[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

WO2018233172A1 - Manufacturing method of graphene-containing slubby yarn having antimicrobial and cooling properties, and application of same in home textile item - Google Patents

Manufacturing method of graphene-containing slubby yarn having antimicrobial and cooling properties, and application of same in home textile item Download PDF

Info

Publication number
WO2018233172A1
WO2018233172A1 PCT/CN2017/108500 CN2017108500W WO2018233172A1 WO 2018233172 A1 WO2018233172 A1 WO 2018233172A1 CN 2017108500 W CN2017108500 W CN 2017108500W WO 2018233172 A1 WO2018233172 A1 WO 2018233172A1
Authority
WO
WIPO (PCT)
Prior art keywords
graphene
yarn
fiber
cotton
slub yarn
Prior art date
Application number
PCT/CN2017/108500
Other languages
French (fr)
Chinese (zh)
Inventor
陈志华
Original Assignee
江苏工程职业技术学院
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 江苏工程职业技术学院 filed Critical 江苏工程职业技术学院
Priority to JP2019501674A priority Critical patent/JP6778316B2/en
Publication of WO2018233172A1 publication Critical patent/WO2018233172A1/en

Links

Classifications

    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/34—Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04—Blended or other yarns or threads containing components made from different materials
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/34—Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns
    • D02G3/346—Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns with coloured effects, i.e. by differential dyeing process
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/208—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
    • D03D15/217—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based natural from plants, e.g. cotton
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/208—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
    • D03D15/225—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based artificial, e.g. viscose
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/01—Natural vegetable fibres
    • D10B2201/10—Bamboo
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20—Cellulose-derived artificial fibres
    • D10B2201/22—Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24—Viscose
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/13—Physical properties anti-allergenic or anti-bacterial

