CN106673438A - Magic star stone glazed brick with surface aventurine effect and preparation method thereof - Google Patents
Magic star stone glazed brick with surface aventurine effect and preparation method thereof Download PDFInfo
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- CN106673438A CN106673438A CN201611231019.2A CN201611231019A CN106673438A CN 106673438 A CN106673438 A CN 106673438A CN 201611231019 A CN201611231019 A CN 201611231019A CN 106673438 A CN106673438 A CN 106673438A
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- glaze
- coat enamel
- cover
- frit
- phlogopite
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/963—Surface properties, e.g. surface roughness
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Glass Compositions (AREA)
Abstract
The invention relates to a magic star stone glazed brick with surface aventurine effect, and provides a magic star stone glazed brick with surface aventurine effect and a preparation method thereof. The magic star stone glazed brick comprises a frit, a surface glaze and a gold mica sheet slurry. The magic star stone glazed brick has the advantages that on the basis of not performing major change on the production technology of the existing glazed brick, the formula composition of the frit, the formula composition of the surface glaze, the formula composition of the gold mica sheet slurry, the optimum selection of granularity of gold mica sheet, the glaze applying technique, the slurry applying technique and the like are adjusted and optimized, so that the surface of the prepared magic star stone glazed brick is matte, and the luster of the surface of the product is measured by a WGG60-E4 luster meter and is 8 to 12; under the light radiation condition, the gold mica sheet at the surface of the product, such as mica or hematite small sheets in the aventurine, is glittering, magic and elegant, so that the special decorativeness and artistry are realized; the technique has higher universality, and is suitable for being popularized in industry.
Description
Technical field：
The present invention relates to the preparing technical field of glazed tile, referring in particular to a kind of surface has the unreal star stone glaze paint of gold dust effect
Brick and preparation method thereof.
Background technology：
Currently, indoor light has become key factor very important during modern house is decorated, rational Lighting Design
The effect of decoration can be effectively improved, as apt word added to clinch the point, but light glazed tile has stronger reflecting effect to light, can
Lighting effect in enhanced room, but, this effect can substantially reduce the pattern decorative effect of glazed tile, and common matt glaze paint
The pattern of brick is single, and brick body poor surface smoothness, the reflecting effect to light is poor, the sensation for giving people than milder and comfortable, but,
This causes that the decorative effect of light loses smart.And a kind of aventurine such as gold dust quartz, gold dust feldspar etc., because containing mica or red
Iron ore small pieces, can put a little glittering and glisten under light illumination, be used to make precious jewelry, ornament, art work etc., and price is held high
It is expensive, therefore if this surface is developed in the Wall or floor tile technology of mass automatic production as aventurine in light irradiation
It is lower can the point glittering reflective unreal star stone glaze paint brick product of point, by the auxiliary patch of common Wall or floor tile, and coordinate the design of indoor light,
Will necessarily make at home take on an entirely new look, elegant, hold wherein, the world as entered a children's stories.
The content of the invention：
It is an object of the invention to overcome disadvantages mentioned above, there is provided a kind of surface have aventurine effect unreal star stone glazed tile and
Its preparation method, on the basis of great change is not made to existing glazed tile production technology, by the formula group to frit
The formula composition of formula composition, phlogopite piece slurry into, cover-coat enamel and glazing, the adjustment of sizing technique and optimization, so that being obtained
Glazed tile product surface seem into unglazed shape, but the mica or bloodstone in the phlogopite piece such as aventurine on surface under light illumination
Small pieces can be put a little glittering reflective, and like a dream, elegant, and glaze quality is good, corrosion resistance and resistance to soiling is strong, abrasion resistance
The defects such as high, pin-free, glaze bubble；The technology possesses stronger universality simultaneously, it is easy in industry promote.
