CN107468563A

CN107468563A - A kind of anti-dandruff silk quality lubrication is without silicone oil shampoo

Info

Publication number: CN107468563A
Application number: CN201710678186.XA
Authority: CN
Inventors: 曾万祥; 覃敢为; 陈海; 黄娜; 曾嘉
Original assignee: Individual
Current assignee: Individual
Priority date: 2017-08-09
Filing date: 2017-08-09
Publication date: 2017-12-15

Abstract

Anti-dandruff and itching-relieving agent is included without silicone oil shampoo, the preparing raw material of the shampoo the invention discloses a kind of anti-dandruff silk quality lubrication, weight percentage of the anti-dandruff and itching-relieving agent in preparing raw material is 0.2~3%；The anti-dandruff and itching-relieving agent includes plant anti-dandruff agent；The plant anti-dandruff agent includes glycyrrhetinic acid, saponin(e and azadirachta seed extract.Anti-dandruff silk quality lubrication of the present invention uses anti-dandruff significant effect without silicone oil shampoo, and non-stimulated to scalp, has the anti-dandruff and itching-relieving agent of multiple anti-dandruff effect；Traditional silicone oil is substituted using fat agent is assigned, with the use of raw materials such as non-stimulated preservative, hair conditioner, surfactants, reaches the overall mildness for improving shampoo, reduces excitant of the cleansing to scalp.While shampoo of the present invention has good anti-dandruff effect, and can effectively cleaning and nourishing hair and scalp, make hair salubrious elegant submissive, be not in after hair washing scalp it is difficult ventilative, greasy thick and heavy phenomenon.

Description

A kind of anti-dandruff silk quality lubrication is without silicone oil shampoo

Technical field

The present invention relates to a kind of hair shampoo article, and in particular to a kind of anti-dandruff silk quality lubrication is without silicone oil shampoo.

Background technology

Hair shampoo article has become the necessity in mankind's daily life, commonly used to clean scalp and conditioning hair.Product Good shampoo of fine quality can effectively clean the dirt grease adhered on scalp and hair, meanwhile, also to the nutrition needed for scalp and Protection, come to hair carry soft, smooth and glossy.But with the progress in epoch, environmental pollution getting worse, people's rhythm of life Also gradually accelerate, daily life system pressure also changes therewith, can not only influence human body endocrine circulation itself, again result in people's body surface The hair of skin is also influenceed accordingly.The species of shampoo is although various in the market, but generally can not all reach deep The effect of level cleaning, but also easily cause the generation of some side effects such as scalp itch and dry hair tarnish.It is strong The scalp ecological environment of health is maintained by the balance of finance, credits and materials：Grease, flora, metabolic balance.When scalp fat secretion is unbalance, scalp is just Easily fuel-displaced it can become greasy thick and heavy；When scalp flora environment is unbalance, bacterium will largely grow, and scalp just occurs that head is itched Hard to bear phenomenon；When scalp metabolic imbalance, stratum corneum is too fast, causes the too fast formation dandruff that comes off.These three balances Once unbalance can all trigger various scalp problems, as more than alopecia, dandruff and head is itched the problems such as hard to bear.But with living standards of the people Raising, consumption concept and health perception gradually strengthen, and to the quality requirement of shampoo also more and more higher, hair and scalp are entered The profound shampoo for cleaning and can reaching reparation nourishing hair simultaneously of row is badly in need of exploitation.

The immediate cause of dandruff is inflammation caused by stimulating.Work as stimulus, for example, the metabolin of fungi, comb it is improper, Take care of hair it is improper Skin Cell can then accelerate hyperplasia, cause dead skin to come off when causing inflammation, that is, our so-called dandruffs. In many cases, the principal element or chlosma amount of dandruff are uneven.It is treatment head to suppress scalp chlosma amount The key of scurf.But anti-dandruff type shampoo is mostly using a kind of or two kinds of anti-dandruff agents, or be known as anti-dandruff with plant currently on the market Composition, undesirable to eliminating chlosma effect, anti-dandruff effect is poor, particularly the more oily hair of dandruff, it is more difficult to reaches To anti-dandruff；Moreover, when using using ZPT as anti-dandruff agent, mostly using single card ripple class thickening suspending agent, cause production Quality stability of the product in selling period.Shampoo above can not meet the composite request of modern people.

In order that hair is submissive in traditional shampoo, add the highly viscous silicon compound of some HMWs serve as it is smooth Agent, they can be adsorbed in each hair surface, form very smooth film.The silicon compound commonly used at present in shampoo has poly- Dimethyl siloxane, amido silicon oil, cyclomethicone etc., in hair-washing hair-care, these silicon-containing compounds can be between hair scale piece Gap fill up, people can be allowed to think that hair sense of touch is very smooth, but because silicone oil has characteristic not soluble in water, be wrapped in head Silicon on hair and scalp is less susceptible to be cleaned, and enrichment so year in year out, silicone oil can adsorb the meeting on hair Cause that hair is thicker, hair weight becomes weight, reduce the electrostatic interaction of hair, hair gradually lost elasticity, produced disconnected hair, scalp Clogging of pores, cause scalp oxygen flow insufficient, papilla may gradual atrophy, scalp just start to occur it is withered and yellow, itch, or even alopecia Phenomenon, and long-term use of siliceous oils product can be covered by silicone oil because of hair, and the real nutrition subsequently nursed cannot be introduced into And hair quality is set to be deteriorated.In addition these organosilicons are not only not soluble in water but also do not dissolve in any surfactant, and environment is discharged into after hair washing It is difficult to it is biodegradable, easily cause environmental pollution.

In addition, the use of preservative is extremely common in washing product, but traditional preservatives have certain toxicity, use Amount is restricted, and does not reach preferable antiseptic effect.Excessive or inappropriate preservative can even make epidermal cell development not into It is ripe, it is loosely organized, so that epidermis is thinning, is easily declined by environmental stimuli, phylactic power defensive power, make skin follow the string gradually, easily production Raw relaxation, microgroove, and constantly defect can then be bred by the Skin Cell of preservative infringement, make skin quality worse and worse.It is so traditional Preservative uses harm so that existing washing product is badly in need of finding natural antiseptic agent or seted out to no added preservative direction.

Such as application number 201410299750.3 discloses a kind of antidandruff and antipruritic shampoo, the shampoo of the invention is by shampoo Matrix and extracts of Chinese herbal medicine are made, wherein, extracts of Chinese herbal medicine is by shrubalthea leaf 30-45%, tea seed cake 20-30%, coptis 10- 15%th, extract and be made after radix scutellariae 10-15%, root bark of white mulberry 5-10%, balsamine 5-10% are mixed by weight percentage.In this application Although what is used is all crude drug component, extra anti-dandruff agent is not used in formula, although various Chinese herb medicines Component is no added safely, but individually plant extracts can not but reach the profound anti-dandruff effect of sterilization, and anti-dandruff effect Fruit slowly effect；Except having used a variety of silicone oil components there is no some other nourishing component in hair conditioner in formula, although washing Touch up can be very submissive for hair afterwards, and people can be allowed to think that hair sense of touch is very smooth, but silicone oil is not soluble in water, be wrapped in hair and Silicon on scalp is less susceptible to be cleaned, and enrichment so year in year out, silicone oil can adsorb can cause on hair Hair is thicker, weight becomes weight, hair is gradually lost elasticity, produces disconnected hair, scalp clogging of pores, causes scalp oxygen flow insufficient, Papilla may gradual atrophy, scalp just start to occur it is withered and yellow, itch, or even the phenomenon of alopecia；Surfactant in formula All it is relatively common, due to being mixed, therefore some characteristic components can not be added；The preservative used is Metagin Ester and ethylparaben, it is relatively common preservative, but is connect studies have reported that them are excessively used in cosmetics and can cause Touch property dermatitis.Also studies have reported that nipagin esters can be accumulated in human body, increase the risk that women suffers from breast cancer with uterine cancer, The residual for there are a large amount of nipagin esters is found in the pathological section of a large amount of patient with breast cancers.

The content of the invention

A kind of anti-dandruff silk quality lubrication is provided without silicon it is an object of the invention to overcome the shortcomings of the prior art part Oil wash floods.

To achieve the above object, the technical scheme taken of the present invention is：A kind of anti-dandruff silk quality lubrication is without silicone oil shampoo, institute The preparing raw material for stating shampoo includes anti-dandruff and itching-relieving agent, and weight percentage of the anti-dandruff and itching-relieving agent in preparing raw material is 0.2~3%；The anti-dandruff and itching-relieving agent includes plant anti-dandruff agent；The plant anti-dandruff agent includes glycyrrhetinic acid, saponin(e and azadirachta Seed extract.

