CN104663670B - One kind collaboration miticide composition - Google Patents
One kind collaboration miticide composition Download PDFInfo
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- CN104663670B CN104663670B CN201310627341.7A CN201310627341A CN104663670B CN 104663670 B CN104663670 B CN 104663670B CN 201310627341 A CN201310627341 A CN 201310627341A CN 104663670 B CN104663670 B CN 104663670B
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract
The invention belongs to field of pesticides, is related to a kind of collaboration miticide composition.Composition contains two kinds of active components of A, B, and the ratio of weight and number between component A and the components of component B two is 1:100‑100:1；Active component A is selected from the chemical compounds I shown in following structural formula, and active component B is selected from and kills insects mites agent, and the active component A structure is as follows, and composition of the invention has the advantages that synergy is obvious, delaying drug resistance, available for preventing and treating various pests.
Description
Technical field
The invention belongs to field of pesticides, is related to a kind of collaboration miticide composition.
Background technology
Insecticide has obvious effect in terms of preventing and treating agriculture and forestry injurious insect or urban health insect.
Chinese invention patent CN101875633 discloses a kind of pyrazolyl acrylonitrile compound and its control insect pest and mite
Harmful purposes, wherein compound 5（Hereinafter referred to as chemical compounds I）Available for preventing and treating various pests, evil mite, especially have to evil mite prominent
The prevention effect gone out..
Insecticide containing single-activity component, is used continuously in control of insect, easily insect is developed immunity to drugs.It is logical
The insecticide for crossing two kinds of active components is compounded into blending ingredients by a certain percentage, can often improve preventive effect, reduces active ingredient
Dosage, it is cost-effective, while the generation of pest resistance to insecticide can be delayed.
Although generally disclose in the prior art chemical compounds I or its homologue can be produced with other Mixture Use of Insecticides it is additional
The advantages of and effect, but the technical scheme of the binary pesticide composition containing chemical compounds I has no specific disclosure.
The content of the invention
Present invention aims at a kind of collaboration miticide composition of exploitation, to meet agricultural and urban health field pest control
The demand that aspect is increasingly improved to insecticide effect and kind is constantly updated.
To achieve the above object, the technical solution adopted by the present invention is：
One kind collaboration miticide composition, composition contains two kinds of active components of A, B, between component A and the components of component B two
Ratio of weight and number is 1:100-100:1；Active component A is selected from the chemical compounds I shown in following structural formula, and active component B is selected from and killed
Insects mites agent,
The active component A structure is as follows：
Chemical compounds I；
Described insects mites agent of killing is selected from Citrazon (Benzoximate), fenisobromolate (Bromopropylate), three chlorbensides
Mite alcohol (Dicofol), second mite ester, dinobuton (Dinobuton), dinitro crotons phenolic ester (Dinocap), Dinocap-4,
Dinocap-6,4,6- Dinitro-O-Cresol (DNOC), chinomethionat (Chinomethionat), Thioquinox, Zo insect amide
(Tolfenpyrad), sulfanilamide (SN) mite ester (Amidoflument), Arsenousoxide, dichlofluanid (Dichlofluanid), sulphur
Yellow (Sulfur), pyriminostrobin, fluacrypyrim (Fluacrypyrim), acequinocyl (Acequinocyl), hydramethylnon
(Hydramethylnon), cyflumetofen (Cyflumetofen), nitrile pyrrole mite ester (Cyenopyrafen) or SYP-10898
（SYP-10898, referring to《World pesticide is complete works of》Insecticide is rolled up, Chemical Industry Press, 2012.2 first editions：P768-769）.
The active component A is chemical compounds I, and active component B is preferably pyriminostrobin；The ratio of weight and number of two kinds of active components
It is optimized for 1:20-100:1；
The active component A is chemical compounds I, and active component B is preferably dicofol；The parts by weight of two kinds of active components
Number ratio is optimized for 1:1-20:1；
The active component A is chemical compounds I, and active component B is preferably SYP-10898；The parts by weight of two kinds of active components
Number ratio is optimized for 1:10-10:1.
The composition of the synergistic effect present invention can be in that finished product preparation form provides.Therefore, present invention additionally comprises one kind to make
The insecticides of dosage form formula.Using composition as active component, be made as needed missible oil, suspending agent, water-dispersible granules,
Aqueous emulsion, soluble concentrate, wettable powder, water dispersible oil suspending agent etc..The accumulation of the active component of composition contains in preparation
Amount is between 0.5%~95%, and preferably cumulative amount is between 1%-85%.The content of active component depends in the composition of the present invention
Amount of application when being used alone, also depends on mixed ratio and synergistic effect degree.The optimum range of active component content according to
The preparation type of composition and it is different.
