WO2011155133A1 - 液晶表示装置及びその製造方法 - Google Patents
液晶表示装置及びその製造方法 Download PDFInfo
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- WO2011155133A1 WO2011155133A1 PCT/JP2011/002771 JP2011002771W WO2011155133A1 WO 2011155133 A1 WO2011155133 A1 WO 2011155133A1 JP 2011002771 W JP2011002771 W JP 2011002771W WO 2011155133 A1 WO2011155133 A1 WO 2011155133A1
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- liquid crystal
- alignment film
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Classifications
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1337—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/005—Processes
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- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/133302—Rigid substrates, e.g. inorganic substrates
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/133388—Constructional arrangements; Manufacturing methods with constructional differences between the display region and the peripheral region
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1337—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
- G02F1/133711—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by organic films, e.g. polymeric films
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1339—Gaskets; Spacers; Sealing of cells
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1345—Conductors connecting electrodes to cell terminals
Definitions
- the present invention relates to a liquid crystal display device and a method for manufacturing the same, and more particularly to control of an application region of an alignment film.
- the liquid crystal display device generally has a structure in which a liquid crystal layer is sealed between a pair of substrates.
- the pair of substrates includes a TFT substrate and a counter substrate.
- a plurality of gate wirings, a plurality of source wirings, a plurality of pixel electrodes, a plurality of TFTs, and the like are formed on the TFT substrate.
- a common electrode common to the plurality of pixel electrodes is formed on the counter substrate.
- the liquid crystal layer is sealed between a TFT substrate and a counter substrate, surrounded by a frame-shaped sealing member.
- a pixel region as a display region and a frame region as a non-display region provided around the outside thereof are formed.
- the frame region of the TFT substrate has a seal member forming region and a terminal region provided on the outer periphery thereof.
- a plurality of terminals for supplying signals to the pixel area are formed.
- the TFT substrate and the counter substrate are provided with an alignment film for regulating the alignment of liquid crystal molecules in the liquid crystal layer on the surface on the liquid crystal layer side.
- the alignment film is made of a resin film such as polyimide, and its surface is rubbed.
- the alignment film is formed by applying liquid polyimide on the surface of the TFT substrate and the counter substrate, and then baking and curing.
- Polyimide can be applied by, for example, a flexographic printing method or an inkjet printing method.
- the viscosity of the alignment film material is relatively set so that the alignment film material such as polyimide discharged and landed toward the substrate is sufficiently spread on the substrate surface. Need to be low.
- the low-viscosity alignment film material easily spreads on the substrate surface, it easily spreads to a frame area that is not originally required.
- the alignment film material reaches the terminal region in the frame region, the plurality of terminals are covered with the alignment film, which is an insulating film, and as a result, conduction between the terminals and the circuit chip mounted on the terminals is hindered.
- Patent Documents 1 and 2 an excessive alignment film material is formed by forming a groove structure between a sealing member forming region of a TFT substrate and a pixel region where display is performed, and accumulating the alignment film material in the groove. It has been proposed to prevent the spread of.
- Patent Document 3 in order to control the wetting and spreading of the alignment film material, a water repellent region is provided on the surface of the TFT substrate, and a concavo-convex structure is formed with the same material as the wiring layer formed on the TFT substrate. It is disclosed to form. Since the concavo-convex structure is formed of the same material as the wiring layer, it can be formed simultaneously with the wiring by etching.
- FIG. 19 is a cross-sectional view showing the principle of controlling the wetting and spreading of the alignment film material in Patent Document 3.
- the concavo-convex structure 100 of Patent Document 3 is composed of a plurality of convex portions 102 arranged on a glass substrate 101 at a predetermined interval.
- the convex part 102 is comprised with the same metal film as a wiring layer.
- Patent Documents 1 and 2 in the configuration in which a plurality of grooves are formed in order to store the alignment film material, the formation areas of the plurality of grooves are compared in order to secure a volume for storing the alignment film material. It is necessary to provide a wide range. As a result, since the distance from the pixel region to the seal member forming region is increased, it is difficult to reduce the width of the frame-like non-display region.
- the present invention has been made in view of these points, and the object of the present invention is to provide an alignment film material while narrowing the non-display area of the liquid crystal display device as much as possible regardless of the layout of the wiring. It is to suppress the spread of.
- a liquid crystal display device includes a first substrate, a second substrate disposed opposite to the first substrate, and the first substrate and the second substrate.
- the present invention is directed to a liquid crystal display device including a liquid crystal layer provided and a sealing member provided between the first substrate and the second substrate and enclosing and sealing the liquid crystal layer.
