CN107296771A

CN107296771A - A kind of desquamation compositions and extra quality multiple-effect are without silicone oil shampoo

Info

Publication number: CN107296771A
Application number: CN201710638891.7A
Authority: CN
Inventors: 曾万祥; 覃敢为; 陈海; 黄娜; 曾嘉
Original assignee: Individual
Current assignee: Individual
Priority date: 2017-07-31
Filing date: 2017-07-31
Publication date: 2017-10-27

Abstract

The invention discloses a kind of desquamation compositions, piroctone olamine salt, hexamidine two (isethionic acid) salt, DM 846 and plant anti-dandruff agent are included；The DM 846 is the mixture of dichlorbenzyl alcohol, isostearoyl dilactic acid sodium, cocamidopropyl propyl amide PG alkyl dimethyl ammonium chlorides and sodium lactate；The plant anti-dandruff agent includes glycyrrhetinic acid, saponin(e and azadirachta seed extract.The invention also discloses a kind of extra quality multiple-effect without silicone oil shampoo.Extra quality multiple-effect of the present invention with the addition of desquamation compositions without silicone oil shampoo, using the design of two kinds of material bodies, make have good cleaning moisturizing effect but can not be while the Multiple components deposited for a long time are separately deposited in hair, use simultaneously, preferably cleaning and nourishes effect can be provided for hair, traditional silicone oil is substituted using fat agent is assigned, coordinates the raw materials such as non-stimulated preservative, hair conditioner, surfactant, effective cleaning and nourishing hair and scalp and good anti-dandruff effect is reached.

Description

A kind of desquamation compositions and extra quality multiple-effect are without silicone oil shampoo

Technical field

The present invention relates to a kind of hair shampoo article, and in particular to a kind of desquamation compositions and extra quality multiple-effect are without silicone oil shampoo.

Background technology

Shampoo refers to a kind of hair products with functions such as cleaning, reparation, anti-dandruff, treatment oil.Best in quality washes The dirt grease adhered on scalp and hair can effectively be cleaned by becoming visible, meanwhile, also to the nutrition and protection needed for scalp, to hair Bring soft, smooth and glossy.The species of shampoo is although various in the market, but generally can not all reach profound clear Clean effect, but also easily cause the generation of some side effects such as scalp itch and dry hair tarnish.The head of health Skin ecological environment is maintained by the balance of finance, credits and materials：Grease, flora, metabolic balance.When scalp fat secretion is unbalance, scalp will be easy It is fuel-displaced to become greasy thick and heavy；When scalp flora environment is unbalance, bacterium will largely grow, and it is hard to bear that scalp just occurs that head is itched Phenomenon；When scalp metabolic imbalance, stratum corneum is too fast, causes the too fast formation dandruff that comes off.These three balances are once lost Weighing apparatus can all trigger various scalp problems, the problems such as such as alopecia, dandruff are more and head itches hard to bear.Many people are for beauty, warp now Often hair-waving is had hair dyed so that hair is withered impaired serious, along with the environmental pollution being on the rise, and the fungi on scalp is more next It is more, cause the various symptom of scalp, such as dandruff is excessive, and hair is short-tempered, alopecia etc..But with the improvement of people's living standards, Consumption concept and health perception gradually strengthen, and to the quality requirement of shampoo also more and more higher, deep layer is carried out to hair and scalp Secondary cleaning simultaneously reaches that repairing the shampoo for nourishing hair is badly in need of exploitation simultaneously.

Contain various anion, cation, nonionic and amphoteric surfactant in usual shampoo formula, due to the moon With cationic surfactant contact for a long time corresponding chemical reaction can then occur for ion, therefore limit some compositions Using cannot just use other that there is the cationic surface of good effects composition using some anion surfactants Hexadecyltrimethylammonium chloride this component will not be added in activating agent, such as usual shampoo because itself be sun from Sub- surfactant, easily produces reaction with the anion surfactant in shampoo etc., but itself is in shampoo There is good effect, after use hair can be made more soft as softening agent and conditioner.

In addition, existing shampoo uses DMDMH, methylisothiazolinone, methylchloroisothiazandnone mostly As preservative, excitant is larger, and head can be caused to itch and dandruff, and the immediate cause of dandruff is inflammation caused by stimulating.Work as thorn The metabolin of stimulus, such as fungi, comb it is improper, take care of hair improper when causing inflammation, Skin Cell can then accelerate hyperplasia, cause dead Skin comes off, that is, our so-called dandruffs.In many cases, the principal element or chlosma amount of dandruff are uneven Weighing apparatus.Suppress the key that scalp chlosma amount is treatment of dandruff.But anti-dandruff type shampoo is mostly using one kind currently on the market Or two kinds of anti-dandruff agents, or be known as and use plant anti-dandruff component, undesirable to eliminating chlosma effect, anti-dandruff effect is poor, especially It is the more oily hair of dandruff, it is more difficult to reach anti-dandruff；Moreover, when using using ZPT as anti-dandruff agent, using mostly Single card ripple class thickening suspending agent, causes product in the quality stability of selling period.Shampoo above can not meet existing For the composite request of people.

In order that hair is submissive in traditional shampoo, add the highly viscous silicon compound of some HMWs and serve as smooth Agent, they can be adsorbed in each hair surface, form very smooth film.The silicon compound commonly used in current shampoo has poly- Dimethyl siloxane, amido silicon oil, cyclomethicone etc., in hair-washing hair-care, these silicon-containing compounds can be between hair scale piece Gap fill up, people can be allowed to think that hair sense of touch is very smooth, but be due to that silicone oil has water insoluble characteristic, be wrapped in head Silicon on hair and scalp is less susceptible to be cleaned, and enrichment so year in year out, silicone oil can adsorb the meeting on hair Cause that hair is thicker, hair weight becomes weight, reduce the electrostatic interaction of hair, hair gradually lost elasticity, produced disconnected hair, scalp Clogging of pores, causes scalp oxygen flow not enough, papilla may gradually atrophy, scalp just start to occur it is withered and yellow, itch, or even alopecia Phenomenon, and siliceous oils product is used for a long time can be covered because of hair by silicone oil, the real nutrition subsequently nursed cannot be introduced into And hair quality is deteriorated.In addition these organosilicons are not only water insoluble but also insoluble in any surfactant, and environment is discharged into after hair washing It is difficult to it is biodegradable, easily cause environmental pollution.

In addition, the use of preservative is extremely common in washing product, but traditional preservatives have certain toxicity, use Amount is restricted, and does not reach preferable antiseptic effect.Excessive or inappropriate preservative can even make epidermal cell development not into Ripe, loosely organized, so that epidermis is thinning, easily by environmental stimuli, phylactic power defensive power declines, and makes skin follow the string gradually, easily production Raw relaxation, microgroove, and the Skin Cell damaged by preservative constantly defect can then be bred, and make skin quality worse and worse.So traditional Using for preservative is endangered so that existing washing product is badly in need of finding natural antiseptic agent or seted out to no added preservative direction.

Such as application number 201410299750.3 discloses a kind of antidandruff and antipruritic shampoo, and the shampoo of the invention is by shampoo Matrix and extracts of Chinese herbal medicine are made, wherein, extracts of Chinese herbal medicine is by shrubalthea leaf 30-45%, tea seed cake 20-30%, coptis 10- 15%th, extract and be made after radix scutellariae 10-15%, root bark of white mulberry 5-10%, balsamine 5-10% are mixed by weight percentage.In this application Although what is used is all crude drug component, extra anti-dandruff agent is not used in formula, although various Chinese herb medicines Component is no added safely, but individually plant extracts can not but reach the anti-dandruff effect of sterilization of profound level, and anti-dandruff effect Fruit slowly effect；Except there is no some other nourishing component using a variety of silicone oil components in hair conditioner in formula, although wash Touch up can be very submissive for hair afterwards, and people can be allowed to think that hair sense of touch is very smooth, but silicone oil is water insoluble, be wrapped in hair and Silicon on scalp is less susceptible to be cleaned, enrichment so year in year out, and silicone oil can be adsorbed can cause on hair Hair is thicker, weight becomes weight, hair is gradually lost elasticity, produces disconnected hair, scalp clogging of pores causes scalp oxygen flow not enough, Papilla may gradually atrophy, scalp just start occur it is withered and yellow, itch, or even alopecia phenomenon；Surfactant in formula All it is relatively common, due to being mixed, therefore some characteristic components can not be added；The preservative used is Metagin Ester and ethylparaben, are relatively common preservatives, but are connect studies have reported that them are excessively used in cosmetics and can cause Touch property dermatitis.Also studies have reported that nipagin esters can be accumulated in human body, the risk that increase women suffers from breast cancer with uterine cancer, The residual for there are a large amount of nipagin esters is found in the pathological section of a large amount of patient with breast cancers.

The content of the invention

A kind of desquamation compositions are provided it is an object of the invention to overcome the weak point of prior art presence and extra quality Multiple-effect is without silicone oil shampoo.

