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WO2010016079A1 - Procédé de fabrication de matériau de matrice céramique pour composant de frottement de freins et matériau de matrice céramique fabriqué par ce procédé - Google Patents

Procédé de fabrication de matériau de matrice céramique pour composant de frottement de freins et matériau de matrice céramique fabriqué par ce procédé Download PDF

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Publication number
WO2010016079A1
WO2010016079A1 PCT/IT2008/000543 IT2008000543W WO2010016079A1 WO 2010016079 A1 WO2010016079 A1 WO 2010016079A1 IT 2008000543 W IT2008000543 W IT 2008000543W WO 2010016079 A1 WO2010016079 A1 WO 2010016079A1
Authority
WO
WIPO (PCT)
Prior art keywords
per
foregoing
mixture
matrix material
ceramic matrix
Prior art date
Application number
PCT/IT2008/000543
Other languages
English (en)
Inventor
Simone Turani
Konstantin Vikoulov
Massimiliano Valle
Marco Orlandi
Original Assignee
Freni Brembo S.P.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Freni Brembo S.P.A. filed Critical Freni Brembo S.P.A.
Priority to JP2011521691A priority Critical patent/JP5959853B2/ja
Priority to EP08876020.2A priority patent/EP2307759B1/fr
Priority to CN200880130538.7A priority patent/CN102138022B/zh
Priority to PCT/IT2008/000543 priority patent/WO2010016079A1/fr
Priority to US13/056,076 priority patent/US8960384B2/en
Priority to ES08875901.4T priority patent/ES2682087T3/es
Priority to US13/056,218 priority patent/US20110198170A1/en
Priority to PCT/IB2008/055519 priority patent/WO2010015897A1/fr
Priority to JP2011521648A priority patent/JP6081059B2/ja
Priority to CN200880130598.9A priority patent/CN102119289B/zh
Priority to PL08875901T priority patent/PL2310714T3/pl
Priority to EP08875901.4A priority patent/EP2310714B1/fr
Publication of WO2010016079A1 publication Critical patent/WO2010016079A1/fr
Priority to JP2015102996A priority patent/JP6046206B2/ja

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D69/00—Friction linings; Attachment thereof; Selection of coacting friction substances or surfaces
    • F16D69/02—Composition of linings ; Methods of manufacturing
    • F16D69/025—Compositions based on an organic binder
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/56—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
    • C04B35/565—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide
    • C04B35/571—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide obtained from Si-containing polymer precursors or organosilicon monomers
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/0022—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof obtained by a chemical conversion or reaction other than those relating to the setting or hardening of cement-like material or to the formation of a sol or a gel, e.g. by carbonising or pyrolysing preformed cellular materials based on polymers, organo-metallic or organo-silicon precursors
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D65/00—Parts or details
    • F16D65/02—Braking members; Mounting thereof
    • F16D65/04—Bands, shoes or pads; Pivots or supporting members therefor
    • F16D65/092—Bands, shoes or pads; Pivots or supporting members therefor for axially-engaging brakes, e.g. disc brakes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D69/00—Friction linings; Attachment thereof; Selection of coacting friction substances or surfaces
    • F16D69/02—Composition of linings ; Methods of manufacturing
    • F16D69/027—Compositions based on metals or inorganic oxides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00362—Friction materials, e.g. used as brake linings, anti-skid materials
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D69/00—Friction linings; Attachment thereof; Selection of coacting friction substances or surfaces
    • F16D2069/001—Material of friction lining and support element of same or similar composition
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D69/00—Friction linings; Attachment thereof; Selection of coacting friction substances or surfaces
    • F16D69/04—Attachment of linings
    • F16D2069/0425—Attachment methods or devices
    • F16D2069/0441—Mechanical interlocking, e.g. roughened lining carrier, mating profiles on friction material and lining carrier
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D69/00—Friction linings; Attachment thereof; Selection of coacting friction substances or surfaces
    • F16D69/04—Attachment of linings
    • F16D2069/0425—Attachment methods or devices
    • F16D2069/0483—Lining or lining carrier material shaped in situ
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2200/00—Materials; Production methods therefor
    • F16D2200/0034—Materials; Production methods therefor non-metallic
    • F16D2200/0039—Ceramics
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2200/00—Materials; Production methods therefor
    • F16D2200/0034—Materials; Production methods therefor non-metallic
    • F16D2200/0039—Ceramics
    • F16D2200/0043—Ceramic base, e.g. metal oxides or ceramic binder
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2200/00—Materials; Production methods therefor
    • F16D2200/006—Materials; Production methods therefor containing fibres or particles
    • F16D2200/0069—Materials; Production methods therefor containing fibres or particles being characterised by their size
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16D—COUPLINGS FOR TRANSMITTING ROTATION; CLUTCHES; BRAKES
    • F16D2200/00—Materials; Production methods therefor
    • F16D2200/0082—Production methods therefor
    • F16D2200/0086—Moulding materials together by application of heat and pressure

Definitions

  • This invention concerns a method for making a ceramic matrix material for friction components of brakes, in particular disc brakes, as well as a ceramic matrix material produced by this method.
  • This invention further concerns a method for making disc brake pads incorporating the said ceramic matrix material.
  • Ceramic matrix materials are widely used for making friction components of brakes.
  • ceramic matrix materials given their characteristics of refractoriness, mean a reduction in heat transmission from the disc to the hydraulic braking system in comparison with friction materials obtained for example by sinterisation of metal powders.