- Each of the first substrate and the second substrate has a pixel region as a display region and a frame region as a non-display region that is an outer peripheral region of the pixel region and includes the seal member formation region. Then, an alignment film formed by curing a fluid alignment film material is formed on the liquid crystal layer side of the first substrate and the second substrate so as to spread from the pixel region to the frame region side.
- the first substrate is formed on the support substrate so as to cover the support substrate, the wiring layer formed on the support substrate, and a part of the surface opposite to the support substrate. Has an insulating film directly covered by the alignment film, and a concave portion is formed on the surface of the insulating film so as to be recessed without penetrating the insulating film.
- edge of the recessed portion is disposed in the frame region, and the tangent plane of the edge moves toward the inside of the recessed portion, and the support substrate side is arranged.
- the edge of the alignment film is supported by the edge of the recess, and the bottom of the recess supporting the edge of the alignment film is supported by the alignment film. Is exposed from.
- the alignment film material before curing is formed so as to spread from the pixel region to the frame region side. And the edge part of an alignment film is formed in a frame area
- an insulating film is formed on the support substrate of the first substrate so as to cover the wiring layer, and a recess is formed in the surface of the insulating film. The edge part of this recessed part is arrange
- the wetting and spreading of the alignment film material is blocked by the edge of the recess.
- the edge portion of the alignment film is supported by the edge portion of the recessed portion.
- the edge portion of the recessed portion is formed so that the tangent plane thereof is inclined toward the support substrate side as it goes inward of the recessed portion, so that the alignment film material can be supported by its viscosity.
- the insulating layer is interposed between the recessed portion and the wiring layer in a state where the recessed portion is disposed so as to overlap the wiring layer, the wiring layer is protected by the insulating layer, and the layout of the wiring layer is concerned.
- the recess can be formed so as to extend continuously. Therefore, it is possible to more appropriately prevent the alignment film material from spreading.
- the alignment film material is accumulated in the groove formed on the substrate, it is unclear to what extent the alignment film material is accumulated in the groove structure volume, so that the liquid crystal is deposited on the substrate.
- a liquid crystal display device is manufactured by dropping the liquid crystal, it is difficult to appropriately define the volume of the liquid crystal material to be dropped, including the free space in the groove structure. If the volume of the liquid crystal material is less than the required amount, bubbles may occur in the liquid crystal layer.
- the alignment film material is not accumulated in the recessed portion, and the alignment film material is dammed up at the edge of the recessed portion, so that the volume of the liquid crystal material to be dropped is made substantially constant. Can be maintained. Therefore, it is possible to prevent the generation of bubbles in the liquid crystal layer by supplying an appropriate volume of the liquid crystal material onto the support substrate.
- the spread of the alignment film material can be suppressed while the non-display area of the liquid crystal display device is significantly narrowed.
- the insulating layer is interposed between the recessed portion and the wiring layer in a state where the recessed portion is placed on the wiring layer, the wiring layer is protected by the insulating layer, and the layout of the wiring layer is concerned.
- the recess can be formed so as to extend continuously. Therefore, it is possible to more appropriately prevent the alignment film material from spreading.
- FIG. 1 is a plan view showing a schematic configuration of the liquid crystal display device according to the first embodiment.
- FIG. 2 is an enlarged plan view showing a region indicated by II in the TFT substrate of FIG.
- FIG. 3 is an enlarged plan view showing a region indicated by III in the TFT substrate of FIG. 4 is a cross-sectional view taken along line IV-IV in FIG.
- FIG. 5 is an enlarged cross-sectional view showing the vicinity of the edge of the recessed portion in the TFT substrate.
- FIG. 6 is an enlarged plan view showing a part of the TFT substrate.
- FIG. 7 is a plan view schematically showing a halftone mask for forming a recessed portion.
- FIG. 8 is a cross-sectional view showing a planarizing film developed after halftone exposure.
- FIG. 1 is a plan view showing a schematic configuration of the liquid crystal display device according to the first embodiment.
- FIG. 2 is an enlarged plan view showing a region indicated by II in the TFT substrate of FIG.
- FIG. 9 is a cross-sectional view showing the planarized film after post-baking.
- FIG. 10 is a cross-sectional view showing a schematic structure of the liquid crystal display device.
- FIG. 11 is a graph showing the relationship between the maximum angle at the edge and the depth of the recessed portion and the spread controllability of the alignment film material.
- FIG. 12 is an enlarged cross-sectional view showing the vicinity of the recessed portion when ⁇ 1max is about 15 °.
- FIG. 13 is an enlarged cross-sectional view showing the vicinity of the recessed portion when ⁇ 1max is about 50 °.
