to 100%, and mixture carries out air-flow crushing, makes 81% pyridalyl furan tebufenozide wetting powder.
Furan tebufenozide is changed to methoxyfenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 1680% pyridalyl furan tebufenozide wetting powder
Pyridalyl 40%, furan tebufenozide 40%, the phonetic formaldehyde condensation products sulphate 5% of alkylphenol-polyethenoxy, tea are withered 5%, precipitated calcium carbonate adds to 100%, and mixture carries out air-flow crushing, makes 80% pyridalyl furan tebufenozide wetting powder.
Furan tebufenozide is changed to methoxyfenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 1775% pyridalyl furan tebufenozide water dispersible granules
Pyridalyl 45%, furan tebufenozide 30%, the phonetic formaldehyde condensation products sulphate 6% of alkylphenol-polyethenoxy, silkworm excrement 5%, sodium carbonate 2%, bentonite add to 100%, mix to make 75% pyridalyl furan tebufenozide water dispersible granules.
Furan tebufenozide is changed to methoxyfenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 1840% pyridalyl furan tebufenozide water dispersible granules
Pyridalyl 20%, furan tebufenozide 20%, tea are withered 5.5%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, sodium bicarbonate 2%, kaolin add to 100%, mix making 40% pyridalyl furan tebufenozide water dispersible granules.
Furan tebufenozide is changed to methoxyfenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 1925% pyridalyl furan tebufenozide suspending agent
Pyridalyl 10%, furan tebufenozide 15%, alkylnaphthalene sulfonate 6%, sldium lauryl sulfate 4.5%, silicone 0.12%, phenolic resins 0.17%, ethylene glycol 3.5%, deionized water add to 100%, mix to make 25% pyridalyl furan tebufenozide suspending agent.
Furan tebufenozide is changed to methoxyfenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 2040% pyridalyl furan tebufenozide suspending agent
Pyridalyl 10%, furan tebufenozide 30%, alkylaryl APEO 5%, soapberry powder 4.5%, silicone 0.09%, gelatin 0.15%, polyethylene glycol 2.8%, deionized water add to 100%, mix to make 40% pyridalyl furan tebufenozide suspending agent.
Furan tebufenozide is changed to methoxyfenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 2130% pyridalyl furan tebufenozide suspension emulsion
Pyridalyl 10%, furan tebufenozide 20%, the phonetic formaldehyde condensation products sulphate 5% of alkylphenol-polyethenoxy, wetting and penetrating agent F 4.5%, phenyl phenol polyoxy ethyl ether 7%, N, dinethylformamide 8%, silicone oil 0.08%, sodium phosphate trimer 0.12%, diethylene glycol (DEG) 3.8%, deionized water add to 100%, mix to make 30% pyridalyl furan tebufenozide suspension emulsion.
Furan tebufenozide is changed to methoxyfenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 2235% pyridalyl furan tebufenozide suspension emulsion
Pyridalyl 5%, furan tebufenozide 30%, aryl phenol polyoxyethylene succinate sulfonate 6%, silkworm excrement 4%, phenyl phenol polyoxy ethyl ether phosphate 5%, 3-methyl cyclohexanol ketenes 8%, C
8 ~ 10Aliphatic alcohols 0.09%, sodium phosphate trimer 0.16%, glycerine 4.0%, deionized water add to 100%, mix to make 35% pyridalyl furan tebufenozide suspension emulsion.
Furan tebufenozide is changed to methoxyfenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 2341% pyridalyl furan tebufenozide microemulsion
Pyridalyl 40%, furan tebufenozide 1%, alkyl biphenyl ether disulfonic acid magnesium salts 6%, 3-methyl cyclohexanol ketenes 4%, glycerine 4.1%, sodium alginate 0.16%, C
8 ~ 10Aliphatic alcohols 0.11%, deionized water supplies 100%, mixes to make 41% pyridalyl furan tebufenozide microemulsion.
Furan tebufenozide is changed to methoxyfenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 2422% pyridalyl furan tebufenozide microemulsion
Pyridalyl 2%, furan tebufenozide 20%, acetonitrile 6%, hydroxyethylcellulose 0.2%, phenethyl phenol polyoxy ethyl polypropylene-base ether 7%, C
10 ~ 20Saturated fat acids 0.08%, deionized water supplies 100%, makes 22% pyridalyl furan tebufenozide microemulsion.
Furan tebufenozide is changed to methoxyfenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 2515% pyridalyl furan tebufenozide aqueous emulsion
Pyridalyl 10%, furan tebufenozide 5%, 3-methyl cyclohexanol ketenes 4%, propyl alcohol 3%, polyoxyethylene nonylphenol ether 5%, phenolic resins 0.15%, silicone compound 0.09%, deionized water adds to 100%, mixes to make 15% pyridalyl furan tebufenozide aqueous emulsion.
Furan tebufenozide is changed to methoxyfenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 2620% pyridalyl furan tebufenozide aqueous emulsion
Pyridalyl 15%, furan tebufenozide 5%, vegetable oil 5.5%, N, dinethylformamide 5.1%, polyoxyethylene nonylphenol ether 6.4%, sodium phosphate trimer 0.15%, silicone 1.8%, deionized water adds to 100%, makes 20% pyridalyl furan tebufenozide aqueous emulsion through mixing.
