[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

CN104449172B - 一种含生物防污剂的防污涂料及其制备方法 - Google Patents

一种含生物防污剂的防污涂料及其制备方法 Download PDF

Info

Publication number
CN104449172B
CN104449172B CN201410836582.7A CN201410836582A CN104449172B CN 104449172 B CN104449172 B CN 104449172B CN 201410836582 A CN201410836582 A CN 201410836582A CN 104449172 B CN104449172 B CN 104449172B
Authority
CN
China
Prior art keywords
agent
bioantifouling
antifouling paint
preparation
bioantifouling agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201410836582.7A
Other languages
English (en)
Other versions
CN104449172A (zh
Inventor
郑纪勇
蔺存国
邱日
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
725th Research Institute of CSIC
Original Assignee
725th Research Institute of CSIC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 725th Research Institute of CSIC filed Critical 725th Research Institute of CSIC
Priority to CN201410836582.7A priority Critical patent/CN104449172B/zh
Publication of CN104449172A publication Critical patent/CN104449172A/zh
Application granted granted Critical
Publication of CN104449172B publication Critical patent/CN104449172B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C221/00—Preparation of compounds containing amino groups and doubly-bound oxygen atoms bound to the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C225/00—Compounds containing amino groups and doubly—bound oxygen atoms bound to the same carbon skeleton, at least one of the doubly—bound oxygen atoms not being part of a —CHO group, e.g. amino ketones
    • C07C225/02—Compounds containing amino groups and doubly—bound oxygen atoms bound to the same carbon skeleton, at least one of the doubly—bound oxygen atoms not being part of a —CHO group, e.g. amino ketones having amino groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C225/14—Compounds containing amino groups and doubly—bound oxygen atoms bound to the same carbon skeleton, at least one of the doubly—bound oxygen atoms not being part of a —CHO group, e.g. amino ketones having amino groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being unsaturated
    • C07C225/16—Compounds containing amino groups and doubly—bound oxygen atoms bound to the same carbon skeleton, at least one of the doubly—bound oxygen atoms not being part of a —CHO group, e.g. amino ketones having amino groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being unsaturated and containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/346—Clay
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • C09D5/1612—Non-macromolecular compounds
    • C09D5/1625—Non-macromolecular compounds organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662—Synthetic film-forming substance
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2265—Oxides; Hydroxides of metals of iron
    • C08K2003/2272—Ferric oxide (Fe2O3)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

本发明属于海洋防污涂料的技术领域，涉及一种含生物防污剂的防污涂料及其制备方法；所含生物防污剂的分子结构由苯环、酚羟基、甲氧基、丙酰基、胺基和R1组成，制备工艺为:先将提取的丹皮酚与三聚甲醛和烷基胺在无水乙醇中混合，再在浓盐酸催化下进行曼尼希反应后，用NaHCO3水溶液中和，再用无水乙醇重结晶得生物防污剂，然后将生物防污剂与三氟丙基‑甲基‑二甲基丙烯酸酯硅烷、甲基丙烯酸甲酯、甲基丙烯酸和甲基丙烯酸丁酯在甲苯中混合进行自由基聚合反应，得到生物防污剂的液体制品，再在液体制品中加入颜料、填料和涂料助剂进行混合，研磨后得到含生物防污剂的防污涂料；其制备工艺简单，原料易得，应用前景广泛，使用环境友好。

