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CN103251523B - Oil-control shampoo composite - Google Patents

Oil-control shampoo composite Download PDF

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Publication number
CN103251523B
CN103251523B CN201310192886.XA CN201310192886A CN103251523B CN 103251523 B CN103251523 B CN 103251523B CN 201310192886 A CN201310192886 A CN 201310192886A CN 103251523 B CN103251523 B CN 103251523B
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oil
salt
control
sodium
acid
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CN103251523A (en
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严祖勇
顾先宇
魏巍
黄霞
沈昱
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Nice Group Co Ltd
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Nice Group Co Ltd
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Abstract

The invention relates to the field of daily use chemicals, and particularly relates to an oil-control shampoo composite which comprises water, surfactants, conditioning agents, a hydrating agent, an oil-control additive and a bacteriostatic agent, wherein the surfactants comprise the following components by the total weight percent of the composite: 8-15 percent of alkyl polyoxyethylene ether sulfate, 1-8 percent of a N-acyl amino acid surfactant and 1-6 percent of a glycine betaine surfactant; the conditioning agents comprise 0.1-2 percent of a cation conditioning agent and 0.1-3 percent of polysiloxane; and according to the total weight percent of the composite, the content of the hydrating agent is 0.1-2 percent, the content of the oil-control additive is 0.05-2 percent, the content of the bacteriostatic agent is 0.05-1 percent, and the balance is water. According to the oil-control shampoo composite, the secretion of oil can be greatly reduced when the scalp is deeply cleaned, and a good oil control effect is realized; and a bacteriostatic agent needing a suspending system is not adopted, and thus the comprehensive using effect is improved.

Description

Control oily hair-washing composition
Technical field
The present invention relates to household chemicals field, in particular to the oily hair-washing composition of control.
Background technology
At present shampoo on the market, of a great variety, function is also had nothing in common with each other, and as anti-dandruff, antipruritic, that nourish, anti-alopecia, also has control oil, for people provide the selection of multiple hair-protecting health-care.Oil-controlling shampoo wherein not only very by the welcome of the ladies of oily hair, and meets the demand that men like fuel-displaced hair, them can be helped to repair not angry, inelastic hair, can also reduce the risk of dandruff, pruritus.
Current most of oil-controlling shampoo is all on the basis of common shampoo, add the function that control oil component gives control oil, and the control oil component of employing mostly is plant extract, herb extract etc.Because Chinese herbal medicine additive is few containing concentration, consumption, also poor with the conformability of other compositions, be difficult to the fat secretion of fundamentally restraining scalp pore, reducing sebaceous gland, therefore this kind of oil-controlling shampoo has been difficult to well oily effect of actual control.
Summary of the invention
The object of the present invention is to provide the oily hair-washing composition of control, to solve the above problems.
Embodiments of the invention provide a kind of control oily hair-washing composition, comprising: water, surfactant, conditioner, wetting agent, control oil additive, antibacterial;
Described surfactant comprises: with composition total weight percentages, 8%-15% polyoxyethylene alkyl ether sulfate salt, 1%-8%N-amic acid type surfactant, 1%-6% betaines surfactant;
Described conditioner comprises: with composition total weight percentages, 0.1%-2% cation opsonizing agent, 0.1%-3% polysiloxanes;
With composition total weight percentages, 0.1%-2% wetting agent, 0.05%-2% control oil additive, 0.05%-1% antibacterial;
Described wetting agent is made up of one or more in sodium lactate, pyrrolidone sodium carboxylate, pantothenylol, ethyl panthenol, protein hydrolyzate, ethoxy urea, Macrogol 200-600;
Described control oil additive comprise following one or more: zinc pyrrolidone carboxylate, vitamin B6, menthol, Borneolum Syntheticum, Citrus aurantifolia oil, active carbon;
Described antibacterial comprise following one or more: Zinc Undecylenate, undecylenic acid single ethanol amide sulfosuccinate disodium, climbazole, Dichlorobenzene base imidazoles dioxolanes, pyridone ethanolamine, isethionic acid six amidine, Camellia sinensis leaf oil.