- FIG. 14 is an enlarged sectional view showing the vicinity of the recessed portion when ⁇ 1max is about 5 °.
- FIG. 15 is an enlarged plan view showing a part of a TFT substrate according to another embodiment.
- FIG. 16 is an enlarged plan view showing a part of a TFT substrate according to another embodiment.
- FIG. 17 is an enlarged plan view showing a corner portion of a TFT substrate according to another embodiment.
- FIG. 18 is an enlarged plan view showing a corner portion of a TFT substrate according to another embodiment.
- FIG. 19 is a cross-sectional view showing the principle of controlling the wetting and spreading of a conventional alignment film material.
- Embodiment 1 of the Invention 1 to 10 show Embodiment 1 of the present invention.
- FIG. 1 is a plan view showing a schematic configuration of the liquid crystal display device 1 according to the first embodiment.
- FIG. 2 is an enlarged plan view showing a region indicated by II in the TFT substrate 11 of FIG.
- FIG. 3 is an enlarged plan view showing a region indicated by III in the TFT substrate 11 of FIG. 4 is a cross-sectional view taken along line IV-IV in FIG.
- FIG. 5 is an enlarged cross-sectional view showing the vicinity of the edge 51 of the recess 48 in the TFT substrate 11.
- FIG. 6 is an enlarged plan view showing a part of the TFT substrate 11. In FIG. 6, an alignment film 23 and a recessed portion 48 described later are not shown.
- FIG. 10 is a cross-sectional view showing a schematic structure of the liquid crystal display device 1.
- the liquid crystal display device 1 includes a TFT substrate 11 as a first substrate, a counter substrate 12 that is a second substrate disposed to face the TFT substrate 11, a TFT substrate 11, And a liquid crystal layer 13 provided between the counter substrates 12.
- the liquid crystal display device 1 includes a seal member 14 provided between the TFT substrate 11 and the counter substrate 12 so as to surround and seal the liquid crystal layer 13.
- the seal member 14 is formed in a substantially rectangular frame shape, and is made of, for example, an ultraviolet heat combined curable resin such as an acrylic or epoxy resin.
- a plurality of conductive particles are dispersed and mixed in the seal member 14.
- the line width of the seal member 14 is, for example, about 0.5 mm to 2.5 mm.
- the TFT substrate 11 and the counter substrate 12 each have a pixel region 31 as a display region and a frame region 32 as a non-display region that is a region around the outside of the pixel region 31.
- the frame region 32 includes a seal member formation region 34 (a formation region of the seal member 14) provided at a predetermined interval from the pixel region 31.
- an alignment film 23 formed by curing the alignment film material 24 having fluidity is formed from the pixel region 31 to the formation region side of the seal member 14. It is formed to spread.
- the alignment film 23 is made of a resin material such as polyimide and regulates the initial alignment of the liquid crystal molecules of the liquid crystal layer 13.
- the alignment film material 24 has its viscosity lowered by adding a solvent to polyimide or the like.
- a vertical alignment film material having a viscosity of 6.5 mPa ⁇ s manufactured by JSR Corporation can be applied.
- the frame region 32 of the TFT substrate 11 is a region opposite to the pixel region 31 of the seal member forming region 34, and a plurality of terminals 28 for supplying signals to the pixel region 31 are formed.
- the terminal area 33 is provided. As shown in FIG. 4, the terminal region 33 is formed in a side region of the TFT substrate 11.
- a pad 20 as an electrode portion made of a transparent conductive film such as ITO (Indium Tin Oxide) is provided on the surface of the planarizing film 43 as an insulating film. A plurality are formed.
- the pads 20 are formed with a thickness of about 100 nm and are arranged along the seal member 14 at a predetermined interval. The pad 20 is for electrically connecting to the common electrode (not shown) of the counter substrate 12 through the conductive particles of the seal member 14.
- a plurality of pixels 5 are arranged in a matrix in the pixel region 31 of the TFT substrate 11.
- Each pixel 5 is formed with a pixel electrode 15 made of a transparent conductive film such as ITO.
- the thickness of the pixel electrode 15 is, for example, about 100 nm.
- Each pixel 5 is formed with a TFT (Thin-Film-Transistor: not shown) as a switching element connected to the pixel electrode 15.
- the semiconductor layer (not shown) constituting the TFT has a configuration in which an i-Si film (intrinsic silicon film) having a thickness of 150 nm and an n + Si film having a thickness of 40 nm are stacked in this order. .
- a SiNx film having a thickness of about 200 nm is stacked on the semiconductor layer as a channel protective film.
