Search Results (38)

This study comprehensively investigates the stress distribution and aging effects in Ethylene Propylene Diene Monomer (EPDM) and Liquid Silicone Rubber (LSR) gasket materials through a novel integration of hyperelastic modeling and advanced machine learning techniques. By employing the Mooney–Rivlin, Ogden, and Yeoh hyperelastic models, we evaluated the mechanical behavior of EPDM and LSR under conditions of no aging, heat aging, and combined heat- and sulfuric-acid exposure. Each model revealed distinct sensitivities to stress distribution and material deformation, with peak von Mises stress values indicating that LSR experiences higher internal stress than EPDM across all conditions. For instance, without aging, LSR shows a von Mises stress of 24.17 MPa compared to 14.96 MPa for EPDM, while under heat and sulfuric acid exposure, LSR still exhibits higher stress values, showcasing its resilience under extreme conditions. Additionally, the ensemble learning approach achieved a classification accuracy of 98% for LSR and 84% for EPDM in predicting aging effects, underscoring the robustness of our predictive framework. These findings offer practical implications for selecting suitable gasket materials and developing predictive maintenance strategies in industrial applications, such as fuel cells, where material integrity under stress and aging is paramount. Full article

This work investigated material extrusion additive manufacturing (MatEx AM) of specialized fluoroelastomer (FKM) compounds for applications in rubber seals and gaskets. The influence of a commercially available perfluoropolyether (PFPE) plasticizer on the printability of a control FKM rubber compound was studied using a custom-designed ram material extruder, Additive Ram Material Extruder (ARME), for printing fully compounded thermoset elastomers. The plasticizer’s effectiveness was assessed based on its ability to address challenges such as high compound viscosity and post-print shrinkage, as well as its impact on interlayer adhesion. The addition of the PFPE plasticizer significantly reduced the FKM compound’s viscosity (by 70%) and post-print shrinkage (by 65%). While the addition of the plasticizer decreased the tensile strength of the control compound, specimens printed with the plasticized FKM retained 34% of the tensile strength of compression-molded samples, compared to only 23% for the unplasticized compound. Finally, the feasibility of seals and gaskets manufacturing using both conventional and unconventional additive manufacturing (AM) approaches was explored. A hybrid method combining AM and soft tooling for compression molding emerged as the optimal method for seal and gasket fabrication. Full article

Gaskets and seals are essential components in the operation of proton exchange membrane (PEM) fuel cells and are required for keeping hydrogen and air/oxygen within their individual compartments. The durability of these gaskets and seals is necessary, as it influences not only the lifespan but also the electrochemical efficiency of the PEM fuel cell. In this study, the cause of silicon leaching from silicone gaskets under simulated fuel cell conditions was investigated. Additionally, to reduce silicon leaching, the silica surface was treated with methyltrimethoxysilane, vinyltriethoxysilane, and (3,3,3-trifluoropropyl)trimethoxysilane. Changes in the silica surface chemistry were investigated by scanning electron microscopy, energy dispersive X-ray spectroscopy, thermogravimetric analysis, elemental analysis, X-ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy. Inductively coupled plasma-optical emission spectroscopy analysis revealed that surface-treated silica was highly effective in reducing silicon leaching. Full article

The asphalt mixture splitting test is one of the most important methods for measuring asphalt’s tensile properties. To characterize the limitations of the traditional splitting test and the influence of the specimen size and loading conditions on the accuracy of the test, the factors affecting the strength of the splitting test were analyzed to reveal the splitting failure state and establish a unified representation model between the splitting and direct tensile tests. Initially, the moment of specimen cracking was taken as a key indicator, combined with image processing technology, to establish a set of criteria to judge the splitting test. Subsequently, standardized splitting tests were conducted and compared to tests of different specimen sizes and loading methods. Based on the octahedral strength theory, the stress points before and after the improved test were compared to the existing failure criteria. Direct tensile and splitting tests were conducted at different rates, and a unified strength–rate function model was established, realizing the unified representation of direct tensile and splitting tests. The research results indicate that the standardized splitting test is prone to the phenomenon wherein the specimen end face cracks before the center, affecting the accuracy of the test and potentially leading to redundant material strength evaluations. Using a loading method with a “35 mm specimen thickness” and a “0.3 mm rubber gasket + 12.7 mm arc-shaped batten” can essentially achieve the test hypothesis of “cracking at the center first”, resulting in less discrete outcomes and closer alignment to the three-dimensional stress failure state. The tensile and splitting strengths are both power function relationships with the rate as the independent variable, establishing a unified function model of the tensile and failure strengths. The research provides a more reliable testing method and calculation model for asphalt pavement structure design, and it also provides an effective basis for the improvement of splitting tests on materials such as concrete and rock. Full article