Preferably, the carbon number of the alkyl group of described polyoxyethylene alkyl ether sulfate salt is 12-16, ethoxy radix is 1-4; Described polyoxyethylene alkyl ether sulfate salt is selected from the sodium salt of polyoxyethylene alkyl ether sulfate or potassium salt or ammonium salt or tri ethanol ammonium salt.
Preferably, the general formula of described betaines surfactant is R 1n +r 2r 3y, R 1for C 8-22alkyl or alkenyl, R 2, R 3for low alkyl group, Y is selected from-CH 2cOOM ,-CH 2cHOHCH 2sO 3m or-CH 2pO 4m, M are hydrogen, sodium, potassium or triethanolamine.
Preferably, described N-amic acid type surfactant comprise following one or more: the sodium salt of N-acylamino acid, potassium salt or triethanolamine salt; The carbon number of the alkyl group of described N-amic acid type surfactant is 8-18, amino acid group be following one or more: glycine, glutamic acid, alanine, sarcosine, taurine or collagen amino acid.
Preferably, described cation opsonizing agent comprise following one or more: quaternized polysaccharide, polyquaternary ammonium salt, micromolecule cationic compound; Described cation opsonizing agent is preferably cationic oligomeric fructose, Polyquaternium-10, polyquaternary ammonium salt-7.
Preferably, described polysiloxanes is the emulsified silicone oil of 0.01-10 micron grain size and/or the amino emulsified silicone oil of 0.01-10 micron grain size; The emulsified silicone oil of the preferred 0.05-1 micron grain size of described polysiloxanes.
The oily hair-washing composition of described control also comprises: viscosity modifier, essence, antiseptic, auxiliary agent;
Described viscosity modifier accounts for the 0.1%-4% of composition total weight;
Described essence, antiseptic, auxiliary agent are in right amount.
Preferably, described viscosity modifier be selected from coconut oil fat acid diethanolamide, O-phthalic alkanol amides, ethylene glycol stearate, Polyoxyethylene Methyl Glucoside Ether dioleate and/or refined salt.
Described auxiliary agent is optionally one or more in ethylenediaminetetraacetic acid, edetate, 2,6-di-tert-butyl-4-methy phenols, polyoxyethylene ether, cellulose modified thing, citric acid, triethanolamine.
Preferably; each constituent content is as follows: to account for the percentages that described control oil wash sends out combination general weight, the sodium laureth sulfate of 8%, 4% palmityl N-methyltaurine sodium, 2% sodium lauroyl glutamate, 2% cocamido propyl betaine, 0.25% cation guar gum, the polysiloxane microemulsion of 1.5%, coconut oil fat acid diethanolamide, the pyridone ethanolamine of 0.15%, zinc pyrrolidone carboxylate, the pyrrolidone sodium carboxylate of 0.1%, appropriate auxiliary agent, the surplus of 0.1% of 2% be water.