To achieve the above object, the technical scheme taken of the present invention is：A kind of desquamation compositions, include piroctone ethanol Amine salt, hexamidine two (isethionic acid) salt, DM-846 and plant anti-dandruff agent；The DM-846 is dichlorbenzyl alcohol, different tristearin The mixture of acyl dilactic acid sodium, cocamidopropyl propyl amide pg dimonium chloride and sodium lactate；The plant anti-dandruff agent is comprising sweet Careless booth acid, saponin(e and azadirachta seed extract.

Enoxolone is classical anti-inflammatory drug, with anti-inflammatory antiallergy, suppresses the effect such as bacterial reproduction.Adjustable skin Immunologic function, strengthen the resistance against diseases of skin, diminish inflammation, pre- hypo-allergenic, cleaning skin, cosmetics can be released and other outer Toxic side effect of boundary's factor to skin.Saponin(e, it is active or antipyretic, calm, antitumor, anti-inflammatory, immunological regulation with antibacterial, anti- The valuable bioactivity such as viral, antimycotic, liver-protecting activity.Azadirachta seed extract possess sterilization and antiviral characteristic and Desinsection, effect of sterilizing.Desquamation compositions of the present invention contain above-mentioned three kinds of materials, with preferable bactericidal action, and plant Thing extract is non-stimulated to scalp, and three plays a role jointly reaches anti-dandruff effect.

Piroctone olamine salt, is also anti-dandruff agent OCTO, famous because of its bacteriostasis, particularly can suppress ovale malaria Protozoon, it is parasitized in the scurf of dandruff, face etc..The material is a kind of efficient, nontoxic non-stimulated anti-dandruff agent, can be extensive Anti-dandruff shampoo, hair-nourishing liquid and hair conditioner etc. is used in wash in shield class cosmetics.OCTO anti-dandruff and itching-relieving mechanism be by sterilization and Antioxidation fundamentally blocks the outside channel that dandruff is produced, so that effectively radical cure dandruff, stopping head itching, rather than by de- The modes such as fat temporarily eliminate dandruff from presentation.Here it is one of the reason for OCTO anti-dandruff and itching-relievings performance is better than like product.Should Material identifies very reliable to the security of eyes, skin through external authoritative institution.Absolute non-toxic, excitant and sensitization. In actual use will not damaged scalp, be not in alopecia, disconnected hair.

Hexamidine two (isethionic acid) salt (Pf-95) it is a kind of new water-soluble cationic dandruff-removing itching-relieve Agent, with broad-spectrum antiseptic and bactericidal property, has to various gram-positive bacterias and negative bacterium and various yeast and molds Very high sterilization and bacteriostasis property, especially to the pityrosporum ovale for causing dandruff, because its unique structure is with very strong Killing action, and to causing the propionibacterium acnes of acne to have very strong suppression and sterilization effect.And very safety is warm With, it is small to skin irritation, with daily chemical products commonly use raw material compatibility it is excellent.Especially because its cationic is produced to hair Raw suction-operated, is more beneficial for the reinforcement and persistently performance of its anti-dandruff effect, this is the characteristic that other anti-dandruff agents do not possess.

DM-846 be by dichlorbenzyl alcohol, isostearoyl dilactic acid sodium, cocamidopropyl propyl amide pg dimonium chloride and The mixture of sodium lactate composition, the efficient sterilizing effect with wide spectrum.There is very strong antibacterial and sterilizing effect to the fungi of scalp Really.The Malassezia furfur being attached on scalp can be killed, efficient moisturizing effect is provided for scalp, effectively prevents scalp Flakes scurf is produced, can be prevented because the inflammation that allergy is produced causes head to be itched；Excessive degreasing is prevented, dry scalp causes to produce skin Bits.There are anti-inflammatory, resistance state effect.There is synergy to the sterilization of other compositions, fungistatic effect in desquamation compositions, can be with Reduce the excitant and anaphylaxis of desquamation compositions.

Desquamation compositions of the present invention are used using compound match of above-mentioned four kinds of different types of anti-dandruff agents, can be highlighted Multiple anti-dandruff effect, Synergistic, also has preferable moisture-keeping efficacy while to scalp bactericidal each other, correct Skin is non-stimulated, and anti-dandruff effect is lasting.

Preferably, the piroctone olamine salt, hexamidine two (isethionic acid) salt, DM-846 and plant anti-dandruff agent Weight ratio be：Piroctone olamine salt：Hexamidine two (isethionic acid) salt：DM-846：Plant anti-dandruff agent=0.01 ~0.3:0.05~0.5:0.1~0.6:0.5~5.

Four kinds of anti-dandruff agents are using anti-dandruff best results during aforementioned proportion compounding use in desquamation compositions of the present invention.

Preferably, the weight ratio of the glycyrrhetinic acid, saponin(e and azadirachta seed extract is：Glycyrrhetinic acid：Saponin(e：Print Spend chinaberry seed extract=1~3:1~3:3~9.

When glycyrrhetinic acid, saponin(e and azadirachta seed extract use above-mentioned ratio, the collaboration of three can be preferably played Synergistic effect, so as to reach preferably anti-dandruff effect.

It is highly preferred that the weight ratio of the glycyrrhetinic acid, saponin(e and azadirachta seed extract is：Glycyrrhetinic acid：Saponin(e： Azadirachta seed extract=1:1:3.

When glycyrrhetinic acid, saponin(e and azadirachta seed extract use above-mentioned ratio, the anti-dandruff best results reached.

Preferably, the dichlorbenzyl alcohol, isostearoyl dilactic acid sodium, cocamidopropyl propyl amide pg dimonium chloride Weight ratio with sodium lactate is：Dichlorbenzyl alcohol, isostearoyl dilactic acid sodium, cocamidopropyl propyl amide PG- dimethylammonium chlorides Ammonium and sodium lactate=18~20:5~7:68~70:5~7.

When each component uses above-mentioned weight ratio in the DM-846, also have while stronger bactericidal and bacteriostatic effect can be reached Preferable moistening effect.

Another object of the present invention also resides in a kind of extra quality multiple-effect of offer without silicone oil shampoo, and the extra quality multiple-effect is without silicone oil Shampoo includes above-mentioned desquamation compositions.

Preferably, the extra quality multiple-effect includes the first material body and the second material body without silicone oil shampoo；

The first material body includes the preparing raw material of following weight percentage：First surface activating agent 15~24% and One preservative 0.3~0.8%；

The second material body includes the preparing raw material of following weight percentage：Second surface activating agent 8~27%, hair Conditioner 4.95~20.1%, the preservative 0.2~1% of desquamation compositions 0.66~6.4% and second.

Extra quality multiple-effect of the present invention refers to the first material without design of the silicone oil shampoo using double-deck material body, bilayer material body Body and the second material body are separately deposited, but the first material body is used together with the second material body when using, and this design can be by using Two containers deposit the first material body and the second material body respectively, or easy to use and carry, using with two chambers The packaging of two outlets separately deposits two kinds of material bodies, and the selection specifically packed can be designed according to actual conditions.First material body Separately deposit, can be avoided because some reactions make some components cannot be while depositing but having well with the second material body Effect, so as to be that shampoo preferably can provide cleaning and nourishes effect for hair.Two kinds of material bodies are separated, and can both be avoided Can not be used caused by the reaction of some of which cationic surfactant and anion surfactant some effects compared with Good composition and the problem of be unable to long-term storage, can cause this shampoo to reach that many effects are deep when in use again The effect that level is cleaned and repaired.

Extra quality multiple-effect of the present invention contains the desquamation compositions without silicone oil shampoo, with preferable anti-dandruff effect.

Preferably, the first surface activating agent is anion surfactant；The second surface activating agent for it is non-from Sub- surfactant and/or amphoteric surfactant.

As a result of the two kinds of material separately deposited bodies, first surface activating agent can be selected preferable to hair cleaning effect Anion surfactant, second surface activating agent can select to the preferable nonionic surfactant of hair nourishes effect And/or amphoteric surfactant, coordinate the use of desquamation compositions, make shampoo of the present invention that there is cleaning to moisten anti-dandruff many Effect of level.

Preferably, the first surface activating agent includes laureth sodium sulfovinate and laruyl alcohol sodium sulfovinate；It is described Laureth sodium sulfovinate and the weight ratio of laruyl alcohol sodium sulfovinate are：Laureth sodium sulfovinate：Laruyl alcohol sulfuric acid Ester sodium=13~18：2~6；The second surface activating agent includes Cocoamidopropyl betaine, imidazoline, coconut oleoyl amine ox Sodium sulfonate, coconut oleoyl amine DEA and coconut oleoyl amine MEA, the Cocoamidopropyl betaine, imidazoline, coconut oleoyl amine taurine The weight ratio of sodium, coconut oleoyl amine DEA and coconut oleoyl amine MEA is：Cocoamidopropyl betaine：Imidazoline：Coconut oleoyl amine ox Sodium sulfonate：Coconut oleoyl amine DEA：Coconut oleoyl amine MEA=5~10：1~10：1~3：0.5~1.5：0.5~2.5.

When first surface activating agent selects above-mentioned anion surfactant, can preferably it be cleaned to hair, second When surfactant uses above-mentioned nonionic surfactant and amphoteric surfactant, also have while with cleaning efficacy There is the moist effect of deep layer, two kinds of surfactants expect separately to deposit in body using aforementioned proportion at two, while making when using With coordinating the use of desquamation compositions, carry out deep clean to hair carry, anti-dandruff and repair moist effect.