- a gate wiring 18 and a source wiring 16 connected to the TFT are formed on the TFT substrate 11.
- the gate wiring 18 has a configuration in which a Ti film having a thickness of about 30 nm, an Al film having a thickness of about 300 nm, and a Ti film having a thickness of about 100 nm are stacked in this order.
- the source wiring 16 has a configuration in which a Ti film having a thickness of about 30 nm and an Al film having a thickness of about 300 nm are stacked in this order.
- the line width of the gate wiring 18 and the source wiring 16 is about 10 ⁇ m. Further, as shown in FIG. 2, the interval between the adjacent gate wirings 18 is about 200 ⁇ m. On the other hand, the interval between adjacent source lines 16 is about 70 ⁇ m as shown in FIG.
- the TFT substrate 11 has a glass substrate 21 that is a support substrate, and the gate wiring 18 and a gate that covers the gate wiring 18 are formed on the surface of the glass substrate 21 on the liquid crystal layer 13 side.
- An insulating film 41 is formed.
- a plurality of lead wires 17 made of the same material as the gate wire 18 are formed in the frame region 32 of the glass substrate 21.
- the line width of the lead-out wiring 17 is about 10 ⁇ m.
- a terminal 28 is provided at the end of the lead wiring 17.
- the source wiring 16 is connected to the lead wiring 17 via a contact portion (not shown).
- the gate insulating film 41 is made of, for example, SiNx and has a thickness of about 400 nm.
- a passivation film 42 as a protective film is formed on the surface of the gate insulating film 41.
- the passivation film 42 is made of an inorganic film such as SiN, and has a thickness of about 250 nm.
- a passivation film 42 and a planarizing film 43 that is an insulating film covering the passivation film 42 are formed on the surface of the source wiring 16. That is, the planarizing film 43 is formed on the glass substrate 21 so as to cover the wiring layer such as the source wiring 16.
- the planarizing film 43 is made of, for example, a photocurable resin (photosensitive resin) such as a photocurable acrylic resin, and has a thickness of about 2 to 2.5 ⁇ m.
- the plurality of pixel electrodes 15 are formed on the surface of the planarizing film 43 in the pixel region 31.
- the sealing member 14 is formed on the surface of the planarizing film 43 in the sealing member forming region 34. A part of the surface of the planarizing film 43 opposite to the glass substrate 21 is directly covered with the alignment film 23.
- a concave portion 48 is formed which is recessed without penetrating the flattening film 43.
- the recessed portion 48 is arranged so that at least a part thereof overlaps with a wiring layer such as the source wiring 16 or the gate wiring 18 when viewed from the normal direction of the surface of the glass substrate 21.
- the recessed portion 48 of the present embodiment is formed so as to extend along the seal member forming region 34.
- the recessed part 48 is formed in a frame shape as a whole by extending in a groove shape along the seal member forming region.
- the groove width of the recessed portion 48 is, for example, about 20 ⁇ m, and the groove depth of the recessed portion 48 is, for example, about 1 ⁇ m.
- the recessed portion 48 can be formed by photolithography as will be described later.
- the edge 51 of the recessed portion 48 is disposed in the frame region 32, and in particular, is disposed between the pixel region 31 and the seal member forming region 34. Further, as shown in FIG. 5, the edge 51 of the recess 48 is formed so that the tangent plane 53 of the edge 51 is inclined toward the glass substrate 21 as it goes inward of the recess 48. ing.
- the edge 25 of the alignment film 23 is supported by the edge 51 of the recess 48, and the bottom of the recess 48 that supports the edge 25 of the alignment film 23 extends from the alignment film 23. Exposed.
- the maximum angle of the tangent plane 53 at the edge 51 of the recess 48 with respect to the surface of the glass substrate 21 is defined as ⁇ 1max. Further, an angle of the tangent plane 53 of the concave portion 48 with respect to the surface of the glass substrate 21 at a position supporting the edge 25 of the alignment film 23 (alignment film material 24) is ⁇ 1. The angle of the tangent plane 54 on the surface of the edge 25 of the alignment film 23 with respect to the tangential plane 53 is ⁇ 2.
- the maximum angle ⁇ 1max of the edge 51 of the recessed portion 48 with respect to the surface of the glass substrate 21 of the tangent plane 53 is defined to be 5 ° or more. On the other hand, the maximum angle ⁇ 1max is preferably defined to be less than 88 °.
- FIG. 11 is a graph showing the relationship between the maximum angle ⁇ 1max at the edge 51 and the depth of the recessed portion 48 and the spread controllability of the alignment film material 24.
