CN105924229A - Glaze for thousand-bead multi-color glazed tile and thousand-bead multi-color glazed tile, and preparation methods thereof - Google Patents
Glaze for thousand-bead multi-color glazed tile and thousand-bead multi-color glazed tile, and preparation methods thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
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- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/10—Frit compositions, i.e. in a powdered or comminuted form containing lead
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
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- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
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Abstract
The invention provides a glaze for a thousand-bead multi-color glazed tile and the thousand-bead multi-color glazed tile, and preparation methods thereof. On the basis of no significant improvement of conventional production processes for glazed tiles, the methods optimize the selection of the variety of a biscuit, the selection and proportioning of frits with different properties in a cover glaze and selection of the granularity of diamond grit glaze particles, adjust the composition of frits of a ground glaze, the cover glaze, a pearlescent multi-color printing glaze and diamond grit glaze particles, the formula composition of the ground glaze, cover glaze, the pearlescent multi-color printing glaze and the diamond grit glaze particles, and adjust and optimize glazing parameters and printing process. Thus, under the irradiation of light or oblique light, the surface of a produced glazed tile product emits glittering starlight as broken diamond grit does and gives out attracting rays of light as pearls do; and the color of a pattern on the pearlescent multi-color printing glaze varies with the angle of light under the dual action of reflection and refraction of the diamond grit glaze particles and the pearlescent multi-color printing glaze, as if peals are inlaid in the surface of the glazed tile, so unique visual effect is presented.
Description
Technical field:
The present invention relates to the preparing technical field of glazed tile, particularly for the glaze of thousand pearl illusion-colour glazed tiles
With preparation method and thousand pearl illusion-colour glazed tile and preparation methoies.
Background technology:
Glazed tile is a big class in Ceramic Tiles family, and due to it, to have rich color, molding surface many
The advantages such as change so that it is serve as particularly important role in house fitting-up.In recent years, along with ink-jet
Printing technique application on ceramic decoration, accelerates the renewal of glazed tile incrustation pattern, and design
The most convenient, but it is confined to single plane pattern decoration.Along with constantly carrying of people's living standard
Height, tends to dicoration and artistry to the ornament materials of household from original practicality, therefore uses
The glazed tile product of single inkjet technology exploitation is difficult to meet the demand in market.
Summary of the invention:
It is an object of the invention to overcome disadvantages mentioned above, it is provided that glaze, brick and the system thereof of thousand pearl illusion-colour glazed tiles
Preparation Method, on the basis of not production technology to existing glazed tile makes great change, emphasis is to biscuit
Preferred, ground-coat enamel, the cover-coat enamel of body kind, Margarita illusion-colour screen printing glaze and bore sand glaze grain slurry frit composition,
Preferred and the proportioning of different performance frit, the formula composition of ground-coat enamel, the formula composition of cover-coat enamel, treasure in cover-coat enamel
The formula of pearl illusion-colour screen printing glaze forms, the formula preferred, brill sand glaze grain slurry of brill sand glaze grain granularity forms,
Glazing process parameter and the adjustment of printing technology and optimization, so that the brill sand glaze grain of preparation and Margarita illusion-colour
Screen printing glaze occurs that such as broken brill sand shape twinkLing stars light and Margarita gem send sudden strain of a muscle under light or skew ray irradiate
Shine tempting radiance, and the pattern color that spray printing is on Margarita illusion-colour screen printing glaze, boring sand glaze grain and Margarita
Under the reflection of illusion-colour screen printing glaze and refraction dual function, special color changeable effect occurs as variable color paper, imitative
One grain Margarita cameo incrustation of Buddhist is on brick face.This technological break-through traditional decoration theory, visual effect is non-
Chang Dute, so that product has dicoration and the artistry of uniqueness；This technology possesses stronger general simultaneously
Adaptive, it is easy in industry promote.
For solving the problems referred to above, the present invention is achieved through the following technical solutions:
The present invention relates to a kind of glaze for preparing thousand pearl illusion-colour glazed tiles, it includes ground-coat enamel, cover-coat enamel, treasure
Pearl illusion-colour screen printing glaze and brill sand glaze grain slurry；
Ground-coat enamel: configure by following parts by weight of component:
Frit a 12～22 parts, lithium porcelain stone powder 26～32 parts, alumina powder 2～8 parts, burn Talcum 5～
11 parts, Zirconium orthosilicate. 4～10 parts, silica flour 22～28 parts, Kaolin 13～21 parts, carboxymethyl fibre
Dimension element 0.07～0.12 part, sodium tripolyphosphate 0.3～0.8 part and water 37～45 parts；
Cover-coat enamel: configure by following parts by weight of component:
Frit a 40～50 parts, frit b 5～15 parts, Zirconium orthosilicate. 5～9 parts, Kaolin 15～25
Part, feldspar powder 6～12 parts, alumina powder 4～8 parts, carboxymethyl cellulose 0.06～0.09 part,
Sodium tripolyphosphate 0.3～0.8 part and water 37～45 parts；
Margarita illusion-colour screen printing glaze: configure by following parts by weight of component:
Frit c 95～99 parts, zinc oxide 0.5～3.5 parts, cerium oxide 0.5～1.5 parts and pottery
Glue roller squeegee oil 80～160 parts；
Bore sand glaze grain slurry: configure by following parts by weight of component:
Frit d grain 30～40 parts and pottery glue roller squeegee oil 60～70 parts；
Wherein said frit a is configured by following parts by weight of component:
Feldspar powder 8～14 parts, calcium carbonate 23～29 parts, zirconium English powder 6～10 parts, zinc oxide 7～13
Part, Pulvis Talci 8～12 parts, titanium dioxide 2～6 parts, potassium carbonate 3～5 parts, silica flour 30～40
Part；
Wherein said frit b is configured by following parts by weight of component:
Feldspar powder 16～24 parts, calcium carbonate 11～19 parts, boric acid 4～8 parts, Pulvis Talci 3～7 parts,
Zirconium English powder 11～17 parts, zinc oxide 8～12 parts, potassium carbonate 1～3 parts, Borax 2～6 parts, stone
English powder 20～28 parts；
Wherein said frit c is configured by following parts by weight of component:
Feldspar powder 30～38 parts, calcium carbonate 15～19 parts, boric acid 1～3 parts, potassium nitrate 0.5～2.5
Part, spodumene powder 1～3 parts, brium carbonate 0.5～2.5 parts, zinc oxide 2～6 parts, red lead powder 0.5～
4.5 parts, silica flour 28～36 parts；
Wherein said frit d grain is configured by following parts by weight of component:
Feldspar powder 12～20 parts, calcium carbonate 10～16 parts, boric acid 8～12 parts, zirconium English powder 12～18
Part, potassium nitrate 3～5 parts, zinc oxide 8～12 parts, titanium dioxide 3～5 parts, silica flour 26～34
Part.