Enoxolone is classical anti-inflammatory drug, has anti-inflammatory antiallergy, suppresses the effect such as bacterial reproduction.Adjustable skin Immunologic function, strengthen the resistance against diseases of skin, diminish inflammation, pre- hypo-allergenic, cleaning skin, cosmetics and other outer can be released Toxic side effect of boundary's factor to skin.Saponin(e, there is the active or antipyretic, calm, antitumor of antibacterial, anti-inflammatory, immunological regulation, anti- The valuable bioactivity such as viral, antimycotic, liver-protecting activity.Azadirachta seed extract possess sterilization and antiviral characteristic and The effect of desinsection, sterilizing.Anti-dandruff silk quality lubrication of the present invention has preferable without above-mentioned three kinds of materials are added in silicone oil shampoo Bactericidal action, and plant extracts is non-stimulated to scalp, and three plays a role the effect for reaching anti-dandruff jointly.Anti-dandruff effect with The increase of anti-dandruff and itching-relieving agent addition and increase, but work as addition of the anti-dandruff and itching-relieving agent in the preparing raw material of the shampoo More than for 3% when, be further added by the amount of anti-dandruff and itching-relieving agent, anti-dandruff effect increase is not notable, therefore when anti-dandruff and itching-relieving agent is washed described When weight percentage in the preparing raw material of shampoo is 0.2~3%, anti-dandruff effect could be preferably played.

Preferably, the weight ratio of the glycyrrhetinic acid, saponin(e and azadirachta seed extract is：Glycyrrhetinic acid：Saponin(e：Print Spend chinaberry seed extract=1~3:1~3:3~9.

When glycyrrhetinic acid, saponin(e and azadirachta seed extract use above-mentioned ratio, the collaboration of three can be preferably played Synergistic effect, so as to reach preferable anti-dandruff effect.

It is highly preferred that the weight ratio of the glycyrrhetinic acid, saponin(e and azadirachta seed extract is：Glycyrrhetinic acid：Saponin(e： Azadirachta seed extract=1:1:3.

When glycyrrhetinic acid, saponin(e and azadirachta seed extract use above-mentioned ratio, the anti-dandruff best results that reach.

Water is also included in the plant anti-dandruff agent, water is 40~60% in the weight percentage of plant anti-dandruff agent.

Preferably, the anti-dandruff and itching-relieving agent also includes (isethionic acid) salt of hexamidine two and piroctone olamine salt； The weight ratio of the plant anti-dandruff agent, (isethionic acid) salt of hexamidine two and piroctone olamine salt is：Plant is anti-dandruff Agent：Hexamidine two (isethionic acid) salt：Piroctone olamine salt=0.1~2：0.01~0.1：0.05~0.3.

Piroctone olamine salt, anti-dandruff agent OCTO is also, it is famous because of its bacteriostasis, it can particularly suppress ovale malaria Protozoon, it is parasitized in the scurf of dandruff, face etc..The material is a kind of efficient, nontoxic non-stimulated anti-dandruff agent, can be extensive Anti-dandruff shampoo, hair-nourishing liquid and hair conditioner etc. is used in wash in shield class cosmetics.OCTO anti-dandruff and itching-relieving mechanism be by sterilization and Antioxidation fundamentally blocks outside channel caused by dandruff, so as to effectively effect a radical cure dandruff, stopping head itching, rather than by de- The modes such as fat temporarily eliminate dandruff from presentation.One of the reason for being better than like product here it is OCTO anti-dandruff and itching-relievings performance.Should Material is identified very reliable to the security of eyes, skin through external authoritative institution.Definitely non-toxic, excitant and sensitization. In actual use will not damaged scalp, be not in alopecia, disconnected hair.

Hexamidine two (isethionic acid) salt (Pf-95) it is a kind of new water-soluble cationic dandruff-removing itching-relieve Agent, there is broad-spectrum antiseptic and bactericidal property, have to various gram-positive bacterias and negative bacterium and various yeast and molds Very high sterilization and bacteriostasis property, especially to the pityrosporum ovale for causing dandruff, because its unique structure is with very strong Killing action, and to causing the propionibacterium acnes of acne to have very strong suppression and sterilization effect.And very safety is warm With, it is small to skin irritation, it is excellent with the compatibility of conventional raw material in daily chemical products.Especially because its cationic is produced to hair Raw suction-operated, it is more beneficial for the reinforcement of its anti-dandruff effect and persistently plays, this is the characteristic that other anti-dandruff agents do not possess.

Shampoo of the present invention matches use using above-mentioned three kinds of different types of anti-dandruff agents are compound, can highlight multiple Anti-dandruff effect, mutual Synergistic, also there is preferable moisture-keeping efficacy while to scalp bactericidal, to scalp without Stimulate, anti-dandruff effect is lasting.Three kinds of anti-dandruff agents use anti-dandruff best results during aforementioned proportion compounding use.

Preferably, the preparing raw material of the shampoo also includes hair conditioner；The hair conditioner is in preparing raw material In weight percentage be 0.3~5%；The hair conditioner includes silk sericin, hydrolyzed wheat protein PG- propyl group At least one of silantriol and Polyquaternium-10.

Silk sericin, is the natural polymer fibrin extracted from silk, content account for silk 70~ 80%, containing 18 kinds of amino acid, there is preferable affinity interaction to hair, protectiveness transparent membrane can be formed in hair surface, prevented Only injury of the thioglycolate salt to hair, the various nutrients needed for hair are supplemented, improve the gloss and elasticity of hair, can be effective Hair damage is prevented, makes hair distribute the gloss of ripples and the slim and graceful softness such as tiffany.Meanwhile silk sericin is to impaired Hair has obvious repairing effect.And then containing abundant cystine inside hydrolyzed wheat protein, it can be with being covered in head Cuticula protein on skin and with because impaired and exposed cortex interacts, repairing impaired epidermis, can effectively be prevented Alopecia hair loss.Shampoo of the present invention uses silk sericin, hydrolyzed wheat protein PG propyl silanes triol and polyquaternary amine Salt -10 is used as hair conditioner, can make the shampoo while with outstanding anti-dandruff effect, moreover it is possible to take good care of nursing head Hair, make hair submissive moist.

It is highly preferred that the hair conditioner include silk sericin, hydrolyzed wheat protein PG- propyl silanes triol and Polyquaternium-10；The weight of the silk sericin, hydrolyzed wheat protein PG- propyl silanes triol and Polyquaternium-10 it Than for：Silk sericin：Hydrolyzed wheat protein PG- propyl silane triols：Polyquaternium-10=0.1~3：0.1~0.5： 0.05~0.5.

When the hair conditioner uses said ratio, it can make shampoo that not only there is preferable anti-dandruff effect, moreover it is possible to repair Multiple disconnected hair, fork hair, improve hair quality, nourish scalp and moist hair.

Preferably, the preparing raw material of the shampoo also includes surfactant, and the surfactant is in preparing raw material In weight percentage be 18~45%；The surfactant includes laureth sodium sulfovinate, bay alcohol sulfuric ester At least one of ammonium, sodium methyl cocoyl taurate, Cocoamidopropyl betaine and coconut oleoyl amine DEA.

Surfactant used in the present invention is relatively mild surfactant, to hair and scalp cleannes compared with It is good, moreover it is possible to mitigate stimulation of the shampoo to scalp to a certain extent, reduce and hair is injured.

It is highly preferred that the surfactant includes laureth sodium sulfovinate, bay alcohol sulfuric ester ammonium and methyl coconut palm Oleoyl taurate；The laureth sodium sulfovinate, bay alcohol sulfuric ester ammonium and sodium methyl cocoyl taurate Weight ratio is：Laureth sodium sulfovinate：Bay alcohol sulfuric ester ammonium：Sodium methyl cocoyl taurate=10~25:3~ 6:0.5~1.

Three kinds of laureth sodium sulfovinate, bay alcohol sulfuric ester ammonium and sodium methyl cocoyl taurate surfactants It is used cooperatively by said ratio, can effectively cleans hair and scalp, submissive hair.

More preferably, the laureth sodium sulfovinate, bay alcohol sulfuric ester ammonium and sodium methyl cocoyl taurate Weight ratio be：Laureth sodium sulfovinate：Bay alcohol sulfuric ester ammonium：Sodium methyl cocoyl taurate=20:5:1.

When laureth sodium sulfovinate, bay alcohol sulfuric ester ammonium and sodium methyl cocoyl taurate use aforementioned proportion Collocation is in use, make shampoo of the present invention high bubble can not only be presented when in use but also can be with the property of smooth, soft hair Matter, and the formation of dandruff and the infringement of correct scared cortex can be reduced, the damage caused by because of electrostatic of reduction hair, make After hair can be made to leave softness, easily felt, allow consumer to use comfortable.

Preferably, the surfactant includes laureth sodium sulfovinate, bay alcohol sulfuric ester ammonium, methyl cocoyl acyl Base sodium taurocholate, Cocoamidopropyl betaine and coconut oleoyl amine DEA；The laureth sodium sulfovinate, laruyl alcohol sulfuric acid Ester ammonium, sodium methyl cocoyl taurate, Cocoamidopropyl betaine and coconut oleoyl amine DEA weight ratio are：Laruyl alcohol Polyethers sodium sulfovinate：Bay alcohol sulfuric ester ammonium：Sodium methyl cocoyl taurate：Cocoamidopropyl betaine：Coconut oleoyl amine DEA=10~25:3~6:0.5~1：3~8:1~5.