The preparation of the composition finished product preparation of the present invention can be prepared by common processing method, i.e., by active material and liquid
Carrier（Solvent）Or after solid carrier mixing, add one or more of surfactants such as emulsifying agent, dispersant, wetting agent, viscous
Mixture, stabilizer and defoamer etc..Contain at least one carrier and at least one surfactant in usual composition.Various
In the case of, it should be ensured that present composition active component is uniformly distributed.
Missible oil usually contains 10~50% active component, 2~20% emulsifying agents, and 0~20% other additives are for example stablized
Agent, bleeding agent etc., and solvent（Also contain cosolvent if necessary）.
Suspending agent generally needs to be sanded, to obtain stable non-deposited flowable product.Usually contain 5 in suspending agent~
75% active component, 5~15% dispersants, 4~10% antifreezing agents, 0~10% other additives such as defoamer, preservative, stably
Agent, bleeding agent and thickener, and liquid-carrier surplus.
Water-dispersible granules are usually made 10~100 international standard sieve mesh（1.676~0.152mm）Particle, it can pass through
It is prepared by extruding, dipping or Spray granulation method.Usual water-dispersible granules contain 0.5~75% active component and 5~20%
Surfactant such as stabilizer, wetting dispersing agent, disintegrant and adhesive, and inert carrier surplus.
Wettable powder usually contains 10~85% active component, in addition to solid inert carrier, usually contains 3~10%
Dispersant, can also containing 0~10% stabilizer and（Or）Other additives, such as bleeding agent or sticker.
Aqueous emulsion is to mix to form oil phase by active compound, organic solvent, surfactant；Water, antifreezing agent are mixed,
Into homogeneous aqueous phase.With high-shear emulsion machine high speed shear oil phase, while aqueous phase is slowly added into oil phase, usual active ingredient
1~60%, surfactant 5~20%, antifreezing agent 2~10%, water surplus.
Microemulsion is to mix active compound, organic solvent, surfactant, water, into homogeneous aqueous phase.Generally have
Imitate composition 1~50%, surfactant 10~40%, antifreezing agent 2~10%, water surplus.
Soluble liquid is to mix active component, organic solvent, surfactant, into transparent and homogeneous liquid.
Usual active ingredient 1~50%, surfactant 6~20%, organic solvent surplus.
Water dispersible oil suspending agent is that active component, surfactant, oil based vehicle are added in sand mill and be sanded, until grain
Footpath is qualified, usual active ingredient 2~60%, surfactant 6~20%, oil based vehicle surplus.
Aqueous dispersion liquid and emulsion（Missible oil, wettable powder or concentrate as the present invention is diluted with water obtain
Composition）It is also within the scope of the invention.Above-mentioned emulsion can be water-in-oil type or oil-in-water type, can have thick
Paste-like consistency.
The preparation of the composition finished product preparation of the present invention can use well known to those skilled in the art（Liquid is solid
Body）Carrier and various auxiliary agents.Such as include but is not limited to following all kinds of materials.
Suitable liquid-carrier or solvent can be water, various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers etc., such as toluene, diformazan
Benzene, acetone, cyclohexanone, acetonitrile, benzene, hexamethylene, isopropanol, ethylene glycol, sorbierite, methanol, ethanol, butanol, dimethyl formyl
Amine, dimethyl sulfoxide (DMSO), N- methyl-pyrrolidons, tributyl phosphate, methyl iso-butyl ketone (MIBK), naphthalane, machine oil, petroleum ether, oleic acid first
One or more in ester, methylated soya oil or the molten fiber of methyl etc..The mixture of different liquids is often what is be applicable.
Suitable solid carrier includes natural or synthesis clay and silicate, includes suitable for the solid carrier of pulvis
The White Carbon black that naturally occurs, rock dust, chalk, quartz, clay, montmorillonite, sodium sulphate, white carbon, silica, diatom
Soil, float stone, gypsum, talcum, bentonite, kaolin, attapulgite, precipitated calcium carbonate, clay and the mineral matter ground of synthesis
（Such as microdispersed silicic acid or aluminum oxide）.Suitable particulate vector include broken and classification natural rock such as calcite,
Marble, float stone, sepiolite and dolomite and the synthesis particle made of the powder of organic matter and inorganic matter.