Preferably, the hair conditioner comprising behenyl base trimethyl ammonium chloride, guar hydroxypropyltrimonium chloride, Polyquaternium -7, Polyquaternium-10, panthenol, hydrolysis fibroin, hexadecyltrimethylammonium chloride, allantoin, the phosphorus of hydroxyl second two Acid, EDETATE SODIUM, phytosterol Queensland nut oleate, 12~13 carbon alcohol lactates, cocoyl glucoside, silk silk gum egg In vain, at least one of dipentaerythritol pentaerythritol tetraisostearate and glyceryl oleate.

Because traditional silicone oil is not dissolved in surfactant system, easily absorption is used for a long time on hair and is difficult clear Wash, hair is gradually lost elasticity for a long time, produce disconnected hair, scalp clogging of pores causes scalp oxygen flow not enough, papilla may be by Gradually atrophy, scalp just start occur it is withered and yellow, itch, or even alopecia phenomenon.The present invention uses phytosterol Queensland nut oleic acid Ester, 12~13 carbon alcohol lactates, dipentaerythritol pentaerythritol tetraisostearate and glyceryl oleate are traditional as fat agent replacement is assigned Silicone oil, they are completely soluble in the surfactant system of shampoo, and their structure and the grease in skin into Divide and all compare approximate, therefore correct leatherware has extraordinary nourish to lubricate, and hair can be made to wash rear salubrious submissive non-greasy, will not There is the gloss of obvious thick and heavy sense, softening hair and increase hair.

Hydrolyze fibroin, be the natural polymer fibrin extracted from silk, content account for silk 70%~ 80%, containing 18 kinds of amino acid, there is preferable affinity interaction to hair, can prevent in hair surface formation protectiveness transparent membrane Only injury of the thioglycolate salt to hair, the various nutrients needed for supplement hair, improves the gloss and elasticity of hair, can be effective Hair damage is prevented, makes hair distribute the gloss of ripples and the slim and graceful softness such as tiffany.Fibroin is hydrolyzed also to by the lost head Hair has obvious repairing effect.And the naturally effective ingredient layering release in hydrolysis fibroin liquid, 10 seconds infiltration flesh Skin skin corium, effectively suppresses melanin generation, and with collagen synthesis is promoted, activating cell improves immunity of cell etc. Effect.

Hexadecyltrimethylammonium chloride, without the application in silicone oil shampoo, can be avoided in extra quality multiple-effect of the present invention Reacted with activating agent inside the anion table in the first material body, good softening agent and hair care can be used as in shampoo Agent.

The hair conditioner selects the above-mentioned material non-stimulated to scalp, makes above-mentioned shampoo of the invention not silicate-containing oil, Scalp and moist hair can be effectively nourished, makes hair submissive glossy not short-tempered after washing.

It is highly preferred that the hair conditioner includes behenyl base trimethyl ammonium chloride, melon glue Hydroxyproyl Trimethyl chlorination Ammonium, polyquaternium -7, Polyquaternium-10, panthenol, hydrolysis fibroin, hexadecyltrimethylammonium chloride, allantoin, hydroxyl second Diphosphonic acid, EDETATE SODIUM, phytosterol Queensland nut oleate, 12~13 carbon alcohol lactates, cocoyl glucoside, silk silk gum Albumen, dipentaerythritol pentaerythritol tetraisostearate and glyceryl oleate；The behenyl base trimethyl ammonium chloride, melon glue hydroxypropyl Trimethyl ammonium chloride, polyquaternium -7, Polyquaternium-10, panthenol, hydrolysis fibroin, hexadecyltrimethylammonium chloride, urine Bursin, Etidronic Acid, EDETATE SODIUM, phytosterol Queensland nut oleate, 12~13 carbon alcohol lactates, cocoyl glucose Glycosides, silk sericin, the weight ratio of dipentaerythritol pentaerythritol tetraisostearate and glyceryl oleate are：Behenyl base trimethyl Ammonium chloride：Guar hydroxypropyltrimonium chloride：Polyquaternium -7：Polyquaternium-10：Panthenol：Hydrolyze fibroin：16 Alkyl trimethyl ammonium chloride：Allantoin：Etidronic Acid：EDETATE SODIUM：Phytosterol Queensland nut oleate：12~13 carbon alcohol Lactate：Cocoyl glucoside：Silk sericin：Dipentaerythritol pentaerythritol tetraisostearate：Glyceryl oleate=0.3~ 0.8：0.1~0.6：1~5：0.05~0.3：0.5~1.5：0.5~1.5：0.5~1.5：0.1~0.5：0.05~0.15： 0.05~0.15：0.2~0.8：0.2~0.8：0.2~2：0.2~1.2：0.2~0.8：0.8~2.5.

When hair conditioner is arranged in pairs or groups in use, making shampoo to have using said ratio and the other compositions of shampoo Effect ground cleaning hair scalp, with preferable anti-dandruff effect, moreover it is possible to repair disconnected hair, fork hair, improve hair quality, nourish scalp and moisten Hair.

Preferably, first preservative and the second preservative are decoyl hydroximic acid, parahydroxyacet-ophenone, glycerine octanoic acid The mixture of fat and butanediol.

The use of preservative is extremely common in washing product, but excessive or inappropriate preservative can make epidermal cell Developmental immaturity, loosely organized, so that epidermis is thinning, easily by environmental stimuli, phylactic power defensive power declines, and meeting damaging cells DNA makes skin Skin is followed the string gradually, easily produces relaxation, microgroove, and the Skin Cell damaged by preservative constantly defect can then be bred, order Skin quality is worse and worse.The present invention uses antiseptic substitute --- and HL-01, is decoyl hydroximic acid, parahydroxyacet-ophenone, caprylic The mixture of sour fat, butanediol.Wherein, decoyl hydroximic acid is more effective to mould, an unbounded quantity of to require, and excitant is low, and The compatibility of cosmetic material is preferable；In addition, decoyl hydroximic acid has chelating Ca²⁺, Fe²⁺And Fe³⁺Effect, it is possible to reduce metal The concentration of ion.Parahydroxyacet-ophenone is a kind of natural plant extracts, is naturally occurring in stem, the leaf of feverfew artemisia scoparia, mattress In the roots of plant such as old wormwood artemisia, Asclepiadaceae plant, kerr tylophora root.It is that current the world of medicine is most safe to application on human skin without any harm High temperature auxiliary activity stabilizer, used in cosmetic industry mainly as preservative, be widely used in medicine, make up Product, industrial circle.Glycerol caprylate is a kind of novel non-toxic high-efficiency broad spectrum preservative.It has to gram- bacteria, mould, yeast Inhibitory action, there is anti-corrosion and emulsification dual-use function, is that can be used for emulsion, surfactant product, the product of water alcohol system, there is anti- The effects such as bacterium, moisturizing, stuffing, it is mainly used in antiseptic and emulsifying agent in food, cosmetics and medical industry.Butanediol is many One kind of first alcohol, often NMF is done and solvent is used in cosmetics, in terms of moisturizing, due to butanediol be small molecule moisturizing into Part, so water ratio very little is grabbed, while also there is certain bacteriostasis.Security is worth affirmative, will not produce irritable inflammation. Therefore, the present invention can be prevented using above-mentioned four kinds of material mixings as a kind of gentle preservative of efficient natural for substituting tradition Rotten agent, reduces the infringement that traditional preservatives are brought to scalp.

Extra quality multiple-effect of the present invention is without silicone oil shampoo, in addition to said components are clearly required, in the lossless present invention Effect in the range of, other adjunct ingredients, such as pH adjusting agent, essence etc., those skilled in the art can be added or used to Conventional content can be selected according to conventional criteria.

Another object of the present invention also resides in a kind of above-mentioned preparation method of the extra quality multiple-effect without silicone oil shampoo of offer, including The preparation and the preparation of the second material body of first material body；

The preparation of the first material body comprises the following steps：

(1) in the deionized water that, first surface activating agent is added to 80~85 DEG C, homogeneous uniform is incubated 30min；

(2), the mixture after step (1) homogeneous is cooled, 40~45 DEG C are cooled to, the first preservative is added, increases Thick dose and essence, stir, and adjust pH value, adjust to target viscosity, produce the first material body；

The preparation of the second material body comprises the following steps：

(a), second surface activating agent and hair conditioner are added in 80~85 DEG C of deionized water, is well mixed, obtains Component A；

(b) component A, is cooled to 40~45 DEG C, second surface activating agent and hair conditioner are added thereto, mixing is equal It is even, obtain component B；

(c) component B, is cooled to less than 42 DEG C, hair conditioner, desquamation compositions, the second preservative are added thereto And thickener, it is well mixed, adjusts pH value, adjusts to target viscosity, produce the second material body.

Thickener can also select Cocoamidopropyl betaine from salt such as sodium chloride.Using above method system Standby shampoo character is stable, it is long-term place be not in bleed, layering, separation, precipitation, discoloration, peculiar smell, demulsification etc. no Good phenomenon.