When the surfactant uses the surfactant of said ratio, each component cooperates, foaming abundancy, correct The effect with deep layer cleaning of skin and hair.

Preferably, the preparing raw material of the shampoo is also comprising tax fat agent；The weight that fat agent is assigned in preparing raw material Percentage composition is 1.5~6%；The tax fat agent includes glyceryl oleate, C12-13 alcohol lactate, cholesterine Queensland nut oleic acid Ester, dipentaerythritol pentaerythritol tetraisostearate, the esters of olive oil PEG-6 polyglycereol -6, phosphatide and three-C12-13 alkanol citric acids At least one of ester.

Because traditional silicone oil is not dissolved in surfactant system, long-term use of easily absorption is on hair and is not easy clear Wash, hair is gradually lost elasticity for a long time, produce disconnected hair, scalp clogging of pores, cause scalp oxygen flow insufficient, papilla may be by Gradually atrophy, scalp just start to occur it is withered and yellow, itch, or even the phenomenon of alopecia.The present invention is from glyceryl oleate, C12-13 alcohol breast Acid esters, cholesterine Queensland nut oleate, dipentaerythritol pentaerythritol tetraisostearate, the esters of olive oil PEG-6 polyglycereol -6, phosphorus Fat and three-C12-13 alkanols citrates substitute traditional silicone oil as fat agent is assigned, their surfactant bodies in shampoo It is completely soluble in system, and the lubricant component in their structure and skin is all more approximate, therefore correct leatherware has very Good nourishing lubrication, hair can be made to wash rear salubrious submissive non-greasy, not have obvious heavy feeling, softening hair and increase head The gloss of hair.

It is highly preferred that the tax fat agent includes glyceryl oleate, C12-13 alcohol lactate, cholesterine Queensland nut oleic acid Ester, dipentaerythritol pentaerythritol tetraisostearate, the esters of olive oil PEG-6 polyglycereol -6, phosphatide and three-C12-13 alkanol citric acids Ester；The glyceryl oleate, C12-13 alcohol lactate, cholesterine Queensland nut oleate, the isostearic acid of dipentaerythritol four Ester, the esters of olive oil PEG-6 polyglycereol -6, the weight ratio of phosphatide and three-C12-13 alkanol citrates are：Glycerine oleic acid Ester：C12-13 alcohol lactates：Cholesterine Queensland nut oleate：Dipentaerythritol pentaerythritol tetraisostearate：Olive oil PEG-6 gathers The esters of glycerine -6：Phosphatide：Three-C12-13 alkanols citrate=1~3：0.1~1：0.05~0.5：0.05~0.5：0.05~ 0.3：0.05~0.1：0.05~0.3.

Drawn through inventor's test of many times, when tax fat agent of the invention uses said ratio, to the submissive and scalp of hair Nourishes effect it is preferable.

Preferably, the shampoo also includes the preparing raw material of following weight percentage：NMF 0.6~6%, chelating Agent 0.1~0.3%, emulsifying agent 1.2~3%, antistatic additive 0.1~0.5%, preservative 0.1~0.8% and anti-sensitizer 0.1~ 0.5%；The NMF includes panthenol and pyrrolidone sodium carboxylate；The chelating agent includes EDETATE SODIUM and Etidronic Acid； The emulsifying agent includes cocoyl glucoside and glycerol caprylate；The antistatic additive includes melon glue Hydroxyproyl Trimethyl chlorination Ammonium；The anti-sensitizer includes allantoin.

Pyrrolidone sodium carboxylate (i.e. Anjidew NL50) is naturally occurring material in skin, is amino acid derivativges, and itself is dissolved in Water and ethanol, but insoluble in oil, there is stronger hygroscopicity, moisture content can also be absorbed from air, answering in cosmetics By the use of being as NMF, its moisture-retaining capacity will be by force than glycerine, propane diols, sorbierite these traditional NMFs.And There is no excitant to skin and eyes, will not block pore yet, it is safe.It as human body natural's moisturizing factor it is important into / mono-, hygroscopicity is high, and it is nontoxic, non-stimulated, stability is good, be that modern age skin or hair care is preferably naturally made up health products, can Make skin, hair that there is wetability, flexibility, elasticity and glossiness, antistatic behaviour.If PCA contents are reduced in cuticula, skin Skin can become dry and coarse, fool proof using this NMF.Pyrrolidone sodium carboxylate is that human skin is natural intrinsic Moisturizing ingredient, be that really pyrrolidone sodium carboxylate is applied in shampoo by skin softener physiologically, the present invention, have compared with While strong moistening effect, the stimulation to scalp is avoided.

Panthenol is the precursor of vitamin B5, therefore also known as dexpanthenol, is widely used in medicine, food, cosmetic industry. There is identical metabolic process in vivo as same vitamin B5, in food service industry, as nutritional supplement and hardening agent, Pantothenic acid is converted into human body interior energy, and then synthesizes coacetylase, promotes the metabolism of human body protein, fat, carbohydrate, keeps skin And mucous membrane, improve hair luster, improve immunity, prevent the generation of disease；In cosmetic industry：Nursing role table on skin It is now the NMF penetrated deep into, stimulates the growth of epithelial cell, promote wound healing, play antiinflammation；Panthenol is on hair Nursing role show as lasting moisture-keeping functions, it can wrap up hair, have moisten, moisturizing is smooth, reduce bifurcated, prevent Hair is damaged, and increases the density of hair, improves the gloss of hair quality.Also small wrinkle, inflammation, Exposure to Sunlight, erosion, anti-anti-avulsion can be prevented and treated Hair, promote hair tonic, keep hair moistening, prevent simply and fracture, enemy initiate the effects such as protection, reparation, nursing.

NMF Anjidew NL50 and panthenol joint is used as NMF so that hair wash do after it is not uninteresting, still So keep the epidermis of wetting, lasting moisturizing.

Preferably, the weight ratio of the panthenol and pyrrolidone sodium carboxylate is：Panthenol：Pyrrolidone sodium carboxylate=0.5 ~5:0.05~0.1；The weight ratio of the EDETATE SODIUM and Etidronic Acid is：EDETATE SODIUM：Etidronic Acid=0.5~ 1:0.1~1；The weight ratio of the cocoyl glucoside and glycerol caprylate is：Cocoyl glucoside：Glycerol caprylate=1 ~2：0.005~0.05.

When anti-dandruff silk quality lubrication of the present invention uses the above-mentioned raw material non-stimulated to scalp and proportioning without silicone oil shampoo, Played a role jointly in shampoo, make shampoo character stable, effect is complete.

Preferably, the preservative includes decoyl hydroximic acid, parahydroxyacet-ophenone, glycerine octanoic acid fat and butanediol.

The use of preservative is extremely common in washing product, but excessive or inappropriate preservative can make epidermal cell Developmental immaturity, it is loosely organized, so that epidermis is thinning, easily declined by environmental stimuli, phylactic power defensive power, meeting damaging cells DNA, make skin Skin follows the string gradually, easily produces relaxation, microgroove, and constantly defect can then be bred by the Skin Cell of preservative infringement, order Skin quality is worse and worse.The present invention uses antiseptic substitute --- HL-01, is decoyl hydroximic acid, parahydroxyacet-ophenone, caprylic The mixture of sour fat, butanediol.Wherein, decoyl hydroximic acid is more effective to mould, an unbounded quantity of requirement, and excitant is low, and The compatibility of cosmetic material is preferable；In addition, decoyl hydroximic acid has chelating Ca²⁺, Fe²⁺And Fe³⁺Effect, it is possible to reduce metal The concentration of ion.Parahydroxyacet-ophenone is a kind of natural plant extracts, is naturally occurring in stem, the leaf of feverfew artemisia scoparia, mattress In the roots of plant such as old wormwood artemisia, Asclepiadaceae plant, kerr tylophora root.It is that current the world of medicine is most safe to application on human skin without any harm High temperature auxiliary activity stabilizer, in cosmetic industry mainly as preservative use, be widely used in medicine, make up Product, industrial circle.Glycerol caprylate is a kind of novel non-toxic high-efficiency broad spectrum preservative.It has to gram- bacteria, mould, yeast Inhibitory action, there are anti-corrosion and emulsification dual-use function, be available for emulsion, surfactant product, the product of water alcohol system, have anti- Bacterium, moisturizing, stuffing and other effects, the antiseptic and emulsifying agent being mainly used in food, cosmetics and medical industry.Butanediol is more One kind of first alcohol, NMF and solvent are often done in cosmetics and is used, in terms of moisturizing, due to butanediol be small molecule moisturizing into Part, so grabbing water ratio very little, while also there is certain bacteriostasis.Security is worth affirmative, will not produce irritable inflammation. Therefore, the present invention can be prevented using above-mentioned four kinds of material mixings as a kind of gentle preservative of efficient natural for substituting tradition Rotten agent, reduce the infringement that traditional preservatives are brought to scalp.