Furan tebufenozide is changed to methoxyfenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 2730% pyridalyl furan tebufenozide micro-capsule suspension
Pyridalyl 25%, furan tebufenozide 5%, polyfunctional group acyl halide dihydroxylic alcohols 3%, sodium alginate 2%, sldium lauryl sulfate 5%, lignosulfonates 5%, N-pyrrolidones 4%, ethylene oxide-propylene oxide block copolymer 5%; citric acid 1.4%, sodium hydroxide 1.2%, deionized water add to 100% weight portion, make 30% pyridalyl furan tebufenozide micro-capsule suspension.
Furan tebufenozide is changed to methoxyfenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 2820% pyridalyl furan tebufenozide microcapsule suspension-suspending agent
Pyridalyl 10%, furan tebufenozide 10%, PIC 5%, polyfunctional group acyl halide polyamines 3%, gelatin 2.5%, vegetable oil 7%, castor oil polyoxyethylene ether 5%, sorbitan monostearate 3%, C
8 ~ 10Aliphatic alcohols 0.07%, sodium phosphate trimer 1.2%, sodium hydroxide 1.4%, citric acid 1.6%, water add to 100% weight portion, make 20% pyridalyl furan tebufenozide microcapsule suspension-suspending agent.
Furan tebufenozide is changed to methoxyfenozide, chlorine worm hydrazides, ring worm hydrazides can form new embodiment.
Embodiment 2955% pyridalyl chlorine worm hydrazides wetting powder
Pyridalyl 5%, chlorine worm hydrazides 50%, alkylaryl APEO 5%, Nekal BX 5%, attapulgite add to 100%, and mixture carries out air-flow crushing, make 55% pyridalyl chlorine worm hydrazides wetting powder.
Effective active composition chlorine worm hydrazides is changed to furan tebufenozide, methoxyfenozide, ring worm hydrazides forms new embodiment.
Embodiment 3060% pyridalyl chlorine worm hydrazides water dispersible granules
Pyridalyl 40%, chlorine worm hydrazides 20%, aliphatic amine polyoxyethylene are phonetic 5%, spaonin powder 6%, urea 2.6%, bentonite add to 100%, mix making 60% pyridalyl chlorine worm hydrazides water dispersible granules.
Effective active composition chlorine worm hydrazides is changed to methoxyfenozide, furan tebufenozide, ring worm hydrazides forms new embodiment.
Embodiment 3130% pyridalyl chlorine Tebufenozide suspending agent
Pyridalyl 10%, chlorine worm hydrazides 20%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5.4%, sldium lauryl sulfate 4.6%, C
8 ~ 10Aliphatic alcohols 0.13%, phenolic resins 0.1%, propane diols 4%, deionized water add to 100%, mix to make 30% pyridalyl chlorine Tebufenozide suspending agent.
Effective active composition chlorine worm hydrazides is changed to methoxyfenozide, furan tebufenozide, ring worm hydrazides forms new embodiment.
Embodiment 3230% pyridalyl chlorine worm hydrazides suspension emulsion
Pyridalyl 15%, chlorine worm hydrazides 15%, alkylphenol-polyethenoxy are phonetic 6%, sldium lauryl sulfate 4%, phenethyl phenol polyoxy ethyl polypropylene-base ether 6%, vegetable oil 5%, silicone compound 0.1%, crospolyvinylpyrrolidone 0.12%, polyvinyl alcohol 2.5%, deionized water add to 100%, mix making 30% pyridalyl chlorine worm hydrazides suspension emulsion.
Effective active composition chlorine worm hydrazides is changed to methoxyfenozide, furan tebufenozide, ring worm hydrazides forms new embodiment.
Embodiment 3311% pyridalyl chlorine worm hydrazides microemulsion
Pyridalyl 10%, chlorine worm hydrazides 1%, N-pyrrolidones 6%, sodium alginate 0.2%, fatty alcohol-polyoxyethylene ether 7%, C
8 ~ 10Aliphatic alcohols 0.12%, deionized water supplies 100%, makes 11% pyridalyl chlorine worm hydrazides microemulsion.
Effective active composition chlorine worm hydrazides is changed to methoxyfenozide, furan tebufenozide, ring worm hydrazides forms new embodiment.
Embodiment 3425% pyridalyl chlorine worm hydrazides aqueous emulsion
Pyridalyl 5%, chlorine worm hydrazides 20%, acetone 5%, ethylene glycol monomethyl ether 5%, benzyl dimethyl phenol polyoxy ethyl ether 6%, melon glue 0.18%, silicone oil 0.08%, glycerine 3.8%, deionized water adds to 100%, mixes to make 25% pyridalyl chlorine worm hydrazides aqueous emulsion.
Effective active composition chlorine worm hydrazides is changed to methoxyfenozide, furan tebufenozide, ring worm hydrazides forms new embodiment.
Embodiment 3540% pyridalyl chlorine worm hydrazides micro-capsule suspension
Pyridalyl 30%, chlorine worm hydrazides 10%, polyfunctional group acyl halide polyamines 3%, PIC 4%, silkworm excrement 5%, the phonetic formaldehyde condensation products sulphate 2.8% of alkylphenol-polyethenoxy, lauryl sodium sulfate 6%, polyoxyethylene nonylphenol ether phosphate 5%, sorbic acid 1.4%, sodium hydroxide 1.6%, deionized water add to 100% weight portion, make 40% pyridalyl chlorine worm hydrazides micro-capsule suspension.