  • a recently spreading technique is based on pyrolysis of ceramic polymer precursors (polymer pyrolysis), normally consisting of organic siliconic polymers
  • This technique involves a process of heating a mixture of siliconic ceramic precursors and appropriate fillers in a controlled or inert atmosphere (e.g. argon flow) at temperatures greater than 800 0 C to achieve the passage from organic to inorganic polymeric structure, with the formation of silicium oxycarbides and/or silicium carbides or nitrides (SiC or Si 3 N 4 ).
  • a controlled or inert atmosphere e.g. argon flow
  • silicium oxycarbides and/or silicium carbides or nitrides SiC or Si 3 N 4
  • pyrolysis offers various advantages both from a strictly operational viewpoint and in the characteristics of the final product.
  • the pyrolysis technique allows better control of the form and purity of the final product and the possibility of working at lower temperatures (800 - 1500 0 C).
  • the friction material is made by setting out from a mixture of one or more organic ceramic precursors (carbosil-siliconic resin), reinforcing fibres (e.g. fibres of carbon, alumina, silicium nitrite or carbide) and fillers (e.g. powders of silicium carbide, graphite, alumina, mullite, silica, titanium oxide, silicium or boron nitride).
  • the mixture is then cold-compacted in a mould. There follows a heating phase within the mould itself for polymerisation of the ceramic precursor and the obtaining of a green body.
  • the green body then undergoes pyrolysis in an inert atmosphere at temperatures between 800 0 C and 1.100°C.
  • the pyrolysis operational cycle envisages a first phase of heating from surrounding temperature to approximately 150 0 C at a speed of around 2°C/min, followed by a second heating phase to 400°C at a speed of 0.4°C/min.
  • the third and fourth heating phases are, respectively, to 760°C at a speed of 0.18°C/min and to 87O 0 C at a speed of 0.46°C/min.
  • the product is then maintained at 870 0 C for about 4 hours and then cooled to surrounding temperature at a speed of approximately 1.2°C per minute.
  • the heating phase requires an overall time of approximately 48 hours and the cooling phase about 12 hours.
  • the support plate is generally in metal (steel) capable of bearing the compression and flexion stresses that typically occur during braking.
  • One limitation of the pyrolysis technique in common moreover with the fusion technique, concerns the impossibility of obtaining the final friction component already directly bonded with the metal support plate. Pyrolysis temperatures (greater than 800 0 C) would in fact lead to unacceptable deformations of the metal support plates traditionally employed.
  • the purpose of this invention is therefore to eliminate the drawbacks of the well known technique described above by supplying a process for the creation of a ceramic matrix friction material based on polymeric pyrolysis which envisages considerable reduction in working time while producing a ceramic matrix friction material whose performances, in terms of friction coefficient and wear resistance, are at least equivalent to those of traditional ceramic matrix friction materials.
  • a further purpose of this invention is to supply a ceramic matrix friction material whose performances, in terms of friction coefficient value and wear resistance, are superior to those of traditional ceramic matrix friction materials.
  • a further purpose of this invention is to supply a method for making disc brake pads which simplifies bonding of the friction component in ceramic matrix material and the metal support plate.
  • This invention concerns a method for making a ceramic matrix material particularly suitable for friction components of brakes, such as the friction portions of disc brake pads.
  • the ceramic matrix friction material produced in accordance with the method of the invention may be used for the production of pads that cooperate tribologically both with disc brakes in composite ceramic material (CCM) and with disc brakes in grey cast iron, ensuring optimal performances in terms of wear resistance, friction and running-in (understood as the time taken to achieve optimal functioning conditions).
  • CCM composite ceramic material
  • the invention moreover concerns a method for creating disc brake pads incorporating the ceramic matrix material.
  • the invention method permits direct bonding of the friction component of a disc brake pad with the related metal support elements (metal support plate) during the production phases of the friction component itself (in ceramic matrix material) without the need to envisage a specific final assembly phase.
  • the method of making a ceramic matrix material for brake friction components consists of the following operational phases:
  • a) prepare a mixture of at least one siliconic type ceramic precursor, of particles of hard materials suitable as abrasives, of particles of substances suitable as lubricants and particles of metal materials; [0036] b) hot-press the mixture to obtain a green body;
  • the mixture includes a catalyst suitable for favouring reticulation of the ceramic precursor during the hot-pressing phase.
  • a suitable catalyst in the initial mixture for the reactions of reticulation of the ceramic precursor permits achievement of a highly accelerated reticulation of the ceramic precursor precisely on completion of the pressing phase and therefore the creation of an extensive ramified polymeric structure within the green body.
  • Accelerated reticulation of the precursor carries a series of advantages.
  • the green body obtained at the end of the hot-pressing phase has such properties of mechanical resistance as to make it easy to manipulate, with simplification of the subsequent work process phases.
  • the extensive ramified polymeric structure created during the pressing phase has the effect of "restraining" the ceramic precursor molecules during the pyrolysis phase, reducing their volatility and therefore increasing the ceramic yield.
  • This extensive ramified structure involves - at least partially - the particles of the additives in the initial mixture (abrasives, lubricants, metals) which are thus incorporated into the structure itself, with advantages both in terms of performances
  • the extensive ramified polymeric structure is maintained in the ceramic matrix material, although modified following the chemical-physical transformations induced by the pyrolysis process, and ensures that the final ceramic matrix material too will have good properties of mechanical resistance, with special reference to wear resistance, to the elastic module and to compressibility.
  • the pyrolysis process is carried out at temperatures below 800 0 C.
  • the good mechanical properties that the extensive ramified polymeric structure gives the green body mean that the degree of progress of the pyrolysis process (temperature and times) can be tailored as required. This in turn means that the degree of ceramisation in the final ceramic matrix material can be planned in function of the latter's performance characteristics.