The beneficial effects of the present invention are：Had one's hair wash the invention provides a kind of desquamation compositions and extra quality multiple-effect without silicone oil Dew, the anti-dandruff effect of desquamation compositions of the present invention is notable and non-stimulated to scalp, with multiple anti-dandruff effect.The present invention The extra quality multiple-effect with the addition of desquamation compositions without silicone oil shampoo, using the design of two kinds of material bodies, make to have well hair Cleaning moisturizing effect but can not the Multiple components that deposit for a long time simultaneously, separately storage, uses, preferably can be carried for hair simultaneously For cleaning and nourishes effect；Traditional silicone oil is substituted using fat agent is assigned, with the use of non-stimulated preservative, hair conditioning The raw materials such as agent, surfactant, reach the overall mildness for improving shampoo, reduce excitant of the cleansing to scalp.This Invent the shampoo can effectively cleaning and nourishing hair and scalp, make hair salubrious elegant submissive, be not in hair washing back Skin hardly possible is ventilative, greasy thick and heavy phenomenon, while having good anti-dandruff effect again.

Embodiment

To better illustrate the object, technical solutions and advantages of the present invention, below in conjunction with specific embodiment to the present invention It is described further.

Embodiment 1

A kind of embodiment of the extra quality multiple-effect of the present invention without silicone oil shampoo, the shampoo includes the first material body and the Two material bodies.

The first material body includes the preparing raw material of following weight percentage：First surface activating agent 17%, first is prevented Rotten agent 0.6%, essence 0.6%, the deionized water of pH adjusting agent 0.3% and surplus；

Wherein, first surface activating agent is the mixture of laureth sodium sulfovinate and laruyl alcohol sodium sulfovinate, described Laureth sodium sulfovinate and the weight ratio of laruyl alcohol sodium sulfovinate are：Laureth sodium sulfovinate：Laruyl alcohol sulfuric acid Ester sodium=14：3；

First preservative is the mixture of decoyl hydroximic acid, parahydroxyacet-ophenone, the sad fat of glycerine and butanediol；Institute PH adjusting agent is stated for citric acid and sodium hydroxide.

The second material body includes the preparing raw material of following weight percentage：Second surface activating agent 16.3%, hair Conditioner 11.46%, the preservative 0.6% of desquamation compositions 3.8% and second, the deionized water of pH adjusting agent 0.3% and surplus；

Wherein, the second surface activating agent be Cocoamidopropyl betaine, imidazoline, coconut oleoyl amine sodium taurocholate, Coconut oleoyl amine DEA and coconut oleoyl amine MEA mixture, the Cocoamidopropyl betaine, imidazoline, coconut oleoyl amine taurine The weight ratio of sodium, coconut oleoyl amine DEA and coconut oleoyl amine MEA is：Cocoamidopropyl betaine：Imidazoline：Coconut oleoyl amine ox Sodium sulfonate：Coconut oleoyl amine DEA：Coconut oleoyl amine MEA=8：2：2：0.8：1.5；

The hair conditioner be behenyl base trimethyl ammonium chloride, guar hydroxypropyltrimonium chloride, polyquaternium- 7th, Polyquaternium-10, panthenol, hydrolysis fibroin, hexadecyltrimethylammonium chloride, allantoin, Etidronic Acid, EDTA bis- Sodium, phytosterol Queensland nut oleate, 12~13 carbon alcohol lactates, cocoyl glucoside, silk sericin, dimerization season penta The mixture of tetrol pentaerythritol tetraisostearate and glyceryl oleate；The behenyl base trimethyl ammonium chloride, melon glue hydroxypropyl trimethylammonium Ammonium chloride, polyquaternium -7, Polyquaternium-10, panthenol, hydrolysis fibroin, hexadecyltrimethylammonium chloride, allantois Element, Etidronic Acid, EDETATE SODIUM, phytosterol Queensland nut oleate, 12~13 carbon alcohol lactates, cocoyl glucoside, The weight ratio of silk sericin, dipentaerythritol pentaerythritol tetraisostearate and glyceryl oleate is：Behenyl base trimethyl chlorine Change ammonium：Guar hydroxypropyltrimonium chloride：Polyquaternium -7：Polyquaternium-10：Panthenol：Hydrolyze fibroin：Hexadecane Base trimethyl ammonium chloride：Allantoin：Etidronic Acid：EDETATE SODIUM：Phytosterol Queensland nut oleate：12~13 carbon alcohol breast Acid esters：Cocoyl glucoside：Silk sericin：Dipentaerythritol pentaerythritol tetraisostearate：Glyceryl oleate=0.4：0.35： 1.5：0.11：1：0.8：0.5：0.3：0.1：0.1：0.5：0.5：1.8：1：0.5：2；

The desquamation compositions are piroctone olamine salt, hexamidine two (isethionic acid) salt, DM-846 and plant The mixture of anti-dandruff agent, the piroctone olamine salt, hexamidine two (isethionic acid) salt, DM-846 and plant anti-dandruff agent Weight ratio be：Piroctone olamine salt：Hexamidine two (isethionic acid) salt：DM-846：Plant anti-dandruff agent=0.1: 0.3:0.4:3；

The DM-846 is dichlorbenzyl alcohol, isostearoyl dilactic acid sodium, cocamidopropyl propyl amide pg dimonium chloride With the mixture of sodium lactate, the dichlorbenzyl alcohol, isostearoyl dilactic acid sodium, cocamidopropyl propyl amide PG- dimethylammonium chlorides The weight ratio of ammonium and sodium lactate is：Dichlorbenzyl alcohol：Isostearoyl dilactic acid sodium：Cocamidopropyl propyl amide PG- dimethyl chlorides Change ammonium：Sodium lactate=19：6：69：6；

The plant anti-dandruff agent is the mixture of glycyrrhetinic acid, saponin(e and azadirachta seed extract；The glycyrrhetinic acid, soap The weight ratio of glycosides and azadirachta seed extract is：Glycyrrhetinic acid：Saponin(e：Azadirachta seed extract=1:1:3；

Second preservative is the mixture of decoyl hydroximic acid, parahydroxyacet-ophenone, the sad fat of glycerine and butanediol； The pH adjusting agent is citric acid and sodium hydroxide.

Preparation method of the extra quality multiple-effect without silicone oil shampoo described in the present embodiment, includes preparation and the second material of the first material body The preparation of body；

The preparation of the first material body comprises the following steps：

(1), laureth sodium sulfovinate and laruyl alcohol sodium sulfovinate are added in 80~85 DEG C of deionized water, homogeneous Uniformly, it is incubated 30min；

(2), the mixture after step (1) homogeneous is cooled, 40~45 DEG C are cooled to, the first preservative is added, increases Thick dose and essence, stir, and adjust pH to 6.0-6.5, and regulation viscosity produces the first material to inner quality standard 10000~12000 Body；

The preparation of the second material body comprises the following steps：

(a), by coconut oleoyl amine sodium taurocholate, coconut oleoyl amine DEA, coconut oleoyl amine MEA, behenyl base trimethyl ammonium chloride, poly- Quaternary ammonium salt -10 (scattered with 10 times of cold pure water), guar hydroxypropyltrimonium chloride (10 times of cold pure water are scattered), 16 Alkyl trimethyl ammonium chloride and allantoin are added in 80~85 DEG C of deionized water, are well mixed, are obtained component A；

(b) component A, is cooled to 40~45 DEG C, Cocoamidopropyl betaine, imidazoline, cocoyl are added thereto Glucoside, polyquaternium -7, Etidronic Acid, EDETATE SODIUM, phytosterol Queensland nut oleate, 12~13 carbon alcohol lactic acid Ester, dipentaerythritol pentaerythritol tetraisostearate and glyceryl oleate, are well mixed, obtain component B；

(c) component B, is cooled to less than 42 DEG C, hydrolysis fibroin, silk sericin are added thereto, panthenol, is gone Consider composition, the second preservative and Cocoamidopropyl betaine to be worth doing, be well mixed, adjust pH to 6.0-6.5, regulation viscosity is to interior Control standard 10000~12000, produces the second material body.