Effective active composition chlorine worm hydrazides is changed to methoxyfenozide, furan tebufenozide, ring worm hydrazides forms new embodiment.
Embodiment 3625% pyridalyl chlorine worm hydrazides microcapsule suspension-suspending agent
Pyridalyl 15%, chlorine worm hydrazides 10%, polyfunctional group acyl halide dihydroxylic alcohols 5%, distortion milk protein 3%, neopelex 2.5%, acetonitrile 6%, phenethyl phenol polyoxy ethyl polypropylene-base ether 5%, alkylaryl polyoxyethylene polyoxypropylene ether 3%, C
10 ~ 20Saturated fat acids (such as capric acid) and acid amides 0.09%, hydroxyethylcellulose 1.2%, sorbic acid 0.4%, sodium hydroxide 0.5%, water add to 100% weight portion, make 25% pyridalyl chlorine worm hydrazides microcapsule suspension-suspending agent.
Effective active composition chlorine worm hydrazides is changed to methoxyfenozide, furan tebufenozide, ring worm hydrazides forms new embodiment.
Embodiment 3780% pyridalyl ring worm hydrazides wetting powder
Pyridalyl 40%, ring worm hydrazides 40%, aryl phenol polyoxyethylene succinate sulfonate 5%, soapberry powder 5%, diatomite add to 100%, and mixture carries out air-flow crushing, makes 80% pyridalyl ring worm hydrazides wetting powder.
Effective active composition ring worm hydrazides is changed to furan tebufenozide, methoxyfenozide, chlorine worm hydrazides forms new embodiment.
Embodiment 3850% pyridalyl ring worm hydrazides water dispersible granules
Pyridalyl 20%, ring worm hydrazides 30%, alkylphenol-polyethenoxy are phonetic 7%, sldium lauryl sulfate 3%, glucose 3%, precipitated calcium carbonate add to 100%, mix making 50% pyridalyl ring worm hydrazides water dispersible granules.
Effective active composition ring worm hydrazides is changed to methoxyfenozide, furan tebufenozide, chlorine worm hydrazides forms new embodiment.
Embodiment 3940% pyridalyl ring Tebufenozide suspending agent
Pyridalyl 10%, ring worm hydrazides 30%, alkylaryl APEO 5%, Nekal BX 4%, C
8 ~ 10Aliphatic alcohols 0.12%, sodium alginate 0.16%, propane diols 3.7%, deionized water add to 100%, mix to make 40% pyridalyl ring Tebufenozide suspending agent.
Effective active composition ring worm hydrazides is changed to methoxyfenozide, furan tebufenozide, chlorine worm hydrazides forms new embodiment.
Embodiment 4030% pyridalyl ring worm hydrazides suspension emulsion
Pyridalyl 20%, ring worm hydrazides 10%, alkylaryl APEO 6%, wetting and penetrating agent F 4%, phenethyl phenol polyoxy ethyl polypropylene-base ether 6%, propyl alcohol 5%, silicone 0.1%, white dextrin 0.12%, diethylene glycol (DEG) 3.5%, deionized water add to 100%, mix making 30% pyridalyl ring worm hydrazides suspension emulsion.
Effective active composition ring worm hydrazides is changed to methoxyfenozide, furan tebufenozide, chlorine worm hydrazides forms new embodiment.
Embodiment 4122% pyridalyl ring worm hydrazides microemulsion
Pyridalyl 20%, ring worm hydrazides 2%, 3-methyl cyclohexanol ketenes 6%, hydroxyethylcellulose 0.2%, sorbitan fatty acid ester APEO 7%, C
10 ~ 20Saturated fat acids (such as capric acid) and acid amides 1.4%, deionized water supplies 100%, makes 22% pyridalyl ring worm hydrazides microemulsion.
Effective active composition ring worm hydrazides is changed to methoxyfenozide, furan tebufenozide, chlorine worm hydrazides forms new embodiment.
Embodiment 4220% pyridalyl ring worm hydrazides aqueous emulsion
Pyridalyl 10%, ring worm hydrazides 10%, 3-methyl cyclohexanol ketenes 5%, acetone 5%, alkyl biphenyl ether disulfonic acid magnesium salts 6%, white dextrin 0.1%, C
10 ~ 20Saturated fat acids 0.14%, polyethylene glycol 3%, deionized water adds to 100%, mixes to make 20% pyridalyl ring worm hydrazides aqueous emulsion.
Effective active composition ring worm hydrazides is changed to methoxyfenozide, furan tebufenozide, chlorine worm hydrazides forms new embodiment.
Embodiment 4325% pyridalyl ring worm hydrazides micro-capsule suspension
Pyridalyl 20%, ring worm hydrazides 5%, PIC 4%, formaldehyde 4%, lauryl sodium sulfate 6%, the phonetic formaldehyde condensation products sulphate 5% of alkylphenol-polyethenoxy, acetonitrile 6%, alkyl biphenyl ether disulfonic acid magnesium salts 5%, sorbic acid 1.8%, sodium hydroxide 0.9%, deionized water add to 100% weight portion, make 25% pyridalyl ring worm hydrazides micro-capsule suspension.
Effective active composition ring worm hydrazides is changed to methoxyfenozide, furan tebufenozide, chlorine worm hydrazides forms new embodiment.
