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WO2011012423A1 - Fibre discontinue en cellulose régénérée - Google Patents

Fibre discontinue en cellulose régénérée Download PDF

Info

Publication number
WO2011012423A1
WO2011012423A1 PCT/EP2010/059868 EP2010059868W WO2011012423A1 WO 2011012423 A1 WO2011012423 A1 WO 2011012423A1 EP 2010059868 W EP2010059868 W EP 2010059868W WO 2011012423 A1 WO2011012423 A1 WO 2011012423A1
Authority
WO
WIPO (PCT)
Prior art keywords
paper
cellulose
fiber
fibers
staple fiber
Prior art date
Application number
PCT/EP2010/059868
Other languages
German (de)
English (en)
Inventor
Ingo Bernt
Original Assignee
Kelheim Fibres Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kelheim Fibres Gmbh filed Critical Kelheim Fibres Gmbh
Publication of WO2011012423A1 publication Critical patent/WO2011012423A1/fr

Links

Classifications

    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
    • D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
    • D01F2/08—Composition of the spinning solution or the bath
    • D01F2/10—Addition to the spinning solution or spinning bath of substances which exert their effect equally well in either
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/253—Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/26—Formation of staple fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/02—Synthetic cellulose fibres
    • D21H13/08—Synthetic cellulose fibres from regenerated cellulose
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
    • D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D21H17/25—Cellulose
    • D21H17/26—Ethers thereof