Anti-dandruff silk quality lubrication of the present invention is without silicone oil shampoo, in addition to said components clearly require, at lossless In the range of The effect of invention, other adjunct ingredients, such as pH adjusting agent, essence etc., art technology can be added or used to Personnel can select conventional content according to conventional criteria.

Another object of the present invention, which also resides in, provides a kind of above-mentioned anti-dandruff preparation method of the silk quality lubrication without silicone oil shampoo, Comprise the following steps：

(1) surfactant, emulsifying agent, anti-dandruff agent, chelating agent, emulsifying agent and hair conditioner, are added 80~85 DEG C Deionized water in, be well mixed, obtain component A；

(2) component A, is cooled to 45~50 DEG C, NMF, chelating agent is added thereto and assigns fat agent, be well mixed, obtain Component B；

(3) component B, is cooled to 40~45 DEG C, adds assign fat agent, anti-dandruff agent, NMF and preservative thereto, mixing Uniformly, component C is obtained；

(4) component C, is cooled to less than 42 DEG C, adjusts pH value, thickener is added, adjusts to target viscosity, is produced described Anti-dandruff silk quality lubrication is without silicone oil shampoo.

Thickener can select the salt such as sodium chloride, can also select Cocoamidopropyl betaine.Using above method system The standby shampoo character formed is stable, it is long-term place be not in bleed, layering, separation, precipitation, discoloration, peculiar smell, demulsification etc. no Good phenomenon.

The beneficial effects of the present invention are：The invention provides a kind of anti-dandruff silk quality lubrication without silicone oil shampoo, the present invention The anti-dandruff silk quality lubrication uses anti-dandruff significant effect without silicone oil shampoo, and non-stimulated to scalp, has multiple anti-dandruff effect Anti-dandruff and itching-relieving agent；Traditional silicone oil is substituted using fat agent is assigned, with the use of non-stimulated preservative, hair conditioner, table The raw materials such as face activating agent, reach the overall mildness for improving shampoo, reduce excitant of the cleansing to scalp.Institute of the present invention While stating shampoo has good anti-dandruff effect, and can effectively cleaning and nourishing hair and scalp, make hair clearly elegant Submissive, being not in that scalp is difficult after having one's hair wash breathes freely, greasy thick and heavy phenomenon.

Embodiment

To better illustrate the object, technical solutions and advantages of the present invention, below in conjunction with specific embodiment to the present invention It is described further.

Embodiment 1

Anti-dandruff a kind of embodiment of the silk quality lubrication without silicone oil shampoo of the present invention, the shampoo include following weight The preparing raw material of percentage composition：Anti-dandruff and itching-relieving agent 0.62%, hair conditioner 2.4%, surfactant 32%, tax fat agent 2.5%th, NMF 1.08%, chelating agent 0.2%, emulsifying agent 1.515%, antistatic additive 0.3%, preservative 0.5%, anti-sensitizer 0.1~0.5%, the deionized water of essence 0.8%, pH adjusting agent 0.3% and surplus；

Wherein, the anti-dandruff and itching-relieving agent is plant anti-dandruff agent, (isethionic acid) salt of hexamidine two and piroctone ethanol The mixture of amine salt；The weight of the plant anti-dandruff agent, (isethionic acid) salt of hexamidine two and piroctone olamine salt it Than for：Plant anti-dandruff agent：Hexamidine two (isethionic acid) salt：Piroctone olamine salt=5:2:1；

The plant anti-dandruff agent is glycyrrhetinic acid, saponin(e, azadirachta seed extract and water；The glycyrrhetinic acid, saponin(e, print Degree chinaberry seed extract and the weight ratio of water are：Glycyrrhetinic acid：Saponin(e：Azadirachta seed extract：Water=1:1:3:5；

The hair conditioner is silk sericin, hydrolyzed wheat protein PG- propyl silanes triol and Polyquaternium-10 Mixture；The weight ratio of the silk sericin, hydrolyzed wheat protein PG- propyl silanes triol and Polyquaternium-10 For：Silk sericin：Hydrolyzed wheat protein PG- propyl silane triols：Polyquaternium-10=2:0.3:0.1；

The surfactant is laureth sodium sulfovinate, bay alcohol sulfuric ester ammonium, methyl cocoyl taurine The mixture of sodium, Cocoamidopropyl betaine and coconut oleoyl amine DEA；The laureth sodium sulfovinate, laruyl alcohol sulfuric acid Ester ammonium, sodium methyl cocoyl taurate, Cocoamidopropyl betaine and coconut oleoyl amine DEA weight ratio are：Laruyl alcohol Polyethers sodium sulfovinate：Bay alcohol sulfuric ester ammonium：Sodium methyl cocoyl taurate：Cocoamidopropyl betaine：Coconut oleoyl amine DEA=20:5:1:4:2；

The tax fat agent is glyceryl oleate, C12-13 alcohol lactate, cholesterine Queensland nut oleate, dimerization Ji Wusi Alcohol pentaerythritol tetraisostearate, the esters of olive oil PEG-6 polyglycereol -6, the mixture of phosphatide and three-C12-13 alkanol citrates；Institute State glyceryl oleate, C12-13 alcohol lactate, cholesterine Queensland nut oleate, dipentaerythritol pentaerythritol tetraisostearate, olive The weight ratio of the esters of olive oil PEG-6 polyglycereol -6, phosphatide and three-C12-13 alkanol citrates is：Glyceryl oleate：C12- 13 alcohol lactates：Cholesterine Queensland nut oleate：Dipentaerythritol pentaerythritol tetraisostearate：Olive oil PEG-6 polyglycereol -6 Esters：Phosphatide：Three-C12-13 alkanols citrate=1.5：0.5：0.1：0.1：0.1：0.1：0.1；

The NMF is the mixture of panthenol and pyrrolidone sodium carboxylate；The weight of the panthenol and pyrrolidone sodium carboxylate Amount the ratio between be：Panthenol：Pyrrolidone sodium carboxylate=1:0.08；

The chelating agent is the mixture of EDETATE SODIUM and Etidronic Acid；The weight of the EDETATE SODIUM and Etidronic Acid Amount the ratio between be：EDETATE SODIUM：Etidronic Acid=1:1；

The emulsifying agent is the mixture of cocoyl glucoside and glycerol caprylate；The cocoyl glucoside and caprylic The weight ratio of acid esters is：Cocoyl glucoside：Glycerol caprylate=1：0.01；

The antistatic additive is guar hydroxypropyltrimonium chloride；The anti-sensitizer is that preservative is described in allantoin Decoyl hydroximic acid, parahydroxyacet-ophenone, the mixture of glycerine octanoic acid fat and butanediol；The pH adjusting agent is citric acid.

Anti-dandruff preparation method of the silk quality lubrication without silicone oil shampoo, comprises the following steps described in the present embodiment：

(1), by laureth sodium sulfovinate, bay alcohol sulfuric ester ammonium, coconut oleoyl amine DEA, methyl cocoyl ox sulphur Sour sodium, EDETATE SODIUM, cocoyl glucoside, hexamidine two (isethionic acid) salt, allantoin, glycerol caprylate add 80~85 DEG C deionized water in, then add the scattered guar hydroxypropyltrimonium chloride of 10 times of cold pure water, add 10 times it is cold pure Moisture scattered Polyquaternium-10 and hydrolyzed wheat protein PG- propyl silane triols, after being evacuated to -0.06~-0.08MPa, 10~15min of its homogeneous is obtained into component A to uniform under stirring at low speed；

(2) component A, is cooled to 45~50 DEG C, adds panthenol, C12-13 alcohol lactate and Etidronic Acid thereto, It is well mixed, obtain component B；

(3) component B, is cooled to 40~45 DEG C, it is anti-dandruff to add glyceryl oleate, silk sericin, plant thereto Agent, cholesterine Queensland nut oleate, dipentaerythritol pentaerythritol tetraisostearate, the esters of olive oil PEG-6 polyglycereol -6, phosphorus Fat, piroctone olamine salt, three-C12-13 alkanols citrates, Anjidew NL50 and preservative, it is well mixed, obtains component C；

(4) component C, is cooled to less than 42 DEG C, adjusts pH value, Cocoamidopropyl betaine is added, adjusts to target Viscosity, the anti-dandruff silk quality lubrication is produced without silicone oil shampoo.

