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中国花岗岩型锂矿床: 重要特征、成矿条件及形成机制

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文章导航 > 岩石学报 > 2024 > 40(2): 347-403
郭春丽, 张斌武, 郑义, 许箭琪, 赵迁迁, 闫金禹, 周睿, 符伟, 黄可. 2024. 中国花岗岩型锂矿床: 重要特征、成矿条件及形成机制. 岩石学报, 40(2): 347-403. doi: 10.18654/1000-0569/2024.02.02
引用本文: 郭春丽, 张斌武, 郑义, 许箭琪, 赵迁迁, 闫金禹, 周睿, 符伟, 黄可. 2024. 中国花岗岩型锂矿床: 重要特征、成矿条件及形成机制. 岩石学报, 40(2): 347-403. doi: 10.18654/1000-0569/2024.02.02
shu
GUO ChunLi, ZHANG BinWu, ZHENG Yi, XU JianQi, ZHAO QianQian, YAN JinYu, ZHOU Rui, FU Wei, HUANG Ke. 2024. Granite-type lithium deposits in China: Important characteristics, metallogenic conditions, and genetic mechanism. Acta Petrologica Sinica, 40(2): 347-403. doi: 10.18654/1000-0569/2024.02.02
Citation: GUO ChunLi, ZHANG BinWu, ZHENG Yi, XU JianQi, ZHAO QianQian, YAN JinYu, ZHOU Rui, FU Wei, HUANG Ke. 2024. Granite-type lithium deposits in China: Important characteristics, metallogenic conditions, and genetic mechanism. Acta Petrologica Sinica, 40(2): 347-403. doi: 10.18654/1000-0569/2024.02.02
shu

中国花岗岩型锂矿床: 重要特征、成矿条件及形成机制

    • 1.

      成矿作用与资源评价自然资源部重点实验室, 中国地质科学院矿产资源研究所, 北京 100037

    • 2.

      自然资源部深地科学与探测技术实验室, 中国地质科学院, 北京 100094

    • 3.

      中国地质大学, 北京 100083

    • 4.

      中南大学, 长沙 410083

  • 基金项目:

    本文受国家自然科学基金重点项目(92162210)、面上项目(42172096)和中国地质调查局项目(DD20221695)联合资助

详细信息
    作者简介:

    郭春丽, 女, 1978年生, 研究员, 从事花岗岩及其相关稀有稀散金属成矿作用研究, E-mail: gchunli@126.com

  • 中图分类号: P588.121;P611;P618.71

Granite-type lithium deposits in China: Important characteristics, metallogenic conditions, and genetic mechanism

    • 1.

      MNR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, Chinese Academy of Geological Sciences, Beijing 100037, China

    • 2.

      SinoProbe Laboratory, Chinese Academy of Geological Sciences, Beijing 100094, China

    • 3.

      China University of Geosciences, Beijing 100083, China

    • 4.

      Central South University, Changsha 410083, China

    摘要

  • 随着新能源汽车产业的快速发展和可控核聚变技术的不断革新, 锂产业已成为各国竞相发展的新兴朝阳产业, 全球锂资源争夺态势愈发激烈。中国是全球拥有花岗岩型锂矿床数量最多的国家, 目前该类型锂矿占全国锂总供应量的1/4, 进一步加强对该类型锂矿的研究和勘查对提升我国锂资源的自给能力至关重要。通过对全国40个主要花岗岩型锂矿床的时空分布、岩石序列、矿物演变、地球化学和高锂含量矿物等特征的梳理, 发现该类矿床主要形成于中生代晚侏罗世-早白垩世期间, 主要集中在华南地区尤以华南腹地的南岭地区最为密集; 近1/3的成矿岩体隐伏于地下, 出露的岩体面积普遍较小, 为0.07~5.7km2; 花岗岩体垂直方向从下至上逐渐从黑云母二长花岗岩演变为锂云母钠长石花岗岩, 其上通常发育云英岩和伟晶岩; 锂及其他稀有元素(铷铯铍铌钽钨锡)一般在强钠长石花岗岩和云英岩中高度富集; 黑云母二长花岗岩→含锂云母钠长花岗岩→云英岩, 岩浆分异程度逐步增加且逐渐从熔体过渡到熔体-流体共存体系, 全岩SiO2含量、Nb/Ta和Zr/Hf比值、A/CNK和δEu值发生规律性变化; 多数情况下岩体伴生煌斑岩脉、辉长岩脉、辉绿岩脉、花岗斑岩脉、细晶岩脉、霏细岩脉等各类脉体。总结规律提出: (1)伟晶岩壳是较早进入岩浆房内的岩浆与上覆围岩接触而冷却固结的产物, 其构成岩浆房与外界的隔绝屏障, 使Li、F、P、H2O等易挥发组分无法逃逸; (2)较晚进入岩浆房的岩浆经历了长时间晶粥体与残留熔体的分凝过程, 锂等稀有金属元素愈来愈富集于残余熔体中, 最终形成富锂花岗岩和云英岩; (3)各类岩脉是岩浆房底部有持续热补给从而使残留含矿熔体能够逐步抽离上升的证据: 基性岩脉来源于下伏高温地幔岩浆, 不含矿中酸性斑岩脉是岩浆房底部堆晶体重熔的产物, 含矿酸性斑岩脉和细粒岩脉来自岩浆房顶部富矿熔体-流体, 三者沿地壳裂隙快速上升至地壳浅部就位。正是由于上覆伟晶岩壳形成的封闭体系和下伏幔源岩浆提供的充足热量, 才使得岩浆房在热驱动机制下长期保持原地分异状态, 最终形成花岗岩型锂矿床。

    Due to the rapid development of the electric vehicle and the continuous innovation of controllable nuclear fusion, the competition of lithium supply capacity is happening all over the world. China has the most quantity of granitic-type lithium deposits in the world and this type of lithium deposits accounts for 1/4 of the total lithium supply in the country at present. So it is very important that the breakthrough not only the theoretical study but also the mineral exploration is crucial to enhance the self-sufficiency of lithium resources in China. In this work, by integrating the geology characteristics, rock sequence, mineral evolution, geochemistry and lithium independent minerals of 40 granitic-type lithium deposits in China, we found that: (1) They mainly formed in Late Jurassic to Early Cretaceous and focused in South China, especially in the Nanling range; (2) There are 1/3 of ore-forming granitic plutons are buried underground and the outcrop areas are commonly small with 0.07~5.7km2; (3) The plutons generally evolved from dark biotite-bearing monzogranite to light lepidolite-bearing albite granite from bottom to top in a vertical direction, with greisen and pegmatite at the top; (4) Li with other rare-metal elements including Rb, Cs, Be, Nb, Ta, W and Sn highly enriched in the albitie granite and greisen; (5) Biotite granite → Li-bearing albite granite → greisen, the crystal fractionation of magmas gradually inceased and the magma system gradually evolved towards melt-fluid coexistence. Moreover, the whole-rock SiO2 contents and values of A/CNK, Nb/Ta, Zr/Hf and δEu changed regularly; (6) Various types of dykes such as lamprophyre, gabbro, diabase, granite porphyry, aplite, and felsite are associated with the ore-bearing plutons in most cases. Based on above characteristics, we concluded that: (1) The pegmatite shell was the product generated the earliest by cooling and consolidation of magma batches, which were injected earlier in the magma reservoir by contacting with the cold wall-rock, so it formed a barrier between the magma reservoir and the outside to prevent escaping of the volatile components of Li, F, P, H2O, and so on; (2) The later batches of magma injected into the magma reservoir experienced a long process of crystal mush-residual melt segregation leading to the increasing enrichment of Li and other rare-metal elements in the residual magma forming ultimately the Li-rich granites and greisens; (3) Various types of dykes are the evidence of continuous heat supply under the magma reservoir, allowing the residual ore-bearing melt to be gradually extracted upwards: the mafic dykes came from the high-temperature mantle magmas; Ore-free intermediate-acidic porphyritic dykes were the product of the cumulate remelting from the bottom of magma reservoir; Ore-bearing acidic porphyritic dykes and aplitic dykes generated from the ore-rich magma from the top of the magma reservoir. This is because that the close system produced by the overlying pegmatite shells and underlying heat below the magma reservoir, the magmas in the magma could keeping crystal fractionation to finally evoled into the granitic-type lithium deposits.

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  • 图 1 

    中国花岗岩型锂矿床构造区带分布图(底图据刘英超等, 2022修改；矿床编号见表 1)

    Figure 1. 

    Distribution of the Chinese granite-type lithium deposits in the tectonic zonation map (base map modified after Liu et al., 2022; the serial number of deposits showen in Table 1)

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    图 2 

    中国花岗岩型锂矿成岩成矿年龄直方图(数据来源于表 2)

    Figure 2. 

    Histograms of crystallization and mineralization ages of the granite-type lithium deposits in China (data from Table 2)

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    图 3 

    代表性矿区显示花岗岩演化序列的手标本照片

    Figure 3. 

    Field photographs of various granites showing the evolutionary process from the representative granite-type lithium deposits

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    图 4 

    代表性矿区各类典型的含锂云母显微镜下照片

    Figure 4. 

    Photomicrographs of various Li-bearing micas from the representative granite-type lithium deposits

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    图 5 

    江西414和白水洞矿床中磷锂铝石显微照片

    Figure 5. 

    Photomicrographs of the amblygonite and montebrasite from the 414 and Baishuidong granite-type lithium deposits in Jiangxi Province

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    图 6 

    代表性矿区的伟晶岩手标本和显微镜下照片

    Figure 6. 

    Field photographs and photomicrographs of various pegmatites from the representative granite-type lithium deposit

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    图 7 

    代表性矿区云英岩手标本和显微镜下照片

    Figure 7. 

    Field photographs and photomicrographs of various greisens from the representative granite-type lithium deposits

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    图 8 

    中国北方与南方花岗岩型锂矿床花岗岩锆石Hf和全岩Nd同位素特征对比

    Figure 8. 

    Comparision diagrams of zircon Hf and whole-rock Nd isotope characteristics in granites from the granite-type lithium deposits in North and South areas

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    图 9 

    中国花岗岩型锂矿床中黑云母二长花岗岩、含锂云母钠长花岗岩、云英岩主量元素分类图

    Figure 9. 

    Classification diagrams of whole-rock major elements for the biotite monzonitic granite, Li-bearing albite granite and greisen in the granite-type lithium deposits in China

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    图 10 

    4个典型花岗岩型锂矿床中黑云母二长花岗岩、含锂云母钠长花岗岩、云英岩稀土元素配分模式(标准化值据Sun and McDonough, 1989)

    Figure 10. 

