WO2023182365A1

WO2023182365A1 - Cool-down method for liquefied gas storage tank

Info

Publication number: WO2023182365A1
Application number: PCT/JP2023/011261
Authority: WO
Inventors: 太一郎下田; 晴彦冨永; 麻子三橋; 章司池島; 邦彦持田; 翔樋渡; 広崇 ▲高▼田; 隆博中島
Original assignee: 川崎重工業株式会社
Priority date: 2022-03-23
Filing date: 2023-03-22
Publication date: 2023-09-28
Also published as: KR20240132088A; JP2023140784A; CN118661053A

Abstract

A method for cooling a tank, which is for storing liquefied gas and which is provided with an inner tank (3) and an outer tank (5), prior to filling of the liquefied gas which is to be stored, said method comprising: introducing cooling liquefied gas (CH) into a space inside the inner tank; and maintaining the open state of a communication passage (11) between the space (7) inside the inner tank and a space (9) between the inner and outer tanks, after the commencement of the introduction of the cooling liquefied gas (CH) and until the temperature of the space (9) between the inner and outer tanks is less than or equal to a prescribed value.

Description

How to cool down a liquefied gas storage tank

Related applications

This application claims priority to Japanese Patent Application No. 2022-046800 filed on March 23, 2022, and is cited in its entirety as a part of this application by reference.

The present disclosure relates to a method for cooling down a liquefied gas storage tank.

Conventionally, it has been proposed to use a double-shell tank including an inner tank and an outer tank as a tank for storing liquefied gas, such as cryogenic liquefied hydrogen (see, for example, Patent Document 1).

Generally, when storing low-temperature liquefied gas in a tank, in order to avoid rapid cooling of the tank by filling a room-temperature tank with a large amount of liquefied gas to be stored at once, Before filling the tank, the tank is cooled at a relatively low speed (hereinafter referred to as "cool down").

Japanese Patent Application Publication No. 2019-151291

However, in the case of tanks with multiple heat insulation structures such as double-shell tanks for liquefied gas, they have high insulation properties, so it takes a long time to cool the entire tank by just cooling the inner tank, and a large amount of cooling is required. liquefied gas will be required. Therefore, the cost required for cooldown increases.

An object of the present disclosure is to shorten the time required to cool down a multi-layer heat-insulated structure tank for storing liquefied gas, and to suppress costs, in order to solve the above-mentioned problems.

In order to achieve the above object, a method for cooling down a liquefied gas storage tank according to the present disclosure includes:
A method for cooling a tank including an inner tank and an outer tank for storing liquefied gas before filling it with the liquefied gas to be stored, the method comprising:
Introducing a cooling liquefied gas into the inner tank space;
After starting the introduction of the cooling liquefied gas, maintain an open state of the communication path between the space between the inner and outer tanks and the inner space of the inner tank until the temperature of the space between the inner and outer tanks becomes equal to or lower than a predetermined value. and,
including.

According to the method for cooling down a liquefied gas storage tank according to the present disclosure, it is possible to shorten the time required for cooling down a multi-layered heat-insulating structure tank for storing liquefied gas, and to suppress costs.

Any combination of at least two configurations disclosed in the claims and/or the specification and/or the drawings is included in the present invention. In particular, any combination of two or more of each of the claims is included in the invention.

The invention will be more clearly understood from the following description of preferred embodiments with reference to the accompanying drawings. However, the embodiments and drawings are merely for illustration and explanation, and should not be used to define the scope of the present invention. The scope of the invention is defined by the appended claims. In the accompanying drawings, the same part numbers in multiple drawings indicate the same or corresponding parts.
1 is a cross-sectional view showing a schematic configuration of a liquefied gas storage tank to which a cool-down method according to an embodiment of the present disclosure is applied. FIG. 2 is a schematic diagram showing an initial state before the start of a cool-down method according to an embodiment of the present disclosure. FIG. 3 is a schematic diagram showing a state during cooling of the inner tank in a cool-down method according to an embodiment of the present disclosure. FIG. 7 is a schematic diagram showing a state during cooling of the inner tank in a cool-down method according to a modified example of an embodiment of the present disclosure. FIG. 7 is a schematic diagram showing a state during cooling of the inner tank in a cool-down method according to another modification of the embodiment of the present disclosure. FIG. 2 is a schematic diagram showing a state in which a cool-down method according to an embodiment of the present disclosure has been completed.

