CN104877577B - A kind of anti-oxidant adhesive composition with ultraviolet radiation absorption function - Google Patents
A kind of anti-oxidant adhesive composition with ultraviolet radiation absorption function Download PDFInfo
- Publication number
- CN104877577B CN104877577B CN201510348003.9A CN201510348003A CN104877577B CN 104877577 B CN104877577 B CN 104877577B CN 201510348003 A CN201510348003 A CN 201510348003A CN 104877577 B CN104877577 B CN 104877577B
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- parts
- adhesive composition
- ultraviolet radiation
- absorption function
- radiation absorption
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- 239000000203 mixture Substances 0.000 title claims abstract description 24
- 239000000853 adhesive Substances 0.000 title claims abstract description 22
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 22
- 239000003963 antioxidant agent Substances 0.000 title claims abstract description 14
- 230000003078 antioxidant effect Effects 0.000 title claims abstract description 14
- 235000006708 antioxidants Nutrition 0.000 title claims abstract description 14
- 230000005855 radiation Effects 0.000 title claims abstract description 9
- 238000010521 absorption reaction Methods 0.000 title claims abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 10
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 16
- YDQWDHRMZQUTBA-UHFFFAOYSA-N Aloe emodin Chemical compound C1=CC=C2C(=O)C3=CC(CO)=CC(O)=C3C(=O)C2=C1O YDQWDHRMZQUTBA-UHFFFAOYSA-N 0.000 claims description 9
- 239000002270 dispersing agent Substances 0.000 claims description 9
- VMJOFTHFJMLIKL-UHFFFAOYSA-N 2-thiophen-2-ylethanol Chemical compound OCCC1=CC=CS1 VMJOFTHFJMLIKL-UHFFFAOYSA-N 0.000 claims description 8
- 229920002101 Chitin Polymers 0.000 claims description 8
- WYQVAPGDARQUBT-FGWHUCSPSA-N Madecassol Chemical compound O([C@@H]1[C@@H](CO)O[C@H]([C@@H]([C@H]1O)O)OC[C@H]1O[C@H]([C@@H]([C@@H](O)[C@@H]1O)O)OC(=O)[C@]12CC[C@H]([C@@H]([C@H]1C=1[C@@]([C@@]3(CC[C@H]4[C@](C)(CO)[C@@H](O)[C@H](O)C[C@]4(C)[C@H]3CC=1)C)(C)CC2)C)C)[C@@H]1O[C@@H](C)[C@H](O)[C@@H](O)[C@H]1O WYQVAPGDARQUBT-FGWHUCSPSA-N 0.000 claims description 8
- OLLPXZHNCXACMM-CMDGGOBGSA-N Propyl cinnamate Chemical compound CCCOC(=O)\C=C\C1=CC=CC=C1 OLLPXZHNCXACMM-CMDGGOBGSA-N 0.000 claims description 8
- 229920000180 alkyd Polymers 0.000 claims description 8
- WYQVAPGDARQUBT-XCWYDTOWSA-N asiaticoside Natural products O=C(O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@H]2[C@H](O)[C@H](O)[C@H](O[C@H]3[C@H](O)[C@H](O)[C@@H](O)[C@H](C)O3)[C@@H](CO)O2)O1)[C@@]12[C@@H]([C@@H](C)[C@H](C)CC1)C=1[C@](C)([C@@]3(C)[C@@H]([C@@]4(C)[C@H]([C@@](CO)(C)[C@@H](O)[C@H](O)C4)CC3)CC=1)CC2 WYQVAPGDARQUBT-XCWYDTOWSA-N 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 8
- YCBSHDKATAPNIA-UHFFFAOYSA-N non-3-ene Chemical compound CCCCCC=CCC YCBSHDKATAPNIA-UHFFFAOYSA-N 0.000 claims description 8
- -1 phenyl ester Chemical class 0.000 claims description 8
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 8
- 239000004800 polyvinyl chloride Substances 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 7
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000003292 glue Substances 0.000 claims 1
- 239000012752 auxiliary agent Substances 0.000 abstract description 3
- 239000011230 binding agent Substances 0.000 description 11
- 238000013329 compounding Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000004224 protection Effects 0.000 description 2
- 230000006750 UV protection Effects 0.000 description 1
- 239000011157 advanced composite material Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000016507 interphase Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of anti-oxidant adhesive composition with ultraviolet radiation absorption function, resin and the auxiliary agent of number of different types is contained in the adhesive composition of the present invention, and the combination of each component makes the adhesive composition of the present invention have good ultraviolet radiation resisting, the performance of resistance to difference variation.
