CN107982110A

CN107982110A - One kind is without silicone oil shampoo

Info

Publication number: CN107982110A
Application number: CN201711414665.7A
Authority: CN
Inventors: 苏晋峰; 陈志盛
Original assignee: GUANGZHOU SHENCAI COSMETICS Co Ltd
Current assignee: GUANGZHOU SHENCAI COSMETICS Co Ltd
Priority date: 2017-12-21
Filing date: 2017-12-21
Publication date: 2018-05-04

Abstract

The invention discloses one kind Tremella fructification extract is included without silicone oil shampoo, the shampoo.The present invention utilizes different poly- polysaccharide (WSK) special construction of itself of white fungus in Tremella fructification extract, continue water conservation by intermolecular hydrogen bonding effect and netted sugar chain structure for hair, worked along both lines by " water conservation " and " water lock ", continue moisturizing for hair and scalp.In addition, since the film surface of formation has hydrophobicity, hair is salubrious after dry hair, non-greasy, after adding WSK in formula, experiments prove that to lather quickness, foam volume, foam stabilizing time, foam sophistication, compliance and cardability have clear improvement, and more preferable use feeling is provided for consumer.

Description

One kind is without silicone oil shampoo

Technical field

The present invention relates to a kind of shampoo, and especially one kind is without silicone oil shampoo.

Background technology

At present, the general silicate-containing oil of commercially available shampoo, easily produces silicone oil accumulation, causes hair after reusing for a long time It is glutinous it is greasy, block the problems such as pore.Although commercially available also have some without silicone oil shampoo, be commercially available no silicone oil shampoo generally by In Monoethanolamine Lauryl Sulfate, the problems such as long-time service easily produces hair quality dry, itching of the scalp.Moreover, at present on the market without silicone oil Shampoo generally existing lather quickness is slower, the situation of foam loosely.To improve sensation of dryness when being rinsed without silicone oil shampoo, More cationic polymer need to be generally added, but excessive cationic deposition polymer easily makes hair produce glutinous soapy feeling, because This, general nursing type is only paid attention to conserving hair without silicone oil shampoo, and have ignored the nourishing to scalp in itself.

The content of the invention

Based on this, provided a kind of without silicone oil hair washing it is an object of the invention to overcome above-mentioned the deficiencies in the prior art part Water.

To achieve the above object, the technical solution used in the present invention is：One kind is without silicone oil shampoo, the shampoo bag Argentiferous ear fruiting body extract.

Preferably, mass percentage of the Tremella fructification extract in the shampoo for 0.005~ 0.02%.

It is highly preferred that mass percentage of the Tremella fructification extract in the shampoo is 0.01%.

It is highly preferred that the Tremella fructification extract is the different poly- polysaccharide of white fungus.

It is highly preferred that the molecular weight of the different poly- polysaccharide of white fungus is more than 1,000,000 dalton.WSK (the different poly- polysaccharide of white fungus) points Son amount is more than 1,000,000 dalton, has splendid film forming.And film surface has hydrophobicity, can make hair after drying more Add dry and comfortable, non-greasy, and the film that WSK is formed is not shunk with the change of humidity, the film formed compared to Sodium Hyaluronate, more Softness, has more preferable ductility and elasticity.The film formed compared to silicone oil, has more preferable gas permeability.

The present invention utilizes different poly- polysaccharide (WSK) special construction of of white fungus itself, by intermolecular hydrogen bonding effect and netted sugar Chain structure continues water conservation for hair, and by WSK of the preferred molecular weight more than 1,000,000 dalton, film lock is formed on hair Water barrier.Worked along both lines by " water conservation " and " water lock ", continue moisturizing for hair and scalp.Further, since the film table formed Face has hydrophobicity, and hair is salubrious after dry hair, non-greasy.After adding WSK in formula, experiments prove that to blistering speed Degree, foam volume, foam stabilizing time, foam sophistication, compliance and cardability have clear improvement, and being provided for consumer preferably makes With sense.