Hereinafter, preferred embodiments of the present disclosure will be described with reference to the drawings. FIG. 1 shows a liquefied gas storage tank (hereinafter simply referred to as "storage tank") 1 to which a cool-down method according to an embodiment of the present disclosure is applied. This storage tank 1 is a tank for storing liquefied gas, and is configured as a double shell tank including an inner tank 3 and an outer tank 5. Note that in this specification, "cool down" means cooling the storage tank 1 before filling the storage tank 1 with the liquefied gas to be stored.

In the present embodiment described below, liquefied hydrogen at an extremely low temperature (approximately -250° C.) will be explained as an example of the liquefied gas to be stored. However, liquefied gas can also include other types of gas, such as liquefied petroleum gas (LPG, approximately -45°C), liquefied ethylene gas (LEG, approximately -100°C), liquefied natural gas (LNG, approximately -160°C), It may be helium (LHe, about −270° C.) or the like.

The storage tank 1 is installed, for example, on a ship such as a liquefied hydrogen carrier. However, the liquefied hydrogen storage facility in which the storage tank 1 is installed is not limited to this example as long as it has a structure and function capable of storing liquefied hydrogen. The liquefied hydrogen storage facility in which the storage tank 1 is installed may be, for example, a ship that uses liquefied hydrogen as a propulsion fuel, a land-based liquefied hydrogen storage facility other than a ship, or a plant that uses liquefied hydrogen. It's fine.

The storage tank 1 is configured as a double shell tank having an inner tank 3 and an outer tank 5. Specifically, the inner tank 3 has an inner tank shell that forms a storage space (hereinafter referred to as "inner tank interior space 7") for liquefied hydrogen to be stored, and an outer circumferential surface of the inner tank shell. It has an inner tank heat insulation layer that covers the inner tank. The outer tank 5 has an outer tank shell that forms an inter-inner/outer tank space 9 that is a heat insulating layer between it and the inner tank 3, and an outer tank heat insulating layer that covers the outer peripheral surface of the outer tank shell. Note that the locations where the heat insulating layers of the inner tank 3 and the outer tank 5 are installed are not limited to this example, but are arbitrary. For example, the heat insulating layers may be installed so as to cover the inner circumferential surface of the outer tank shell. Moreover, one or both of the heat-insulating layers of the inner tank 3 and the outer tank 5 may be omitted. This storage tank 1 is normally operated with low-temperature hydrogen gas sealed in the space 9 between the inner and outer tanks, which is a heat insulating layer.

In this embodiment, a communication passage 11 is provided that communicates the inner tank interior space 7 and the outer and outer tank space 9. The communication path 11 is configured to be openable and closable. In the illustrated example, specifically, a vaporized gas discharge passage 13 that discharges vaporized gas of liquefied hydrogen (hereinafter simply referred to as “vaporized gas”) G1 generated in the inner tank space 7 to the outside of the storage tank 1 and a hydrogen gas introduction passage 15 that introduces hydrogen gas (hereinafter referred to as "external hydrogen gas") G2 from a hydrogen gas source (not shown) provided outside the storage tank 1 into the space 9 between the inner and outer tanks. A connecting passage 17 connecting the vaporized gas discharge passage 13 and the hydrogen gas introduction passage 15 is provided outside the storage tank 1. A communication passage 11 is formed by the vaporized gas discharge passage 13, the connection passage 17, and the hydrogen gas introduction passage 15. Further, an on-off valve 19 is provided in the communication passage 11, and the communication passage 11 is configured to be openable and closable by this on-off valve 19. In this example, the on-off valve 19 is provided in a portion of the hydrogen gas introduction passage 15 downstream of the connection point with the connection passage 17, but the position and number of the on-off valves 19 are not limited to this example. Further, the on-off valve 19 may be a valve that can be opened and closed manually, or may be a valve that is automatically opened and closed according to a set differential pressure.