  • pyrolysis at temperatures below 800 0 C and especially between 400 0 C and 600 0 C results in considerable improvement in friction material performances.
  • the graphs in Figure 3 show the results of braking tests (friction coefficient in function of number of braking operations) carried out on three different disc brake pads.
  • Curves (a) and (b) refer to two pads created in accordance with the invention, with maximum pyrolysis temperatures of respectively 500 0 C and 700°C.
  • Curve (c) refers to a traditional pad with maximum pyrolysis temperature of 900 0 C.
  • a comparison of the graphs shows the increase of the friction coefficient in the pads produced as per the invention, an increase that is more marked in the pads created with a pyrolysis temperature between 400 0 C and 600 0 C.
  • the method of the invention includes at least one first phase of mixing the basic components, a second phase of hot-pressing the mixture and a third phase of pyrolysis of the green body (or moulded body).
  • the phase of mixing the basic components of the ceramic matrix material should preferably be done in a horizontal blade mixer. However other types of mixers may be envisaged, depending on the characteristics and quantities of the components to be mixed.
  • the phase of mixing the various components takes place in two stages.
  • the polymeric ceramic precursor is mixed with the appropriate catalyst (for reticulation reactions) in the absence of the other components. In this way a more homogeneous mixture is obtained in terms of catalyst distribution and therefore (on completion of the pressing phase) a reticulation of the precursor spread throughout the mass of the material. [0055] Most favourably, this first mixing stage is carried out for sufficient time to ensure suitable mixing, preferably between 1 and 3 minutes. [0056] In the second mixing stage all the other components are added to the precursor-catalyst mixture: abrasives, lubricants and metal materials. [0057] Most favourably, this second mixing stage is carried out for sufficient time to ensure suitable mixing, preferably between 3 and 5 minutes.
  • the hot-pressing phase is preferably carried out with a vertical press operating in compression on a steel mould.
  • the mould should be a plate (or matrix) with a through aperture and a perimeter section corresponding to the form to be given to the body in ceramic matrix material (e.g. the friction portion of the pad).
  • the plate-matrix may be equipped with one, two or more apertures.
  • the operation begins by blocking one end of the through aperture (preferably the lower one, with reference to a horizontal orientation of the plate- matrix in the press) using the head of the punch with which the press is equipped.
  • the aperture (which defines a loading chamber) is then filled with the mixture.
  • the upper end is then closed with a metal plate of shape and thickness appropriately selected in function of the pad applications. With the plate suitably locked in position pressing is begun by actuating the punch.
  • the temperature inside the mould is measured with thermocouples inserted in the mould itself.
  • Presses and moulds other than the one described above may be envisaged.
  • Jointly with or separately from what is described above, during the hot- pressing phase the pressures exerted on the material in the mould should preferably be between 250 and 500 Kg/cm 2 .
  • the pressing phase should preferably be carried out at temperatures between 120°C and 150°C to permit fluidification of the ceramic precursor and the achievement of viscosity values such as to facilitate close contact and bonding between the precursor and the other components of the mixture.
  • the pressing phase should preferably be carried out with alternate cycles of application and release of force.
  • the pressing phase envisages three consecutive cycles of application and release of force, each lasting about 30 seconds (15 seconds of application and 15 seconds of release). There follows a final phase of continuous application of force for approximately 90 - 210 seconds.
  • the overall pressing phase requires a period of time that varies between 3 and 5 minutes. The pressing times and temperatures allow the well fluidified ceramic precursor to spread homogeneously to all portions of the mould and among the particles of the various mix components.
  • the support plate is co-pressed with the mixture of precursor, catalyst and filler and then undergoes pyrolysis together with the green body.
  • a characterising aspect of the invention is that the pyrolysis process in carried out at temperatures below 800 0 C.
  • the best results in terms of improving friction material performances are obtained by carrying out the pyrolysis process in such a way as to reach maximum temperatures between 400 and 600 0 C.
  • the pyrolysis process is carried out envisaging a time at maximum temperature between 3 and 5 hours, and preferably 4 hours.
  • the speed of heating the green body from surrounding to maximum temperature should preferably be between 4 and 6°C/min, preferably 5°C/min.
  • the pyrolysis process should preferably be carried out in an isothermal kiln. [0077] Most favourably, with view to avoiding oxidative phenomena that would alter the ceramisation processes, pyrolysis is carried out in an inert atmosphere.
  • the inert atmosphere should preferably be created with a flow of argon or nitrogen, in cases where the formation of silicium oxycarbides is preferred (with general formula SiO x C y ) in the ceramic matrix material.
  • argon or nitrogen in cases where the formation of silicium oxycarbides is preferred (with general formula SiO x C y ) in the ceramic matrix material.
  • Different atmospheres may also be envisaged, for example in ammonia flow, in cases where the formation of silicium oxynitrides is desired (with general formula SiO x Ny) in the ceramic matrix material.
  • the support plate is bonded to the already created friction material.
  • the essential purpose of these phases is to prepare the ceramic matrix material body in such a way that it can be subsequently coupled - in accordance with envisaged tolerances - with support elements (e.g. a metal support plate) in order to create a disc brake pad.
  • the method may also envisage, on completion of the above phases of adjustment and/or surface refinishing phases, a phase of assembly of the friction component with a metal support plate by means of suitable fixing elements such as bolts, rivets or glue.
  • a phase of assembly of the friction component with a metal support plate by means of suitable fixing elements such as bolts, rivets or glue.
  • the surface finishing phase should be carried out after the phase of assembling the friction component and the support plate.