Description

一种含生物防污剂的防污涂料及其制备方法
技术领域：
本发明属于海洋防污涂料的技术领域，涉及一种海洋环境中物体设施表面污损防护用的涂料，特别是一种含生物防污剂的防污涂料及其制备方法，对防除水下设施表面附着污损生物具有明显效果。
背景技术：
海水中存在着大量污损生物，如藤壶、贻贝、海鞘、苔藓虫、水螅、海绵、绿藻、硅藻等，这些生物可附着在结构物表面，如船舶、船坞、码头、石油平台、海底电缆、浮标、水雷、电厂冷却管道、渔网等，会对海洋环境中的结构物带来危害和经济损失，如造成船舶航行阻力加大，通海管道阻塞，冷却设备导热性降低，渔网渔具堵塞等。目前，解决海洋生物污损的最简便有效的方法是涂刷防污涂料，现有的海洋防污涂料通常是由树脂、防污剂、颜填料、助剂和溶剂组成，其中防污剂和树脂是防污性能的关键。在防污剂方面，有机锡具有良好的防污效果，已得到普遍使用，然而，这种防污剂对其它非目标生物如鱼类、贝类等也有强毒性，并在生物体和海泥中累积，危害海洋生态环境，甚至经食物链传递危及人类健康。世界海事组织已禁止有机锡和DDT等有毒防污剂在防污涂料中的应用，设计和制备新型环保防污剂是未来发展趋势。在现有技术中，各种防污剂很多，如中国专利CN 1189293A公开了一种哒嗪酮类防污剂；中国专利CN1392208A公开了一种海洋大叶藻提取物制成的防污剂；中国专利CN1820603A公开了一种氯氰菊酯防污剂；中国专利CN1651412A公开了一种吲哚的酰胺衍生物防污剂；中国专利CN1499928A公开了烷基胺衍生物防污剂等，现有防污剂的防污性能仍需进一步研发，以期制备一种高性能、环保型海洋防污剂取代现有的技术产品。通常，树脂在涂料中主要起成膜作用，并随着高分子技术的发展，树脂也具备防污性，防污涂料使用树脂的研究从20世纪90年代至今已有大量专利文献公开，其中以基于聚硅氧烷、聚氨酯、丙烯酸酯等的涂料研究较多，如中国专利GB1457590公开了三丁基锡丙烯酸聚合物自抛光 树脂；中国专利CN102402739A公开了一种低表面能氟硅改性丙烯酸防污树脂；中国专利CN101029207A公开了氟硅嵌段聚合物型低表面能树脂；中国专利CN101775144A公开了一种氟硅树脂等；上述这些树脂和防污涂料的合成，均采用硅单体和氟单体，再分别与丙烯酸单体聚合，或者采用硅氧烷聚合链与碳聚合链交联形成聚合物，但开发简单易用，并兼具多种特性的优良树脂的技术和产品仍是有进一步研究和开发的必要。
发明内容：
本发明的目的在于克服现有技术存在的缺点，提供一种环保型含有生物防污剂防污涂料及其制备方法，利用氟硅丙烯酸脂对生物防污剂进行包裹，以控制防污剂缓慢水解释放，其防污具备防除污损生物附着和生长的功能，采用生物防污剂和水解型低表面能树脂相结合，通过两者的共同作用增加防污效果。
为了实现上述发明目的，本发明涉及的防污涂料中所含生物防污剂的分子结构为：
其生物防污剂分子结构由苯环、酚羟基、甲氧基、丙酰基、胺基和R1组成，其中R1为C1-C10的线性或支化的烷基链，优选C4-C8的线性烷基链；该分子结构的部分基团(式中虚线内的分子结构)来源于天然活性成分丹皮酚，由牡丹、芍药和徐长卿植物的根皮或全草中提取，另外含有曼尼希碱结构和烷基胺结构。