Embodiment 4420% pyridalyl ring worm hydrazides microcapsule suspension-suspending agent
Pyridalyl 15%, ring worm hydrazides 5%, distortion milk protein 5%, polyvinyl alcohol 2%, neopelex 2.5%, ethyl acetate 6%, ethylene oxide-propylene oxide block copolymer 5%, polyoxyethylene nonylphenol ether 3%, silicone compound 0.6%, crospolyvinylpyrrolidone 1.2%, sodium hydroxide 1.4%, citric acid 1.5%, water add to 100% weight portion, make 20% pyridalyl ring worm hydrazides microcapsule suspension-suspending agent.
Effective active composition ring worm hydrazides is changed to methoxyfenozide, furan tebufenozide, chlorine worm hydrazides forms new embodiment.
The embodiment of the invention is the method that adopts Toxicity Determination and field trial to combine.First by Toxicity Determination, the co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC＜80 are antagonism, and 80≤CTC≤120 are summation action, and CTC＞120 are synergistic effect, on this basis, carry out field trial again.
Test method: respectively the mother liquor of each mixed agent is diluted to five series concentration during test, places respectively beaker for subsequent use.Adopt and to soak first the method that connects worm behind the leaf, the blade of the same size that does not contact any medicament soaked in the liquid that configures behind the 5s take out, naturally dry, put into insect box, then connect for the examination larva, under 25 ℃ of conditions, raise, every processing repeats for 3 times, every to repeat used examination borer population be 50, establishes simultaneously blank, checks dead borer population in 72h, calculate lethality and corrected mortality, try to achieve virulence regression equation and calculate LC
50Value.If the contrast lethality then is considered as invalid test greater than 10%.Computing formula is as follows:
Borer population alive behind borer population-medicine alive before the medicine
Lethality (%)=------------* 100
Borer population alive before the medicine
Processed group lethality-control group lethality
Corrected mortality (%)=---------------* 100
100-control group lethality
The insect corrected mortality is converted into probit value (y), and concentration for the treatment of (μ g/ml) converts logarithm value (x) to, draws virulence regression equation with method of least squares, and calculates thus the value of every kind of medicament.Calculate co-toxicity coefficient CTC according to the abundant equation of Sun Yun.Computing formula following (take pyridalyl as the standard medicament, its toxicity index is 100):
The LC of pyridalyl
50
The toxicity index of B (TI)=------------* 100
The LC of active component B
50
The LC of pyridalyl
50
The toxicity index of M (ATI)=---------* 100
The LC of M
50
TI * the P of the theoretical toxicity index (TTI) of M=pyridalyl
PyridalylTI * P of+active component B
Active component B
The ATI of M
Co-toxicity coefficient (CTC)=------* 100
The TTI of M
In the formula: M is the mixture of different proportionings;
P
Active component BBe active component B shared ratio in composition;
P
PyridalylBe pyridalyl shared ratio in composition.
Annotate: active component B is a kind of arbitrarily in methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, the ring worm hydrazides.
Application Example two:
For trying insect: the paddy rice rice leaf roller.
Experimental scheme: effective lethal concentration scope of determining pyridalyl, the former medicine of methoxyfenozide and the two different proportioning mixture through preliminary experiment.
Toxicity test result one
The different proportionings from methoxyfenozide of table 1 pyridalyl are to the toxicity test of paddy rice rice leaf roller
As shown in Table 1, the composite control of pyridalyl and methoxyfenozide paddy rice rice leaf roller fit over 80:1 to 1:80 the time, co-toxicity coefficient is all greater than 120, illustrating that both are mixed in 80:1 to 1:80 scope all shows synergistic effect, especially when pyridalyl and methoxyfenozide get proportioning at 10:1 to 1:10, synergistic effect is more obviously outstanding, co-toxicity coefficient maximum when pyridalyl and methoxyfenozide weight ratio are 1:1 wherein, and synergistic effect is the most obvious.Find simultaneously, pyridalyl and methoxyfenozide proportioning are composite when 10:1,9:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10 also to have preferably synergistic effect to rice leaf roller, striped rice borer, paddy stem borer, pink rice borer, rice fulgorid, diamond-back moth, cabbage caterpillar, prodenia litura, beet armyworm, 2 insects such as noctuid, cotton bollworm, pink bollworm, thrips of entrusting, and co-toxicity coefficient is all greater than 220.
Application Example three:
For trying insect: the cotton cotton bollworm.
Experimental scheme: effective lethal concentration scope of determining pyridalyl, the former medicine of furan tebufenozide and the two different proportioning mixture through preliminary experiment.
Toxicity test result two
The different proportionings from furan tebufenozide of table 2 pyridalyl are to the toxicity test of cotton cotton bollworm
As shown in Table 2, the proportioning of the composite control of pyridalyl and furan tebufenozide cotton cotton bollworm is when 80:1 to 1:80, co-toxicity coefficient is all greater than 120, illustrating that both are mixed in 80:1 to 1:80 scope all shows synergistic effect, especially when the proportioning of pyridalyl and furan tebufenozide during at 10:1 to 1:10, synergistic effect is more obviously outstanding, wherein co-toxicity coefficient is maximum when pyridalyl and furan tebufenozide weight ratio are 1:1, synergistic effect is the most obvious, find simultaneously, pyridalyl and furan tebufenozide proportioning are at 10:1,9:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9, composite to rice leaf roller during 1:10, striped rice borer, paddy stem borer, pink rice borer, rice fulgorid, diamond-back moth, cabbage caterpillar, prodenia litura, beet armyworm, 2 committee noctuids, cotton bollworm, pink bollworm, the insects such as thrips also have preferably synergistic effect, and co-toxicity coefficient is all greater than 250.