    Rare-earth element patterns of the biotite monzonitic granite, Li-bearing albite granite and greisen from four typicl granite-type lithium deposits (normalization values from Sun and McDonough, 1989)

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    图 11 

    中国花岗岩型锂矿床中黑云母二长花岗岩、含锂云母钠长花岗岩、云英岩演化趋势判别图

    Figure 11. 

    Discrimination diagrams of evolutionary trend for the biotite monzonitic granite, Li-bearing albite granite and greisen in the granite-type lithium deposits in China

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    图 12 

    中国花岗岩型锂矿床云母分类图(底图据Tischendorf et al., 1997)

    Figure 12. 

    Classification diagram of mica group minerals from the granite-type lithium deposits in China (base map after Tischendorf et al., 1997)

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    图 13 

    中国花岗岩型锂矿床云母Li、F、Rb、Cs、Nb、Ta、W、Sn元素含量相关图

    Figure 13. 

    Correlation diagrams of the Li, F, Rb, Cs, Nb, Ta, W, Sn contents in micas from the granite-type lithium deposits in China

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    图 14 

    代表性成矿花岗岩体不同类型岩性接触关系野外照片

    Figure 14. 

    Field photographs of contact relations between different lithological types in the representative ore-bearing granitic plutons

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    图 15 

    花岗岩型锂矿床形成模式图

    Figure 15. 

    The model diagram showing the forming process of the granite-type lithium deposit

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    表 1 

    中国花岗岩型锂矿床基本特征汇总表

    Table 1. 

    Summary of essential characteristics from the granite-type lithium deposits in China

    省区 序号 矿床名称 所属市县 成矿母岩/面积
    (km2)    		 Li2O资源量(万t) 全岩Li2O含量(%) 云母Li2O含量(%) 参考文献
    江西 1 414 宜春市 雅山岩体/9.5 71.53 0.02~3.23 0.04~11.68 Pollard, 2021; Li et al., 2015, 2018b; 李胜虎, 2015
    2 白水洞 宜丰县 甘坊岩体/400 1086.65 0.28~1.67 0.08~8.19 吴学敏等, 2016; 刘爽等, 2019; 王成辉等, 2019; 陈祺等, 2022; 陈祥云等, 2023; 刘泽等, 2023
    3 黄沙坪 奉新县 岩体 16.92 0.47 王核等, 2022; 孙艳等, 2019
    4 松树岗 横峰县 隐伏岩体 60.38 0.17~0.34 1.03~4.09 曾庆友等, 2021; 薛荣, 2019; 诸泽颖, 2018
    5 黄山 横峰县 隐伏岩体 0.02~0.09 0.9~3.64 Zhu et al., 2019; 江小强, 2020; Wang et al., 2023
    6 姜坑里 石城县 岩株 1.37 0.3 刘爽等, 2019; 王核等, 2022
    7 海罗岭 石城县 岩株/0.6 0.26 0.12 王核等, 2022; 徐喆等, 2023
    8 牛岭坳 赣县 3.3 0.11 江西省地质矿产勘查开发局赣南地质调查大队, 2010①; 王核等, 2022
    9 上坪 于都县 隐伏岩体 0.47 3.17 王核等, 2022
    10 九曲 龙南市 岩体/2.65 30 0.3 江西省地质局第一地质大队, 2022②
    11 留家山 安福县 细晶岩 21.6 0.65 王核等, 2022; 徐喆等, 2022
    12 浒坑 安福县 细晶岩 0.5 徐喆等, 2022
    13 茅坪 崇义县 隐伏岩体 陈莉莉等, 2018; 陈光弘, 2019; Chen et al., 2019
    14 旱叫山 会昌县 岩株/0.466 张何猛, 2011; 蔡小龙和王佳玲, 2022
    湖南 15 正冲 道县 金鸡岭岩体/390 27 0.56 0.35~1.01 文春华等, 2016; 王核等, 2022
    16 辉山坪 桂阳县、常宁市 大义山岩体/280 0.02~0.49 0.05~2.53 Zhang et al., 2022b; Zhao et al., 2022; 张遵遵等, 2023
    17 香花铺 临武县 尖峰岭岩体/4.4 8.17 0.0054~0.82 1.50~3.54 邱瑞照等, 1998a; 文春华等, 2017; 覃莉茜等, 2021; 袁玲玲等, 2022; 王正东等, 1974③
    18 香花岭 临武县 癞子岭岩体/2.2 0.0028~0.56 1.05~3.55 邱瑞照等, 1998a; 朱金初等, 2011; Xie et al., 2018; 覃莉茜等, 2021; 袁玲玲等, 2022
    19 金竹垄 茶陵县 隐伏岩体 孙颖超等, 2017; 毛禹杰等, 2021
    20 长城岭 宜章县 花岗斑岩体 0.07~0.78 0.96~10.92 张术根等, 2015; 朱恩异等, 2021, 2022; 蒋宗和, 2021
    21 上堡 耒阳县 岩体/2.1 0.11~0.41 陈湘立等, 2003; 伍光英, 2005; Zhao et al., 2021
    22 界牌岭 宜章县 花岗斑岩体/0.12 0.002~1.06 0.39~4.02 Xie et al., 2016; 林晓青, 2020
    23 小江 桂东县 岩体/2 0.02~0.07 李建康等, 2012
    广东 24 深坑 广宁县 岩体 冯进喜, 2018
    25 一六 曲江县 宝山岩株/0.4 0.2 0.07~0.21 秦锦华等, 2022; 王核等, 2022
    26 良源 始兴县 隐伏岩体 肖惠良等, 2010; 范飞鹏等, 2022
    27 中坝 紫金县 岩株/0.071 0.25 张国庆, 2016
    广西 28 栗木 恭城县 泡水岭岩株/0.1 0.09 0.81 黄雅乔, 1980; 史明魁和孙恭安, 1981; 李惠等, 1983; 杜杰等, 1990④; 张怀峰等, 2013; 董业才, 2014; Peng et al., 2023
    香坛岭和牛栏岭岩株/1.2 0.07~0.14 1.67 黄雅乔, 1980; 史明魁和孙恭安, 1981; 杜杰等, 1990; 张怀峰等, 2013; 董业才, 2014; Peng et al., 2023
    老虎头岩株/0.2 0.15~0.23 0.01~1.92 李惠等, 1983; 张怀峰等, 2013; 董业才, 2014; 马万伟, 2019; 马万伟等, 2020
    金竹源隐伏岩体 0.64 李惠等, 1983; 林德松, 1985; 张怀峰等, 2013
    大岐岭隐伏岩体 0.04~0.07 0.39 林德松, 1985
    水溪庙隐伏岩体 0.046~0.164 0.81~6.49 史明魁和孙恭安, 1981; 李惠等, 1983; 林德松, 1985; 曹瑞欣, 2009; 张怀峰等, 2013; Peng et al., 2023
    狮子岭隐伏岩体 0.21 林德松, 1985
    29 巴马 巴马县 花岗斑岩脉 0.094 0.3~0.4 姚明等, 2016
    浙江 30 河桥 临安县 河桥岩体/59.13 0.02~0.07 0.25~3.42 武彬等, 2015; 周静, 2016; 王吴梦雨, 2019
    江苏 31 善安浜 苏州市 隐伏岩体 袁晓军等, 2004; 何坚平, 2006; 司晓博, 2021
    云南 32 新歧 腾冲县 岩体/40 0.077~0.112 白嘉芬, 1987; 董方浏等, 2006; 李良等, 2009; 丛冲和罗士俊, 2012
    福建 33 大坪 永定县 花岗斑岩株 0.04~0.08 0.72~1.92 江善元等, 2016⑤; 胡永斌等, 2017; 刘永超等, 2017; 江善元, 2019; 王锦荣等, 2020b
    内蒙古 34 赵井沟 武川县 隐伏岩体 2.12 0.06~0.24 0.91~4.14 聂凤军等, 2013; 柴华和武景龙, 2013; Wei et al., 2020; 吴欢欢, 2020; Zhang and Jiang, 2021
    35 石灰窑 白音郭勒 地表出露多个小岩株 0.1~0.96 0.29~4.40 朱京占等, 2013; Duan et al., 2021; Zhou et al., 2022
    36 加不斯 镶黄旗 隐伏岩体 4.14 0.05~1.53 0.49~6.69 张荣臻等, 2023; Wang et al., 2022b; Zhang et al., 2022a, 2023a
    37 东七一山 北山 岩株/1.3 0.14~0.22 3.46 刘洪, 1986; 王勇等, 2009; 吕博等, 2011; 康建飞, 2019
    河北 38 麻地 兴隆县 岩体/5.7 115 0.04~0.25 2.85 苗群峰, 2018; 侯江龙, 2018; 苗群峰和齐云飞, 2020
    39 汉儿庄 迁西县 岩株/0.81 0.13~0.32 赵凯华等, 2018⑥; 郭志伟, 2019
    甘肃 40 国宝山 瓜州县 岩体/13 1.91 赖杨等, 2016
    注：①江西省地质矿产勘查开发局赣南地质调查大队. 2010. 江西省赣县6812(牛岭坳)稀土矿核查区资源储量核查报告
    ②江西省地质局第一地质大队. 2022. 江西省龙南市龙泰铜多金属矿核实项目设计
    ③王正东, 熊永久, 刘干宏, 谭日录, 贺文良, 马静山, 张如周, 农宜让, 易佑磁, 陈吉祥, 代仁初, 刘福初, 管于英, 欧阳祥胜, 陈鼎凯, 吴永驹, 包秋君, 吴介初, 文礼仪, 苏爱莲, 倪再泉, 姚吉珍, 万迪光, 周金铭. 1974. 湖南临武香花铺矿区尖峰岭钽铌矿床地质勘探总结报告
    ④杜杰, 唐章焕, 吴精适, 陈佩成, 李清生, 罗毅, 吴玉书, 廖耀雄, 秦映林. 1990. 广西恭城县栗木矿田水溪庙花岗岩型锡钽铌矿床锡矿段详查地质报告
    ⑤江善元, 沈开和, 范张华, 郭腾飞, 叶盛源, 陈文庆, 詹勇, 黄照强, 陈珍烟, 王锦荣. 2016. 福建永定-南平地区稀有、稀土矿调查评价报告
    ⑥赵凯华, 白智慧, 刘博, 谢芷峰, 刘杰, 边防, 高甫, 闫领军, 侯恩石, 周雪, 张弛, 刘才云, 崔丙志, 赵智伟. 2018. 河北省迁西县汉儿庄-抚宁县响山一带稀有稀土元素矿产调查报告
    下载: 导出CSV

    表 2 

    中国花岗岩型锂矿床成岩成矿年龄汇总表

    Table 2. 

