WO2014010561A1 - 二酸化炭素供給装置 - Google Patents
二酸化炭素供給装置 Download PDFInfo
- Publication number
- WO2014010561A1 WO2014010561A1 PCT/JP2013/068661 JP2013068661W WO2014010561A1 WO 2014010561 A1 WO2014010561 A1 WO 2014010561A1 JP 2013068661 W JP2013068661 W JP 2013068661W WO 2014010561 A1 WO2014010561 A1 WO 2014010561A1
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- WO
- WIPO (PCT)
- Prior art keywords
- heat
- carbon dioxide
- supply device
- refrigerator
- heat exchanger
- Prior art date
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 148
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 74
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 73
- 238000005057 refrigeration Methods 0.000 claims abstract description 37
- 238000010521 absorption reaction Methods 0.000 claims abstract description 29
- 239000012530 fluid Substances 0.000 claims abstract description 26
- 238000002485 combustion reaction Methods 0.000 claims abstract description 15
- 238000005338 heat storage Methods 0.000 claims description 56
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 48
- 238000001179 sorption measurement Methods 0.000 claims description 47
- 239000002274 desiccant Substances 0.000 claims description 17
- 238000003898 horticulture Methods 0.000 claims description 10
- 230000017525 heat dissipation Effects 0.000 claims description 7
- 230000006835 compression Effects 0.000 claims description 3
- 238000007906 compression Methods 0.000 claims description 3
- 239000007789 gas Substances 0.000 description 28
- 239000003507 refrigerant Substances 0.000 description 25
- 238000010438 heat treatment Methods 0.000 description 18
- 238000000034 method Methods 0.000 description 17
- 238000010586 diagram Methods 0.000 description 13
- 239000000446 fuel Substances 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 238000003795 desorption Methods 0.000 description 9
- 238000007791 dehumidification Methods 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- 239000000498 cooling water Substances 0.000 description 7
- 230000029553 photosynthesis Effects 0.000 description 7
- 238000010672 photosynthesis Methods 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 239000003463 adsorbent Substances 0.000 description 6
- 239000000567 combustion gas Substances 0.000 description 6
- 239000006096 absorbing agent Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000007664 blowing Methods 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 244000005700 microbiome Species 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 238000009423 ventilation Methods 0.000 description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- -1 but in general Chemical compound 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- AMXOYNBUYSYVKV-UHFFFAOYSA-M lithium bromide Chemical compound [Li+].[Br-] AMXOYNBUYSYVKV-UHFFFAOYSA-M 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 238000009834 vaporization Methods 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 235000012255 calcium oxide Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- IPLONMMJNGTUAI-UHFFFAOYSA-M lithium;bromide;hydrate Chemical compound [Li+].O.[Br-] IPLONMMJNGTUAI-UHFFFAOYSA-M 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000000629 steam reforming Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 230000026683 transduction Effects 0.000 description 1
- 238000010361 transduction Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G7/00—Botany in general
- A01G7/02—Treatment of plants with carbon dioxide
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G9/00—Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
- A01G9/18—Greenhouses for treating plants with carbon dioxide or the like
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G9/00—Cultivation in receptacles, forcing-frames or greenhouses; Edging for beds, lawn or the like
- A01G9/24—Devices or systems for heating, ventilating, regulating temperature, illuminating, or watering, in greenhouses, forcing-frames, or the like
- A01G9/246—Air-conditioning systems
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/25—Greenhouse technology, e.g. cooling systems therefor
Definitions
- the present invention relates to a carbon dioxide supply device for supplying carbon dioxide to be used for plant photosynthesis in a horticultural green house or the like.
- a heating boiler, a humidifier for adjusting humidity, and the like may be installed.
- CO2 carbon dioxide
- Patent Document 1 discloses a device that supplies combustion gas into a house with a fan. In such a device, heat at the time of combustion is also supplied into the house at the same time.
- a house that uses sunlight in a situation where solar heat is supplied too much during the day, the temperature inside the house rises due to unnecessary supply of combustion gas heat in addition to the CO2 required in the house.
- an environment suitable for plants cannot be realized. Therefore, in order to suppress the temperature rise, if the temperature and humidity adjustment opening / closing windows are opened, the temperature will decrease, but CO2 supplied by combustion will also be released to the outside at the same time, increasing the CO2 concentration. become unable.
- Patent Document 2 discloses a system for exchanging heat between exhaust gas and fluid to lower the exhaust gas temperature. However, after removing the heat generated together with CO2, it is only discarded in a cooling tower or the like, and there is a problem that the energy of the fuel cannot be effectively used.
- the present invention provides a carbon dioxide supply device that effectively uses heat generated when CO2 is supplied.
- the invention of claim 1 includes a combustor (1), a refrigerator (3), and an endothermic heat exchanger (6) through which a fluid cooled in a refrigeration cycle of the refrigerator (3) flows.
- the carbon dioxide supply apparatus comprising the above, when combusted in the combustor (1), the exhaust gas containing carbon dioxide is passed through the heat absorption heat exchanger (6) to be cooled and supplied to the facility horticulture house. This is a carbon dioxide supply device.
- the exhaust gas is preferably cooled to a temperature at which it can be directly supplied to the plants in the house. However, it is not necessary to cool to a temperature that can be directly supplied, and it is possible to supply the plants in the house after further cooling with an additional cooler or the like.