Application Example four:
For trying insect: the wild cabbage diamond-back moth.
Experimental scheme: effective lethal concentration scope of determining pyridalyl, the ring former medicine of worm hydrazides and the two different proportioning mixture through preliminary experiment.
Toxicity test result three
Table 3 pyridalyl and the toxicity test of the different proportionings of ring worm hydrazides to the wild cabbage diamond-back moth
As shown in Table 3, the proportioning of pyridalyl and the composite control wild cabbage of ring worm hydrazides diamond-back moth is when 80:1 to 1:80, co-toxicity coefficient is all greater than 120, illustrating that both are mixed in 80:1 to 1:80 scope all shows synergistic effect, especially when the proportioning of pyridalyl and ring worm hydrazides during at 10:1 to 1:10, synergistic effect is more obviously outstanding, wherein co-toxicity coefficient is maximum when pyridalyl is 1:1 with ring worm hydrazides weight ratio, synergistic effect is the most obvious, find simultaneously, pyridalyl and ring worm hydrazides proportioning are at 10:1,9:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10, the time composite to rice leaf roller, striped rice borer, paddy stem borer, pink rice borer, rice fulgorid, diamond-back moth, cabbage caterpillar, prodenia litura, beet armyworm, 2 committee noctuids, cotton bollworm, pink bollworm, the insects such as thrips also have preferably synergistic effect, and co-toxicity coefficient is all greater than 220.
Application Example five:
For trying insect: rice-stem borer.
Experimental scheme: effective lethal concentration scope of determining pyridalyl, the former medicine of chlorine worm hydrazides and the two different proportioning mixture through preliminary experiment.
Toxicity test result four
Table 4 pyridalyl and the toxicity test of the different proportionings of chlorine worm hydrazides to rice-stem borer
As shown in Table 3, the proportioning of the composite control of pyridalyl and chlorine worm hydrazides rice-stem borer is when 80:1 to 1:80, co-toxicity coefficient is all greater than 120, illustrating that both are mixed in 80:1 to 1:80 scope all shows synergistic effect, especially when the proportioning of pyridalyl and chlorine worm hydrazides during at 10:1 to 1:20, synergistic effect is more obviously outstanding, wherein co-toxicity coefficient is maximum when pyridalyl and chlorine worm hydrazides weight ratio are 1:2, synergistic effect is the most obvious, find simultaneously, pyridalyl and chlorine worm hydrazides proportioning are at 10:1,9:1,8:1,7:1,6:1,5:1,4:1,3:1,2:1,1:1,1:2,1:3,1:4,1:5,1:6,1:7,1:8,1:9,1:10,1:11,1:12,1:13,1:14,1:15,1:16,1:17,1:18,1:19, composite to rice leaf roller during 1:20, striped rice borer, paddy stem borer, pink rice borer, rice fulgorid, diamond-back moth, cabbage caterpillar, prodenia litura, beet armyworm, 2 committee noctuids, cotton bollworm, pink bollworm, the insects such as thrips also have preferably synergistic effect, and co-toxicity coefficient is all greater than 240.
Application Example sixThe effect test of pyridalyl and methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides and composite control cabbage pieris thereof
This experimental establishment is in Qishan County, Baoji, Shaanxi province city; test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd.; contrast medicament 10% pyridalyl suspending agent (autogamy); 240 grams per liter methoxyfenozide suspending agents (commercial); 10% furan tebufenozide suspending agent (autogamy); 10% chlorine Tebufenozide suspending agent (autogamy), 10% ring Tebufenozide suspending agent (autogamy).
Conventional spray-on process is adopted in test, and investigation cabbage pieris insect pest index before the medicine in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 1 day, 3 days, 7 days after the dispenser and calculated preventive effect.Experimental result is as follows:
Table 5 pyridalyl, methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides and the composite control cabbage pieris test of pesticide effectiveness thereof
| Treatment agent | The preparation dosage | 1 preventive effect (%) behind the medicine | 3 preventive effects (%) behind the medicine | 7 preventive effects (%) behind the medicine |
| Example 1 | 15 g/acres | 97.01 | 97.14 | 97.09 |
| Example 2 | 25 g/acres | 99.59 | 99.87 | 99.64 |
| Example 15 | 14 g/acres | 98.17 | 98.54 | 98.28 |
| Example 16 | 15 g/acres | 99.66 | 99.99 | 99.94 |
| Example 29 | 27 g/acres | 97.24 | 97.51 | 97.40 |
| Example 30 | 25 g/acres | 98.14 | 98.49 | 98.33 |
| Example 37 | 16 g/acres | 99.89 | 100.00 | 99.92 |
| Example 38 | 30 g/acres | 98.79 | 99.13 | 98.94 |
| 10% pyridalyl suspending agent | 65 g/acres | 66.43 | 68.52 | 67.24 |
| 240 grams per liter methoxyfenozide suspending agents | 45 g/acres | 65.51 | 66.78 | 66.09 |
| 10% furan tebufenozide suspending agent | 70 g/acres | 64.19 | 66.59 | 65.28 |
| 10% chlorine Tebufenozide suspending agent | 100 g/acres | 62.69 | 64.71 | 63.82 |
| 10% ring Tebufenozide suspending agent | 70 g/acres | 63.49 | 64.81 | 64.02 |
As can be seen from Table 5, can effectively prevent and treat cabbage pieris after pyridalyl and methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides are composite, control efficiency all is better than the preventive effect of single dose, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example sevenThe test of pesticide effectiveness of pyridalyl and methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides and composite control Yellow Rice Borer thereof
This experimental establishment is in Pingchang County, Bazhong City, Sichuan Province; test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd.; contrast medicament 10% pyridalyl suspending agent (autogamy); 240 grams per liter methoxyfenozide suspending agents (commercial); 10% furan tebufenozide suspending agent (autogamy); 10% chlorine Tebufenozide suspending agent (autogamy), 10% ring Tebufenozide suspending agent (autogamy).