The oily hair-washing composition of control provided by the invention, wherein, surfactant, for not stimulating, gentle surfactant, by polyoxyethylene alkyl ether sulfate salt, N-acylamino-hydrochlorate, betaines is composite forms, comparatively strong to sebum emulsifying capacity, effectively to remove on hair residual cleaning ingredients on dust and hair, reach deep layer cleaning, mild low-stimulation effect; Gathering on hair after conditioner can reduce life-time service, salubriouser after hair is washed; Wetting agent, has certain moistening effect in hair-washing composition formula, can avoid the over-drying scalp itch caused and stimulate sebum excessive secretion, can also bring the dry soft effect sent out simultaneously; In addition, present inventor finds that scalp is subject to free fatty stimulation that oils and fats can be caused too much to secrete, add appropriate antimicrobial component as new health azoles (i.e. Dichlorobenzene base imidazoles dioxolanes), pyridone ethanolamine etc., reduce free fatty generation by breedings such as chlosmas on their suppression hairs and oil-control is too much; Interpolation active carbon, water-soluble zinc salt such as zinc pyrrolidone carboxylate can restrain scalp pore, reduce oils and fats and generate; Add suitable wetting agent if pyrrolidone sodium carboxylate, pantothenylol or ethoxy urea etc. are in maintenance scalp and hair-care humidity, the oils and fats reducing dry scalp and/or hair quality overflows.The comprehensive proportioning of above-mentioned each composition is formed the oily hair-washing composition of control by the application, the composite conditioner of gentle inirritative surfactant system, the cation opsonizing agent do not gathered and silicone oil greatly can reduce the secretion of oils and fats simultaneously at the clean scalp of deep layer, and with antibacterial, control that oil additive etc. is collaborative can realize good control oil effect, and do not adopt the antibacterial needing suspension system, improve comprehensive result of use.
Accompanying drawing explanation
Fig. 1 shows the cumulant of embodiment four-embodiment seven.
Detailed description of the invention
Also by reference to the accompanying drawings the present invention is described in further detail below by specific embodiment.
Embodiment one:
The oily hair-washing composition of a kind of control, comprising: water, surfactant, conditioner, wetting agent, control oil additive, antibacterial;
Described surfactant comprises: with composition total weight percentages, 8%-15% polyoxyethylene alkyl ether sulfate salt, 1%-8%N-amic acid type surfactant, 1%-6% betaines surfactant;
Described conditioner comprises: with composition total weight percentages, 0.1%-2% cation opsonizing agent, 0.1%-3% polysiloxanes;
With composition total weight percentages, 0.1%-2% wetting agent, 0.05%-2% control oil additive, 0.05%-1% antibacterial, surplus are water;
Described wetting agent comprise following one or more: sodium lactate, pyrrolidone sodium carboxylate, pantothenylol, ethyl panthenol, protein hydrolyzate, ethoxy urea, Macrogol 200-600;
Described control oil additive comprise following one or more: zinc pyrrolidone carboxylate, vitamin B6, menthol, Borneolum Syntheticum, Citrus aurantifolia oil, active carbon;
Described antibacterial comprise following one or more: Zinc Undecylenate, undecylenic acid single ethanol amide sulfosuccinate disodium, climbazole, Dichlorobenzene base imidazoles dioxolanes, pyridone ethanolamine, isethionic acid six amidine, Camellia sinensis leaf oil.
The oily hair-washing composition of control provided by the invention, wherein, surfactant, for not stimulating, gentle surfactant, by polyoxyethylene alkyl ether sulfate salt, N-acylamino-hydrochlorate, betaines is composite forms, comparatively strong to sebum emulsifying capacity, effectively to remove on hair residual cleaning ingredients on dust and hair, reach deep layer cleaning, mild low-stimulation effect; Gathering on hair after conditioner can reduce life-time service, salubriouser after hair is washed; Wetting agent, has certain moistening effect in hair-washing composition formula, can avoid the over-drying scalp itch caused and stimulate sebum excessive secretion, can also bring the dry soft effect sent out simultaneously; In addition, present inventor finds that scalp is subject to free fatty stimulation that oils and fats can be caused too much to secrete, add appropriate antimicrobial component as new health azoles (i.e. Dichlorobenzene base imidazoles dioxolanes), pyridone ethanolamine etc., reduce free fatty generation by breedings such as chlosmas on their suppression hairs and oil-control is too much; Interpolation active carbon, water-soluble zinc salt such as zinc pyrrolidone carboxylate can restrain scalp pore, reduce oils and fats and generate; Add suitable wetting agent if pyrrolidone sodium carboxylate, pantothenylol or ethoxy urea etc. are in maintenance scalp and hair-care humidity, the oils and fats reducing dry scalp and/or hair quality overflows.The comprehensive proportioning of above-mentioned each composition is formed the oily hair-washing composition of control by the application, the composite conditioner of gentle inirritative surfactant system, the cation opsonizing agent do not gathered and silicone oil greatly can reduce the secretion of oils and fats simultaneously at the clean scalp of deep layer, and with antibacterial, control that oil additive etc. is collaborative can realize good control oil effect, and do not adopt the antibacterial needing suspension system, improve comprehensive result of use.