In order to solve the above technical problems, the present invention is achieved through the following technical solutions：
There is the unreal star stone glazed tile of aventurine effect on a kind of surface of the invention, and it includes：
Frit：Prepared by following weight percent composition：
SiO263%~64%, Al2O37.4%~8.2%, CaO 9.4%~10.2%, MgO 1.6%~2.4%,
K2O 3.6%~4.2%, Na2O 1.6%~2.2%, TiO20.8%~1.4%, ZnO 3%~4%, ZrO24%~
5%, SrO 0.4%~0.8%, B2O33.1%~3.9%, all of component sum is 100%；
Cover-coat enamel：Prepared by following weight percent composition：
SiO238.5%~40.5%, Al2O315%~17%, CaO 8.5%~10.5%, MgO 3%~4%,
K2O 1.5%~2.5%, Na2O 0.5%~0.9%, TiO20.5%~0.9%, ZrO27%~9%, B2O31.8%~
2.4%, BaO 2%~3%, ZnO 9.2%~11.2%, SrO 0.5%~0.9%, burning decrement 4.5%~6.5%, institute
Some component sums are 100%；
Added weight percentage is 0.5%~0.9% auxiliary material, and additional auxiliary material therein includes carboxymethyl
Cellulose and sodium tripolyphosphate；The glaze volume of the cover-coat enamel weighs 720~880g/ ㎡ for aqueous glaze slip；The cover-coat enamel composition
SiO2/Al2O3The ratio of mol ratio is 4~4.4, and the surface gloss that high temperature burns till glaze below is 8~12, is seen under magnifying glass
Glaze paint is observed while separating out anorthite, baryta fledspar, mullite microcrystal；
Phlogopite piece is starched：Prepared by following parts by weight of component：
0.6~1.2 part of phlogopite piece, 0.4~1 part of carboxymethylcellulose calcium, 0.2~0.6 part of polyvinyl alcohol, 100 parts of water；Its
In phlogopite piece granularity be 60~120 mesh；The sizing amount of described phlogopite piece slurry weighs 44~55g/ ㎡ for aqueous wet pulp.
There is the preparation method of the unreal star stone glazed tile of gold dust effect the invention further relates to a kind of surface, it includes following step
Suddenly：
The preparation of A, frit：
The percentage by weight of the component of frit is：
SiO263%~64%, Al2O37.4%~8.2%, CaO 9.4%~10.2%, MgO 1.6%~2.4%,
K2O 3.6%~4.2%, Na2O 1.6%~2.2%, TiO20.8%~1.4%, ZnO 3%~4%, ZrO24%~
5%, SrO 0.4%~0.8%, B2O33.1%~3.9%, all of component sum is 100%；
Granularity containing said components is respectively less than the raw material of 150 mesh：Silica flour, feldspar powder, alumina powder, calcium carbonate, talcum
Powder, titanium dioxide, zinc oxide, zirconium English powder, strontium carbonate, potassium carbonate, sodium carbonate and boric acid, according to said components scope dispensing, mix
The mixing of conjunction machine, frit tank furnace are founded, 1500 DEG C~1520 DEG C of the temperature range founded, and then into frit granules, drying is for water quenching
Obtain frit；
The preparation of B, cover-coat enamel：
The percentage by weight of the component of cover-coat enamel is：
SiO238.5%~40.5%, Al2O315%~17%, CaO 8.5%~10.5%, MgO 3%~4%,
K2O 1.5%~2.5%, Na2O 0.5%~0.9%, TiO20.5%~0.9%, ZrO27%~9%, B2O31.8%~
2.4%, BaO 2%~3%, ZnO 9.2%~11.2%, SrO 0.5%~0.9%, burning decrement 4.5%~6.5%, institute
Some component sums are 100%；
By the weight percent content of above-mentioned cover-coat enamel component, choose frit that the above-mentioned steps A of corresponding proportion prepares,
Feldspar powder, silica flour, alumina powder, calcium carbonate, burning talcum, kaolin, zirconium silicate, zinc oxide, strontium carbonate, barium carbonate, titanium white
Powder, Firebrake ZB and additional auxiliary material 0.5%~0.9%, add appropriate water through ball milling it is in small, broken bits into fineness be 325 mesh sieves
To tail over be mass percent 0.3%~0.6%, containing the glaze slip that mass percent is 28%~30% moisture, sieved through except iron
Obtain final product cover-coat enamel；Additional auxiliary material therein includes carboxymethylcellulose calcium and sodium tripolyphosphate；The SiO of described cover-coat enamel composition2/
