CN104893622B - A kind of antioxidation adhesive composition - Google Patents
A kind of antioxidation adhesive composition Download PDFInfo
- Publication number
- CN104893622B CN104893622B CN201510347836.3A CN201510347836A CN104893622B CN 104893622 B CN104893622 B CN 104893622B CN 201510347836 A CN201510347836 A CN 201510347836A CN 104893622 B CN104893622 B CN 104893622B
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- CN
- China
- Prior art keywords
- parts
- adhesive composition
- antioxidation
- dispersant
- nonene
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 24
- 239000000853 adhesive Substances 0.000 title claims abstract description 23
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 23
- 230000003064 anti-oxidating effect Effects 0.000 title claims abstract description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 16
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 16
- 239000000843 powder Substances 0.000 claims description 16
- 239000002270 dispersing agent Substances 0.000 claims description 9
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims description 8
- OLLPXZHNCXACMM-CMDGGOBGSA-N Propyl cinnamate Chemical compound CCCOC(=O)\C=C\C1=CC=CC=C1 OLLPXZHNCXACMM-CMDGGOBGSA-N 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 8
- 229920000180 alkyd Polymers 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 8
- -1 phenyl ester Chemical class 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 229920002050 silicone resin Polymers 0.000 claims description 8
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 8
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 7
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 7
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 7
- 239000002994 raw material Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 abstract description 3
- 230000005855 radiation Effects 0.000 abstract description 3
- 229920005989 resin Polymers 0.000 abstract description 3
- 239000011347 resin Substances 0.000 abstract description 3
- 239000011230 binding agent Substances 0.000 description 11
- 238000013329 compounding Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000011157 advanced composite material Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000004224 protection Effects 0.000 description 2
- 230000006750 UV protection Effects 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000016507 interphase Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to a kind of antioxidation adhesive composition, containing resin and the auxiliary agent of number of different types in the adhesive composition of the present invention, the combination of each component makes the adhesive composition of the present invention have good ultraviolet radiation resisting, the performance of resistance to difference variation.
Description
Technical field
The present invention relates to a kind of antioxidation adhesive composition.
Background technology
Along with the fast development of China's Material Field, the advanced composite material (ACM) in a large number with excellent properties is widely used
In every field such as the infrastructure such as building, railway, highway, Aero-Space, medical treatment, household electrical appliances.Numerous functional binding agents also should
Transport and give birth to.In many multifunctional binders, antioxidation UV resistance binding agent is a kind of important function binding agent, and its effect is right
The binder temperature that in external environment, the ultraviolet radiation of sunlight causes changes and oxidation is controlled by, and has binding agent anti-ageing
Change and oxidation protection effect.The temperature control effect of current existing antioxidation binding agent and non-oxidizability still suffer from many problems, still
Need to continue to improve.
Summary of the invention
In order to overcome the deficiencies in the prior art, the invention provides a kind of antioxidation adhesive composition, this binding agent group
Compound employs resin and the auxiliary agent of number of different types, the combination of each component make it have good ultraviolet radiation resisting,
The performance of resistance to difference variation.
It is as follows that the present invention solves the technical scheme that above-mentioned technical problem used:
A kind of antioxidation adhesive composition, this adhesive composition is made up of the raw material of following parts by weight:
Styrene-acrylic copolymer emulsion 10-15 part
Fluororesin 4-8 part
Alkyd resin 5-10 part
Diphenylethyllene phenol polyoxyethylene ether 1-3 part
Glycerol glycerinate 2-5 part
Organic fluorinated silicone resin 5-10 part
Cinnamic acid propyl ester 5-10 part
Butyl carbitol 1-2 part
3-nonene-2-ketone 0.2-1 part
Phthalocyanine blue 0.1-0.5 part
Zirconia powder 1-3 part
Silica powder 1-5 part
Oxybenzoic acid phenyl ester 1-3 part
Dispersant 1-5 part
Deionized water 40-50 part.