Embodiment two:
The basis of embodiment one further comprises: viscosity modifier, essence, antiseptic, auxiliary agent; Described viscosity modifier accounts for the 0.1%-4% of composition total weight; Described essence, antiseptic, auxiliary agent are in right amount.
Surfactant, for not stimulating, gentle surfactant, by polyoxyethylene alkyl ether sulfate salt, N-acylamino-hydrochlorate, betaines is composite forms.Comparatively strong to sebum emulsifying capacity, effectively to remove on hair residual cleaning ingredients on dust and hair, reach deep layer cleaning, mild low-stimulation effect.Wherein:
Polyoxyethylene alkyl ether sulfate salt:
Polyoxyethylene alkyl ether sulfate salt, it is 25%-70% aqueous solution that abbreviation AES, commercially available AES are generally mass fraction, and average ethoxylation number is 3, is actually the mixture of 1-4, and the carbon number of alkyl group is 12-16.AES foam performance is good, and cloud point, zest are all low than alkyl sulfate salt, have good aqueous solubility, more stable.Composite with other aniones, nonionic or amphoteric surfactant, all there is cooperative effect to its zest, viscosity and foam, easy-to-use salt thickening.In different concrete enforcement, can select from the sodium salt of polyoxyethylene alkyl ether sulfate, potassium salt, ammonium salt or tri ethanol ammonium salt, wherein, sodium laureth sulfate, its pH value (solution content 5%) about 7-8, zest is less.
N-amic acid type surfactant:
N-amic acid type surfactant is the amide that amino acid whose amino and fatty acid condensation are formed; the carbon number of the alkyl group of N-amic acid type surfactant is 8-18; amino acid group be following one or more: glycine, glutamic acid, alanine, sarcosine, taurine, collagen amino acid; it is nontoxic, biodegradable; compatibility is good; foaming capacity is good; be not subject to the impact of pH and the water hardness; and gentle, zest is very low, can significantly reduce formula system zest, can also play certain moistening effect.Select from the sodium salt of N-acylamino acid, potassium salt or triethanolamine salt in concrete enforcement, wherein, preferred palmityl N-methyltaurine sodium, sodium lauroyl glutamate etc., it is reported, use the shampoo containing N-acyl methyl taurine sodium, dandruff amount reduces, and can be used to the shampoo of preparing " everyday having one's hair wash "; Sodium lauroyl glutamate also has certain moisture-keeping efficacy.
Betaines surfactant:
Betaines surfactant belongs to amphoteric surfactant, the electrolyte of low toxicity, low stimulation, resistance to hard water and higher concentration, there is certain bactericidal properties and press down mouldiness, emulsifying wettability and foaminess is fine, biological degradability is good, and can with nearly all other types surfactant compatibility, and have cooperative effect.The general formula of betaines surfactant is R 1n +r 2r 3y, R 1for C 8-22alkyl or alkenyl, R 2, R 3for low alkyl group, Y is selected from-CH 2cOOM ,-CH 2cHOHCH 2sO 3m or-CH 2pO 4m, M are hydrogen, sodium, potassium or triethanolamine.Betaine series surfactants comprises carboxylic acid type, sulfuric acid ester type and sulfonic acid type, and basic molecular structure is made up of quaternary ammonium salt cationic and respective anionic, and when pH convergence 7, zest is minimum.Wherein, preferred cocamido propyl betaine.