Conventional spray-on process is adopted in test, and investigation Yellow Rice Borer insect pest index before the medicine in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 1 day, 5 days, 7 days after the dispenser and calculated preventive effect.Experimental result is as follows:
Table 6 pyridalyl, methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides and the composite control Yellow Rice Borer test of pesticide effectiveness thereof
| Treatment agent | The preparation consumption | 1 day preventive effect (%) behind the medicine | 5 days preventive effects (%) behind the medicine | 7 days preventive effects (%) behind the medicine |
| Example 3 | 15 g/acres | ?98.05 | 98.29 | 98.17 |
| Example 4 | 25 g/acres | 98.31 | 98.59 | 98.40 |
| Example 17 | 20 g/acres | 98.76 | 98.91 | 98.87 |
| Example 18 | 35 g/acres | 99.34 | 99.59 | 99.41 |
| Example 31 | 50 g/acres | 99.45 | 99.91 | 99.70 |
| Example 32 | 52 g/acres | 98.91 | 99.05 | 98.99 |
| Example 39 | 35 g/acres | 98.25 | 98.71 | 98.60 |
| Example 40 | 40 g/acres | 98.27 | 98.64 | 98.52 |
| 10% pyridalyl suspending agent | 60 g/acres | 64.21 | 66.39 | 65.18 |
| 240 grams per liter methoxyfenozide suspending agents | 40 g/acres | 62.92 | 66.75 | 64.51 |
| 10% furan tebufenozide suspending agent | 70 g/acres | 63.19 | 67.55 | 65.93 |
| 10% chlorine Tebufenozide suspending agent | 95 g/acres | 64.29 | 67.21 | 66.77 |
| 10% ring Tebufenozide suspending agent | 70 g/acres | 61.94 | 63.87 | 62.99 |
As can be seen from Table 6, can effectively prevent and treat Yellow Rice Borer after pyridalyl and methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides are composite, control efficiency all is better than the preventive effect of single dose, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example eightThe test of pesticide effectiveness of pyridalyl and methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides and composite control cotton pink bollworm thereof
This experimental establishment is in Weinan City Dali County, Shaanxi Province; test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd.; contrast medicament 10% pyridalyl suspending agent (autogamy); 240 grams per liter methoxyfenozide suspending agents (commercial); 10% furan tebufenozide suspending agent (autogamy); 10% chlorine Tebufenozide suspending agent (autogamy), 10% ring Tebufenozide suspending agent (autogamy).
Test and adopt conventional spray-on process, investigation cotton pink bollworm evil index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 1 day, 5 days, 7 days after the dispenser and is calculated preventive effect before the medicine.Experimental result is as follows:
Table 7 pyridalyl, methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides and the composite control cotton pink bollworm test of pesticide effectiveness thereof
| Treatment agent | The preparation consumption | 1 day preventive effect (%) behind the medicine | 5 days preventive effects (%) behind the medicine | 7 days preventive effects (%) behind the medicine |
| Example 5 | 20 g/acres | 98.09 | 98.25 | 98.14 |
| Example 6 | 21 g/acres | 99.25 | 99.47 | 99.39 |
| Example 7 | 27 g/acres | 97.89 | 98.21 | 98.11 |
| Example 19 | 27 g/acres | 99.01 | 99.15 | 99.10 |
| Example 20 | 20 g/acres | 98.57 | 98.92 | 98.68 |
| Example 21 | 25 g/acres | 98.62 | 98.99 | 98.74 |
| Example 33 | 40 g/acres | 97.05 | 97.24 | 97.15 |
| Example 34 | 28 g/acres | 98.25 | 98.51 | 98.40 |
| Example 41 | 30 g/acres | 97.09 | 97.3 | 97.20 |
| Example 42 | 25 g/acres | 99.15 | 99.49 | 99.37 |
| 10% pyridalyl suspending agent | 65 g/acres | 64.15 | 66.91 | 65.83 |
| 240 grams per liter methoxyfenozide suspending agents | 40 g/acres | 63.51 | 65.91 | 64.88 |
| 10% furan tebufenozide suspending agent | 65 g/acres | 65.19 | 67.42 | 66.81 |
| 10% chlorine Tebufenozide suspending agent | 100 g/acres | 63.26 | 65.51 | 64.55 |
| 10% ring Tebufenozide suspending agent | 65 g/acres | 62.87 | 66.12 | 65.99 |
As can be seen from Table 7, can effectively prevent and treat the cotton pink bollworm after pyridalyl and methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides are composite, control efficiency all is better than the preventive effect of single dose, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example nineThe test of pesticide effectiveness of pyridalyl and methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides and 2 committees of composite control of maize noctuid thereof
This experimental establishment is in Liquan County, Xianyang, Shanxi province city; test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd.; contrast medicament 10% pyridalyl suspending agent (autogamy); 240 grams per liter methoxyfenozide suspending agents (commercial); 10% furan tebufenozide suspending agent (autogamy); 10% chlorine Tebufenozide suspending agent (autogamy), 10% ring Tebufenozide suspending agent (autogamy).