Suitable co-solvents are methanol, phenol, isoamyl alcohol, dimethyl sulfoxide (DMSO), tributyl phosphate, ethyl acetate, butanone, diformazan
One in base formamide, dimethyl sulfoxide (DMSO), N- methyl-pyrrolidons, methyl oleate, methyl iso-butyl ketone (MIBK), the molten fiber of methyl etc.
Kind is several.
Suitable emulsifying agent can be ethoxylated castor oil, polyoxyethylene (n20) phenethyl phenolic group oleic acid ester, alkyl virtue
Base polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin APEO, triphenyl vinyl phenol polyoxyethylene (n20) ether phosphorus
It is acidified triethanolamine salt, castor oil polyoxyethylene ether, alkyl vinyl aryl phenyl ether（YUS-SC3）, diphenyl phenolic group polyoxy second
Alkene (n18) ether formaldehyde condensation products, the different thionic acid calcium of oleic acid, agriculture breast AEO-3, agriculture breast 0201B, agriculture breast 0203B, agriculture breast T-20, agriculture breast
T-85, agriculture breast S-80, agriculture breast 507#, agriculture breast 100#, agriculture breast 36#, agriculture breast 500#, agriculture breast 600#, Nongru-700 #, agriculture breast 1601#,
Agriculture breast OX-2681, agriculture breast OX-8686, agriculture breast 2201#, agriculture breast NP-7, agriculture breast OX-635, agriculture breast OX-653, agriculture breast YUS-
D935, agriculture breast YUS-CP120, agriculture breast YUS-A41B, agriculture breast YUS-D3020, agriculture breast NP-10, agriculture breast NP-15 etc..
Suitable dispersant can be the sodium salt, poly- of sodium lignin sulfonate, calcium lignosulfonate, alkyl naphthalene sulfonic acid condensation polymer
Carboxylate dispersants GY-D800, polycarboxylate salt dispersant GY-D04, polycarboxylate salt dispersant GY-D02, naphthalene sulfonate formaldehyde contracting
Compound, naphtholsulfonic acid formaldehyde condensation products sodium salt, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, alkyl-diethylene glycol ether-sodium sulfonate, N- first
Base-oleoyl-sodium taurocholate, detergent LS, methanonaphthalene sodium sulfonate, oleic acid methylaminoethyl sodium sulfonate, epoxidized polyether, point
Powder SP-28F, dispersant SP-SC3, up to profit dispersant D909S, alkylaryl APEO, dodecyl polyoxyethylene
Ether phosphate, polyaryl phenol polyethenoxy ether, to tertbutyl ether, piperonyl butoxide, alkyl amide taurate, alkyl naphthalene sulfonic acid
Salt formaldehyde condensation products（NNO）, ethylene oxide-propylene oxide block copolymer APES formaldehyde condensation product, N- first
Base-fatty acyl group-sodium taurocholate, APES formaldehyde condensation product, nekal（Nekal BX）, two fourths
Base naphthalene sulfonic acid-formaldehyde condensation product, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulfate, alkylphenol-polyethenoxy based phosphates,
Dispersant YUS-NV1203, dispersant YUS-NV1420, dispersant YUS-WG4, dispersant YUS-TG285, dispersant YUS-
WP1, dispersant YUS-110, dispersant YUS-EP60P, dispersant YUS-CH1100, etc..
Suitable wetting agent can be lauryl sodium sulfate, sodium sulphate, Morwet EFW, wetting agent SP-SC3266,
Wetting agent YUS-LXC, wetting agent YUS-204, isopropyl naphthalene sulfonate, alkylol polyoxyethylene base ether sodium sulfate, alkyl phenol gather
Oxyethylene group ether formaldehyde condensation products sulfate, sldium lauryl sulfate, neopelex, calcium dodecyl benzene sulfonate, alkane
Base sodium naphthalene sulfonate aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether etc..
Suitable thickener can be synthesis（Such as carbonyl methylol alcohol, polyvinyl alcohol, polyvinyl acetate）Or natural water
Soluble polymer（Such as xanthans, gelatin, gum arabic, polyvinylpyrrolidone, aluminium-magnesium silicate, polyvinyl alcohol, polyethylene glycol
8000th, phenolic resin, shellac, methylcellulose, soluble starch, carboxymethyl cellulose and sodium alginate etc.）, with powder,
Grain or latex form are added in preparation.
Suitable defoamer is bubble enemy, silicone, C8-10 fatty alcohols, phosphoric acid ester, C10-20 saturated fat acids（Such as
Capric acid）And acid amides etc..
Suitable adhesive can be polyvinyl alcohol, polyvinyl acetate, xanthans, gelatin, carboxymethyl cellulose and sea
Mosanom etc..