The invention still further relates to the preparation method of a kind of glaze for preparing thousand pearl illusion-colour glazed tiles, it include with
Lower step:
A, the preparation of ground-coat enamel, prepare by weight:
By frit a 12～22 parts, lithium porcelain stone powder 26～32 parts, alumina powder 2～8 parts, burn Talcum
5～11 parts, Zirconium orthosilicate. 4～10 parts, silica flour 22～28 parts, Kaolin 13～21 parts, carboxylic first
Base cellulose 0.07～0.12 part, sodium tripolyphosphate 0.3～0.8 part and water 37～45 parts mix together
Close and wear into the glaze slip for mass percent 0.2%～0.4% that tails over that fineness is 325 mesh sieves, cross and screen out ferrum i.e.
Obtain ground-coat enamel；
B, the preparation of cover-coat enamel, prepare by weight:
By frit a 40～50 parts, frit b 5～15 parts, Zirconium orthosilicate. 5～9 parts, Kaolin 15～
25 parts, feldspar powder 6～12 parts, alumina powder 4～8 parts, carboxymethyl cellulose 0.06～0.09 part,
Sodium tripolyphosphate 0.3～0.8 part and water 37～45 parts are mixed together and wear into fineness is 325 mesh sieves
Tailing over the glaze slip for mass percent 0.25%～0.55%, screening out ferrum i.e. obtains cover-coat enamel excessively；
Frit a during wherein prepared by ground-coat enamel and cover-coat enamel is prepared by following parts by weight of component:
By feldspar powder 8～14 parts, calcium carbonate 23～29 parts, zirconium English powder 6～10 parts, zinc oxide 7～
13 parts, Pulvis Talci 8～12 parts, titanium dioxide 2～6 parts, potassium carbonate 3～5 parts, silica flour 30～
40 parts, carry out dispensing mixing, found in Cinker clew furnace, glass melting temperature 1520 DEG C～1540 DEG C, shrend
Become frit granule drying frit a；
Frit b therein is prepared by following parts by weight of component by following weight portion:
By feldspar powder 16～24 parts, calcium carbonate 11～19 parts, boric acid 4～8 parts, Pulvis Talci 3～7
Part, zirconium English powder 11～17 parts, zinc oxide 8～12 parts, potassium carbonate 1～3 parts, Borax 2～6 parts,
Silica flour 20～28 parts carry out dispensing mixing, found in Cinker clew furnace, glass melting temperature 1520 DEG C～
1540 DEG C, shrend becomes frit granule drying frit b；
C, the preparation of Margarita illusion-colour screen printing glaze, prepare by weight:
By frit c 95～99 parts, zinc oxide 0.5～3.5 parts, cerium oxide 0.5～1.5 parts and pottery
It is the tailing over as mass percent of 325 mesh sieves that fineness is worn in porcelain glue roller squeegee oil 80～160 parts of mixing
The glaze slip of 0.02%～0.06%, screening out ferrum i.e. obtains Margarita illusion-colour screen printing glaze excessively；
Wherein said frit c is prepared by following parts by weight of component by following weight portion:
Feldspar powder 30～38 parts, calcium carbonate 15～19 parts, boric acid 1～3 parts, potassium nitrate 0.5～2.5
Part, spodumene powder 1～3 parts, brium carbonate 0.5～2.5 parts, zinc oxide 2～6 parts, red lead powder 0.5～
4.5 parts, silica flour 28～36 parts carry out dispensing mixing, found, glass melting temperature in Cinker clew furnace
1520 DEG C～1540 DEG C, shrend becomes frit granule drying frit c；
D, the preparation of brill sand glaze grain slurry, prepare by weight:
By frit d grain 30～40 parts and pottery glue roller squeegee oil 60～70 parts of mixing and stirring and get final product
Bore sand glaze grain slurry.
The invention still further relates to a kind of thousand pearl illusion-colour glazed tiles, comprising:
Biscuit body: the biscuit body manufactured for ceramic polished waste residue；
Ground-coat enamel: configure by following parts by weight of component:
Frit a 12～22 parts, lithium porcelain stone powder 26～32 parts, alumina powder 2～8 parts, burn Talcum 5～
11 parts, Zirconium orthosilicate. 4～10 parts, silica flour 22～28 parts, Kaolin 13～21 parts, carboxymethyl fibre
Dimension element 0.07～0.12 part, sodium tripolyphosphate 0.3～0.8 part and water 37～45 parts；Executing of ground-coat enamel
Glaze amount is 0.7～0.9/, described glaze volume is aqueous glaze slip weight；
Cover-coat enamel: configure by following parts by weight of component:
Frit a 40～50 parts, frit b 5～15 parts, Zirconium orthosilicate. 5～9 parts, Kaolin 15～25
Part, feldspar powder 6～12 parts, alumina powder 4～8 parts, carboxymethyl cellulose 0.06～0.09 part,
Sodium tripolyphosphate 0.3～0.8 part and water 37～45 parts；The glaze volume of cover-coat enamel is 0.75～1.05
/, described glaze volume is aqueous glaze slip weight；
Margarita illusion-colour screen printing glaze: configure by following parts by weight of component:
Frit c 95～99 parts, zinc oxide 0.5～3.5 parts, cerium oxide 0.5～1.5 parts and pottery
Glue roller squeegee oil 80～160 parts；The thickness of Margarita illusion-colour screen printing glaze printed patterns is 0.4～0.7；
Bore sand glaze grain slurry: configure by following parts by weight of component:
Frit d grain 30～40 parts and pottery glue roller squeegee oil 60～70 parts；Bore the sizing of sand glaze grain slurry
Amount is 0.19～0.24/, described sizing amount is wet pulp weight；
Wherein said frit a is configured by following parts by weight of component:
Feldspar powder 8～14 parts, calcium carbonate 23～29 parts, zirconium English powder 6～10 parts, zinc oxide 7～13
Part, Pulvis Talci 8～12 parts, titanium dioxide 2～6 parts, potassium carbonate 3～5 parts, silica flour 30～40
Part；
Wherein said frit b is configured by following parts by weight of component:
Feldspar powder 16～24 parts, calcium carbonate 11～19 parts, boric acid 4～8 parts, Pulvis Talci 3～7 parts,
Zirconium English powder 11～17 parts, zinc oxide 8～12 parts, potassium carbonate 1～3 parts, Borax 2～6 parts, stone
English powder 20～28 parts；
Wherein said frit c is configured by following parts by weight of component:
Feldspar powder 30～38 parts, calcium carbonate 15～19 parts, boric acid 1～3 parts, potassium nitrate 0.5～2.5
Part, spodumene powder 1～3 parts, brium carbonate 0.5～2.5 parts, zinc oxide 2～6 parts, red lead powder 0.5～
4.5 parts, silica flour 28～36 parts；
Wherein said frit d grain is configured by following parts by weight of component:
Feldspar powder 12～20 parts, calcium carbonate 10～16 parts, boric acid 8～12 parts, zirconium English powder 12～18
Part, potassium nitrate 3～5 parts, zinc oxide 8～12 parts, titanium dioxide 3～5 parts, silica flour 26～34
Part.