    Summary of crystallization and mineralization ages from the granite-type lithium deposits in China

    省区 序号 矿床名称 成岩成矿年龄 参考文献
    测试矿物 分析方法 年龄(Ma)
    江西 1 414 锆石(C) LA-ICP-MS U-Pb 158±1.8、156±0.4 左梦璐, 2016
    铌钽铁矿(M) LA-ICP-MS U-Pb 160±1 Che et al., 2015
    锆石(C) U-Pb 155 卜涛和赵葵东, 2015
    辉钼矿(M) Re-Os 156.0±2.8 易先奎等, 2015
    辉钼矿(M) Re-Os 150.6±5.1 李胜虎, 2015
    锆石(C) LA-ICP-MS U-Pb 155.9±0.6 李胜虎, 2015
    锆石(C) LA-ICP-MS U-Pb 150.1±1.0、150.2±1.4 杨泽黎, 2015
    2 白水洞 锆石(C) LA-ICP-MS U-Pb 146.3±1.08 姜宝亮等, 2022
    锆石(C) LA-ICP-MS U-Pb 148±7、146.8±3.3、144.2±2.1、143.9±1.7、152.2±3.2 Wang et al., 2022a
    铌铁矿族矿物(M) LA-ICP-MS U-Pb 144±5 刘莹, 2019
    4 松树岗 黑云母(M) K-Ar 124~131 江西省地质调查研究院, 2015①
    铌钽氧化物(M) LA-ICP-MS U-Pb 130±2、129±1 诸泽颖, 2018; Che et al., 2019
    5 黄山 铌钽氧化物(M) LA-ICP-MS U-Pb 130±1、129±1 诸泽颖, 2018; Che et al., 2015, 2019
    锆石(C) SIMS U-Pb 133.6±2.2 Xiang et al., 2017
    独居石(M) LA-ICP-MS U-Pb 119±1.2 江小强, 2020
    6 姜坑里 全岩(C) Rb-Sr 140.6 周亮等, 1989 ②
    7 海罗岭 锆石(C) LA-ICP-MS U-Pb 141.9±1.1 徐喆等, 2023
    独居石(M) LA-ICP-MS U-Pb 141.7±0.7、137.6±0.7 徐喆等, 2023
    8 牛岭坳 全岩(C) Rb-Sr 132 李启津, 1976③
    9 上坪 锆石(C) SHRIMP U-Pb 159.7±5.5、154.9±2.3 张文兰等, 2012
    10 九曲 锆石(C) LA-ICP-MS U-Pb 169.6±0.8 赵希林等, 2013
    锆石(C) SHRIMP U-Pb 169±8 赵希林等, 2013
    白云母(M) Ar-Ar 170.4±2.2 赵希林等, 2013
    13 茅坪 辉钼矿(M) Re-Os 156.5±3.9 曾载淋等, 2009
    锡石(M) LA-ICP-MS U-Pb 156.8±1.5、156.9±1.4 Chen et al., 2019
    云母(M) Ar-Ar 156±1、155±1 Legros, 2017
    黑钨矿(M) ID-TIMS U-Pb 156.28±0.46、160.37±0.36 Legros, 2017
    14 旱叫山 全岩(C) K-Ar 144 ~ 150 陈毓川等, 1989
    132 中国矿产地质志编委会, 2019
    132~136 何维基, 2001
    湖南 15 正冲 全岩(C) Rb-Sr 153.7±2.3、142.0±8.5 王京彬, 1990
    独居石(M) LA-ICP-MS U-Pb 149.9±0.5、150.1±0.9、150.0±0.6、149.9±1.0、148.8±1.0 Liu et al., 2022a
    锆石(C) SHRIMP U-Pb 156±2 付建明等, 2004
    锆石(C) LA-ICP-MS U-Pb 151.7±1.5、152.9±0.9 Liu et al., 2019
    16 辉山坪 锆石(湖冲庵)(C) LA-ICP-MS U-Pb 158.7±1.3、159.5±1.0、160.2±2.2 李剑锋等, 2023
    锆石(岩前)(C) LA-ICP-MS U-Pb 157±1.4、158.8±1.1、159.3±0.9 李剑锋等, 2023
    锆石(介头)(C) LA-ICP-MS U-Pb 153.5±0.9、157.7±0.9 李剑锋等, 2023
    锆石(道士仙、岩前)(C) LA-ICP-MS U-Pb 154.8±0.9、156.2±2.0、157.6±1.1 李剑锋等, 2023
    锆石(下东卡坪、小恒)(C) LA-ICP-MS U-Pb 154.9±1.9、155.2±0.9、155.8±1.5 李剑锋等, 2023
    锆石(杉树排、小恒)(C) LA-ICP-MS U-Pb 151.2±2.8、153.4±3.1、154±2.5 李剑锋等, 2023
    锆石(小恒)(C) LA-ICP-MS U-Pb 151.7±1.1、154.1±1、154.5±1.8 李剑锋等, 2023
    锆石(小江)(C) LA-ICP-MS U-Pb 150±1.2、150.4±2、151.6±1.1 李剑锋等, 2023
    锡石(M) LA-ICP-MS U-Pb 154±4、154.0±2.3、159±3 李剑锋等, 2023
    铁锂云母(M) Ar-Ar 154.7±1.1、152.6±0.9、151.1±0.9 李剑锋等, 2023
    石英(M) Rb-Sr 148±5、148.1±2.1 李剑锋等, 2023
    锆石(藤山坳)(C) LA-ICP-MS U-Pb 146.2±1.6、158.2±1.2 张遵遵等, 2022
    锆石(C) LA-ICP-MS U-Pb 154.5±1.6、155.5±0.5 Lu et al., 2022
    白云母(M) Ar-Ar 150.4±0.9 Lu et al., 2022
    锆石(C) LA-ICP-MS U-Pb 144±1、160±1、161±1、161±1、161±1 Zhang et al., 2022b
    锆石(C) LA-ICP-MS U-Pb 153.0±1.8、154.0±1.8 Zhao et al., 2022
    锡石(M) LA-ICP-MS U-Pb 154.0±5.4 Zhao et al., 2022
    锆石(C) LA-ICP-MS U-Pb 153.7±1.2、154.5±1.6、155.5±0.5、157.1±1.1 尤帅毅, 2022
    绢云母(M) Ar-Ar 150.4±0.9 尤帅毅, 2022
    石英(M) Rb-Sr 150.4±0.9 尤帅毅, 2022
    锆石(C) LA-ICP-MS U-Pb 158.2±1.6 Zhang et al., 2021
    锡石(M) LA-ICP-MS U-Pb 156.7±4.3 Zhang et al., 2021
    白云母(M) Ar-Ar 151.8±1.51 Zhang et al., 2021
    锆石(C) LA-ICP-MS U-Pb 154.6±1.2、154.7±1.6 Lu et al., 2021
    白云母(M) Ar-Ar 151.1±0.9 Lu et al., 2021
    白云母(M) Ar-Ar 152.6±0.7、154.7±1.1 Guo et al., 2019
    锆石(C) LA-ICP-MS U-Pb 154.2±2.0、159.6±1.9 Guo et al., 2019
    锡石(M) LA-ICP-MS U-Pb 156.5±2.8、158.0±1.8 Sun et al., 2018
    辉钼矿(M) Re-Os 157.9±7.7 Sun et al., 2018
    锆石(C) LA-ICP-MS U-Pb 156.3±1.2 Sun et al., 2018
    锆石(C) LA-ICP-MS U-Pb 153.4±1.1 赵增霞等, 2017
    锆石(C) LA-ICP-MS U-Pb 164.2±2.6、169.9±1.8、171.8±1.9 李勇等, 2015
    石英(M) Rb-Sr 160±1 张晓军等, 2014
    锆石(C) LA-ICP-MS U-Pb 168.5±2.8、147.5±3.5 费利东, 2012
    黑云母(M) Ar-Ar 156.2±1.6 刘耀荣等, 2005
    17 香花铺 锆石(C) LA-ICP-MS U-Pb 154.3±2.2 Wu et al., 2022
    锆石(C) LA-ICP-MS U-Pb 160.7±2.2 轩一撒等, 2014
    锆石(C) LA-ICP-MS U-Pb 165.3±1.4 Yang et al., 2018
    锆石(C) LA-ICP-MS U-Pb 156±2、157±2 Che et al., 2019
    白云母(M) Ar-Ar 161.3±1.1、158.7±1.2 Yuan et al., 2007
    独居石(M) LA-ICP-MS U-Pb 153.8±0.8 袁玲玲等, 2022
    18 香花岭 锆石(C) LA-ICP-MS U-Pb 155±2、154.4±1.0 朱金初等, 2011
    锆石(C) LA-ICP-MS U-Pb 225.3±2.4、149.8±2.2、148.1±2.9、150.4±1.0、81.6±1.1 Li et al., 2018a
    锆石(C) LA-ICP-MS U-Pb 222.2±4.2、152.5±4.7、152.1±1.2、152.7±6.0、81.9±6.0 Xiao et al., 2019
    锆石(C) LA-ICP-MS U-Pb 152.8±0.6、156.4±1.4 Yang et al., 2018
    锆石(C) SHRIMP 156.4±1.5、144.5±1.9、144.5±5、139.5±1.9、124.2±1.8 Wu et al., 2022
    独居石(M) LA-ICP-MS U-Pb 155.5±0.7、155.3±0.5 Wu et al., 2022
    白云母(M) Ar-Ar 154.4±1.1 Yuan et al., 2007
    锡石(M) LA-ICP-MS U-Pb 156±4 Yuan et al., 2008
    铌铁矿-坦铁矿(M) LA-ICP-MS U-Pb 158±6 Che et al., 2019
    辉钼矿(M) Re-Os 157.8±4.1 Wu et al., 2022
    19 金竹垄 铌钽氧化物(M) LA-ICP-MS U-Pb 153~158 毛禹杰等, 2021
    铌钽氧化物(M) LA-ICP-MS U-Pb 156 Che et al., 2019
    锆石(C) LA-ICP-MS U-Pb 155±1 孙颖超等, 2017
    白云母(M) Ar-Ar 148.3±1.1 孙颖超等, 2017
    20 长城岭 锆石(C) LA-ICP-MS U-Pb 153±14、231.6±0.7 刘勇等, 2012
    锆石(C) LA-ICP-MS U-Pb 222.5±1.8 朱恩异等, 2022
    21 上堡 黄铁矿(M) Re-Os 85 Huang et al., 2017
    锆石(C) LA-ICP-MS U-Pb 87.3±0.9 Zhao et al., 2021