Embodiment 2

Anti-dandruff a kind of embodiment of the silk quality lubrication without silicone oil shampoo of the present invention, the shampoo include following weight The preparing raw material of percentage composition：Anti-dandruff and itching-relieving agent 0.2%, hair conditioner 5%, surfactant 45%, assign fat agent 1.5%, NMF 0.6%, chelating agent 0.1~0.3%, emulsifying agent 1.2%, antistatic additive 0.1%, preservative 0.1%, anti-sensitizer 0.1%th, the deionized water of essence 0.8%, pH adjusting agent 0.3% and surplus；

Wherein, the anti-dandruff and itching-relieving agent is plant anti-dandruff agent, (isethionic acid) salt of hexamidine two and piroctone ethanol The mixture of amine salt；The weight of the plant anti-dandruff agent, (isethionic acid) salt of hexamidine two and piroctone olamine salt it Than for：Plant anti-dandruff agent：Hexamidine two (isethionic acid) salt：Piroctone olamine salt=1:1:3；

The plant anti-dandruff agent is glycyrrhetinic acid, saponin(e, azadirachta seed extract and water；The glycyrrhetinic acid, saponin(e, print Degree chinaberry seed extract and the weight ratio of water are：Glycyrrhetinic acid：Saponin(e：Azadirachta seed extract：Water=1:1:9:11；

The hair conditioner is silk sericin, hydrolyzed wheat protein PG- propyl silanes triol and Polyquaternium-10 Mixture；The weight ratio of the silk sericin, hydrolyzed wheat protein PG- propyl silanes triol and Polyquaternium-10 For：Silk sericin：Hydrolyzed wheat protein PG- propyl silane triols：Polyquaternium-10=1:5:5；

The surfactant is laureth sodium sulfovinate, bay alcohol sulfuric ester ammonium, methyl cocoyl taurine The mixture of sodium, Cocoamidopropyl betaine and coconut oleoyl amine DEA；The laureth sodium sulfovinate, laruyl alcohol sulfuric acid Ester ammonium, sodium methyl cocoyl taurate, Cocoamidopropyl betaine and coconut oleoyl amine DEA weight ratio are：Laruyl alcohol Polyethers sodium sulfovinate：Bay alcohol sulfuric ester ammonium：Sodium methyl cocoyl taurate：Cocoamidopropyl betaine：Coconut oleoyl amine DEA=10~25:3~6:0.5~1:3~8:1~5；

The tax fat agent is glyceryl oleate, C12-13 alcohol lactate, cholesterine Queensland nut oleate, dimerization Ji Wusi Alcohol pentaerythritol tetraisostearate, the esters of olive oil PEG-6 polyglycereol -6, the mixture of phosphatide and three-C12-13 alkanol citrates；Institute State glyceryl oleate, C12-13 alcohol lactate, cholesterine Queensland nut oleate, dipentaerythritol pentaerythritol tetraisostearate, olive The weight ratio of the esters of olive oil PEG-6 polyglycereol -6, phosphatide and three-C12-13 alkanol citrates is：Glyceryl oleate：C12- 13 alcohol lactates：Cholesterine Queensland nut oleate：Dipentaerythritol pentaerythritol tetraisostearate：Olive oil PEG-6 polyglycereol -6 Esters：Phosphatide：Three-C12-13 alkanols citrate=1：1：0.5：0.05：0.05：0.05：0.3；

The NMF is the mixture of panthenol and pyrrolidone sodium carboxylate；The weight of the panthenol and pyrrolidone sodium carboxylate Amount the ratio between be：Panthenol：Pyrrolidone sodium carboxylate=5:1；

The chelating agent is the mixture of EDETATE SODIUM and Etidronic Acid；The weight of the EDETATE SODIUM and Etidronic Acid Amount the ratio between be：EDETATE SODIUM：Etidronic Acid=1:2；

The emulsifying agent is the mixture of cocoyl glucoside and glycerol caprylate；The cocoyl glucoside and caprylic The weight ratio of acid esters is：Cocoyl glucoside：Glycerol caprylate=1：0.05；

Anti-dandruff preparation method of the silk quality lubrication without silicone oil shampoo is same as Example 1 described in the present embodiment.

Embodiment 3

Anti-dandruff a kind of embodiment of the silk quality lubrication without silicone oil shampoo of the present invention, the shampoo include following weight The preparing raw material of percentage composition：Anti-dandruff and itching-relieving agent 3%, hair conditioner 0.3%, surfactant 18%, tax fat agent 6%, guarantor Humectant 6%, chelating agent 0.3%, emulsifying agent 3%, antistatic additive 0.5%, preservative 0.8%, anti-sensitizer 0.5%, essence 0.8%th, the deionized water of pH adjusting agent 0.3% and surplus；

Wherein, the anti-dandruff and itching-relieving agent is plant anti-dandruff agent, (isethionic acid) salt of hexamidine two and piroctone ethanol The mixture of amine salt；The weight of the plant anti-dandruff agent, (isethionic acid) salt of hexamidine two and piroctone olamine salt it Than for：Plant anti-dandruff agent：Hexamidine two (isethionic acid) salt：Piroctone olamine salt=2：0.01：0.05；

The plant anti-dandruff agent is glycyrrhetinic acid, saponin(e, azadirachta seed extract and water；The glycyrrhetinic acid, saponin(e, print Degree chinaberry seed extract and the weight ratio of water are：Glycyrrhetinic acid：Saponin(e：Azadirachta seed extract：Water=1:1:1:3；

The hair conditioner is silk sericin, hydrolyzed wheat protein PG- propyl silanes triol and Polyquaternium-10 Mixture；The weight ratio of the silk sericin, hydrolyzed wheat protein PG- propyl silanes triol and Polyquaternium-10 For：Silk sericin：Hydrolyzed wheat protein PG- propyl silane triols：Polyquaternium-10=3:0.1:0.05；

The surfactant is laureth sodium sulfovinate, bay alcohol sulfuric ester ammonium, methyl cocoyl taurine The mixture of sodium, Cocoamidopropyl betaine and coconut oleoyl amine DEA；The laureth sodium sulfovinate, laruyl alcohol sulfuric acid Ester ammonium, sodium methyl cocoyl taurate, Cocoamidopropyl betaine and coconut oleoyl amine DEA weight ratio are：Laruyl alcohol Polyethers sodium sulfovinate：Bay alcohol sulfuric ester ammonium：Sodium methyl cocoyl taurate：Cocoamidopropyl betaine：Coconut oleoyl amine DEA=10:6:0.5:3:1；

The tax fat agent is glyceryl oleate, C12-13 alcohol lactate, cholesterine Queensland nut oleate, dimerization Ji Wusi Alcohol pentaerythritol tetraisostearate, the esters of olive oil PEG-6 polyglycereol -6, the mixture of phosphatide and three-C12-13 alkanol citrates；Institute State glyceryl oleate, C12-13 alcohol lactate, cholesterine Queensland nut oleate, dipentaerythritol pentaerythritol tetraisostearate, olive The weight ratio of the esters of olive oil PEG-6 polyglycereol -6, phosphatide and three-C12-13 alkanol citrates is：Glyceryl oleate：C12- 13 alcohol lactates：Cholesterine Queensland nut oleate：Dipentaerythritol pentaerythritol tetraisostearate：Olive oil PEG-6 polyglycereol -6 Esters：Phosphatide：Three-C12-13 alkanols citrate=1：1：0.5：0.5：0.3：0.1：0.05；

The NMF is the mixture of panthenol and pyrrolidone sodium carboxylate；The weight of the panthenol and pyrrolidone sodium carboxylate Amount the ratio between be：Panthenol：Pyrrolidone sodium carboxylate=10:1；

The chelating agent is the mixture of EDETATE SODIUM and Etidronic Acid；The weight of the EDETATE SODIUM and Etidronic Acid Amount the ratio between be：EDETATE SODIUM：Etidronic Acid=10:1；

The emulsifying agent is the mixture of cocoyl glucoside and glycerol caprylate；The cocoyl glucoside and caprylic The weight ratio of acid esters is：Cocoyl glucoside：Glycerol caprylate=2：0.005；

Embodiment 4

Anti-dandruff a kind of embodiment of the silk quality lubrication without silicone oil shampoo of the present invention, the shampoo include following weight The preparing raw material of percentage composition：Anti-dandruff and itching-relieving agent 2.2%, hair conditioner 3%, surfactant 32%, tax fat agent 4%, guarantor Humectant 5%, chelating agent 0.1%, emulsifying agent 1.5%, antistatic additive 0.4%, preservative 0.5%, anti-sensitizer 0.4%, essence 0.8%th, the deionized water of pH adjusting agent 0.3% and surplus；

The hair conditioner is silk sericin, hydrolyzed wheat protein PG- propyl silanes triol and Polyquaternium-10 Mixture；The weight ratio of the silk sericin, hydrolyzed wheat protein PG- propyl silanes triol and Polyquaternium-10 For：Silk sericin：Hydrolyzed wheat protein PG- propyl silane triols：Polyquaternium-10=3:0.5:0.05；

The tax fat agent is glyceryl oleate, C12-13 alcohol lactate, cholesterine Queensland nut oleate, dimerization Ji Wusi Alcohol pentaerythritol tetraisostearate, the esters of olive oil PEG-6 polyglycereol -6, the mixture of phosphatide and three-C12-13 alkanol citrates；Institute State glyceryl oleate, C12-13 alcohol lactate, cholesterine Queensland nut oleate, dipentaerythritol pentaerythritol tetraisostearate, olive The weight ratio of the esters of olive oil PEG-6 polyglycereol -6, phosphatide and three-C12-13 alkanol citrates is：Glyceryl oleate：C12- 13 alcohol lactates：Cholesterine Queensland nut oleate：Dipentaerythritol pentaerythritol tetraisostearate：Olive oil PEG-6 polyglycereol -6 Esters：Phosphatide：Three-C12-13 alkanols citrate=1：0.1：0.5：0.05：0.05：0.08：0.02；