Description
Technical field
The present invention relates to a kind of anti-oxidant adhesive composition of ultraviolet radiation absorption function.
Background technology
With the fast development of China's Material Field, a large amount of advanced composite material (ACM)s with excellent properties are widely used
In the infrastructure such as building, railway, highway, the every field such as Aero-Space, medical treatment, household electrical appliances.Numerous feature binding agents also should
Transport and give birth to.In many multifunctional binders, anti-oxidant UV resistance binding agent is a kind of important function binding agent, and its effect is right
The binder temperature that the ultraviolet radioactive of sunshine is caused in external environment changes and oxidation is controlled by, and binding agent is had anti-ageing
Change and oxidation protection effect.The temperature control effect of existing at present anti-oxidant binding agent and non-oxidizability still suffer from many problems, still
Need to continue to improve.
Content of the invention
In order to overcome the deficiencies in the prior art, the invention provides a kind of anti-oxidant adhesive composition, the binding agent group
The resin of number of different types and auxiliary agent used in compound, the combination of each component make it have good ultraviolet radiation resisting,
The performance of resistance to difference variation.
The technical scheme adopted by present invention solution above-mentioned technical problem is as follows：
A kind of anti-oxidant adhesive composition, the adhesive composition are made up of the raw material of following parts by weight：
Styrene-acrylic copolymer emulsion 10-15 part
Polyvinyl chloride resin 4-12 part
Alkyd resin 5-10 part
Diphenylethyllene phenol APEO 1-3 part
Asiaticosid 1-4 part
1,8- dihydroxy -3- methylol anthraquinone 6-12 part
Cinnamic acid propyl ester 5-10 part
2- thiophene ethanol 1-2 part
3- nonene -2- ketone 0.2-1 part
Phthalocyanine blue 0.1-0.5 part
Zirconia powder 1-3 part
Chitin 0.8-5 part
Septichen phenyl ester 1-3 part
Dispersant 1-5 part
Deionized water 40-50 part.
Preferably, the adhesive composition is made up of the raw material of following parts by weight：
12 parts of Styrene-acrylic copolymer emulsion
8 parts of polyvinyl chloride resin
8 parts of alkyd resin
2 parts of diphenylethyllene phenol APEO
3 parts of asiaticosid
8 parts of 1,8- dihydroxy -3- methylol anthraquinone
7 parts of cinnamic acid propyl ester
1.5 parts of 2- thiophene ethanol
0.6 part of 3- nonene -2- ketone
0.3 part of phthalocyanine blue
2 parts of zirconia powder
2 parts of chitin
2 parts of septichen phenyl ester
3 parts of dispersant
45 parts of deionized water.
Beneficial effect
The combination of various kinds of resin and auxiliary agent, such as alkyd resin, PVC tree is employed in the adhesive composition of the present invention
Fat, Aloe-emodin, the compounding of asiaticosid generate cooperative effect, the modified tack of binding agent,
Resistance to water.Cinnamic acid propyl ester, 2- thiophene ethanol, the compounding use of 3- nonene -2- ketone improve the heatproof of binding agent
Denaturation.Septichen phenyl ester, Styrene-acrylic copolymer emulsion, zirconia powder, the compounding use of chitin improve
Binding agent absorbs the ability of ultraviolet, the interphase interaction that each group is divided so that adhesive composition has excellent uvioresistant
Irradiate the performance with resistance to difference variation.