Aerosol can be made during for preventing and treating city insect, it is necessary to add propellant wherein, bait formulation can also be made
Composition, in addition to containing active component, also containing one or more foodstuffs for being suitable to insect's food-taking, optional attractant and
Optional wetting agent.
Present invention additionally comprises the present composition to be prepared into Insecticiding-miticiding preparation control agriculture and forestry injurious insect or urban health insect
Purposes.It is particularly adapted to prevent and treat a variety of important agricultural pests such as blister mite, cotton Tetranychus cinnabarinus, vegetables tetranychid, leaves of Hawthorn
Mite, panonychus citri, phyllocoptruta oleivora, apple tetranychus, Tetranychus urticae, goitre mite, flour mite etc., city insect such as termite, blattaria, ant
Ant, flies, mosquito class etc..For fruit tree such as apple, pears, citrus, lichee etc., Cereal such as wheat, rice etc., beans such as soybean,
Kidney bean etc., cotton, vegetables such as wild cabbage, cauliflower, Chinese cabbage, rape, tomato, capsicum and flowers.During for preventing and treating city insect,
It can be used for family, various public places, office space and trees etc..
Present invention additionally comprises a kind of method for controlling insect pest, can impose on the present composition with effective dose needs to control
Insect or its growth medium on.The more suitable effective dose generally selected is 10 grams to 500 grams of per hectare, preferably effectively
Dosage is 15 grams to 100 grams of per hectare.
In addition, the composition for showing the present invention through indoor biological determination of activity has synergistic effect.For example, chemical compounds I with
Dicofol is 1:1-20:In the range of 1, with pyriminostrobin 1:20-100:In the range of 1, with SYP-10898 1:10-10:1
In the range of, certain synergistic effect is shown to Tetranychus cinnabarinus.
The invention has the advantages that：
1. the composition of the present invention shows obvious synergistic effect in certain ratio range, the compound pair is improved
The prevention effect of insect.
2. the present composition reduces the dosage of compound in the application, so as to reduce use cost, environment is reduced
Pollution.
It is anti-with it the problem of in the absence of cross resistance 3. the mechanism of action of each active ingredient is different in the present composition
The generation of pest resistance to insecticide can be delayed by controlling insect, and improve the prevention effect of antagonism population.
Embodiment
Specific examples below is used to the present invention be further described, but the present invention is only limitted to absolutely not these examples.It is real
Each component percentage composition or proportioning in example is applied to be by weight.Active component in each formula is calculated with effective content, composition
Each material of kind can prepare by conventional methods.
Formulation Example
The preparation of embodiment 1,21% dicofol chemical compounds I missible oil
By recipe requirements, 1 part of dicofol, 20 parts of chemical compounds Is, 5 parts of agriculture breast 0201B, 5 parts of agriculture breasts are separately added into
507#, 2 parts of agriculture breast 1601#, 8 parts of methanol, dimethylbenzene are complemented in 100% addition mixing kettle, are uniformly mixed, are used if necessary
Hot bath dissolves by heating, you can obtains 21% dicofol chemical compounds I missible oil.
Can also by the Citrazon described by dicofol alternative costs specification, fenisobromolate, second mite ester, dinobuton,
Dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4,6- Dinitro-O-Cresol, chinomethionat, Thioquinox, Zo worm acyl
Amine, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, pyriminostrobin, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen,
Nitrile pyrrole mite ester, SYP-10898 etc. kill one kind in insects mites agent, form 21% new active component B chemical compounds I missible oil.Implement
The preparation of example 2,21% Citrazon chemical compounds I wettable powder
By recipe requirements, by 1 part of Citrazon, 20 parts of chemical compounds Is, 2 parts of lauryl sodium sulfate, 4 parts of naphtholsulfonic acid formaldehyde
Condensation product sodium salt, 4 parts of dispersant YUS-WP1,5 parts of White Carbon blacks, precipitated calcium carbonate complement to 100% and are sufficiently mixed, through ultra-fine grinding
After machine crushes, you can obtain 21% Citrazon chemical compounds I wettable powder.
Can also by the fenisobromolate described by Citrazon alternative costs specification, dicofol, second mite ester, dinobuton,
Dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4,6- Dinitro-O-Cresol, chinomethionat, Thioquinox, Zo worm acyl
Amine, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, pyriminostrobin, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen,
Nitrile pyrrole mite ester, SYP-10898 etc. kill one kind in insects mites agent, form 21% new active component B chemical compounds I wettable powders
Agent.