This article performs computer simulations of the change in magnetization in the ferromagnetic film when polarized electric current passes through it. The model examines multilayer structures from ferromagnetic and nonmagnetic films. A sandwich system comprises two ferromagnetic layers separated by a nonmagnetic gasket. Ferromagnetic films have different magnetic susceptibility. The first ferromagnetic film is magnetically hard and acts as a fixed layer. The second ferromagnetic film is magnetically soft, with a switched direction of magnetization. The current direction is perpendicular to the film plane (CPP geometry). Spin transfer is carried out by electrons that polarize in the first ferromagnetic film and transmit spin to the second ferromagnetic film. We use the Ising model to describe the magnetic properties of the system and the Metropolis algorithm to form the thermodynamic states of the spin system. Simulations are performed at temperatures below the Curie points for both materials. The result of computer simulation is the dependence of magnetization in the magnetically soft film on the current strength in the system. Calculations show that there is a critical value of the current at which the magnetization sign of the controlled film changes. The magnetization versus current plot is stepwise. The change in the magnetization sign is due to an increase in the polarization of the electron gas. The plot of electron gas polarization versus current is also stepwise. Full article

Ensuring the safety of electric vehicles is paramount, and one critical concern is the potential for hazardous hydrogen fuel leaks caused by the degradation of Proton-Exchange Membrane Fuel Cell (PEMFC) gasket materials. This study employs advanced techniques to address this issue. We leverage Finite Element Analysis (FEA) to rigorously assess the suitability of gasket materials for PEMFC applications, focusing on two crucial conditions: ageing and tensile stress. To achieve this, we introduce a comprehensive “dual degradation framework” that considers the effects of contact pressure and von Mises stress. These factors are instrumental in evaluating the performance and durability of Liquid Silicon Rubber (LSR) and Ethylene Propylene Diene Monomer (EPDM) materials. Our findings reveal the Yeoh model as the most accurate and efficient choice for ageing simulations, boasting a minimal Mean Absolute Percentage Error (MAPE) and computational time of just 0.27 s. In contrast, the Ogden model, while accurate, requires more computational resources. In assessing overall model performance using MAE, Root Mean Square Error (RMSE), and R-squared metrics, both LSR and EPDM materials proved promising, with LSR exhibiting superior performance in most areas. Furthermore, our study incorporates uniaxial tensile testing, which yields RMSE and MAE values of 0.30% and 0.40%, respectively. These results provide valuable insights into material behaviour under tensile stress. Our research underscores the pivotal role of FEA in identifying optimal gasket materials for PEMFC applications. Notably, LSR is a superior choice, demonstrating enhanced FEA modelling performance under ageing and tensile conditions. These findings promise to significantly contribute to developing safer and more reliable electric vehicles by advancing gasket material design. Full article

The article presents the influence of important design parameters of a spiral gasket on axial stiffness and leakage level. These parameters were the angle of inclination of the central part of the spiral section, the length of the vertical part of the spiral section, and the degree of densification of the material filling the metal coils. The scope of work was divided into two stages. In the first, experimental tests were conducted to determine the stiffness and tightness of a standard spiral gasket at two extreme levels of densification of the filler material, and the elastic–plastic properties of expanded graphite, which is the filler material of the metal spirals, were determined. In the second stage, multivariate numerical calculations were carried out to determine the axial stiffness of the gasket and to evaluate the distribution of contact pressure on the sealing surface. A novel aspect of the work is the proposal of a mathematical model to estimate the averaged value of the modulus of elasticity of the filler material as a function of the degree of densification and the execution of an experimental plan that significantly allowed the adoption of a limited number of analysed model variants used in the numerical calculations. Full article

The sealing system, as the most important load-bearing component, is a critical part of the stack assembly in a proton exchange membrane fuel cell (PEMFC). Currently, flat or single-peak sealing gaskets are commonly used for large metal bipolar plate sealing, which can easily cause problems such as significant internal stress and distortion displacement. In order to solve this problem, an innovative double-peak sealing gasket structure is proposed. Based on the Mooney–Rivlin constitutive model, the impact of the sealing material hardness, friction coefficient, and compression ratio on the sealing performance are investigated. Meanwhile, the double-peak seal is fabricated and assembled into a single fuel cell for testing. The results show that the sealing performance of a double-peak sealing gasket with extended wings has been optimized, and the maximum contact pressure on the upper and lower contact surfaces is 1.2 MPa and 0.67 MPa, respectively, which is greater than the given air pressure of 0.1 MPa. And the sealing effect is optimal with a 45 Shore A hardness rubber, a friction coefficient of 0.05, and an initial compression ratio of 35%. The simulation and experimental sealing performance of the sealing gasket under different compression ratios remain similar. Full article