Al2O3The ratio of mol ratio is 4~4.4；
The preparation of C, phlogopite piece slurry, prepares by weight：
By 100 parts of water, 0.6~1.2 part of additional phlogopite piece, 0.4~1 part of carboxymethylcellulose calcium, polyvinyl alcohol 0.2~
0.6 part, mixing and stirring obtains final product phlogopite piece slurry；The granularity of phlogopite piece therein is 60~120 mesh；
D, the preparation of product and burn till：
On the glazed tile base substrate for normally having applied ground-coat enamel, the cover-coat enamel that above-mentioned steps B is prepared, the glaze volume of cover-coat enamel are first applied
It is 720~880g/ ㎡, described glaze volume is aqueous glaze slip weight, then by stamp, then is sprayed phlogopite piece slurry with spray gun
On the adobe body for having printed flower, the sizing amount of phlogopite piece slurry is 44~55g/ ㎡, and described sizing amount is aqueous wet pulp weight, so
Afterwards by applying prime cement, roller kilns glaze firing is entered back into, maximum sintering temperature scope is 1115 DEG C~1135 DEG C, and firing time scope is
40~70 minutes, by edging, get product；The surface gloss that high temperature burns till glaze below is 8~12, is amplifying Microscopic observation
Anorthite, baryta fledspar, mullite microcrystal are separated out to glaze paint simultaneously.
The glazed tile that there is unreal star stone glazed tile of aventurine effect and preparation method thereof, manufacture on a kind of surface of the invention is produced
Product surface seems into unglazed shape, and the glossiness for measuring product surface with WGG60-E4 Grossmeters is 8~12, but under light illumination,
Mica or bloodstone small pieces in the phlogopite piece such as aventurine on surface can put it is a little glittering reflective, like a dream, elegant, tool
There are the dicoration and artistry of uniqueness, while the technology possesses stronger universality, it is easy in industry promote.
There is unreal star stone glazed tile of aventurine effect and preparation method thereof on surface of the invention, is constituted by frit formula
The optimization constituted with cover-coat enamel formula, on the one hand ensure that cover-coat enamel has low glossiness after burning till, so that guarantee fund's mica sheet
Can put under light illumination a little glittering reflective, if glossiness of the cover-coat enamel after burning till is too high, under light illumination, the reflective of cover-coat enamel can subtract
Reflecting effect weak or even that phlogopite piece can be covered, through the present inventor's research find cover-coat enamel burn till after glossiness control 8~
12 are advisable, therefore SiO in cover-coat enamel composition2/Al2O3Mol ratio is extremely important, should control 4~4.4：1, because from ternary phase diagrams
In as can be seen that SiO2/Al2O3The ratio of mol ratio is that the glaze composition between 4~4.4 is the mat glaze fallen in high-aluminum low-silicon
Region, and the region because separate out feldspar microcrystal be presented unglazed, such as anorthite, baryta fledspar, while the region also generates
Mullite, wollastonite crystallite and make glaze paint present it is unglazed, through the present inventor study find, cover-coat enamel of the invention glaze table after burning till
Face separates out anorthite, baryta fledspar and mullite microcrystal simultaneously, so that cover-coat enamel is presented 8~12 low-luster, ensure that
Phlogopite piece can put a little glittering reflective special-effect under light illumination；On the other hand, glaze melt body of the cover-coat enamel in high temperature will also have