The preparation of embodiment 3,40% chinomethionat chemical compounds I wettable powder（1:1）
By recipe requirements, by 20 parts of chinomethionats, 20 parts of chemical compounds Is, 2 parts of lauryl sodium sulfate, 3 parts of N- methyl-oleoyls
It is base-sodium taurocholate, 2 parts of methanonaphthalene sodium sulfonates, 4 parts of naphthalenesulfonic acid-formaldehyde condensates, 2 parts of detergent LS, 10 parts of White Carbon blacks, swollen
Profit soil complements to 100% and is sufficiently mixed, after ultra-fine pulverizer disintegrating, you can obtain 40% chinomethionat chemical compounds I wettable powder
Agent.
Can also by the Citrazon described by chinomethionat alternative costs specification, fenisobromolate, dicofol, second mite ester,
Dinobuton, dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4,6- Dinitro-O-Cresol, Thioquinox, Zo worm acyl
Amine, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, pyriminostrobin, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen,
Nitrile pyrrole mite ester, SYP-10898 etc. kill one kind in insects mites agent, form 40% new active component B chemical compounds I wettable powders
Agent.
The preparation of embodiment 4,22% fenisobromolate chemical compounds I aqueous emulsion
By recipe requirements, by 2 parts of fenisobromolates, 20 parts of chemical compounds Is, 4 parts of polyoxyethylene (n20) phenethyl phenolic group oleic acid ester,
6 parts of agriculture breast OX-2681,2 parts of agriculture breast 1601#, 8 parts of dimethylbenzene, 5 parts of tributyl phosphates are added in mixing kettle, are stirred, are made molten
Solution is into homogeneous oil phase, under high velocity agitation, by excess water（Complement to 100%）It is added to oil phase, you can obtain favorable dispersibility
22% fenisobromolate chemical compounds I aqueous emulsion.
Can also by the Citrazon described by fenisobromolate alternative costs specification, dicofol, second mite ester, dinobuton,
Dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4,6- Dinitro-O-Cresol, chinomethionat, Thioquinox, Zo worm acyl
Amine, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, pyriminostrobin, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen,
Nitrile pyrrole mite ester, SYP-10898 etc. kill one kind in insects mites agent, form 22% new active component B chemical compounds I aqueous emulsions.
The preparation of embodiment 5,40% dicofol chemical compounds I aqueous emulsion（1:1）
By recipe requirements, by 20 parts of dicofols, 20 parts of chemical compounds Is, 5 parts of triphenyl vinyl phenol polyoxyethylene (n20) ether
Phosphorylation triethanolamine salt, 8 parts of agriculture breast 2201#, 5 parts of agriculture breast 0201B, 10 parts of cyclohexanone, 10 parts of dimethylbenzene are added in mixing kettle,
It is stirred, makes to be dissolved into homogeneous oil phase, under high velocity agitation, by excess water（Complement to 100%）It is added to oil phase, you can
To 40% dicofol chemical compounds I aqueous emulsion of favorable dispersibility.
Can also by the Citrazon described by dicofol alternative costs specification, fenisobromolate, second mite ester, dinobuton,
Dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4,6- Dinitro-O-Cresol, chinomethionat, Thioquinox, Zo worm acyl
Amine, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, pyriminostrobin, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen,
Nitrile pyrrole mite ester, SYP-10898 etc. kill one kind in insects mites agent, form 40% new active component B chemical compounds I aqueous emulsions.
Embodiment 6,60% Citrazon chemical compounds I water-dispersible granules（1:1）
By recipe requirements, 30 parts of Citrazons, 30 parts of chemical compounds Is, 3 parts of alkyl-diethylene glycol ether-sodium sulfonates, 5 parts are disperseed
Agent YUS-WG4,3 parts of naphtholsulfonic acid formaldehyde condensation products, 8 parts of sodium sulphate, 5 portions of soluble starches, diatomite complement to 100% and are added in
Together, co-grinding is carried out, then after adding water to mediate, adds in the comminutor equipped with certain specification screen cloth and is granulated.Then
Again through drying, screening (pressing screen cloth scope), you can obtain 60% Citrazon chemical compounds I water-dispersible granules.
Can also by the fenisobromolate described by Citrazon alternative costs specification, dicofol, second mite ester, dinobuton,
Dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4,6- Dinitro-O-Cresol, chinomethionat, Thioquinox, Zo worm acyl
Amine, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, pyriminostrobin, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen,
Nitrile pyrrole mite ester, SYP-10898 etc. kill one kind in insects mites agent, form 60% new active component B chemical compounds I water dispersible grains
Agent（1:1）.