- the example which cools to the temperature which can be directly supplied to the plant mentioned above is an example to the last.
- the combustor 1 is not limited to a dedicated combustion device or a boiler for heating or hot water supply, but may be any one that can utilize exhaust gas, such as an internal combustion engine, an external combustion engine, or fuel using steam reforming of carbon-containing fuel. Defined as broadly including batteries.
- the heat-driven refrigerator 3 of the first embodiment of the present invention will be described in an embodiment using an adsorption refrigeration cycle, but is not limited to this, and an absorption refrigeration cycle (absorption refrigeration cycle) A normal refrigeration cycle using the compressor 3 may be used.
- the refrigerator is used as including all of them.
- this embodiment mainly includes a combustor 1, a heat-driven refrigerator 3 that can absorb heat using the heat energy of the combustor 1, and an endothermic device that generates heat from the heat-driven refrigerator 3.
- the endothermic heat exchanger 6 cools and adjusts the humidity of the combustion gas discharged from the combustor 1 with the cold water.
- the combustor 1 emits combustion gas containing CO2, supplies CO2 in the facility horticultural house, and generates hot water.
- the hot water heated by the combustor 1 is input to the heat-driven refrigerator 3 through the piping circuit of the line L1, and the heat energy of the combustor 1 is used without waste, so that the adsorption-type refrigeration cycle of the heat-driven refrigerator 3 is used. (Described later) is activated. Further, the secondary heat exchanger 2 recovers heat from the combustion gas generated in the combustor 1.
- the chilled water cooled by the evaporator 102 (see FIG. 2A) of the heat-driven refrigerator 3 is combusted including CO2 discharged from the combustor 1 from the connection port e of the heat-driven refrigerator 3 through the circuit of the line L2. It is supplied to the heat absorption heat exchanger 6 used for gas cooling and humidity control, and returns to the connection port d of the heat driven refrigerator 3.
- the line L3 through which the fluid in the heat storage tank 5 flows is connected so as to return to the heat storage tank 5 after passing through the secondary heat exchanger 2 and the connection ports c and f of the heat-driven refrigerator 3.
- a liquid-liquid heat exchanger 4 is installed in the line L3, and heat exchange with the hot water after passing through the line L1 in the heat-driven refrigerator 3 is performed.
- the hot water after passing through the line L 1 is recovered in the line L 3 by the liquid-liquid heat exchanger 4 and stored in the heat storage tank 5.
- the presence of the heat storage tank 5 is effective in terms of heat recovery, but the present embodiment can be realized without the heat storage tank 5.
- the lines of the connection ports c and f of the heat-driven refrigerator 3 may be a line that is cooled by a heat radiating fan or the like.
- Combustion gas containing CO 2 generated by the combustor 1 is cooled by the heat-absorbing heat exchanger 6 to have an appropriate temperature suitable for plants, and is blown into the facility horticultural house by the blower fan 8.
- a heat dissipation heat exchanger 7 is installed downstream of the heat absorption heat exchanger 6, and air blown by the fan 8 flows into the heat dissipation heat exchanger 7 through the heat absorption heat exchanger 6.
- the heat-driven refrigerator 3 needs to discharge the heat of the hot water used and the heat absorbed by the adsorption refrigeration cycle as exhaust heat of the refrigerator itself. Therefore, the fluid in the heat storage tank 5 is used as cooling water in the line L3.
- the cooling water in the line L3 is passed through a secondary heat exchanger 2 installed to recover heat that could not be removed by the combustor 1 from the exhaust gas before being supplied to the heat-driven refrigerator 3, Heat recovery is also performed while lowering the gas temperature. After the heat of the exhaust gas is recovered, the exhaust heat in the heat-driven refrigerator 3 is recovered, and then heat exchange is performed with the hot water after use in the heat-driven refrigerator 3 via the liquid-liquid heat exchanger 4 to increase the temperature.
- the fluid is stored in the heat storage tank 5 as a fluid.
- the heat of the heat storage tank 5 can be used in a heat dissipation heat exchanger 7 for radiating heat for use in heating and humidity control.
- This embodiment has a configuration including three-way valves 9a to 9d and a four-way valve 10 for switching between a heat absorption + humidity control + heat storage mode and a humidity control + heating mode.
- the three-way valves 9a to 9d and the four-way valve 10 can be constituted by a plurality of on-off valves.
- FIG. 2A is a diagram in which the first adsorber 101b of the adsorption refrigeration cycle of this embodiment is operating as an adsorption process, and the second adsorber 101c is operating as a desorbed process.
- FIG. 2B is a diagram in which the four-way valves 105a and 105b are switched by 90 °, the second adsorber 101c is operating as an adsorption process, and the first adsorber 101b is operating as a desorption process.
- the first adsorber 101b, the condenser 103, the second adsorber 101c, and the evaporator 102 are sequentially connected in a pipe to circulate the refrigerant.
- 106a to 106c are fluid pumps.
- water is generally used, but a fluid obtained by mixing water with an ethylene glycol antifreeze may be used.
- the first adsorber 101b and the second adsorber 101c adsorb the gaseous refrigerant when cooled, and are filled with an adsorbent that desorbs the refrigerant when heated. 101d is accommodated.