Definitions

  • the invention belongs to the field of novel material blended yarns, and particularly relates to a preparation method of graphene antibacterial cool slub yarn and application in the home textile product.
  • Graphene composite fiber materials have become a research hotspot in recent years. At present, there are a lot of researches on the potential applications of graphene composite fiber materials, such as energy storage materials, conversion equipment, sensors, wires and so on.
  • Graphene has excellent antibacterial properties and thermal conductivity. When graphene is finished on fabric, antibacterial fabric can be prepared. Compared with traditional inorganic and organic antibacterial agents, graphene has no cytotoxicity and is more suitable for direct contact with human skin. However, due to the lack of affinity between graphene and textiles, it is difficult to process graphene onto textiles by conventional processes.
  • the present invention provides a method for preparing a graphene antibacterial cool slub yarn and an application thereof in a home textile product, which can be applied to a home textile product.
  • the yarn is composed of graphene nylon composite fiber, bamboo fiber, viscose fiber, and the above fiber is spun into a slub yarn by a spun yarn process.
  • the graphene antibacterial cool slub yarn obtained by the invention is blended by a plurality of functional fibers, and the advantages of the fibers used in the collection are all in one body.
  • the adhesive has softness, moisture absorption and light weight performance
  • the bamboo fiber is antibacterial and cool.
  • the new graphene nylon composite fiber has antistatic, antibacterial, anti-caries, cool and soft properties.
  • a method for preparing graphene antibacterial cool slub yarn the yarn is composed of 30-60 parts by weight of graphene nylon composite fiber, 20-30 parts of bamboo fiber, 10-20 parts of viscose a fiber composition, the above fiber is spun into a slub yarn by a ring spinning machine spinning process; the process comprises the following process steps: mixing Cotton, carding, drawing, spinning, winding, the specific operation is as follows:
  • the cotton mixing and carding process adopting a continuous weighing computer with a color mixing process, manual weighing and weighing ⁇ mixing cotton ⁇ opening cotton ⁇ carding, continuous weighing and weighing feeding of the cotton mixing bin, and negative pressure extraction by the fan Soft and open.
  • the main parameters of the carding process the speed of the cotton picker is 400-500 rpm, the speed of the needle opener is 800-1000 rpm, the speed of the roll is 10 r/min, the speed of the licking roll is 400-500 rpm, and the speed of the cylinder is 300-400 rpm.
  • the cylinder-cover 3 points are 0.19mm, 0.21mm, 0.24mm, and the dry strips are 10 ⁇ 20g/5m;
  • the drawing process using Trützschler HSR1000 type draw frame, the main parameters of the process, using two-way combination, the front zone gauge is 40-45mm, the rear zone gauge is 46-53mm, and the rear zone drafting multiple is 1.0- 1.4, the delivery speed is 200-230m/min, the draw ratio is 8-9, and the dry weight of the sliver is 8-15/5m;
  • the spinning process the slub yarn is spun by a JWFl 562E ring spinning machine, and the number of slub yarns is 12, 14, 16, 20, 21, 24, 30, 32, 40. ⁇ to Z ⁇ , the front roller speed is 140-220r ⁇ min -1 , and the front zone is drawn 15-40 times.
  • the graphene nylon composite fiber has a single-layer graphene content of 0.3-0.8%, the color is gray-black, and the viscose fiber overcomes the characteristics of the gray color of the graphene nylon composite fiber, and adopts a computer automatic color matching technology to design and match the yarn.
  • the line presents a special level of guilt.
  • the graphene nylon composite fiber can also be replaced by a graphene polyester composite fiber.
  • the bamboo fiber and the viscose fiber are colored fibers, and the color bamboo yarn is designed by color matching.
  • the draw frame process uses three parallel steps and eight feeds.
  • the spinning process is to reduce the winding by using a special antistatic agent for the roller to process the rubber roller; using a fluorine-plated steel collar and a wire ring.
  • the dyeing and finishing process is finished with a cool feeling, further enhancing the feel and feel of the fabric.
  • Slub yarn prepared according to the preparation method of the graphene antibacterial cool slub yarn In the application of the product, the prepared graphene antibacterial cool slub yarn is woven, dyed and finished into a fabric for home textile.
  • the graphene antibacterial cool slub yarn obtained by the invention is blended by a plurality of functional fibers, and the advantages of the fibers used in the collection are compared, and the viscose is superior to the natural cotton fiber in softness and moisture absorption compared with the conventional cotton yarn.
  • the yarn prepared by the invention is applied to the home textile, and the home textile product has a layered feeling, a three-dimensional feeling, and has multiple functions at the same time.
  • the visual sense of the slub yarn and the fabric thereof and the visual sense are provided by a black-gray graphene nylon composite fiber, a natural color or a color bamboo fiber, and a viscose fiber through a computer color mixing system.
  • the main antibacterial, antimony, antistatic, cool and other functions of the slub yarn and its fabric are provided by graphene nylon composite fiber.
  • graphene nylon composite fiber For traditional inorganic and organic antibacterial agents, graphene is not cytotoxic, and is more suitable for Direct contact with human skin, graphene nylon composite fiber.
  • the secondary antibacterial property and coolness of the slub yarn and its fabric are reinforced by bamboo fibers.
  • the softness, comfort, breathability, sweat absorption and the like of the slub yarn and its fabric are mainly supported by viscose fibers.
  • the yarn prepared by the invention is prepared into a summer home textile fabric, and the relevant test indexes of the obtained fabric are as follows: dimensional change rate: warp direction -2.8%, weft direction -2.8%; strength: 329.8N color fastness: washable (discoloration , staining) 3-4 grade; anti-mite performance: 95%; antistatic performance: vertical resistance is less than 100 ⁇ ; contact cold feeling (q.max): 0.306W / cm 2 .
  • the graphene nylon composite fiber described in the present invention may also be replaced with a graphene polyester composite fiber.
  • the bamboo fiber and the viscose fiber are colored fibers, and the color bamboo yarn is designed by color matching.
  • the draw frame process uses three parallel steps and eight feeds.
  • the spinning process is to reduce the winding by using a special antistatic agent for the roller to process the rubber roller; using a fluorine-plated steel collar and a wire ring.
  • the dyeing and finishing process is finished with a cool feeling to further strengthen the feel and feel of the fabric.
  • the prepared graphene antibacterial cool slub yarn is woven, dyed and finished into a fabric for use in home textile products.
  • the invention discloses a preparation method of graphene antibacterial cool slub yarn, wherein the yarn consists of 30 parts by weight of graphene nylon composite fiber, 20 parts of bamboo fiber, and 10 parts of viscose fiber, and the fiber is passed through a ring ingot.