Described biscuit body is the biscuit body that ceramic polished waste residue manufactures.
The invention still further relates to the preparation method of a kind of thousand pearl illusion-colour glazed tiles, it comprises the following steps:
A, the preparation of biscuit body: biscuit body is the biscuit body that ceramic polished waste residue manufactures；
B, the preparation of ground-coat enamel, prepare by weight:
By frit a 12～22 parts, lithium porcelain stone powder 26～32 parts, alumina powder 2～8 parts, burn Talcum
5～11 parts, Zirconium orthosilicate. 4～10 parts, silica flour 22～28 parts, Kaolin 13～21 parts, carboxylic first
Base cellulose 0.07～0.12 part, sodium tripolyphosphate 0.3～0.8 part and water 37～45 parts mix together
Close and wear into the glaze slip for mass percent 0.2%～0.4% that tails over that fineness is 325 mesh sieves, cross and screen out ferrum i.e.
Obtain ground-coat enamel；
C, the preparation of cover-coat enamel, prepare by weight:
By frit a 40～50 parts, frit b 5～15 parts, Zirconium orthosilicate. 5～9 parts, Kaolin 15～
25 parts, feldspar powder 6～12 parts, alumina powder 4～8 parts, carboxymethyl cellulose 0.06～0.09 part,
Sodium tripolyphosphate 0.3～0.8 part and water 37～45 parts are mixed together and wear into fineness is 325 mesh sieves
Tailing over the glaze slip for mass percent 0.25%～0.55%, screening out ferrum i.e. obtains cover-coat enamel excessively；
Frit a during wherein prepared by ground-coat enamel and cover-coat enamel is prepared by following parts by weight of component:
By feldspar powder 8～14 parts, calcium carbonate 23～29 parts, zirconium English powder 6～10 parts, zinc oxide 7～
13 parts, Pulvis Talci 8～12 parts, titanium dioxide 2～6 parts, potassium carbonate 3～5 parts, silica flour 30～
40 parts, carry out dispensing mixing, found in Cinker clew furnace, glass melting temperature 1520 DEG C～1540 DEG C, shrend
Become frit granule drying frit a；
Frit b therein is prepared by following parts by weight of component by following weight portion:
By feldspar powder 16～24 parts, calcium carbonate 11～19 parts, boric acid 4～8 parts, Pulvis Talci 3～7
Part, zirconium English powder 11～17 parts, zinc oxide 8～12 parts, potassium carbonate 1～3 parts, Borax 2～6 parts,
Silica flour 20～28 parts carry out dispensing mixing, found in Cinker clew furnace, glass melting temperature 1520 DEG C～
1540 DEG C, shrend becomes frit granule drying frit b；
D, the preparation of Margarita illusion-colour screen printing glaze, prepare by weight:
By frit c 95～99 parts, zinc oxide 0.5～3.5 parts, cerium oxide 0.5～1.5 parts and pottery
It is the tailing over as mass percent of 325 mesh sieves that fineness is worn in porcelain glue roller squeegee oil 80～160 parts of mixing
The glaze slip of 0.02%～0.06%, screening out ferrum i.e. obtains Margarita illusion-colour screen printing glaze excessively；
Wherein said frit c is prepared by following parts by weight of component by following weight portion:
Feldspar powder 30～38 parts, calcium carbonate 15～19 parts, boric acid 1～3 parts, potassium nitrate 0.5～2.5
Part, spodumene powder 1～3 parts, brium carbonate 0.5～2.5 parts, zinc oxide 2～6 parts, red lead powder 0.5～
4.5 parts, silica flour 28～36 parts carry out dispensing mixing, found, glass melting temperature in Cinker clew furnace
1520 DEG C～1540 DEG C, shrend becomes frit granule drying frit c；
E, the preparation of brill sand glaze grain slurry, prepare by weight:
By frit d grain 30～40 parts and pottery glue roller squeegee oil 60～70 parts of mixing and stirring and get final product
Bore sand glaze grain slurry；
F, the preparation of product and burn till:
Biscuit body step A obtained, first executes the ground-coat enamel that step B obtains, and the glaze volume of ground-coat enamel is for executing
Glaze amount is 0.7～0.9/, described glaze volume is aqueous glaze slip weight；Step is executed again in time doing at the beginning of ground-coat enamel
The cover-coat enamel that rapid C obtains, glaze volume is 0.75～1.05/, described glaze volume is aqueous glaze slip weight；
Then Margarita illusion-colour screen printing glaze step D obtained by silk-screen plate or offset printing roller is imprinted on the cover-coat enamel of adobe
On, the thickness of Margarita illusion-colour screen printing glaze printed patterns is 0.4～0.7, then enters through ink-jet decorating machine
Row is ink-jet printed, then executes the brill sand glaze grain slurry that step E obtains, and sizing amount is 0.19～0.24/,
Described sizing amount is wet pulp weight, then through side washing, enters roller kilns glaze firing, maximum sintering temperature scope
Being 1090 DEG C～1130 DEG C, firing time is 40～70 minutes, through edging, i.e. makes finished product.