本发明涉及的含生物防污剂的防污涂料的制备工艺包括生物防污剂制备和防污涂料制备两个步骤，其中，生物防污剂的制备是：将 提取的天然分子丹皮酚与三聚甲醛和烷基胺R1NH2在无水乙醇中混合，在浓盐酸催化下进行曼尼希反应，其各成分配置重量比例为丹皮酚：三聚甲醛：烷基胺：无水乙醇：浓盐酸＝1：(1～4)：(1～2)：30：(0.1～1)，反应温度为25～140℃，反应时间为1～48小时，反应完毕后用重量百分比浓度为10％的NaHCO3水溶液中和至pH＝7，分离得到的产物再用无水乙醇重结晶纯化后制得生物防污剂，其中浓盐酸的重量百分比浓度为37％；其氟硅丙烯酸酯包裹生物防污剂的防污涂料制备工艺为：将制备的生物防污剂与三氟丙基-甲基-二甲基丙烯酸酯硅烷、甲基丙烯酸甲酯、甲基丙烯酸、甲基丙烯酸丁酯在甲苯中混合均匀，以偶氮二异丁腈为引发剂进行自由基聚合反应，其各成分的重量配置比例为:生物防污剂：三氟丙基-甲基-二甲基丙烯酸酯硅烷:甲基丙烯酸甲酯:甲基丙烯酸、甲基丙烯酸丁酯:偶氮二异丁腈:甲苯＝1:1:1:1:3:(0.05～0.1):30，在80～90℃下搅拌反应3～8小时，即得到用氟硅丙烯酸酯包裹生物防污剂的液体制品；再在液体制品中按常规工艺加入常规使用的颜料、填料和涂料助剂进行混合，研磨达到80微米细度，即制备得氟硅丙烯酸酯包裹生物防污剂的防污涂料。
本发明与现有技术相比，其氟硅丙烯酸脂包裹生物防污剂的防污涂料中含有生物防污剂作为污损生物附着生长抑制剂，对硅藻附着的半数抑制浓度达到1ppm；以氟硅丙烯酸树脂作为成膜物，不但可以利用酸根和胺基的作用包裹防污剂，而且可在接触海水后，通过硅氧酯键水解，缓慢释放出防污剂和具有低表面能特性的氟硅氧烷，进一步抑制污损生物的附着；具备防污性好、表面能低和水解抛光效果好等防污特性，其制备工艺简单，原料易得，应用前景广泛，使用环境友好。
具体实施方式：
下面结合本实施例进一步说明本发明的具体实施方案。
实施例1：生物防污剂的制备
将丹皮酚1mol、三聚甲醛3mol、正辛胺1mol、300ml无水乙醇放入反应容器中，使完全溶解搅拌，在回流冷凝条件下缓慢加入37％ 浓盐酸3ml，在80℃温度下反应24小时；反应结束后用重量百分比浓度为10％NaHCO3水溶液中和至pH＝7，产物用无水乙醇重结晶，即得到生物防污剂。
实施例2：用氟硅丙烯酸脂包裹生物防污剂的防污涂料的制备
将实施例1所得的生物防污剂10g，氟硅烷基丙烯酸酯10g，甲基丙烯酸甲酯10g、甲基丙烯酸10g、丙烯酸丁酯30g、偶氮二异丁腈0.3g与甲苯200g搅拌混合均匀，在90℃下搅拌反应5小时，得到氟硅丙烯酸酯包裹生物防污剂的液体制品，取该液体制品30g，加入氧化锌15g，氧化铁10g，蒙脱土2g，膨润土1g，二甲苯30g，反复研磨分散均匀后制得防污涂料。
实施例3：生物防污剂对硅藻的防除性能测试
取实施例1制备的生物防污剂50mg加入到500ml容量瓶中，加蒸馏水至刻度线，制备100ppm浓度母液100ml；然后将母液稀释成10、5、3、1、0.5、0.1ppm的浓度梯度，然后各取0.9ml分别加入到24孔培养板中,再分别加入1.8ml配制好的f/2培养液，加入硅藻种0.3ml；于20℃、1900lux光照、明暗周期为12h∶12h条件下培养3～7天后对底部附着硅藻计数；根据底部硅藻附着个数，统计计算得到半数抑制浓度为0.8ppm；说明本实施例制备的生物防污剂可抑制硅藻生长，影响污损生物群落的生成，达到防污效果。
实施例4：用氟硅丙烯酸树脂包裹生物防污剂的防污涂料实海测试
按照国家标准GB 5370-2007《防污漆样板浅海浸泡试验方法》，取实施例2的用氟硅丙烯酸包裹生物防污剂的防污涂料涂刷在实海测试样板表面，进行实海防污活性测试，结果表明，该防污涂料达到1年以上的防污期效。