Suitable viscosity, so as to ensure that the surface quality of product, such as anti-pollution characteristic, and to the cementability of phlogopite piece.Such as
The viscosity of fruit glaze melt body is too high, gas can be caused to discharge difficult, makes glaze paint coarse, and the defects such as pin hole, glaze bubble occurs, so that shadow
Ring the surface quality and durability against pollution of product, meanwhile, phlogopite piece bonding not enough firmly, post-production or when using it is easy to fall off；
If the viscosity of glaze melt body is too low, phlogopite piece can completely be melted in high temperature, so as to lose the laminated structure of phlogopite piece
Even combined together with cover-coat enamel completely, so as to weaken or lose the glittering reflective effect of point under illumination completely.Therefore in frit
And with the addition of and glaze melt body viscosity is played regulatory role and to anorthite, baryta fledspar, mullite crystallization in right amount in cover-coat enamel formula composition
Favorable MgO, TiO2、ZnO、ZrO2、SrO、B2O3、Al2O3Deng oxide；Further, since phlogopite piece burns in high temperature
Into when easily aoxidize and blackening, therefore the Firebrake ZB of appropriate antioxidation is also added in cover-coat enamel formula, and control
Suitable burning decrement in cover-coat enamel composition, it is ensured that phlogopite piece is not oxidized in high temperature burns till.The formula group of phlogopite piece slurry
Into with glazing, the optimization of sizing technique, on the one hand ensure that the bonding force of the glaze base substrate after phlogopite piece and printing ornament, will not
Because the effect of kiln hood drifting dust blower fan and smoking blower fan is blown off or is taken away, on the other hand ensure that phlogopite piece being capable of uniform monolithic
Be distributed in glaze surface, otherwise can because local multi-disc simultaneously cloth on cover-coat enamel surface, when high temperature burns till, the golden cloud of bottom can be caused
Master slice is aoxidized and blackening, and the phlogopite piece on top is Nian Jie with cover-coat enamel bad, is easily dropped；Phlogopite is additionally ensured that
Piece will not be affected blackening because the organic matter in methylcellulose, polyvinyl alcohol and printing glaze composition is aoxidized in high temperature.
A kind of surface of the invention has unreal star stone glazed tile of aventurine effect and preparation method thereof to have the following advantages：
1st, due to optimize the composition of cover-coat enamel frit, the formula composition of cover-coat enamel, the formula composition of phlogopite piece slurry, glazing and
Adjustment and optimization of sizing technique etc., so that the product surface of manufacture is presented the effect such as aventurine, under light illumination, surface
Phlogopite piece can put a little glittering and glisten, like a dream, elegant, with unique dicoration and artistry.
2nd, the product surface flatness, the modulus of rupture, rupture strength, resistance to acids and bases, wearability, thermal shock resistance, radioactivity,
Lead-indium alloy reaches the requirement of GB/T4100-2015, GB6566-2011 and HJ/T297-2006 standard.
3rd, the product uses existing glazed tile production technology, makes to put glittering and glisten under the distinctive illumination of aventurine
Effect be able to copy on glaze paint brick product, it is easy to accomplish industrialized scale.
Brief description of the drawings：
Fig. 1 is the process chart for preparing the unreal star stone glazed tile that there is gold dust effect on a kind of surface of the invention.
Specific embodiment：
The present invention is described in further detail with reference to embodiment.