Embodiment 2

The first material body includes the preparing raw material of following weight percentage：First surface activating agent 15%, first is prevented Rotten agent 0.3%, essence 0.6%, the deionized water of pH adjusting agent 0.3% and surplus；

Wherein, first surface activating agent is the mixture of laureth sodium sulfovinate and laruyl alcohol sodium sulfovinate, described Laureth sodium sulfovinate and the weight ratio of laruyl alcohol sodium sulfovinate are：Laureth sodium sulfovinate：Laruyl alcohol sulfuric acid Ester sodium=13：2；

The second material body includes the preparing raw material of following weight percentage：Second surface activating agent 8%, hair conditioning Agent 20.1%, the preservative 0.2% of desquamation compositions 0.66% and second, the deionized water of pH adjusting agent 0.2% and surplus；

Wherein, the second surface activating agent be Cocoamidopropyl betaine, imidazoline, coconut oleoyl amine sodium taurocholate, Coconut oleoyl amine DEA and coconut oleoyl amine MEA mixture, the Cocoamidopropyl betaine, imidazoline, coconut oleoyl amine taurine The weight ratio of sodium, coconut oleoyl amine DEA and coconut oleoyl amine MEA is：Cocoamidopropyl betaine：Imidazoline：Coconut oleoyl amine ox Sodium sulfonate：Coconut oleoyl amine DEA：Coconut oleoyl amine MEA=5：1：1：0.5：0.5；

The hair conditioner be behenyl base trimethyl ammonium chloride, guar hydroxypropyltrimonium chloride, polyquaternium- 7th, Polyquaternium-10, panthenol, hydrolysis fibroin, hexadecyltrimethylammonium chloride, allantoin, Etidronic Acid, EDTA bis- Sodium, phytosterol Queensland nut oleate, 12~13 carbon alcohol lactates, cocoyl glucoside, silk sericin, dimerization season penta The mixture of tetrol pentaerythritol tetraisostearate and glyceryl oleate；The behenyl base trimethyl ammonium chloride, melon glue hydroxypropyl trimethylammonium Ammonium chloride, polyquaternium -7, Polyquaternium-10, panthenol, hydrolysis fibroin, hexadecyltrimethylammonium chloride, allantois Element, Etidronic Acid, EDETATE SODIUM, phytosterol Queensland nut oleate, 12~13 carbon alcohol lactates, cocoyl glucoside, The weight ratio of silk sericin, dipentaerythritol pentaerythritol tetraisostearate and glyceryl oleate is：Behenyl base trimethyl chlorine Change ammonium：Guar hydroxypropyltrimonium chloride：Polyquaternium -7：Polyquaternium-10：Panthenol：Hydrolyze fibroin：Hexadecane Base trimethyl ammonium chloride：Allantoin：Etidronic Acid：EDETATE SODIUM：Phytosterol Queensland nut oleate：12~13 carbon alcohol breast Acid esters：Cocoyl glucoside：Silk sericin：Dipentaerythritol pentaerythritol tetraisostearate：Glyceryl oleate=0.8：0.6： 5：0.3：1.5：1.5：1.5：0.5：0.15：0.15：0.8：0.8：2：1.2：0.8：2.5；

The desquamation compositions are piroctone olamine salt, hexamidine two (isethionic acid) salt, DM-846 and plant The mixture of anti-dandruff agent, the piroctone olamine salt, hexamidine two (isethionic acid) salt, DM-846 and plant anti-dandruff agent Weight ratio be：Piroctone olamine salt：Hexamidine two (isethionic acid) salt：DM-846：Plant anti-dandruff agent=0.01: 0.05:0.1:0.5；

The DM-846 is dichlorbenzyl alcohol, isostearoyl dilactic acid sodium, cocamidopropyl propyl amide pg dimonium chloride With the mixture of sodium lactate, the dichlorbenzyl alcohol, isostearoyl dilactic acid sodium, cocamidopropyl propyl amide PG- dimethylammonium chlorides The weight ratio of ammonium and sodium lactate is：Dichlorbenzyl alcohol：Isostearoyl dilactic acid sodium：Cocamidopropyl propyl amide PG- dimethyl chlorides Change ammonium：Sodium lactate=20：7：70：7；

The plant anti-dandruff agent is the mixture of glycyrrhetinic acid, saponin(e and azadirachta seed extract；The glycyrrhetinic acid, soap The weight ratio of glycosides and azadirachta seed extract is：Glycyrrhetinic acid：Saponin(e：Azadirachta seed extract=1:1:9；

Preparation method of the extra quality multiple-effect without silicone oil shampoo is same as Example 1 described in the present embodiment.

Embodiment 3

The first material body includes the preparing raw material of following weight percentage：First surface activating agent 24%, first is prevented Rotten agent 0.8%, essence 0.6%, the deionized water of pH adjusting agent 0.2% and surplus；

Wherein, first surface activating agent is the mixture of laureth sodium sulfovinate and laruyl alcohol sodium sulfovinate, described Laureth sodium sulfovinate and the weight ratio of laruyl alcohol sodium sulfovinate are：Laureth sodium sulfovinate：Laruyl alcohol sulfuric acid Ester sodium=18：6；

The second material body includes the preparing raw material of following weight percentage：Second surface activating agent 27%, hair are adjusted Manage the deionized water of agent 4.95%, the preservative 1% of desquamation compositions 6.4% and second, pH adjusting agent 0.1% and surplus；

Wherein, the second surface activating agent be Cocoamidopropyl betaine, imidazoline, coconut oleoyl amine sodium taurocholate, Coconut oleoyl amine DEA and coconut oleoyl amine MEA mixture, the Cocoamidopropyl betaine, imidazoline, coconut oleoyl amine taurine The weight ratio of sodium, coconut oleoyl amine DEA and coconut oleoyl amine MEA is：Cocoamidopropyl betaine：Imidazoline：Coconut oleoyl amine ox Sodium sulfonate：Coconut oleoyl amine DEA：Coconut oleoyl amine MEA=10：10：3：1.5：2.5；

The hair conditioner be behenyl base trimethyl ammonium chloride, guar hydroxypropyltrimonium chloride, polyquaternium- 7th, Polyquaternium-10, panthenol, hydrolysis fibroin, hexadecyltrimethylammonium chloride, allantoin, Etidronic Acid, EDTA bis- Sodium, phytosterol Queensland nut oleate, 12~13 carbon alcohol lactates, cocoyl glucoside, silk sericin, dimerization season penta The mixture of tetrol pentaerythritol tetraisostearate and glyceryl oleate；The behenyl base trimethyl ammonium chloride, melon glue hydroxypropyl trimethylammonium Ammonium chloride, polyquaternium -7, Polyquaternium-10, panthenol, hydrolysis fibroin, hexadecyltrimethylammonium chloride, allantois Element, Etidronic Acid, EDETATE SODIUM, phytosterol Queensland nut oleate, 12~13 carbon alcohol lactates, cocoyl glucoside, The weight ratio of silk sericin, dipentaerythritol pentaerythritol tetraisostearate and glyceryl oleate is：Behenyl base trimethyl chlorine Change ammonium：Guar hydroxypropyltrimonium chloride：Polyquaternium -7：Polyquaternium-10：Panthenol：Hydrolyze fibroin：Hexadecane Base trimethyl ammonium chloride：Allantoin：Etidronic Acid：EDETATE SODIUM：Phytosterol Queensland nut oleate：12~13 carbon alcohol breast Acid esters：Cocoyl glucoside：Silk sericin：Dipentaerythritol pentaerythritol tetraisostearate：Glyceryl oleate=0.3：0.1： 1：0.05：0.5：0.5：0.5：0.1：0.05：0.05：0.2：0.2：0.2：0.2：0.2：0.8；

The desquamation compositions are piroctone olamine salt, hexamidine two (isethionic acid) salt, DM-846 and plant The mixture of anti-dandruff agent, the piroctone olamine salt, hexamidine two (isethionic acid) salt, DM-846 and plant anti-dandruff agent Weight ratio be：Piroctone olamine salt：Hexamidine two (isethionic acid) salt：DM-846：Plant anti-dandruff agent=0.3: 0.5:0.6:5；

The DM-846 is dichlorbenzyl alcohol, isostearoyl dilactic acid sodium, cocamidopropyl propyl amide pg dimonium chloride With the mixture of sodium lactate, the dichlorbenzyl alcohol, isostearoyl dilactic acid sodium, cocamidopropyl propyl amide PG- dimethylammonium chlorides The weight ratio of ammonium and sodium lactate is：Dichlorbenzyl alcohol：Isostearoyl dilactic acid sodium：Cocamidopropyl propyl amide PG- dimethyl chlorides Change ammonium：Sodium lactate=18：5：68：5；

The plant anti-dandruff agent is the mixture of glycyrrhetinic acid, saponin(e and azadirachta seed extract；The glycyrrhetinic acid, soap The weight ratio of glycosides and azadirachta seed extract is：Glycyrrhetinic acid：Saponin(e：Azadirachta seed extract=1:1:1；

Embodiment 4

The first material body includes the preparing raw material of following weight percentage：First surface activating agent 20%, first is prevented Rotten agent 0.5%, essence 0.6%, the deionized water of pH adjusting agent 0.1% and surplus；

Wherein, first surface activating agent is the mixture of laureth sodium sulfovinate and laruyl alcohol sodium sulfovinate, described Laureth sodium sulfovinate and the weight ratio of laruyl alcohol sodium sulfovinate are：Laureth sodium sulfovinate：Laruyl alcohol sulfuric acid Ester sodium=15：5；

The second material body includes the preparing raw material of following weight percentage：Second surface activating agent 16%, hair are adjusted Manage the deionized water of agent 13.7%, the preservative 0.8% of desquamation compositions 4% and second, pH adjusting agent 0.1% and surplus；

Wherein, the second surface activating agent be Cocoamidopropyl betaine, imidazoline, coconut oleoyl amine sodium taurocholate, Coconut oleoyl amine DEA and coconut oleoyl amine MEA mixture, the Cocoamidopropyl betaine, imidazoline, coconut oleoyl amine taurine The weight ratio of sodium, coconut oleoyl amine DEA and coconut oleoyl amine MEA is：Cocoamidopropyl betaine：Imidazoline：Coconut oleoyl amine ox Sodium sulfonate：Coconut oleoyl amine DEA：Coconut oleoyl amine MEA=6：6：1：1：2；

