CA2957666C - Functionalized silica with elastomer binder - Google Patents
Functionalized silica with elastomer binder Download PDFInfo
- Publication number
- CA2957666C CA2957666C CA2957666A CA2957666A CA2957666C CA 2957666 C CA2957666 C CA 2957666C CA 2957666 A CA2957666 A CA 2957666A CA 2957666 A CA2957666 A CA 2957666A CA 2957666 C CA2957666 C CA 2957666C
- Authority
- CA
- Canada
- Prior art keywords
- silica
- rubber
- polymer
- hydrophobated
- functionalized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 422
- 239000000377 silicon dioxide Substances 0.000 title claims abstract description 199
- 229920001971 elastomer Polymers 0.000 title claims abstract description 65
- 239000000806 elastomer Substances 0.000 title claims abstract description 16
- 239000011230 binding agent Substances 0.000 title description 2
- 229920000642 polymer Polymers 0.000 claims abstract description 62
- 239000002245 particle Substances 0.000 claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 15
- 239000011248 coating agent Substances 0.000 claims abstract description 7
- 238000000576 coating method Methods 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims description 35
- 238000010058 rubber compounding Methods 0.000 claims description 26
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 21
- 229910000077 silane Inorganic materials 0.000 claims description 21
- 238000002156 mixing Methods 0.000 claims description 19
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 239000002904 solvent Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000011414 polymer cement Substances 0.000 claims description 8
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 7
- 239000003960 organic solvent Substances 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000005060 rubber Substances 0.000 abstract description 49
- 239000000203 mixture Substances 0.000 abstract description 31
- 238000009472 formulation Methods 0.000 abstract description 5
- 239000000047 product Substances 0.000 description 79
- 239000000243 solution Substances 0.000 description 24
- 150000001875 compounds Chemical class 0.000 description 20
- 229920000126 latex Polymers 0.000 description 19
- 239000006185 dispersion Substances 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000003963 antioxidant agent Substances 0.000 description 12
- 235000006708 antioxidants Nutrition 0.000 description 12
- 239000010734 process oil Substances 0.000 description 12
- 239000000945 filler Substances 0.000 description 11
- 238000001035 drying Methods 0.000 description 10
- 239000004908 Emulsion polymer Substances 0.000 description 9
- 230000008569 process Effects 0.000 description 9
- 239000004594 Masterbatch (MB) Substances 0.000 description 8
- 230000003078 antioxidant effect Effects 0.000 description 8
- 230000008901 benefit Effects 0.000 description 8
- 239000000701 coagulant Substances 0.000 description 8
- 239000002131 composite material Substances 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- 239000000706 filtrate Substances 0.000 description 7
- 238000001914 filtration Methods 0.000 description 7
- 239000012528 membrane Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000007580 dry-mixing Methods 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 238000001694 spray drying Methods 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 239000007822 coupling agent Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000000638 solvent extraction Methods 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 239000006087 Silane Coupling Agent Substances 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 239000004816 latex Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- 238000000861 blow drying Methods 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000015271 coagulation Effects 0.000 description 3
- 238000005345 coagulation Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 238000007720 emulsion polymerization reaction Methods 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 239000012254 powdered material Substances 0.000 description 3