Preferably, the no silicone oil shampoo, also includes the conditioner of following parts by weight：Acrylamido propyl trimethyl chlorine Change 0.04~0.06 part of ammonium/acrylamide copolymer, 0.05~0.15 part of hydroxypropyl guar hydroxypropyltrimonium chloride, 0.2~0.4 part of PPG-3 nutmegs alcohol ether, 0.1~0.3 part of palmitamide hydroxypropyltrimonium chloride, isooctadecanol 0.4~0.6 0.4~0.6 part of the mixture of part, quaternary ammonium salt -80 and propane diols.

It is highly preferred that the no silicone oil shampoo, the conditioner of following parts by weight is also included：Acrylamido propyl trimethyl 0.05 part of ammonium chloride/acrylamide copolymer, 0.1 part of hydroxypropyl guar hydroxypropyltrimonium chloride, PPG-3 myristyl alcohols 0.3 part of ether, 0.2 part of palmitamide hydroxypropyltrimonium chloride, 0.5 part of isooctadecanol, the mixture of quaternary ammonium salt -80 and propane diols 0.5 part.

Preferably, the no silicone oil shampoo, also includes the surfactant of following parts by weight：Laureth sulfuric ester 14~16 parts of sodium, 14~16 parts of Cocoamidopropyl betaine, 0.2~0.4 part of glycerol monolaurate, sodium lauroyl sarcosine 2 ~4 parts.

It is highly preferred that the no silicone oil shampoo, the surfactant of following parts by weight is also included：Laureth sulfuric acid 15 parts of ester sodium, 15 parts of Cocoamidopropyl betaine, 0.3 part of glycerol monolaurate, 3 parts of sodium lauroyl sarcosine.

Preferably, the no silicone oil shampoo, also includes the component of following parts by weight：Disodium ethylene diamine tetraacetate 0.04~ 0.06 part, 0.005~0.015 part of citric acid, 60~70 parts of water.

Preferably, the no silicone oil shampoo, also includes the preservative of 0.07~0.09 parts by weight, and the preservative is first The mixture of base chloroisothiazole quinoline ketone and methylisothiazolinone.

In addition, some other assistant agents can also be added according to actual needs in shampoo of the present invention, it is such as refrigerant Agent, aromatic etc..

Relative to the prior art, beneficial effects of the present invention are：

The present invention is by Tremella fructification extract (the different poly- polysaccharide of white fungus) and its specific conditioner for hair and surface-active Agent is used cooperatively, and has some following advantage：

1st, the different poly- polysaccharide (WSK) of white fungus is due to the special construction of itself, intermolecular hydrogen bond action and netted sugar chain structure, It is can absorb itself more than 500 times of moisture, there is excellent water binding ability, moisture retention is splendid, make hair keep water profit, It is glossy；

2nd, it is after adding minimal amount of WSK in being formulated, then equal to lather quickness, foam volume, foam stabilizing time and foam sophistication There is obvious improvement, moreover it is possible to submissive hair, and cardability is improved, it can accordingly reduce the addition of cationic polymer in formula Amount；Separately since additive amount is extremely low, too many ultimate cost will not be increased；

3rd, the film that WSK is formed is not shunk with the change of humidity, the film formed compared to Sodium Hyaluronate, more soft, With more preferable ductility and elasticity.The film formed compared to silicone oil, has more preferable gas permeability；

4th, since WSK has good moisture retention in itself, its effect has widely been approved in skin care industry, after washing The film of formation can also form scalp preferable maintenance effect.

Brief description of the drawings

Fig. 1 is the water droplet state diagram of each desciccator diaphragm of drop on a glass；

Fig. 2 is damaged hair sample surfaces and instills the contact angle between water droplet；

Fig. 3 changes over time situation map for filter weight；

The step of Fig. 4 is the WSK solution that filter paper filters 0.2% concentration and result figure；

Fig. 5 is foam volume and foam stabilizing time test result figure；

Fig. 6 is present invention hair washing water bubble sophistication situation map；

Fig. 7 is the foam sophistication situation map of micro- Microscopic observation shampoo of the present invention.

Embodiment

To better illustrate the object, technical solutions and advantages of the present invention, below in conjunction with the drawings and specific embodiments pair The present invention is described further.