- ⁇ indicates that the edge 51 appropriately supported the alignment film material 24, and X indicates that the alignment film material 24 was not properly supported by the edge 51.
- the viscosity of the alignment film material used in the experiment is 6.5 mPa ⁇ s.
- FIGS. 12 to 14 are enlarged sectional views showing the vicinity of the recessed portion 48 when ⁇ 1max is about 15 °, about 50 °, and about 5 °, respectively.
- the symbol A indicates a position where the angle ⁇ 1 of the tangent plane 53 of the recessed portion 48 becomes the maximum angle ⁇ 1max.
- Reference symbol B indicates the position of the edge 25 of the alignment film 23 (alignment film material 24) that is blocked by the edge 51 of the recess 48.
- the depth of the recess 48 has no correlation with the spread control of the alignment film material 24, and only the maximum angle ⁇ 1max of the edge 51 affects the spread control of the alignment film material 24.
- the maximum angle ⁇ 1max is less than 5 °, the alignment film material 24 spreads without being supported by the edge portion 51.
- the maximum angle ⁇ 1max is 88 ° or more, ⁇ 1max + ⁇ 2 is 90 ° or more and the alignment film cannot be blocked. Therefore, it was found that the alignment film material 24 can be satisfactorily supported at the edge portion 51 when the maximum angle ⁇ 1max is 5 ° or more and less than 88 °.
- the alignment film material 24 flowing from the pixel region 31 side can be blocked by the angle ⁇ 2 at the edge 51.
- the alignment film 23 and the alignment film material 24 swell toward the liquid crystal layer 13 in the vicinity of the edge 51 of the recess 48.
- the region where the alignment film 23 and the alignment film material 24 are raised has a width of about 200 ⁇ m. Further, the thickness a of the raised region of the alignment film material 24 is about 10 ⁇ m or less, and the thickness a of the raised region of the alignment film 23 after curing is about 0.7 ⁇ m. On the other hand, the thickness b of the flat alignment film material 24 on the pixel region 31 side is about 3 ⁇ m, while the thickness b of the flat alignment film 23 after curing on the pixel region 31 side is about 0.1 ⁇ m. is there.
- the counter substrate 12 has a glass substrate (not shown) which is a support substrate.
- a glass substrate (not shown) which is a support substrate.
- a plurality of colored layers (not shown) constituting a color filter (not shown) and a black matrix (not shown) as a light shielding film are formed.
- a common electrode (not shown) made of a transparent conductive film such as ITO is formed on the surface of the color filter. Similar to the TFT substrate 11, the surface of the common electrode is covered with an alignment film (not shown).
- the manufacturing method of the liquid crystal display device 1 includes a step of forming the TFT substrate 11, a step of forming the counter substrate 12, and a step of bonding the TFT substrate 11 and the counter substrate 12 to each other via the liquid crystal layer 13 and the seal member 14. And have.
- the liquid crystal display device 1 forms a frame-shaped seal member 14 on the TFT substrate 11 or the counter substrate 12, drops liquid crystal inside the seal member 14, and then attaches the TFT substrate 11 and the counter substrate 12 to each other. Manufactured by matching.
- the process of forming the TFT substrate 11 includes a process of forming the wiring layers 16 and 18 on the glass substrate 21 that is a transparent support substrate, and a planarizing film 43 so as to cover the wiring layers 16 and 18 on the glass substrate 21. And a step of forming the alignment film 23 directly on the surface of the planarizing film 43 so as to cover the wiring layers 16 and 18.
- the gate wiring 18 In the process of forming the wiring layers 16 and 18, the gate wiring 18, the gate insulating film 41, the silicon film (not shown), the source wiring 16, the passivation film 42, the planarization film 43, the ITO film, etc. are formed on the surface of the glass substrate 21. Form.
- a metal film such as the gate wiring 18 is formed by a sputtering method, and a semiconductor layer, an insulating film, and a channel protective film constituting the TFT are formed by a CVD method and then formed into a predetermined shape by photolithography and wet etching or dry etching, respectively. .
- the concave portion 48 that is recessed from the surface of the flattening film 43 without penetrating the flattening film 43 is viewed from the normal direction of the surface of the glass substrate 21.
- the edge 51 of the recess 48 is disposed in the frame region 32, and the tangent plane of the edge 51 is the inner side of the recess 48. It forms so that it may incline to the glass substrate 21 side as it goes to.
- the recess 48 is formed so as to extend along the formation region of the seal member 14. Further, the recessed portion 48 is disposed between the pixel region 31 and the formation region of the seal member 14.