Embodiment 7,44% chinomethionat chemical compounds I water-dispersible granules
By recipe requirements, 4 parts of chinomethionats, 40 parts of chemical compounds Is, 4 parts of methyl naphthalene sulfonate formaldehyde condensates, 5 parts are disperseed
Agent YUS-TG285,1 part of Morwet EFW, 5 parts of PEG 8000s, 10 parts of sodium sulphate, attapulgite complement to 100% and are added in one
Rise, carry out co-grinding, then after adding water to mediate, add in the comminutor equipped with certain specification screen cloth and be granulated.Then again
Through drying, screening (pressing screen cloth scope), you can obtain 44% chinomethionat chemical compounds I water-dispersible granules.
Can also by the Citrazon described by chinomethionat alternative costs specification, fenisobromolate, dicofol, second mite ester,
Dinobuton, dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4,6- Dinitro-O-Cresol, Thioquinox, Zo worm acyl
Amine, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, pyriminostrobin, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen,
Nitrile pyrrole mite ester, SYP-10898 etc. kill one kind in insects mites agent, form 44% new active component B chemical compounds I water dispersible grains
Agent.
Embodiment 8,12%SYP-10898 chemical compounds I suspending agents
By recipe requirements, by 2 parts of SYP-10898,10 parts of chemical compounds Is, 4 parts of polycarboxylate salt dispersant GY-D04,2 parts of methylenes
Base sodium naphthalene sulfonate, 2 parts of agriculture breast 1601#, 4 parts of agriculture breast 0201B, 0.1 part of xanthans, 0.5 part of white carbon, 5 parts of ethylene glycol, mended with water
Foot is added sequentially to mix in blending tank, first passes through high shear and carry out coarse crushing, homogenize, be then pumped into sand mill to 100%
Middle carry out fine grinding, the granularity that material is sanded is detected with particles distribution instrument, after particle diameter reaches standard requirement, filtering, you can obtain
12%SYP-10898 chemical compounds I suspending agents.
Can also be by the Citrazon described by SYP-10898 alternative costs specifications, fenisobromolate, dicofol, second mite
Ester, dinobuton, dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4,6- Dinitro-O-Cresol, chinomethionat,
Thioquinox, Zo insect amide, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, pyriminostrobin, fluacrypyrim, mite of going out
Quinone, hydramethylnon, cyflumetofen, nitrile pyrrole mite ester etc. kill one kind in insects mites agent, form 12% new active component B chemical compounds Is
Suspending agent.
Example 9,50% Sulfur chemical compounds I suspending agent（1:1）
By recipe requirements, by 25 parts of Sulfurs, 25 parts of chemical compounds Is, 3 parts of sodium lignin sulfonates, 5 parts of N- methyl-oleoyl-oxen
Sodium sulfonate, 2 parts of dispersant SP-SC3, Nongru-700 #, 0.1 part of xanthans, 0.2 part of white carbon, 5 parts of ethylene glycol, complemented to water
100%, it is added sequentially to mix in blending tank, first passes through high shear and carry out coarse crushing, homogenize, then be pumped into sand mill
Row fine grinding, the granularity that material is sanded is detected with particles distribution instrument, after particle diameter reaches standard requirement, filtering, you can obtain 50% sulphur
Yellow chemical compounds I suspending agent.
Can also by the Citrazon described by Sulfur alternative costs specification, fenisobromolate, dicofol, second mite ester, disappear
Mite is logical, dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4,6- Dinitro-O-Cresol, chinomethionat, Thioquinox, Zo
Insect amide, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, pyriminostrobin, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen,
Nitrile pyrrole mite ester, SYP-10898 etc. kill one kind in insects mites agent, form 50% new active component B chemical compounds I suspending agents（1:
1）.
Embodiment 10,21% fenisobromolate chemical compounds I microemulsion
By recipe requirements, by 1 part of fenisobromolate, 20 parts of chemical compounds Is, 6 parts of triphenyl vinyl phenol polyoxyethylene (n20) ether phosphoric acid
Change triethanolamine salt, 4 parts of agriculture breast NP-15,3 parts of castor oil polyoxyethylene ethers, 6 parts of ethyl acetate, 5 parts of acetonitriles to be added together, make
Homogeneous oil phase is dissolved into, surplus complements to 100% with water, under high velocity agitation, aqueous phase is added into oil phase or is added to oil phase
Aqueous phase, form 21% fenisobromolate chemical compounds I microemulsion of favorable dispersibility.