- the adsorbent adsorbs the surrounding vapor, whereby the liquid refrigerant in the evaporator 102 evaporates, and at the time of this evaporation, heat is taken from the fluid in the line L2 flowing through the evaporator 102 so that cold water is generated. It is configured.
- the refrigeration cycle includes a pipe extending from the outlet port 111 of the evaporator 102 to the inlet port 112 of the condenser 103 via the first adsorber 101b and the outlet port 113 of the condenser 103 via the second adsorber 101c. And a pipe extending to the inlet port 114 of the evaporator 102.
- a check On the way from the outlet port 111 of the evaporator 102 to the first adsorber 101b, a check that opens when the pressure on the first adsorber 101b side falls below a predetermined value below the pressure on the evaporator 102 side.
- a steam valve (check valve) 104a having a valve structure is provided. The check valve 104a allows the refrigerant to flow from the evaporator 102 toward the first adsorber 101b and prevents the reverse flow of the refrigerant in the opposite direction.
- the valve On the way from the first adsorber 101b to the inlet port 112 of the condenser 103, the valve is opened when the pressure on the first adsorber 101b side rises above a predetermined value (higher than the pressure on the condenser 103 side).
- a steam valve (check valve) 104c having a check valve structure is installed. The check valve 104c allows the refrigerant to flow from the first adsorber 101b to the condenser 103, and prevents the refrigerant from flowing backward in the opposite direction.
- the valve opens when the pressure on the second adsorber 101c side falls below a predetermined value below the pressure on the evaporator 102 side.
- a steam valve (check valve) 104b having a check valve structure is installed. The check valve 104b allows the refrigerant to flow from the evaporator 102 toward the second adsorber 101c, and prevents the refrigerant from flowing backward in the opposite direction.
- the valve On the way from the second adsorber 101c to the inlet port 113 of the condenser 103, the valve is opened when the pressure on the second adsorber 101c side rises above a predetermined value (higher than the pressure on the condenser 103 side).
- a steam valve (check valve) 104d having a check valve structure is installed. The check valve 104d allows the refrigerant to flow from the second adsorber 101c toward the condenser 103, and prevents the refrigerant from flowing backward in the opposite direction.
- the first adsorbing core 101a and the second adsorbing core 101d are configured by a known heat exchanger and a large number of adsorbents attached to the surface of a heat exchanging portion such as tubes and fins of the heat exchanger.
- the heat exchanger includes a plurality of tubes through which the heating medium or the cooling medium flows, a header tank in which one end of these tubes is bonded to distribute or collect the heating medium or the cooling medium, and the surface of each tube. It has a large number of fins.
- the adsorbent has a function of capturing (adsorbing) the refrigerant vapor by being cooled and dissociating (desorbing) the refrigerant adsorbed by being heated.
- adsorbent for example, a main framework made of aluminum oxide, phosphoric acid, silicic acid oxide, zeolite, silica gel, activated alumina, or activated carbon is employed.
- a heating medium to the first adsorption core 101a and the second adsorption core 101d, the refrigerant adsorbed by the adsorbents of the first and second adsorption cores 101a and 101d is desorbed and released as vapor.
- An outlet port 115 opened at the side surface of the condenser 103 is formed below the side portion of the condenser 103, and an inlet port 116 opened at the side surface of the evaporator 102 is formed below the side portion of the evaporator 102. And is connected to an outlet port 115 of the condenser 103 via a pipe 107.
- the refrigerant in the condenser 103 is condensed by the cooling water from the line L3, and flows back from the outlet port 115 of the condenser 103 to the inlet port 116 of the evaporator 102 by gravity or differential pressure.
- the operation of the adsorption refrigeration cycle of this embodiment will be described.
- the first adsorber 101b operates as an adsorption process
- the second adsorber 101c operates as a desorption process.
- the valve positions of the four-way valves 105a and 105b are switched by 90 ° from the state shown in FIG. 2A, and the second adsorber 101c operates as an adsorption process and the first adsorber 101b operates as a desorption process.
- the valve positions of the four-way valves 105a and 105b are controlled by an electronic control unit (hereinafter referred to as ECU).
- ECU electronice control unit
- the ECU alternately switches the valve positions of the four-way valves 105a and 105b shown in FIGS. 2A and 2B at predetermined control cycles, and repeatedly executes the switching control.
- the first adsorber 101b operates as an adsorption process
- the second adsorber 101c operates as a desorption process. From the state in which the water vapor of the first adsorption core 101a is released and the desorption is completed in the previous step, the first adsorption core 101a starts to absorb water vapor by being cooled with the cooling water flowing through the connection ports c and f. The inside of the adsorber 101b is depressurized.
- the four-way valves 105a and 105b are switched by 90 ° and switched to the state shown in FIG. 2B. This time, since the desorption of the second adsorption core 101d is completed, the water vapor adsorption of the second adsorption core 101d starts, and the inside of the second adsorber 101c is depressurized. When the check valve 104b is eventually opened, the vaporization of the refrigerant proceeds in the evaporator 102.
- the water in the pipe flowing in from the connection port d of the line L2 is constantly deprived of heat and cooled, and cold water is continuously supplied to the heat absorption heat exchanger 6 used for cooling the exhaust gas.