Note that the specific configuration of the communication path 11 between the inner tank interior space 7 and the outer and outer tank space 9 and the specific configuration that allows the communication path 11 to be opened and closed are not limited to this example. Further, the above-mentioned "hydrogen gas source" may have any configuration as long as it can serve as a supply source of hydrogen gas, and is typically a tank that stores hydrogen gas, but for example, it may be a tank that stores liquefied hydrogen. It may also be a combination of a tank and a vaporizer.

Further, in this embodiment, an inner tank temperature detection device 21 that detects the temperature of the inner tank 3, an inner tank space pressure detection device 23 that monitors the pressure of the inner tank space 7, and a temperature detection device 23 that detects the temperature of the space 9 between the inner and outer tanks. The inner and outer tank space temperature detection device 25 detects the pressure in the inner and outer tank space 9, and the inner and outer tank space pressure sensor 27 detects the pressure in the inner and outer tank space 9. These detection devices consist of a sensor element that detects the physical quantity to be detected (temperature, pressure), various circuits that perform necessary processing such as signal conversion processing and arithmetic processing on the obtained detected quantity, and information necessary for these processing. The device is equipped with a memory for storing the data, a power source circuit such as a power supply element such as a battery or a power supply circuit for receiving power supply from the outside, a transmission circuit for transmitting the output signal to the outside by wire or wirelessly, and the like. Note that as such a temperature sensing device and a pressure sensing device, a device that measures parts other than those described above, such as an inner tank temperature sensing device or an outer tank temperature sensing device, may be provided. Moreover, only the necessary temperature sensing devices and pressure sensing devices may be provided depending on the embodiment of the cool-down method described later.

A method for cooling down the storage tank 1 configured in this way will be described in detail below.

In this embodiment, in the storage tank 1 in the initial state at the time of starting the cool-down shown in FIG. In each of the spaces 9, hydrogen gas exists at room temperature and atmospheric pressure (0 kPaG), for example. However, the temperature and pressure of the hydrogen gas in the initial state are not limited to room temperature and atmospheric pressure. From this state, as shown in FIG. 2B, liquefied hydrogen for cooling (hereinafter simply referred to as "hydrogen for cooling") CH is introduced into the inner tank space 7. In this example, cooling hydrogen CH is sprayed into the inner tank space 7 using the sprayer 29 .

By continuing to spray the cooling hydrogen CH in this state, the temperature of the inner tank 3 is reduced. As the temperature of the inner tank 3 decreases, the temperature of the space 9 between the inner and outer tanks also decreases. Further, in the inner tank space 7, vaporized gas G1 in which the cooling hydrogen CH is vaporized is generated, and the pressure increases, while in the inner tank space 9, the pressure decreases due to the temperature drop. Since the communication passage 11 is opened as described above, the vaporized gas G1 generated in the inner tank inner space 7 flows into the inner and outer tank space 9 via the communication passage 11 due to the pressure difference between both

spaces

7 and 9. do. After starting the spraying of hydrogen CH for cooling, the space 9 between the inner and outer tanks and the inner tank are heated until the temperature of the space 9 between the inner and outer tanks becomes equal to or lower than a predetermined value (hereinafter, this temperature is referred to as the "first predetermined temperature"). The communication path 11 with the inner space 7 is maintained in an open state.

If the pressure difference between the two spaces exceeds a predetermined range while cooling the inner tank 3 with the communication passage 11 open, a pressure difference adjustment device is used to adjust the pressure difference between the two spaces. may be adjusted so that it falls within a predetermined range. For example, if the pressure in the space 9 between the inner and outer tanks is excessively low, a device 31 (hereinafter simply referred to as a "gas feeding device") that forcibly feeds hydrogen gas to the space 9 between the inner and outer tanks is connected. The gas supply device 31 may be provided on the passage 11, for example in the connection passage 17, and supply the vaporized gas G1 in the inner tank space 7 to the space 9 between the inner and outer tanks. The gas supply device 31 is a device that moves gas by applying pressure to the gas, such as a turbo or positive displacement compressor, blower, or fan. In place of or in addition to the forced supply of the vaporized gas G1, external hydrogen gas G2 may be supplied from the hydrogen gas introduction passage 15 to the space 9 between the inner and outer tanks. In this case, as shown as a modification in FIG. 2C, the gas supply device 31 may be provided on the hydrogen gas introduction passage 15, and a bypass passage 15a may be provided for when the gas supply device 31 is not used. good.