  • the spinning machine spinning process is spun into a slub yarn; the process comprises the following process steps: mixing cotton, carding, drawing, spinning, winding, the specific operation is as follows:
  • the cotton mixing and carding process adopting a continuous weighing computer with a color mixing process, manual weighing and weighing ⁇ mixing cotton ⁇ opening cotton ⁇ carding, continuous weighing and weighing feeding of the cotton mixing bin, and negative pressure extraction by the fan Soft and open.
  • Main parameters of the carding process the speed of the cotton machine is 400 rpm, the speed of the needle opening machine is 800 rpm, the speed of the roller is 10 r/min, the speed of the licking roller is 400 rpm, the speed of the cylinder is 300 rpm, and the cylinder of the cylinder is 3 points.
  • the distance is 0.19mm, 0.21mm, 0.24mm, and the dry strip is 10g/5m;
  • the drawing process the Trützschler HSR1000 draw frame is used, the main parameters of the process are two-way combination, the front zone spacing is 40mm, the rear zone spacing is 46mm, the rear zone drafting multiple is 1.0, and the delivery speed is 200m. /min, the draw ratio is 8, and the dry weight of the sliver is 8/5m;
  • the spinning process the slub yarn is spun by a JWFl 562E ring spinning machine, and the number of slub yarn counts is 12, 14, 16, 20, 21, 24, 30, 32, 40. ⁇ to Z ⁇ , the front roller speed is 140-220r ⁇ min -1 , and the front zone is drawn 15-40 times.
  • the single-layer graphene content of the graphene nylon composite fiber is 0.3%, the color is gray-black, and the viscose fiber overcomes the gray-black characteristic of the graphene nylon composite fiber, and the computer automatic color matching technology is designed and matched to make the yarn have a special level. Feeling.
  • the invention discloses a method for preparing graphene antibacterial cool slub yarn, wherein the yarn consists of 60 parts by weight of graphene nylon composite fiber, 30 parts of bamboo fiber, 20 parts of viscose fiber, and the fiber is passed through a ring ingot.
  • the spinning machine spinning process is spun into a slub yarn; the process comprises the following process steps: mixing cotton, carding, drawing, spinning, winding, the specific operation is as follows:
  • the cotton mixing and carding process adopting a continuous weighing computer with a color mixing process, manual weighing and weighing ⁇ mixing cotton ⁇ opening cotton ⁇ carding, continuous weighing and weighing feeding of the cotton mixing bin, and negative pressure extraction by the fan Soft and open.
  • Main parameters of the carding process the speed of the cotton machine is 500 rpm, the speed of the needle opening machine is 1000 rpm, the speed of the roller is 10 r/min, the speed of the licking roller is 500 rpm, the speed of the cylinder is 400 rpm, and the cylinder of the cylinder is 3 points.
  • the drawing process the Trützschler HSR1000 draw frame is used, the main parameters of the process are two-way combination, the front zone is 45mm, the rear zone is 53mm, the rear zone draw is 1.4, and the delivery speed is 230m. /min, the draw ratio is 9, and the dry weight of the sliver is 15/5m;
  • the spinning process the slub yarn is spun by a JWFl 562E ring spinning machine, and the number of slub yarns is 12, 14, 16, 20, 21, 24, 30, 32, 40. ⁇ to Z ⁇ , the front roller speed is 140-220r ⁇ min -1 , and the front zone is drawn 15-40 times.
  • the graphene nylon composite fiber has a single-layer graphene content of 0.8%, the color is gray-black, and the viscose fiber overcomes the characteristics of the gray color of the graphene nylon composite fiber, and adopts the computer automatic color matching technology to design and match the manner.
  • the yarn is given a special layering sensation.
  • the invention discloses a method for preparing graphene antibacterial cool slub yarn, which comprises 40 parts by weight of graphene nylon composite fiber, 27 parts of bamboo fiber and 13 parts of viscose fiber, and the fiber is passed through a ring ingot.
  • the spinning machine spinning process is spun into a slub yarn; the process comprises the following process steps: mixing cotton, carding, drawing, spinning, winding, the specific operation is as follows:
  • the cotton mixing and carding process adopting a continuous weighing computer with a color mixing process, manual weighing and weighing ⁇ mixing cotton ⁇ opening cotton ⁇ carding, continuous weighing and weighing feeding of the cotton mixing bin, and negative pressure extraction by the fan Soft and open.
  • Main parameters of the carding process the speed of the cotton machine is 460 rpm, the speed of the needle opening machine is 900 rpm, the speed of the roller is 10 r/min, the speed of the licking roller is 440 rpm, the speed of the cylinder is 370 rpm, and the cylinder of the cylinder is 3 points.
  • the distance is 0.19mm, 0.21mm, 0.24mm, and the dry weight of the raw strip is 18g/5m;
  • the drawing process using Trützschler HSR1000 draw frame, the main parameters of the process, using two passes, the front zone gauge is 42mm, the rear zone is 49mm, the rear zone draw ratio is 1.3, and the delivery speed is 210m. /min, the draw ratio is 8, and the dry weight of the sliver is 11/5m;
  • the spinning process the slub yarn is spun by a JWFl 562E ring spinning machine, and the number of slub yarns is 12, 14, 16, 20, 21, 24, 30, 32, 40. ⁇ to Z ⁇ , the front roller speed is 170r ⁇ min -1 , and the front zone is drawn 30 times.
  • the single-layer graphene content of the graphene nylon composite fiber is 0.6%, the color is gray-black, and the viscose fiber overcomes the gray-black characteristic of the graphene nylon composite fiber, and the computer automatic color matching technology is designed and matched to make the yarn have a special level. Feeling.
  • the graphene antibacterial cool slub yarn obtained by the invention is blended by a plurality of functional fibers, and the advantages of the fibers used in the collection are compared. Compared with the conventional cotton yarn, the viscose is superior to the natural cotton fiber in softness, moisture absorption and light weight performance. With bamboo fiber antibacterial cooling and other properties, while using new graphene nylon composite fiber Antistatic, antibacterial, antimony, cool, soft and comfortable properties.
  • the yarn prepared by the invention is applied to the home textile, and the home textile product has a layered feeling, a three-dimensional feeling, and has multiple functions at the same time.
  • the visual sense of the slub yarn and the fabric thereof and the visual sense are provided by a black-gray graphene nylon composite fiber, a natural color or a color bamboo fiber, and a viscose fiber through a computer color mixing system.
  • the main antibacterial, antimony, antistatic, cool and other functions of the slub yarn and its fabric are provided by graphene nylon composite fiber.
  • graphene nylon composite fiber For traditional inorganic and organic antibacterial agents, graphene is not cytotoxic, and is more suitable for Direct contact with human skin, graphene nylon composite fiber.
  • the secondary antibacterial property and coolness of the slub yarn and its fabric are reinforced by bamboo fibers.
  • the softness, comfort, breathability, sweat absorption and the like of the slub yarn and its fabric are mainly supported by viscose fibers.
  • the yarn prepared by the invention is prepared into a summer home textile fabric, and the relevant test indexes of the obtained fabric are as follows:

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Botany (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Preliminary Treatment Of Fibers (AREA)
  • Spinning Or Twisting Of Yarns (AREA)

Abstract

Provided is a manufacturing method of a graphene-containing slubby yarn having antimicrobial and cooling properties. The yarn comprises the following components in parts by weight of: 30-60 parts of a graphene-nylon composite fiber; 20-30 parts of a bamboo fiber; and 10-20 parts of a viscose. The above fibers are spun into a slubby yarn by means of a ring spinning machine. The manufacturing method comprises the following steps: cotton blending; carding; drawing; spinning; and spooling. The graphene-containing slubby yarn having antimicrobial and cooling properties is formed by blending and spinning multiple fibers having different properties, and thus has advantages of these fibers. Compared with conventional cotton yarns, the viscose enables the graphene-containing slubby yarn to have superior performance to natural cotton fibers in various aspects including softness, dampness absorption and weight. The present invention has antimicrobial and cooling properties of a bamboo fiber, and use of a novel graphene-nylon composite fiber enhances antistatic properties, antimicrobial and cooling performance, softness and comfort. When the above yarn is applied in a home textile item, the finished home textile item has a good layering effect, produces favorable sense of depth, and has many functional properties.

Description

一种石墨烯抗菌凉爽竹节纱的制备方法及其在家纺产品中的应用Preparation method of graphene antibacterial cool slub yarn and application thereof in spinning products 技术领域Technical field
本发明属于新型材料混纺纱线领域，具体涉及一种石墨烯抗菌凉爽竹节纱的制备方法及其在家纺产品中应用。The invention belongs to the field of novel material blended yarns, and particularly relates to a preparation method of graphene antibacterial cool slub yarn and application in the home textile product.
背景技术Background technique
石墨烯复合纤维材料近年来成为研究热点，目前对石墨烯复合纤维材料的潜在应用已有大量研究，如储能材料、转换设备、传感器、导线等。石墨烯具有优异的抗菌性能及热传导性，将石墨烯整理到织物上，即可制备抗菌织物，相对于传统的无机、有机抗菌剂，石墨烯基本没有细胞毒性，更适合与人体皮肤直接接触。但是，由于石墨烯与纺织品之间缺乏亲和力，因此很难通过传统工艺将石墨烯处理到纺织品上。Graphene composite fiber materials have become a research hotspot in recent years. At present, there are a lot of researches on the potential applications of graphene composite fiber materials, such as energy storage materials, conversion equipment, sensors, wires and so on. Graphene has excellent antibacterial properties and thermal conductivity. When graphene is finished on fabric, antibacterial fabric can be prepared. Compared with traditional inorganic and organic antibacterial agents, graphene has no cytotoxicity and is more suitable for direct contact with human skin. However, due to the lack of affinity between graphene and textiles, it is difficult to process graphene onto textiles by conventional processes.
发明内容Summary of the invention
发明目的：为了解决现有技术的不足，本发明提供了一种石墨烯抗菌凉爽竹节纱的制备方法及其在家纺产品中应用,该纱线可应用于家纺产品。该纱线由石墨烯锦纶复合纤维、竹纤维，粘胶纤维组成，将上述纤维通过细纱工艺纺成竹节纱。本发明得到的石墨烯抗菌凉爽竹节纱由多种功能纤维混纺而成，集所用纤维的优点于一身，与传统棉纱相比，具有粘胶柔软、吸湿、自重轻性能，竹纤维抗菌凉爽，同时新型石墨烯锦纶复合纤维抗静电、抗菌、抗螨、凉爽、柔软等性能。OBJECT OF THE INVENTION In order to solve the deficiencies of the prior art, the present invention provides a method for preparing a graphene antibacterial cool slub yarn and an application thereof in a home textile product, which can be applied to a home textile product. The yarn is composed of graphene nylon composite fiber, bamboo fiber, viscose fiber, and the above fiber is spun into a slub yarn by a spun yarn process. The graphene antibacterial cool slub yarn obtained by the invention is blended by a plurality of functional fibers, and the advantages of the fibers used in the collection are all in one body. Compared with the traditional cotton yarn, the adhesive has softness, moisture absorption and light weight performance, and the bamboo fiber is antibacterial and cool. At the same time, the new graphene nylon composite fiber has antistatic, antibacterial, anti-caries, cool and soft properties.
技术方案：一种石墨烯抗菌凉爽竹节纱的制备方法，该纱线由重量份数为30-60份的石墨烯锦纶复合纤维、20-30份的竹纤维，10-20份的粘胶纤维组成，将上述纤维通过环锭细纱机纺工艺纺成竹节纱；该工艺包括如下工艺步骤：混 棉、梳棉、并条、细纱、络筒，具体操作如下：Technical Solution: A method for preparing graphene antibacterial cool slub yarn, the yarn is composed of 30-60 parts by weight of graphene nylon composite fiber, 20-30 parts of bamboo fiber, 10-20 parts of viscose a fiber composition, the above fiber is spun into a slub yarn by a ring spinning machine spinning process; the process comprises the following process steps: mixing Cotton, carding, drawing, spinning, winding, the specific operation is as follows:
所述混棉、梳棉工序：采用连续称重电脑配比色混纺工艺，人工配比称重→混棉→开棉→梳棉，混棉仓连续称重定量喂入，通过风机负压抽取柔和开松。梳棉工序主要参数，抓棉机开松打手转速400～500rpm，梳针开棉机打手转速800～1000rpm，成卷罗拉转速10r/min，刺辊转速400～500rpm，锡林转速300～400rpm，锡林-盖板3点隔距0.19mm、0.21mm、0.24mm，生条干定量10～20g/5m；The cotton mixing and carding process: adopting a continuous weighing computer with a color mixing process, manual weighing and weighing→mixing cotton→opening cotton→carding, continuous weighing and weighing feeding of the cotton mixing bin, and negative pressure extraction by the fan Soft and open. The main parameters of the carding process, the speed of the cotton picker is 400-500 rpm, the speed of the needle opener is 800-1000 rpm, the speed of the roll is 10 r/min, the speed of the licking roll is 400-500 rpm, and the speed of the cylinder is 300-400 rpm. The cylinder-cover 3 points are 0.19mm, 0.21mm, 0.24mm, and the dry strips are 10~20g/5m;
所述并条工序：采用特吕茨勒HSR1000型并条机，工序主要参数，采用二道并合，前区隔距40-45mm，后区隔距46-53mm，后区牵伸倍数1.0-1.4，出条速度200-230m/min，牵伸倍数8-9，条子干重8-15/5m；The drawing process: using Trützschler HSR1000 type draw frame, the main parameters of the process, using two-way combination, the front zone gauge is 40-45mm, the rear zone gauge is 46-53mm, and the rear zone drafting multiple is 1.0- 1.4, the delivery speed is 200-230m/min, the draw ratio is 8-9, and the dry weight of the sliver is 8-15/5m;
所述细纱工序：采用JWFl 562E环锭细纱机纺制竹节纱，竹节纱支数12支、14支、16支、20支、21支、24支、30支、32支、40支。捻向Z捻，前罗拉速度140-220r·min-1，前区牵伸15-40倍。The spinning process: the slub yarn is spun by a JWFl 562E ring spinning machine, and the number of slub yarns is 12, 14, 16, 20, 21, 24, 30, 32, 40.捻 to Z捻, the front roller speed is 140-220r·min -1 , and the front zone is drawn 15-40 times.
作为优化：所述石墨烯锦纶复合纤维单层石墨烯含量为0.3-0.8％，颜色为灰黑色，粘胶纤维克服石墨烯锦纶复合纤维灰黑的特性，采用电脑自动配色技术设计搭配方式使得纱线呈现特殊的层次朦胧感。As an optimization: the graphene nylon composite fiber has a single-layer graphene content of 0.3-0.8%, the color is gray-black, and the viscose fiber overcomes the characteristics of the gray color of the graphene nylon composite fiber, and adopts a computer automatic color matching technology to design and match the yarn. The line presents a special level of guilt.
作为优化：所述石墨烯锦纶复合纤维也可用石墨烯涤纶复合纤维替代。As an optimization: the graphene nylon composite fiber can also be replaced by a graphene polyester composite fiber.
作为优化：所述竹纤维、粘胶纤维采用有色纤维，通过配色，设计段彩竹节纱。As an optimization: the bamboo fiber and the viscose fiber are colored fibers, and the color bamboo yarn is designed by color matching.
作为优化：所述并条机工序采用三道并条工序，8根喂入。As an optimization: the draw frame process uses three parallel steps and eight feeds.
作为优化：所述细纱工序为减少缠绕采用皮辊专用抗静电剂处理胶辊；运用镀氟钢领、钢丝圈。As an optimization: the spinning process is to reduce the winding by using a special antistatic agent for the roller to process the rubber roller; using a fluorine-plated steel collar and a wire ring.
作为优化：所述染整工序采用凉爽感整理，进一步强化面料的手感及触感。As an optimization: the dyeing and finishing process is finished with a cool feeling, further enhancing the feel and feel of the fabric.