Conditioner
Gathering on hair after selected conditioner can reduce life-time service, salubriouser after hair is washed.Be selected from not easily to produce and gather the cation opsonizing agent of effect and/or the polysiloxanes of microemulsified.Being suitable for cation opsonizing agent of the present invention is low charge density high molecular polymer and/or micromolecule cationic compound, comprise quaternized polysaccharide, quaternized hydrolytic collagen, polyquaternary ammonium salt and their derivant, as cation guar gum, cationic oligomeric fructose, cationic cellulose, Polyquaternium-10, quaternized Cassia bean gum, polyquaternary ammonium salt-7, polyquaternary ammonium salt-47, polyquaternary ammonium salt-39, quaternary ammonium salt-22 etc., continue to use, hair can not produce bring because of accumulation coarse, dry and astringent or the sensation of hardening.Be suitable for polysiloxanes of the present invention and be selected from the amino emulsified silicone oil of the emulsified silicone oil of 0.01-10 micron grain size, 0.01-10 micron one or more.Greatly can improve dry, wet Comb rationality after the compositions of the application adds these silicone oil, increase feel soft as hair gloss and silk, do not accumulate on hair simultaneously.Again can select particle diameter in some are specifically implemented, the emulsified silicone oil of the particle diameters such as such as 0.05 micron, 0.1 micron, 0.5 micron, 2 microns, 1 micron, 3 microns, cumulative bad is very low.
Wetting agent
Described wetting agent is made up of one or more in sodium lactate, pyrrolidone sodium carboxylate, pantothenylol, ethyl panthenol, protein hydrolyzate, ethoxy urea, Macrogol 200-600.They commonly use wetting agent for washing hair products, in hair-washing composition formula, have certain moistening effect, can avoid the over-drying scalp itch caused and stimulate sebum excessive secretion, can also bring the dry soft effect sent out simultaneously.
Antibacterial
Described antibacterial comprise in Zinc Undecylenate, undecylenic acid single ethanol amide sulfosuccinate disodium, climbazole, Dichlorobenzene base imidazoles dioxolanes, pyridone ethanolamine, isethionic acid six amidine one or more, and/or Camellia sinensis leaf oil.Due to the existence of the funguses such as chlosma on scalp, sebum is caused to be decomposed into unsaturated fatty acid, and then the excessive secretion of scalp irritation sebum, by adding suitable antibacterial, control the breeding of scalp chlosma, effectively can remove dandruff, can sebum secretion be reduced again, reach the effect of anti-dandruff control oil.The application selects the antibacterial not adopting and need suspension system, improves comprehensive result of use.
Control oil additive
Described control oil additive comprise in zinc pyrrolidone carboxylate, vitamin B6, menthol, Borneolum Syntheticum one or more, or Citrus aurantifolia oil or active carbon.Menthol, Borneolum Syntheticum can bring moment salubrious sense, have again auxiliary itching-relieving efficacies; Zinc pyrrolidone carboxylate, Citrus aurantifolia quintessence oil, bamboo charcoal are the common control oil component of daily cosmetics, can work in coordination with in the composition and promote integral formulation control oil effect.
Viscosity modifier
Described viscosity modifier be selected from coconut oil fat acid diethanolamide, O-phthalic alkanol amides, ethylene glycol stearate, Polyoxyethylene Methyl Glucoside Ether dioleate and/or refined salt.
Auxiliary agent
The auxiliary agent that the present invention adopts can for conventional hair washing auxiliary agent, for composition conventional in compositions, do not damage the hair conditioning of compositions, mildness, not characteristic of concentration and control oily effect, such as: comprise in ethylenediaminetetraacetic acid, edetate, 2,6-di-tert-butyl-4-methy phenols, polyoxyethylene ether, cellulose modified thing, citric acid, triethanolamine one or more.