The NMF is the mixture of panthenol and pyrrolidone sodium carboxylate；The weight of the panthenol and pyrrolidone sodium carboxylate Amount the ratio between be：Panthenol：Pyrrolidone sodium carboxylate=3:0.05；

The chelating agent is the mixture of EDETATE SODIUM and Etidronic Acid；The weight of the EDETATE SODIUM and Etidronic Acid Amount the ratio between be：EDETATE SODIUM：Etidronic Acid=8:1；

The emulsifying agent is the mixture of cocoyl glucoside and glycerol caprylate；The cocoyl glucoside and caprylic The weight ratio of acid esters is：Cocoyl glucoside：Glycerol caprylate=20:1；

Embodiment 5

Anti-dandruff a kind of embodiment of the silk quality lubrication without silicone oil shampoo of the present invention, the shampoo include following weight The preparing raw material of percentage composition：The weight percentage of anti-dandruff and itching-relieving agent 2.5%, hair conditioner in preparing raw material is 1.5%th, weight percentage of the surfactant in preparing raw material is 25%, assigns weight percent of the fat agent in preparing raw material Content is 4%, NMF 2%, chelating agent 0.2%, emulsifying agent 1.9%, antistatic additive 0.2%, preservative 0.5%, anti-sensitizer 0.2%th, the deionized water of essence 0.8%, pH adjusting agent 0.3% and surplus；

Wherein, the anti-dandruff and itching-relieving agent is plant anti-dandruff agent, (isethionic acid) salt of hexamidine two and piroctone ethanol The mixture of amine salt；The weight of the plant anti-dandruff agent, (isethionic acid) salt of hexamidine two and piroctone olamine salt it Than for：Plant anti-dandruff agent：Hexamidine two (isethionic acid) salt：Piroctone olamine salt=1：0.08：0.15；

The hair conditioner is silk sericin, hydrolyzed wheat protein PG- propyl silanes triol and Polyquaternium-10 Mixture；The weight ratio of the silk sericin, hydrolyzed wheat protein PG- propyl silanes triol and Polyquaternium-10 For：Silk sericin：Hydrolyzed wheat protein PG- propyl silane triols：Polyquaternium-10=1:0.4:1；

The surfactant is laureth sodium sulfovinate, bay alcohol sulfuric ester ammonium, methyl cocoyl taurine The mixture of sodium, Cocoamidopropyl betaine and coconut oleoyl amine DEA；The laureth sodium sulfovinate, laruyl alcohol sulfuric acid Ester ammonium, sodium methyl cocoyl taurate, Cocoamidopropyl betaine and coconut oleoyl amine DEA weight ratio are：Laruyl alcohol Polyethers sodium sulfovinate：Bay alcohol sulfuric ester ammonium：Sodium methyl cocoyl taurate：Cocoamidopropyl betaine：Coconut oleoyl amine DEA=20:3:0.5:5:4；

The tax fat agent is glyceryl oleate, C12-13 alcohol lactate, cholesterine Queensland nut oleate, dimerization Ji Wusi Alcohol pentaerythritol tetraisostearate, the esters of olive oil PEG-6 polyglycereol -6, the mixture of phosphatide and three-C12-13 alkanol citrates；Institute State glyceryl oleate, C12-13 alcohol lactate, cholesterine Queensland nut oleate, dipentaerythritol pentaerythritol tetraisostearate, olive The weight ratio of the esters of olive oil PEG-6 polyglycereol -6, phosphatide and three-C12-13 alkanol citrates is：Glyceryl oleate：C12- 13 alcohol lactates：Cholesterine Queensland nut oleate：Dipentaerythritol pentaerythritol tetraisostearate：Olive oil PEG-6 polyglycereol -6 Esters：Phosphatide：Three-C12-13 alkanols citrate=2：0.5：0.2：0.2：0.2：0.05：0.05；

The emulsifying agent is the mixture of cocoyl glucoside and glycerol caprylate；The cocoyl glucoside and caprylic The weight ratio of acid esters is：Cocoyl glucoside：Glycerol caprylate=1：0.02；

Embodiment 6

Anti-dandruff a kind of embodiment of the silk quality lubrication without silicone oil shampoo of the present invention, the shampoo include following weight The preparing raw material of percentage composition：Anti-dandruff and itching-relieving agent 2%, hair conditioner 4%, surfactant 25%, tax fat agent 5%, moisturizing Agent 5%, chelating agent 0.2%, emulsifying agent 1.9%, antistatic additive 0.4%, preservative 0.5%, anti-sensitizer 0.4%, essence 0.8%th, the deionized water of pH adjusting agent 0.3% and surplus；

Wherein, the anti-dandruff and itching-relieving agent is plant anti-dandruff agent, (isethionic acid) salt of hexamidine two and piroctone ethanol The mixture of amine salt；The weight of the plant anti-dandruff agent, (isethionic acid) salt of hexamidine two and piroctone olamine salt it Than for：Plant anti-dandruff agent：Hexamidine two (isethionic acid) salt：Piroctone olamine salt=8:1:3；

The hair conditioner is silk sericin, hydrolyzed wheat protein PG- propyl silanes triol and Polyquaternium-10 Mixture；The weight ratio of the silk sericin, hydrolyzed wheat protein PG- propyl silanes triol and Polyquaternium-10 For：Silk sericin：Hydrolyzed wheat protein PG- propyl silane triols：Polyquaternium-10=1.5:0.1:0.1；

The surfactant is laureth sodium sulfovinate, bay alcohol sulfuric ester ammonium, methyl cocoyl taurine The mixture of sodium, Cocoamidopropyl betaine and coconut oleoyl amine DEA；The laureth sodium sulfovinate, laruyl alcohol sulfuric acid Ester ammonium, sodium methyl cocoyl taurate, Cocoamidopropyl betaine and coconut oleoyl amine DEA weight ratio are：Laruyl alcohol Polyethers sodium sulfovinate：Bay alcohol sulfuric ester ammonium：Sodium methyl cocoyl taurate：Cocoamidopropyl betaine：Coconut oleoyl amine DEA=25:5:0.6:5:3；

The tax fat agent is glyceryl oleate, C12-13 alcohol lactate, cholesterine Queensland nut oleate, dimerization Ji Wusi Alcohol pentaerythritol tetraisostearate, the esters of olive oil PEG-6 polyglycereol -6, the mixture of phosphatide and three-C12-13 alkanol citrates；Institute State glyceryl oleate, C12-13 alcohol lactate, cholesterine Queensland nut oleate, dipentaerythritol pentaerythritol tetraisostearate, olive The weight ratio of the esters of olive oil PEG-6 polyglycereol -6, phosphatide and three-C12-13 alkanol citrates is：Glyceryl oleate：C12- 13 alcohol lactates：Cholesterine Queensland nut oleate：Dipentaerythritol pentaerythritol tetraisostearate：Olive oil PEG-6 polyglycereol -6 Esters：Phosphatide：Three-C12-13 alkanols citrate=1~3：0.1~1：0.08：0.08：0.08：0.1：0.2；

The NMF is the mixture of panthenol and pyrrolidone sodium carboxylate；The weight of the panthenol and pyrrolidone sodium carboxylate Amount the ratio between be：Panthenol：Pyrrolidone sodium carboxylate=5:0.08；

The chelating agent is the mixture of EDETATE SODIUM and Etidronic Acid；The weight of the EDETATE SODIUM and Etidronic Acid Amount the ratio between be：EDETATE SODIUM：Etidronic Acid=5:8；

The emulsifying agent is the mixture of cocoyl glucoside and glycerol caprylate；The cocoyl glucoside and caprylic The weight ratio of acid esters is：Cocoyl glucoside：Glycerol caprylate=1：0.008；

Embodiment 7

Anti-dandruff silk quality lubrication described in the present embodiment is washed without silicone oil shampoo and anti-dandruff silk quality lubrication described in embodiment 1 without silicone oil The difference of shampoo is to be only that the composition of surfactant is different；I.e. described surfactant is laureth sulfuric ester The mixing of sodium, bay alcohol sulfuric ester ammonium, sodium methyl cocoyl taurate, Cocoamidopropyl betaine and coconut oleoyl amine DEA Thing；The laureth sodium sulfovinate, bay alcohol sulfuric ester ammonium, sodium methyl cocoyl taurate, cocamidopropyl propyl amide sweet tea Dish alkali and coconut oleoyl amine DEA weight ratio is：Laureth sodium sulfovinate：Bay alcohol sulfuric ester ammonium：Methyl cocoyl Sodium taurocholate：Cocoamidopropyl betaine：Coconut oleoyl amine DEA=20:5:0.5:4:2.