Test and adopt conventional spray-on process, 2 committees of investigation corn noctuid insect pest index before the medicine in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 1 day, 5 days, 7 days after the dispenser and is calculated preventive effect.Experimental result is as follows:
Table 8 pyridalyl, methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides and 2 committees of composite control of maize noctuid test of pesticide effectiveness thereof
| Treatment agent | The preparation dosage | 1 day preventive effect (%) behind the medicine | 5 days preventive effects (%) behind the medicine | 7 days preventive effects (%) behind the medicine |
| Example 8 | 40 g/acres | 98.34 | 98.69 | 98.51 |
| Example 9 | 20 g/acres | 97.01 | 97.09 | 97.06 |
| Example 10 | 32 g/acres | 97.10 | 98.18 | 97.12 |
| Example 22 | 25 g/acres | 98.05 | 98.14 | 98.10 |
| Example 23 | 20 g/acres | 97.02 | 97.13 | 97.10 |
| Example 24 | 39 g/acres | 97.12 | 97.20 | 97.15 |
| Example 35 | 20 g/acres | 98.45 | 98.87 | 98.52 |
| Example 36 | 37 g/acres | 98.59 | 98.99 | 98.88 |
| Example 43 | 38 g/acres | 98.25 | 98.43 | 98.37 |
| Example 44 | 40 g/acres | 98.43 | 98.59 | 98.48 |
| 10% pyridalyl suspending agent | 65 g/acres | 64.15 | 66.91 | 65.83 |
| 240 grams per liter methoxyfenozide suspending agents | 40 g/acres | 63.51 | 65.91 | 64.88 |
| 10% furan tebufenozide suspending agent | 65 g/acres | 65.19 | 67.42 | 66.81 |
| 10% chlorine Tebufenozide suspending agent | 100 g/acres | 63.26 | 65.51 | 64.55 |
| 10% ring Tebufenozide suspending agent | 65 g/acres | 62.87 | 66.12 | 65.99 |
As can be seen from Table 8, effective 2 of the control of maize noctuid of entrusting after pyridalyl and methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides are composite, control efficiency all is better than the preventive effect of single dose, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
Application Example tenThe test of pesticide effectiveness of pyridalyl and methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides and composite control eggplant thrips thereof
This experimental establishment is at Shaanxi Province's Yangling District; test medicine is provided by Shaanxi Welch Crop Protection Co., Ltd.; contrast medicament 10% pyridalyl suspending agent (autogamy); 240 grams per liter methoxyfenozide suspending agents (commercial); 10% furan tebufenozide suspending agent (autogamy); 10% chlorine Tebufenozide suspending agent (autogamy), 10% ring Tebufenozide suspending agent (autogamy).
Conventional spray-on process is adopted in test, and investigation eggplant thrips insect pest index in the dispenser of insect pest initial stage of origination, was investigated the insect pest indexes in 1 day, 5 days, 7 days after the dispenser and calculated preventive effect before the medicine.Experimental result is as follows:
Table 9 pyridalyl, methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides and the composite control eggplant thrips test of pesticide effectiveness thereof
| Treatment agent | The preparation consumption | 1 day preventive effect (%) behind the medicine | 5 days preventive effects (%) behind the medicine | 7 days preventive effects (%) behind the medicine |
| Example 11 | 30 g/acres | 98.29 | 98.51 | 98.43 |
| Example 12 | 20 g/acres | 98.37 | 98.62 | 98.50 |
| Example 13 | 48 g/acres | 97.09 | 97.18 | 97.11 |
| Example 14 | 40 g/acres | 98.64 | 98.83 | 98.69 |
| Example 25 | 45 g/acres | 98.92 | 99.05 | 98.95 |
| Example 26 | 40 g/acres | 98.47 | 98.75 | 98.69 |
| Example 27 | 30 g/acres | 98.29 | 98.54 | 98.37 |
| Example 28 | 48 g/acres | 99.00 | 99.05 | 99.04 |
| 10% pyridalyl suspending agent | 70 g/acres | 64.51 | 65.93 | 64.90 |
| 240 grams per liter methoxyfenozide suspending agents | 50 g/acres | 65.17 | 66.32 | 65.91 |
| 10% furan tebufenozide suspending agent | 75 g/acres | 65.47 | 67.12 | 66.90 |
| 10% chlorine Tebufenozide suspending agent | 100 g/acres | 62.19 | 65.34 | 64.27 |
| 10% ring Tebufenozide suspending agent | 75 g/acres | 63.18 | 66.31 | 65.07 |
As can be seen from Table 9, can effectively prevent and treat the eggplant thrips after pyridalyl and methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, ring worm hydrazides are composite, control efficiency all is better than the preventive effect of single dose, and efficiency time is long.In the test scope of medication, the target crop is had no adverse effects.