Embodiment three:
Control oily hair-washing composition: comprise following composition; to account for the percentages that described control oil wash sends out combination general weight, the sodium laureth sulfate of 8%, 4% palmityl N-methyltaurine sodium, 2% sodium lauroyl glutamate, 2% cocamido propyl betaine, 0.25% cation guar gum, the polysiloxane emulsion of 1.5%, coconut oil fat acid diethanolamide, the pyridone ethanolamine of 0.15%, zinc pyrrolidone carboxylate, the pyrrolidone sodium carboxylate of 0.1%, appropriate auxiliary agent, the surplus of 0.1% of 2% be water.
For the percentage composition summation ensureing the oily hair-washing composition of control is 100%, therefore, do surplus with water.
The proportioning of concrete composition in different embodiment is below provided:
Table 1 controls fluid composition formula (composition total weight percentage ratio)
In table 1, zein value is lived by internationally recognized table, and zest method of testing---zein laboratory method (zein test) obtains, and reflects the irritating power of example four to seven compositions.Test philosophy and concrete method of testing are shown in patent " the mild compositions of low accumulation " (application number 201210338926.2).
Zein value is the value of internationally recognized zein laboratory method definition, has reacted surfactant or compositions zest power, without corresponding Chinese name, can be translated into " stimulus value ".
1, zest test
The formula of comparative example four and embodiment five, is not difficult to find to add merely the zest that new health azoles and menthol can not reduce formula.By contrast, under the formula table surfactant system of embodiment six, zest reduces obviously, and the low stimulation levels of convergence, the zest and the example six that add the example seven after new health azoles and menthol are close, also belong to low stimulation levels.
2, cumulative bad test
Referenced patent " the mild compositions of low accumulation " (application number 201210338926.2) cumulative bad test philosophy and concrete mode, successively cumulative bad test is carried out to example four-seven, experimental result as shown in Figure 1, transverse axis is washing times (1-10), the longitudinal axis is cumulative amount (0.00-0.4) after each washing, and unit is gram.As can be seen from Figure 1, embodiment four, five cumulant increases in obvious increasing trend with shampoos, and embodiment six, seven cumulant increases in smooth trend with shampoos.
3, the test on probation of oily effect is controlled
Select embodiment five, seven and on the market certain brand control oil type shampoo (matched group) do the test on probation of the oily effect of control.Using method is identical with number of times, and by choosing crowd's (men and women does not limit, seborrhea degree do not limit) of seborrheica hair quality, totally 150 examples, enter group at random, be divided equally into 3 groups, and embodiment five, seven on probation or certain brand control oil wash become visible by random.Three groups enter group situation in table 2,3, and result of the test statistical data is in table 4.
Three groups of tester's sex statistics participated in by table 2
Group Number Man Female
Embodiment five 50 27 23
Embodiment seven 50 30 20
Matched group 50 29 21
Add up to 150 86 64
Three groups of tester's age distribution participated in by table 3
Table 4 controls oily effect statistics on probation
Illustrate: effective percentage calculates " effect is fine ", " effective " two item number certificate.
Table 4 result shows, and the control oil effective percentage of embodiment five, seven and matched group is followed successively by 30%, 80% and 74%, and the control oil effect of embodiment seven is better than matched group, is obviously better than embodiment five.
The foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, for a person skilled in the art, the present invention can have various modifications and variations.Within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.