  • the elements supporting the friction component are bonded to the latter directly during the phases of creating the friction material.
  • the mixture to be pressed is composed as follows (percentages expressed in weight with regard to the mixture): ceramic precursor and catalyst between 5 and 10%; abrasives between 20% and 30%; metal materials not greater than 60%; lubricants not greater than 50%.
  • the ceramic polymeric precursor is of a siliconic type and may in particular be selected from the group including polysilanes, polycarbosilanes, polysilazanes and polysiloxanes with general formula [ - - ]n-
  • the precursor should be selected from the polysiloxanes, independently of the substituting functional groups and of the degree of ramification of the polymer, with general formula [ - RSiO 1 5 - ] n , where R indicates hydrogen or an organic functional group (alkylic, acrylic etc).
  • the precursor should be selected from the sesquisiloxanes and in particular the polymethyl-sesquisiloxanes. [0091] Mixtures of two or more different organic precursors may be envisaged.
  • the ceramic precursor's weight percentage in the mixture is between 6% and 9%.
  • the catalyst should be selected from organic coordination compounds with metals selected from the group including zinc, copper, aluminium, iron, zirconium, vanadium, chromium, manganese, cobalt, nickel and titanium.
  • the catalyst is selected from the acetonates, the beta- dicetonates and the carboxylates.
  • An especially preferred catalyst is zinc or zirconium acetylacetonate.
  • the catalyst is present with a stoichiometric percentage with regard to the ceramic precursor, preferably a percentage between 0.15% and 0.3% of the mixture weight.
  • the ceramic precursor and catalyst used should be in powder form. But components in other forms, such as fluids, may also be used.
  • the abrasives consist of powdered silicium carbide.
  • other materials with hardness properties such as to function as abrasives may also be used, such as for example boron carbide, silicium, zircon, zirconium oxide
  • silicium carbide is in the form of powder in two different particle sizes.
  • the relationship between the average diameters of the two powders is between 9 and 11 , and preferably 10.
  • Average diameter of a powder is intended as the value corresponding to d 50 of the particle size distribution curve.
  • the differentiated particle size of the silicium carbide powder means that a compatibly sized abrasive can be supplied to all the remaining components of the mixture.
  • the two different particle sizes result in abrasives that operate at different energy levels, to the advantage of final friction material performances.
  • the smaller particle size abrasives wear out there is a progressive "crumbling" of the larger particle size abrasives. This results in an averagely constant presence of smaller particle size abrasives.
  • the silicium carbide powders in the two different particle sizes should have average diameters between 1 ⁇ m and 600 ⁇ m.
  • the weight ratio between the silicium carbide powders of greater and lesser particle size is between 0.8 and 1.8.
  • the weight ratio between larger and smaller particle size silicium carbide powder should be between 0.8 and 1.2, preferably 1.
  • the weight ratio between larger and smaller particle size silicium carbide powder should be between 1.2 and 1.8, preferably 1.5.
  • the metal particles consist of particles in iron and/or iron alloy.
  • metal particles replacing or in addition to particles in iron and/or iron alloy consist of particles in copper and/or brass.
  • the particles in copper and brass, individually or mixed are present in a percentage of less than 20% of mixture weight.
  • the term "particle” is intended to include parts of materials in the form of both powders and fibres.
  • steel wool is especially preferred.
  • the metal particles (iron, iron alloys, copper and/or brass) in powder form should have an average diameter of less than 300 ⁇ m, whereas metal particles in fibre form (iron, iron alloys, copper and/or brass) should have an average diameter of less than 100 ⁇ m and a length of less than 1 mm.
  • the lubricants consist of graphite in powder.
  • the lubricants may consist of powdered coke, tin sulphide and/or tin.
  • the percentage of graphite should be between 9% and 13% of mixture weight while powdered coke, tin sulphide and tin (where envisaged) should have weights of less than 35%, 10% and 5% respectively with regard to the mixture.
  • the ceramic matrix friction material produced with the invention method may be used to manufacture pads that cooperate tribologically with disc brakes in composite ceramic material (CCM) or in grey cast iron, guaranteeing optimum performance in both cases in terms of value of friction coefficient stability and wear resistance.
  • CCM composite ceramic material
  • the mixture undergoing the pressing phase should have the following general composition (percentages expressed in weight with regard to the mixture): ceramic precursor and catalyst between 5 and 10%; abrasives between 20% and 30%; metal materials between 25% and 60%; lubricants between 10% and 50%.
  • the weight ratio between the silicium carbide powder with greater particle size and the powder of lesser particle size should be between 1.2 and 1.8, and preferably 1.5.
  • the greater size particle powdered silicium carbide (SiC) is present in a percentage between 12% and 18% of mixture weight while the percentage of finer SiC powder is between 6% and 12% of mixture weight.
  • the metal particles consist of powdered iron, from 5% to 20% of mixture weight, steel wool from 5% to 30% of mixture weight and (where envisaged) copper and/or brass powder and/or fibres in percentages less than 20% of mixture weight.
  • Graphite preferably in powder form, constitutes between 9% and
  • Example 1 [00129] Mix 780 grams of polymethyl-sesquisiloxane resin (CH 3 - SiO 3/2 ) n in Wacker - Belsil ® PMS MK Powder (softening interval 50-60 0 C) and 20 grams of powdered zinc acetylacetonate in a horizontal blade mixer for approximately 2 minutes. Then add 1.500 grams of powdered SiC class FEPA F36 (average diameter 525 ⁇ m) and 1.000 grams of powdered SiC class FEPA F220 (average diameter 58 ⁇ m). Continue by adding 1.800 grams of copper in powder, 2.700 grams of steel wool, 1.000 grams of iron in powder and lastly 1.200 grams of graphite in powder. The second phase of mixing is protracted for approximately 4 minutes.