    铌钽氧化物(M) LA-ICP-MS U-Pb 86.8±0.4 Zhao et al., 2021
    22 界牌岭 全岩(C) Sr-Nd 87.9±2.5 刘悟辉等, 2006
    黑云母(M) Ar-Ar 91.1±1.1 毛景文等, 2007
    锆石(C) SHRIMP U-Pb 92±1.6 卢友月等, 2013
    锆石(C) LA-ICP-MS U-Pb 90.5±0.9 Yuan et al., 2015
    黑云母(M) Ar-Ar 92.1±0.7 Yuan et al., 2015
    锆石(C) LA-ICP-MS U-Pb 91±1 Xie et al., 2016
    铌铁矿(M) LA-ICP-MS U-Pb 89±2 Xie et al., 2016
    广东 24 深坑 铌钽氧化物(M) LA-ICP-MS U-Pb 245±3 Che et al., 2019
    25 一六 辉钼矿(M) Re-Os 155.6±2.1 余伟, 2020
    全岩(C) K-Ar 137 吴桂捷等, 1994
    26 良源 锆石(C) SHRIMP U-Pb 159.2 ~ 163.6 范飞鹏等, 2022
    锆石(C) LA-ICP-MS U-Pb 163±1.6 范飞鹏等, 2022
    白云母(M) Ar-Ar 166.4±1.1、168.7±1.2 范飞鹏等, 2022
    辉钼矿(M) Re-Os 160.5±1.4 范飞鹏等, 2022
    27 中坝 锆石(C) LA-ICP-MS U-Pb 135.4±0.6、137±0.9 张国庆, 2016
    广西 28 栗木 锆石(泡水岭)(C) LA-ICP-MS U-Pb 210±4、222±5、239.8±4.3 娄峰等, 2014
    锆石(泡水岭)(C) LA-ICP-MS U-Pb 230.8±0.6 Feng et al., 2019
    锆石(泡水岭)(C) LA-ICP-MS U-Pb 227.7±4.5 Huang et al., 2020
    锆石(牛栏岭)(C) LA-ICP-MS U-Pb 223.6±1.7、223.7±1.7 张怀峰等, 2013
    锆石(鱼菜岩体)(C) LA-ICP-MS U-Pb 222.7±1.2 Feng et al., 2019
    锆石(大岐岭)(C) LA-ICP-MS U-Pb 224.8±1.6 张怀峰等, 2014
    锆石(老虎头)(C) LA-ICP-MS U-Pb 203.1±3.0 Huang et al., 2020
    锆石(老虎头)(C) LA-ICP-MS U-Pb 216.3±1.7 潘知博等, 2023
    锆石(水溪庙)(C) LA-ICP-MS U-Pb 202.9±3.8 Huang et al., 2020
    锆石(水溪庙)(C) SHRIMP U-Pb 212.3±1.8 马丽艳等, 2013
    锆石(三个黄牛)(C) SHRIMP U-Pb 214±5 康志强等, 2012
    锆石(金竹源)(C) SHRIMP U-Pb 218.3±2.4 康志强等, 2012
    锆石(金竹源)(C) SHRIMP U-Pb 218.3±2.4 Feng et al., 2013
    锡石(水溪庙)(M) LA-ICP-MS U-Pb 210.7±2.5 潘知博等, 2023
    锡石(老虎头)(M) LA-ICP-MS U-Pb 210.1±4.9 潘知博等, 2023
    锡石(金竹源)(M) LA-ICP-MS U-Pb 219.6±1.5、219.9±2.2、217.3±3.2 潘知博等, 2023
    铌铁矿-钽铁矿(水溪庙)(M) LA-ICP-MS U-Pb 217±2 Che et al., 2019
    铌铁矿-钽铁矿(金竹源)(M) LA-ICP-MS U-Pb 219±3 Che et al., 2019
    锂云母(水溪庙)(M) K-Ar 185.3 曹瑞欣, 2009
    白云母(老虎头)(M) Ar-Ar 214.3±4.5 杨锋等, 2009
    白云母(金竹源)(M) Ar-Ar 212.4±5 张怀峰, 2014
    白云母(含矿石英脉)(M) K-Ar 205.7±3.9 Feng et al., 2019
    白云母(老虎头)(M) Ar-Ar 206.6±3.5 杨锋等, 2009
    白云母(金竹源)(M) Ar-Ar 210.5±3.7 张怀峰等, 2014
    白云母(含矿石英脉)(M) Ar-Ar 207±15、204.5±6.2 Feng et al., 2019
    白云母(含矿石英脉)(M) Ar-Ar 213.66±1.10、208.37±1.23、208.01±1.04 Huang et al., 2020
    浙江 30 河桥 锆石(C) LA-ICP-MS U-Pb 127.0±1.8 Wu et al., 2012
    锆石(C) LA-ICP-MS U-Pb 149±6 武彬等, 2015
    铌钽氧化物(M) LA-ICP-MS U-Pb 130.5±1.7 王吴梦雨, 2019
    江苏 31 善安浜 锆石(C) LA-ICP-MS U-Pb 106.5±1.2 汪相, 2022
    云南 32 新歧 全岩(C) Rb-Sr 52.5 董方浏等, 2006
    黑云母(M) Rb-Sr 72~76 云南省地质科学研究所锡矿组, 1982
    锆石(C) LA-ICP-MS U-Pb 61.9±1.4 周新平等, 2015
    福建 33 大坪 铌钽氧化物(M) LA-ICP-MS U-Pb 184.2±6.8、182.4±3.3 王锦荣等, 2020a
    锆石(C) SIMS U-Pb 186.7±1.2 王锦荣等, 2020b
    锆石(C) LA-ICP-MS U-Pb 190.7±1.1 王锦荣等, 2020b
    内蒙古 34 赵井沟 锆石(C) SIMS U-Pb 127±2 吴欢欢, 2020
    锆石(C) LA-ICP-MS U-Pb 277.14±0.82、277±2.1、276.6±2.1 聂凤军等, 2013
    锆石(C) LA-ICP-MS U-Pb 125±1 李志丹等, 2019
    独居石(M) LA-ICP-MS U-Pb 124±2、124±3、124±2、125±1、121±1 李志丹等, 2019
    铌钽氧化物(M) LA-ICP-MS U-Pb 134.6±1.0、131.8±2.1 Wei et al., 2020
    热液锆石(M) LA-ICP-MS U-Pb 116±2、112.8±2.2、118.9±1.8 李雪等, 2021
    铌钽氧化物(M) LA-ICP-MS U-Pb 129±3、130±2、130±3、130±3、114±2 Zhang and Jiang, 2021
    锡石(M) LA-ICP-MS U-Pb 130±1 Zhang and Jiang, 2021
    独居石(M) LA-ICP-MS U-Pb 132±1 Zhang and Jiang, 2021
    白云母(M) Ar-Ar 129±1 Zhang and Jiang, 2021
    铌钽氧化物(M) LA-ICP-MS U-Pb 116.9±1.4 Li et al., 2023
    天河石(M) Ar-Ar 124±2 孙艳, 2013
    白云母(M) Ar-Ar 124±2 高允等, 2017
    黑云母(M) Ar-Ar 134.55±0.79 李志丹等, 2019
    35 石灰窑 独居石(C) LA-ICP-MS U-Pb 144.8±1.2、145.2±5.1、147.9±2.7、145±1.6、146.8±4.6、141±4.2 Duan et al., 2021
    独居石(C) LA-ICP-MS U-Pb 150.2±0.6、147±1.7 Zhou et al., 2022
    铌钽氧化物(M) LA-ICP-MS U-Pb 146.7±4.7 Zhou et al., 2022
    白云母(M) Ar-Ar 146.3±1.1、145.6±1 Zhou et al., 2022
    锡石(M) LA-ICP-MS U-Pb 150.3±5.2、146.9±3.5、145.8±4.6 Zhang et al., 2023b
    锡石(M) LA-ICP-MS U-Pb 147±3.5、147.7±1.9 Chen et al., 2023
    36 加不斯 锆石(C) LA-ICP-MS U-Pb 144 李志丹等, 2019
    锆石(C) LA-ICP-MS U-Pb 150±2、148±2、151±5、153±14、150±3、101±2 Zhang et al., 2022a
    锡石(M) LA-ICP-MS U-Pb 149±2、149±2、104±9 Zhang et al., 2022a
    独居石(C) LA-ICP-MS U-Pb 148±7、141±2、141±3、137±2、132±2、136±3 Zhang et al., 2023a
    锡石(M) LA-ICP-MS U-Pb 148±2、146±1 Zhang et al., 2023a
    37 东七一山 锆石(C) LA-ICP-MS U-Pb 220.4±1.3、220.6±1.6、220.0±1.1、219.9±1.9 张善明等, 2023
    辉钼矿(M) Re-Os 211±1 张善明等, 2023
    全岩(C) Rb-Sr 128.2±1.1 吕博等, 2011
    河北 38 麻地 独居石(C) LA-ICP-MS U-Pb 175.0±1.1 侯江龙, 2018
    锆石(C) LA-ICP-MS U-Pb 156±2、165±2 齐云飞等, 2021
    锆石(C) LA-ICP-MS U-Pb 160±2、175.5±1.4 苗群峰, 2018
    39 汉儿庄 锆石(C) U-Pb 205±2、183±2、196±2、167~151 孙金龙和赵迪, 2023
    甘肃 40 国宝山 锆石(C) LA-ICP-MS U-Pb 255.4±4、250.9±3.3、250±3.9 贺昕宇等, 2022
    锆石(C) LA-ICP-MS U-Pb 246.5±2、246.8±3 Chen et al., 2022
    独居石(C) LA-ICP-MS U-Pb 249±1.5、245±1.2、243.4±2、247.1±2.4 Chen et al., 2022
    锡石(M) LA-ICP-MS U-Pb 247.1±1.9、241.8±3.1、242.2±0.9 Chen et al., 2022
    铌铁矿(M) LA-ICP-MS U-Pb 239.8±5.5、243.5±2.3、243.6±1.9 Chen et al., 2022
    锆石(C) LA-ICP-MS U-Pb 247±3、202±3 贺昕宇, 2019
    锆石(C) LA-ICP-MS U-Pb 427±8、406±5 贾志磊, 2016
    注：矿物名称后标注(C)代表成岩年龄、(M)代表成矿年龄. 矿床编号同表 1，没有搜集到成岩成矿年龄数据的矿床，未在表 2列出；后表同理，编号同表 1，未搜集到相关数据的矿床未在表中列出
    ①江西省地质调查研究院. 2015. 江西省灵山地区矿产地质调查报告
    ②周亮, 苟月明, 王取义, 刘昌实, 贺伯初. 1989. 赣南石城及寻乌锡多金属隐伏矿预测研究. 赣州: 江西省地质矿产局赣南地质调查大队
    ③李启津. 1976. 江西赣县黄钇钽矿——天河石花岗岩矿床物质成分报告. 桂林: 桂林冶金地质所
    下载: 导出CSV