一种根据所述的石墨烯抗菌凉爽竹节纱的制备方法制备出的竹节纱在家纺 产品中的应用，所制备的石墨烯抗菌凉爽竹节纱经过织造、染整制成面料用于家纺。Slub yarn prepared according to the preparation method of the graphene antibacterial cool slub yarn In the application of the product, the prepared graphene antibacterial cool slub yarn is woven, dyed and finished into a fabric for home textile.
有益效果：本发明得到的石墨烯抗菌凉爽竹节纱由多种功能纤维混纺而成，集所用纤维的优点于一身，与传统棉纱相比，具有粘胶优于天然棉纤维的柔软、吸湿、自重轻性能，具有竹纤维抗菌凉爽等性能，同时采用新型石墨烯锦纶复合纤维强化抗静电、抗菌、除螨、凉爽柔软舒适等性能。本发明制备的纱线应用到家纺上，家纺成品富有层次感、立体感，同时具有多项功能性。Advantageous Effects: The graphene antibacterial cool slub yarn obtained by the invention is blended by a plurality of functional fibers, and the advantages of the fibers used in the collection are compared, and the viscose is superior to the natural cotton fiber in softness and moisture absorption compared with the conventional cotton yarn. Self-weight and light performance, with bamboo fiber antibacterial cooling and other properties, while using new graphene nylon composite fiber to enhance antistatic, antibacterial, antimony, cool and soft and comfortable properties. The yarn prepared by the invention is applied to the home textile, and the home textile product has a layered feeling, a three-dimensional feeling, and has multiple functions at the same time.
本发明中竹节纱及其面料的层次感、立体感等视觉感官由黑灰色石墨烯锦纶复合纤维及本色或彩色竹纤维、粘胶纤维通过电脑混色系统提供。In the present invention, the visual sense of the slub yarn and the fabric thereof and the visual sense are provided by a black-gray graphene nylon composite fiber, a natural color or a color bamboo fiber, and a viscose fiber through a computer color mixing system.
本发明中竹节纱及其面料的主要抗菌、除螨、抗静电、凉爽等功能性由石墨烯锦纶复合纤维提供，对于传统的无机、有机抗菌剂，石墨烯基本没有细胞毒性，更适合与人体皮肤直接接触，石墨烯锦纶复合纤维。The main antibacterial, antimony, antistatic, cool and other functions of the slub yarn and its fabric are provided by graphene nylon composite fiber. For traditional inorganic and organic antibacterial agents, graphene is not cytotoxic, and is more suitable for Direct contact with human skin, graphene nylon composite fiber.
本发明中竹节纱及其面料的次要抗菌性、凉爽性由竹纤维强化。In the present invention, the secondary antibacterial property and coolness of the slub yarn and its fabric are reinforced by bamboo fibers.
本发明中竹节纱及其面料的柔软、舒适、透气、吸汗等触感性能主要由粘胶纤维支持。In the present invention, the softness, comfort, breathability, sweat absorption and the like of the slub yarn and its fabric are mainly supported by viscose fibers.
本发明将制得的纱线制备成夏季家纺面料，所得织物的相关测试指标如下：尺寸变化率：经向-2.8％，纬向-2.8％；强力：329.8N染色牢度：耐洗(变色、沾色)3-4级；防螨性能：95％；抗静电性能：垂直电阻小于100Ω；接触冷感(q.max)：0.306W/cm2。The yarn prepared by the invention is prepared into a summer home textile fabric, and the relevant test indexes of the obtained fabric are as follows: dimensional change rate: warp direction -2.8%, weft direction -2.8%; strength: 329.8N color fastness: washable (discoloration , staining) 3-4 grade; anti-mite performance: 95%; antistatic performance: vertical resistance is less than 100Ω; contact cold feeling (q.max): 0.306W / cm 2 .
具体实施方式Detailed ways
下面将对本发明实施例中的技术方案进行清楚、完整地描述，以使本领域的技术人员能够更好的理解本发明的优点和特征，从而对本发明的保护范围做出更为清楚的界定。本发明所描述的实施例仅仅是本发明一部分实施例，而不 是全部的实施例，基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动的前提下所获得的所有其他实施例，都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described in the following, so that those skilled in the art can better understand the advantages and features of the present invention, and the scope of the present invention is more clearly defined. The described embodiments of the present invention are only a part of embodiments of the present invention, and are not All of the other embodiments obtained by those skilled in the art based on the embodiments of the present invention without creative efforts are within the scope of the present invention.
作为综述，本发明中所述石墨烯锦纶复合纤维也可用石墨烯涤纶复合纤维替代。所述竹纤维、粘胶纤维采用有色纤维，通过配色，设计段彩竹节纱。所述并条机工序采用三道并条工序，8根喂入。所述细纱工序为减少缠绕采用皮辊专用抗静电剂处理胶辊；运用镀氟钢领、钢丝圈。所述染整工序采用凉爽感整理，进一步强化面料的手感及触感。As a review, the graphene nylon composite fiber described in the present invention may also be replaced with a graphene polyester composite fiber. The bamboo fiber and the viscose fiber are colored fibers, and the color bamboo yarn is designed by color matching. The draw frame process uses three parallel steps and eight feeds. The spinning process is to reduce the winding by using a special antistatic agent for the roller to process the rubber roller; using a fluorine-plated steel collar and a wire ring. The dyeing and finishing process is finished with a cool feeling to further strengthen the feel and feel of the fabric.
根据所述的石墨烯抗菌凉爽竹节纱的制备方法，所制备的石墨烯抗菌凉爽竹节纱经过织造、染整制成面料应用于家纺产品中。According to the preparation method of the graphene antibacterial cool slub yarn, the prepared graphene antibacterial cool slub yarn is woven, dyed and finished into a fabric for use in home textile products.
具体实施例1Specific embodiment 1
一种石墨烯抗菌凉爽竹节纱的制备方法，该纱线由重量份数为30份的石墨烯锦纶复合纤维、20份的竹纤维，10份的粘胶纤维组成，将上述纤维通过环锭细纱机纺工艺纺成竹节纱；该工艺包括如下工艺步骤：混棉、梳棉、并条、细纱、络筒，具体操作如下：The invention discloses a preparation method of graphene antibacterial cool slub yarn, wherein the yarn consists of 30 parts by weight of graphene nylon composite fiber, 20 parts of bamboo fiber, and 10 parts of viscose fiber, and the fiber is passed through a ring ingot. The spinning machine spinning process is spun into a slub yarn; the process comprises the following process steps: mixing cotton, carding, drawing, spinning, winding, the specific operation is as follows:
所述混棉、梳棉工序：采用连续称重电脑配比色混纺工艺，人工配比称重→混棉→开棉→梳棉，混棉仓连续称重定量喂入，通过风机负压抽取柔和开松。梳棉工序主要参数，抓棉机开松打手转速400rpm，梳针开棉机打手转速800rpm，成卷罗拉转速10r/min，刺辊转速400rpm，锡林转速300rpm，锡林-盖板3点隔距0.19mm、0.21mm、0.24mm，生条干定量10g/5m；The cotton mixing and carding process: adopting a continuous weighing computer with a color mixing process, manual weighing and weighing→mixing cotton→opening cotton→carding, continuous weighing and weighing feeding of the cotton mixing bin, and negative pressure extraction by the fan Soft and open. Main parameters of the carding process, the speed of the cotton machine is 400 rpm, the speed of the needle opening machine is 800 rpm, the speed of the roller is 10 r/min, the speed of the licking roller is 400 rpm, the speed of the cylinder is 300 rpm, and the cylinder of the cylinder is 3 points. The distance is 0.19mm, 0.21mm, 0.24mm, and the dry strip is 10g/5m;
所述并条工序：采用特吕茨勒HSR1000型并条机，工序主要参数，采用二道并合，前区隔距40mm，后区隔距46mm，后区牵伸倍数1.0，出条速度200m/min，牵伸倍数8，条子干重8/5m；The drawing process: the Trützschler HSR1000 draw frame is used, the main parameters of the process are two-way combination, the front zone spacing is 40mm, the rear zone spacing is 46mm, the rear zone drafting multiple is 1.0, and the delivery speed is 200m. /min, the draw ratio is 8, and the dry weight of the sliver is 8/5m;
所述细纱工序：采用JWFl 562E环锭细纱机纺制竹节纱，竹节纱支数12支、 14支、16支、20支、21支、24支、30支、32支、40支。捻向Z捻，前罗拉速度140-220r·min-1，前区牵伸15-40倍。The spinning process: the slub yarn is spun by a JWFl 562E ring spinning machine, and the number of slub yarn counts is 12, 14, 16, 20, 21, 24, 30, 32, 40.捻 to Z捻, the front roller speed is 140-220r·min -1 , and the front zone is drawn 15-40 times.
所述石墨烯锦纶复合纤维单层石墨烯含量为0.3％，颜色为灰黑色，粘胶纤维克服石墨烯锦纶复合纤维灰黑的特性，采用电脑自动配色技术设计搭配方式使得纱线呈现特殊的层次朦胧感。The single-layer graphene content of the graphene nylon composite fiber is 0.3%, the color is gray-black, and the viscose fiber overcomes the gray-black characteristic of the graphene nylon composite fiber, and the computer automatic color matching technology is designed and matched to make the yarn have a special level. Feeling.
具体实施例2Specific embodiment 2