Furthermore, if the pressure in the space 9 between the inner and outer tanks is excessively high, the hydrogen gas in the space 9 between the inner and outer tanks may be exhausted using the exhaust device 33, as shown as a modification in FIG. 2D. As shown in the figure, this exhaust device 33 can be provided on a dedicated exhaust passage 35. However, the installation mode of the exhaust device 33 is not limited to this example, and it may be provided, for example, in the middle of the hydrogen gas introduction passage 15. The "predetermined range" of the pressure difference between the inner tank space 7 and the outer and outer tank space 9 is determined, for example, based on the set pressure of a safety valve installed in the inner tank 3. Note that it is not essential to provide the exhaust device 33 in the exhaust passage 35. For example, when the pressure in the inner tank space 7 is kept higher than atmospheric pressure, the gas in the space 9 between the inner and outer tanks can be discharged only through the exhaust passage 35.

Furthermore, even if the pressure in the space 9 between the inner and outer tanks decreases even though the communication path 11 is open, the pressure in the space 9 between the inner and outer tanks may be adjusted using the gas supply device 31.

In this way, by communicating the inner tank inner space 7 and the inner/outer tank inter-tank space 9 while cooling the inner tank 3 with the cooling hydrogen CH, the low temperature vaporized gas G1 generated in the inner tank inner space 7 is As the pressure in the inner tank space 7 increases and the pressure in the inner and outer tank space 9 decreases, it is introduced into the inner and outer tank space 9. This promotes cooling of the space 9 between the inner and outer tanks and the outer tank 5, thereby reducing the time required to cool down the entire storage tank 1 compared to simply cooling only the inner tank 3, and reducing costs. be able to. Furthermore, since the inflow of vaporized gas G1 suppresses an excessive drop in pressure in the space 9 between the inner and outer tanks, the minimum allowable pressure in the space 9 between the inner and outer tanks, taking into account the mechanical strength of the inner tank 3 and the outer tank 5, is It becomes easier to maintain.

Note that if the temperature of the vaporized gas G1 and/or the external hydrogen gas G2 introduced into the space 9 between the inner and outer tanks is not low enough to cool the space 9 between the inner and outer tanks to the first predetermined temperature, or if the temperature is excessively low, A temperature adjustment device (not shown) is provided on the communication path 11 (for example, the hydrogen gas introduction path 15), and the temperature adjustment device is used to supply hydrogen gas whose temperature is adjusted to about the first predetermined temperature into the space 9 between the inner and outer tanks. may be introduced.

Thereafter, when the temperature of the space 9 between the inner and outer tanks falls to the first predetermined temperature, the on-off valve 19 is closed, the communication passage 11 is closed, and the supply of hydrogen gas to the space 9 between the inner and outer tanks is stopped. By closing the communication path 11, the temperature of the space 9 between the inner and outer tanks is prevented from decreasing excessively. However, it is not essential to close the communication path 11. Moreover, after the communication path 11 is once closed, the communication path 11 may be opened as necessary.

The first predetermined temperature of the space 9 between the inner and outer tanks is determined based on the set temperature (for example, 110 K) of the space 9 between the inner and outer tanks during steady operation of the storage tank 1. In this embodiment, in order to maintain the space temperature between the inner and outer tanks at or above the set temperature, a temperature slightly higher than the set temperature (for example, 120 K) is set as the first predetermined temperature.

Thereafter, as shown in FIG. 2E, when the temperature of the inner tank 3 and the temperature of the space 9 between the inner and outer tanks have respectively decreased to the target temperatures, the communication passage 11 is closed and the spraying of the cooling hydrogen CH is stopped. to end the cooldown.

In this embodiment, an example has been described in which cool down is performed using liquefied hydrogen for cooling, but cool down may be performed using liquefied gas other than liquefied hydrogen. For example, the cooldown may be performed in stages, such as introducing liquefied nitrogen from a state in which air is present in the inner tank 3, and then replacing the liquefied nitrogen with liquefied hydrogen.