  • the mixture's overall composition is as follows (percentages expressed in weight with regard to the mixture): 15% of powdered SiC F36; 10% powdered SiC F220; 18% copper in powder; 27% steel wool; 10% iron in powder;
  • the copper and iron powders have an average diameter of approximately 200 ⁇ m and approximately 250 ⁇ m respectively.
  • the steel wool has an average diameter of approximately 80 ⁇ m and an average length of approximately 0.8 mm.
  • the graphite powder has an average diameter of approximately 600 ⁇ m.
  • a portion of the mixture thus obtained then undergoes a hot-pressing phase in a vertical press in order to obtain the green body, as well as the accelerated reticulation of the polymethyl-sesquisiloxane resin.
  • the mixture and a steel plate are pressed simultaneously.
  • a plate (or matrix) with a through aperture and a substantially rectangular perimeter section corresponding to the form to be given to the body in ceramic matrix material.
  • the aperture has an area of approximately 60 cm 2 and a depth of approximately 8 cm.
  • the operation begins by blocking the lower end of the through aperture, using the head of the punch with which the press is equipped.
  • the aperture is then filled with the mixture and the upper end closed with a metal plate about 5 mm thick. With the plate suitably locked in position, pressing is begun by actuating the punch.
  • the temperature inside the mould (measured by means of thermocouples) is maintained around 12O 0 C.
  • the maximum pressure applied during pressing is around 400 Kg/cm 2 .
  • Three consecutive cycles of application and release of force are envisaged, each lasting about 30 seconds (15 seconds of application and 15 seconds of release).
  • the overall pressing phase requires a period of approximately 4 minutes.
  • the green body obtained on completion of the pressing phase has a thickness of approximately 16 mm, to which the (unvaried) thickness of the plate must be added.
  • the ceramic matrix material thus obtained has a thickness of approximately 16 mm (excluding the thickness of the steel plate) and weighs approximately 300 grams. [00139] The body then undergoes finishing work in order to bring the thickness to 14 or 15 mm, depending on the end use of the pad.
  • Example 2
  • Wacker - Belsil ® PMS MK Powder softening interval 50-60 0 C
  • 20 grams of powdered zinc acetylacetonate in a horizontal blade mixer for approximately 2 minutes.
  • 1.500 grams of powdered SiC class FEPA F100 average diameter 129 ⁇ m
  • 1.000 grams of powdered SiC class FEPA F500 average diameter d 50 12.8 ⁇ m.
  • 1.800 grams of brass in powder 2.700 grams of steel wool, 900 grams of iron in powder, 1.000 grams of graphite in powder and lastly 300 grams of tin in powder.
  • the second phase of mixing is protracted for approximately 4 minutes.
  • the mixture's overall composition is as follows (percentages expressed in weight with regard to the mixture): 15% of powdered SiC F100; 10% powdered SiC F500; 18% brass in powder; 27% steel wool; 9% iron in powder; 10% graphite in powder; 3% tin in powder; 7.8% polymethyl-sesquisiloxane resin; 0.2% zinc acetylacetonate.
  • the brass and iron powders have an average diameter of approximately 250 ⁇ m and approximately 200 ⁇ m respectively.
  • the steel wool has an average diameter of approximately 80 ⁇ m and an average length of approximately 0.6 mm.
  • the graphite and tin powders have an average diameter of approximately 400 ⁇ m and approximately 80 ⁇ m respectively.
  • a portion of the mixture thus obtained then undergoes a hot-pressing phase in a vertical press in order to obtain the green body, as well as the accelerated reticulation of the sesquisiloxane resin.
  • the mixture and a steel plate are pressed simultaneously.
  • a plate (or matrix) with a through aperture and a substantially rectangular perimeter section corresponding to the form to be given to the body in ceramic matrix material.
  • the aperture has an area of approximately 60 cm 2 and a depth of about 8 cm.
  • the operation begins by blocking the lower end of the through aperture, using the head of the punch with which the press is equipped. The aperture is then filled with the mixture and the upper end closed with a metal plate about 5 mm thick.
  • pressing is begun by actuating the punch.
  • the temperature inside the mould is maintained around 130 0 C.
  • the maximum pressure applied during pressing is around 450 Kg/cm 2 .
  • Three consecutive cycles of application and release of force are envisaged, each lasting about 30 seconds (15 seconds of application and 15 seconds of release).
  • the overall pressing phase requires a period of approximately 5 minutes.
  • the green body obtained on completion of the pressing phase has a thickness of approximately 16 mm, to which the (unvaried) thickness of the plate must be added.
  • the green body is heated from surrounding temperature (25°C) to approximately 400 0 C at a speed of approximately 6°C/min and kept at 400 0 C for approximately 4 hours and 30 minutes.
  • the ceramic matrix material thus obtained has a thickness of approximately 16 mm (excluding the thickness of the steel plate) and weighs approximately 300 grams.
  • the body in ceramic matrix material then undergoes finishing work in order to bring the thickness to 14 or 15 mm, depending on the end use of the pad.
  • Example 3 [00151] Mix 780 grams of cyclopentasiloxane resin Wacker - Belsil ® RG100 and 20 grams of powdered zinc acetylacetonate in a horizontal blade mixer for approximately 2 minutes. Then add 1.300 grams of powdered SiC class FEPA F46 (average diameter 370 ⁇ m) and 800 grams of powdered SiC class FEPA F280 (average diameter dso 36.5 ⁇ m). Continue by adding 2.500 grams of steel wool, 300 grams of iron in powder, 1.000 grams of graphite in powder, 3.000 grams of coke in powder and lastly 300 grams of tin in powder. The second phase of mixing is protracted for approximately 4 minutes.