Preferably, this adhesive composition is made up of the raw material of following parts by weight:
Styrene-acrylic copolymer emulsion 12 parts
Fluororesin 6 parts
Alkyd resin 8 parts
Diphenylethyllene phenol polyoxyethylene ether 2 parts
Glycerol glycerinate 3 parts
Organic fluorinated silicone resin 8 parts
Cinnamic acid propyl ester 7 parts
Butyl carbitol 1.5 parts
3-nonene-2-ketone 0.6 part
Phthalocyanine blue 0.3 part
Zirconia powder 2 parts
Silica powder 3 parts
Oxybenzoic acid phenyl ester 2 parts
Dispersant 3 parts
Deionized water 45 parts.
Beneficial effect
The adhesive composition of the present invention have employed the combination of various kinds of resin and auxiliary agent, such as alkyd resin, fluororesin,
Organic fluorinated silicone resin, the compounding cooperative effect that creates of glycerol glycerinate, the modified tack of binding agent, water-fast
Property.Cinnamic acid propyl ester, butyl carbitol, the compounding use of 3-nonene-2-ketone improve the temp. variation resistant of binding agent
Property.Oxybenzoic acid phenyl ester, Styrene-acrylic copolymer emulsion, zirconia powder, the compounding use of silica powder improve
Binding agent absorbs the ability of ultraviolet, the interphase interaction of each component so that adhesive composition has the uvioresistant of excellence
Irradiate and the performance of resistance to difference variation.
Specific embodiments
Below by specific embodiment, the present invention is described in detail, but the scope of protection of present invention is not limited to
In the scope that embodiment is expressed.
Embodiment 1
A kind of antioxidation adhesive composition, this adhesive composition is made up of the raw material of following parts by weight:
Styrene-acrylic copolymer emulsion 15 parts
Fluororesin 8 parts
Alkyd resin 10 parts
Diphenylethyllene phenol polyoxyethylene ether 3 parts
Glycerol glycerinate 5 parts
Organic fluorinated silicone resin 10 parts
Cinnamic acid propyl ester 10 parts
Butyl carbitol 2 parts
3-nonene-2-ketone 1 part
Phthalocyanine blue 0.5 part
Zirconia powder 3 parts
Silica powder 5 parts
Oxybenzoic acid phenyl ester 1-3 part
Dispersant 1-5 part
Deionized water 40-50 part.
Embodiment 2
A kind of antioxidation adhesive composition, this adhesive composition is made up of the raw material of following parts by weight:
Styrene-acrylic copolymer emulsion 10 parts
Fluororesin 4 parts
Alkyd resin 5 parts
Diphenylethyllene phenol polyoxyethylene ether 1 part
Glycerol glycerinate 2 parts
Organic fluorinated silicone resin 5 parts
Cinnamic acid propyl ester 5 parts
Butyl carbitol 1 part
3-nonene-2-ketone 0.2 part
Phthalocyanine blue 0.1 part
Zirconia powder 1 part
Silica powder 1 part
Oxybenzoic acid phenyl ester 1 part
Dispersant 1 part
Deionized water 40 parts.
Embodiment 3
A kind of antioxidation adhesive composition, this adhesive composition is made up of the raw material of following parts by weight:
Styrene-acrylic copolymer emulsion 12 parts
Fluororesin 6 parts
Alkyd resin 8 parts
Diphenylethyllene phenol polyoxyethylene ether 2 parts
Glycerol glycerinate 3 parts
Organic fluorinated silicone resin 8 parts
Cinnamic acid propyl ester 7 parts
Butyl carbitol 1.5 parts
3-nonene-2-ketone 0.6 part
Phthalocyanine blue 0.3 part
Zirconia powder 2 parts
Silica powder 3 parts
Oxybenzoic acid phenyl ester 2 parts
Dispersant 3 parts
Deionized water 45 parts.
Claims (3)
1. an antioxidation adhesive composition, it is characterised in that this adhesive composition is by the raw material group of following parts by weight
Become:
Styrene-acrylic copolymer emulsion 10-15 part
Fluororesin 4-8 part
Alkyd resin 5-10 part
Diphenylethyllene phenol polyoxyethylene ether 1-3 part
Glycerol glycerinate 2-5 part
Organic fluorinated silicone resin 5-10 part
Cinnamic acid propyl ester 5-10 part
Butyl carbitol 1-2 part
3-nonene-2-ketone 0.2-1 part
Phthalocyanine blue 0.1-0.5 part
Zirconia powder 1-3 part
Silica powder 1-5 part
Oxybenzoic acid phenyl ester 1-3 part
Dispersant 1-5 part
Deionized water 40-50 part.