Definitions

  • the present invention relates to a regenerated cellulose staple fiber obtained by the viscose method.
  • the invention relates to a regenerated cellulose staple fiber in
  • Short-cut shape which is used in fibrous structures formed by wet processes, e.g. Papers or nonwovens contributes to increase the dry strength.
  • CMC carboxymethylcellulose
  • US 20050092451 A1 describes an aqueous solution of CMC as a binder for dispersible leaves.
  • JP 2004313486 A describes an aqueous solution of CMC as a binder for wet-laid nonwovens.
  • US 3,318,990 describes a process for the production of viscose flat fibers in which, on the one hand, sodium carbonate and on the other hand a water-swelling high molecular substance, e.g. CMC, mixed. The result is a collapsed hollow cross-sectional structure.
  • a water-swelling high molecular substance e.g. CMC
  • the resulting fibers are described as being completely flat.
  • the collapsed cross-sectional structure holds together even when wet.
  • the fibers are suitable according to US 3,318,990 for the production of paper.
  • the object of the present invention is to provide an adjuvant for producing papers, in particular specialty papers for achieving high dry strengths or a binder fiber for nonwovens, which are produced in a wet process.
  • a regenerated cellulose staple fiber selected from the group consisting of
  • B D ⁇ 5, preferably ⁇ 4.5, particularly preferably 3-4,
  • a regenerated cellulose staple fiber selected from the group consisting of standard viscose fibers and solid flat fibers in short cut form (ie with a cut length of 20 mm or less) incorporating CMC is an excellent excipient for producing papers having improved strength is also excellent in the production of wet nonwovens.
  • short cut is commonly used for fibers having a fiber length of 10 mm or less.
  • short cut also includes fibers having a length of up to 20 mm.
  • the short cut fiber according to the invention is selected from the group consisting of standard viscose fibers and solid flat fibers whose cross section has a ratio of width B to thickness D of B: D ⁇ 5, preferably ⁇ 4.5, particularly preferably 3-4.
  • Standard viscose fibers have an irregular ribbed cross-section.
  • solid flat fibers are meant, for the purposes of the present invention, fibers whose cross-section is a continuous cellulose matrix. This distinguishes these fibers from fibers resulting from the collapse of a hollow cross-sectional structure (as described, for example, in U.S. 3,318,990), which is detectable at the cross-section as well as at the rippled surface structure typical of massive flax fibers.
  • massive flat fibers can be obtained by spinning a viscose through a nozzle having openings in the form of a narrow rectangular slit.
  • the cross section of the solid flat fiber according to the invention has a ratio of width B to thickness D of B: D ⁇ 5, preferably ⁇ 4.5, particularly preferably 3-4.
  • the cross section can be influenced in particular by the geometry of the spinneret opening.
  • No. 3,318,990 A describes that only when the width / thickness ratio of a flat fiber is greater than 5 (in particular up to 10-20) is a significant increase in the paper produced from such fibers ascertainable.
  • the binding of the CMC in the fiber according to the invention is stronger than in the case of fibers in which CMC is only subsequently coated onto the cellulosic fiber.
  • the use of the insoluble fiber of the invention also results in less
  • Viscose fibers with a proportion of CMC are known. It is a mixed fiber, which by the incorporation of carboxymethylcellulose in the
  • Viscose spinning composition is obtained.
  • Such fibers have also been produced commercially (US 4,199,367 A, US 4,289,824 A).
  • a Viskosepinnmasse is prepared by the usual methods.
  • the spinning mass is added immediately before spinning a 8-12 wt.% Solution of carboxymethyl cellulose (CMC), so that the desired storage amount based on underivatized cellulose results.
  • Post-processing and drying are carried out by the usual methods.
  • the proportion of incorporated carboxymethyl cellulose in the regenerated cellulose fiber is preferably 5% by weight to 50% by weight, more preferably 15% by weight to 40% by weight, most preferably 20% by weight to 30% by weight, based on underivatized cellulose ,
  • the carboxymethylcellulose may be a commercial product having a degree of substitution DS of 0.6-1.2, preferably 0.65-0.85 and a viscosity (2% solution, 25 ° C.) of 30-800 mPas; preferably 50-100 mPas.
  • the fiber titer of the fiber according to the invention is preferably from 0.5 dtex to 8 dtex, more preferably from 1.3 to 6 dtex.
  • the cutting length of the fiber according to the invention is preferably 2 to 20 mm, more preferably 4 to 8 mm.
  • the cellulose staple fiber according to the invention is outstandingly suitable as a binder fiber for products containing short cut fibers as well as for nonwovens, which are produced in a wet process, in particular as an auxiliary for the production of paper or
  • Paper-like products such as tea bags, gas and fluid filters, security papers and decorative papers. Accordingly, the present invention also relates to a paper or paper-like product, such as tea bags, gas and Fluidf ⁇ lter, security paper, decorative paper containing the cellulase staple fiber according to the invention.
  • the paper or paper-like product according to the invention preferably contains from 10 to 99%, particularly preferably from 15 to 45%, of the cellulosic staple fiber according to the invention.
  • a standard viscose fiber is made by the usual methods. Of the
  • Viscose spinning material is added immediately before spinning the amount of a 10% solution of carboxymethyl cellulose (CMC), so that there is a storage of, for example, 20-30% CMC on cellulose.
  • Post-processing and drying are carried out by the usual methods; The fiber is cut inline to a length of 20 mm or less, especially 4-8 mm.
  • the short-cut fibers can be used as special fibers directly in papermaking.
  • a massive flat fiber can be made by incorporating CMC and spinning through a rectangular spinning aperture.
  • Atro fibers or fiber mixture
  • 300 liters of water Each 75 g of atro fibers (or fiber mixture) are dispersed for this purpose in 300 liters of water.
  • the nonwoven is then placed on a screen belt at a defined take-off speed.
  • nonwovens were produced with a basis weight of about 50 g / m 2 . All webs when wet showed a strength suitable for handling. The nonwovens were then dried without moving in air.
  • Fleece A The fleece shows no appreciable strength in the dried state. It is not possible to handle the fleece without it decaying.
  • Nonwoven in leaf shape to handle is
  • Fleece B The fleece shows a much higher strength than the fleeces A and C.
  • the use of the invention fiber in wet nonwovens thus allows the production of nonwovens with significantly improved dry strength.
  • the fiber of the invention acts here as a binder fiber and thus allows a saving of other binders.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Nonwoven Fabrics (AREA)
  • Artificial Filaments (AREA)
  • Paper (AREA)

Abstract

La présente invention porte sur une fibre discontinue en cellulose régénérée choisie dans le groupe constitué par a) des fibres de viscose standard et b) des fibres plates massives dont la section transversale a un rapport de largeur B à l'épaisseur D de B:D < 5, de préférence < 4,5, de façon plus préférée de 3-4. Dans la fibre discontinue en cellulose, de la carboxyméthylcellulose est incorporée laquelle est caractérisée par une longueur de coupe de 20 mm ou moins. La fibre selon l'invention est appropriée comme adjuvant dans la production de papier ou de non-tissé.
PCT/EP2010/059868 2009-07-31 2010-07-09 Fibre discontinue en cellulose régénérée WO2011012423A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09450140.0 2009-07-31
EP09450140A EP2280099A1 (fr) 2009-07-31 2009-07-31 Fibre de pile de cellulose régénérée

Publications (1)

Publication Number Publication Date
WO2011012423A1 true WO2011012423A1 (fr) 2011-02-03