  • the mixture's overall composition is as follows (percentages expressed in weight with regard to the mixture): 13% powdered SiC F46; 8% powdered SiC F280; 25% steel wool; 3% iron in powder; 10% graphite in powder; 30% coke in powder; 3% tin in powder; 7.8% siliconic resin; 0.2% zinc acetylacetonate.
  • the iron powder has an average diameter of approximately 150 ⁇ m.
  • the steel wool has an average diameter of approximately 60 ⁇ m and an average length of approximately 0.5 mm.
  • the graphite, coke and tin powders have an average diameter of approximately 700 ⁇ m, approximately 600 ⁇ m and approximately 90 ⁇ m respectively.
  • a portion of the mixture thus obtained then undergoes a hot-pressing phase in a vertical press in order to obtain the green body, as well as the accelerated reticulation of the siloxanic resin.
  • the mixture and a steel plate are pressed simultaneously.
  • a plate (or matrix) with a through aperture and a substantially rectangular perimeter section corresponding to the form to be given to the body in ceramic matrix material.
  • the aperture has an area of approximately 60 cm 2 and a depth of about 8 cm.
  • the operation begins by blocking the lower end of the through aperture, using the head of the punch with which the press is equipped. The aperture is then filled with the mixture and the upper end closed with a metal plate about 5 mm thick.
  • pressing is begun by actuating the punch.
  • the temperature inside the mould is maintained around 150 0 C.
  • the maximum pressure applied during pressing is around 350 Kg/cm 2 .
  • Three consecutive cycles of application and release of force are envisaged, each lasting about 30 seconds (15 seconds of application and 15 seconds of release).
  • the overall pressing phase requires a period of approximately 5 minutes.
  • the green body obtained on completion of the pressing phase has a thickness of approximately 16 mm, to which the (unvaried) thickness of the plate must be added.
  • the green body is heated from surrounding temperature (25°C) to approximately 600 0 C at a speed of approximately 4°C/min and kept at 600 0 C for approximately 3 hours and 30 minutes.
  • the ceramic matrix material thus obtained has a thickness of approximately 16 mm (excluding the thickness of the steel plate) and weighs approximately 300 grams.
  • the mixture for the pressing phase has the following general composition (percentages expressed in weight with regard to the mixture): ceramic precursor and catalyst between 5 and 10%; abrasives between 20% and 30%; metal materials between 30% and 60%; lubricants between 10% and 40%.
  • the weight ratio between the silicium carbide powder with greater particle size and the powder of lesser particle size should be between 0.8 and 1.2, and preferably 1.
  • the greater size particle powdered silicium carbide (SiC) is present in a percentage between 10% and 15% of mixture weight.
  • the metal particles consist of steel wool from 20% to 30% of mixture weight (which may be wholly or partly replaced by powdered iron) and (where envisaged) copper and/or brass powder and/or fibres in percentages less than 20% of mixture weight.
  • the material for discs in CCM also includes silicium among the particles, preferably in powder form.
  • silicium powder is present with a weight percentage between 9 and 11% of the mixture, preferably 10%.
  • the silicium powder preferably has an average diameter of less than 50 ⁇ m.
  • Graphite preferably in powder form, constitutes between 11% and
  • mixture weight 13% of mixture weight, preferably 12%. Where coke is envisaged the percentage is less than 20% of mixture weight, whereas tin sulphide and tin (where envisaged), preferably in powder form, should be less than 10% and 5% of mixture weight respectively.
  • Wacker - Belsil ® PMS MK Powder softening interval 50-60 0 C
  • 20 grams of powdered zinc acetylacetonate in a horizontal blade mixer for approximately 2 minutes.
  • 1.200 grams of powdered SiC class FEPA F46 average diameter 370 ⁇ m
  • 1.300 grams of powdered SiC class FEPA F280 average diameter 36.5 ⁇ m.
  • 1.800 grams of copper in powder 2.700 grams of steel wool; 1.000 grams of silicium in powder and lastly 1.200 grams of graphite in powder.
  • the second phase of mixing is protracted for approximately 4 minutes.
  • the mixture's overall composition is as follows (percentages expressed in weight with regard to the mixture): 12% of powdered SiC F46; 13% powdered SiC F280; 18% copper in powder; 27% steel wool; 10% silicium in powder; 12% graphite in powder; 7.8% sesquisiloxane resin; 0.2% zinc acetylacetonate.
  • the copper and silicium powders have an average diameter of approximately 150 ⁇ m and approximately 40 ⁇ m respectively.
  • the steel wool has an average diameter of approximately 50 ⁇ m and an average length of approximately 0.4 mm.
  • the graphite powder has an average diameter of approximately 300 ⁇ m.
  • a portion of the mixture thus obtained then undergoes a hot-pressing phase in a vertical press in order to obtain the green body, as well as the accelerated reticulation of the sesquisiloxane resin.
  • the mixture and a steel plate are pressed simultaneously.
  • a plate (or matrix) with a through aperture and a substantially rectangular perimeter section corresponding to the form to be given to the body in ceramic matrix material.
  • the aperture has an area of approximately 148 cm 2 and a depth of about 8 cm.
  • the operation begins by blocking the lower end of the through aperture, using the head of the punch with which the press is equipped.
