CN105745270B - 适用于无底漆涂装的刚性聚丙烯组合物 - Google Patents

适用于无底漆涂装的刚性聚丙烯组合物 Download PDF

Info

Publication number: CN105745270B
Authority: CN; China
Prior art keywords: hpp; polypropylene composition; polypropylene; propylene copolymer; heterophasic propylene
Prior art date: 2013-05-31
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Active

Application number

CN201480027634.4A

Other languages

English (en)

Chinese (zh)

Other versions

CN105745270A (zh

Inventor

格奥尔格·格雷斯滕贝格尔

克劳迪娅·克尼泽尔

达妮埃拉·米列娃

迪特里希·格洛格尔

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Borealis AG

Original Assignee

Borealis AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2013-05-31

Filing date

2014-05-15

Publication date

2017-11-24

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=48520828&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN105745270(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

2014-05-15 Application filed by Borealis AG filed Critical Borealis AG

2016-07-06 Publication of CN105745270A publication Critical patent/CN105745270A/zh

2017-11-24 Application granted granted Critical

2017-11-24 Publication of CN105745270B publication Critical patent/CN105745270B/zh

Status Active legal-status Critical Current

2034-05-15 Anticipated expiration legal-status Critical

Links

239000004743 Polypropylene Substances 0.000 title claims abstract description 193
229920001155 polypropylene Polymers 0.000 title claims abstract description 193
239000000203 mixture Substances 0.000 title claims abstract description 170
-1 polypropylene Polymers 0.000 title claims description 216
238000010422 painting Methods 0.000 title 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 192
229920001577 copolymer Polymers 0.000 claims description 177
229920005629 polypropylene homopolymer Polymers 0.000 claims description 153
239000011159 matrix material Substances 0.000 claims description 53
229920001198 elastomeric copolymer Polymers 0.000 claims description 43
239000012764 mineral filler Substances 0.000 claims description 41
229920000642 polymer Polymers 0.000 claims description 40
229920001384 propylene homopolymer Polymers 0.000 claims description 35
239000000155 melt Substances 0.000 claims description 33
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 28
239000008096 xylene Substances 0.000 claims description 28
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 26
239000005977 Ethylene Substances 0.000 claims description 26
239000000454 talc Substances 0.000 claims description 13
229910052623 talc Inorganic materials 0.000 claims description 13
238000002347 injection Methods 0.000 claims description 11
239000007924 injection Substances 0.000 claims description 11
239000002245 particle Substances 0.000 claims description 11
239000004711 α-olefin Substances 0.000 claims description 9
150000001336 alkenes Chemical class 0.000 claims description 8
239000005995 Aluminium silicate Substances 0.000 claims description 5
235000012211 aluminium silicate Nutrition 0.000 claims description 5
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 5
239000010445 mica Substances 0.000 claims description 5
229910052618 mica group Inorganic materials 0.000 claims description 5
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 5
239000010456 wollastonite Substances 0.000 claims description 5
229910052882 wollastonite Inorganic materials 0.000 claims description 5
239000011248 coating agent Substances 0.000 abstract description 6
238000000576 coating method Methods 0.000 abstract description 6
238000000034 method Methods 0.000 description 29
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 29
239000012071 phase Substances 0.000 description 23
239000003054 catalyst Substances 0.000 description 20
239000007789 gas Substances 0.000 description 20
238000006116 polymerization reaction Methods 0.000 description 15
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 13
239000002002 slurry Substances 0.000 description 13
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 11
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 11
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 11
239000000463 material Substances 0.000 description 11
238000005259 measurement Methods 0.000 description 11