Embodiment 8

Anti-dandruff silk quality lubrication described in the present embodiment is washed without silicone oil shampoo and anti-dandruff silk quality lubrication described in embodiment 1 without silicone oil The difference of shampoo is to be only that the composition of surfactant is different；I.e. described surfactant is laureth sulfuric ester The mixing of sodium, bay alcohol sulfuric ester ammonium, sodium methyl cocoyl taurate, Cocoamidopropyl betaine and coconut oleoyl amine DEA Thing；The laureth sodium sulfovinate, bay alcohol sulfuric ester ammonium, sodium methyl cocoyl taurate, cocamidopropyl propyl amide sweet tea Dish alkali and coconut oleoyl amine DEA weight ratio is：Laureth sodium sulfovinate：Bay alcohol sulfuric ester ammonium：Methyl cocoyl Sodium taurocholate：Cocoamidopropyl betaine：Coconut oleoyl amine DEA=20:1:1:4:2.

Embodiment 9

Anti-dandruff silk quality lubrication described in the present embodiment is washed without silicone oil shampoo and anti-dandruff silk quality lubrication described in embodiment 1 without silicone oil The difference of shampoo is to be only that the composition of surfactant is different；I.e. described surfactant is laureth sulfuric ester The mixing of sodium, bay alcohol sulfuric ester ammonium, sodium methyl cocoyl taurate, Cocoamidopropyl betaine and coconut oleoyl amine DEA Thing；The laureth sodium sulfovinate, bay alcohol sulfuric ester ammonium, sodium methyl cocoyl taurate, cocamidopropyl propyl amide sweet tea Dish alkali and coconut oleoyl amine DEA weight ratio is：Laureth sodium sulfovinate：Bay alcohol sulfuric ester ammonium：Methyl cocoyl Sodium taurocholate：Cocoamidopropyl betaine：Coconut oleoyl amine DEA=25:5:1:4:2.

Comparative example 1

Shampoo described in this comparative example is with anti-dandruff silk quality difference of the lubrication without silicone oil shampoo described in embodiment 1 for only It is that the composition of anti-dandruff and itching-relieving agent is different, plant anti-dandruff agent is free of in the anti-dandruff and itching-relieving agent of shampoo described in this comparative example；That is institute Anti-dandruff and itching-relieving agent is stated as piroctone olamine salt and the mixture of hexamidine two (isethionic acid) salt, piroctone olamine The weight ratio of salt and hexamidine two (isethionic acid) salt is 1:2.

The preparation method of shampoo described in this comparative example is same as Example 1.

Comparative example 2

Shampoo described in this comparative example is with anti-dandruff silk quality difference of the lubrication without silicone oil shampoo described in embodiment 1 for only It is that the composition of anti-dandruff and itching-relieving agent is different, piroctone olamine is free of in the anti-dandruff and itching-relieving agent of shampoo described in this comparative example Salt；I.e. described anti-dandruff and itching-relieving agent is the mixture of plant anti-dandruff agent and hexamidine two (isethionic acid) salt；The plant is anti-dandruff The weight ratio of agent and hexamidine two (isethionic acid) salt is：Plant anti-dandruff agent：Hexamidine two (isethionic acid) salt=5: 2。

Comparative example 3

Shampoo described in this comparative example is with anti-dandruff silk quality difference of the lubrication without silicone oil shampoo described in embodiment 1 for only It is that the composition of anti-dandruff and itching-relieving agent is different, (the ethoxy of hexamidine two is free of in the anti-dandruff and itching-relieving agent of shampoo described in this comparative example Sulfonic acid) salt；I.e. described anti-dandruff and itching-relieving agent is the mixture of plant anti-dandruff agent and piroctone olamine salt；The plant anti-dandruff agent Weight ratio with piroctone olamine salt is：Plant anti-dandruff agent：Piroctone olamine salt=5:1.

Comparative example 4

Shampoo described in this comparative example is with anti-dandruff silk quality difference of the lubrication without silicone oil shampoo described in embodiment 1 for only It is that the composition of anti-dandruff and itching-relieving agent is different, containing only (the ethoxy of hexamidine two in the anti-dandruff and itching-relieving agent of shampoo described in this comparative example Sulfonic acid).

Comparative example 5

Shampoo described in this comparative example is with anti-dandruff silk quality difference of the lubrication without silicone oil shampoo described in embodiment 1 for only It is that the composition of anti-dandruff and itching-relieving agent is different, containing only plant anti-dandruff agent in the anti-dandruff and itching-relieving agent of shampoo described in this comparative example.

Comparative example 6

Shampoo described in this comparative example is with anti-dandruff silk quality difference of the lubrication without silicone oil shampoo described in embodiment 1 for only It is that the composition of anti-dandruff and itching-relieving agent is different, containing only piroctone olamine in the anti-dandruff and itching-relieving agent of shampoo described in this comparative example Salt.

Comparative example 7

Shampoo described in this comparative example is with anti-dandruff silk quality difference of the lubrication without silicone oil shampoo described in embodiment 1 for only It is that the composition of hair conditioner is different, silk sericin is free of in the hair conditioner of shampoo described in this comparative example；I.e. The hair conditioner is the mixture of hydrolyzed wheat protein PG- propyl silanes triol and Polyquaternium-10；The hydrolyzed wheat The weight ratio of albumen PG- propyl silanes triol and Polyquaternium-10 is：Hydrolyzed wheat protein PG- propyl silane triols：Poly- season Ammonium salt -10=3:1.

Comparative example 8

Shampoo described in this comparative example is with anti-dandruff silk quality difference of the lubrication without silicone oil shampoo described in embodiment 1 for only It is that the composition of hair conditioner is different, hydrolyzed wheat protein PG- is free of in the hair conditioner of shampoo described in this comparative example Propyl silane triol；I.e. described hair conditioner is the mixture of silk sericin and Polyquaternium-10；The silk silk gum The weight ratio of albumen and Polyquaternium-10 is：Silk sericin：Polyquaternium-10=2:0.1.

Embodiment 10

Anti-dandruff silk quality lubrication in described to embodiment 1~9 carries out Physico-chemical tests, gained Testing index without silicone oil shampoo It is as follows：

1st, character detects

The anti-dandruff silk quality lubrication of embodiment 1~9 is suitable without silicone oil shampoo viscosity, has good stability, fragrant Charming, silk moistens smooth, translucent shampoo.

2nd, pH value detects

Anti-dandruff silk quality lubrication described to embodiment 1~9 is determined with pH meter without silicone oil hair washing water sampling, measures pH value as 5.5 ~6.0.

3rd, viscosity number detects

Anti-dandruff silk quality lubrication described to embodiment 1~9 is determined with viscosimeter without silicone oil hair washing water sampling, measures viscosity number 10000~15000.

4th, Detection of Stability

Anti-dandruff silk quality lubrication described to embodiment 1~9 is encapsulated in transparence cosmetic bottle without silicone oil hair washing water sampling In, be respectively placed in quartz lamp illumination, -15 DEG C, 5 DEG C, 25 DEG C, under 48 DEG C of experiment conditions, to outward appearance, fragrance, pH value, viscosity and Sundry item carries out the continuance test of 3 months by a definite date, sees whether to occur bleed, layering, separation, precipitation, discoloration, peculiar smell, broken The bad phenomenons such as breast, testing result show that the bad result of the above does not appear in the test of 1~9 shampoo of embodiment Cheng Zhong, illustrate that it has good stability.

5th, centrifugation detection

Anti-dandruff silk quality lubrication described to embodiment 1~9 is encapsulated in centrifuge tube without silicone oil hair washing water sampling 30min is centrifuged under 3000r/min, sees whether to occur not dispersion component, testing result and shows, 1~7 shampoo of embodiment Do not occur not dispersion component, illustrate that its Combination is good.

6th, anaphylaxis is stimulated to detect

It is applied to 300 age brackets by anti-dandruff silk quality lubrication described to embodiment 1~9 in right amount without silicone oil hair washing water sampling On 18-58 year volunteer's the back of the hand, to observe 30min, see whether it phenomena such as redness, dermexanthesis, foaming occurs, observe result table Bright, all volunteers do not occur above-mentioned ill symptomses in 30min, illustrate that this product will not produce stimulation and anaphylaxis to skin Problem.

7th, comprehensive using effect detection

Using opinion poll point system, by asking volunteer to try out the sample of embodiment 1~9 and comparative example 7,8 respectively, and Fill in table on probation and carry out overall merit its using effect.Every group of sample chooses (the year age grade of volunteer 50 in all ages and classes stage Section is 18-38 volunteer 25 and the volunteer 25 of 38~58 age levels) as object on probation, hair washing one in every two days It is secondary, it is used continuously three months, fills in table on probation after on probation and scored.Every using effect total score is 5 points in grade form：5 points It is best result, represents very satisfied；4 points are preferable, are relatively satisfied with；3 points are to receive；Less than 3 points are to connect The scope received, every using effect average situation are as shown in table 1.