The hair conditioner be behenyl base trimethyl ammonium chloride, guar hydroxypropyltrimonium chloride, polyquaternium- 7th, Polyquaternium-10, panthenol, hydrolysis fibroin, hexadecyltrimethylammonium chloride, allantoin, Etidronic Acid, EDTA bis- Sodium, phytosterol Queensland nut oleate, 12~13 carbon alcohol lactates, cocoyl glucoside, silk sericin, dimerization season penta The mixture of tetrol pentaerythritol tetraisostearate and glyceryl oleate；The behenyl base trimethyl ammonium chloride, melon glue hydroxypropyl trimethylammonium Ammonium chloride, polyquaternium -7, Polyquaternium-10, panthenol, hydrolysis fibroin, hexadecyltrimethylammonium chloride, allantois Element, Etidronic Acid, EDETATE SODIUM, phytosterol Queensland nut oleate, 12~13 carbon alcohol lactates, cocoyl glucoside, The weight ratio of silk sericin, dipentaerythritol pentaerythritol tetraisostearate and glyceryl oleate is：Behenyl base trimethyl chlorine Change ammonium：Guar hydroxypropyltrimonium chloride：Polyquaternium -7：Polyquaternium-10：Panthenol：Hydrolyze fibroin：Hexadecane Base trimethyl ammonium chloride：Allantoin：Etidronic Acid：EDETATE SODIUM：Phytosterol Queensland nut oleate：12~13 carbon alcohol breast Acid esters：Cocoyl glucoside：Silk sericin：Dipentaerythritol pentaerythritol tetraisostearate：Glyceryl oleate=0.5：0.5： 2：0.1：1：1：1：0.4：1：1：0.6：0.6：1.2：0.8：0.5：1.5；

The desquamation compositions are piroctone olamine salt, hexamidine two (isethionic acid) salt, DM-846 and plant The mixture of anti-dandruff agent, the piroctone olamine salt, hexamidine two (isethionic acid) salt, DM-846 and plant anti-dandruff agent Weight ratio be：Piroctone olamine salt：Hexamidine two (isethionic acid) salt：DM-846：Plant anti-dandruff agent=0.2: 0.3:0.5:3；

The DM-846 is dichlorbenzyl alcohol, isostearoyl dilactic acid sodium, cocamidopropyl propyl amide pg dimonium chloride With the mixture of sodium lactate, the dichlorbenzyl alcohol, isostearoyl dilactic acid sodium, cocamidopropyl propyl amide PG- dimethylammonium chlorides The weight ratio of ammonium and sodium lactate is：Dichlorbenzyl alcohol：Isostearoyl dilactic acid sodium：Cocamidopropyl propyl amide PG- dimethyl chlorides Change ammonium：Sodium lactate=18：6：69：5；

Second preservative is the mixture of decoyl hydroximic acid, parahydroxyacet-ophenone, the sad fat of glycerine and butanediol； The pH adjusting agent is citric acid and sodium hydroxide..

Embodiment 5

Extra quality multiple-effect described in the present embodiment the difference is that only head in the second material body without silicone oil shampoo and embodiment 1 The difference of the addition of hexadecyltrimethylammonium chloride in conditioner is sent out, i.e., the second material body is comprising following described in the present embodiment The preparing raw material of weight percentage：Second surface activating agent 16.3%, hair conditioner 11.06%, desquamation compositions 3.8% With the deionized water of the second preservative 0.6%, pH adjusting agent 0.3% and surplus；

Wherein, the hair conditioner is behenyl base trimethyl ammonium chloride, guar hydroxypropyltrimonium chloride, poly- season Ammonium salt -7, Polyquaternium-10, panthenol, hydrolysis fibroin, hexadecyltrimethylammonium chloride, allantoin, Etidronic Acid, EDETATE SODIUM, phytosterol Queensland nut oleate, 12~13 carbon alcohol lactates, cocoyl glucoside, silk sericin, two The mixture of polypentaerythritol pentaerythritol tetraisostearate and glyceryl oleate；The behenyl base trimethyl ammonium chloride, melon glue hydroxypropyl Base trimethyl ammonium chloride, polyquaternium -7, Polyquaternium-10, panthenol, hydrolysis fibroin, hexadecyltrimethylammonium chloride, Allantoin, Etidronic Acid, EDETATE SODIUM, phytosterol Queensland nut oleate, 12~13 carbon alcohol lactates, cocoyl glucose Glycosides, silk sericin, the weight ratio of dipentaerythritol pentaerythritol tetraisostearate and glyceryl oleate are：Behenyl base trimethyl Ammonium chloride：Guar hydroxypropyltrimonium chloride：Polyquaternium -7：Polyquaternium-10：Panthenol：Hydrolyze fibroin：16 Alkyl trimethyl ammonium chloride：Allantoin：Etidronic Acid：EDETATE SODIUM：Phytosterol Queensland nut oleate：12~13 carbon alcohol Lactate：Cocoyl glucoside：Silk sericin：Dipentaerythritol pentaerythritol tetraisostearate：Glyceryl oleate=0.4： 0.35：1.5：0.11：1：0.8：0.1：0.3：0.1：0.1：0.5：0.5：1.8：1：0.5：2；

The second surface activating agent, desquamation compositions, the second preservative are same as Example 1；

Embodiment 6

The difference is that only in the second material body without silicone oil shampoo and embodiment 1 of extra quality multiple-effect described in the present embodiment Consider the difference of composition to be worth doing, i.e., the second material body includes the preparing raw material of following weight percentage described in the present embodiment：Second table Face activating agent 16.3%, hair conditioner 11.46%, the preservative 0.6% of desquamation compositions 3% and second, pH adjusting agent 0.3% With the deionized water of surplus；

The desquamation compositions are only anti-dandruff agent containing plant, the plant anti-dandruff agent, second surface activating agent, hair conditioning Agent, the second preservative are same as Example 1.

Embodiment 7

The difference is that only in the second material body without silicone oil shampoo and embodiment 1 of extra quality multiple-effect described in the present embodiment Consider the difference of composition to be worth doing, i.e., the second material body includes the preparing raw material of following weight percentage described in the present embodiment：Second table Face activating agent 16.3%, hair conditioner 11.46%, the preservative 0.6% of desquamation compositions 3.1% and second, pH adjusting agent 0.3% and the deionized water of surplus；

The desquamation compositions are the mixture of piroctone olamine salt and plant anti-dandruff agent, the piroctone ethanol Amine salt and the weight ratio of plant anti-dandruff agent are：0.1:3；The plant anti-dandruff agent, second surface activating agent, hair conditioner, Second preservative is same as Example 1.

Embodiment 8

The difference is that only in the second material body without silicone oil shampoo and embodiment 1 of extra quality multiple-effect described in the present embodiment Consider the difference of composition to be worth doing, i.e., the second material body includes the preparing raw material of following weight percentage described in the present embodiment：Second table Face activating agent 16.3%, hair conditioner 11.46%, the preservative 0.6% of desquamation compositions 3.3% and second, pH adjusting agent 0.3% and the deionized water of surplus；

The desquamation compositions are (isethionic acid) salt of hexamidine two and the mixture of plant anti-dandruff agent, the hexamidine Two (isethionic acid) salt and the weight ratio of plant anti-dandruff agent are：0.3:3；The plant anti-dandruff agent, second surface activating agent, Hair conditioner, the second preservative are same as Example 1.

Embodiment 9

The difference is that only in the second material body without silicone oil shampoo and embodiment 1 of extra quality multiple-effect described in the present embodiment Consider the difference of composition to be worth doing, i.e., the second material body includes the preparing raw material of following weight percentage described in the present embodiment：Second table Face activating agent 16.3%, hair conditioner 11.46%, the preservative 0.6% of desquamation compositions 3.4% and second, pH adjusting agent 0.3% and the deionized water of surplus；

The desquamation compositions are DM-846 and the mixture of plant anti-dandruff agent, the DM-846 and plant anti-dandruff agent weight Amount the ratio between be：0.3:3；The plant anti-dandruff agent, DM-846, second surface activating agent, hair conditioner, the second preservative and reality Apply example 1 identical.

Embodiment 10

The desquamation compositions are piroctone olamine salt, (isethionic acid) salt of hexamidine two and plant anti-dandruff agent Mixture, the weight ratio of the piroctone olamine salt, (isethionic acid) salt of hexamidine two and plant anti-dandruff agent is：Pyrrole Roc ketone ethanolamine salt：Hexamidine two (isethionic acid) salt：Plant anti-dandruff agent=0.1:0.3:3；The plant anti-dandruff agent, Two surfactants, hair conditioner, the second preservative are same as Example 1.Extra quality multiple-effect is washed without silicone oil described in the present embodiment The preparation method become visible is same as Example 1.