Preferred by biscuit body kind, the biscuit body that Ceramics polishing slag manufactures, it is at high temperature
Due to the discharge of gases a large amount of in waste residue in calcination process, form substantial amounts of open pore in billet surface,
These open pores are the guarantees that biscuit body water absorption rate, surface breathability and hydrophobicity are the most excellent.Therefore
This biscuit body is after having drenched ground-coat enamel, cover-coat enamel, and the moisture content in ground-coat enamel, cover-coat enamel can pass through at short notice
These open pores penetrate into rapidly in biscuit body, and the residual gas in these open pores is at moisture simultaneously
Extruding under break through ground-coat enamel, cover coat comes surface, thus at the table of the adobe body having drenched ground-coat enamel, cover-coat enamel
Face leaves the opening spilehole of many, when printing Margarita illusion-colour screen printing glaze and executing brill sand glaze grain slurry, these
Opening spilehole can quickly make Margarita illusion-colour screen printing glaze and bore the ceramic glue roller squeegee oil in sand glaze grain slurry
Penetrate in cover-coat enamel by these pores, make Margarita illusion-colour screen printing glaze pattern ensure thickness and the shape of printing
Rapid solidification under shape, will not scatter and even subside；The follow-up ceramic glue roller squeegee oil bored in sand grains slurry
It also is able to penetrate in cover-coat enamel quickly through these pores, not only ensure that brill sand glaze grain is firmly adsorbed on
Adobe surface will not be blown away by kiln hood drifting dust blower fan or be blown away by the fume extraction fan in kiln, but also will not
The pattern printing Margarita illusion-colour screen printing glaze and the ink-jet decorating machine of leading portion printing damages；Ground-coat enamel formula
The optimization of composition, on the one hand guarantees ground-coat enamel good air permeability in high temperature, makes the ceramic waste residue in base substrate exist
In high temperature, the gas of release can be discharged in time, on the other hand can be formed firm with base substrate and cover-coat enamel again
Intermediate layer balances the coefficient of expansion of base, glaze, it is ensured that the flatness of product, improves again the heat resistanceheat resistant of product
Pinking；Owing to the thousand pearl illusion-colour glazed tile products of the present invention are under light or skew ray irradiate, surface goes out simultaneously
Now send, such as broken brill sand shape twinkLing stars light and Margarita gem, the tempting radiance that glitter, and spray printing is unreal Margarita
Pattern color at color printing brushing glazing, can glitter radiance boring sand glaze twinkLing stars light and Margarita illusion-colour screen printing glaze
Reflection and refraction dual function under color changeable effect occurs, a grain Margarita cameo incrustation is in brick face seemingly
On, therefore the cooperation of cover-coat enamel, Margarita illusion-colour screen printing glaze and brill sand glaze grain three is the most perfect, cover-coat enamel
Preferred and the proportioning of middle different frit, the optimization of cover-coat enamel formula composition, it is ensured that cover-coat enamel is when high-temperature calcination
Have suitable high temperature viscosity and a melting behaviour, not only to ensure to bore sand glaze grain and Margarita illusion-colour screen printing glaze and its
Bonding intact, occur without because of defects such as bonding bad and cracking, pin holes；But also brill sand can not be made
Glaze grain and Margarita illusion-colour screen printing glaze are the most melted, collapse so that they melt, and make reflection, refractive optical power inadequate,
Weaken as bored sand flicker starlight and the effect of Margarita gemstone sparkle radiance, even will bore sand grains and Margarita illusion-colour
Screen printing glaze fuses into one, and loses brill sand flicker starlight and the effect of Margarita gemstone sparkle radiance completely；Bore sand
The composition of the frit of glaze grain and the optimization of brill sand glaze grain formula composition, on the one hand can make brill sand glaze grain uniform
Be layered on the brick face having printed pattern, again will not to printing pattern damage；The most all right
Ensure that boring sand glaze grain adsorbs firmly on the adobe face having printed pattern, is not destroyed by outside；Most important
Be it when high-temperature calcination, bore sand glaze grain and just occur melting so that it is can be well by mutual between granule
Bond together, but also keep complete graininess, ensure that the reflection to light, simultaneously
Bonding intact with cover-coat enamel and Margarita illusion-colour screen printing glaze again；Margarita illusion-colour screen printing glaze frit composition and formula composition
Optimization, on the one hand ensure that Margarita illusion-colour screen printing glaze has heigh clarity, high after high-temperature calcination
Glossiness, high index of refraction so that it is under the irradiation of light, send the radiance glittered；On the other hand ensure again
The integrity of self so that it is dimpling is on cover-coat enamel；The most also to ensure to have suitable melting behaviour, a side
Face ensures to make the pattern of ink jet printing be dissolved in the unreal glazed colour layer of Margarita, can not destroy again the complete of pattern
Property；On the other hand make the brill sand glaze grain executing on its face under topic again before keeping complete graininess, again
Melting adhered intact, thus at its numerous tangent plane of surface self-assembling formation, when light irradiates or reflexes to it
Time on face, these tangent planes reflect light back into naturally, thus send such as the radiance of Margarita gemstone sparkle,
The most again by inside part anaclasis to glaze layer, so that sinking to the pattern color inside glaze layer from different angles
Degree reflexes to, in the eyes of people, the special-effect of variable color occur.Glazing process parameter and the tune of printing technology
Whole with optimize, on the one hand ensure that ground-coat enamel, cover-coat enamel, brill sand glaze grain, Margarita illusion-colour screen printing glaze have the most swollen
Swollen coefficient, makes them be combined with each other intact, in turn ensure that the flatness of product；On the other hand in turn ensure that
The integrity of the pattern of different designs and property of naturally coincideing closely.
The beneficial effect that the employing present invention is brought:
1, due to the preferred kind of biscuit body, ground-coat enamel, the composition of cover-coat enamel frit, cover-coat enamel different performance
Preferred and the proportioning of frit, the formula composition of ground-coat enamel, the frit of Margarita illusion-colour screen printing glaze form, Margarita is unreal
The formula of color printing brushing glazing forms, the granularity of brill sand glaze grain frit composition, brill sand glaze grain is preferred and formula forms,
The optimization of glazing process parameter and printing technology etc., so that utilizing the thousand pearl illusion-colour glazes that this technology manufactures
Brick product, under light or skew ray irradiate, surface occurs as precious in broken brill sand shape flicker starlight and Margarita simultaneously
The radiance glittered as stone, and print Margarita illusion-colour screen printing glaze at pattern color can with the difference of light angle in
Existing different color, makes product have decorative effect and the aesthetic of uniqueness.
2, this product surface flatness, the modulus of rupture, water absorption rate, resistance to acids and bases, thermal shock resistance lead cadmium
Stripping quantity all reaches GB/T4100-2015, GB6566-2011 and HJ/T297-2006 standard-required.
3, body recipe employs larger amount of ceramic polished waste residue so that reducing production cost
Save again resource simultaneously, reach the purpose of energy-saving and emission-reduction.
4, use existing glazed tile production technology, make the technology of preparing of thousand pearl illusion-colour glazed tiles possess relatively
Strong universality, it is easy in industry promote.