Family

ID=41429634

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2010/059868 WO2011012423A1 (fr) 2009-07-31 2010-07-09 Fibre discontinue en cellulose régénérée

Country Status (2)

Country Link
EP (1) EP2280099A1 (fr)
WO (1) WO2011012423A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013079305A1 (fr) * 2011-11-29 2013-06-06 Kelheim Fibres Gmbh Fibre de cellulose régénérée
EP3315659A1 (fr) 2016-10-27 2018-05-02 Kelheim Fibres GmbH Fibre artificielle de cellulose et non-tissé ou papier comprenant la fibre de cellulose
US20200002859A1 (en) * 2017-03-03 2020-01-02 Kelheim Fibres Gmbh Use of a viscose fiber
EP3223636B1 (fr) 2014-11-25 2020-03-04 Swedish Match North Europe AB Produit en sachet oral
CN116356442A (zh) * 2023-04-07 2023-06-30 德州学院 一种超细旦再生纤维素纤维及其制备方法

Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1036359A (en) 1963-11-26 1966-07-20 Toyo Spinning Co Ltd Method for converting cellulose ethers into filamentary form
GB1063217A (en) * 1962-08-25 1967-03-30 Kurashiki Rayon Kk Papers and non-woven fabrics containing mixed spun fibres
US3318990A (en) 1962-08-18 1967-05-09 Kurashiki Rayon Co Method of manufacturing flat viscose fibers
GB1088249A (en) * 1963-12-09 1967-10-25 Kurashiki Rayon Kk Cellulose products and method of manufacturing same
US4199367A (en) 1975-11-07 1980-04-22 Avtex Fibers Inc. Alloy rayon
GB2062652A (en) * 1979-10-18 1981-05-28 Chemiefaser Lenzing Inc Absorbent regenerated cellulose fibres
US4289824A (en) 1977-04-22 1981-09-15 Avtex Fibers Inc. High fluid-holding alloy rayon fiber mass
DD214398A1 (de) * 1983-04-04 1984-10-10 Schwarza Chemiefaser Verfahren zur herstellung von celluloseregeneratfasern mit hohem fluessigkeitsrueckhaltevermoegen
JPS60139899A (ja) 1983-12-28 1985-07-24 三島製紙株式会社 耐候性および強度の勝れた水溶紙の製造法
JPH038897A (ja) 1989-03-25 1991-01-16 Lion Corp 水解性・吸収性シート状体およびその製造方法
JPH04174792A (ja) 1990-11-07 1992-06-22 Lion Corp 包装用崩壊性シートおよび包装体
JPH06192991A (ja) 1992-10-29 1994-07-12 Nichirin Kagaku Kogyo Kk 水分散性シートの製造方法
EP1065302A1 (fr) * 1998-12-28 2001-01-03 Pigeon Corporation Fibre reagissant a l'humidite, procede de production de cette fibre, non-tisse et utilisation de cette fibre et de ce non-tisse
JP2004313486A (ja) 2003-04-16 2004-11-11 Kao Corp 水解性清掃物品
US6846924B1 (en) 1996-01-10 2005-01-25 Sca Hygiene Products Ab Method of producing an absorbent material, an absorbent material and absorbent articles including the material in question
US20050092451A1 (en) 2003-10-29 2005-05-05 Hollingsworth & Vose Company Water dispersible products
US20080196188A1 (en) 2005-06-15 2008-08-21 Kelheim Fibres Gmbh Fibrous Composite that is Dissoluble or Decomposable in Water, and Products Manufactured Thereform