Embodiment 11

The difference is that only in the second material body without silicone oil shampoo and embodiment 1 of extra quality multiple-effect described in the present embodiment Consider the difference of composition to be worth doing, i.e., the second material body includes the preparing raw material of following weight percentage described in the present embodiment：Second table Face activating agent 16.3%, hair conditioner 11.46%, the preservative 0.6% of desquamation compositions 3.5% and second, pH adjusting agent 0.3% and the deionized water of surplus；

The desquamation compositions are the mixture of piroctone olamine salt, DM-846 and plant anti-dandruff agent, pyrrole sieve The weight ratio of gram ketone ethanolamine salt, DM-846 and plant anti-dandruff agent is：Piroctone olamine salt：DM-846：Plant is anti-dandruff Agent=0.1:0.3:3；The plant anti-dandruff agent, DM-846, second surface activating agent, hair conditioner, the second preservative and reality Apply example 1 identical.

Embodiment 12

The difference is that only in the second material body without silicone oil shampoo and embodiment 1 of extra quality multiple-effect described in the present embodiment Consider the difference of composition to be worth doing, i.e., the second material body includes the preparing raw material of following weight percentage described in the present embodiment：Second table Face activating agent 16.3%, hair conditioner 11.46%, the preservative 0.6% of desquamation compositions 3.7% and second, pH adjusting agent 0.3% and the deionized water of surplus；

The desquamation compositions are the mixture of hexamidine two (isethionic acid) salt, DM-846 and plant anti-dandruff agent, institute The weight ratio for stating hexamidine two (isethionic acid) salt, DM-846 and plant anti-dandruff agent is：Hexamidine two (isethionic acid) Salt：DM-846：Plant anti-dandruff agent=0.3:0.4:3；The plant anti-dandruff agent, DM-846, second surface activating agent, hair conditioning Agent, the second preservative are same as Example 1.

Comparative example 1

Shampoo described in this comparative example is with difference of the extra quality multiple-effect without silicone oil shampoo described in embodiment 1：This is right Shampoo described in ratio is only the first material body in embodiment 1, without the second material body.

Comparative example 2

Shampoo described in this comparative example is with difference of the extra quality multiple-effect without silicone oil shampoo described in embodiment 1：This is right Shampoo described in ratio is only the second material body in embodiment 1, without the first material body.

Comparative example 3

Shampoo described in this comparative example the difference is that only that desquamation compositions are not in the second material body with embodiment 1 Together, i.e., the second material body includes the preparing raw material of following weight percentage described in the present embodiment：Second surface activating agent 16.3%th, hair conditioner 11.46%, the preservative 0.6% of desquamation compositions 0.1% and second, pH adjusting agent 0.3% and surplus Deionized water；

The desquamation compositions are piroctone olamine salt；The second surface activating agent, hair conditioner, second prevent Rotten agent is same as Example 1.

The preparation method of shampoo described in this comparative example is same as Example 1.

Comparative example 4

Shampoo described in this comparative example the difference is that only that desquamation compositions are not in the second material body with embodiment 1 Together, i.e., the second material body includes the preparing raw material of following weight percentage described in the present embodiment：Second surface activating agent 16.3%th, hair conditioner 11.46%, the preservative 0.6% of desquamation compositions 0.3% and second, pH adjusting agent 0.3% and surplus Deionized water；

The desquamation compositions are hexamidine two (isethionic acid) salt；The second surface activating agent, hair conditioner, Second preservative is same as Example 1.

Comparative example 5

Shampoo described in this comparative example the difference is that only that desquamation compositions are not in the second material body with embodiment 1 Together, i.e., the second material body includes the preparing raw material of following weight percentage described in the present embodiment：Second surface activating agent 16.3%th, hair conditioner 11.46%, the preservative 0.6% of desquamation compositions 0.4% and second, pH adjusting agent 0.3% and surplus Deionized water；

The desquamation compositions are DM-846；The DM-846, second surface activating agent, hair conditioner, the second anti-corrosion Agent is same as Example 1.

Comparative example 6

The desquamation compositions are the mixture of piroctone olamine salt and hexamidine two (isethionic acid) salt；It is described The weight ratio of piroctone olamine salt and hexamidine two (isethionic acid) salt is：Piroctone olamine salt：Hexamidine Two (isethionic acid) salt=0.1:0.3；The second surface activating agent, hair conditioner, the second preservative and the phase of embodiment 1 Together.

Comparative example 7

Shampoo described in this comparative example the difference is that only that desquamation compositions are not in the second material body with embodiment 1 Together, i.e., the second material body includes the preparing raw material of following weight percentage described in the present embodiment：Second surface activating agent 16.3%th, hair conditioner 11.46%, the preservative 0.6% of desquamation compositions 0.5% and second, pH adjusting agent 0.3% and surplus Deionized water；

The desquamation compositions are piroctone olamine salt and DM-846 mixture；The piroctone olamine salt Weight ratio with DM-846 is：Piroctone olamine salt：DM-846=0.1:0.4；The DM-846, second surface activity Agent, hair conditioner, the second preservative are same as Example 1.

Comparative example 8

Shampoo described in this comparative example the difference is that only that desquamation compositions are not in the second material body with embodiment 1 Together, i.e., the second material body includes the preparing raw material of following weight percentage described in the present embodiment：Second surface activating agent 16.3%th, hair conditioner 11.46%, the preservative 0.6% of desquamation compositions 0.7% and second, pH adjusting agent 0.3% and surplus Deionized water；

The desquamation compositions are (isethionic acid) salt of hexamidine two and DM-846 mixture；The pyrrole hexamidine two (isethionic acid) salt and DM-846 weight ratio is：Hexamidine two (isethionic acid) salt：DM-846=0.3:0.4；Institute State DM-846, second surface activating agent, hair conditioner, the second preservative same as Example 1.

Comparative example 9

The desquamation compositions are piroctone olamine salt, the mixture of hexamidine two (isethionic acid) salt；It is described Piroctone olamine salt, the weight ratio of hexamidine two (isethionic acid) salt are：Piroctone olamine salt：Hexamidine two (isethionic acid) salt=0.1:0.4；The second surface activating agent, hair conditioner, the second preservative and the phase of embodiment 1 Together.

Embodiment 13

Physico-chemical tests are carried out without silicone oil shampoo to the extra quality multiple-effect in described in embodiment 1~12, gained Testing index is such as Under：

1st, character is detected

Extra quality multiple-effect described in embodiment 1~12 is suitable without silicone oil shampoo viscosity, has good stability, fragrant fan People, silk profit is smooth, fine and smooth uniform light blue shampoo

2nd, pH value is detected

Extra quality multiple-effect described in embodiment 1~12 is sampled without silicone oil shampoo, determined with pH meter, measure pH value for 5.5~ 6.5。

3rd, viscosity number is detected

Extra quality multiple-effect described in embodiment 1~12 is sampled without silicone oil shampoo, is determined with viscosimeter, measures viscosity number 10000~12000.

4th, Detection of Stability

Extra quality multiple-effect described in embodiment 1~12 is sampled without silicone oil shampoo, is encapsulated in transparence cosmetic bottle, point Be not placed in quartz lamp illumination, -15 DEG C, 5 DEG C, 25 DEG C, under 48 DEG C of experiment conditions, to outward appearance, fragrance, pH value, viscosity and other Project carries out the continuance test of 3 months by a definite date, sees whether bleed, layering, separation, precipitation, discoloration, peculiar smell, demulsification etc. occur Bad phenomenon, testing result shows that the bad result of the above is not appeared in the test process of shampoo described in embodiment 1~7, Illustrate that it has good stability.

5th, centrifugation detection

Extra quality multiple-effect described in embodiment 1~12 is sampled without silicone oil shampoo, is encapsulated in centrifuge tube in 3000r/ 30min is centrifuged under min, sees whether not dispersion component occur, testing result shows that shampoo described in embodiment 1~7 is not There is not dispersion component, illustrate that its Combination is good.

6th, anaphylaxis is stimulated to detect

Extra quality multiple-effect described in embodiment 1~12 is sampled without silicone oil shampoo, it is applied to 300 age brackets in right amount is On 18-58 Sui volunteer's the back of the hand, 30min is observed, sees whether it the phenomenons such as redness, dermexanthesis, foaming occurs, result table is observed Bright, all volunteers do not occur above-mentioned ill symptomses in 30min, and illustrating that this product will not be produced to skin stimulates and anaphylaxis Problem.

7th, comprehensive using effect detection

Using opinion poll point system, by asking volunteer to try out the sample of embodiment 1~5 and comparative example 1,2 respectively, and Fill in table on probation and carry out overall merit its using effect.Every group of embodiment sample chooses the volunteer 50 in all ages and classes stage (age level is 18-38 volunteer 25 and the volunteer 25 of 38~58 age levels) is used as object on probation, every two days Hair washing is once, continuous to use three months, fills in table on probation after trying out and is scored.Every using effect total score is 5 in grade form Point：5 points are best results, are represented very satisfied；4 points are preferable, are relatively satisfied with；3 points are to receive；Less than 3 points is not Acceptable scope, every using effect average situation is as shown in table 1.