150000001993 dienes Chemical class 0.000 description 10
238000002156 mixing Methods 0.000 description 10
239000003973 paint Substances 0.000 description 10
238000012360 testing method Methods 0.000 description 10
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 9
238000002360 preparation method Methods 0.000 description 9
239000000047 product Substances 0.000 description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 8
LDLDYFCCDKENPD-UHFFFAOYSA-N ethenylcyclohexane Chemical compound C=CC1CCCCC1 LDLDYFCCDKENPD-UHFFFAOYSA-N 0.000 description 8
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 8
239000004698 Polyethylene Substances 0.000 description 7
239000000654 additive Substances 0.000 description 7
125000004432 carbon atom Chemical group C* 0.000 description 7
229920000573 polyethylene Polymers 0.000 description 7
239000002987 primer (paints) Substances 0.000 description 7
FMZUHGYZWYNSOA-VVBFYGJXSA-N (1r)-1-[(4r,4ar,8as)-2,6-diphenyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C([C@@H]1OC(O[C@@H]([C@@H]1O1)[C@H](O)CO)C=2C=CC=CC=2)OC1C1=CC=CC=C1 FMZUHGYZWYNSOA-VVBFYGJXSA-N 0.000 description 6
229920000181 Ethylene propylene rubber Polymers 0.000 description 6
229920001971 elastomer Polymers 0.000 description 6
TWRXJAOTZQYOKJ-UHFFFAOYSA-L magnesium chloride Substances [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 6
239000000178 monomer Substances 0.000 description 6
238000004062 sedimentation Methods 0.000 description 6
125000000217 alkyl group Chemical group 0.000 description 5
238000002844 melting Methods 0.000 description 5
230000008018 melting Effects 0.000 description 5
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
239000000126 substance Substances 0.000 description 5
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 4
238000005481 NMR spectroscopy Methods 0.000 description 4
238000002425 crystallisation Methods 0.000 description 4
230000008025 crystallization Effects 0.000 description 4
FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 4
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 4
239000007788 liquid Substances 0.000 description 4
229910001629 magnesium chloride Inorganic materials 0.000 description 4
TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
239000002667 nucleating agent Substances 0.000 description 4
239000007921 spray Substances 0.000 description 4
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 4
229920002554 vinyl polymer Polymers 0.000 description 4
PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 3
PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
FUDNBFMOXDUIIE-UHFFFAOYSA-N 3,7-dimethylocta-1,6-diene Chemical compound C=CC(C)CCC=C(C)C FUDNBFMOXDUIIE-UHFFFAOYSA-N 0.000 description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
229910003074 TiCl4 Inorganic materials 0.000 description 3
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
239000011954 Ziegler–Natta catalyst Substances 0.000 description 3
125000001931 aliphatic group Chemical group 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
230000000052 comparative effect Effects 0.000 description 3
125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 3
229940087101 dibenzylidene sorbitol Drugs 0.000 description 3
JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 3
229920001038 ethylene copolymer Polymers 0.000 description 3
229910052739 hydrogen Inorganic materials 0.000 description 3
239000001257 hydrogen Substances 0.000 description 3
238000001746 injection moulding Methods 0.000 description 3
125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 3
KOFGHHIZTRGVAF-UHFFFAOYSA-N n-ethyl-n-triethoxysilylethanamine Chemical compound CCO[Si](OCC)(OCC)N(CC)CC KOFGHHIZTRGVAF-UHFFFAOYSA-N 0.000 description 3
229910052719 titanium Inorganic materials 0.000 description 3
239000010936 titanium Substances 0.000 description 3
238000005809 transesterification reaction Methods 0.000 description 3
YWEWWNPYDDHZDI-JJKKTNRVSA-N (1r)-1-[(4r,4ar,8as)-2,6-bis(3,4-dimethylphenyl)-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C1=C(C)C(C)=CC=C1C1O[C@H]2[C@@H]([C@H](O)CO)OC(C=3C=C(C)C(C)=CC=3)O[C@H]2CO1 YWEWWNPYDDHZDI-JJKKTNRVSA-N 0.000 description 2
ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