After draw through different local throughout the country tests, pyridalyl and methoxyfenozide, furan tebufenozide, ring worm hydrazides, the composite wetting powder of making of chlorine worm hydrazides, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, microcapsule suspending agent, behind microcapsule suspension-suspending agent to the rice leaf roller of all kinds of crops, striped rice borer, paddy stem borer, pink rice borer, rice fulgorid, diamond-back moth, cabbage caterpillar, prodenia litura, beet armyworm, 2 committee noctuids, cotton bollworm, pink bollworm, the preventive effect of the common insect such as thrips is all more than 95%, be better than the single dose preventive effect, synergistic effect is obvious.
Claims (9)
1. efficient pesticides composition, comprise active components A, active component B, it is characterized in that: active components A is pyridalyl, active component B is a kind of arbitrarily in methoxyfenozide, furan tebufenozide, chlorine worm hydrazides, the ring worm hydrazides, and the weight ratio 1:80 of active components A and active component B ~ 80:1.
2. insecticides according to claim 1, it is characterized in that: the weight ratio of active components A and active component B is 1:40 ~ 40:1.
3. insecticides according to claim 2, it is characterized in that: the weight ratio of pyridalyl and methoxyfenozide is 1:10 ~ 10:1.
4. insecticides according to claim 2, it is characterized in that: the weight ratio of pyridalyl and furan tebufenozide is 1:10 ~ 10:1.
5. insecticides according to claim 2, it is characterized in that: the weight ratio of pyridalyl and chlorine worm hydrazides is 1:20 ~ 10:1.
6. insecticides according to claim 2 is characterized in that: the weight ratio of pyridalyl and ring worm hydrazides is 1:10 ~ 10:1.
7. the described insecticides of any one according to claim 1 ~ 6, it is characterized in that: composition is made wetting powder, water dispersible granules, suspending agent, suspension emulsion, aqueous emulsion, microemulsion, micro-capsule suspension, microcapsule suspension-suspending agent.
8. insecticides according to claim 7 is used for the application of control crop pests.
9. application according to claim 8 is characterized in that institute's pest control comprises: rice leaf roller, striped rice borer, paddy stem borer, pink rice borer, rice fulgorid, diamond-back moth, cabbage caterpillar, prodenia litura, beet armyworm, 2 entrust noctuid, cotton bollworm, pink bollworm, thrips.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103181388A (en) * | 2012-12-04 | 2013-07-03 | 海利尔药业集团股份有限公司 | Pesticide composition containing pyridalyl and methoxyfenozide |
| CN104738043A (en) * | 2013-12-26 | 2015-07-01 | 南京华洲药业有限公司 | Composite insecticidal composition containing pyridalyl and fufenozide and application thereof |
| CN104738037A (en) * | 2013-12-25 | 2015-07-01 | 南京华洲药业有限公司 | Composite insecticidal composition containing pyridalyl and methoxyfenozide and application thereof |
| CN104738041A (en) * | 2013-12-26 | 2015-07-01 | 南京华洲药业有限公司 | Composite insecticidal composition containing pyridalyl and halofenozide and use thereof |
| CN104738038A (en) * | 2013-12-25 | 2015-07-01 | 南京华洲药业有限公司 | Composite insecticidal composition containing pyridalyl and chromafenozide and application thereof |
| CN106857527A (en) * | 2016-12-30 | 2017-06-20 | 新昌县赛因斯生物科技有限公司 | A kind of complex insecticidal composition containing fluorine chlorine ether chrysanthemum ester and its application |
| CN106857526A (en) * | 2016-12-30 | 2017-06-20 | 新昌县赛因斯生物科技有限公司 | A kind of Pesticidal combination containing pyridalyl and methoxyfenozide |
| CN109769817A (en) * | 2017-11-15 | 2019-05-21 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103181388A (en) * | 2012-12-04 | 2013-07-03 | 海利尔药业集团股份有限公司 | Pesticide composition containing pyridalyl and methoxyfenozide |
| CN104738037A (en) * | 2013-12-25 | 2015-07-01 | 南京华洲药业有限公司 | Composite insecticidal composition containing pyridalyl and methoxyfenozide and application thereof |
| CN104738038A (en) * | 2013-12-25 | 2015-07-01 | 南京华洲药业有限公司 | Composite insecticidal composition containing pyridalyl and chromafenozide and application thereof |
| CN104738043A (en) * | 2013-12-26 | 2015-07-01 | 南京华洲药业有限公司 | Composite insecticidal composition containing pyridalyl and fufenozide and application thereof |
| CN104738041A (en) * | 2013-12-26 | 2015-07-01 | 南京华洲药业有限公司 | Composite insecticidal composition containing pyridalyl and halofenozide and use thereof |
| CN106857527A (en) * | 2016-12-30 | 2017-06-20 | 新昌县赛因斯生物科技有限公司 | A kind of complex insecticidal composition containing fluorine chlorine ether chrysanthemum ester and its application |
| CN106857526A (en) * | 2016-12-30 | 2017-06-20 | 新昌县赛因斯生物科技有限公司 | A kind of Pesticidal combination containing pyridalyl and methoxyfenozide |
| CN109769817A (en) * | 2017-11-15 | 2019-05-21 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
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