    表 3 

    中国花岗岩型锂矿床岩性和云母演化汇总表

    Table 3. 

    Summary of lithological and mica evolutionary from the granite-type lithium deposits in China

    省区 序号 矿床名称 成矿母岩/面积(km2) 岩性演化(岩体垂向方向由下至上排列) 云母演化(按岩浆从低到高分异排列) 参考文献
    江西 1 414 雅山岩体/9.5 中粗粒黑鳞云母-白云母花岗岩→细粒斑状白云母花岗岩→中粒白云母花岗岩→锂云母花岗岩→黄玉锂云母花岗岩 富铁黑云母→铁叶云母→黑鳞云母→锂云母；白云母→多硅白云母→富锂多硅白云母→锂云母 Yin et al., 1995; 黄小龙等, 2001
    2 白水洞 甘坊岩体/400 黑云母花岗岩→二云母花岗岩→锂(白)云母碱长花岗岩→黄玉锂云母碱长花岗岩 黑云母→白云母→铁锂云母→锂白云母→锂云母 王成辉等, 2018; 陈祥云等, 2023; 刘泽等, 2023
    3 黄沙坪 岩体 锂云母 孙艳等, 2019; 王核等, 2022
    4 松树岗 隐伏岩体 厚大钠长石化花岗岩→钾长石化(钠长石化)云英岩化花岗岩带→不连续钾长石化花岗岩带→不连续伟晶岩带 含锂白云母→铁锂云母 Zhu et al., 2015; 蔡报元等, 2017; 钟建昇和靳鑫, 2017; 诸泽颖, 2018
    5 黄山 隐伏岩体 中粒黑云母花岗岩→细粒钠长石化花岗岩→伟晶岩脉 黑云母→黑鳞云母→铁锂云母 诸泽颖, 2018; Zhu et al., 2019; 江小强, 2020; Wang et al., 2023
    6 姜坑里 岩株 二云母二长花岗岩带→铁锂云母碱长花岗岩带→富钠长石花岗岩带→云英岩带→似伟晶岩带 铁锂云母→锂云母 杨岳清等, 2021
    7 海罗岭 岩株/0.6 中细粒黑云母花岗岩→中细粒白岗岩→中粒铁锂云母化、钠长石化含钽花岗岩 铁锂云母→锂云母 梁景时等, 2014; 徐喆等, 2023
    8 牛岭坳 锂云母 江西省地质矿产勘查开发局赣南地质调查大队, 2010
    9 上坪 隐伏岩体 中粗粒黑云母花岗岩→中细粒弱钠长石化二云母花岗岩→细粒中等钠长石化白云母花岗岩 含锂云母 王颖辉等, 2019
    10 九曲 岩体/2.65 中细粒斑状二云母花岗岩→细(微)粒斑状白云母花岗岩 铁锂云母 江西省地质局第一地质大队, 2022
    11 留家山 细晶岩 细晶岩 锂云母 徐喆等, 2022
    12 浒坑 细晶岩 细晶岩 铁锂云母 徐喆等, 2022
    13 茅坪 隐伏岩体 中粒斑状黑云母花岗岩→细粒白云母花岗岩→云英岩化花岗岩→云英岩→含矿长石石英脉 黑鳞云母→富锂多硅白云母→铁锂云母 陈光弘, 2019
    14 旱叫山 岩株/0.466 细粒斑状碱长花岗岩 黑云母→黑鳞云母→铁锂云母 张何猛, 2011
    湖南 15 正冲 金鸡岭岩体/390 中细粒斑状黑云母花岗岩→中粗粒斑状黑云母花岗岩→花岗斑岩→云英斑岩(又称石英铁锂云母黄玉岩) 黑云母→铁锂云母 王京彬, 1990; 文春华等, 2016; Liu et al., 2022b
    16 辉山坪 大义山岩体/280 细中粒斑状角闪黑云二长花岗岩→中粗粒斑状黑云母二长花岗岩→中细粒斑状黑云母二长花岗岩→细粒少斑状黑云母二长花岗岩→细粒斑状(含电气石)二云母二(正)长花岗岩→细粒少斑状二云母正长花岗岩 铁叶云母→黑鳞云母; 白云母→多硅白云母→富锂多硅白云母 李剑锋等, 2023; 张遵遵等, 2023
    17 香花铺 尖峰岭岩体/4.4 碱长花岗岩带→钠长花岗岩带→云英岩带→伟晶岩带 黑云母→黑鳞云母→铁锂云母→铝质铁锂云母→锂白云母 邱瑞照等, 1998a; 覃莉茜等, 2021; 袁玲玲等, 2022
    18 香花岭 癞子岭岩体/2.2 黑鳞云母花岗岩带→浅色花岗岩(二云母花岗岩和锂白云母花岗岩)带→钠长石花岗岩带→云英岩带→块状石英和黄玉伟晶岩带 黑云母→黑鳞云母→铁锂云母 邱瑞照等, 1998a; 朱金初等, 2011
    19 金竹垄 隐伏岩体 黑云母花岗岩→二云母花岗岩→白云母花岗岩→钠长石花岗岩→云英岩→长石石英伟晶岩壳 白云母→铁锂云母→锂云母 孙颖超等, 2017; 毛禹杰等, 2021
    20 长城岭 花岗斑岩体 花岗斑岩 白云母→锂白云母→锂云母 张术根等, 2015; 朱恩异等, 2021, 2022; 蒋宗和, 2021
    21 上堡 岩体/2.1 中细粒斑状黑云母二(正)长花岗岩→细中粒斑状黑(二)云母二(正)长花岗岩→细粒二云母正长花岗岩 铁锂云母→锂云母 陈湘立等, 2003; 伍光英, 2005; 雷泽恒等, 2009; Zhao et al., 2021
    22 界牌岭 花岗斑岩株/0.12 巨晶花岗斑岩→中晶花岗斑岩→中细晶花岗斑岩 白云母→铁锂云母 卢友月等, 2013; Yuan et al., 2015
    23 小江 岩体/2 粗粒黑云母花岗岩→黑云母斑状花岗岩→细粒二云母花岗岩 白云母 李建康等, 2012
    广东 24 深坑 岩体 细粒片麻状黑云母花岗岩 锂云母 赵仕钦, 2006
    25 一六 宝山岩株/0.4 中细粒似斑状黑云母花岗岩→细粒白云母花岗岩 白云母→锂云母 裴太昌, 1990; 和秋姣等, 2017, 2018
    26 良源 隐伏岩体 似斑状黑云母花岗岩带→中细粒二云母花岗岩带→细粒锂白云母含钠长石花岗岩带→细粒锂云母钠长石花岗岩带→云英岩→富云母云英岩→似伟晶岩带 铁锂云母→锂云母 肖惠良等, 2023
    27 中坝 岩株/0.071 中粗粒黑云母花岗岩→中粒斑状黑云母花岗岩→中细粒黑云母花岗岩→细粒钠长石花岗岩 铁锂云母→锂云母 张国庆, 2016
    广西 28 栗木 泡水岭岩株/0.1，香坛岭和牛栏岭岩株/1.2，老虎头岩株/0.2，金竹源、大岐岭、水溪庙、狮子岭均为隐伏岩体 (泡水岭、香坛岭、牛栏岭、老虎头、水溪庙)白云母花岗岩→铁锂云母花岗岩 多硅白云母→含锂多硅白云母；黑鳞云母→铁锂云母 史明魁和孙恭安, 1981
    (水溪庙)不含矿花岗岩→钨锡花岗岩→锡铌钽花岗岩 多硅白云母→含锂多硅白云母；黑磷云母→铁锂云母 曹瑞欣, 2009
    (老虎头)黑鳞云母花岗岩→铁锂云母花岗岩 黑鳞云母→铁锂云母→锂云母 马万伟, 2019
    马万伟等, 2020
    二云母花岗岩(Ⅳ带)→层状细晶岩群+斑状含锂白云母花岗岩(Ⅲ带)→中细粒白云母花岗岩(又名钠长钾长花岗岩)(Ⅱ带)→非对称伟晶-细晶花岗岩+云英岩化、钠长石化花岗岩(Ⅰ带)→伟晶岩-细晶岩脉带(+萤石石英脉)→钨锡长石石英脉带(+萤石石英脉) 白云母大多数由黑云母转变而来，有轻微绢云母化(Ⅳ带)→白云母(Ⅱ带、Ⅲ带)→含锂白云母和绢云母(Ⅰ带) 董业才等, 2021; 梁磊等, 2017, 2021; 梁磊和张玲, 2019
    19 巴马 花岗斑岩脉 边缘相微晶花岗结构花岗斑岩→中心相变余微晶花岗结构和斑状结构花岗斑岩 白云母 姚明等, 2016
    浙江 30 河桥 河桥岩体/59.13 边缘相细中粒二长花岗岩→过渡相中细粒二长花岗岩→中心相中粗粒二长花岗岩; 岩体内部有细粒斑状钠长石花岗岩脉侵入 铁黑云母→黑鳞云母→铁锂云母 武彬等, 2015; 周静, 2016; 王吴梦雨, 2019
    江苏 31 善安浜 隐伏岩体 含角闪石黑云母花岗岩→中粗粒似斑状黑云母花岗岩→细粒黑云母花岗岩→富钠长石花岗岩→黄玉花岗岩→伟晶岩壳 锂白云母→铁锂云母→锂云母; 黑鳞云母→铁锂云母 袁晓军等, 2004; 何坚平, 2006; 司晓博, 2021
    云南 32 新歧 岩体/40 似斑状二长花岗岩→钾长石化花岗岩→钠化花岗岩→云英岩异离体→天河石花岗岩脉、花岗伟晶岩脉 黑云母→白云母→铁锂云母 白嘉芬, 1987; 李良等, 2009; 丛冲和罗士俊, 2012
    福建 33 大坪 花岗斑岩株 黑鳞云母碱长花岗斑岩 黑鳞云母→铁锂云母; 锂多硅白云母→铁锂云母 胡永斌等, 2017; 刘永超等, 2017; 江善元, 2019
    内蒙古 34 赵井沟 隐伏岩体 碱长花岗岩→钠长石花岗岩→云英岩化钠长花岗岩→云英岩→似伟晶岩壳→伟晶岩脉、细晶岩脉 含锂铷白云母→铁锂云母→锂云母 聂凤军等, 2013; 柴华和武景龙, 2013; 吴欢欢, 2020; Zhang and Jiang, 2021
    35 石灰窑 地表出露多个小岩株 似斑状碱长花岗岩→钠长石花岗岩→云英岩化钠长石花岗岩→云英岩化花岗岩→云英岩→天河石花岗伟晶岩 锂多硅白云母→铁锂云母 朱京占等, 2013; 鄂阿强, 2018; Duan et al., 2021; Zhou et al., 2022
    36 加不斯 隐伏岩体 黑云母花岗岩→二云母花岗岩→锂云母钠长石花岗岩→云英岩化黄玉锂云母花岗岩→似伟晶岩壳 铁锂云母→锂云母 张荣臻等, 2023; Zhang et al., 2022a, 2023a
    37 东七一山 岩株/1.3 碱长花岗斑岩→似斑状钾长花岗岩 铁锂云母→锂云母 吕博等, 2011
    河北 38 麻地 岩体/5.7 肉红色碱长花岗岩→灰白色碱长花岗岩→白色含天河石碱长花岗岩 锂铁云母(锂白云母)→铁锂云母→锂云母 苗群峰, 2018
    39 汉儿庄 岩株/0.81 肉红色碱长花岗岩→灰白色碱长花岗岩 锂云母 龚传伟等, 2021
    甘肃 40 国宝山 岩体/13 似斑状中粗粒花岗闪长岩→黑云母中细粒二长花岗岩→含天河石花岗岩→含天河石花岗伟晶岩 黑云母→铁锂云母 张岱, 2015
    下载: 导出CSV

    表 4 

    中国花岗岩型锂矿床三类伟晶岩主要特征汇总表

    Table 4. 