BJQHLKABXJIVAM-BGYRXZFFSA-N 1-o-[(2r)-2-ethylhexyl] 2-o-[(2s)-2-ethylhexyl] benzene-1,2-dicarboxylate Chemical compound CCCC[C@H](CC)COC(=O)C1=CC=CC=C1C(=O)OC[C@H](CC)CCCC BJQHLKABXJIVAM-BGYRXZFFSA-N 0.000 description 2
HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 2
229920002943 EPDM rubber Polymers 0.000 description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
239000013065 commercial product Substances 0.000 description 2
238000012937 correction Methods 0.000 description 2
125000000753 cycloalkyl group Chemical group 0.000 description 2
125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
238000000113 differential scanning calorimetry Methods 0.000 description 2
YCZJVRCZIPDYHH-UHFFFAOYSA-N ditridecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCCC YCZJVRCZIPDYHH-UHFFFAOYSA-N 0.000 description 2
239000000806 elastomer Substances 0.000 description 2
238000001125 extrusion Methods 0.000 description 2
230000005484 gravity Effects 0.000 description 2
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 2
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
239000007791 liquid phase Substances 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
238000000465 moulding Methods 0.000 description 2
125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
JGMMIGGLIIRHFV-UHFFFAOYSA-N nonane-1,2,3,4,5,6,7,8,9-nonol Chemical class OCC(O)C(O)C(O)C(O)C(O)C(O)C(O)CO JGMMIGGLIIRHFV-UHFFFAOYSA-N 0.000 description 2
125000002524 organometallic group Chemical group 0.000 description 2
239000008188 pellet Substances 0.000 description 2
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
238000011002 quantification Methods 0.000 description 2
239000011541 reaction mixture Substances 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
239000011949 solid catalyst Substances 0.000 description 2
239000000600 sorbitol Substances 0.000 description 2
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
238000005406 washing Methods 0.000 description 2
OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 1
KEMUGHMYINTXKW-NQOXHWNZSA-N (1z,5z)-cyclododeca-1,5-diene Chemical compound C1CCC\C=C/CC\C=C/CC1 KEMUGHMYINTXKW-NQOXHWNZSA-N 0.000 description 1
CHMCAIRITMOPFF-CGXNFDGLSA-N (3R,4S,5R,6S)-3-methyl-1,8-diphenylocta-1,7-diene-2,3,4,5,6,7-hexol Chemical compound C[C@@](C(O)=CC1=CC=CC=C1)(O)[C@@H](O)[C@H](O)[C@H](O)C(O)=CC1=CC=CC=C1 CHMCAIRITMOPFF-CGXNFDGLSA-N 0.000 description 1
RJUCIROUEDJQIB-GQCTYLIASA-N (6e)-octa-1,6-diene Chemical compound C\C=C\CCCC=C RJUCIROUEDJQIB-GQCTYLIASA-N 0.000 description 1
PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 1
VYXHVRARDIDEHS-UHFFFAOYSA-N 1,5-cyclooctadiene Chemical compound C1CC=CCCC=C1 VYXHVRARDIDEHS-UHFFFAOYSA-N 0.000 description 1
239000004912 1,5-cyclooctadiene Substances 0.000 description 1
PPWUTZVGSFPZOC-UHFFFAOYSA-N 1-methyl-2,3,3a,4-tetrahydro-1h-indene Chemical compound C1C=CC=C2C(C)CCC21 PPWUTZVGSFPZOC-UHFFFAOYSA-N 0.000 description 1
YXRZFCBXBJIBAP-UHFFFAOYSA-N 2,6-dimethylocta-1,7-diene Chemical compound C=CC(C)CCCC(C)=C YXRZFCBXBJIBAP-UHFFFAOYSA-N 0.000 description 1
OEGQMCQKZSQYBV-UHFFFAOYSA-N 2-nonan-4-yloxycarbonylbenzoic acid Chemical compound CCCCCC(CCC)OC(=O)C1=CC=CC=C1C(O)=O OEGQMCQKZSQYBV-UHFFFAOYSA-N 0.000 description 1
UFERIGCCDYCZLN-UHFFFAOYSA-N 3a,4,7,7a-tetrahydro-1h-indene Chemical compound C1C=CCC2CC=CC21 UFERIGCCDYCZLN-UHFFFAOYSA-N 0.000 description 1
BBDKZWKEPDTENS-UHFFFAOYSA-N 4-Vinylcyclohexene Chemical compound C=CC1CCC=CC1 BBDKZWKEPDTENS-UHFFFAOYSA-N 0.000 description 1
IZLXZVWFPZWXMZ-UHFFFAOYSA-N 5-cyclohexylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1=CC2CC1CC2=C1CCCCC1 IZLXZVWFPZWXMZ-UHFFFAOYSA-N 0.000 description 1
BDEXHIMNEUYKBS-UHFFFAOYSA-N 5-cyclopent-2-en-1-ylbicyclo[2.2.1]hept-2-ene Chemical compound C1=CCCC1C1C(C=C2)CC2C1 BDEXHIMNEUYKBS-UHFFFAOYSA-N 0.000 description 1
VSQLAQKFRFTMNS-UHFFFAOYSA-N 5-methylhexa-1,4-diene Chemical compound CC(C)=CCC=C VSQLAQKFRFTMNS-UHFFFAOYSA-N 0.000 description 1
WTQBISBWKRKLIJ-UHFFFAOYSA-N 5-methylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C)CC1C=C2 WTQBISBWKRKLIJ-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