一种石墨烯抗菌凉爽竹节纱的制备方法，该纱线由重量份数为60份的石墨烯锦纶复合纤维、30份的竹纤维，20份的粘胶纤维组成，将上述纤维通过环锭细纱机纺工艺纺成竹节纱；该工艺包括如下工艺步骤：混棉、梳棉、并条、细纱、络筒，具体操作如下：The invention discloses a method for preparing graphene antibacterial cool slub yarn, wherein the yarn consists of 60 parts by weight of graphene nylon composite fiber, 30 parts of bamboo fiber, 20 parts of viscose fiber, and the fiber is passed through a ring ingot. The spinning machine spinning process is spun into a slub yarn; the process comprises the following process steps: mixing cotton, carding, drawing, spinning, winding, the specific operation is as follows:
所述混棉、梳棉工序：采用连续称重电脑配比色混纺工艺，人工配比称重→混棉→开棉→梳棉，混棉仓连续称重定量喂入，通过风机负压抽取柔和开松。梳棉工序主要参数，抓棉机开松打手转速500rpm，梳针开棉机打手转速1000rpm，成卷罗拉转速10r/min，刺辊转速500rpm，锡林转速400rpm，锡林-盖板3点隔距0.19mm、0.21mm、0.24mm，生条干定量20g/5m；The cotton mixing and carding process: adopting a continuous weighing computer with a color mixing process, manual weighing and weighing→mixing cotton→opening cotton→carding, continuous weighing and weighing feeding of the cotton mixing bin, and negative pressure extraction by the fan Soft and open. Main parameters of the carding process, the speed of the cotton machine is 500 rpm, the speed of the needle opening machine is 1000 rpm, the speed of the roller is 10 r/min, the speed of the licking roller is 500 rpm, the speed of the cylinder is 400 rpm, and the cylinder of the cylinder is 3 points. Distance 0.19mm, 0.21mm, 0.24mm, dry strips quantitative 20g/5m;
所述并条工序：采用特吕茨勒HSR1000型并条机，工序主要参数，采用二道并合，前区隔距45mm，后区隔距53mm，后区牵伸倍数1.4，出条速度230m/min，牵伸倍数9，条子干重15/5m；The drawing process: the Trützschler HSR1000 draw frame is used, the main parameters of the process are two-way combination, the front zone is 45mm, the rear zone is 53mm, the rear zone draw is 1.4, and the delivery speed is 230m. /min, the draw ratio is 9, and the dry weight of the sliver is 15/5m;
所述细纱工序：采用JWFl 562E环锭细纱机纺制竹节纱，竹节纱支数12支、14支、16支、20支、21支、24支、30支、32支、40支。捻向Z捻，前罗拉速度140-220r·min-1，前区牵伸15-40倍。The spinning process: the slub yarn is spun by a JWFl 562E ring spinning machine, and the number of slub yarns is 12, 14, 16, 20, 21, 24, 30, 32, 40.捻 to Z捻, the front roller speed is 140-220r·min -1 , and the front zone is drawn 15-40 times.
所述石墨烯锦纶复合纤维单层石墨烯含量为0.8％，颜色为灰黑色，粘胶纤维克服石墨烯锦纶复合纤维灰黑的特性，采用电脑自动配色技术设计搭配方式 使得纱线呈现特殊的层次朦胧感。The graphene nylon composite fiber has a single-layer graphene content of 0.8%, the color is gray-black, and the viscose fiber overcomes the characteristics of the gray color of the graphene nylon composite fiber, and adopts the computer automatic color matching technology to design and match the manner. The yarn is given a special layering sensation.
具体实施例3Specific embodiment 3
一种石墨烯抗菌凉爽竹节纱的制备方法，该纱线由重量份数为40份的石墨烯锦纶复合纤维、27份的竹纤维，13份的粘胶纤维组成，将上述纤维通过环锭细纱机纺工艺纺成竹节纱；该工艺包括如下工艺步骤：混棉、梳棉、并条、细纱、络筒，具体操作如下：The invention discloses a method for preparing graphene antibacterial cool slub yarn, which comprises 40 parts by weight of graphene nylon composite fiber, 27 parts of bamboo fiber and 13 parts of viscose fiber, and the fiber is passed through a ring ingot. The spinning machine spinning process is spun into a slub yarn; the process comprises the following process steps: mixing cotton, carding, drawing, spinning, winding, the specific operation is as follows:
所述混棉、梳棉工序：采用连续称重电脑配比色混纺工艺，人工配比称重→混棉→开棉→梳棉，混棉仓连续称重定量喂入，通过风机负压抽取柔和开松。梳棉工序主要参数，抓棉机开松打手转速460rpm，梳针开棉机打手转速900rpm，成卷罗拉转速10r/min，刺辊转速440rpm，锡林转速370rpm，锡林-盖板3点隔距0.19mm、0.21mm、0.24mm，生条干定量18g/5m；The cotton mixing and carding process: adopting a continuous weighing computer with a color mixing process, manual weighing and weighing→mixing cotton→opening cotton→carding, continuous weighing and weighing feeding of the cotton mixing bin, and negative pressure extraction by the fan Soft and open. Main parameters of the carding process, the speed of the cotton machine is 460 rpm, the speed of the needle opening machine is 900 rpm, the speed of the roller is 10 r/min, the speed of the licking roller is 440 rpm, the speed of the cylinder is 370 rpm, and the cylinder of the cylinder is 3 points. The distance is 0.19mm, 0.21mm, 0.24mm, and the dry weight of the raw strip is 18g/5m;
所述并条工序：采用特吕茨勒HSR1000型并条机，工序主要参数，采用二道并合，前区隔距42mm，后区隔距49mm，后区牵伸倍数1.3，出条速度210m/min，牵伸倍数8，条子干重11/5m；The drawing process: using Trützschler HSR1000 draw frame, the main parameters of the process, using two passes, the front zone gauge is 42mm, the rear zone is 49mm, the rear zone draw ratio is 1.3, and the delivery speed is 210m. /min, the draw ratio is 8, and the dry weight of the sliver is 11/5m;
所述细纱工序：采用JWFl 562E环锭细纱机纺制竹节纱，竹节纱支数12支、14支、16支、20支、21支、24支、30支、32支、40支。捻向Z捻，前罗拉速度170r·min-1，前区牵伸30倍。The spinning process: the slub yarn is spun by a JWFl 562E ring spinning machine, and the number of slub yarns is 12, 14, 16, 20, 21, 24, 30, 32, 40.捻 to Z捻, the front roller speed is 170r·min -1 , and the front zone is drawn 30 times.
所述石墨烯锦纶复合纤维单层石墨烯含量为0.6％，颜色为灰黑色，粘胶纤维克服石墨烯锦纶复合纤维灰黑的特性，采用电脑自动配色技术设计搭配方式使得纱线呈现特殊的层次朦胧感。The single-layer graphene content of the graphene nylon composite fiber is 0.6%, the color is gray-black, and the viscose fiber overcomes the gray-black characteristic of the graphene nylon composite fiber, and the computer automatic color matching technology is designed and matched to make the yarn have a special level. Feeling.
本发明得到的石墨烯抗菌凉爽竹节纱由多种功能纤维混纺而成，集所用纤维的优点于一身，与传统棉纱相比，具有粘胶优于天然棉纤维的柔软、吸湿、自重轻性能，具有竹纤维抗菌凉爽等性能，同时采用新型石墨烯锦纶复合纤维强 化抗静电、抗菌、除螨、凉爽柔软舒适等性能。本发明制备的纱线应用到家纺上，家纺成品富有层次感、立体感，同时具有多项功能性。The graphene antibacterial cool slub yarn obtained by the invention is blended by a plurality of functional fibers, and the advantages of the fibers used in the collection are compared. Compared with the conventional cotton yarn, the viscose is superior to the natural cotton fiber in softness, moisture absorption and light weight performance. With bamboo fiber antibacterial cooling and other properties, while using new graphene nylon composite fiber Antistatic, antibacterial, antimony, cool, soft and comfortable properties. The yarn prepared by the invention is applied to the home textile, and the home textile product has a layered feeling, a three-dimensional feeling, and has multiple functions at the same time.
本发明中竹节纱及其面料的层次感、立体感等视觉感官由黑灰色石墨烯锦纶复合纤维及本色或彩色竹纤维、粘胶纤维通过电脑混色系统提供。In the present invention, the visual sense of the slub yarn and the fabric thereof and the visual sense are provided by a black-gray graphene nylon composite fiber, a natural color or a color bamboo fiber, and a viscose fiber through a computer color mixing system.
本发明中竹节纱及其面料的主要抗菌、除螨、抗静电、凉爽等功能性由石墨烯锦纶复合纤维提供，对于传统的无机、有机抗菌剂，石墨烯基本没有细胞毒性，更适合与人体皮肤直接接触，石墨烯锦纶复合纤维。The main antibacterial, antimony, antistatic, cool and other functions of the slub yarn and its fabric are provided by graphene nylon composite fiber. For traditional inorganic and organic antibacterial agents, graphene is not cytotoxic, and is more suitable for Direct contact with human skin, graphene nylon composite fiber.
本发明中竹节纱及其面料的次要抗菌性、凉爽性由竹纤维强化。In the present invention, the secondary antibacterial property and coolness of the slub yarn and its fabric are reinforced by bamboo fibers.
本发明中竹节纱及其面料的柔软、舒适、透气、吸汗等触感性能主要由粘胶纤维支持。In the present invention, the softness, comfort, breathability, sweat absorption and the like of the slub yarn and its fabric are mainly supported by viscose fibers.
本发明将制得的纱线制备成夏季家纺面料，所得织物的相关测试指标如下：The yarn prepared by the invention is prepared into a summer home textile fabric, and the relevant test indexes of the obtained fabric are as follows:
尺寸变化率：经向-2.8％，纬向-2.8％；强力：329.8N染色牢度：耐洗(变色、沾色)3-4级；防螨性能：95％；抗静电性能：垂直电阻小于100Ω；接触冷感(q.max)：0.306W/cm2。 Dimensional change rate: warp-2.8%, weft-2.8%; strength: 329.8N color fastness: washable (discoloration, staining) 3-4 grade; anti-mite performance: 95%; antistatic property: vertical resistance Less than 100 Ω; contact cold feeling (q. max): 0.306 W/cm 2 .