    Summary of three types of pegmatite from the granite-type lithium deposits in China

    省区 序号 矿床名称 赋存部位 形态和厚度 矿物组成 参考文献
    江西 1 414 黄玉锂云母花岗岩之上，变质沉积岩围岩之下 长度小于400m，厚约几厘米至几米不等；石英和长石形成UST结构 以钾长石与石英为主，且含锂云母、锂长石、锂电气石、氟磷锰铁矿、铌钽锰铁矿、锆石、黄玉、磷钇矿、细晶石、黄铜矿、闪锌矿 Lin et al., 1995; 黄小娥和徐志华, 2005; 李胜虎, 2015; 徐喆等, 2018; 吴鸣谦, 2017; Pollard, 2021; 万泰安, 2022
    2 白水洞 夹在黑鳞云母-白云母花岗岩与含锂云母碱长花岗之间 脉状 石英、钾长石、钠长石、铁锂云母、锂白云母、锂云母 李仁泽等, 2020
    4 松树岗 岩体顶部 壳状，厚度变化较大(0~18m) 70%~80%微斜长石，10%~15%石英，5%~8%铁锂云母，少量钠长石 周旻等, 2006; 钟建昇和靳鑫, 2017; Zhu et al., 2015
    5 黄山 岩体顶部，成组围绕岩体平行接触带产出 规模差异大：小者长几米，宽0.1m；大者长500~600m，宽几十米.受张性裂隙控制，形态上呈分枝复合、膨胀收缩、尖灭再现等特征 主要由钠长石、微斜长石、云母、石英组成，含有铌铁矿、钍石、钛铁金红石；云母Li2O含量2.6%~3.0%；根据铌钽元素含量可分为富铌伟晶岩和富钽伟晶岩 刘友华等, 2011; Zhu et al., 2019; 江小强, 2020; 孙建东等, 2023; Wang et al., 2023
    6 姜坑里 夹在震旦系浅变质岩与云英岩带之间 杨岳清等, 2021
    7 海罗岭 岩体上部和顶部 呈脉状或透镜状，由内而外具有分带特征：从碱性长石伟晶岩→云母锂辉石伟晶岩→云母石英伟晶岩 云母锂辉石伟晶岩：锂辉石61%，云母25%，石英8%，长石5%，褐帘石1%；Nb2O5含量为0.0439%，Ta2O5含量为0.0161%，Li2O含量为0.72%，Rb2O含量为0.38% 胡论元等, 2015; 徐喆等, 2023
    9 上坪 脉状(似伟晶岩脉) 王颖辉等, 2019
    12 浒坑 与含黑钨矿石英脉在空间上共生 脉状(伟晶岩脉或细晶岩脉) 章伟, 2009
    13 茅坪 岩体顶部 壳状 陈光弘, 2019
    湖南 16 辉山坪 岩体顶部，细粒二云母二长花岗岩与黑云母二长花岗岩接触面 壳状，厚0.05~5.4m 钾长石、云母、石英、绿柱石、电气石；全岩Li2O含量为0.16%~0.47%，云母Li2O含量为0.17%~1.8% 周厚祥等, 2005; 张遵遵等, 2023
    17 香花铺 岩体顶部 层状，厚度10~20m 主要由钾长石、石英和少量钠长石组成，含铁锂云母和黄玉 常海亮和黄惠兰, 1998; 朱金初等, 2011; 文春华等, 2017; 覃莉茜等, 2021; 袁玲玲等, 2022
    18 香花岭 岩体顶部，局部可见伟晶岩脉侵入到云英岩和钠长花岗岩中 伟晶岩带厚5~15m，铁锂云母水平展布成为平行韵律层，黄玉垂直云母层呈现UST结构 钾长石、石英、铁锂云母和黄玉；云母Li2O含量>2.5% 朱金初等, 2011; 覃莉茜等, 2021; 袁玲玲等, 2022
    19 金竹垄 岩体顶部 壳状 长石、石英 孙颖超等, 2017; 毛禹杰等, 2021
    23 小江 细粒花岗岩裂隙中 脉状 主要由长石、石英、白云母组成，含绿柱石、锡石等 李建康等, 2012
    广东 24 深坑 岩体上部和顶部 绝大多数伟晶岩脉NNE走向，少数SN、EW走向 主要由钠长石、石英、白云母组成，铌钽矿物主要为铌钽铁矿-钽铌铁矿，其次为铌钇矿、钽锰矿、细晶石、铌铁金红石，铍矿物主要为绿柱石，含少量硅铍石 赵仕钦, 2006; 冯进喜, 2018
    25 一六 白云母花岗岩内部和顶部裂隙中 脉状，宽度1~3cm，走向延伸可达10m 主要矿物为石英、绿柱石、微斜长石，次要矿物为白云母，副矿物包括铌钽铁矿、金红石、锆石、磷灰石、白钨矿等；云母Li2O含量0.23% 秦锦华等, 2022
    26 良源 隐伏岩体顶部 沿花岗岩或花岗细晶岩脉两侧产出，厚度小于4m 肉眼可见辉钼矿、黄铁矿 肖惠良等, 2012, 2023
    27 中坝 ①团块状；②脉状 ①粗晶钾长石、石英、云母 张国庆, 2016
    广西 28 栗木 老虎头矿体顶部、水溪庙矿体顶部及边缘 团块状、似层状 主要由钾长石、石英、钠长石、白云母组成，还发育较多黄玉、萤石、黑鳞云母等 尹国栋, 1987; 黄雅乔, 1980; 林德松, 1993; 曹瑞欣, 2009; 梁玲慧, 2013; 梁磊等, 2017, 2021; 张玲和梁磊. 2018
    水溪庙岩体顶部 壳状，厚度不大，形态受花岗岩体边界控制 主要由石英、钾长石、钠长石、云母组成，出现大量细晶石 林德松, 1993; 曹瑞欣, 2009; 梁玲慧, 2013
    沟挂垒隐伏花岗岩体顶部 层状，与下部细粒花岗岩之间有约20cm的过渡带 肉红色钾长石，粒径达3.5cm×8cm 梁磊, 2014
    水溪庙隐伏岩体脊部两侧，其根部与岩体相连，支脉穿切入围岩 脉状，沿两组共轭断裂填充，相向倾斜，随岩脊轴向变化而变化，剖面上小下大，呈向上的楔形 主要由微斜长石和石英巨晶组成，长石直径约1~3cm，大者可达5cm；其次有云母、方解石、黄玉、萤石，脉壁有铁锂云母镶边 甘晓春等, 1992; 覃宗光和姚锦其, 2008; 姚锦其和李惠, 2008; 曹瑞欣, 2009; 覃宗光等, 2011; 梁玲慧, 2013
    水溪庙细粒黄玉-钠长石花岗岩顶部 层状，延长>200m，延伸>100m，最厚可达15~20m，往南北两端逐渐变薄和尖灭 主要由石英、钾长石和钠长石组成，其次为黄玉和白云母，含有锡石、锰铌钽铁矿、细晶石、钽铁金红石、黑钨矿等 朱金初等, 1996
    沟挂垒岩体顶部 脉状，产状较陡 中心的粗粒矿物为石英和肉红色钾长石，侧部的细晶成分主要为钠长石、石英、白云母 梁磊, 2014
    浙江 30 河桥 以脉状或枝状侵入围岩中，NE或近NS走向 岩脉长约2~10m(最宽可达1m以上)，细者仅1~2cm，倾角20°~50° 主要由石英、长石、云母组成，少量萤石、黄玉等；云母Li2O含量0.14%~0.16%；含有铌钽矿物(铌铁矿、铌锰矿、重钽铁矿、细晶石等)、钇矿物(褐钇铌矿、黑稀金矿)、钨矿物(黑钨矿、白钨矿、铌钨矿物)、铈矿物(独居石、氟铈矿、氟碳铈矿)、钍矿物等 王吴梦雨等, 2019
    江苏 31 善安浜 ①壳的形式产在岩体顶部；②脉的形式穿插钠长石花岗岩中 ①壳厚0.81~5.01m；②脉宽0.1~1.66m ①石英、长石、云母等；②的主要矿物组成为石英、长石、云母及微量萤石、铌铁矿、钽铁矿、锆石等 袁晓军等, 2004
    云南 32 新歧 岩体上部，花岗伟晶岩脉 脉状 含Sn、W及稀有金属 李良等, 2009
    内蒙古 34 赵井沟 ①岩体顶部；②侵入岩体及围岩 ①壳状、厚度从1~10m，由细粒钠长花岗岩与锯齿状石英韵律层交替出现，石英形成UST结构；②脉状、透镜状 ①主要由钠长石、微斜长石、石英、黑云母组成，含有萤石、托帕石、电气石等；②主要矿物为石英、天河石、钠长石、(铁)锂云母，副矿物有萤石、黑云母、托帕石、硬玉、独居石、铌铁矿、电气石等；云母Li2O含量0.46%~2.87% Wei et al., 2020; 吴欢欢, 2020; Li et al., 2023; 聂凤军等, 2013
    35 石灰窑 ①岩体顶部；②侵入岩体及围岩 ①壳状，由石英和正长石组成UST结构；②脉状，长20~30m，宽1~20m，最长的岩脉延伸超过500m ①石英、碱性长石；②钠长石、天河石、石英、铁锂云母，副矿物为黄玉、萤石、电气石、锆石、独居石、铌钽氧化物等；铁锂云母Li2O含量3.8%~4.4% 孙艳, 2013
    Zhou et al., 2022; Zhang et al., 2023b
    36 加不斯 夹在锂云母钠长石花岗岩与黑云母花岗岩之间 ①天河石-锂云母伟晶岩，厚度4~50cm，天河石形成UST结构；②钾长石-黑云母伟晶岩，几厘米至几米 ①主要由石英、天河石、锂云母、钠长石组成；②主要由石英、钾长石和黑云母组成 Zhang et al., 2022a, 2023a
    河北 38 麻地 岩体靠近围岩接触带部位 团块状、细脉状，大小从几厘米至几十厘米 钾长石、石英和铁锂云母 苗群峰和齐云飞, 2020
    39 汉儿庄 灰白色碱长花岗岩与围岩接触带附近 不连续的似伟晶岩带，宽数米，长十几米至几十米 钾长石、石英 郭志伟, 2019; 龚传伟等, 2021
    甘肃 40 国宝山 侵入于含天河石二长花岗岩中 脉状，长约5m，宽10~30cm 石英30%~35%、天河石40%~45%、钠长石5%~10%、白云母10%~15%，副矿物有石榴子石、萤石、独居石、铌铁矿等 贾志磊, 2016; 贺昕宇, 2019; Chen et al., 2022
    下载: 导出CSV

    表 5 

    中国花岗岩型锂矿床云英岩主要特征汇总表

    Table 5. 