Embodiment 1

A kind of embodiment of no silicone oil shampoo of the present invention, shampoo described in the present embodiment include following parts by weight Component：

Different poly- 0.01 part of the polysaccharide (WSK) of white fungus, acrylamido propyl trimethyl ammonium chloride/acrylamide copolymer 0.05 Part, 0.1 part of hydroxypropyl guar hydroxypropyltrimonium chloride, 0.3 part of PPG-3 nutmegs alcohol ether, palmitamide propyl group front three 0.2 part of ammonium chloride, 0.5 part of isooctadecanol, mixture (ABIL Quat 3272) 0.5 part, month of quaternary ammonium salt -80 and propane diols 15 parts of laureth sodium sulfovinate, 15 parts of Cocoamidopropyl betaine, 0.3 part of glycerol monolaurate, sodium lauroyl sarcosine 3 Part, 0.05 part of disodium ethylene diamine tetraacetate, 0.01 part of citric acid, 64.40 parts of water, 0.08 part of preservative (MICROCARE CM), 0.5 part of essence.

Embodiment 2

Different poly- 0.005 part of the polysaccharide (WSK) of white fungus, acrylamido propyl trimethyl ammonium chloride/acrylamide copolymer 0.04 Part, 0.05 part of hydroxypropyl guar hydroxypropyltrimonium chloride, 0.2 part of PPG-3 nutmegs alcohol ether, palmitamide propyl group front three 0.1 part of ammonium chloride, 0.4 part of isooctadecanol, mixture (ABIL Quat 3272) 0.4 part, month of quaternary ammonium salt -80 and propane diols 14 parts of laureth sodium sulfovinate, 14 parts of Cocoamidopropyl betaine, 0.2 part of glycerol monolaurate, sodium lauroyl sarcosine 2 Part, 0.04 part of disodium ethylene diamine tetraacetate, 0.005 part of citric acid, 60 parts of water, 0.07 part of preservative (MICROCARE CM), perfume 0.5 part of essence.

Embodiment 3

Different poly- 0.02 part of the polysaccharide (WSK) of white fungus, acrylamido propyl trimethyl ammonium chloride/acrylamide copolymer 0.06 Part, 0.15 part of hydroxypropyl guar hydroxypropyltrimonium chloride, 0.4 part of PPG-3 nutmegs alcohol ether, palmitamide propyl group front three 0.3 part of ammonium chloride, 0.6 part of isooctadecanol, mixture (ABIL Quat 3272) 0.6 part, month of quaternary ammonium salt -80 and propane diols 16 parts of laureth sodium sulfovinate, 16 parts of Cocoamidopropyl betaine, 0.4 part of glycerol monolaurate, sodium lauroyl sarcosine 4 Part, 0.06 part of disodium ethylene diamine tetraacetate, 0.015 part of citric acid, 70 parts of water, 0.09 part of preservative (MICROCARE CM), perfume 0.5 part of essence.

Embodiment 4

Dry and comfortable effect test

Experimental principle：When drop is freely in the space from field of force influence, it is in due to the presence of interfacial tension Spherical shape.But when drop is contacted with surface, its net shape is depending on the cohesive force and drop of drop internal are with consolidating The relative size of adhesion between body.When a drop is placed on surface, drop can be sprawled automatically in the surface of solids Come, or to exist with drop of the surface of solids into certain contact angle.Contact angle is reactive material and liquid wetting relation Key criteria, θ=90 ° can be used as wetting and non-wetted boundary, θ<Wettable, θ at 90 °>It is nonwetting at 90 °.

Test method 1：0.1% WSK, sodium hyaluronate solution, water are applied on glass plate respectively, at 80 DEG C Dried up under hot wind.The water of 5 μ L is dropped on the glass panel for scribbling WSK, aqueous solution of sodium hyaluronate and blank group respectively, from side Face is by microscope photographing, as shown in Figure 1：It can be seen that from attached drawing 1 relative to Sodium Hyaluronate, the drying that WSK is formed Film contact angle bigger, hydrophobicity are more excellent.