Claims (1)

1.一种含生物防污剂的防污涂料的制备方法，其特征在于：所述防污涂料所含生物防污剂的分子结构为：
其生物防污剂分子结构由苯环、酚羟基、甲氧基、丙酰基、胺基和R1组成，其中R1为C1-C10的线性或支化的烷基链；分子结构中的部分基团来源于天然活性成分丹皮酚，由牡丹、芍药和徐长卿植物的根皮或全草中提取，另外含有曼尼希碱结构和烷基胺结构；
所述的含生物防污剂的防污涂料的制备方法包括生物防污剂的制备和防污涂料的制备两个步骤，其中，生物防污剂的制备工艺是：将提取的天然分子丹皮酚与三聚甲醛和烷基胺在无水乙醇中混合，在浓盐酸催化下进行曼尼希反应，其各成分配置重量比例为丹皮酚：三聚甲醛：烷基胺：无水乙醇：浓盐酸＝1：(1～4)：(1～2)：30：(0.1～1)，反应温度为25～140℃，反应时间为1～48小时，反应完毕后用重量百分比浓度为10％的NaHCO3水溶液中和至pH＝7，分离得到的产物再用无水乙醇重结晶纯化后制得生物防污剂，其中浓盐酸的重量百分比浓度为37％；氟硅丙烯酸酯包裹生物防污剂的防污涂料的制备工艺为：将制备的生物防污剂与三氟丙基-甲基-二甲基丙烯酸酯硅 烷、甲基丙烯酸甲酯、甲基丙烯酸、甲基丙烯酸丁酯在甲苯中混合均匀，以偶氮二异丁腈为引发剂进行自由基聚合反应，其各成分的重量配置比例为：生物防污剂:三氟丙基-甲基-二甲基丙烯酸酯硅烷:甲基丙烯酸甲酯:甲基丙烯酸:甲基丙烯酸丁酯:偶氮二异丁腈:甲苯＝1:1:1:1:3:(0.05～0.1):30，在80～90℃下搅拌反应3～8小时，即得到用氟硅丙烯酸酯包裹生物防污剂的液体制品；再在液体制品中按常规工艺加入常规使用的颜料、填料和涂料助剂进行混合，研磨达到80微米细度，即制得氟硅丙烯酸酯包裹生物防污剂的防污涂料。
CN201410836582.7A 2014-12-29 2014-12-29 一种含生物防污剂的防污涂料及其制备方法 Expired - Fee Related CN104449172B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410836582.7A CN104449172B (zh) 2014-12-29 2014-12-29 一种含生物防污剂的防污涂料及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410836582.7A CN104449172B (zh) 2014-12-29 2014-12-29 一种含生物防污剂的防污涂料及其制备方法

Publications (2)

Publication Number Publication Date
CN104449172A CN104449172A (zh) 2015-03-25
CN104449172B true CN104449172B (zh) 2016-08-17

Family

ID=52895952

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410836582.7A Expired - Fee Related CN104449172B (zh) 2014-12-29 2014-12-29 一种含生物防污剂的防污涂料及其制备方法

Country Status (1)