- the temperature of the exhaust gas generated in the combustor 1 can be lowered.
- the combustor 1 in order to artificially supply CO2 in the facility horticultural house, the combustor 1 is combusted and exhaust gas containing CO2 is supplied into the facility horticulture house. At that time, in the combustor 1, hot water is generated by exchanging heat with heat generated during combustion, and the hot water is supplied to the heat-driven refrigerator 3.
- the heat-driven refrigerator can generate cold water using hot water as energy, and can supply the generated cold water to the heat absorption heat exchanger 6.
- the heat-driven refrigerator 3 is operated while recovering and using the heat generated in the combustor 1. And it becomes possible to reduce to the temperature which can be directly supplied to a plant by cooling the exhaust gas containing CO2 which generate
- the above-described process is activated when photosynthesis is performed, and the heat generated during that time drives the heat-driven refrigerator 3 and is stored in the heat storage tank 5.
- the heat stored in the heat storage tank can be stored while collecting heat in the facility horticultural house in addition to the heat generated by the combustor 1.
- FIG. 3 a mode in which heating and dehumidification in the house are performed with reference to FIG. 3 when there is no problem in plant growth without photosynthesis and without supply of CO 2 will be described with reference to FIG. 1 except for the setting positions of the valves 9a to 9d and the four-way valve 10.
- the outlet of the heat storage tank 5 is upward in the drawing and is changed to the opposite of FIG.
- the air blown from the blower fan 8 is configured to pass through the heat-absorbing heat exchanger 6 and the heat-dissipating heat exchanger 7 in this order, but is not necessarily limited thereto.
- the three-way valves 9a to 9d and the four-way valve 10 in FIG. 1 are switched and set as shown in FIG. 3, and the combustor 1 is normally turned off. Hot water in the heat storage tank 5 is supplied from the upper part of the tank to the connection port b of the heat-driven refrigerator 3 to operate the adsorption refrigeration cycle.
- the cold water generated in the heat driven refrigerator 3 is sent to the heat absorption heat exchanger 6, and the air blown from the blower fan 8 is cooled. Further, the cooling water including the exhaust heat generated in the heat-driven refrigerator 3 (hot water at a predetermined temperature) flows out from the connection port f of the heat-driven refrigerator 3 and is supplied to the heat exchanger 7 for heat dissipation. Thereby, it becomes possible to dehumidify and heat the air sent to the facility horticultural house by the blower fan 8 by the amount of heat stored in the heat storage tank 5.
- the fluid that uses the amount of heat in the hot water returns to the lower part of the heat storage tank in the figure, and the temperature of the hot water in the heat storage tank 5 decreases and becomes a temperature range in which the heat-driven refrigerator 3 cannot operate.
- the heat exchanger 7 can be supplied with a fluid containing the amount of stored heat via the heat-driven refrigerator 3, and heating can be performed until the temperature in the facility horticultural house and the fluid reach the same temperature.
- the flow path is connected to the inlet of the heat generator 1 and connected to the opening b of the heat-driven refrigerator 3 via the combustor 1.
- the rest is the same as in the first embodiment.
- the heat storage amount in the heat storage tank 5 is again reduced by turning on the combustor 1. Can be increased. Therefore, it is possible to perform dehumidifying heating for a longer time than in the first embodiment.
- the heat generated for supplying CO2 is effectively used. And it becomes possible to reduce the energy consumption of the heating apparatus and dehumidification apparatus separately installed in the facility horticultural house, and the energy used in the facility horticultural house can be used effectively. Moreover, dehumidification becomes possible by adjusting the humidity in a state where the facility horticulture house is sealed. Therefore, heating energy can be reduced as compared with a method of dehumidifying while introducing outside air and heating together. In addition, it is possible to reduce the probability of insects that are harmful to plants due to the introduction of outside air. In order to use CO2 and heat in the facility horticultural house, the entire system is desirably installed in the facility horticultural house.
- the heat storage tank 5 by installing the heat storage tank 5 indoors, heat radiation from the outer wall of the tank, for example, The heat that is gradually dissipated to the outside of the tank when the temperature drops, such as at night, can also contribute to the heating in the facility horticulture house. Since the combustor 1 also emits light during combustion, the exhaust gas containing CO2 and light may be used simultaneously.
- the second embodiment is an embodiment in which a humidity control / heat storage device 110 is attached to a facility horticultural house to enable humidification even during the day.
- the desiccant desorbs moisture.
- FIGS. 4 and 5 in order to supply the exhaust gas containing the cooled CO 2 supplied to the facility horticultural house, the combustor 1 is turned on and the thermally driven refrigerator 3 is operated as in the first embodiment of FIG.
- FIG. 5 shows a case where the combustor 1 and the thermally driven refrigerator 3 are turned off.
- the combustor 1 is turned on, and the fluid discharged from the heat storage tank 5 is thermally driven from the connection port c while passing through the secondary heat exchanger 2 as in FIG. 1. Pass through refrigerator 3.
- the circuit configuration in the heat-driven refrigerator 3 is the same as in FIGS. Thereafter, the fluid flowing out from the connection port d of the heat-driven refrigerator 3 rises in temperature while exchanging heat in the liquid-liquid heat exchanger 4, passes through the humidity control / heat storage device 110 described later, and returns to the heat storage tank 5.