Can also by the Citrazon described by fenisobromolate alternative costs specification, dicofol, second mite ester, dinobuton,
Dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4,6- Dinitro-O-Cresol, chinomethionat, Thioquinox, Zo worm acyl
Amine, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, pyriminostrobin, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen,
Nitrile pyrrole mite ester, SYP-10898 etc. kill one kind in insects mites agent, form 21% new active component B chemical compounds I microemulsions.
Embodiment 11,21% dinobuton chemical compounds I soluble concentrate
By recipe requirements, by 1 part of dinobuton, 20 parts of chemical compounds Is, 15 parts of agriculture breast 507#, 5 parts of agriculture breast 1601#, 6 parts of agriculture breasts
100#, 12 parts of dimethylformamides, 10 parts of methanol, 20 parts of dimethyl sulfoxide (DMSO)s, 17 parts of molten fibers of methyl are well mixed, used if necessary
Hot bath dissolves by heating, and the soluble concentrate of 15% avermectin compounds I can be made, that the molten fiber of methyl complements to 100% mixing is equal
It is even, dissolved by heating if necessary with hot bath, 21% dinobuton chemical compounds I soluble concentrate can be made.
Can also by the Citrazon described by dinobuton alternative costs specification, fenisobromolate, dicofol, second mite ester,
Dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4,6- Dinitro-O-Cresol, chinomethionat, Thioquinox, Zo worm acyl
Amine, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, pyriminostrobin, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen,
Nitrile pyrrole mite ester, SYP-10898 etc. kill one kind in insects mites agent, form 21% new active component B chemical compounds I soluble concentrates.
Embodiment 12,21% pyriminostrobin chemical compounds I water dispersible oil suspending agent
By recipe requirements, by 1 part of pyriminostrobin, 20 parts of chemical compounds Is, 3 parts of agriculture breast 0201B, 4 parts of dispersant YUS-110,5 parts
Agriculture breast S-80,3 parts of white carbons, 3 parts of agriculture breast 500#, methyl oleate complement to 100% and are added sequentially to mix in blending tank, first pass through
Cross high shear to carry out coarse crushing, homogenize, be then pumped into sand mill and carry out fine grinding, detected with particles distribution instrument and material is sanded
Granularity, after particle diameter reaches standard requirement, filtering, you can obtain 21% pyriminostrobin chemical compounds I water dispersible oil suspending agent.
Can also by the Citrazon described by pyriminostrobin alternative costs specification, fenisobromolate, dicofol, second mite ester,
Dinobuton, dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4,6- Dinitro-O-Cresol, chinomethionat, Thioquinox,
Zo insect amides, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen,
Nitrile pyrrole mite ester, SYP-10898 etc. kill one kind in insects mites agent, form 21% new active component B chemical compounds I water dispersible oils
Suspension.
Indoor biological determination of activity
Synergism determination of composition of the embodiment 13 containing chemical compounds I to Tetranychus cinnabarinus
For trying object：Tetranychus cinnabarinus（Tetranychus cinnabarinus Boisduval）, into mite, indoor feeding
Sensitive strain.
Test condition：Temperature：24~26 DEG C, humidity：RH60%, illumination：L:D=14:10
Test method：Using pot-spraying method.The potted plant Kidney bean seedling of sizing of hot-house culture（2 true leaves）, a piece of true leaf is stayed,
Mite 40-60 heads are connected into thereon.Examination material is handled with decoction using Airbrush spray-on processes, dried in the shade naturally.Blank control is first handled,
Then aforesaid operations are repeated from low to high according to experimental design dosage, often handle 4 repetitions.Test worm after processing is placed in
In observation ward, routine observation test worm response situation, number of dead and live insects is investigated after 72h, calculate the death rate.
Evaluation uses Bliss methods, and this method is one of classical way for evaluating mixture effect.Bliss proposes according to it
Independent joint action concept thinks, theoretical death rate P during Mixture Use of Insecticides can be calculated with following formula：
P=Pm+Pn(1-Pm)
PmFor the death rate of the first active component target when concentration is m（%）；PnIt is n for the second active component concentration
When target the death rate（%）.
If the actual of two kinds of active component targets after being mixed with finite concentration is more than theoretical death rate P,
Judge that two kinds of active components are used in mixed way with synergistic effect in the case where setting concentration, it is on the contrary then be antagonism.
It the results are shown in Table 1.