Claims (9)

1. control an oily hair-washing composition, it is characterized in that, comprising: water, surfactant, conditioner, wetting agent, control oil additive, antibacterial;
Described surfactant comprises: with composition total weight percentages, 8%-15% polyoxyethylene alkyl ether sulfate salt, 1%-8%N-amic acid type surfactant, 1%-6% betaines surfactant;
Described conditioner comprises: with composition total weight percentages, 0.1%-2% cation opsonizing agent, 0.1%-3% polysiloxanes;
With composition total weight percentages, 0.1%-2% wetting agent, 0.05%-2% control oil additive, 0.05%-1% antibacterial, surplus are water;
Described wetting agent comprise following one or more: sodium lactate, pyrrolidone sodium carboxylate, pantothenylol, ethyl panthenol, protein hydrolyzate, ethoxy urea, Macrogol 200-600;
Described control oil additive comprise following one or more: zinc pyrrolidone carboxylate, vitamin B6, menthol, Borneolum Syntheticum, Citrus aurantifolia oil, active carbon;
Described antibacterial comprise following one or more: Zinc Undecylenate, undecylenic acid single ethanol amide sulfosuccinate disodium, climbazole, Dichlorobenzene base imidazoles dioxolanes, pyridone ethanolamine, isethionic acid six amidine, Camellia sinensis leaf oil;
Described polysiloxanes is the emulsified silicone oil of 0.01-10 micron grain size and/or the amino emulsified silicone oil of 0.01-10 micron grain size;
Described cation opsonizing agent comprise following one or more: quaternized polysaccharide, polyquaternary ammonium salt, micromolecule cationic compound.
2. the oily hair-washing composition of control according to claim 1, is characterized in that,
The carbon number of the alkyl group of described polyoxyethylene alkyl ether sulfate salt is 12-16, ethoxy radix is 1-4; Described polyoxyethylene alkyl ether sulfate salt is selected from the sodium salt of polyoxyethylene alkyl ether sulfate or potassium salt or ammonium salt or tri ethanol ammonium salt.
3. the oily hair-washing composition of control according to claim 1, is characterized in that,
The general formula of described betaines surfactant is R1N+R2R3Y, R1 is C8-22 alkyl or alkenyl, and R2, R3 are low alkyl group, and Y is selected from-CH2COOM ,-CH2CHOHCH2SO3M or-CH2PO4M, and M is hydrogen, sodium, potassium or triethanolamine.
4. the oily hair-washing composition of control according to claim 1, is characterized in that,
Described N-amic acid type surfactant is selected from the sodium salt of N-acylamino acid, potassium salt or triethanolamine salt; The carbon number of the alkyl group of described N-amic acid type surfactant is 8-18, amino acid group be following one or more: glycine, glutamic acid, alanine, sarcosine, taurine or collagen amino acid.
5. the oily hair-washing composition of control according to claim 1, is characterized in that,
Described cation opsonizing agent is one or more in cationic oligomeric fructose, Polyquaternium-10, polyquaternary ammonium salt-7, quaternary ammonium salt-22.
6. the oily hair-washing composition of control according to claim 1, is characterized in that,
The emulsified silicone oil of described polysiloxanes 0.05-1 micron grain size.
7. the control oil hair-washing composition according to any one of claim 1-6, is characterized in that, also comprise: viscosity modifier, essence, antiseptic, auxiliary agent;
Described viscosity modifier accounts for the 0.1%-4% of composition total weight;
Described essence, antiseptic, auxiliary agent are in right amount.
8. the oily hair-washing composition of control according to claim 7, is characterized in that,
Described viscosity modifier be selected from coconut oil fat acid diethanolamide, O-phthalic alkanol amides, ethylene glycol stearate, Polyoxyethylene Methyl Glucoside Ether oleate and/or refined salt;
Described auxiliary agent is optionally one or more in ethylenediaminetetraacetic acid, edetate, 2,6-di-tert-butyl-4-methy phenols, polyoxyethylene ether, cellulose modified thing, citric acid, triethanolamine.
9. the oily hair-washing composition of control according to claim 7, is characterized in that,
Each constituent content is as follows: to account for the percentages that described control oil wash sends out combination general weight, the sodium laureth sulfate of 8%, 4% palmityl N-methyltaurine sodium, 2% sodium lauroyl glutamate, 2% cocamido propyl betaine, 0.25% cation guar gum, the polysiloxane microemulsion of 1.5%, coconut oil fat acid diethanolamide, the pyridone ethanolamine of 0.15%, zinc pyrrolidone carboxylate, the pyrrolidone sodium carboxylate of 0.1%, appropriate auxiliary agent, the surplus of 0.1% of 2% be water.
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