- the exhaust gas containing the cooled CO2 it is the same as in the first embodiment of FIG. The same applies to the effect.
- the humidity control / heat storage device 110 for humidifying the daytime is added to the facility horticulture house.
- the humidity control / heat storage device 110 uses a desiccant that adsorbs and desorbs moisture.
- the desiccant is heated, and the desiccant desorbs the adsorbed moisture.
- the blower fan 8b By supplying the desorbed moisture with the blower fan 8b, the inside of the house can be humidified.
- the desorption of moisture in the humidity control / heat storage device 110 is completed and the heat storage in the heat storage tank 5 is completed, the positions of the three-way valves 19a to 19d are changed from FIG. 4 (combustor 1: ON). It can be switched and used as shown in FIG. 5 (combustor 1: OFF).
- the heat absorption heat exchanger 6 is supplied with hot water flowing out from the upper part (on the drawing) of the heat storage tank 5 when the heat radiation pump 17 is operated. Then, this heat exchanger 6 functions as a heat exchanger for heat radiation instead of the heat absorbing function in FIG. And the air ventilated from the ventilation fan 8a passes through the heat exchanger 6, becomes warm air, and is supplied in a house. Such warm air heating can be stored in the heat storage tank 5.
- the fluid does not circulate in the heat exchanger 6 unless the heat dissipation pump 17 is activated.
- the fluid can circulate in the heat exchanger 6 by the pump 106 c (FIG. 2A) in the heat-driven refrigerator 3.
- the humidity control / heat storage device 110 has the following effects by blowing air to the desiccant.
- the desiccant generates heat while adsorbing the moisture of the gas supplied to the desiccant, but the moisture adsorption amount of the desiccant is reduced in the heat generation state. Therefore, the blower fan 8b is driven to blow air so that air flows into the desiccant. Since the heat generated during the adsorption of the desiccant is dissipated by this air blowing, the moisture adsorption capacity of the desiccant can be ensured.
- an inorganic or organic substance such as silica gel, zeolite activated carbon, alumina, metal oxide, quicklime, calcium chloride, lithium bromide, synthetic resin, or the like may be used.
- FIGS. 6 and 7 The third embodiment of FIGS. 6 and 7 is an embodiment in which the heat-driven refrigerator 3 is an absorption refrigeration cycle. Others are the same as the first and second embodiments. That is, the connection ports a to f of the heat-driven refrigerator 3 in FIGS. 1 and 3 to 5 are connected to the connection ports a to f of FIGS. 6 and 7, the connection port cf in the heat-driven refrigerator 3 is connected in parallel in FIG. 6, and the connection line cf in FIG. 7 is shown in FIG.
- the refrigerant in the evaporator 202 is vaporized by the low pressure generated by absorbing the refrigerant in the absorber 201 in a known high-absorbing liquid (absorption liquid, water-lithium bromide, ammonia-water, etc.). This is a refrigerator that produces low temperatures.
- the refrigerant is evaporated by the low-pressure evaporator 202 to produce cold water / cold liquid in the line L2 (d to e), and the evaporated refrigerant is absorbed by the absorption liquid by the absorber 201.
- the absorption liquid that has absorbed the refrigerant is heated by a regenerator 203 to evaporate and separate the refrigerant, and the concentrated solution is returned to the absorber 201 again via the pressure reducing valve 205.
- the evaporated and separated refrigerant is cooled and liquefied by the condenser 204 and is again used for heat absorption by the evaporator 202 via the pressure reducing valve 206.
- the line of the connection port cf in the heat-driven refrigerator 3 is branched in parallel so as to flow to the condenser 204 and the absorber 201.
- the embodiment of FIG. 204 and the absorber 201 are connected so as to flow in series. What is necessary is just to select suitably by the temperature etc. of the cooling water which flows through each component. The effect is the same as that of the first embodiment.
- the heat-driven refrigerator 3 may be an adsorption refrigeration cycle or an absorption refrigeration cycle, and in the case of an adsorption refrigeration cycle, the operating heat source temperature can be lowered.
- the fourth embodiment in FIG. 8 is an embodiment using an engine-driven refrigerator (the compressor is driven by belt transmission by the rotation of the engine).
- This is an embodiment having an engine 1 as a combustor that generates CO 2 and a compressor 22 driven by the engine.
- a condenser 25, an expansion valve 24, and a heat-absorbing heat exchanger (evaporator) 6 are connected by piping so as to form a refrigeration cycle.
- a heat exchanger 23 is installed to exchange heat with the condenser 25 of the refrigeration cycle.
- the heat storage tank 5, the secondary heat exchanger 2 that recovers heat from the engine exhaust gas, the heat exchanger 23, the cooling unit of the engine 1, and the humidity control / heat storage device 110 are connected by the fluid circuit F in this order.
- the flow path is switched by the three-way valves 29a to 29d.
- the compressor 22 is rotated by the power obtained from the engine 1, and cold is obtained by operating the vapor compression refrigeration cycle.
- the engine 1 generates exhaust gas containing CO2 that is generated when the fuel burns.