Claims (8)

  1. 一种石墨烯抗菌凉爽竹节纱的制备方法，其特征在于：该纱线由重量份数为30-60份的石墨烯锦纶复合纤维、20-30份的竹纤维，10-20份的粘胶纤维组成，将上述纤维通过环锭细纱机纺工艺纺成竹节纱；该工艺包括如下工艺步骤：混棉、梳棉、并条、细纱、络筒，具体操作如下：The invention discloses a method for preparing graphene antibacterial cool slub yarn, which is characterized in that: the yarn is composed of 30-60 parts by weight of graphene nylon composite fiber, 20-30 parts of bamboo fiber, 10-20 parts of sticky The composition of the rubber fiber, the fiber is spun into a slub yarn by a ring spinning machine spinning process; the process comprises the following process steps: mixing cotton, carding, drawing, spinning, winding, the specific operation is as follows:
    所述混棉、梳棉工序：采用连续称重电脑配比色混纺工艺，人工配比称重→混棉→开棉→梳棉，混棉仓连续称重定量喂入，通过风机负压抽取柔和开松。梳棉工序主要参数，抓棉机开松打手转速400～500rpm，梳针开棉机打手转速800～1000rpm，成卷罗拉转速10r/min，刺辊转速400～500rpm，锡林转速300～400rpm，锡林-盖板3点隔距0.19mm、0.21mm、0.24mm，生条干定量10～20g/5m；The cotton mixing and carding process: adopting a continuous weighing computer with a color mixing process, manual weighing and weighing→mixing cotton→opening cotton→carding, continuous weighing and weighing feeding of the cotton mixing bin, and negative pressure extraction by the fan Soft and open. The main parameters of the carding process, the speed of the cotton picker is 400-500 rpm, the speed of the needle opener is 800-1000 rpm, the speed of the roll is 10 r/min, the speed of the licking roll is 400-500 rpm, and the speed of the cylinder is 300-400 rpm. The cylinder-cover 3 points are 0.19mm, 0.21mm, 0.24mm, and the dry strips are 10~20g/5m;
    所述并条工序：采用特吕茨勒HSR1000型并条机，工序主要参数，采用二道并合，前区隔距40-45mm，后区隔距46-53mm，后区牵伸倍数1.0-1.4，出条速度200-230m/min，牵伸倍数8-9，条子干重8-15/5m；The drawing process: using Trützschler HSR1000 type draw frame, the main parameters of the process, using two-way combination, the front zone gauge is 40-45mm, the rear zone gauge is 46-53mm, and the rear zone drafting multiple is 1.0- 1.4, the delivery speed is 200-230m/min, the draw ratio is 8-9, and the dry weight of the sliver is 8-15/5m;
    所述细纱工序：采用JWFl 562E环锭细纱机纺制竹节纱，竹节纱支数12支、14支、16支、20支、21支、24支、30支、32支、40支。捻向Z捻，前罗拉速度140-220r·min-1，前区牵伸15-40倍。The spinning process: the slub yarn is spun by a JWFl 562E ring spinning machine, and the number of slub yarns is 12, 14, 16, 20, 21, 24, 30, 32, 40.捻 to Z捻, the front roller speed is 140-220r·min -1 , and the front zone is drawn 15-40 times.
  2. 根据权利要求1所述的石墨烯抗菌凉爽竹节纱的制备方法，其特征在于：所述石墨烯锦纶复合纤维单层石墨烯含量为0.3-0.8％，颜色为灰黑色，粘胶纤维克服石墨烯锦纶复合纤维灰黑的特性，采用电脑自动配色技术设计搭配方式使得纱线呈现特殊的层次朦胧感。The method for preparing a graphene antibacterial cool slub yarn according to claim 1, wherein the graphene nylon composite fiber has a single layer graphene content of 0.3-0.8%, the color is grayish black, and the viscose fiber overcomes graphite. The characteristics of the gray color of the olefinic composite fiber are designed and matched by the computer automatic color matching technology to make the yarn have a special layering feeling.
  3. 根据权利要求1所述的石墨烯抗菌凉爽竹节纱的制备方法，其特征在于：所述石墨烯锦纶复合纤维也可用石墨烯涤纶复合纤维替代。The method for preparing a graphene antibacterial cool slub yarn according to claim 1, wherein the graphene nylon composite fiber can also be replaced by a graphene polyester composite fiber.
  4. 根据权利要求1所述的石墨烯抗菌凉爽竹节纱的制备方法，其特征在于：所述竹纤维、粘胶纤维采用有色纤维，通过配色，设计段彩竹节纱。 The method for preparing a graphene antibacterial cool slub yarn according to claim 1, wherein the bamboo fiber and the viscose fiber are colored fibers, and the color bamboo yarn is designed by color matching.
  5. 根据权利要求1所述的石墨烯抗菌凉爽竹节纱的制备方法，其特征在于：所述并条机工序采用三道并条工序，8根喂入。The method for preparing a graphene antibacterial cool slub yarn according to claim 1, wherein the draw frame process is carried out by three parallel steps and eight feeds.
  6. 根据权利要求1所述的石墨烯抗菌凉爽竹节纱的制备方法，其特征在于：所述细纱工序为减少缠绕采用皮辊专用抗静电剂处理胶辊；运用镀氟钢领、钢丝圈。The method for preparing a graphene antibacterial cool slub yarn according to claim 1, wherein the spinning process is to reduce the winding by using a special antistatic agent for the roller, and to use a fluorine-plated steel collar and a wire ring.
  7. 根据权利要求1所述的石墨烯抗菌凉爽竹节纱的制备方法，其特征在于：所述染整工序采用凉爽感整理，进一步强化面料的手感及触感。The method for preparing a graphene antibacterial cool slub yarn according to claim 1, wherein the dyeing and finishing process is finished with a cool feeling to further enhance the feel and feel of the fabric.
  8. 一种根据权利要求1所述的石墨烯抗菌凉爽竹节纱的制备方法制备出的竹节纱在家纺产品中的应用，其特征在于：所制备的石墨烯抗菌凉爽竹节纱经过织造、染整制成面料用于家纺。 The utility model relates to a bamboo yarn produced by the method for preparing a graphene antibacterial cool slub yarn according to claim 1, wherein the prepared graphene antibacterial cool slub yarn is woven and dyed. The finished fabric is used for home textiles.
PCT/CN2017/108500 2017-06-21 2017-10-31 Manufacturing method of graphene-containing slubby yarn having antimicrobial and cooling properties, and application of same in home textile item WO2018233172A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2019501674A JP6778316B2 (en) 2017-06-21 2017-10-31 Manufacturing method of antibacterial refreshing slab yarn of graphene and application to household textile products

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201710473241.1 2017-06-21
CN201710473241.1A CN107268137A (en) 2017-06-21 2017-06-21 A kind of preparation method of the nice and cool slub of Graphene antibiosis and its application in home textile product

Publications (1)

Publication Number Publication Date
WO2018233172A1 true WO2018233172A1 (en) 2018-12-27

Family

ID=60068038

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2017/108500 WO2018233172A1 (en) 2017-06-21 2017-10-31 Manufacturing method of graphene-containing slubby yarn having antimicrobial and cooling properties, and application of same in home textile item

Country Status (3)

Country Link
JP (1) JP6778316B2 (en)
CN (1) CN107268137A (en)
WO (1) WO2018233172A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112941681A (en) * 2021-01-26 2021-06-11 滁州霞客无染彩色纺有限公司 Textile yarn with antistatic function