- the planarizing film 43 can be formed using a photosensitive organic material such as a photocurable acrylic resin or a non-photosensitive insulating film.
- a photosensitive organic material such as a photocurable acrylic resin or a non-photosensitive insulating film.
- the organic material is formed on the glass substrate 21 so as to have a flat surface by, for example, a spin coating method (also possible by a slit coating method or an ink jet method).
- FIG. 7 is a plan view schematically showing a halftone mask 60 for forming the recessed portion 48.
- FIG. 8 is a cross-sectional view showing the planarizing film 43 developed after halftone exposure.
- FIG. 9 is a cross-sectional view showing the planarizing film 43 after post-baking.
- each slit 61 has a width of about 3 ⁇ m and is arranged at a pitch of about 3 ⁇ m. Accordingly, the region where the slit 61 is formed has a width of about 15 ⁇ m as a whole.
- a groove 62 made of a concave bent surface is formed as shown in FIG.
- the planarizing film 43 in which the groove 62 is formed is post-baked and heated, so that the curved surface of the planarizing film 43 becomes a gentle curved surface.
- the groove 62 is heated by heating, and the recessed portion 48 having the curved edge portion 51 is formed.
- the insulating material layer is uniformly formed on the glass substrate 21 by, for example, a CVD method (also possible by a sputtering method or application of a coating type material). After forming with a sufficient film thickness, a photosensitive resist is applied to the entire surface of the insulating material layer. Next, a predetermined resist pattern is formed by photolithography. Thereafter, the recess 48 is formed by etching the insulating material layer (wet etching or dry etching) and removing the resist pattern.
- the alignment film material 24 having fluidity is formed so as to spread from the pixel region to the frame region, and the edge 25 of the alignment film material 24 is formed into the recessed portion.
- the bottom of the recess 48 that supports the edge portion 25 of the alignment film material 24 is exposed from the alignment film material 24.
- an ITO layer is formed on the surface of the planarizing film 43, and a plurality of pixel electrodes 15 are formed by patterning the ITO layer by photolithography and etching. Thereafter, a fluid alignment film material 24 such as polyimide is supplied by an ink jet method so as to cover the pixel electrode 15 and the like.
- the edge 25 of the alignment film material 24 is supported by the edge 51.
- the alignment film material 24 rises toward the liquid crystal layer 13 and is dammed in the vicinity of the edge 51 of the recess 48. Thereafter, the alignment film material 24 is baked to form the alignment film 23. In this way, the TFT substrate 11 is manufactured.
- the TFT substrate 11 is provided with the recessed portion 48 for supporting the alignment film 23 (alignment film material 24), and the glass substrate as the tangential plane 53 moves toward the inside of the recessed portion 48.
- 21 is formed in the recessed portion 48 so that the alignment film 23 (alignment film material 24) is supported by the edge 51, and the edge of the alignment film 23 (alignment film material 24) is supported.
- the edge 25 can be supported even when the alignment film material 24 has a relatively low viscosity.
- the alignment film material 24 is placed closer to the seal member forming region 34 than the edge 51 of the recess 48. Since a groove structure or the like for storing is unnecessary, the alignment film material 24 and the seal member 14 are appropriately suppressed by appropriately suppressing the spread of the alignment film material 24 while greatly reducing the frame region 32 of the liquid crystal display device 1. Can be prevented.
- the alignment film material 24 can be more reliably supported at the edge 51.
- the planarizing film 43 is interposed between the concave portion 48 and the wiring layer in a state in which the concave portion 48 is disposed so as to overlap the wiring layer such as the source wiring 16, the wiring layer is formed by the planarizing film 43. While protecting from an etchant or the like, the recessed portion 48 can be formed to continuously extend regardless of the layout of the wiring layer. Therefore, since the recessed portion 48 can be formed in a ring shape surrounding the pixel region 31 along the seal member forming region 34, the alignment film material 24 can be more appropriately prevented from spreading.
- the alignment film material is accumulated in the groove formed on the substrate, it is unclear to what extent the alignment film material is accumulated in the groove structure, so that the liquid crystal is deposited on the substrate.
- the liquid crystal display device is manufactured by dropping the liquid crystal, it is difficult to appropriately define the volume of the liquid crystal material to be dropped, including the free space in the groove structure. If the volume of the liquid crystal material is less than the required amount, bubbles may occur in the liquid crystal layer.
- the alignment film material 24 is dammed up at the edge 51 of the recess 48 without storing the alignment film material 24 inside the recess 48. Therefore, the volume of the liquid crystal material to be dropped can be maintained substantially constant. Therefore, an appropriate volume of liquid crystal material can be supplied onto the glass substrate 21 to prevent bubbles from being generated in the liquid crystal layer 13.