Embodiment 1：
There is the preparation method of the unreal star stone glazed tile of aventurine effect on a kind of surface, and it is comprised the following steps：
A, prepare frit：
The chemical composition composition such as table 1 below of frit：
The chemical composition table (percentage by weight, %) of table 1, frit
| Component | SiO2 | Al2O3 | CaO | MgO | K2O | Na2O | TiO2 | Zn0 | ZrO2 | SrO | B2O3 |
| 1# | 63 | 8.2 | 9.8 | 1.6 | 3.9 | 1.7 | 0.8 | 3 | 4 | 0.4 | 3.6 |
| 2# | 63.5 | 7.4 | 9.6 | 2 | 3.7 | 1.6 | 0.8 | 3 | 4.5 | 0.4 | 3.5 |
| 3# | 63 | 7.4 | 9.4 | 1.8 | 3.6 | 1.8 | 1 | 3.5 | 4 | 0.6 | 3.9 |
| 4# | 64 | 7.8 | 9.4 | 1.6 | 3.6 | 1.6 | 1.1 | 3 | 4 | 0.5 | 3.4 |
| 5# | 63 | 7.4 | 10.2 | 1.6 | 3.6 | 2.2 | 0.8 | 3.1 | 4.2 | 0.4 | 3.5 |
| 6# | 63 | 7.4 | 9.4 | 2.4 | 4.2 | 1.9 | 0.8 | 3 | 4 | 0.8 | 3.1 |
| 7# | 63 | 7.4 | 9.4 | 1.6 | 3.6 | 1.6 | 1.4 | 4 | 4.5 | 0.4 | 3.1 |
| 8# | 63.1 | 7.5 | 9.5 | 1.6 | 3.6 | 1.6 | 0.9 | 3.5 | 5 | 0.5 | 3.2 |
Prepare frit：The granularity for choosing corresponding proportion by the chemical composition of table 1 is respectively less than the silica flour of 150 mesh, length
Stone flour, alumina powder, calcium carbonate, talcum powder, titanium dioxide, zinc oxide, zirconium English powder, strontium carbonate, potassium carbonate, sodium carbonate, boric acid are former
Material, carries out dispensing, mixes in mixer, is founded in frit tank furnace, 1500 DEG C of glass melting temperature scope~1520 DEG C, Ran Houshui
Quench into frit granules drying frit；
B, prepare cover-coat enamel：
The chemical composition of cover-coat enamel such as table 2 below：
The chemical composition table (percentage by weight, %) of table 2, cover-coat enamel
Prepare cover-coat enamel：Frit, length that the above-mentioned steps A of corresponding proportion is prepared are chosen by the chemical composition of table 2
Stone flour, silica flour, alumina powder, calcium carbonate, burn talcum, kaolin, zirconium silicate, zinc oxide, strontium carbonate, barium carbonate, titanium dioxide,
Firebrake ZB and the auxiliary material that added weight percentage is 0.5%~0.9% carry out dispensing；Appropriate water is added through ball milling
In small, broken bits is mass percent 0.3%~0.6% for 325 mesh sieves are tailed over into fineness, containing the water that mass percent is 28%~30%
Point glaze slip, through except iron sieving storage, to obtain final product cover-coat enamel standby；Additional auxiliary material therein includes carboxymethylcellulose calcium and three
Polyphosphate sodium；The SiO of described cover-coat enamel composition2/Al2O3The ratio of mol ratio is 4~4.4；
C, prepare phlogopite piece slurry：
The formula constituent such as table 3 below of phlogopite piece slurry：
The formula constituent table (weight portion) of table 3, phlogopite piece slurry
| Component | Phlogopite piece | Carboxymethylcellulose calcium | Polyvinyl alcohol | Water |
| 1# | 0.6 | 1 | 0.2 | 100 |
| 2# | 0.9 | 0.7 | 0.4 | 100 |
| 3# | 1.2 | 0.4 | 0.6 | 100 |
Prepare phlogopite piece slurry：The formula composition starched by the phlogopite piece of table 3 weighs phlogopite piece, carboxymethylcellulose calcium, gathers
Vinyl alcohol, water, be mixed together stir obtain final product phlogopite piece slurry it is standby；The granularity of phlogopite piece therein is 60~120 mesh；
D, prepare product：
Apply the cover-coat enamel that above-mentioned steps are prepared on the adobe surface for normally having applied ground-coat enamel, the glaze volume of cover-coat enamel for 720~
880g/ ㎡, described glaze volume is aqueous glaze slip weight, needs to be entered with silk-screen plate or offset printing roller or ink jet printer further according to product design
Row printing ornament, then sprayed in the adobe of printing ornament phlogopite piece slurry with spray gun, the sizing amount of phlogopite piece slurry is 44
~55g/ ㎡, described sizing amount is aqueous wet pulp weight, then by applying prime cement, enters back into roller kilns glaze firing, and highest burns till temperature
Degree scope is 1115 DEG C~1135 DEG C, and firing time scope is 40~70 minutes, by edging, last finished product；High temperature burns
Surface gloss into glaze below is 8~12, observes that glaze paint separates out anorthite, baryta fledspar, mullite simultaneously under magnifying glass
Microcrystal.