Specific embodiment
Below by specific embodiment, the present invention is described in detail, but the scope of protection of present invention is not limited to
Scope in embodiment expression.
Embodiment 1
A kind of anti-oxidant adhesive composition, the adhesive composition are made up of the raw material of following parts by weight：
10 parts of Styrene-acrylic copolymer emulsion
4 parts of polyvinyl chloride resin
5 parts of alkyd resin
1 part of diphenylethyllene phenol APEO
1 part of asiaticosid
6 parts of 1,8- dihydroxy -3- methylol anthraquinone
5 parts of cinnamic acid propyl ester
1 part of 2- thiophene ethanol
0.2 part of 3- nonene -2- ketone
0.1 part of phthalocyanine blue
1 part of zirconia powder
0.8 part of chitin
1 part of septichen phenyl ester
1 part of dispersant
40 parts of deionized water.
Embodiment 2
A kind of anti-oxidant adhesive composition, the adhesive composition are made up of the raw material of following parts by weight：
15 parts of Styrene-acrylic copolymer emulsion
12 parts of polyvinyl chloride resin
10 parts of alkyd resin
3 parts of diphenylethyllene phenol APEO
4 parts of asiaticosid
12 parts of 1,8- dihydroxy -3- methylol anthraquinone
10 parts of cinnamic acid propyl ester
2 parts of 2- thiophene ethanol
1 part of 3- nonene -2- ketone
0.5 part of phthalocyanine blue
3 parts of zirconia powder
5 parts of chitin
3 parts of septichen phenyl ester
5 parts of dispersant
50 parts of deionized water.
Embodiment 3
A kind of anti-oxidant adhesive composition, the adhesive composition are made up of the raw material of following parts by weight：
12 parts of Styrene-acrylic copolymer emulsion
8 parts of polyvinyl chloride resin
8 parts of alkyd resin
2 parts of diphenylethyllene phenol APEO
3 parts of asiaticosid
8 parts of 1,8- dihydroxy -3- methylol anthraquinone
7 parts of cinnamic acid propyl ester
1.5 parts of 2- thiophene ethanol
0.6 part of 3- nonene -2- ketone
0.3 part of phthalocyanine blue
2 parts of zirconia powder
2 parts of chitin
2 parts of septichen phenyl ester
3 parts of dispersant
45 parts of deionized water.
Claims (3)
1. a kind of anti-oxidant adhesive composition with ultraviolet radiation absorption function, it is characterised in that the adhesive composition by
The raw material composition of following parts by weight：
Styrene-acrylic copolymer emulsion 10-15 part
Polyvinyl chloride resin 4-12 part
Alkyd resin 5-10 part
Diphenylethyllene phenol APEO 1-3 part
Asiaticosid 1-4 part
1,8- dihydroxy -3- methylol anthraquinone 6-12 part
Cinnamic acid propyl ester 5-10 part
2- thiophene ethanol 1-2 part
3- nonene -2- ketone 0.2-1 part
Phthalocyanine blue 0.1-0.5 part
Zirconia powder 1-3 part
Chitin 0.8-5 part
Septichen phenyl ester 1-3 part
Dispersant 1-5 part
Deionized water 40-50 part.
2. there is the anti-oxidant adhesive composition of ultraviolet radiation absorption function as claimed in claim 1, it is characterised in that：This glues
Knot agent composition is made up of the raw material of following parts by weight：
12 parts of Styrene-acrylic copolymer emulsion
8 parts of polyvinyl chloride resin
8 parts of alkyd resin
2 parts of diphenylethyllene phenol APEO
3 parts of asiaticosid
8 parts of 1,8- dihydroxy -3- methylol anthraquinone
7 parts of cinnamic acid propyl ester
1.5 parts of 2- thiophene ethanol
0.6 part of 3- nonene -2- ketone
0.3 part of phthalocyanine blue
2 parts of zirconia powder
2 parts of chitin
2 parts of septichen phenyl ester
3 parts of dispersant
45 parts of deionized water.