- the planarizing film 43 is made of a photocurable acrylic resin, the recessed portion 48 and its edge portion 51 can be easily formed into an appropriate shape with good controllability by halftone exposure.
- the recessed portion 48 is formed in a ring shape that seamlessly surrounds the pixel region 31 along the seal member forming region 34.
- the present invention is not limited to this, and the recessed portion 48 is interrupted at least at one location. It may be a shape.
- the recessed portion 48 can be formed in a discontinuous shape in a region where there is no problem even if the alignment film 23 spreads.
- FIG. 15 and FIG. 16 are enlarged plan views showing a part of the TFT substrate in other embodiments.
- the first embodiment the example in which the single concave portion 48 is provided along the seal member forming region 34 has been described.
- the present invention is not limited to this, and a plurality of concave portions 48 are provided as shown in FIG. May be provided along the seal member forming region 34.
- the edge portion 51 of the portion 48 can prevent the alignment film material 24 from spreading.
- the present invention is not limited to this, and as shown in FIG. It is good also as a shape. Even in this case, the spread of the alignment film material 24 can be suitably prevented.
- 17 and 18 are plan views showing enlarged corners of the TFT substrate in other embodiments.
- the recessed portion 48 may be bent at a substantially right angle as shown in FIG. 17, or may be arcuate as shown in FIG.
- the present invention is useful for a liquid crystal display device and a method for manufacturing the same, and is particularly suitable for controlling an application region of an alignment film.
- Liquid crystal display device 11 TFT substrate (first substrate) 12 Counter substrate (second substrate) 13 Liquid crystal layer 14 Seal member 16 Source wiring (wiring layer) 18 Gate wiring (wiring layer) 21 Glass substrate (support substrate) 23 Alignment film 24 Alignment film material 25 Edge 31 pixel area 32 Frame area 34 Seal member forming area 43 Planarizing film (insulating film) 48 Recess 51 edge
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Abstract
Description
次に、本発明の作用について説明する。
図1~図10は、本発明の実施形態1を示している。
次に、上記液晶表示装置1の製造方法について説明する。
したがって、この実施形態1によると、TFT基板11に配向膜23(配向膜材料24)を支持するための凹陥部48を設けると共に、接平面53が凹陥部48の内側へ向かうに連れてガラス基板21へ傾斜するような縁部51を当該凹陥部48に形成したので、その縁部51によって配向膜23(配向膜材料24)を支持すると共に、当該配向膜23(配向膜材料24)の端縁部25を、その配向膜材料24の粘性が比較的低くても支持することが可能になる。
上記実施形態1では、凹陥部48をシール部材形成領域34に沿って画素領域31を途切れなく囲むリング状に形成したが、本発明はこれに限らず、凹陥部48は少なくとも一箇所において途切れた形状であってもよい。例えば、TFT基板11における配線パターン等に応じて、配向膜23が広がっても問題がない領域では、凹陥部48を途切れた形状に形成することが可能である。
11 TFT基板(第1基板)
12 対向基板(第2基板)
13 液晶層
14 シール部材
16 ソース配線(配線層)
18 ゲート配線(配線層)