Accompanying drawing illustrates:
Fig. 1 is the preparation technology flow chart of thousand pearl illusion-colour glazed tiles.
Detailed description of the invention:
Below in conjunction with embodiment, the present invention is described in further detail.
Embodiment 1:
A kind of thousand pearl illusion-colour glazed tile preparation methoies, including biscuit body, frit, ground-coat enamel, cover-coat enamel, Margarita
The preparation process of illusion-colour screen printing glaze and brill sand glaze grain slurry etc..
Prepare biscuit body: wherein said biscuit body is the biscuit body manufactured with polishing slag, useless with polishing
The manufacture method of the biscuit body that slag manufactures, the number of patent application applicant is: 201210050321.3,
Patent name is special for the invention of " utilizing polishing slag to manufacture ceramic tile blank and the formula of glazed tile and method "
Profit application has been disclosed.
Prepare frit a:
Weigh granularity by the formula composition of table 1 frit a and be respectively less than the raw material feldspar powder of 150 mesh, carbon
Acid calcium, zirconium English powder, zinc oxide, Pulvis Talci, titanium dioxide, potassium carbonate, silica flour, carry out dispensing,
Mixer mixes 30 minutes, founds in Cinker clew furnace, glass melting temperature 1520 DEG C～1540 DEG C, shrend
Become frit granule drying frit a.
Table 1, formula composition table (weight portion) of frit a
| Component | Feldspar powder | Calcium carbonate | Zirconium English powder | Zinc oxide | Pulvis Talci | Titanium dioxide | Potassium carbonate | Silica flour |
| 1# | 8 | 23 | 10 | 8 | 12 | 6 | 3 | 30 |
| 2# | 11 | 26 | 8 | 10 | 8 | 2 | 5 | 30 |
| 3# | 14 | 24 | 6 | 7 | 10 | 4 | 4 | 31 |
| 4# | 8 | 25 | 6 | 13 | 8 | 2 | 3 | 35 |
| 5# | 9 | 29 | 7 | 9 | 9 | 3 | 4 | 30 |
| 6# | 8.5 | 23 | 6.5 | 7 | 9 | 2.5 | 3.5 | 40 |
Prepare frit b:
Weigh granularity by the formula composition of table 2 frit b and be respectively less than the raw material feldspar powder of 150 mesh, carbon
Acid calcium, boric acid, Pulvis Talci, zirconium English powder, zinc oxide, potassium carbonate, Borax, silica flour, carry out dispensing,
Batch mixer mixes 30 minutes, founds in Cinker clew furnace, glass melting temperature 1520 DEG C～1540 DEG C, water
Quench into frit granule drying frit b.
Table 2, formula composition table (weight portion) of frit b
Prepare frit c:
Weigh granularity by the formula composition of table 3 frit c and be respectively less than the raw material feldspar powder of 150 mesh, carbon
Acid calcium, boric acid, potassium nitrate, spodumene powder, brium carbonate, zinc oxide, red lead powder, silica flour, carried out
Dispensing, mixes 30 minutes in batch mixer, founds, glass melting temperature 1520 DEG C～1540 DEG C in Cinker clew furnace,
Shrend becomes frit granule drying frit c.
Table 3, formula composition table (weight portion) of frit c
| Component | Feldspar powder | Calcium carbonate | Boric acid | Potassium nitrate | Spodumene powder | Brium carbonate | Zinc oxide | Red lead powder | Silica flour |
| 1# | 30 | 19 | 3 | 1.5 | 3 | 2.5 | 6 | 3 | 32 |
| 2# | 34 | 17 | 2 | 2.5 | 1 | 1.5 | 4 | 2 | 36 |
| 3# | 38 | 15 | 1 | 0.5 | 2 | 0.5 | 5.5 | 4.5 | 33 |
| 4# | 38 | 19 | 3 | 2 | 3 | 2.5 | 2 | 2.5 | 28 |
| 5# | 36 | 18 | 2 | 1 | 2 | 1.5 | 5 | 0.5 | 34 |
Prepare frit d grain:
Weigh granularity by the formula composition of table 4 frit d and be respectively less than the raw material feldspar powder of 150 mesh, carbon
Acid calcium, boric acid, zirconium English powder, potassium nitrate, zinc oxide, titanium dioxide, silica flour, carry out dispensing, mixed
Mixing 30 minutes in material machine, found, glass melting temperature 1520 DEG C～1540 DEG C in Cinker clew furnace, shrend becomes
The drying of frit granule is broken into 80 mesh again～200 purposes thin frit grain i.e. obtains frit d grain.
Table 4, formula composition table (weight portion) of frit d grain
| Component | Feldspar powder | Calcium carbonate | Boric acid | Zirconium English powder | Potassium nitrate | Zinc oxide | Titanium dioxide | Silica flour |
| 1# | 12 | 16 | 10 | 16 | 5 | 12 | 3 | 26 |
| 2# | 16 | 13 | 12 | 12 | 3 | 10 | 4 | 30 |
| 3# | 20 | 10 | 8 | 15 | 4 | 8 | 5 | 30 |
| 4# | 12 | 11 | 8 | 18 | 4.5 | 9 | 3.5 | 34 |
Prepare ground-coat enamel:
Frit a, lithium porcelain stone powder, alumina powder, burning Talcum, silicic acid is weighed by table 5 ground-coat enamel formula composition
Zirconium, silica flour, Kaolin, the carboxymethyl cellulose of additional 0.07～0.12 part, 0.3～0.8 part
Sodium tripolyphosphate, the water of 37～45 parts, enter ball mill tailing over as mass percent to 325 mesh sieves in small, broken bits
The glaze slip of 0.2%～0.4%, crosses and screens out ferrum and store that i.e. to obtain ground-coat enamel standby.
Table 5, ground-coat enamel formula composition table (weight portion)
| Component | Frit a | Lithium porcelain stone powder | Alumina powder | Burn Talcum | Zirconium orthosilicate. | Silica flour | Kaolin |
| 1# | 12 | 29 | 6 | 8 | 10 | 22 | 13 |
| 2# | 17 | 27 | 3 | 11 | 4 | 25 | 13 |
| 3# | 22 | 26 | 2 | 5 | 7 | 23 | 15 |
| 4# | 12 | 32 | 5 | 5 | 4 | 28 | 14 |
| 5# | 13 | 28 | 4 | 7 | 6 | 25 | 17 |
| 6# | 14 | 27 | 3 | 6 | 5 | 24 | 21 |
| 7# | 15 | 26 | 8 | 5 | 4 | 24 | 18 |
Prepare cover-coat enamel:
By table 6 cover-coat enamel formula composition claim block frit a, frit b, Zirconium orthosilicate., Kaolin, feldspar powder,
Alumina powder, the carboxymethyl cellulose of additional 0.06～0.09 part, the sodium tripolyphosphate of 0.3～0.8 part,
The water of 37～45 parts, enters ball mill tailing over as mass percent 0.25%～0.55% to 325 mesh sieves in small, broken bits
Glaze slip, cross and screen out ferrum and store that i.e. to obtain cover-coat enamel standby.