    Summary of greisen from the granite-type lithium deposits in China

    省区 序号 矿床名称 赋存部位 形态和厚度 矿物组成 参考文献
    江西 1 414 在伟晶岩带与锂云母钠长石花岗岩带之间 一层不连续分布的云英岩带，厚度10~20cm 主要有石英、锂云母、微斜长石、钠长石、黄玉，副矿物有铌钽锰矿、细晶石、磷灰石、锆石、辉钼矿、黄铜矿、闪锌矿 徐喆等, 2018; 李胜虎, 2015; 朱金初等, 2002
    2 白水洞 岩体内某些部位 石英和云母相对占优势而构成似云英岩结构 王成辉等，2019
    4 松树岗 连续性差的伟晶岩和钾长石化花岗型矿石下部，厚大钠长石化花岗岩型矿石上部 似鞍状 云英岩中钽、铌等金属元素品位高 蔡报元等, 2017; 钟建昇和靳鑫, 2017; 兰正卿, 2019
    6 姜坑里 夹在似伟晶岩带与富钠长石花岗岩带之间 所含稀有金属为铌钽铁矿 杨岳清等, 2021
    7 海罗岭 岩体顶部 厚度500m 胡论元等, 2015
    13 茅坪 岩体顶部 似层状、扁豆状、透镜状、不规则状，厚度几米至几十米 石英、铁锂云母、富锂多硅白云母、黑钨矿、锡石、辉钼矿等 陈莉莉等, 2018; 陈光弘, 2019
    湖南 15 正冲 岩体顶部(云英斑岩) 似层状、扁豆状，长300m、宽20~40m，延深600m 斑晶为石英(~60%)和铁锂云母(~26%)，基质为长石(~4%)、黄玉和白云母(~3%)、锡石和黑钨矿(~1%)等，云母Li2O含量0.35%~1.01% 王京彬, 1990; 文春华等, 2016; 舒良树等, 2021
    16 辉山坪 岩体顶部 脉状、厚板状，长0.3~1km，宽1~2km 石英、云母、电气石、毒砂、锡石、黄铜矿、黑钨矿、黄玉、方铅矿和闪锌矿等；全岩Li2O含量0.04%~0.54%，云母Li2O含量0.7%~2.53% 曾志方, 2013; 张遵遵等, 2023
    17 香花铺 伟晶岩与钠长石花岗岩之间 呈条带状或块状构造，厚30~70m 石英(30%~65%)、铁锂云母(15%~35%)和黄玉(15%~30%) 文春华等, 2017; 覃莉茜等, 2021; 袁玲玲等, 2022
    18 香花岭 伟晶岩与钠长石花岗岩之间 层状或块状，厚度20~40m 石英~55%、铁锂云母~30%、黄玉~12%，含有锆石、铌铁氧化物、锡石、黑钨矿等；全岩Li2O含量1.03%，云母Li2O含量3.4% 朱金初等, 2011; 王正军等, 2018; 覃莉茜等, 2021
    19 金竹垄 细粒钠长石花岗岩与似伟晶岩盖之间 由白云母条带与石英条带相间分布，各条带宽度为2.5~5cm 主要由石英和各种浅色云母(如白云母、绢云母、铁锂云母和锂云母)组成 孙颖超等, 2017; 毛禹杰等, 2021
    22 界牌岭 海拔标高-480m以下 层状，厚约80m 石英、黄玉、白云母、铁锂云母 田野等, 2017; Xie et al., 2016
    广东 25 一六 伟晶岩脉与白云母花岗岩接触部位 脉状 石英、白云母、绿柱石、白钨矿、黄铁矿、毒砂、黄铜矿、闪锌矿、辉钼矿；全岩Li2O含量0.23% 余伟, 2020; 秦锦华等, 2022
    26 良源 似伟晶岩带与细粒锂云母钠长石花岗岩带之间 脉状、层状、透镜状、囊包状 石英、锂云母、微斜长石、钠长石、黄玉、铌钽矿物、细晶石、锆石、磷灰石、黑钨矿、白钨矿、硫化物 肖惠良等, 2012; 陈乐柱等, 2015; 范飞鹏等, 2022
    27 中坝 ①交代成因云英岩；②沿裂隙填充而成云英岩 ①石英次生加大、长石绢(白)云母化、锂云母化 张国庆, 2016
    广西 28 栗木 三个黄牛、老虎头、水溪庙、金竹源岩体 脉状 细粒石英和含锂云母(包括部分绢云母)、晚期黄玉、萤石及氟磷铁锰矿等矿物交代早期微斜长石、钠长石和云母 林德松和王开选, 1987; 杨锋等, 2009; 梁玲慧, 2013
    沟挂垒岩体中上部无斑或少斑白云母花岗岩中 厚度0.5~2m 表现为白云母、石英交代斜长石、钾长石 梁磊等, 2013
    鱼菜岩体上部、三个黄牛和水溪庙似伟晶岩壳下部岩体中 层状，厚度数米 晚期细粒石英、绢白云母、黄玉、氟磷铁锰矿等矿物交代早期钾长石等造岩矿物 覃宗光等, 2011; 董业才, 2014
    水溪庙岩体中钠长石化花岗石上部 呈团块状、网脉状面型分布，厚10~150m 晚期细粒石英、含锂云母和绢云母、黄玉、萤石交代早期微斜长石、钠长石和云母 曹瑞欣, 2009
    岩体顶部 云英岩化花岗岩细脉带，厚度最大可达20m 主要由细粒石英、含锂白云母、绢云母、黄玉、萤石、氟磷锰矿等组成 梁磊等, 2017; 梁磊和张玲, 2019; 钟玉龙, 2021
    鱼菜岩体顶部 钠长石化-云英岩化花岗岩细脉带，单脉规模一般较小，其厚度为十几厘米至几十厘米，最厚处可达2m 主要由钠长石、石英、钾长石以及绢云母组成，含少量萤石、碳酸盐和黄铁矿等 覃宗光等, 2011
    内蒙古 34 赵井沟 ①碱长花岗岩和花岗伟晶岩中 ①条带状、团块状、扁豆体 ①石英(>50%)、云母(＜40%)以及黄玉、天河石、萤石、铌钽铁矿、锆石，其中云母Li2O含量0.59%~0.84% 聂凤军等, 2013; Wei et al., 2020; Zhang and Jiang, 2021
    35 石灰窑 ①云英岩；②云英岩化钠长石花岗岩；③钠长石花岗岩中的云英岩 ①团块状；②条带状；③圆形结核或口袋状 ①由锂云母、萤石和石英组成；②由石英，钠长石，钾长石，多硅白云母和少量黄玉与萤石构成；③由白云母、石英、萤石和少量钠长石构成 Duan et al., 2022; Zhou et al., 2022; Zhang et al., 2023b
    36 加不斯 钠长花岗岩体与似伟晶岩壳之间 集中在黄玉锂云母钠长花岗岩顶部，向下蚀变强度逐渐减弱 蚀变矿物为含铌钽(细晶石、铌锰矿等)和含氟矿物(萤石、黄玉等)，是Nb、Ta、Li的主要矿体 张荣臻等, 2023; Zhang et al., 2022a, 2023a
    37 东七一山 岩体中部含钨石英大脉两侧及岩体的西南边缘 云英岩化蚀变带长30~200m，宽3~20m 鳞片状绢云母和大小不等的粒状石英交代钾长石和斜长石 康建飞, 2019
    河北 38 麻地 云英岩化 苗群峰, 2018
    下载: 导出CSV

    表 6 

    中国花岗岩型锂矿床除伟晶岩脉之外的各类岩脉主要特征汇总表

    Table 6. 

    Summary of various dykes except pegmatite dykes from the granite-type lithium deposits in China