Although FIG. 1 shows an independent double-shell tank formed independently of the ship's hull as an example of the storage tank 1, the cool-down method according to the present embodiment is not limited to this example. , can be applied to any type of storage tank. For example, the cool-down method according to the present embodiment can also be applied to a type of storage tank that is formed integrally with the hull. Further, the multiple heat insulation structure of the storage tank may be a triple structure or more, and the cool down method according to the present embodiment is applied to the inner tank space and any other intertank space of such a multiple heat insulation structure. be able to.

The cool down according to the present embodiment is typically performed, for example, after construction of the storage tank 1, after construction of liquefied gas storage equipment such as a ship in which the storage tank 1 is installed, or after the construction of the equipment or the storage tank 1. Maintenance is carried out after warming up the storage tank 1 and before loading it again. However, the cool-down method according to the present embodiment is also applied when carrying out an empty voyage (ballast voyage) after unloading the liquefied gas in the storage tank 1 when the storage tank 1 is installed on a ship. be able to. That is, during a ballast voyage, the temperature of the inner tank 3 may gradually rise, and in that case, the above-mentioned cool-down method can be applied. In addition, when cooling down the storage tank 1 during a ballast voyage, for example, the liquefied gas left in the inner tank 3 for cooling down without unloading is used to cool down the pumps etc. installed in the inner tank 3. A feeding device transports the liquefied gas to the top of the tank for cooling down. When a plurality of storage tanks 1 are installed, liquefied gas or vaporized gas for cooling down may be supplied from other storage tanks 1.

According to the cool-down method according to the present embodiment described above, while cooling the inner tank 3 with liquefied hydrogen, the inner tank space 7 and the space 9 between the inner and outer tanks are communicated with each other. The generated low-temperature vaporized gas G1 is introduced into the space 9 between the inner and outer tanks as the pressure in the space 9 between the inner and outer tanks decreases. This promotes cooling of the space 9 between the inner and outer tanks and the outer tank 5, thereby reducing the time required to cool down the entire storage tank 1 compared to simply cooling only the inner tank 3, and reducing costs. be able to. Furthermore, since the inflow of the vaporized gas G1 suppresses a drop in the pressure in the space 9 between the inner and outer tanks, the minimum allowable pressure in the space 9 between the inner and outer tanks is maintained, taking into account the mechanical strength of the inner tank 3 and the outer tank 5. It becomes easier.

In the cool-down method according to the present embodiment, when the difference between the pressure in the inner tank space 7 and the pressure in the inner and outer tank spaces 9 is outside a predetermined range, the pressure in the inner and outer tank spaces 9 is adjusted to be within a predetermined range. may be adjusted. This makes it easier to maintain the minimum allowable pressure in the space 9 between the inner and outer tanks, taking into consideration the mechanical strength of the inner tank 3 and the outer tank 5.

In the cool-down method according to the present embodiment, the communication passage 11 may be closed when the temperature of the space 9 between the inner and outer tanks becomes equal to or lower than the first predetermined temperature. This prevents the temperature of the space 9 between the inner and outer tanks from decreasing excessively.

As described above, the preferred embodiments of the present disclosure have been described with reference to the drawings, but various additions, changes, or deletions can be made without departing from the spirit of the present disclosure. Accordingly, such are also included within the scope of this disclosure.

1 Liquefied gas storage tank 3 Inner tank 5 Outer tank 7 Inner tank inner space 9 Space between inner and outer tanks 11 Communication path 29 Sprayer 31 Gas feeder CH Cooling liquefied gas G1 Vaporized gas G2 External hydrogen gas

Claims

A method for cooling a tank including an inner tank and an outer tank for storing liquefied gas before filling it with the liquefied gas to be stored, the method comprising:
Introducing a cooling liquefied gas into the inner tank space;
After starting the introduction of the cooling liquefied gas, maintain an open state of the communication path between the space between the inner and outer tanks and the inner space of the inner tank until the temperature of the space between the inner and outer tanks becomes equal to or lower than a predetermined value. and,
including,
How to cool down a liquefied gas storage tank.
The cool-down method according to claim 1,
closing the communication passage when the temperature of the space between the inner and outer tanks becomes equal to or lower than the predetermined value;
How to cool down.
The cool-down method according to claim 1 or 2,
If the difference between the pressure in the inner tank space and the pressure in the inner and outer tank space is outside a predetermined range, adjusting the pressure in the inner and outer tank space to be within the predetermined range.
How to cool down.