Patent Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3318990A (en) 1962-08-18 1967-05-09 Kurashiki Rayon Co Method of manufacturing flat viscose fibers
GB1063217A (en) * 1962-08-25 1967-03-30 Kurashiki Rayon Kk Papers and non-woven fabrics containing mixed spun fibres
GB1036359A (en) 1963-11-26 1966-07-20 Toyo Spinning Co Ltd Method for converting cellulose ethers into filamentary form
GB1088249A (en) * 1963-12-09 1967-10-25 Kurashiki Rayon Kk Cellulose products and method of manufacturing same
US4199367A (en) 1975-11-07 1980-04-22 Avtex Fibers Inc. Alloy rayon
US4289824A (en) 1977-04-22 1981-09-15 Avtex Fibers Inc. High fluid-holding alloy rayon fiber mass
GB2062652A (en) * 1979-10-18 1981-05-28 Chemiefaser Lenzing Inc Absorbent regenerated cellulose fibres
DD214398A1 (de) * 1983-04-04 1984-10-10 Schwarza Chemiefaser Verfahren zur herstellung von celluloseregeneratfasern mit hohem fluessigkeitsrueckhaltevermoegen
JPS60139899A (ja) 1983-12-28 1985-07-24 三島製紙株式会社 耐候性および強度の勝れた水溶紙の製造法
JPH038897A (ja) 1989-03-25 1991-01-16 Lion Corp 水解性・吸収性シート状体およびその製造方法
JPH04174792A (ja) 1990-11-07 1992-06-22 Lion Corp 包装用崩壊性シートおよび包装体
JPH06192991A (ja) 1992-10-29 1994-07-12 Nichirin Kagaku Kogyo Kk 水分散性シートの製造方法
US6846924B1 (en) 1996-01-10 2005-01-25 Sca Hygiene Products Ab Method of producing an absorbent material, an absorbent material and absorbent articles including the material in question
EP1065302A1 (fr) * 1998-12-28 2001-01-03 Pigeon Corporation Fibre reagissant a l'humidite, procede de production de cette fibre, non-tisse et utilisation de cette fibre et de ce non-tisse
JP2004313486A (ja) 2003-04-16 2004-11-11 Kao Corp 水解性清掃物品
US20050092451A1 (en) 2003-10-29 2005-05-05 Hollingsworth & Vose Company Water dispersible products
US20080196188A1 (en) 2005-06-15 2008-08-21 Kelheim Fibres Gmbh Fibrous Composite that is Dissoluble or Decomposable in Water, and Products Manufactured Thereform

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
J. LAINE; T. LINDSTRÖM, IPW - DAS PAPIER, 2001, pages 40 - 45
K. ERHARD; K. FROHBERG: "Verbesserung der Spaltfestigkeit von Papier durch CMCmodifizierte Faserstoffe", PTS-FORSCHUNGSBERICHT, 29 September 2005 (2005-09-29)
NR. L; J. LAINE; G. G. NORDMARK; T. LINDSTRÖM, NORDIC PULP AND PAPER RESEARCH JOURNAL, vol. 15, no. 5, 2000, pages 520 - 526

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103958749A (zh) * 2011-11-29 2014-07-30 凯尔海姆纤维制品有限责任公司 再生纤维素纤维
CN103958749B (zh) * 2011-11-29 2016-10-05 凯尔海姆纤维制品有限责任公司 再生纤维素纤维
WO2013079305A1 (fr) * 2011-11-29 2013-06-06 Kelheim Fibres Gmbh Fibre de cellulose régénérée
US11149367B2 (en) 2011-11-29 2021-10-19 Kelheim Fibres Gmbh Regenerated cellulose fiber
TWI626342B (zh) * 2011-11-29 2018-06-11 開爾海姆纖維公司 再生纖維素纖維和含彼之纖維束，及它們的製造方法和用於製造不織物與紙的用途
EP3223636B1 (fr) 2014-11-25 2020-03-04 Swedish Match North Europe AB Produit en sachet oral
EP3315659A1 (fr) 2016-10-27 2018-05-02 Kelheim Fibres GmbH Fibre artificielle de cellulose et non-tissé ou papier comprenant la fibre de cellulose
KR20190066016A (ko) * 2016-10-27 2019-06-12 켈하임 피브레스 게엠베하 인조 셀룰로오스 섬유 및 상기 셀룰로오스 섬유를 포함하는 부직포 제품 또는 직물
WO2018078094A1 (fr) 2016-10-27 2018-05-03 Kelheim Fibres Gmbh Fibre cellulosique artificielle et produit ou tissu non tissé comportant la fibre cellulosique
KR102376083B1 (ko) 2016-10-27 2022-03-18 켈하임 피브레스 게엠베하 인조 셀룰로오스 섬유 및 상기 셀룰로오스 섬유를 포함하는 부직포 제품 또는 직물
US11313075B2 (en) 2016-10-27 2022-04-26 Kelheim Fibres Gmbh Man-made cellulosic fiber and nonwoven product or fabric comprising the cellulosic fiber
US20200002859A1 (en) * 2017-03-03 2020-01-02 Kelheim Fibres Gmbh Use of a viscose fiber
US12104299B2 (en) * 2017-03-03 2024-10-01 Kelheim Fibres Gmbh Use of a viscose fiber
CN116356442A (zh) * 2023-04-07 2023-06-30 德州学院 一种超细旦再生纤维素纤维及其制备方法
CN116356442B (zh) * 2023-04-07 2025-02-21 德州学院 一种超细旦再生纤维素纤维及其制备方法

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