Country Link
CN (1) CN104449172B (zh)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105038449A (zh) * 2015-06-30 2015-11-11 芜湖县双宝建材有限公司 一种耐磨高附着力环保耐腐蚀防污涂料
CN110093090B (zh) * 2019-05-28 2021-06-29 沈阳顺风新材料有限公司 一种室内用抑菌涂料的制备方法
CN115075012B (zh) * 2022-06-16 2023-07-07 太原理工大学 一种防污网具及其制备方法和应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3244519B2 (ja) * 1991-08-26 2002-01-07 昭和電工株式会社 アクリル官能性メチルフルオロアルキルシルセスキオキサン化合物
EP0811669B1 (en) * 1995-02-20 2004-02-04 Daikin Industries, Limited Use of a fluorsilicate as stain-proofing agent
US6767978B2 (en) * 2002-01-03 2004-07-27 Atofina Chemicals, Inc. Copolymers containing fluoro and silyl groups and their use in marine antifoulant composition
JP2009155500A (ja) * 2007-12-27 2009-07-16 Sakai Silk Screen:Kk 防汚用塗料組成物及び付着防止体
CN101225142B (zh) * 2008-01-25 2011-04-20 中国船舶重工集团公司第七二五研究所 一种侧链悬挂丹皮酚结构的硅烷偶联剂改性丙烯酸树脂的合成方法
CN101307007A (zh) * 2008-05-30 2008-11-19 中国船舶重工集团公司第七二五研究所 一种丹皮酚及其衍生物防污剂
CN102634255B (zh) * 2012-03-09 2014-05-14 淮海工学院 一种海洋防污涂料及其制备方法
CN103951576A (zh) * 2014-05-06 2014-07-30 中国海洋大学 单官能度具类辣椒素功能结构的丙烯酰胺化合物及其制备方法与应用

Also Published As

Publication number Publication date
CN104449172A (zh) 2015-03-25

Similar Documents

Publication Publication Date Title
CN102993853B (zh) 一种无毒料释放型防污漆及其制备方法
CN101624502B (zh) 防垢涂料组合物和使用它的水下结构
AU2014222855B2 (en) Anti-fouling compositions with a fluorinated oxyalkylene-containing polymer or oligomer
CN104449172B (zh) 一种含生物防污剂的防污涂料及其制备方法
US9840627B2 (en) Application of camptothecin and derivatives thereof as antifouling agent
JP6067199B1 (ja) 防汚塗料組成物、防汚塗膜、防汚基材、防汚基材の製造方法および防汚塗料組成物の貯蔵方法
KR20010033462A (ko) 오염 방지방법
CN105199577B (zh) 一种抗菌型低表面能海洋防污涂料组合物
BR112019013971A2 (pt) composição de revestimento de liberação de incrustação líquida não aquosa para controlar bioincrustantes aquosos em objetos produzidos pelo homem, substrato, processo para controlar bioincrustação aquática de um objeto produzido pelo homem e uso da composição de revestimento de liberação de incrustação
CN112694833A (zh) 一种含玄武岩纤维粉及鳞片粉的复合低表面能防污涂料及其制备方法
CN104513340B (zh) 一种氟硅丙烯酸自抛光防污树脂及其制备方法
JP2018080274A (ja) 防汚塗料組成物、防汚塗膜およびこれらの用途
KR20060125683A (ko) 도료 조성물, 오염방지 도막, 수중 구조물, 및 수중구조물의 오염방지 방법
CN1616560A (zh) 环保型防污剂材料及防污油漆涂料
JPH01306479A (ja) 無毒性防汚塗料組成物
JP4154345B2 (ja) 塗料組成物及び共重合体
CN102093770B (zh) 杨梅栲胶在制备海洋防污涂料中的应用
CN101307007A (zh) 一种丹皮酚及其衍生物防污剂
CN114891405A (zh) 智能防污微胶囊粒子、其制备方法及其具有智能防污功能的环保性海洋防污涂层
CN100341964C (zh) 海洋深水网箱的抗污漆
KR20220078860A (ko) 변성 에테르 폴리디알킬실록산 화합물, 이의 제조방법 및 이를 포함하는 해상용 방오도료
CN102125038A (zh) 一种含丹皮酚和烟碱结构的防污剂及其制备方法
CN101314682B (zh) 一种防污添加剂及其制备方法
JPH01201377A (ja) 防汚塗料用樹脂組成物
KR20060074046A (ko) 방오 도료 조성물

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160817

Termination date: 20181229