Test method 2：Impaired hair is immersed to the WSK, aqueous solution of sodium hyaluronate and pure water of 0.01% concentration respectively In (40 DEG C, 30min), then carry out 3min dryings respectively with hair dryer (about 80 DEG C).Measure damaged hair sample surfaces and drop Enter the contact angle between water droplet.

Specifically the test method of contact angle is：Connect using the XG-CAMB1 types of Shang Haixuan Yi Chuanxi Industrial Equipment Co., Ltd Feeler tester measures the contact angle after various processing between hair surface and pure water, and step is as follows：

1. test solution is prepared：The WSK and aqueous solution of sodium hyaluronate that 100ml mass concentrations are 0.01% are prepared respectively, and it is accurate The pure water of standby portion equivalent is spare as blank group.

2. the operation of contact angle tester：Take phase homogenous quantities damaged hair sample immerse respectively 0.01% concentration WSK, In aqueous solution of sodium hyaluronate and pure water, and 30min is kept the temperature at super thermostat (40 ± 1) DEG C, then with hair dryer (about 80 DEG C) 3min dryings are carried out respectively.Hair sample is separately fixed on the sample stage of XG-CAMB1 type contact angle testers (single Layer, tiling), turn injector feed liquor knob (gets about 2 μ l pure water), makes to form drop in the front end of injector syringe needle, by pin Droplet transfer on point is to sample surfaces.Click on the high order end, most right of drop with left mouse button in order on the picture of shooting End and top, contact angle is calculated using 3 Dian Liang supreme people's courts, and each sample is measured 5 times, is averaged respectively, as a result such as table 1 and figure Shown in 2.

Table 1 respectively handles back hair and pure water contact angle test result

On the basis of the contact angle of blank group (i.e. 100%), then the sample sets after Sodium Hyaluronate is handled are opposite contacts Angle is 105.9%, and the sample sets relative contact angle after WSK is handled is 114.0%, and 5.9% He has been respectively increased in contact angle 14%.Hydrophobic film that WSK formed on damaged hair is can be seen that to the hydrophobic of hair surface from the data in table 1 and Fig. 2 Property improvement clearly, this soft protective film causes moisture preferably to lock while on hair surface and keep dry It is refreshing, not glutinous greasy.

Embodiment 5

Moistening effect is tested

Test method 1：It is all 0.2% WSK, Sodium Hyaluronate, the aqueous solution of glycerine and blank by mass concentration respectively Group (pure water) 10g is dropped on same filter paper respectively to be absorbed, and is fixing 25 DEG C, filter paper is measured under 50% relative humidities Weight changes over time situation, as shown in Figure 3, from figure 3, it can be seen that relative to general common moisturizer (such as hyalomitome Sour sodium, glycerine etc.), the moisture-retaining capacity of WSK is more preferably under same concentrations.

Test method 2：0.2g WSK are dissolved in 100g water, the WSK solution of 0.2% concentration are configured to, after stirring evenly Filtered with filter paper, specific steps and the results are shown in Figure 4, it turns out that 500 times of water is completely absorbed, not over filter Paper, all stays in funnel, this explanation WSK has outstanding moisture-retaining capacity, can absorb and pin the water of itself 500 times of weight Point.

Embodiment 6

Foam volume, the experiment of foam stabilizing chronergy

Test method 1：The hair washing water sample and same recipe that are 0.01% by 1 formula ratio of embodiment configuration WSK contents but The blank sample for not adding WSK makees blank group, and above-mentioned two sample making is loaded compressing pump type blistering into 15% aqueous solution respectively In container, then the amount (about 1.4g) for pressing 7 times is placed in plate, observes the continuation of foam after foam height and 10min, As shown in figure 5, can be evident that from Fig. 5, compared with the sample for being not added with WSK, present invention hair washing water sample has more Plentiful foam volume and longer foam stabilizing time.