IJFPVINAQGWBRJ-UHFFFAOYSA-N Diisooctyl phthalate Chemical compound CC(C)CCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCC(C)C IJFPVINAQGWBRJ-UHFFFAOYSA-N 0.000 description 1
229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
229920000034 Plastomer Polymers 0.000 description 1
BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
230000003213 activating effect Effects 0.000 description 1
125000005234 alkyl aluminium group Chemical group 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
238000003556 assay Methods 0.000 description 1
FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 1
239000010866 blackwater Substances 0.000 description 1
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
235000013539 calcium stearate Nutrition 0.000 description 1
239000008116 calcium stearate Substances 0.000 description 1
238000001460 carbon-13 nuclear magnetic resonance spectrum Methods 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
239000002131 composite material Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000000748 compression moulding Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
UVJHQYIOXKWHFD-UHFFFAOYSA-N cyclohexa-1,4-diene Chemical compound C1C=CCC=C1 UVJHQYIOXKWHFD-UHFFFAOYSA-N 0.000 description 1
HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 1
DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical compound CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 description 1
125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
UHOVQNZJYSORNB-MICDWDOJSA-N deuteriobenzene Chemical compound [2H]C1=CC=CC=C1 UHOVQNZJYSORNB-MICDWDOJSA-N 0.000 description 1
238000010586 diagram Methods 0.000 description 1
GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 1
VHPUZTHRFWIGAW-UHFFFAOYSA-N dimethoxy-di(propan-2-yl)silane Chemical compound CO[Si](OC)(C(C)C)C(C)C VHPUZTHRFWIGAW-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
125000004185 ester group Chemical group 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000000945 filler Substances 0.000 description 1
230000004927 fusion Effects 0.000 description 1
235000021189 garnishes Nutrition 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
150000002430 hydrocarbons Chemical group 0.000 description 1
229910001701 hydrotalcite Inorganic materials 0.000 description 1
229960001545 hydrotalcite Drugs 0.000 description 1
238000009863 impact test Methods 0.000 description 1
238000004898 kneading Methods 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
150000002848 norbornenes Chemical class 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
238000012805 post-processing Methods 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000002203 pretreatment Methods 0.000 description 1
239000013615 primer Substances 0.000 description 1
238000012545 processing Methods 0.000 description 1
239000000376 reactant Substances 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
235000010234 sodium benzoate Nutrition 0.000 description 1
239000004299 sodium benzoate Substances 0.000 description 1
ZHROMWXOTYBIMF-UHFFFAOYSA-M sodium;1,3,7,9-tetratert-butyl-11-oxido-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Na+].C1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP([O-])(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C ZHROMWXOTYBIMF-UHFFFAOYSA-M 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000000638 solvent extraction Methods 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
239000000758 substrate Substances 0.000 description 1
238000004381 surface treatment Methods 0.000 description 1
238000011282 treatment Methods 0.000 description 1
ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 1
AZSKHRTUXHLAHS-UHFFFAOYSA-N tris(2,4-di-tert-butylphenyl) phosphate Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(=O)(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C AZSKHRTUXHLAHS-UHFFFAOYSA-N 0.000 description 1
PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/02—Heterophasic composition
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)
Paints Or Removers (AREA)
Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
Manufacturing & Machinery (AREA)
Materials Engineering (AREA)
Engineering & Computer Science (AREA)
Body Structure For Vehicles (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