- 150000004756 silanes Chemical class 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- 244000043261 Hevea brasiliensis Species 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003637 basic solution Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 235000011148 calcium chloride Nutrition 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000012065 filter cake Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 229920003052 natural elastomer Polymers 0.000 description 2
- 229920001194 natural rubber Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- -1 silicas Substances 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- DCQBZYNUSLHVJC-UHFFFAOYSA-N 3-triethoxysilylpropane-1-thiol Chemical compound CCO[Si](OCC)(OCC)CCCS DCQBZYNUSLHVJC-UHFFFAOYSA-N 0.000 description 1
- HKMVWLQFAYGKSI-UHFFFAOYSA-N 3-triethoxysilylpropyl thiocyanate Chemical compound CCO[Si](OCC)(OCC)CCCSC#N HKMVWLQFAYGKSI-UHFFFAOYSA-N 0.000 description 1
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 description 1
- XODFSNXVWMJCOU-UHFFFAOYSA-N 3-trimethoxysilylpropyl thiocyanate Chemical compound CO[Si](OC)(OC)CCCSC#N XODFSNXVWMJCOU-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical group SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical class [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- HESLUACQQJVBGX-UHFFFAOYSA-N o-(3-triethoxysilylpropyl) octanethioate Chemical compound CCCCCCCC(=S)OCCC[Si](OCC)(OCC)OCC HESLUACQQJVBGX-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000010074 rubber mixing Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000002444 silanisation Methods 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- TXDNPSYEJHXKMK-UHFFFAOYSA-N sulfanylsilane Chemical compound S[SiH3] TXDNPSYEJHXKMK-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
- FBBATURSCRIBHN-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyldisulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSCCC[Si](OCC)(OCC)OCC FBBATURSCRIBHN-UHFFFAOYSA-N 0.000 description 1
- VTHOKNTVYKTUPI-UHFFFAOYSA-N triethoxy-[3-(3-triethoxysilylpropyltetrasulfanyl)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCSSSSCCC[Si](OCC)(OCC)OCC VTHOKNTVYKTUPI-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/08—Ingredients agglomerated by treatment with a binding agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/006—Additives being defined by their surface area
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Tires In General (AREA)
- Silicon Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US14/456,613 | 2014-08-11 | ||
| US14/456,613 US9238729B2 (en) | 2013-02-12 | 2014-08-11 | Functionalized silica with elastomer binder |
| PCT/US2015/044420 WO2016025365A1 (en) | 2014-08-11 | 2015-08-10 | Functionalized silica with elastomer binder |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2957666A1 CA2957666A1 (en) | 2016-02-18 |
| CA2957666C true CA2957666C (en) | 2018-03-13 |
Family
ID=55304522
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2957666A Active CA2957666C (en) | 2014-08-11 | 2015-08-10 | Functionalized silica with elastomer binder |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP3180200B1 (de) |
| JP (1) | JP6295374B2 (de) |
| KR (1) | KR101824851B1 (de) |
| CN (1) | CN107074014B (de) |
| BR (1) | BR112017002610B1 (de) |
| CA (1) | CA2957666C (de) |
| ES (1) | ES2735748T3 (de) |
| MX (1) | MX368651B (de) |
| PL (1) | PL3180200T3 (de) |
| RS (1) | RS59273B1 (de) |
| RU (1) | RU2669869C2 (de) |
| WO (1) | WO2016025365A1 (de) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20190308451A1 (en) * | 2018-04-10 | 2019-10-10 | Kraton Polymers Llc | Tire Compositions and Methods for Making Thereof |
| US11680157B2 (en) | 2018-04-10 | 2023-06-20 | Kraton Corporation | Tire compositions and methods for making thereof |
| CN111073046A (zh) * | 2018-10-18 | 2020-04-28 | 中国石油天然气股份有限公司 | 一种橡胶填料纳米白炭黑高分散的改性方法 |
| CN111073347A (zh) * | 2018-10-18 | 2020-04-28 | 中国石油天然气股份有限公司 | 一种橡胶填料用超分散纳米白炭黑的制备方法 |