  • the aperture is then filled with the mixture and the upper end closed with a metal plate about 5 mm thick. With the plate suitably locked in position, pressing is begun by actuating the punch.
  • the temperature inside the mould is maintained around 120 0 C.
  • the maximum pressure applied during pressing is around 300 Kg/cm 2 .
  • Three consecutive cycles of application and release of force are envisaged, each lasting about 30 seconds (15 seconds of application and 15 seconds of release).
  • the overall pressing phase requires a period of approximately 3 minutes.
  • the green body obtained on completion of the pressing phase has a thickness of approximately 16 mm, to which the (unvaried) thickness of the plate must be added.
  • the ceramic matrix material thus obtained has a thickness of approximately 16 mm (excluding the thickness of the steel plate) and weighs approximately 710 grams. [00181] The body in ceramic matrix material then undergoes finishing work in order to bring the thickness to 14 or 15 mm, depending on the end use of the pad.
  • Wacker - Belsil ® PMS MK Powder softening interval 50-60 0 C
  • 20 grams of powdered zinc acetylacetonate in a horizontal blade mixer for approximately 2 minutes.
  • 1.200 grams of powdered SiC class FEPA F54 average diameter 310 ⁇ m
  • 1.300 grams of powdered SiC class FEPA F320 average diameter d 50 29.2 ⁇ r ⁇ .
  • silicium in powder 2.700 grams of steel wool, 1.200 grams of graphite in powder and lastly 1.800 grams of coke in powder.
  • the second phase of mixing is protracted for approximately 4 minutes.
  • the mixture's overall composition is as follows (percentages expressed in weight with regard to the mixture): 12% powdered SiC F54; 13% powdered SiC F320; 27% steel wool; 10% silicium in powder; 12% graphite in powder; 18% coke in powder; 7.8% sesquisiloxane resin; 0.2% zinc acetylacetonate.
  • the silicium powder has an average diameter of approximately 35 ⁇ m.
  • the steel wool has an average diameter of approximately 70 ⁇ m and an average length of approximately 0.6 mm.
  • the graphite and coke powders have an average diameter of approximately 500 ⁇ m.
  • a portion of the mixture thus obtained then undergoes a hot-pressing phase in a vertical press in order to obtain the green body, as well as the accelerated reticulation of the sesquisiloxane resin.
  • the mixture and a steel plate are pressed simultaneously.
  • a plate (or matrix) with a through aperture and a substantially rectangular perimeter section corresponding to the form to be given to the body in ceramic matrix material.
  • the aperture has an area of approximately 148 cm 2 and a depth of about 8 cm.
  • the temperature inside the mould is maintained around 130 0 C.
  • the maximum pressure applied during pressing is approximately 250 Kg/cm 2 .
  • Three consecutive cycles of application and release of force are envisaged, each lasting about 30 seconds (15 seconds of application and 15 seconds of release).
  • the overall pressing phase requires a period of approximately 4 minutes.
  • the green body obtained on completion of the pressing phase has a thickness of approximately 16 mm, to which the (unvaried) thickness of the plate must be added.
  • the ceramic matrix material thus obtained has a thickness of approximately 16 mm (excluding the thickness of the steel plate) and weighs approximately 710 grams. [00192] The body in ceramic matrix material then undergoes finishing work in order to bring the thickness to 14 or 15 mm, depending on the end use of the pad.
  • the mixture's overall composition is as follows (percentages expressed in weight with regard to the mixture): 12% powdered SiC F40; 13% powdered SiC F240; 21% steel wool; 15% brass in powder; 10% silicium in powder; 12% graphite in powder; 9% tin sulphide in powder; 3% tin in powder; 7.8% siliconic resin; 0.2% zinc acetylacetonate.
  • the brass and silicium powders have an average diameter of approximately 200 ⁇ m and approximately 45 ⁇ m respectively.
  • the steel wool has an average diameter of approximately 80 ⁇ m and an average length of approximately 0.8 mm.
  • the graphite and tin sulphide powders have an average diameter of approximately 750 ⁇ m and approximately 90 ⁇ m respectively.
  • a portion of the mixture thus obtained then undergoes a hot-pressing phase in a vertical press in order to obtain the green body, as well as the accelerated reticulation of the sesquisiloxane resin.
  • the mixture and a steel plate are pressed simultaneously.
  • a plate (or matrix) with a through aperture and a substantially rectangular perimeter section corresponding to the form to be given to the body in ceramic matrix material.
  • the aperture has an area of approximately 148 cm 2 and a depth of about 8 cm.
  • the operation begins by blocking the lower end of the through aperture, using the head of the punch with which the press is equipped.
  • the aperture is then filled with the mixture and the upper end closed with a metal plate about 5 mm thick. With the plate suitably locked in position, pressing is begun by actuating the punch.
  • the temperature inside the mould is maintained around 130 0 C.
  • the maximum pressure applied during pressing is around 450 Kg/cm 2 .
  • the ceramic matrix material thus obtained has a thickness of approximately 16 mm (excluding the thickness of the steel plate) and weighs approximately 710 grams.
  • the body in ceramic matrix material then undergoes finishing work in order to bring the thickness to 14 or 15 mm, depending on the end use of the pad.
  • the tests consisted in subjecting the samples to series of 50 braking operations.
  • This invention concerns a method for making disc brake pads, including a friction component in ceramic matrix material and a metal support element for the friction component.
  • the method envisages the following general operational phases: - making the friction component in ceramic matrix material; - bonding the friction component to the support element. [00213]
  • the method is distinguished by the fact that the phase of creating the friction component is carried out as per the procedure described above and by the fact that the support element is directly bonded with the ceramic matrix material in formation.