3 compounds such as the chemical compounds I of table 1 and dicofol are used in mixed way the synergism determination to Tetranychus cinnabarinus into mite
Claims (6)
1. one kind collaboration miticide composition, it is characterised in that：Composition contains two kinds of active components of A, B, component A and component B two
Ratio of weight and number between component is 1:5-1:10、10:1；Active component A is selected from the chemical compounds I shown in following structural formula, activity
Component B is selected from SYP-10898；
The active component A structure is as follows：
Chemical compounds I.
2. according to the composition described in claim 1, it is characterised in that：Composition can be configured to missible oil, suspending agent, moisture and dissipate
Property granula, aqueous emulsion, microemulsion, soluble concentrate, wettable powder or water dispersible oil suspending agent.
3. according to the composition described in claim 2, it is characterised in that：The cumulative amount of active component is in 0.5%- in composition
Between 95%.
4. according to the composition described in claim 3, it is characterised in that：The cumulative amount of active component is in 1%-85% in composition
Between.
A kind of 5. collaboration miticide composition application according to described in claim 1, it is characterised in that：The composition is used to prepare
Insecticidal/acaricidal agent, for controlling agricultural pests or urban health insect.
6. according to the collaboration miticide composition application described in claim 5, it is characterised in that：With effective agent gauge, will be prepared into
The composition of insecticidal/acaricidal agent is imposed on the medium of the insect for needing to control or its growth.
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| CN106305732B (en) * | 2015-06-18 | 2019-03-19 | 沈阳中化农药化工研发有限公司 | A kind of insecticide acaricide composition containing flufenzine |
| CN106605654A (en) * | 2015-10-21 | 2017-05-03 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing SYP-9625 |
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| CN106614677A (en) * | 2015-10-30 | 2017-05-10 | 陕西韦尔奇作物保护有限公司 | Insecticidal pesticide composition containing SYP-9625 |
| CN105454242B (en) * | 2015-12-03 | 2019-03-19 | 陕西标正作物科学有限公司 | A kind of composition pesticide and application thereof containing nitrile pyrrole mite ester |
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| CN106719687A (en) * | 2017-02-16 | 2017-05-31 | 佛山市瑞生通科技有限公司 | A kind of composition pesticide of the mite nitrile of azoles containing second and cyflumetofen |
| CN106937634A (en) * | 2017-03-15 | 2017-07-11 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of acaricide composition and its application method |
| CN106942235A (en) * | 2017-03-21 | 2017-07-14 | 佛山市瑞生通科技有限公司 | A kind of Pesticidal combination containing propylene glycol alginate and second azoles mite nitrile |
| CN108684681B (en) * | 2017-03-31 | 2021-03-30 | 沈阳中化农药化工研发有限公司 | Mite killing preparation and application thereof |
| CN109691451B (en) * | 2017-10-24 | 2021-03-05 | 沈阳中化农药化工研发有限公司 | Insecticidal and acaricidal synergistic composition containing ethacrylonitrile and application thereof |
| CN109122692B (en) * | 2018-10-18 | 2020-08-07 | 江苏省农业科学院 | Insecticidal and acaricidal pesticide composition with synergistic effect |
| CN111226945B (en) * | 2018-11-29 | 2021-11-23 | 沈阳中化农药化工研发有限公司 | Synergistic insecticidal and acaricidal composition |
| CN111789122A (en) * | 2019-04-09 | 2020-10-20 | 浙江省化工研究院有限公司 | Acaricidal composition containing oxapyrile-acarbonitrile and spirocyclic tetronic acid pesticide |
| CN118303417A (en) * | 2023-01-13 | 2024-07-09 | 广西壮族自治区农业科学院 | Insecticidal composition containing cycloxaprid and used for preventing and controlling taro field red spiders |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101875633A (en) * | 2009-04-29 | 2010-11-03 | 中国中化股份有限公司 | Pyrazolyl acrylonitrile compound and application thereof |
| CN102438987A (en) * | 2009-05-22 | 2012-05-02 | 日产化学工业株式会社 | Crystal of cyazofamid and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2003201280A (en) * | 2001-10-24 | 2003-07-18 | Nissan Chem Ind Ltd | Acrylonitrile compound |
| JP2008150302A (en) * | 2006-12-15 | 2008-07-03 | Nissan Chem Ind Ltd | Insecticidal or acaricidal composition |
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2013
- 2013-11-26 CN CN201310627341.7A patent/CN104663670B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101875633A (en) * | 2009-04-29 | 2010-11-03 | 中国中化股份有限公司 | Pyrazolyl acrylonitrile compound and application thereof |
| CN102438987A (en) * | 2009-05-22 | 2012-05-02 | 日产化学工业株式会社 | Crystal of cyazofamid and preparation method thereof |
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