The present invention has the preparation method of the unreal star stone glazed tile of aventurine effect by a kind of above-mentioned surface, prepares
Unreal star stone glaze paint brick product, glaze paint is seemed in unglazed shape, with WGG60-E4 Grossmeters measure product surface glossiness be 8~
12, but under light illumination, mica or bloodstone small pieces in the phlogopite piece such as aventurine on surface can be put a little glittering and glisten, such as dream
Like unreal, elegant, with unique dicoration and artistry, product indices such as table 4 below after testing：
Table 4：Product quality inspection result
In sum, only presently preferred embodiments of the present invention, not makees any formal limitation to the present invention；It is all
The those of ordinary skill of the industry can swimmingly be implemented the present invention by the above；But it is all to be familiar with this professional technology people
Member without departing from the scope of the present invention, a little change for being made using disclosed above technology contents, repaiies
Decorations and the equivalent variations for developing, are Equivalent embodiments of the invention；Meanwhile, it is all real to more than according to substantial technological of the invention
Apply any equivalent variations that example is made change, modification with develop, still fall within technical scheme protection domain it
It is interior.
Claims (2)
1. there is the unreal star stone glazed tile of aventurine effect on a kind of surface, it is characterised in that：
Frit：Prepared by following weight percent composition：
SiO263%~64%, Al2O37.4%~8.2%, CaO 9.4%~10.2%, MgO 1.6%~2.4%, K2O
3.6%~4.2%, Na2O 1.6%~2.2%, TiO20.8%~1.4%, ZnO 3%~4%, ZrO24%~5%,
SrO 0.4%~0.8%, B2O33.1%~3.9%, all of component sum is 100%；
Cover-coat enamel：Prepared by following weight percent composition：
SiO238.5%~40.5%, Al2O315%~17%, CaO 8.5%~10.5%, MgO 3%~4%, K2O
1.5%~2.5%, Na2O 0.5%~0.9%, TiO20.5%~0.9%, ZrO27%~9%, B2O31.8%~
2.4%, BaO 2%~3%, ZnO 9.2%~11.2%, SrO 0.5%~0.9%, burning decrement 4.5%~6.5%, institute
Some component sums are 100%；
Added weight percentage is 0.5%~0.9% auxiliary material, and additional auxiliary material therein includes carboxymethyl cellulose
Element and sodium tripolyphosphate；The glaze volume of the cover-coat enamel weighs 720~880g/ ㎡, the SiO of the cover-coat enamel composition for aqueous glaze slip2/
Al2O3The ratio of mol ratio is 4~4.4, and the surface gloss that high temperature burns till glaze below is 8~12, is amplifying Microscopic observation glaze paint
Anorthite, baryta fledspar, mullite microcrystal are separated out simultaneously.
Phlogopite piece is starched, and is prepared by following parts by weight of component：
0.6~1.2 part of phlogopite piece, 0.4~1 part of carboxymethylcellulose calcium, 0.2~0.6 part of polyvinyl alcohol, 100 parts of water；It is therein
Phlogopite piece granularity is 60~120 mesh；The sizing amount of described phlogopite piece slurry weighs 44~55g/ ㎡ for aqueous wet pulp.