- the heat contained in the exhaust gas is recovered by an exhaust heat recovery device (secondary heat exchanger 2), and also in the heat absorption heat exchanger (evaporator) 6 on the downstream side of the heat exchanger 2, the refrigeration is performed. It is recovered using the endotherm generated in the cycle. Thereby, the exhaust gas is cooled.
- the fluid in the heat storage tank 5 is recovered by the secondary heat exchanger 2 in the fluid circuit F, and at the downstream side, the heat radiated from the refrigeration cycle is recovered by the heat exchanger 23 in the condenser 25 of the refrigeration cycle. After that, it is flowed into the engine as engine cooling water to recover heat.
- the humidity control / heat storage device 110 performs humidification (dehumidification) as in the second embodiment, and returns to the heat storage tank 5.
- the desiccant included in the device 110 is heated by the heat of the fluid returning to the tank 5, and the adsorbed moisture is released. And the air from the ventilation fan 8b is humidified.
- the three-way valves 29a and 29b are switched (90 ° clockwise), the heat storage tank 5 and the heat exchanger 7 for heat radiation Can be connected to each other, and the warm water can be supplied by flowing the hot water in the heat storage tank 5.
- the humidity control / heat storage device 110 since the humidity control / heat storage device 110 is separately attached, the three-way valves 29c and 29d are switched so that the hot water flow path of the tank 5 bypasses the device 110, Dehumidification is also performed by blowing air with the blower fan 8b.
- the power source may be an internal combustion engine or an external combustion engine, or a fuel cell using a fuel containing carbon.
- hot water is stored in the heat storage tank 5, thereby operating the heat-driven refrigerator 3.
- the lines of the connection ports c and f of the heat-driven refrigerator 3 cool the heat exchanger for heat dissipation with the fan 8c in the facility horticultural house (may be cooled outside the house). Other than that, it is the same as the first and second embodiments.
- the heat (ie, heat energy) generated in the combustor 1 is stored in the heat storage tank 5 in the form of warm water.
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Abstract
Description
(第1実施形態)
本発明の第1実施形態は、施設園芸ハウス内で人口的にCO2を供給させるため、燃焼器1を燃焼させてCO2を含む排気ガスをハウス内に供給するものである。その際、燃焼器内では、燃焼時に発生する熱と熱交換して、温水を発生させるようになっており、その温水を熱駆動冷凍機3へ供給する。熱駆動冷凍機3は、供給された温水をエネルギにして冷水を発生させる。その発生した冷水を、今度は吸熱用熱交換器6へ供給して、CO2を含む排気ガスを冷却するものである。排気ガスの冷却は、ハウス内の植物に直接供給が可能な温度まで低下させるのが好適である。ただし、直接供給可能な温度まで冷却させなくてもよく、追加の冷却器などでさらに冷却してからハウス内の植物に供給することも可能である。上述した植物に直接供給可能な温度まで冷却する例は、あくまで一例である。
本実施形態の熱駆動冷凍機3である吸着式冷凍サイクルを、図2A、2Bを参照して説明する。なお、この吸着式冷凍サイクルは、一例として例示するものであって、一般的な周知の吸着式冷凍サイクルであれば、本実施形態において適用可能である。