The embodiment 1~9 of table 1 and comparative example 7, the 8 shampoo items using effect average situations

As it can be seen from table 1 embodiment 1~9 and comparative example 7,8 shampoos show as it is non-stimulated, cleannes compared with It is good, but compared with comparative example 7,8, the submissive effect of 1~9 shampoo of embodiment is more preferable, illustrates of the present invention anti-dandruff Silk quality lubrication has preferable anti-dandruff, a softer and smoother touch and moisturizing effect concurrently without silicone oil shampoo, and non-stimulated to scalp Effect.For embodiment 1 compared with embodiment 7~9, the cleannes scoring of embodiment 1 is higher, shows the laureth sulfuric acid The weight ratio of ester sodium, bay alcohol sulfuric ester ammonium and sodium methyl cocoyl taurate is：Laureth sodium sulfovinate：Bay Alcohol sulfuric ester ammonium：Sodium methyl cocoyl taurate=20:5:When 1, cleannes are more preferably.

Embodiment 1 and 1~6 shampoo of comparative example are used into opinion poll point system, by asking volunteer to try respectively With the sample of embodiment 1 and comparative example 1~6, and table on probation is filled in evaluate the anti-dandruff effect of sample.Every group of embodiment sample is equal Choose (the volunteer 25 and the will of 38~58 age levels that age level is 18-38 of volunteer 50 in all ages and classes stage Hope person 25) once, it is used continuously three months as object on probation, hair washing in every two days, fill in table on probation after on probation and scored. Every using effect total score is 5 points in grade form：5 points are best results, are represented very satisfied；4 points be it is preferable, it is relatively full Meaning；3 points are to receive；Less than the 3 points scopes for that cannot receive, anti-dandruff effect average situation are as shown in table 2.

The anti-dandruff effect of 1~6 shampoo of the embodiment 1 of table 2 and comparative example

From table 2 it can be seen that using the anti-dandruff positive effect of shampoo described in the embodiment 1 of three kinds of anti-dandruff agents better than contrast Only with two of which or a kind of anti-dandruff effect of shampoo in example 1~6, illustrate respectively to go in anti-dandruff and itching-relieving agent of the present invention Agent energy mutually compatibility Synergistic is considered to be worth doing to reach preferable anti-dandruff effect.

Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than the present invention is protected The limitation of scope is protected, although being explained in detail with reference to preferred embodiment to the present invention, one of ordinary skill in the art should Understand, technical scheme can be modified or equivalent substitution, without departing from the essence of technical solution of the present invention And scope.

Claims

1. a kind of anti-dandruff silk quality lubrication is without silicone oil shampoo, it is characterised in that the preparing raw material of the shampoo includes anti-dandruff stop Itch agent, weight percentage of the anti-dandruff and itching-relieving agent in preparing raw material is 0.2~3%；The anti-dandruff and itching-relieving agent, which includes, plants Thing anti-dandruff agent；The plant anti-dandruff agent includes glycyrrhetinic acid, saponin(e and azadirachta seed extract.

2. anti-dandruff silk quality lubrication is without silicone oil shampoo as claimed in claim 1, it is characterised in that the glycyrrhetinic acid, saponin(e and The weight ratio of azadirachta seed extract is：Glycyrrhetinic acid：Saponin(e：Azadirachta seed extract=1~3:1~3:3~9；It is preferred that Ground, the weight ratio of the glycyrrhetinic acid, saponin(e and azadirachta seed extract are：Glycyrrhetinic acid：Saponin(e：Azadirachta seed extract =1:1:3.

3. anti-dandruff silk quality lubrication is without silicone oil shampoo as claimed in claim 1, it is characterised in that the anti-dandruff and itching-relieving agent also includes (isethionic acid) salt of hexamidine two and piroctone olamine salt；The plant anti-dandruff agent, hexamidine two (isethionic acid) Salt and the weight ratio of piroctone olamine salt are：Plant anti-dandruff agent：Hexamidine two (isethionic acid) salt：Piroctone second Alcohol amine salt=0.1~2：0.01~0.1：0.05~0.3.

4. anti-dandruff silk quality lubrication is without silicone oil shampoo as any one of claims 1 to 3, it is characterised in that the hair washing The preparing raw material of water also includes hair conditioner；Weight percentage of the hair conditioner in preparing raw material be 0.3~ 5%；The hair conditioner is included in silk sericin, hydrolyzed wheat protein PG- propyl silanes triol and Polyquaternium-10 At least one；Preferably, the hair conditioner includes silk sericin, hydrolyzed wheat protein PG- propyl silane triols And Polyquaternium-10；The weight of the silk sericin, hydrolyzed wheat protein PG- propyl silanes triol and Polyquaternium-10 The ratio between be：Silk sericin：Hydrolyzed wheat protein PG- propyl silane triols：Polyquaternium-10=0.1~3:0.1~0.5: 0.05~0.5.

5. anti-dandruff silk quality lubrication is without silicone oil shampoo as claimed in claim 4, it is characterised in that the preparing raw material of the shampoo Surfactant is also included, weight percentage of the surfactant in preparing raw material is 18~45%；The surface Activating agent includes laureth sodium sulfovinate, bay alcohol sulfuric ester ammonium, sodium methyl cocoyl taurate, cocamidopropyl propyl amide At least one of glycine betaine and coconut oleoyl amine DEA.

6. anti-dandruff silk quality lubrication is without silicone oil shampoo as claimed in claim 5, it is characterised in that the surfactant includes the moon Laureth sodium sulfovinate, bay alcohol sulfuric ester ammonium and sodium methyl cocoyl taurate；The laureth sodium sulfovinate, Bay alcohol sulfuric ester ammonium and the weight ratio of sodium methyl cocoyl taurate are：Laureth sodium sulfovinate：Laruyl alcohol sulphur Acid esters ammonium：Sodium methyl cocoyl taurate=10~25:3~6:0.5~1；Preferably, the laureth sulfuric ester The weight ratio of sodium, bay alcohol sulfuric ester ammonium and sodium methyl cocoyl taurate is：Laureth sodium sulfovinate：Laruyl alcohol Sulfuric ester ammonium：Sodium methyl cocoyl taurate=20:5:1.

7. anti-dandruff silk quality lubrication is without silicone oil shampoo as claimed in claim 4, it is characterised in that the preparing raw material of the shampoo Also comprising tax fat agent；The weight percentage that fat agent is assigned in preparing raw material is 1.5~6%；The tax fat agent includes sweet Oily oleate, C12-13 alcohol lactate, cholesterine Queensland nut oleate, dipentaerythritol pentaerythritol tetraisostearate, olive oil At least one of the esters of PEG-6 polyglycereol -6, phosphatide and three-C12-13 alkanol citrates；Preferably, the tax fat agent bag Containing glyceryl oleate, C12-13 alcohol lactate, cholesterine Queensland nut oleate, dipentaerythritol pentaerythritol tetraisostearate, olive The esters of olive oil PEG-6 polyglycereol -6, phosphatide and three-C12-13 alkanol citrates；The glyceryl oleate, C12-13 alcohol lactic acid Ester, cholesterine Queensland nut oleate, dipentaerythritol pentaerythritol tetraisostearate, the esters of olive oil PEG-6 polyglycereol -6, phosphatide Weight ratio with three-C12-13 alkanol citrates is：Glyceryl oleate：C12-13 alcohol lactates：Cholesterine Queensland nut Oleate：Dipentaerythritol pentaerythritol tetraisostearate：The esters of olive oil PEG-6 polyglycereol -6：Phosphatide：Three-C12-13 alkanol lemons Lemon acid esters=1~3：0.1~1：0.05~0.5：0.05~0.5：0.05~0.3：0.05~0.1：0.05~0.3.

8. anti-dandruff silk quality lubrication is without silicone oil shampoo as claimed in claim 4, it is characterised in that the shampoo is also comprising following The preparing raw material of weight percentage：It is NMF 0.6~6%, chelating agent 0.1~0.3%, emulsifying agent 1.2~3%, antistatic Agent 0.1~0.5%, preservative 0.1~0.8% and anti-sensitizer 0.1~0.5%；The NMF includes panthenol and pyrrolidones Carboxylic acid sodium；The chelating agent includes EDETATE SODIUM and Etidronic Acid；The emulsifying agent includes cocoyl glucoside and caprylic Acid esters；The antistatic additive includes guar hydroxypropyltrimonium chloride；The anti-sensitizer includes allantoin.

9. anti-dandruff silk quality lubrication is without silicone oil shampoo as claimed in claim 8, it is characterised in that panthenol and the pyrrolidones carboxylic The weight ratio of sour sodium is：Panthenol：Pyrrolidone sodium carboxylate=0.5~5:0.05~0.1；The phosphorus of EDETATE SODIUM and hydroxyl second two Acid weight ratio be：EDETATE SODIUM：Etidronic Acid=0.5~1:0.1~1；Cocoyl glucoside and the glycerine octanoic acid The weight ratio of ester is：Cocoyl glucoside：Glycerol caprylate=1~2：0.005~0.05.

10. anti-dandruff silk quality lubrication is without silicone oil shampoo as claimed in claim 8, it is characterised in that the preservative includes decoyl Hydroximic acid, parahydroxyacet-ophenone, glycerine octanoic acid fat and butanediol.