Table 6, cover-coat enamel formula composition table (weight portion)
| Component | Frit a | Frit b | Zirconium orthosilicate. | Kaolin | Feldspar powder | Alumina powder |
| 1# | 40 | 15 | 7 | 20 | 12 | 6 |
| 2# | 45 | 10 | 9 | 19 | 9 | 8 |
| 3# | 50 | 5 | 5 | 25 | 11 | 4 |
| 4# | 50 | 14 | 8 | 15 | 6 | 7 |
Preparation Margarita illusion-colour screen printing glaze:
Form by the formula of table 7 Margarita illusion-colour screen printing glaze and weigh frit c, zinc oxide, cerium oxide, additional
The ceramic glue roller squeegee oil of 80～160 parts, enters ball mill tailing over as mass percent to 325 mesh sieves in small, broken bits
The glaze slip of 0.02%～0.06%, crosses and screens out ferrum and store that i.e. to obtain Margarita illusion-colour screen printing glaze standby.
Table 7, Margarita illusion-colour screen printing glaze formula composition table (weight portion)
| Component | Frit c | Zinc oxide | Cerium oxide |
| 1# | 99 | 0.5 | 0.5 |
| 2# | 95 | 3.5 | 1.5 |
| 3# | 97 | 2 | 1 |
Preparation is bored sand glaze grain and is starched:
By table 8 bore sand glaze grain slurry formula composition weigh frit d grain, pottery glue roller squeegee oil together enter stirring
Bucket stir stores i.e. obtain brill sand glaze grain starch standby.
Table 8, brill sand glaze grain slurry formula composition table (weight portion)
| Component | Frit d grain | Pottery glue roller squeegee oil |
| 1# | 30 | 70 |
| 2# | 35 | 65 |
| 3# | 40 | 60 |
Prepare thousand pearl illusion-colour glazed tiles:
Execute above-mentioned steps with bell jar pouring glaze in the biscuit surface manufactured with ceramic polished waste residue to be prepared into
The ground-coat enamel arrived, glaze volume is 0.7～0.9/, described glaze volume is aqueous glaze slip weight, treats ground-coat enamel
Execute, time just dry, the cover-coat enamel that above-mentioned steps prepares again, glaze volume is 0.75～1.05/, described in execute
Glaze amount is aqueous glaze slip weight, then needs to print above-mentioned steps with silk-screen plate or offset printing roller according to design and obtains
The Margarita illusion-colour screen printing glaze arrived, the thickness of Margarita illusion-colour screen printing glaze printed patterns is 0.4～0.7, then
Through ink-jet printed, then execute the brill sand glaze grain slurry that above-mentioned steps obtains, sizing amount is 0.19～0.24/
, described sizing amount is wet pulp weight, then through side washing, enters roller kilns glaze firing, maximum sintering temperature
Scope is 1090 DEG C～1130 DEG C, and firing time is 40～70 minutes, through edging, finally prepares into
Product.
The present invention is by the preparation method of thousand above-mentioned pearl illusion-colour glazed tiles, the thousand pearl illusion-colour glaze prepared
Face brick product, what glaze was executed bores the sand glaze grain Margarita illusion-colour screen printing glaze with printing in light and skew ray irradiation
Under, occur that such as broken brill sand shape twinkLing stars light and Margarita gem send the tempting radiance that glitter, and spray simultaneously
It is imprinted on the typographic pattern color of Margarita illusion-colour, bores sand glaze grain and the reflection of Margarita illusion-colour screen printing glaze and folding
Penetrate under dual function, along with the difference of light angle, special color changeable effect, a grain treasure seemingly can occur
Jewelry stone is embedded on brick face, and visual effect is unique, has dicoration and the artistry of height.
The indices of product such as table 9 below after testing.
Table 9: product quality inspection result
In sum, only presently preferred embodiments of the present invention, not the present invention is made any in form
Restriction；The those of ordinary skill of all industry all can be implemented the present invention swimmingly by the above；But
Be all those skilled in the art in the range of without departing from technical solution of the present invention, available above institute
The technology contents that discloses and a little change made, the equivalent variations modifying and develop, be the present invention's
Equivalent embodiments；Meanwhile, all any equivalents above example made according to the substantial technological of the present invention
Change change, modify and develop, within all still falling within the protection domain of technical scheme.
Claims (4)
1. for the glaze of preparation thousand pearl illusion-colour glazed tiles, it is characterised in that:
It includes ground-coat enamel, cover-coat enamel, Margarita illusion-colour screen printing glaze and bores sand glaze grain slurry；
Ground-coat enamel: configure by following parts by weight of component:
Frit a 12～22 parts, lithium porcelain stone powder 26～32 parts, alumina powder 2～8 parts, burn Talcum 5～11 parts, Zirconium orthosilicate. 4～10 parts, silica flour 22～28 parts, Kaolin 13～21 parts, carboxymethyl cellulose 0.07～0.12 part, sodium tripolyphosphate 0.3～0.8 part and water 37～45 parts；
Cover-coat enamel: configure by following parts by weight of component:
Frit a 40～50 parts, frit b 5～15 parts, Zirconium orthosilicate. 5～9 parts, Kaolin 15～25 parts, feldspar powder 6～12 parts, alumina powder 4～8 parts, carboxymethyl cellulose 0.06～0.09 part, sodium tripolyphosphate 0.3～0.8 part and water 37～45 parts；
Margarita illusion-colour screen printing glaze: configure by following parts by weight of component:
Frit c 95～99 parts, zinc oxide 0.5～3.5 parts, cerium oxide 0.5～1.5 parts and pottery glue roller squeegee oil 80～160 parts；
Bore sand glaze grain slurry: configure by following parts by weight of component:
Frit d grain 30～40 parts and pottery glue roller squeegee oil 60～70 parts；
Wherein said frit a is configured by following parts by weight of component:
Feldspar powder 8～14 parts, calcium carbonate 23～29 parts, zirconium English powder 6～10 parts, zinc oxide 7～13 parts, Pulvis Talci 8～12 parts, titanium dioxide 2～6 parts, potassium carbonate 3～5 parts, silica flour 30～40 parts；
Wherein said frit b is configured by following parts by weight of component:
Feldspar powder 16～24 parts, calcium carbonate 11～19 parts, boric acid 4～8 parts, Pulvis Talci 3～7 parts, zirconium English powder 11～17 parts, zinc oxide 8～12 parts, potassium carbonate 1～3 parts, Borax 2～6 parts, silica flour 20～28 parts；
Wherein said frit c is configured by following parts by weight of component:
Feldspar powder 30～38 parts, calcium carbonate 15～19 parts, boric acid 1～3 parts, potassium nitrate 0.5～2.5 parts, spodumene powder 1～3 parts, brium carbonate 0.5～2.5 parts, zinc oxide 2～6 parts, red lead powder 0.5～4.5 parts, silica flour 28～36 parts；
Wherein said frit d grain is configured by following parts by weight of component:
Feldspar powder 12～20 parts, calcium carbonate 10～16 parts, boric acid 8～12 parts, zirconium English powder 12～18 parts, potassium nitrate 3～5 parts, zinc oxide 8～12 parts, titanium dioxide 3～5 parts, silica flour 26～34 parts.