CN201480027634.4A 2013-05-31 2014-05-15 适用于无底漆涂装的刚性聚丙烯组合物 Active CN105745270B (zh)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
EP13170001		2013-05-31
EP13170001.5		2013-05-31
PCT/EP2014/059912 WO2014191211A1 (en)	2013-05-31	2014-05-15	Stiff polypropylene composition suitable for primerless painting

Publications (2)

Publication Number	Publication Date
CN105745270A CN105745270A (zh)	2016-07-06
CN105745270B true CN105745270B (zh)	2017-11-24

Family

ID=48520828

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CN201480027634.4A Active CN105745270B (zh)	2013-05-31	2014-05-15	适用于无底漆涂装的刚性聚丙烯组合物

Country Status (12)

Country	Link
US (1)	US9701825B2 (ko)
EP (1)	EP3004240B8 (ko)
JP (1)	JP6144411B2 (ko)
KR (1)	KR101787866B1 (ko)
CN (1)	CN105745270B (ko)
BR (1)	BR112015028770B1 (ko)
CA (1)	CA2907978C (ko)
EA (1)	EA033398B1 (ko)
ES (1)	ES2640797T3 (ko)
MX (1)	MX363416B (ko)
WO (1)	WO2014191211A1 (ko)
ZA (1)	ZA201505853B (ko)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP3127951B1 (en) *	2015-08-03	2019-10-09	Borealis AG	Polypropylene composition suitable for foamed sheets and articles
MX365523B (es) *	2015-11-17	2019-06-06	Borealis Ag	Composicion de poliolefina termoplastica (tpo) de flujo elevado con excelente impacto a baja temperatura.
BR112018009394B1 (pt) *	2015-11-17	2022-05-03	Borealis Ag	Copolímero de propileno heterofásico, composição de poliolefina, artigo automotivo, processo para preparação de uma composição de poliolefina, e, uso de um copolímero de propileno heterofásico
KR20180103570A (ko)	2017-03-10	2018-09-19	현대자동차주식회사	폴리프로필렌 수지 조성물 및 이의 성형품
JP6853387B2 (ja) *	2017-06-30	2021-03-31	ボレアリスエージー	優れた外観を備えるポリプロピレン組成物
EP3489297B1 (en) *	2017-11-28	2021-08-04	Borealis AG	Polymer composition with improved paint adhesion
ES2890961T3 (es) *	2017-11-28	2022-01-25	Borealis Ag	Composición de polímero con adherencia de la pintura mejorada
CN111655781A (zh) *	2018-01-22	2020-09-11	Sabic环球技术有限责任公司	具有改进的escr耐性的聚烯烃组合物
SG11202012149VA (en) *	2018-06-15	2021-01-28	Borealis Ag	Flame retardant polyolefin composition
EP3620486B1 (en)	2018-09-06	2020-11-18	Borealis AG	Polypropylene based composition with improved paintability
EP3620487B1 (en)	2018-09-06	2020-11-18	Borealis AG	Polypropylene based composition with improved paintability
EP3647356B8 (en) *	2018-10-31	2022-03-30	Borealis AG	Polyolefin composition with improved balance of properties
EP3914645A1 (en) *	2019-01-25	2021-12-01	Abu Dhabi Polymers Co. Ltd (Borouge) Llc.	Foamable polypropylene composition with excellent mechanical performance
KR102587753B1 (ko) *	2021-08-31	2023-10-11	한화토탈에너지스 주식회사	폴리프로필렌 수지 조성물 및 이로부터 제조된 성형품
WO2024094676A1 (en)	2022-10-31	2024-05-10	Borealis Ag	Compositon for automotive exterior parts

Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP2410007A1 (en) *	2010-07-22	2012-01-25	Borealis AG	Polypropylene/talc composition with improved impact behavior
CN102449047A (zh) *	2009-06-09	2012-05-09	博里利斯股份公司	具有优异流动性、高硬度、优异延展性和低线性热膨胀系数的汽车材料

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FI80055C (fi)	1986-06-09	1990-04-10	Neste Oy	Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner.
FI86866C (fi)	1990-12-19	1992-10-26	Neste Oy	Foerfarande foer modifiering av katalysatorer avsedda foer polymerisation av olefiner
FI86867C (fi)	1990-12-28	1992-10-26	Neste Oy	Flerstegsprocess foer framstaellning av polyeten
FI88047C (fi)	1991-05-09	1993-03-25	Neste Oy	Pao tvenne elektrondonorer baserad katalysator foer polymerisation av olefiner
FI88048C (fi)	1991-05-09	1993-03-25	Neste Oy	Grovkornig polyolefin, dess framstaellningsmetod och en i metoden anvaend katalysator
JP2849574B2 (ja) *	1995-06-27	1999-01-20	三井化学株式会社	自動車バンパー用樹脂組成物及びそれから得られた自動車バンパー
JPH09194646A (ja) *	1996-01-17	1997-07-29	Mitsui Petrochem Ind Ltd	ポリプロピレン系樹脂組成物
FI111848B (fi)	1997-06-24	2003-09-30	Borealis Tech Oy	Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi
FI980342A0 (fi)	1997-11-07	1998-02-13	Borealis As	Polymerroer och -roerkopplingar
FI974175A (fi)	1997-11-07	1999-05-08	Borealis As	Menetelmä polypropeenin valmistamiseksi
FI991057A0 (fi)	1999-05-07	1999-05-07	Borealis As	Korkean jäykkyyden propeenipolymeerit ja menetelmä niiden valmistamiseksi
ATE499392T1 (de)	2002-06-25	2011-03-15	Borealis Tech Oy	Polyolefin mit verbesserter kratzfestigkeit und verfahren zu seiner herstelung
EP1484343A1 (en)	2003-06-06	2004-12-08	Universiteit Twente	Process for the catalytic polymerization of olefins, a reactor system and its use in the same process
JP5005660B2 (ja) *	2008-11-17	2012-08-22	株式会社プライムポリマー	自動車内装用ポリプロピレン樹脂組成物
EP2495280A1 (en)	2011-03-03	2012-09-05	Borealis AG	Polyolefin composition with low CLTE and reduced occurrence of flow marks
EP2495264B1 (en)	2011-03-04	2013-05-08	Borealis AG	Exterior automotive article with reduced paintability failure