  • the support element should be pressed simultaneously with the initial ceramic matrix material during the hot-pressing phase referred to above.
  • This invention therefore considerably reduces working time for the production of a friction component in ceramic matrix material: from an average overall time of approximately 60-80 hours (without considering assembly with the metal support) to an average time of approximately 8-12 hours.
  • the ceramic matrix friction material made with the method proposed in the invention offers performances, in terms of friction coefficient and wear resistance, that are at least equivalent if not superior to those of traditional ceramic matrix friction materials.
  • the friction coefficient found in the invention materials is in fact on average 0.42 - 0.45 as against the values of traditional materials, which are approximately 0.35 - 0.4.
  • the invention method moreover permits simplification of brake pad and metal support plate production by cutting out the specific phase of final assembly of friction component in ceramic matrix material and metal support plate. [00219]
  • the invention has achieved its initial goals. [00220] Obviously in its practical implementation it may take on forms and configurations different from what is illustrated above, but without for this reason being excluded from the present context of protection.

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Abstract

L'invention concerne un procédé de fabrication de matériau de matrice céramique pour composants de frottement de frein, en particulier des freins à disque, qui comprend les phases opérationnelles suivantes : (a) préparation d'un mélange d'au moins un précurseur de céramique de type silicone, de particules de matériaux durs convenant comme abrasifs, de particules de substances convenant comme lubrifiants et de particules de matériaux métalliques, (b) pressage à chaud du mélange afin d'obtenir un corps vert, (c) soumission du corps vert à un processus de pyrolyse afin d'obtenir la céramisation du liant céramique, ce qui permet d'obtenir un matériau de matrice céramique. L'invention se caractérise en ce que le mélange comprend un catalyseur convenant pour favoriser la réticulation du précurseur de céramique pendant la phase de pressage à chaud et en ce que le processus de pyrolyse est effectué à des températures inférieures à 800 degrés C, et plus précisément comprises entre 400 degrés C et 600 degrés C.
PCT/IT2008/000543 2008-08-08 2008-08-08 Procédé de fabrication de matériau de matrice céramique pour composant de frottement de freins et matériau de matrice céramique fabriqué par ce procédé WO2010016079A1 (fr)

Priority Applications (13)

Application Number Priority Date Filing Date Title
JP2011521691A JP5959853B2 (ja) 2008-08-08 2008-08-08 ブレーキの摩擦部品用のセラミックマトリクス材料を製造する方法
EP08876020.2A EP2307759B1 (fr) 2008-08-08 2008-08-08 Procédé de fabrication de matériau de matrice céramique pour composant de frottement de freins et matériau de matrice céramique fabriqué par ce procédé
CN200880130538.7A CN102138022B (zh) 2008-08-08 2008-08-08 用于制动器的摩擦组件的陶瓷基体材料的制备方法及其制得的陶瓷基体材料
PCT/IT2008/000543 WO2010016079A1 (fr) 2008-08-08 2008-08-08 Procédé de fabrication de matériau de matrice céramique pour composant de frottement de freins et matériau de matrice céramique fabriqué par ce procédé
US13/056,076 US8960384B2 (en) 2008-08-08 2008-08-08 Method for making a ceramic matrix material for friction components of brakes and ceramic matrix material made by such method
ES08875901.4T ES2682087T3 (es) 2008-08-08 2008-12-23 Pastilla de freno para sistemas de frenado, en particular para frenos de disco
US13/056,218 US20110198170A1 (en) 2008-08-08 2008-12-23 Brake Pad for Braking Systems, In Particular for Disc Brakes
PCT/IB2008/055519 WO2010015897A1 (fr) 2008-08-08 2008-12-23 Patin de frein pour systèmes de freinage, en particulier pour freins à disque
JP2011521648A JP6081059B2 (ja) 2008-08-08 2008-12-23 ブレーキシステム用の、特にディスクブレーキ用のブレーキパッド
CN200880130598.9A CN102119289B (zh) 2008-08-08 2008-12-23 用于制动系统，尤其是用于盘式制动器的制动衬块
PL08875901T PL2310714T3 (pl) 2008-08-08 2008-12-23 Płytka cierna hamulca do układów hamulcowych, w szczególności do hamulców tarczowych
EP08875901.4A EP2310714B1 (fr) 2008-08-08 2008-12-23 Patin de frein pour systèmes de freinage, en particulier pour freins à disque
JP2015102996A JP6046206B2 (ja) 2008-08-08 2015-05-20 ブレーキシステム用の、特にディスクブレーキ用のブレーキパッド

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PCT/IT2008/000543 WO2010016079A1 (fr) 2008-08-08 2008-08-08 Procédé de fabrication de matériau de matrice céramique pour composant de frottement de freins et matériau de matrice céramique fabriqué par ce procédé

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PCT/IB2008/055519 WO2010015897A1 (fr) 2008-08-08 2008-12-23 Patin de frein pour systèmes de freinage, en particulier pour freins à disque

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CN102138022B (zh) 2015-06-10
CN102119289A (zh) 2011-07-06
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JP2011530682A (ja) 2011-12-22
PL2310714T3 (pl) 2018-11-30
EP2307759A1 (fr) 2011-04-13
JP6046206B2 (ja) 2016-12-14
WO2010015897A9 (fr) 2011-05-26
WO2010015897A1 (fr) 2010-02-11
JP5959853B2 (ja) 2016-08-02
EP2310714A1 (fr) 2011-04-20
CN102138022A (zh) 2011-07-27
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JP6081059B2 (ja) 2017-02-15
US20110308899A1 (en) 2011-12-22

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