2. for preparing the preparation method of the glaze of thousand pearl illusion-colour glazed tiles, it is characterised in that:
It comprises the following steps:
A, the preparation of ground-coat enamel, prepare by weight:
By frit a 12～22 parts, lithium porcelain stone powder 26～32 parts, alumina powder 2～8 parts, burn Talcum 5～11 parts, Zirconium orthosilicate. 4～10 parts, silica flour 22～28 parts, Kaolin 13～21 parts, carboxymethyl cellulose 0.07～0.12 part, sodium tripolyphosphate 0.3～0.8 part and water 37～45 parts be mixed together and wear into the glaze slip for mass percent 0.2%～0.4% that tails over that fineness is 325 mesh sieves, cross and screen out ferrum and i.e. obtain ground-coat enamel；
B, the preparation of cover-coat enamel, prepare by weight:
Frit a 40～50 parts, frit b 5～15 parts, Zirconium orthosilicate. 5～9 parts, Kaolin 15～25 parts, feldspar powder 6～12 parts, alumina powder 4～8 parts, carboxymethyl cellulose 0.06～0.09 part, sodium tripolyphosphate 0.3～0.8 part and water 37～45 parts are mixed together and wear into the glaze slip for mass percent 0.25%～0.55% that tails over that fineness is 325 mesh sieves, cross and screen out ferrum and i.e. obtain cover-coat enamel；
Frit a during wherein prepared by ground-coat enamel and cover-coat enamel is prepared by following parts by weight of component:
By feldspar powder 8～14 parts, calcium carbonate 23～29 parts, zirconium English powder 6～10 parts, zinc oxide 7～13 parts, Pulvis Talci 8～12 parts, titanium dioxide 2～6 parts, potassium carbonate 3～5 parts, silica flour 30～40 parts, carry out dispensing mixing, found in Cinker clew furnace, glass melting temperature 1520 DEG C～1540 DEG C, shrend becomes frit granule drying frit a；
Frit b therein is prepared by following parts by weight of component by following weight portion:
Feldspar powder 16～24 parts, calcium carbonate 11～19 parts, boric acid 4～8 parts, Pulvis Talci 3～7 parts, zirconium English powder 11～17 parts, zinc oxide 8～12 parts, potassium carbonate 1～3 parts, Borax 2～6 parts, silica flour 20～28 parts are carried out dispensing mixing, found in Cinker clew furnace, glass melting temperature 1520 DEG C～1540 DEG C, shrend becomes frit granule drying frit b；
C, the preparation of Margarita illusion-colour screen printing glaze, prepare by weight:
Frit c 95～99 parts, zinc oxide 0.5～3.5 parts, cerium oxide 0.5～1.5 parts and pottery glue roller squeegee oil 80～160 parts of mixing are worn into the glaze slip for mass percent 0.02%～0.06% that tails over that fineness is 325 mesh sieves, crosses and screen out ferrum and i.e. obtain Margarita illusion-colour screen printing glaze；
Wherein said frit c is prepared by following parts by weight of component by following weight portion:
Feldspar powder 30～38 parts, calcium carbonate 15～19 parts, boric acid 1～3 parts, potassium nitrate 0.5～2.5 parts, spodumene powder 1～3 parts, brium carbonate 0.5～2.5 parts, zinc oxide 2～6 parts, red lead powder 0.5～4.5 parts, silica flour 28～36 parts carry out dispensing mixing, found in Cinker clew furnace, glass melting temperature 1520 DEG C～1540 DEG C, shrend becomes frit granule drying frit c；
D, the preparation of brill sand glaze grain slurry, prepare by weight:
Frit d grain 30～40 parts and pottery glue roller squeegee oil 60～70 parts of mixing and stirring are i.e. obtained brill sand glaze grain slurry.