Test method 2：It is as follows using the blistering and foam stability energy, step of Roche foam meter test product：

1. test solution is prepared：The hair washing water sample that WSK contents are 0.01% is respectively configured by the formula ratio in embodiment 1~3 The blank sample for same recipe but not adding WSK makees blank group, weighs sample 2.5g respectively in 1000mL volumetric flasks, adds 900ml distilled water dissolves, and adds 1500mg/kg hard water 100ml, is heated to (40 ± 1) DEG C, and stirring makes sample uniform dissolution.

2. the operation of Roche foam meter：Super thermostat is preheated to (40 ± 1) DEG C, makes Roche foam meter constant temperature (40 ±1)℃.Funnel is quantified with 200ml and draws part test solution, is rinsed along foam meter wall pipe, is then taken test solution to be put into foam meter Bottom alignment master scale to 50ml, then with 200ml quantify funnel draw 200ml test solutions, fixed funnel center, make it with The cross section perpendicular of graded tube, ensures that test solution drips along graded tube center line, and bulb outlet is placed on 900mL graduation marks.Open ball Pipe piston, flows down test solution, when the test solution stream in bulb is complete, starts stopwatch immediately and records foam height, and it is high to be denoted as blistering Degree, foam height is denoted as foam stabilizing height after re-recording 5min.Take and (obtained twice in the range of allowable error under the conditions of repeatability The result of independent experiment twice between absolute difference be not more than 5mm) result average value as end product, as a result retain to Integer-bit, the results are shown in Table 2：

2 foam height of table and foam stabilizing height results

It can be seen that the addition of WSK from the data in table 2, make shampoo of the present invention that there is preferable blistering and foam stability Energy.

Embodiment 7

Foam sophistication effect test

Test method 1：The hair washing water sample and same recipe that are 0.01% by 1 formula ratio of embodiment configuration WSK contents but The blank sample for not adding WSK makees blank group, respectively by above-mentioned two sample making into 15% aqueous solution 100g, respectively using small Type blender, stirs 1min.Take identical quality foam to be applied to be observed on hand, as shown in fig. 6, from fig. 6, it can be seen that originally The foam of invention shampoo is finer and smoother.

Test method 2：The hair washing water sample and same recipe that are 0.01% by 1 formula ratio of embodiment configuration WSK contents but The blank sample for not adding WSK makees blank group, and above-mentioned two sample making is loaded compressing pump type blistering into 15% aqueous solution respectively In container.Then the amount (1g) of 5 times will be pressed, with (50 times) observations of microscope, the results are shown in Figure 7, can from Fig. 7 Go out, foam diameter is obviously reduced after adding 0.01%WSK, and sophistication improves more apparent.

Embodiment 8

Compliance and cardability effect test

Test method：

1. topknot pre-processes：By the topknot of the big topknot newly bought back processing growth 27cm, weight 20g, (hair ties end 3cm, hair Forge end 24cm).First with the water treatment that temperature is 40 DEG C, it is repeated twice, dries；Topknot is placed on equipped with ether When immersion 2 is small in 150gPET plastic bottles, after repetition is secondary, take out, drying；Hair is placed on equipped with 5g K12 and tap water 1000ml beakers in be heated to 80 DEG C, soak two hours, repeat secondary, rinsed with tap water, until non-foam, then natural Dry.

Topknot hair washing water process：4g hair washing water samples are weighed, the new topknot being placed in after processing, is washed and dressed with comb, equal to foam It is even, 5 minutes are stood, topknot is rinsed with tap water, until non-foam, naturally dry.

2. cardability is tested：

A, shampoo does cardability before and after the processing：Topknot is placed on 25 DEG C, the constant-temperature constant-humidity environment of 40%RH after pretreatment When drying 8 is small.Shampoo before processing is measured on 3343 section bar material experiment instruments of INSTRON and does cardability, draw speed is 1000mm/min。

B, shampoo wet cardability before and after the processing：Shampoo before and after the processing topknot in 25 DEG C, the constant temperature and humidity ring of 60%RH Border is tested.Measure shampoo wet cardability before and after the processing, stretching speed respectively on 3343 section bar material experiment instruments of INSTRON Spend for 1000mm/min.