| CN111073354A (zh) * | 2018-10-18 | 2020-04-28 | 中国石油天然气股份有限公司 | 一种橡胶填料纳米白炭黑超分散的改性方法 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5166227A (en) | 1989-08-17 | 1992-11-24 | Zeon Chemicals Usa, Inc. | Free flowing particles of an emulsion polymer having SiO2 incorporated therein |
| DE19808746A1 (de) * | 1997-07-10 | 1999-01-21 | Bayer Ag | Verfahren zur Herstellung von füllstoffhaltigen Kautschukmischungen |
| CN1206025A (zh) * | 1997-07-10 | 1999-01-27 | 拜尔公司 | 填充的橡胶混合物的制备方法 |
| CA2216062A1 (en) * | 1997-09-19 | 1999-03-19 | Bayer Inc. | Silica-containing rubber composition |
| DE19814839A1 (de) * | 1998-04-02 | 1999-10-07 | Bayer Ag | Hydrophobierte oxidische oder silikatische Füllstoffe enthaltende Emulsionskautschukmischungen sowie deren Verwendung zur Herstellung von Reifen |
| CN1368995A (zh) * | 1999-08-19 | 2002-09-11 | 陶氏康宁公司 | 化学改性硅石填料,生产方法和含有它的硅氧烷组合物 |
| ES2267842T3 (es) * | 2000-10-13 | 2007-03-16 | Michelin Soc Tech | Composicion de caucho que comprende como agente de acoplamiento un organosilano polifuncional. |
| DE10151430A1 (de) * | 2001-10-18 | 2003-04-30 | Degussa | Silikatische und oxidische Füllstoffe enthaltende Kautschukgranulate |
| JP2003138025A (ja) * | 2001-11-06 | 2003-05-14 | Tokuyama Corp | シリカ充填ゴムの製造方法 |
| US7101922B2 (en) * | 2001-12-18 | 2006-09-05 | The Goodyear Tire & Rubber Company | Method for preparing elastomer/silica composite |
| WO2004014796A1 (de) * | 2002-08-03 | 2004-02-19 | Degussa Ag | Hochdispersible fällungskieselsäure mit hoher oberfläche |
| WO2005000957A1 (ja) * | 2003-06-30 | 2005-01-06 | Zeon Corporation | シリカ含有ゴム組成物及びその製造方法 |
| US7307121B2 (en) * | 2004-03-19 | 2007-12-11 | The Goodyear Tire & Rubber Company | Silica containing rubber composition |
| JP2006225600A (ja) * | 2005-02-21 | 2006-08-31 | Bridgestone Corp | ゴム組成物を用いた空気入りタイヤ |
| US20060225615A1 (en) * | 2005-04-11 | 2006-10-12 | Raman Narayan K | Treated filler and process and producing |
| ES2665457T3 (es) * | 2008-07-24 | 2018-04-25 | Industrias Negromex, S.A. De C.V | Procesos para elaborar silano, sílice hidrofobizada, mezcla maestra de sílice y productos de caucho |
| FR2954775B1 (fr) * | 2009-10-30 | 2012-03-30 | Michelin Soc Tech | Methode de preparation d'un melange maitre d'elastomere dienique synthetique et de silice |
| US20130203940A1 (en) * | 2012-02-02 | 2013-08-08 | Lion Copolymer, Llc | Preparation of styrene butadiene rubber masterbatch using polyamide and an epoxidized silica |
-
2015
- 2015-08-10 CN CN201580042590.7A patent/CN107074014B/zh active Active
- 2015-08-10 KR KR1020177006115A patent/KR101824851B1/ko active IP Right Grant
- 2015-08-10 BR BR112017002610-4A patent/BR112017002610B1/pt active IP Right Grant
- 2015-08-10 CA CA2957666A patent/CA2957666C/en active Active
- 2015-08-10 RS RSP20190915 patent/RS59273B1/sr unknown
- 2015-08-10 MX MX2017001561A patent/MX368651B/es active IP Right Grant
- 2015-08-10 EP EP15831692.7A patent/EP3180200B1/de active Active
- 2015-08-10 JP JP2017507418A patent/JP6295374B2/ja not_active Expired - Fee Related
- 2015-08-10 WO PCT/US2015/044420 patent/WO2016025365A1/en active Application Filing
- 2015-08-10 ES ES15831692T patent/ES2735748T3/es active Active
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- 2015-08-10 RU RU2017107252A patent/RU2669869C2/ru active
Also Published As
| Publication number | Publication date |
|---|---|
| ES2735748T3 (es) | 2019-12-20 |
| EP3180200A4 (de) | 2018-04-25 |
| KR101824851B1 (ko) | 2018-03-14 |
| CN107074014A (zh) | 2017-08-18 |
| MX368651B (es) | 2019-10-10 |
| PL3180200T3 (pl) | 2020-01-31 |
| RU2669869C2 (ru) | 2018-10-16 |
| EP3180200A1 (de) | 2017-06-21 |
| CA2957666A1 (en) | 2016-02-18 |
| BR112017002610A2 (pt) | 2017-12-05 |
| MX2017001561A (es) | 2017-08-02 |
| CN107074014B (zh) | 2019-05-17 |
| RU2017107252A (ru) | 2018-09-13 |
| KR20170030650A (ko) | 2017-03-17 |
| WO2016025365A1 (en) | 2016-02-18 |
| BR112017002610B1 (pt) | 2021-07-27 |
| JP2017526774A (ja) | 2017-09-14 |
| JP6295374B2 (ja) | 2018-03-14 |
| RU2017107252A3 (de) | 2018-09-13 |
| RS59273B1 (sr) | 2019-10-31 |
| EP3180200B1 (de) | 2019-06-19 |
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