図2Aは、本実施形態の吸着式冷凍サイクルの第1吸着器101bが吸着工程、第2吸着器101cが脱着工程(desorbed process)として作動している図である。一方、図2Bは、四方弁105a、105bが90°切り替わって、第2吸着器101cが吸着工程、第1吸着器101bが脱着工程として作動している図である。
除湿暖房を行う場合には、図1の三方弁9a~9dと四方弁10を切替えて図3のように設定し、通常は燃焼器1をOFFにする。蓄熱タンク5内の温水を、タンク上部から熱駆動冷凍機3の接続口bに供給し、吸着式冷凍サイクルを作動させる。
なお、図10の第5実施形態に示すように、第1実施形態の流路を変更しても良い。この実施形態では、図3に示される蓄熱タンク5の上部開口から四方弁10を経由して熱駆動冷凍機3の開口部bに接続する流路を、図10の如く、四方弁10から燃焼器1の入口に接続させ、燃焼器1を経由して熱駆動冷凍機3の開口部bに接続する流路に変更した例である。それ以外は、第1実施形態と同様である。
この図10の第5実施形態の構成により、除湿暖房時、蓄熱タンク5内に蓄えられた熱量が低下した場合でも、燃焼器1をONにすることで、蓄熱タンク5内の蓄熱量を再び増大させることができる。従って、第1実施形態に比べ、より長時間の除湿暖房を可能とすることができる。
CO2及び熱を施設園芸ハウス内で利用するためには、システム全体は、施設園芸ハウス内に設置することが望ましく、特に蓄熱タンク5を屋内に設置することで、タンク外壁からの放熱、例えば、夜間等の気温低下時に徐々にタンク外部へ放熱される熱も、施設園芸ハウス内の加温に寄与させることができる。燃焼器1に関しては燃焼時に光も放出しているため、CO2を含む排気ガスと光を同時に利用するようにしても良い。
第2実施形態は、図4、5に示すように、施設園芸ハウスへ、日中でも加湿を行うことを可能とするため、調湿・蓄熱装置110を付設した実施形態である。温水が調湿・蓄熱装置110内に流れると、乾燥剤が水分を脱離するようにしている。以下、図4、5を参照して第2実施形態を説明する。図4では、施設園芸ハウスに供給する冷却したCO2を含む排気ガスを供給するために、図1の第1実施形態と同じく、燃焼器1をONとし、熱駆動冷凍機3を作動させる。図5では、燃焼器1、熱駆動冷凍機3をOFFにした場合を示している。
次に、調湿・蓄熱装置110での水分の脱離が完了し、蓄熱タンク5にも蓄熱が完了した状態では、三方弁19a~dの位置を、図4(燃焼器1:ON)から図5(燃焼器1:OFF)に示すように切替えて使用することができる。
図6、7の第3実施形態は、熱駆動冷凍機3を吸収式冷凍サイクルにした実施形態である。その他は、第1、2実施形態と同様である。すなわち、図1、3~5における熱駆動冷凍機3の接続口a~fは、図6、7の接続口a~fに連結している。図6、7において、熱駆動冷凍機3内の接続口c-fのラインを、並列にしたものが図6であり、直列にしたものが図7である。吸収式冷凍サイクルは、周知の吸収力の高い液体(吸収液、水-臭化リチウム、アンモニア-水など)に吸収器201で冷媒を吸収させて発生する低圧によって、蒸発器202の冷媒を気化させて低温をつくる冷凍機である。
図8の第4実施形態は、エンジン駆動式冷凍機(エンジンの回転によりベルト伝動で圧縮機を駆動)を使用した実施形態である。CO2を発生する燃焼器としてのエンジン1と、そのエンジンにより駆動される圧縮機22を有する実施形態である。この圧縮機22により、冷凍サイクルを形成するように凝縮器25と膨張弁24と吸熱用熱交換器(蒸発器)6が配管で接続されている。この冷凍サイクルの凝縮器25と熱交換するために熱交換器23が設置されている。一例として、蓄熱タンク5、エンジン排気ガスから熱回収する二次熱交換器2、熱交換器23、エンジン1の冷却部、調湿・蓄熱装置110とは、この順序で、流体回路Fで繋がれており、三方弁29a~29dにて流路を切替えている。これらの接続順序は、二次熱交換器2、熱交換器23、エンジン1の冷却部等の温度を考慮して適宜設定すればよく、図8の実施形態に限定されるものではない。
蓄熱タンク5の蓄熱、及びハウス内へ所望のCO2量の供給が完了している場合には、三方弁29a、29bを切替え(90°右回り)、蓄熱タンク5と放熱用熱交換器7とを連結して、蓄熱タンク5内の温水を流すことで暖房を行うことが可能となる。上記回路では図4、5の第2実施形態と同様に、別途調湿・蓄熱装置110が取り付けてあるので、タンク5の温水流路が装置110をバイパスするよう三方弁29c、29dを切替え、送風ファン8bで送風することによって、除湿も行う。
なお、動力源は内燃機関、外燃機関を問わず、また炭素を含む燃料を使用する燃料電池でも可能である。
図9の実施形態では、蓄熱タンク5に高温の温水を蓄熱して、それによって熱駆動冷凍機3を作動させる。熱駆動冷凍機3の接続口c、fのラインは、施設園芸ハウス内で放熱用熱交換器をファン8cで冷却している(ハウス外で冷却しても良い)。それ以外においては、第1、2実施形態と同様である。この実施形態では、燃焼器1で発生した熱(すなわち熱エネルギ)を蓄熱タンク5に温水という形態で蓄熱させたものであることは言うまでもない。
3 冷凍機
5 蓄熱タンク
6 吸熱用熱交換器
Claims (14)
- 燃焼器(1)、冷凍機(3)、該冷凍機(3)の冷凍サイクルで冷却した流体が流れる吸熱用熱交換器(6)を具備する二酸化炭素供給装置において、
前記燃焼器(1)で燃焼した場合に二酸化炭素を含む排気ガスを、前記吸熱用熱交換器(6)に通過させ冷却し、施設園芸ハウス内に供給する二酸化炭素供給装置。 - 前記冷凍機(3)が、熱駆動冷凍機であって、前記燃焼器(1)での燃焼で発生した熱エネルギによって前記冷凍機(3)の冷凍サイクルを駆動することを特徴とする請求項1に記載の二酸化炭素供給装置。
- 前記供給装置は、さらに蓄熱タンク(5)を具備することを特徴とする請求項1又は2に記載の二酸化炭素供給装置。
- 前記蓄熱タンク(5)によって、前記燃焼器(1)での燃焼で発生する熱エネルギと前記熱駆動冷凍機(3)から発生する排熱とを回収したことを特徴とする請求項3に記載の二酸化炭素供給装置。
- 前記冷凍機(3)の冷凍サイクルが、吸着式冷凍サイクル、又は、吸収式冷凍サイクルであることを特徴とする請求項1から4のいずれか1項に記載の二酸化炭素供給装置。
- 前記供給装置は、前記蓄熱タンク(5)からの流体により、乾燥剤が吸着している水分を脱離する調湿・蓄熱装置(110)を具備することを特徴とする請求項3から5のいずれか1項に記載の二酸化炭素供給装置。