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107268137A (en) * 2017-06-21 2017-10-20 江苏工程职业技术学院 A kind of preparation method of the nice and cool slub of Graphene antibiosis and its application in home textile product
JP7342354B2 (en) * 2017-12-04 2023-09-12 大日本印刷株式会社 light irradiation device
CN108468122A (en) * 2018-02-07 2018-08-31 江苏工程职业技术学院 A kind of production technology of Novel cool flame-proof antibiotic home textile yarn
CN108442001A (en) * 2018-03-07 2018-08-24 如皋市丁堰纺织有限公司 A kind of antistatic high emulation cashmere blended yarn of fever antimicrobial form and its fabric
CN108866712A (en) * 2018-07-23 2018-11-23 临汾市广源织业有限公司 A kind of multifunctional textile fiber yarn
CN109137191A (en) * 2018-11-15 2019-01-04 罗莱生活科技股份有限公司 A kind of preparation method of the nice and cool yarn of Graphene antibiosis
CN109468724B (en) * 2019-01-08 2020-04-21 达利丝绸（浙江）有限公司 Production process of graphene and chinlon composite fiber and mulberry silk interwoven fabric
CN110512333A (en) * 2019-05-07 2019-11-29 常州兴烯石墨烯科技有限公司 A kind of preparation method of the warming straw mats of graphene far infrared heating
CN110528151A (en) * 2019-09-19 2019-12-03 河南新野纺织股份有限公司 A kind of modified viscose fabric of biomass graphene and its method for weaving
CN111270515A (en) * 2020-02-11 2020-06-12 任国峰 Graphene antibacterial fabric and preparation method thereof
CN111364142A (en) * 2020-02-28 2020-07-03 骏隆翔(厦门)纤维科技有限公司 Antibacterial breathable composite yarn and manufacturing method thereof
CN113862873A (en) * 2021-10-28 2021-12-31 正凯纺织有限公司 Multifunctional graphene/polyester-viscose interwoven fabric and preparation method thereof
CN115262043B (en) * 2022-08-30 2023-08-18 浙江烯禾纺织科技有限公司 Airflow carding device in graphene multi-dimensional flocculus production and processing method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103184603A (en) * 2011-12-31 2013-07-03 上海德福伦化纤有限公司 Novel supercool polyester fiber blended yarn and spinning method thereof
CN103225149A (en) * 2013-04-08 2013-07-31 盛宇家纺集团股份有限公司 Method for processing multi-fibre spun yarn and multi-fiber spun yarn processed through method
US20140050920A1 (en) * 2012-08-14 2014-02-20 Nthdegree Technologies Worldwide Inc. Graphene-Based Threads, Fibers or Yarns with Nth-Order Layers and Twisting and Methods of Fabricating Same
CN205474200U (en) * 2016-01-18 2016-08-17 上海奥领纺织新材料有限公司 Multi -functional yarn of graphene fiber blending
CN105951237A (en) * 2016-07-15 2016-09-21 义乌市麻尚生针织品有限公司 Blended yarn with hemp and cotton multifunctional fiber reinforced by graphene fiber
CN106319710A (en) * 2016-09-30 2017-01-11 无锡市长安曙光手套厂 Composite textile material and preparation method
CN107268137A (en) * 2017-06-21 2017-10-20 江苏工程职业技术学院 A kind of preparation method of the nice and cool slub of Graphene antibiosis and its application in home textile product

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100557106C (en) * 2003-02-27 2009-11-04 株洲雪松麻业有限责任公司 A kind of spinning that contains bamboo fiber and preparation method thereof
JP4179957B2 (en) * 2003-10-09 2008-11-12 日清紡績株式会社 Slab yarn and its manufacturing method
JP2005187430A (en) * 2003-12-26 2005-07-14 Shikibo Ltd Deodorizing agent and antibacterial agent composed of blast-crushed natural plant fiber
JP2008063686A (en) * 2006-09-06 2008-03-21 Unitika Textiles Ltd Composite spun yarn
KR101755044B1 (en) * 2009-03-16 2017-07-06 보르벡크 머터리얼스 코포레이션 Polymeric fibers and articles made therefrom
CN103290548A (en) * 2012-02-29 2013-09-11 江南大学 Method for producing segment-colored slub yarn through blending and siro spinning of dacron and viscose
CN102677247B (en) * 2012-05-03 2015-02-11 如皋市丁堰纺织有限公司 Method for producing multicolor composite slub or satin color yarn series, shell fabric and yarn
CN106757616A (en) * 2017-01-19 2017-05-31 青岛大学 The complex yarn and its preparation technology of a kind of new heat accumulation thermal antibacterial bacteriostatic

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103184603A (en) * 2011-12-31 2013-07-03 上海德福伦化纤有限公司 Novel supercool polyester fiber blended yarn and spinning method thereof
US20140050920A1 (en) * 2012-08-14 2014-02-20 Nthdegree Technologies Worldwide Inc. Graphene-Based Threads, Fibers or Yarns with Nth-Order Layers and Twisting and Methods of Fabricating Same
CN103225149A (en) * 2013-04-08 2013-07-31 盛宇家纺集团股份有限公司 Method for processing multi-fibre spun yarn and multi-fiber spun yarn processed through method
CN205474200U (en) * 2016-01-18 2016-08-17 上海奥领纺织新材料有限公司 Multi -functional yarn of graphene fiber blending
CN105951237A (en) * 2016-07-15 2016-09-21 义乌市麻尚生针织品有限公司 Blended yarn with hemp and cotton multifunctional fiber reinforced by graphene fiber
CN106319710A (en) * 2016-09-30 2017-01-11 无锡市长安曙光手套厂 Composite textile material and preparation method
CN107268137A (en) * 2017-06-21 2017-10-20 江苏工程职业技术学院 A kind of preparation method of the nice and cool slub of Graphene antibiosis and its application in home textile product

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112941681A (en) * 2021-01-26 2021-06-11 滁州霞客无染彩色纺有限公司 Textile yarn with antistatic function

Also Published As

Publication number Publication date
JP2019527306A (en) 2019-09-26
CN107268137A (en) 2017-10-20
JP6778316B2 (en) 2020-10-28

Similar Documents

Publication Publication Date Title
WO2018233172A1 (en) Manufacturing method of graphene-containing slubby yarn having antimicrobial and cooling properties, and application of same in home textile item
CN103603109A (en) Semi-worsted emerald pearl fiber blended healthcare yarn and production method and application thereof
CN103952824A (en) Cotton, ramie and bamboo blended grey yarns and production process thereof
CN103981613A (en) Far infrared hollow thermal yarns and processing method
CN102704097A (en) Spinning process of high-count combed yakwool pure woven yarns
CN103422211A (en) Multi-fiber color-mixed semi-worsted antibacterial yarns and spinning technology thereof
CN107083598A (en) A kind of half spinning double-colored long shusu paintball power slub and preparation method thereof
CN102634919A (en) Weaving method of jutecell/modal siro spinning functional fabric
CN107245785A (en) A kind of half spinning twin-core Duan coloured silks spin wrap yarn and preparation method thereof
CN107475882A (en) A kind of peppermint cotton blended knitted fabric and preparation method thereof
CN103741305B (en) Scribbled containing Herba Pileae Scriptae fiber and mint fibers and preparation method thereof
CN105019082B (en) A kind of bamboo fibre and acrylic fiber blending air vortex spinning product and its Weaving method
CN102505236A (en) Blended segment colored yarn manufacture method
CN103726155A (en) Jade fiber siro spinning cool antimicrobial yarn and spinning technology thereof
CN103422209A (en) Coffee carbon siro spinning heather yarn and spinning process thereof
CN102787409A (en) Compact siro yarn and preparation method thereof
CN102899904A (en) Cashmere sweater anti-pilling treatment agent
CN202688586U (en) White bamboo charcoal polyester fiber and viscose fiber blended yarn
CN103156302B (en) Aloe/viscose/modal function sweater and manufacture method thereof
CN104611797A (en) Wine red superfine denier yarn bamboo fiber and special-shaped colored polyester fiber blending product and spinning method thereof
CN103422210A (en) Functional hydroscopic and fast-dry heather yarn and spinning process thereof
CN103141962A (en) Jade fiber/bamboo fiber/modal functional sweater and manufacturing method thereof
CN115058810B (en) Modal, double-resistant acrylic fiber and mulberry silk fiber compact siro spinning process
CN105624861A (en) Cool sense-offered anti-bacteria type yarn and spinning technology thereof
CN104862842A (en) Novel blended yarn and production process thereof

Legal Events

Date Code Title Description
ENP Entry into the national phase

Ref document number: 2019501674

Country of ref document: JP

Kind code of ref document: A

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17914404

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 17914404

Country of ref document: EP

Kind code of ref document: A1