High performance polymer matrix composites with low friction and wear rate are of urgent requirement in sliding bearings and gaskets. In this study, the PTFE/MoS₂ composites were prepared and the effect of testing temperature on the tribological properties were investigated. Results show that the friction coefficient and wear rate are approximately (0.14–0.19) and (4.18–13.38 × 10⁻⁴ mm³/Nm) at testing temperatures from 25 to 250 °C, respectively. At testing temperatures above 200 °C, the coefficient of friction of the composite with the addition of MoS₂ is lower than that of pure PTFE, while the wear rate of the composite material with the addition of 2 wt.% and 5 wt.% MoS₂ is lower than that of pure PTFE at temperatures above 150 °C. At low testing temperatures (25–100 °C), the main wear mechanism is that of slight abrasive wear, while from 150 °C to 250 °C, the main wear mechanism transformed to fatigue and severe abrasive wear. Full article

Mineral dehydration in the subduction zone enormously affects Earth’s geodynamics and the global geochemical cycles of elements. This work uses Raman spectroscopy and X-ray diffraction to investigate the dehydration process of antigorite under compression and shear loading conditions in a rotational diamond anvil cell (RDAC) at room temperature. In order to compare the shear effects, T301 stainless steel and Kapton plastic are applied as the gasket materials. In the experiment using a high-strength T301 stainless steel gasket, two new broad OH-stretching peaks of H₂O and H₃O₂⁻ appear at 3303 and 3558 cm⁻¹, respectively, at 1.7 GPa. The original sharp OH-stretching peaks of antigorite at 3668 and 3699 cm⁻¹ remain, while the central pressure is increased to 8.0 GPa, and the largest pressure gradient is about 2.5 GPa in the sample chamber. In another experiment with a low-strength gasket of Kapton plastic, two new OH-stretching broad peaks of H₂O and H₃O₂⁻ also start to appear at 3303 and 3558 cm⁻¹, respectively, at a lower pressure of 0.3 GPa, but the original sharp OH-stretching peaks of antigorite at 3668 and 3699 cm⁻¹ almost completely vanish as the central pressure reaches 3.0 GPa, with the largest pressure gradient at around 4.8 GPa. The comparison between the two experiments shows that antigorite is easier to dehydrate in the chamber of a Kapton plastic gasket with a larger gradient of shear stress. However, its axial compression stress is lower. The high-pressure Raman spectra of MgO₂(OH)₄ octahedron and SiO₄ tetrahedron in the low wavenumber zones (100–1200 cm⁻¹) combined with the micro-beam X-ray diffraction spectrum of the recovered product strongly support the structural breakdown of antigorite. This investigation reveals that the water-bearing silicate minerals have strong shear dehydration in the cold subduction zone of the plate, which has important applications in predicting the physical and chemical properties of subduction zones and deducing the rate of plate subduction. Full article

Ethylene–propylene–diene monomer (EPDM) rubber is one of the rapidly developing synthetic rubbers for use as a gasket material in proton exchange membrane (PEM) fuel cell applications. Despite its excellent elastic and sealing properties, EPDM faces challenges such as molding processability and recycling ability. To overcome these challenges, thermoplastic vulcanizate (TPV), which comprises vulcanized EPDM in polypropylene matrix, was investigated as a gasket material for PEM fuel cell applications. TPV showed better long-term stability in terms of tension and compression set behaviors under accelerated aging conditions than EPDM. Additionally, TPV exhibited significantly higher crosslinking density and surface hardness than EPDM, regardless of the test temperature and aging time. TPV and EPDM showed similar leakage rates for the entire range of test inlet pressure values, regardless of the applied temperature. Therefore, we can conclude that TPV exhibits a similar sealing capability with more stable mechanical properties compared with commercialized EPDM gaskets in terms of He leakage performance. Full article