21 ガラス基板(支持基板)
23 配向膜
24 配向膜材料
25 端縁部
31 画素領域
32 額縁領域
34 シール部材形成領域
43 平坦化膜(絶縁膜)
48 凹陥部
51 縁部
Claims (10)
- 第1基板と、
上記第1基板に対向して配置された第2基板と、
上記第1基板及び第2基板の間に設けられた液晶層と、
上記第1基板及び第2基板の間に設けられて上記液晶層を囲んで封止するシール部材とを備えた液晶表示装置であって、
上記第1基板及び第2基板は、表示領域としての画素領域と、該画素領域の外側周囲の領域であって上記シール部材の形成領域を含む非表示領域としての額縁領域とをそれぞれ有し、
上記第1基板及び第2基板の上記液晶層側には、流動性を有する配向膜材料が硬化することによって形成された配向膜が、上記画素領域から上記額縁領域側へ広がるように形成され、
上記第1基板は、支持基板と、該支持基板上に形成された配線層と、該配線層を覆うように上記支持基板上に形成され、上記支持基板と反対側の表面の一部が上記配向膜によって直接に覆われた絶縁膜とを有し、
上記絶縁膜の表面には、当該絶縁膜を貫通せずに窪んで設けられた凹陥部が形成され、
上記凹陥部は、上記支持基板の表面の法線方向から見て少なくとも一部が上記配線層と重なるように配置され、
上記凹陥部の縁部は、上記額縁領域に配置されると共に、当該縁部の接平面が当該凹陥部の内側へ向かうに連れて上記支持基板側へ傾斜するように形成され、
上記配向膜の端縁部は、上記凹陥部の縁部によって支持されると共に、当該配向膜の端縁部を支持している凹陥部の底は、上記配向膜から露出している
ことを特徴とする液晶表示装置。 - 請求項1に記載された液晶表示装置において、
上記凹陥部は、上記シール部材の形成領域に沿って延びるように形成されている
ことを特徴とする液晶表示装置。 - 請求項1又は2に記載された液晶表示装置において、
上記凹陥部は、上記画素領域と上記シール部材の形成領域との間に配置されている
ことを特徴とする液晶表示装置。 - 請求項1乃至3の何れか1つに記載された液晶表示装置において、
上記配向膜は、上記凹陥部の縁部近傍において上記液晶層側に盛り上がっている
ことを特徴とする液晶表示装置。 - 請求項1乃至4の何れか1つに記載された液晶表示装置において、
上記絶縁膜は、光硬化性樹脂によって構成されている
ことを特徴とする液晶表示装置。 - 互いに対向する第1基板及び第2基板が、表示領域としての画素領域と、該画素領域の外側周囲の領域であってシール部材の形成領域を含む非表示領域としての額縁領域とをそれぞれ有する液晶表示装置を製造する方法であって、
第1基板を形成する工程と、
第2基板を形成する工程と、
上記第1基板と第2基板とを液晶層及びシール部材を介して互いに貼り合わせる工程とを有し、
上記第1基板を形成する工程には、支持基板上に配線層を形成する工程と、上記支持基板上に上記配線層を覆うように絶縁膜を形成する工程と、上記配線層を覆うように上記絶縁膜の表面に直接に配向膜を形成する工程とが含まれ、
上記絶縁膜を形成する工程では、上記絶縁膜の表面に対し、当該絶縁膜を貫通せずに窪んで設けられた凹陥部を、上記支持基板の表面の法線方向から見て少なくとも一部が上記配線層と重なるように形成し、且つ、上記凹陥部の縁部を、上記額縁領域に配置すると共に、当該縁部の接平面が当該凹陥部の内側へ向かうに連れて上記支持基板側へ傾斜するように形成し、
上記配向膜を形成する工程では、流動性を有する配向膜材料を上記画素領域から上記額縁領域へ広がるように形成し、当該配向膜材料の端縁部を上記凹陥部の縁部によって支持すると共に、当該配向膜材料の端縁部を支持している凹陥部の底を上記配向膜材料から露出させる
ことを特徴とする液晶表示装置の製造方法。 - 請求項6に記載された液晶表示装置の製造方法において、
上記絶縁膜を形成する工程では、上記凹陥部を上記シール部材の形成領域に沿って延びるように形成する
ことを特徴とする液晶表示装置の製造方法。 - 請求項6又は7に記載された液晶表示装置の製造方法において、
上記絶縁膜を形成する工程では、上記凹陥部を上記画素領域と上記シール部材の形成領域との間に配置する
ことを特徴とする液晶表示装置の製造方法。 - 請求項6乃至8の何れか1つに記載された液晶表示装置の製造方法において、
上記配向膜を形成する工程では、上記配向膜を上記凹陥部の縁部近傍において上記液晶層側に盛り上がらせる
ことを特徴とする液晶表示装置の製造方法。 - 請求項6乃至9の何れか1つに記載された液晶表示装置の製造方法において、
上記絶縁膜を形成する工程では、上記絶縁膜を光硬化性樹脂によって構成する
ことを特徴とする液晶表示装置の製造方法。
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US13/702,697 US8885127B2 (en) | 2010-06-10 | 2011-05-18 | Liquid crystal display device and method for fabricating the same |
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CN109581752B (zh) * | 2018-12-24 | 2021-07-27 | 惠科股份有限公司 | 配向液的涂布方法及涂布系统 |
CN114779533A (zh) * | 2022-04-11 | 2022-07-22 | Tcl华星光电技术有限公司 | 配向膜及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
EP2581784A4 (en) | 2014-01-01 |
US8885127B2 (en) | 2014-11-11 |
EP2581784A1 (en) | 2013-04-17 |
CN102939560A (zh) | 2013-02-20 |
JPWO2011155133A1 (ja) | 2013-08-01 |
JP5302460B2 (ja) | 2013-10-02 |
US20130077035A1 (en) | 2013-03-28 |
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