3. there is the anti-oxidant adhesive composition of ultraviolet radiation absorption function as claimed in claim 1, it is characterised in that：Described
Dispersant be macromolecular waterproof type dispersant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510348003.9A CN104877577B (en) | 2015-06-23 | 2015-06-23 | A kind of anti-oxidant adhesive composition with ultraviolet radiation absorption function |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510348003.9A CN104877577B (en) | 2015-06-23 | 2015-06-23 | A kind of anti-oxidant adhesive composition with ultraviolet radiation absorption function |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104877577A CN104877577A (en) | 2015-09-02 |
| CN104877577B true CN104877577B (en) | 2017-03-08 |
Family
ID=53945266
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510348003.9A Active CN104877577B (en) | 2015-06-23 | 2015-06-23 | A kind of anti-oxidant adhesive composition with ultraviolet radiation absorption function |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104877577B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101045847A (en) * | 2006-03-31 | 2007-10-03 | 中国科学院过程工程研究所 | Adhesive and paint for absorbing formol |
| CN103173157A (en) * | 2013-03-25 | 2013-06-26 | 上海晶华粘胶制品发展有限公司 | Hydrophobic masking tape and preparation method thereof |
| CN104341986A (en) * | 2014-10-14 | 2015-02-11 | 凤阳徽亨商贸有限公司 | Acid/alkali-corrosion-resistant high-hardness paint for glass doors and preparation method thereof |
| CN104428378A (en) * | 2012-07-06 | 2015-03-18 | 巴斯夫欧洲公司 | Use of aqueous hybrid binders and alkyd systems for coating agents |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101679801A (en) * | 2007-06-15 | 2010-03-24 | 巴斯夫欧洲公司 | low-voc aqueous hybrid binder |
-
2015
- 2015-06-23 CN CN201510348003.9A patent/CN104877577B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101045847A (en) * | 2006-03-31 | 2007-10-03 | 中国科学院过程工程研究所 | Adhesive and paint for absorbing formol |
| CN104428378A (en) * | 2012-07-06 | 2015-03-18 | 巴斯夫欧洲公司 | Use of aqueous hybrid binders and alkyd systems for coating agents |
| CN103173157A (en) * | 2013-03-25 | 2013-06-26 | 上海晶华粘胶制品发展有限公司 | Hydrophobic masking tape and preparation method thereof |
| CN104341986A (en) * | 2014-10-14 | 2015-02-11 | 凤阳徽亨商贸有限公司 | Acid/alkali-corrosion-resistant high-hardness paint for glass doors and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN104877577A (en) | 2015-09-02 |
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| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information |
Inventor after: Du Yifang Inventor after: Yan Xindong Inventor after: Zhang Weizhi Inventor before: Zhou Meiqin |
|
| COR | Change of bibliographic data | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP02 | Change in the address of a patent holder | ||
| CP02 | Change in the address of a patent holder |
Address after: No. 1088, Zhongxing North Road, Buxi street, Deqing County, Huzhou City, Zhejiang Province Patentee after: Zhou Meiqin Address before: 311821 Zhejiang city of Shaoxing province Zhuji City Hua Zhen Xin Zhai Cun on No. 100 Patentee before: Zhou Meiqin |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200506 Address after: 264200 automobile repair South workshop, xihengtong, Qingdao Road, songjiawa, Weihai Economic and Technological Zone, Weihai City, Shandong Province Patentee after: Weihai BORANG yacht Co.,Ltd. Address before: No. 1088, Zhongxing North Road, Buxi street, Deqing County, Huzhou City, Zhejiang Province Patentee before: Zhou Meiqin |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: An antioxidant binder composition with UV absorption function Effective date of registration: 20230913 Granted publication date: 20170308 Pledgee: China Construction Bank Corporation Weihai Economic Development Sub branch Pledgor: Weihai BORANG yacht Co.,Ltd. Registration number: Y2023980056597 |