Underground pipelines are vital parts to urban water supply, gas supply, and other lifeline systems, affecting the sustainable development of cities to a great extent. The pipeline joint, which is a weak link, may be seriously damaged during natural disasters such as earthquakes. The failure of pipe joints can cause leakage accidents, resulting in system failure and interruption, and even some secondary disasters. Herein, based on uniaxial and plane tensile test results of a T-rubber gasket material, the assembly process and sealing performance of a T-rubber gasket joint of a ductile iron pipe are numerically simulated using the Ogden third-order strain energy density function to fit the material constant. The simulation accounts for severe nonlinearities, including large deformations, hyperelasticity, and complex contacts. The effects of the assembly friction coefficient, assembly depth, and radial clearance deviation of the socket and spigot on the seal contact pressure are analyzed. The results suggest that the entire history of the deformation and stress variations during assembly can be clearly visualized and accurately calculated. For the different friction coefficients, the assembly depth corresponding to the sliding friction condition of the spigot pipe was 74 mm, while the minimum pushing force required to assemble the T-rubber gasket joint of a DN300 ductile iron pipe was 6.8 kN at the ideal situation with a friction coefficient of 0. The effective contact pressure of the rubber gasket seepage surface under various operating conditions is much higher than the normal pressure of municipal pipelines, thus indicating that the rubber gasket joint exhibits the ideal sealing performance. Furthermore, a certain deviation, which is about 20 mm, is allowed for the assembly depth of the rubber gasket joint such that the axial displacement of the pipe joint can be adapted under an earthquake or ground displacement. Full article

As the first waterproof component of the immersed tunnel, it is very important to ensure the remaining compression of the GINA gasket to resist external water intrusion. This paper proposed a method for determining warning thresholds for the remaining compression of the GINA gasket based on a material-to-mechanical analysis. In terms of material analysis, two factors that affect the GINA gasket are investigated: rubber hardness and cross-sectional shape, and they are adopted as the basis for subsequent mechanical analysis. In terms of mechanical analysis, uneven settlement during the operation period is considered to be the major cause of joint deformation, which is further divided into four modes: bending, shear, expansion, and torsion, with the computation model of the GINA gasket established to obtain the warning threshold. After that, a graded early warning method is adopted, and corresponding thresholds are given after an investigation of previous studies, which are validated by a three-dimensional finite element analysis. The deformation monitoring data between the E28 and E29 elements of the Hong Kong–Zhuhai–Macao Bridge Immersed Tunnel are used to verify the proposed method. The results show that the GINA gasket of the Hong Kong–Zhuhai–Macao Bridge Immersed Tunnel is currently in a safe state, and its deformation is much lower than the minimum warning level. Full article

This study focuses on the preparation and characterization of composite gaskets designed for the sealing of the solid oxide cell stacks operating below 700 °C. The seals were fabricated with the addition of various amounts (10–90 wt.%) of 3 mol.% yttria partially stabilized zirconia to a BaO-Al₂O₃-CaO-SiO₂ glass matrix. The sample gaskets in the form of thin frames were shaped by tape casting. The quality of the junctions between the composites and Crofer 22APU steel commonly used as an SOC interconnect was evaluated after thermal treatment of heating to 710 °C, then cooling to the working temperature of around 620 °C and then leaving them for 10h in an air atmosphere, before cooling to room temperature. The samples were also studied after 3, 5, and 10 thermal cycles to determine the changes in microstructure and to evaluate the porosity and possible crystallization of the glass phase. The compression of the seals was calculated on the basis of differences in thickness before and after thermal treatment. The influence of zirconia additions on the mechanical properties of the seals was studied. The experimental results confirmed that glass–ceramic composites are promising materials for gaskets in SOC stacks. The most beneficial properties were obtained for a composite containing 40 wt.% of YSZ. Full article

This study presents the improved stabilization effects of graphene on a polymer substrate, namely a styrene-isoprene-styrene triblock copolymer (SIS) which creates opportunities for long-term applications and radiation processing. The added graphene has a remarkable activity on the protection of polymer against their oxidation due to the penetration of free macroradical fragments into the free interlayer space. The chemiluminescence procedure used for the evaluation of the progress of oxidation reveals the delaying effect of oxidative degradation by the doubling extension of oxidation induction time, when the material formulation containing graphene is oxidized at 130 °C. The pristine polymer that is thermally aged requires an activation energy of 142 kJ mol⁻¹, while the modified material needs 148, 158 and 169 kJ mol⁻¹, for the oxidative degradation in the presence of 1, 2 and, respectively, 3 wt% of graphene. The contribution of graphene content (1 wt%) on the stability improvement of SIS is demonstrated by the increase of onset oxidation temperature from 190 °C for neat polymer to 196 °C in the presence of graphene and to 205 °C for the polymer stabilized with graphene and rosemary extract. The addition of graphene into the polymer formulations is a successful method for enlarging durability instead of the modification of receipt with synthesis antioxidants. The presumable applications of these studied materials cover the areas of medical wear, food packaging, commodities, sealing gaskets and others that may also be included through the products for nuclear power plants. Full article