3. a pearl illusion-colour glazed tile, it is characterised in that:
Comprising:
Biscuit body: the biscuit body manufactured for ceramic polished waste residue；
Ground-coat enamel: configure by following parts by weight of component:
Frit a 12～22 parts, lithium porcelain stone powder 26～32 parts, alumina powder 2～8 parts, burn Talcum 5～11 parts, Zirconium orthosilicate. 4～10 parts, silica flour 22～28 parts, Kaolin 13～21 parts, carboxymethyl cellulose 0.07～0.12 part, sodium tripolyphosphate 0.3～0.8 part and water 37～45 parts；The glaze volume of ground-coat enamel is 0.7～0.9/, described glaze volume is aqueous glaze slip weight；
Cover-coat enamel: configure by following parts by weight of component:
Frit a 40～50 parts, frit b 5～15 parts, Zirconium orthosilicate. 5～9 parts, Kaolin 15～25 parts, feldspar powder 6～12 parts, alumina powder 4～8 parts, carboxymethyl cellulose 0.06～0.09 part, sodium tripolyphosphate 0.3～0.8 part and water 37～45 parts；The glaze volume of cover-coat enamel is 0.75～1.05/, described glaze volume is aqueous glaze slip weight；
Margarita illusion-colour screen printing glaze: configure by following parts by weight of component:
Frit c 95～99 parts, zinc oxide 0.5～3.5 parts, cerium oxide 0.5～1.5 parts and pottery glue roller squeegee oil 80～160 parts；The thickness of Margarita illusion-colour screen printing glaze printed patterns is 0.4～0.7；
Bore sand glaze grain slurry: configure by following parts by weight of component:
Frit d grain 30～40 parts and pottery glue roller squeegee oil 60～70 parts；The sizing amount boring sand glaze grain slurry is 0.19～0.24/, described sizing amount is wet pulp weight；
Wherein said frit a is configured by following parts by weight of component:
Feldspar powder 8～14 parts, calcium carbonate 23～29 parts, zirconium English powder 6～10 parts, zinc oxide 7～13 parts, Pulvis Talci 8～12 parts, titanium dioxide 2～6 parts, potassium carbonate 3～5 parts, silica flour 30～40 parts；
Wherein said frit b is configured by following parts by weight of component:
Feldspar powder 16～24 parts, calcium carbonate 11～19 parts, boric acid 4～8 parts, Pulvis Talci 3～7 parts, zirconium English powder 11～17 parts, zinc oxide 8～12 parts, potassium carbonate 1～3 parts, Borax 2～6 parts, silica flour 20～28 parts；
Wherein said frit c is configured by following parts by weight of component:
Feldspar powder 30～38 parts, calcium carbonate 15～19 parts, boric acid 1～3 parts, potassium nitrate 0.5～2.5 parts, spodumene powder 1～3 parts, brium carbonate 0.5～2.5 parts, zinc oxide 2～6 parts, red lead powder 0.5～4.5 parts, silica flour 28～36 parts；
Wherein said frit d grain is configured by following parts by weight of component:
Feldspar powder 12～20 parts, calcium carbonate 10～16 parts, boric acid 8～12 parts, zirconium English powder 12～18 parts, potassium nitrate 3～5 parts, zinc oxide 8～12 parts, titanium dioxide 3～5 parts, silica flour 26～34 parts.
4. the preparation method of a pearl illusion-colour glazed tile, it is characterised in that:
It comprises the following steps:
A, the preparation of biscuit body: biscuit body is the biscuit body that ceramic polished waste residue manufactures；
B, the preparation of ground-coat enamel, prepare by weight:
By frit a 12～22 parts, lithium porcelain stone powder 26～32 parts, alumina powder 2～8 parts, burn Talcum 5～11 parts, Zirconium orthosilicate. 4～10 parts, silica flour 22～28 parts, Kaolin 13～21 parts, carboxymethyl cellulose 0.07～0.12 part, sodium tripolyphosphate 0.3～0.8 part and water 37～45 parts be mixed together and wear into the glaze slip for mass percent 0.2%～0.4% that tails over that fineness is 325 mesh sieves, cross and screen out ferrum and i.e. obtain ground-coat enamel；
C, the preparation of cover-coat enamel, prepare by weight:
Frit a 40～50 parts, frit b 5～15 parts, Zirconium orthosilicate. 5～9 parts, Kaolin 15～25 parts, feldspar powder 6～12 parts, alumina powder 4～8 parts, carboxymethyl cellulose 0.06～0.09 part, sodium tripolyphosphate 0.3～0.8 part and water 37～45 parts are mixed together and wear into the glaze slip for mass percent 0.25%～0.55% that tails over that fineness is 325 mesh sieves, cross and screen out ferrum and i.e. obtain cover-coat enamel；
Frit a during wherein prepared by ground-coat enamel and cover-coat enamel is prepared by following parts by weight of component:
By feldspar powder 8～14 parts, calcium carbonate 23～29 parts, zirconium English powder 6～10 parts, zinc oxide 7～13 parts, Pulvis Talci 8～12 parts, titanium dioxide 2～6 parts, potassium carbonate 3～5 parts, silica flour 30～40 parts, carry out dispensing mixing, found in Cinker clew furnace, glass melting temperature 1520 DEG C～1540 DEG C, shrend becomes frit granule drying frit a；
Frit b therein is prepared by following parts by weight of component by following weight portion:
Feldspar powder 16～24 parts, calcium carbonate 11～19 parts, boric acid 4～8 parts, Pulvis Talci 3～7 parts, zirconium English powder 11～17 parts, zinc oxide 8～12 parts, potassium carbonate 1～3 parts, Borax 2～6 parts, silica flour 20～28 parts are carried out dispensing mixing, found in Cinker clew furnace, glass melting temperature 1520 DEG C～1540 DEG C, shrend becomes frit granule drying frit b；
D, the preparation of Margarita illusion-colour screen printing glaze, prepare by weight:
Frit c 95～99 parts, zinc oxide 0.5～3.5 parts, cerium oxide 0.5～1.5 parts and pottery glue roller squeegee oil 80～160 parts of mixing are worn into the glaze slip for mass percent 0.02%～0.06% that tails over that fineness is 325 mesh sieves, crosses and screen out ferrum and i.e. obtain Margarita illusion-colour screen printing glaze；
Wherein said frit c is prepared by following parts by weight of component by following weight portion:
Feldspar powder 30～38 parts, calcium carbonate 15～19 parts, boric acid 1～3 parts, potassium nitrate 0.5～2.5 parts, spodumene powder 1～3 parts, brium carbonate 0.5～2.5 parts, zinc oxide 2～6 parts, red lead powder 0.5～4.5 parts, silica flour 28～36 parts carry out dispensing mixing, found in Cinker clew furnace, glass melting temperature 1520 DEG C～1540 DEG C, shrend becomes frit granule drying frit c；
E, the preparation of brill sand glaze grain slurry, prepare by weight:
Frit d grain 30～40 parts and pottery glue roller squeegee oil 60～70 parts of mixing and stirring are i.e. obtained brill sand glaze grain slurry；
F, the preparation of product and burn till:
Biscuit body step A obtained, first executes the ground-coat enamel that step B obtains, the glaze volume of ground-coat enamel be glaze volume be 0.7～0.9/, described glaze volume is aqueous glaze slip weight；Until at the beginning of ground-coat enamel dry time execute the cover-coat enamel that step C obtains again, glaze volume is 0.75～1.05/, described glaze volume is aqueous glaze slip weight；Then Margarita illusion-colour screen printing glaze step D obtained by silk-screen plate or offset printing roller is imprinted on the cover-coat enamel of adobe, the thickness of Margarita illusion-colour screen printing glaze printed patterns is 0.4～0.7, carry out ink-jet printed through ink-jet decorating machine again, execute the brill sand glaze grain slurry that step E obtains again, sizing amount is 0.19～0.24/, described sizing amount is wet pulp weight, again through side washing, enter roller kilns glaze firing, maximum sintering temperature scope is 1090 DEG C～1130 DEG C, firing time is 40～70 minutes, through edging, i.e. makes finished product.
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