    省区 序号 矿床名称 岩性 产状 矿物组成和全岩Li2O含量(%) 与花岗岩体关系 参考文献
    江西 1 414 含矿细晶岩脉 岩体周边或者穿切黑云母花岗岩和二云母花岗岩 喻良桂, 2007; 吴鸣谦, 2017; 徐喆等, 2018
    2 白水洞 细晶岩脉、白岗岩脉、霏细岩脉 同安：NE-SW走向，长度150m~2km，宽约20m，深约300m 钠长石、石英、锂云母、黄玉、磷锂铝石、铌钽氧化物、细晶石、锡石；Li2O含量1.2%~2.3% 岩体南侧 罗微, 2012; 吴学敏等, 2016; 王成辉等, 2019; 刘莹, 2019; 陈祺等, 2022
    东溪：霏细岩脉呈透镜状、长100~300m，宽20~60m 锰钽铌铁矿、锰铌铁矿、重钽铁矿、含钽锡石、细晶石、锂云母、鳞钽云母、绿柱石；Li2O含量1.67% 岩体北东侧 周建廷等, 2011; 张福神等, 2018; 刘爽等, 2019; 姜宝亮等, 2022; 陈祺等, 2022
    4 松树岗 花岗斑岩、石英斑岩、云斜煌斑岩、闪长岩脉 云斜煌斑岩、闪长岩脉隐伏于地下 蔡报元等, 2017; 朱志成等, 2018
    5 黄山 花岗斑岩脉、基性岩脉、闪长岩岩脉、萤石石英脉、细晶岩脉 花岗斑岩脉的斑晶以石英和轻微蚀变长石为主，基质主要由细粒钾长石、斜长石、石英、黑云母组成 岩体周边，或穿切灵山岩体 刘友华等, 2011; 曹振辉等, 2019; Zhu et al., 2019; Liu et al., 2022c
    7 海罗岭 花岗斑岩脉、石英闪长岩脉、角闪煌斑岩脉、石英脉 徐喆等, 2023
    9 上坪 含矿花岗斑岩脉 岩墙状，NE、NW走向，长400~1800m，宽3~30m 石英、云母、长石、角闪石、锆石、磁铁矿；Li2O含量0.005%~0.018% 王颖辉等, 2019; 邱文江等, 2018
    10 九曲 ①花岗斑岩脉；②煌斑岩脉 ①花岗斑岩脉主要含石英、斜长石、钾长石、黑云母、磁铁矿、褐铁矿等；②煌斑岩脉主要有黑云母、斜长石、磁铁矿、方解石等 侵入九曲花岗岩株和变质围岩中 江西省地质局第一地质大队, 2022
    11 留家山 花岗细晶岩脉 长约10km，宽约5.2~7.7m Li2O含量0.65% 侵入片麻状中细粒斑状黑云母二长花岗岩 徐喆等, 2022
    12 浒坑 细晶岩脉 NEE走向，长约200m，宽约5m 石英32%、斜长石33%、钾长石30%、云母5%；Li2O含量0.5% 侵入中细粒白云母花岗岩和变质围岩中 徐喆等, 2022
    13 茅坪 闪长斑岩脉、辉绿(长)闪长岩脉、煌斑岩脉、细晶岩脉 充填NW、EW、NS向断裂中，规模较小 有的被含矿石英脉穿切 陈光弘, 2019
    14 旱叫山 霏细斑岩脉、细晶岩脉 脉状 张何猛, 2011
    湖南 17 香花铺 石英斑岩脉、伟晶岩脉、细晶岩脉、伊利石化花岗岩脉、花岗斑岩脉 两组走向，分别为NE-NEE向和NNW向，倾向不一，倾角较陡，60°~88° 穿切岩体 朱真真等, 2019
    18 香花岭 ①东北侧黄玉铁锂云母霏细岩脉(431岩脉)；②西侧花岗斑岩脉；③西南侧花岗斑岩脉；④东南侧石英斑岩脉 ①黄玉铁锂云母霏细岩脉长1770m，宽1.8~18.4m，倾角42°~78°；②西侧花岗斑岩脉长约800m，宽10~18m；③西南侧花岗斑岩脉长约1000m，宽10~20m；④东南侧石英斑岩脉长4600m，宽10~30m，倾角60°~80° ①黄玉铁锂云母霏细岩脉主要由黄玉、钾长石、钠长石、石英和铁锂云母组成，含富锆铪石、锡石、白钨矿、钨锰矿、钇榍石、萤石、磁铁矿、钛铁矿、毒砂、黄铁矿、黄铜矿、钙铬榴石、普通辉石、透辉石、电气石、硅铍石、蓝柱石等；②、③、④岩脉未发现重要矿化 ①东北侧黄玉铁锂云母霏细岩脉西端侵入于癞子岭岩体中，大部分侵入于泥盆纪地层；②西侧花岗斑岩脉东端侵入于癞子岭岩体，大部侵入于泥盆纪地层；③、④侵入于泥盆纪地层 周涛, 2009; 朱金初等, 2011; Huang et al., 2015a
    19 金竹垄 ①煌斑岩脉；②细晶岩脉 ①煌斑岩脉长200~2600m、宽0.3~6m；②细晶岩脉宽3~8cm ①煌斑岩脉主要由单斜辉石、黑云母、斜长石和角闪石组成；②细晶岩脉主要由钾长石、斜长石、石英和白云母组成 ①煌斑岩侵入邓阜仙花岗岩体；②细晶岩切穿邓阜仙花岗岩体和煌斑岩脉 Liu et al., 2020
    20 长城岭 ①玄武岩脉；②辉长岩脉；③辉绿玢岩脉；④花岗斑岩脉 岩脉状、岩墙状、小岩株状 ①玄武岩斑晶为斜长石、辉石，偶见橄榄石；②辉长岩斑晶为斜长石、辉石，偶见角闪石、橄榄石；③辉绿玢岩斑晶为斜长石、钾长石，少量辉石和角闪石；④花岗斑岩脉斑晶为石英、长石和白云母，其中Li2O含量0.07%~0.78% ①玄武岩脉仅出露于矿区北段；②辉长岩脉见于矿山坑道和采场；③辉绿玢岩脉主要出露于中段和南段；④花岗斑岩脉随处可见，富铷锂等稀有元素 蒋宗和, 2021; 朱恩异等, 2022; 戴宝章等, 2007; Jiang et al., 2009; 刘勇等, 2012; 张术根等, 2015; 杨帆等, 2018
    21 上堡 辉绿岩脉 岩墙、岩豆、岩脉状产出，长几十米至3000m，宽度一般20~30m 侵入岩体内部 陈湘立等, 2003; 伍光英, 2005; 雷泽恒等, 2009; Zhao et al., 2021
    22 界牌岭 含黑钨矿石英脉 穿切围岩 Xie et al., 2016
    广东 26 良源 ①花岗细晶岩脉；②石英闪长斑岩脉；③云斜煌斑岩脉 ①花岗细晶岩脉呈SN向脉状产出，厚1m以下，长十几米；②石英闪长斑岩呈脉状，厚10cm至数米，长十几米至百米 肖惠良等, 2012
    27 中坝 基性岩脉、酸性岩脉 广东省地质矿产局, 1988
    广西 28 栗木 含钨锡长石石英脉带 矿体厚度较小，NS向和近EW向两组，脉幅0.2~1m，长度30~100m，深度60~80m 主要由微斜长石和石英组成，含有锡石、黑钨矿、白钨矿、黝锡矿等，脉壁有铁锂云母镶边，矿脉Li2O含量0.064% 位于隐伏锡钽铌花岗岩体上部的围岩中 陈儒庆和袁奎荣, 1988; 甘晓春等, 1992; 姚锦其和李惠, 2008; 曹瑞欣, 2009; 梁玲慧, 2013; 张怀峰等, 2014
    (水溪庙)萤石铁锂云母细脉带 多分布于地表附近，并有少数向下延伸，脉幅0.1~3.0cm，单脉长度1~20m 以锂云母、萤石为主，次有钾长石、方解石、硬水铝石、电气石、绿泥石、黄铁矿、毒砂、黝锡矿、锡石，极少量的黄玉、磷灰石、绿柱石、白钨矿、黑钨矿、闪锌矿、方铅矿 是隐伏锡钽铌花岗岩岩体的最外带，矿脉Li2O含量0.06%~3.05% 甘晓春等, 1992; 林德松和王开选, 1986; 姚锦其和李惠, 2008; 曹瑞欣, 2009
    (大岐岭)萤石铁锂云母细脉带 走向NS，脉幅0.1~2cm 主要矿物为含锂白云母、萤石；次要矿物方解石、硬水铝石、白云石、电气石；稀少矿物黄铁矿、方铅矿、锡石、绿柱石 隐伏花岗岩顶部，矿脉Li2O含量0.35% 林德松和王开选, 1986
    (金竹源)萤石铁锂云母细脉带 走向NW、NS-NNE，脉幅0.1~1cm 主要矿物为含锂白云母、萤石；次要矿物绿泥石、硬水铝石、方解石、电气石、黄铁矿、毒砂、黝锡矿；稀少矿物黑钨矿、锡石、白钨矿、褐铁矿、绿柱石 隐伏花岗岩顶部，矿脉Li2O含量0.097% 林德松和王开选, 1986
    (狮子岭)萤石铁锂云母细脉带 走向近，NS、NE脉幅0.1~1cm 主要矿物为含锂白云母、萤石；次要矿物硬水铝石、方解石、电气石；稀少矿物绿泥石、黄铁矿、绿柱石 隐伏花岗岩顶部，矿脉Li2O含量0.47% 林德松和王开选, 1986
    铌钽矿化花岗细晶岩脉 细晶岩脉形态变化较大，常见膨缩和分支现象，地表出露脉长2550m，厚40~50m 主要有石英、绢云母(水白云母)、长石；次要矿物高岭石；副矿物锡石、白钨矿、黑钨矿、白钨矿 刘南利和潘彤, 1994
    29 巴马 ①花岗斑岩脉；②辉绿岩脉、辉长辉绿岩脉 ①沿断裂充填呈岩脉产出；②早期形成似层状，晚期沿断裂侵入形成岩脉 ①斑晶由钠长石、石英、白云母组成，偶见钾长石、磷灰石，磷灰石越多铍锂含量越高，其中Be、Li、Ta、Cs含量高；②主要矿物为拉长石、普通辉石 有少数花岗斑岩脉侵入到辉绿(辉长)岩中 姚明等, 2016
    浙江 30 河桥 辉绿岩脉、流纹岩脉、石英脉、细粒钠长石花岗岩脉 穿插花岗岩体 周静, 2016
    江苏 31 善安浜 闪长玢岩脉、辉绿岩脉 穿插花岗岩体 袁晓军等, 2004; 何坚平, 2006
    福建 33 大坪 ①辉长岩脉；②闪长玢岩脉 ①辉长岩脉主要由斜长石、辉石和不透明矿物组成 穿插花岗岩体 江善元, 2019; 王锦荣等, 2020a; 王锦荣等, 2021
    内蒙古 34 赵井沟 细晶岩脉(细晶质钠长岩、钠长细晶岩、细晶岩) 脉状 主要矿物有石英、天河石、钠长石以及白云母、锂云母、铁锂云母，副矿物包含萤石、白云母、托帕石、锆石、独居石、锰铌铁矿、电气石等；全岩Li2O含量0.01%~0.06% 侵入到花岗岩株和围岩中 聂凤军等, 2013; 高允等, 2017; 吴欢欢, 2020
    35 石灰窑 石英脉、辉绿岩脉、正长斑岩脉、花岗细晶岩脉、霏细岩脉、闪长岩脉等 沿裂隙贯入，走向NE、NNE、NW向，个别呈EW向；规模一般长10~500m、宽1~20m 段先哲等, 2016; Zhang et al., 2023b
    37 东七一山 花岗斑岩脉 脉状 钾长石、斜长石、石英、黑云母 侵入黑云母花岗岩 康建飞, 2019
    河北 38 麻地 ①煌斑岩脉；②细粒花岗岩脉；③石英脉 ①脉状；②岩枝，宽约1m；③脉状，宽约2~30m ①角闪石、斜长石；②石英、钾长石和钠长石；③石英、褐铁矿和黄铁矿 ①充填于岩体内部NW向裂隙中；②穿插片麻岩；③充填于岩体张节理内，和分布于片麻岩中 苗群峰, 2018
    39 汉儿庄 花岗斑岩脉、石英脉 郭志伟, 2019; 龚传伟等, 2021
    甘肃 40 国宝山 基性岩脉 脉状 切穿岩体与围岩 Chen et al., 2022
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收稿日期:  2023-10-11
修回日期:  2023-12-22
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