2014
- 2014-05-15 CA CA2907978A patent/CA2907978C/en not_active Expired - Fee Related
- 2014-05-15 BR BR112015028770-0A patent/BR112015028770B1/pt active IP Right Grant
- 2014-05-15 EA EA201501128A patent/EA033398B1/ru not_active IP Right Cessation
- 2014-05-15 MX MX2015015591A patent/MX363416B/es unknown
- 2014-05-15 EP EP14727742.0A patent/EP3004240B8/en active Active
- 2014-05-15 US US14/891,053 patent/US9701825B2/en active Active
- 2014-05-15 JP JP2016508198A patent/JP6144411B2/ja not_active Ceased
- 2014-05-15 ES ES14727742.0T patent/ES2640797T3/es active Active
- 2014-05-15 WO PCT/EP2014/059912 patent/WO2014191211A1/en active Application Filing
- 2014-05-15 CN CN201480027634.4A patent/CN105745270B/zh active Active
- 2014-05-15 KR KR1020157035511A patent/KR101787866B1/ko active IP Right Grant
2015
- 2015-08-14 ZA ZA201505853A patent/ZA201505853B/en unknown

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN102449047A (zh) *	2009-06-09	2012-05-09	博里利斯股份公司	具有优异流动性、高硬度、优异延展性和低线性热膨胀系数的汽车材料
EP2410007A1 (en) *	2010-07-22	2012-01-25	Borealis AG	Polypropylene/talc composition with improved impact behavior

Also Published As

Publication number	Publication date
CN105745270A (zh)	2016-07-06
EP3004240B1 (en)	2017-07-05
CA2907978C (en)	2018-06-05
KR20160010543A (ko)	2016-01-27
MX2015015591A (es)	2016-03-03
JP6144411B2 (ja)	2017-06-07
MX363416B (es)	2019-03-22
BR112015028770B1 (pt)	2020-09-01
EP3004240B8 (en)	2017-08-09
BR112015028770A2 (pt)	2017-07-25
WO2014191211A1 (en)	2014-12-04
EA201501128A1 (ru)	2016-05-31
CA2907978A1 (en)	2014-12-04
EP3004240A1 (en)	2016-04-13
JP2016516863A (ja)	2016-06-09
US9701825B2 (en)	2017-07-11
US20160108219A1 (en)	2016-04-21
ZA201505853B (en)	2019-10-30
EA033398B1 (ru)	2019-10-31
ES2640797T3 (es)	2017-11-06
KR101787866B1 (ko)	2017-10-18

Publication	Publication Date	Title
CN105745270B (zh)	2017-11-24	适用于无底漆涂装的刚性聚丙烯组合物
KR101982995B1 (ko)	2019-05-27	자동차용 폴리프로필렌 조성물
EP2915846B1 (en)	2016-09-07	High flow polyolefin composition with low shrinkage and clte
CN108559179B (zh)	2021-06-29	虎纹改性剂
EP2275485B1 (en)	2011-06-08	Heterophasic polypropylene copolymer composition
AU2010305546B2 (en)	2013-05-09	Glass fibre composite of improved processability
CN104884525B (zh)	2016-08-31	虎纹改性剂
KR101650637B1 (ko)	2016-08-23	균형잡힌 특성 프로파일을 갖는 저 충전된 폴리프로필렌 조성물
EP2758467A1 (en)	2014-07-30	Heterophasic propylene copolymer with excellent stiffness and impact balance
US9783666B2 (en)	2017-10-10	Polypropylene composition with excellent paint adhesion
EP2586823A1 (en)	2013-05-01	Heterophasic propylene copolymer comprising an external plastomeric olefin copolymer
US10392492B2 (en)	2019-08-27	Polypropylene composition suitable for primerless painting
CN108495867B (zh)	2020-08-25	具有低clte的多相丙烯共聚物
CA3002116C (en)	2018-11-06	Heterophasic composition
WO2014095848A1 (en)	2014-06-26	Automotive compound with reduced tigerskin

Legal Events

Date	Code	Title
2016-07-06	C06	Publication
2016-07-06	PB01	Publication
2016-08-03	C10	Entry into substantive examination
2016-08-03	SE01	Entry into force of request for substantive examination
2017-11-24	GR01	Patent grant
2017-11-24	GR01	Patent grant