- 送風用ファン(8)で空気を通過させて前記施設園芸ハウス内に供給する放熱用熱交換器(7)をさらに設け、
前記熱駆動冷凍機(3)を前記蓄熱タンク(5)からの流体により駆動できるようにし、かつ、前記熱駆動冷凍機(3)から発生する排熱を前記放熱用熱交換器(7)で放熱するようにする、切替弁(9a~9d、10)を具備することを特徴とする請求項3から6のいずれか1項に記載の二酸化炭素供給装置。 - 前記放熱用熱交換器(7)を、前記吸熱用熱交換器(6)の下流に設け、前記送風用ファン(8)で送風される空気は前記吸熱用熱交換器(6)を経て、前記放熱用熱交換器(7)へ流入することを特徴とする請求項7に記載の二酸化炭素供給装置。
- 前記吸熱用熱交換器(6)を、前記蓄熱タンク(5)からの流体を流して放熱用熱交換器として機能させるようにする、切替弁(19a~19d)を具備することを特徴とする請求項3から6のいずれか1項に記載の二酸化炭素供給装置。
- 前記冷凍機が、燃焼器(1)であるエンジンにより圧縮駆動される、蒸気圧縮式冷凍サイクルであって、前記吸熱用熱交換器(6)が、前記蒸気圧縮式冷凍サイクルの蒸発器であり、前記燃焼器(1)で燃焼した二酸化炭素を含む排気ガスを、前記吸熱用熱交換器(6)に通過させて冷却し、施設園芸ハウス内に供給する請求項1に記載の二酸化炭素供給装置。
- 前記供給装置が、さらに蓄熱タンク(5)を具備し、前記蓄熱タンク(5)に、前記燃焼器(1)で燃焼した熱エネルギを蓄熱させ、その熱エネルギによって熱駆動冷凍機(3)を駆動したことを特徴とする請求項1に記載の二酸化炭素供給装置。
- 前記供給装置を、施設園芸ハウスの屋内に設置したことを特徴とする請求項1から11のいずれか1項に記載の二酸化炭素供給装置。
- 前記燃焼器(1)の熱エネルギと光を別々に利用したことを特徴とする請求項1から12のいずれか1項に記載の二酸化炭素供給装置。
- 前記燃焼器(1)で燃焼した二酸化炭素を含む排気ガスを、前記吸熱用熱交換器(6)に通過させ、前記施設園芸ハウス内の植物に供給可能な温度まで冷却することを特徴とする請求項1から13のいずれか1項に記載の二酸化炭素供給装置。
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- 2013-07-08 CN CN201380036304.7A patent/CN104427858B/zh not_active Expired - Fee Related
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JP2015188864A (ja) * | 2014-03-28 | 2015-11-02 | フタバ産業株式会社 | ガス冷却装置 |
WO2015190213A1 (ja) * | 2014-06-10 | 2015-12-17 | フタバ産業株式会社 | 二酸化炭素施用装置 |
JP2015231348A (ja) * | 2014-06-10 | 2015-12-24 | フタバ産業株式会社 | 二酸化炭素施用装置 |
CN106659128A (zh) * | 2014-06-10 | 2017-05-10 | 双叶产业株式会社 | 二氧化碳施用设备 |
JP2016007163A (ja) * | 2014-06-24 | 2016-01-18 | ネポン株式会社 | 炭酸ガス発生システム |
US9968037B2 (en) * | 2015-04-06 | 2018-05-15 | Michael Kisting | Short chain hydrocarbon combustor and carbon dioxide generator |
US20160286737A1 (en) * | 2015-04-06 | 2016-10-06 | Michael Kisting | Short Chain Hydrocarbon Combustor and Carbon Dioxide Generator |
JP2017147996A (ja) * | 2016-02-25 | 2017-08-31 | 株式会社デンソー | 二酸化炭素供給システム |
JP2017176169A (ja) * | 2016-03-24 | 2017-10-05 | 株式会社デンソー | 二酸化炭素供給装置 |
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JP2018174807A (ja) * | 2017-04-13 | 2018-11-15 | 株式会社Ihi | 植物の栽培施設内の環境管理システム |
GB2567633A (en) * | 2017-10-16 | 2019-04-24 | Linde Ag | Method and Apparatus for improving greenhouse cultivation |
JP2019154400A (ja) * | 2018-03-16 | 2019-09-19 | 株式会社Ihi | 植物栽培室の管理システムおよび植物栽培室の管理制御方法 |
JP2022011713A (ja) * | 2020-06-30 | 2022-01-17 | 株式会社ノーリツ | Co2供給装置およびco2供給システム |
JP7495609B2 (ja) | 2020-06-30 | 2024-06-05 | 株式会社ノーリツ | Co2供給システム |
Also Published As
Publication number | Publication date |
---|---|
KR101681601B1 (ko) | 2016-12-01 |
KR20150027126A (ko) | 2015-03-11 |
EP2873316A1 (en) | 2015-05-20 |
CN104427858B (zh) | 2017-03-08 |
CN104427858A (zh) | 2015-03-18 |
JP6028799B2 (ja) | 2016-11-16 |
EP2873316A4 (en) | 2016-01-27 |
JPWO2014010561A1 (ja) | 2016-06-23 |
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