2. antioxidation adhesive composition as claimed in claim 1, it is characterised in that: this adhesive composition is by following weight
The raw material composition of number:
Styrene-acrylic copolymer emulsion 12 parts
Fluororesin 6 parts
Alkyd resin 8 parts
Diphenylethyllene phenol polyoxyethylene ether 2 parts
Glycerol glycerinate 3 parts
Organic fluorinated silicone resin 8 parts
Cinnamic acid propyl ester 7 parts
Butyl carbitol 1.5 parts
3-nonene-2-ketone 0.6 part
Phthalocyanine blue 0.3 part
Zirconia powder 2 parts
Silica powder 3 parts
Oxybenzoic acid phenyl ester 2 parts
Dispersant 3 parts
Deionized water 45 parts.
3. antioxidation adhesive composition as claimed in claim 1, it is characterised in that: described dispersant is macromolecular waterproof
Type dispersant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510347836.3A CN104893622B (en) | 2015-06-23 | 2015-06-23 | A kind of antioxidation adhesive composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510347836.3A CN104893622B (en) | 2015-06-23 | 2015-06-23 | A kind of antioxidation adhesive composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104893622A CN104893622A (en) | 2015-09-09 |
| CN104893622B true CN104893622B (en) | 2016-08-24 |
Family
ID=54026597
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510347836.3A Active CN104893622B (en) | 2015-06-23 | 2015-06-23 | A kind of antioxidation adhesive composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104893622B (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1392210A (en) * | 2002-07-18 | 2003-01-22 | 中山大学 | High weather resistant water-thinned wall paint and its preparing method |
| CN1594381A (en) * | 2004-06-25 | 2005-03-16 | 吉林大学 | Fluoropolymer modified polyacrylate dispersion and its preparation and use |
| CN101045847A (en) * | 2006-03-31 | 2007-10-03 | 中国科学院过程工程研究所 | Adhesive and paint for absorbing formol |
| CN104341986A (en) * | 2014-10-14 | 2015-02-11 | 凤阳徽亨商贸有限公司 | Acid/alkali-corrosion-resistant high-hardness paint for glass doors and preparation method thereof |
| CN104428378A (en) * | 2012-07-06 | 2015-03-18 | 巴斯夫欧洲公司 | Use of aqueous hybrid binders and alkyd systems for coating agents |
-
2015
- 2015-06-23 CN CN201510347836.3A patent/CN104893622B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1392210A (en) * | 2002-07-18 | 2003-01-22 | 中山大学 | High weather resistant water-thinned wall paint and its preparing method |
| CN1594381A (en) * | 2004-06-25 | 2005-03-16 | 吉林大学 | Fluoropolymer modified polyacrylate dispersion and its preparation and use |
| CN101045847A (en) * | 2006-03-31 | 2007-10-03 | 中国科学院过程工程研究所 | Adhesive and paint for absorbing formol |
| CN104428378A (en) * | 2012-07-06 | 2015-03-18 | 巴斯夫欧洲公司 | Use of aqueous hybrid binders and alkyd systems for coating agents |
| CN104341986A (en) * | 2014-10-14 | 2015-02-11 | 凤阳徽亨商贸有限公司 | Acid/alkali-corrosion-resistant high-hardness paint for glass doors and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104893622A (en) | 2015-09-09 |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Zhao Chonglian Inventor after: Li Lijun Inventor after: Huang Jingao Inventor before: Zhou Meiqin |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180122 Address after: 065000 Yongqing Industrial Park, Langfang, Hebei Patentee after: Yongqing Holtzman door industry Co., Ltd. Address before: 311821 Zhejiang city of Shaoxing province Zhuji City Hua Zhen Xin Zhai Cun on No. 100 Patentee before: Zhou Meiqin |