Shampoo items using effect average situation described in the embodiment 1~5 of table 1 and comparative example 1,2

Using effect	Cleannes	Anti-dandruff effect	A softer and smoother touch property	Moisturizing and nourishing	It is nonirritant
						Embodiment 1	4.99	4.98	4.95	4.92	5.00
Embodiment 2	4.92	4.95	4.89	4.87	5.00
						Embodiment 3	4.93	4.92	4.92	4.90	5.00
Embodiment 4	4.93	4.95	4.96	4.95	5.00
						Embodiment 5	4.94	4.98	4.83	4.88	5.00
Comparative example 1	4.85	3.90	2.84	2.98	5.00
						Comparative example 2	4.88	4.90	4.85	4.83	5.00

Test result as shown in table 1, as a result shows：Shampoo described in embodiment 1~5 and comparative example 1,2 shows as nothing Stimulate, cleannes are preferable, but compared with comparative example 1, the anti-dandruff effect of shampoo described in embodiment 1~5 and comparative example 2 is more Good, compared with comparative example 2, a softer and smoother touch and moisturizing of shampoo described in embodiment 1~5 is better, illustrates the present invention The extra quality multiple-effect has preferable anti-dandruff, a softer and smoother touch and moisturizing effect concurrently without silicone oil shampoo, and to scalp without The effect of stimulation.

Shampoo described in embodiment 1,6~12 and comparative example 3~9 is used into opinion poll point system, by asking volunteer The sample of embodiment 6~12 and comparative example 3~9 is tried out respectively, and fills in table on probation to evaluate the anti-dandruff effect of sample.Every group real Apply (the volunteer that age level is 18-38 25 and 38~58 years of volunteer 50 that a sample chooses all ages and classes stage The volunteer 25 of age grade section) object on probation is used as, hair washing in every two days is once, continuous to use three months, fills on probation after trying out Table is scored.Every using effect total score is 5 points in grade form：5 points are best results, are represented very satisfied；4 points be it is preferable, Relatively it is satisfied with；3 points are to receive；Less than 3 points are the scope that cannot receive, anti-dandruff effect average situation such as table Shown in 2.

The anti-dandruff effect of shampoo described in the embodiment 1,6~12 of table 2 and comparative example 3~9

Only adopted from table 2 it can be seen that being substantially better than using the anti-dandruff effect of shampoo described in the embodiment 1 of four kinds of anti-dandruff agents With wherein three kinds, two kinds and a kind of anti-dandruff effect of shampoo, illustrate that each anti-dandruff agent mutually compatibility can be assisted in desquamation compositions With synergy to reach preferable anti-dandruff effect.

Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than the present invention is protected The limitation of scope is protected, although being explained in detail with reference to preferred embodiment to the present invention, one of ordinary skill in the art should Understand, technical scheme can be modified or equivalent substitution, without departing from the essence of technical solution of the present invention And scope.

Claims

1. a kind of desquamation compositions, it is characterised in that comprising piroctone olamine salt, hexamidine two (isethionic acid) salt, DM-846 and plant anti-dandruff agent；The DM-846 is dichlorbenzyl alcohol, isostearoyl dilactic acid sodium, cocamidopropyl propyl amide PG- The mixture of alkyl dimethyl ammonium chloride and sodium lactate；The plant anti-dandruff agent includes glycyrrhetinic acid, saponin(e and azadirachta seed extract.

2. desquamation compositions as claimed in claim 1, it is characterised in that the piroctone olamine salt, (the hydroxyl second of hexamidine two Base sulfonic acid) weight ratio of salt, DM-846 and plant anti-dandruff agent is：Piroctone olamine salt：(the ethoxy sulphur of hexamidine two Acid) salt：DM-846：Plant anti-dandruff agent=0.01~0.3:0.05~0.5:0.1~0.6:0.5~5.

3. desquamation compositions as claimed in claim 1, it is characterised in that the glycyrrhetinic acid, saponin(e and azadirachta seed extract Weight ratio be：Glycyrrhetinic acid：Saponin(e：Azadirachta seed extract=1~3:1~3:3~9；Preferably, the glycyrrhetin Acid, the weight ratio of saponin(e and azadirachta seed extract are：Glycyrrhetinic acid：Saponin(e：Azadirachta seed extract=1:1:3.

4. desquamation compositions as claimed in claim 1, it is characterised in that the dichlorbenzyl alcohol, isostearoyl dilactic acid sodium, The weight ratio of cocamidopropyl propyl amide pg dimonium chloride and sodium lactate is：Dichlorbenzyl alcohol：Isostearoyl dilactic acid Sodium：Cocamidopropyl propyl amide pg dimonium chloride：Sodium lactate=18~20：5~7：68~70：5~7.

5. a kind of extra quality multiple-effect is without silicone oil shampoo, it is characterised in that comprising anti-dandruff group any one of Claims 1 to 5 Compound.

6. extra quality multiple-effect as claimed in claim 5 is without silicone oil shampoo, it is characterised in that the extra quality multiple-effect is without silicone oil shampoo Including the first material body and the second material body；

The first material body includes the preparing raw material of following weight percentage：First surface activating agent 15~24% and first is prevented Rotten agent 0.3~0.8%；

The second material body includes the preparing raw material of following weight percentage：Second surface activating agent 8~27%, hair conditioning Agent 4.95~20.1%, the preservative 0.2~1% of desquamation compositions 0.66~6.4% and second.

7. extra quality multiple-effect as claimed in claim 6 is without silicone oil shampoo, it is characterised in that the first surface activating agent for it is cloudy from Sub- surfactant；The second surface activating agent is nonionic surfactant and/or amphoteric surfactant.

8. extra quality multiple-effect is without silicone oil shampoo described in claim 6, it is characterised in that the first surface activating agent includes bay Alcohol polyethers sodium sulfovinate and laruyl alcohol sodium sulfovinate；The weight of the laureth sodium sulfovinate and laruyl alcohol sodium sulfovinate it Than for：Laureth sodium sulfovinate：Laruyl alcohol sodium sulfovinate=13~18：2~6；The second surface activating agent includes coconut palm Oleamide CAB, imidazoline, coconut oleoyl amine sodium taurocholate, coconut oleoyl amine DEA and coconut oleoyl amine MEA, the cocounut oil acyl Amine CAB, imidazoline, coconut oleoyl amine sodium taurocholate, coconut oleoyl amine DEA and coconut oleoyl amine MEA weight ratio are：Coconut palm Oleamide CAB：Imidazoline：Coconut oleoyl amine sodium taurocholate：Coconut oleoyl amine DEA：Coconut oleoyl amine MEA=5~10：1~ 10：1~3：0.5~1.5：0.5~2.5.

9. extra quality multiple-effect as claimed in claim 6 is without silicone oil shampoo, it is characterised in that the hair conditioner includes behenyl base Trimethyl ammonium chloride, guar hydroxypropyltrimonium chloride, polyquaternium -7, Polyquaternium-10, panthenol, hydrolysis silk egg In vain, hexadecyltrimethylammonium chloride, allantoin, Etidronic Acid, EDETATE SODIUM, phytosterol Queensland nut oleate, 12 ~13 carbon alcohol lactates, cocoyl glucoside, silk sericin, dipentaerythritol pentaerythritol tetraisostearate and glyceryl oleate At least one of；Preferably, the hair conditioner includes behenyl base trimethyl ammonium chloride, melon glue Hydroxyproyl Trimethyl chlorine Change ammonium, polyquaternium -7, Polyquaternium-10, panthenol, hydrolysis fibroin, hexadecyltrimethylammonium chloride, allantoin, hydroxyl Second diphosphonic acid, EDETATE SODIUM, phytosterol Queensland nut oleate, 12~13 carbon alcohol lactates, cocoyl glucoside, silk silk Glue protein, dipentaerythritol pentaerythritol tetraisostearate and glyceryl oleate；The behenyl base trimethyl ammonium chloride, melon glue hydroxypropyl Base trimethyl ammonium chloride, polyquaternium -7, Polyquaternium-10, panthenol, hydrolysis fibroin, hexadecyltrimethylammonium chloride, Allantoin, Etidronic Acid, EDETATE SODIUM, phytosterol Queensland nut oleate, 12~13 carbon alcohol lactates, cocoyl glucose Glycosides, silk sericin, the weight ratio of dipentaerythritol pentaerythritol tetraisostearate and glyceryl oleate are：Behenyl base trimethyl Ammonium chloride：Guar hydroxypropyltrimonium chloride：Polyquaternium -7：Polyquaternium-10：Panthenol：Hydrolyze fibroin：16 Alkyl trimethyl ammonium chloride：Allantoin：Etidronic Acid：EDETATE SODIUM：Phytosterol Queensland nut oleate：12~13 carbon alcohol Lactate：Cocoyl glucoside：Silk sericin：Dipentaerythritol pentaerythritol tetraisostearate：Glyceryl oleate=0.3~ 0.8：0.1~0.6：1~5：0.05~0.3：0.5~1.5：0.5~1.5：0.5~1.5：0.1~0.5：0.05~0.15： 0.05~0.15：0.2~0.8：0.2~0.8：0.2~2：0.2~1.2：0.2~0.8：0.8~2.5.

10. extra quality multiple-effect as claimed in claim 6 is without silicone oil shampoo, it is characterised in that first preservative and second is prevented Rotten agent is the mixture of decoyl hydroximic acid, parahydroxyacet-ophenone, the sad fat of glycerine and butanediol.