2. there is the preparation method of the unreal star stone glazed tile of aventurine effect on a kind of surface, it is characterised in that：
It is comprised the following steps：
The preparation of A, frit：
The percentage by weight of the component of frit is：
SiO263%~64%, Al2O37.4%~8.2%, CaO 9.4%~10.2%, MgO 1.6%~2.4%, K2O
3.6%~4.2%, Na2O 1.6%~2.2%, TiO20.8%~1.4%, ZnO 3%~4%, ZrO24%~5%,
SrO 0.4%~0.8%, B2O33.1%~3.9%, all of component sum is 100%；
Granularity containing said components is respectively less than the raw material of 150 mesh：Silica flour, feldspar powder, alumina powder, calcium carbonate, talcum powder, titanium
White powder, zinc oxide, zirconium English powder, strontium carbonate, potassium carbonate, sodium carbonate and boric acid, mix according to said components scope dispensing, mixer
Close, frit tank furnace is founded, 1500 DEG C~1520 DEG C of the temperature range founded, then water quenching is into frit granules, drying frit；
The preparation of B, cover-coat enamel：
The percentage by weight of the component of cover-coat enamel is：
SiO238.5%~40.5%, Al2O315%~17%, CaO 8.5%~10.5%, MgO 3%~4%, K2O
1.5%~2.5%, Na2O 0.5%~0.9%, TiO20.5%~0.9%, ZrO27%~9%, B2O31.8%~
2.4%, BaO 2%~3%, ZnO 9.2%~11.2%, SrO 0.5%~0.9%, burning decrement 4.5%~6.5%, institute
Some component sums are 100%；
By the weight percent content of above-mentioned cover-coat enamel component, frit, feldspar that the above-mentioned steps A of corresponding proportion is prepared are chosen
Powder, silica flour, alumina powder, calcium carbonate, burning talcum, kaolin, zirconium silicate, zinc oxide, strontium carbonate, barium carbonate, titanium dioxide, boron
Sour zinc and the auxiliary material that added weight percentage is 0.5%~0.9%, add appropriate water in small, broken bits into fineness through ball milling
It is tailing over for mass percent 0.3%~0.6% and containing the glaze slip that mass percent is 28%~30% moisture for 325 mesh sieves,
Cover-coat enamel is obtained final product through except iron sieving；Additional auxiliary material therein includes carboxymethylcellulose calcium and sodium tripolyphosphate；Described face
The SiO of glaze composition2/Al2O3The ratio of mol ratio is 4~4.4；
The preparation of C, phlogopite piece slurry, prepares by weight：
By 100 parts of water, 0.6~1.2 part of additional phlogopite piece, 0.4~1 part of carboxymethylcellulose calcium, 0.2~0.6 part of polyvinyl alcohol,
Mixing and stirring obtains final product phlogopite piece slurry；The granularity of phlogopite piece therein is 60~120 mesh；
D, the preparation of product and burn till：
On the glazed tile base substrate for normally having applied ground-coat enamel, the cover-coat enamel that above-mentioned steps B is prepared first is applied, the glaze volume of cover-coat enamel is
720~880g/ ㎡, described glaze volume is aqueous glaze slip weight, then by stamp, then is sprayed phlogopite piece slurry with spray gun
Print on the adobe body of flower, the sizing amount of phlogopite piece slurry is 44~55g/ ㎡, and described sizing amount is aqueous wet pulp weight, then
By applying prime cement, roller kilns glaze firing is entered back into, maximum sintering temperature scope is 1115 DEG C~1135 DEG C, and firing time scope is 40
~70 minutes, by edging, get product；The surface gloss that high temperature burns till glaze below is 8~12, is amplifying Microscopic observation glaze
Face separates out anorthite, baryta fledspar, mullite microcrystal simultaneously.
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