3. carding force reduction degree formula calculates：Carding force reduction degree (%)=[carding force (the hair washing water process of blank sample Before) carding force of-hair washing water process sample]/blank sample carding force (shampoo before processing) × 100%, specific test knot Fruit is as shown in table 3:

The dry carding force of the present invention of table 3 reduces amplitude, wet carding force reduces amplitude data

	Embodiment 1	Embodiment 2	Embodiment 3	Blank group
					Dry carding force reduces amplitude/%	43.4	42.1	41.8	29.1
Wet carding force reduces amplitude/%	9.9	9.5	9.3	4.9

The quality of cardability is to judge an important indicator of shampoo quality, the measuring embodiment 1~3 and sky The shampoo organized in vain, does topknot, the reduction amplitude of wet carding force.It was found from the data in table 3：Displacement 50~150mm it Between, the sample comb power wet to topknot and dry comb power of adding 0.01%WSK have obvious improve (to improve shampoo to hair Cardability and compliance).

Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than the present invention is protected The limitation of scope is protected, although being explained in detail with reference to preferred embodiment to the present invention, those of ordinary skill in the art should Understand, can be to technical scheme technical scheme is modified or replaced equivalently, without departing from the essence of technical solution of the present invention And scope.

Claims

1. one kind is without silicone oil shampoo, it is characterised in that the shampoo includes Tremella fructification extract.

2. as claimed in claim 1 without silicone oil shampoo, it is characterised in that the Tremella fructification extract is in the hair washing Mass percentage in water is 0.005~0.02%.

3. as claimed in claim 2 without silicone oil shampoo, it is characterised in that the Tremella fructification extract is in the hair washing Mass percentage in water is 0.01%.

4. as claimed in claim 1 without silicone oil shampoo, it is characterised in that the Tremella fructification extract is different poly- for white fungus Polysaccharide.

5. if Claims 1 to 4 any one of them is without silicone oil shampoo, it is characterised in that also include the tune of following parts by weight Manage agent：Acrylamido propyl trimethyl ammonium chloride/0.04~0.06 part of acrylamide copolymer, hydroxypropyl melon glue hydroxypropyl three 0.05~0.15 part of ammonio methacrylate, 0.2~0.4 part of PPG-3 nutmegs alcohol ether, palmitamide hydroxypropyltrimonium chloride 0.1 ~0.3 part, 0.4~0.6 part of isooctadecanol, 0.4~0.6 part of the mixture of quaternary ammonium salt -80 and propane diols.

6. as claimed in claim 5 without silicone oil shampoo, it is characterised in that also include the conditioner of following parts by weight：Propylene 0.05 part of amidopropyltrimonium chloride/acrylamide copolymer, hydroxypropyl guar hydroxypropyltrimonium chloride 0.1 Part, 0.3 part of PPG-3 nutmegs alcohol ether, 0.2 part of palmitamide hydroxypropyltrimonium chloride, 0.5 part of isooctadecanol, quaternary ammonium salt -80 With 0.5 part of the mixture of propane diols.

7. as claimed in claim 1 without silicone oil shampoo, it is characterised in that also include the surfactant of following parts by weight： 14~16 parts of laureth sodium sulfovinate, 14~16 parts of Cocoamidopropyl betaine, 0.2~0.4 part of glycerol monolaurate, 2~4 parts of sodium lauroyl sarcosine.

8. as claimed in claim 7 without silicone oil shampoo, it is characterised in that also include the surfactant of following parts by weight： 15 parts of laureth sodium sulfovinate, 15 parts of Cocoamidopropyl betaine, 0.3 part of glycerol monolaurate, Hamposyl L 3 parts of sodium.

9. as claimed in claim 1 without silicone oil shampoo, it is characterised in that also include the component of following parts by weight：Ethylenediamine 0.04~0.06 part of tetraacethyl disodium, 0.005~0.015 part of citric acid, 60~70 parts of water.

10. as claimed in claim 1 without silicone oil shampoo, it is characterised in that also include the anti-corrosion of 0.07~0.09 parts by weight Agent, the preservative are methylchloroisothiazandnone and the mixture of methylisothiazolinone.