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WO2009146784A3 - Modifizierter gas- und dampfturbinenprozess mit integrierter kohledruckvergasung - Google Patents

Modifizierter gas- und dampfturbinenprozess mit integrierter kohledruckvergasung Download PDF

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Publication number
WO2009146784A3
WO2009146784A3 PCT/EP2009/003470 EP2009003470W WO2009146784A3 WO 2009146784 A3 WO2009146784 A3 WO 2009146784A3 EP 2009003470 W EP2009003470 W EP 2009003470W WO 2009146784 A3 WO2009146784 A3 WO 2009146784A3
Authority
WO
WIPO (PCT)
Prior art keywords
syngas
under pressure
steam turbine
coal gasification
modified gas
Prior art date
Application number
PCT/EP2009/003470
Other languages
English (en)
French (fr)
Other versions
WO2009146784A2 (de
Inventor
Ralf Abraham
Domenico Pavone
Original Assignee
Uhde Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uhde Gmbh filed Critical Uhde Gmbh
Priority to EP09757167A priority Critical patent/EP2286072A2/de
Priority to CA2725503A priority patent/CA2725503A1/en
Priority to AU2009254315A priority patent/AU2009254315A1/en
Priority to BRPI0913260A priority patent/BRPI0913260A2/pt
Priority to RU2010154458/05A priority patent/RU2528998C2/ru
Priority to CN2009801206367A priority patent/CN102149795A/zh
Priority to US12/737,032 priority patent/US8951316B2/en
Publication of WO2009146784A2 publication Critical patent/WO2009146784A2/de
Priority to ZA2010/08639A priority patent/ZA201008639B/en
Publication of WO2009146784A3 publication Critical patent/WO2009146784A3/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/52—Ash-removing devices
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/02—Dust removal
    • C10K1/026—Dust removal by centrifugal forces
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/32—Purifying combustible gases containing carbon monoxide with selectively adsorptive solids, e.g. active carbon
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
    • F02C3/20—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products
    • F02C3/26—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products the fuel or oxidant being solid or pulverulent, e.g. in slurry or suspension
    • F02C3/28—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products the fuel or oxidant being solid or pulverulent, e.g. in slurry or suspension using a separate gas producer for gasifying the fuel before combustion
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C6/00—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use
    • F02C6/18—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas-turbine plants for special use using the waste heat of gas-turbine plants outside the plants themselves, e.g. gas-turbine power heat plants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/146—At least two purification steps in series
    • C01B2203/147—Three or more purification steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/84—Energy production
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
    • C10J2300/1606—Combustion processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1643—Conversion of synthesis gas to energy
    • C10J2300/165—Conversion of synthesis gas to energy integrated with a gas turbine or gas motor
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1643—Conversion of synthesis gas to energy
    • C10J2300/1653—Conversion of synthesis gas to energy integrated in a gasification combined cycle [IGCC]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1671—Integration of gasification processes with another plant or parts within the plant with the production of electricity
    • C10J2300/1675—Integration of gasification processes with another plant or parts within the plant with the production of electricity making use of a steam turbine
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Industrial Gases (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)

Abstract

Die Erfindung betrifft ein Verfahren zur Herstellung, Reinigung und Verbrennung von Synthesegas zum Zwecke der Erzeugung von elektrischer Energie. Dabei wird das Synthesegas aus einem festen, kohlenstoffhaltigen Brennstoff mit einem sauerstoffhaltigen Gas erzeugt und durch eine Schlackeabscheidung und eine Alkalienabscheidung gereinigt. Nach dieser Reinigung gelangt das hergestellte Synthesegas in eine Expansionsturbine, wo die Druckenergie zur Erzeugung von Strom genutzt wird. Durch die Reinigung und Alkalienabscheidung wird die Expansionsturbine vor Korrosion und mechanischem Angriff geschützt. Das entspannte Synthesegas wird dann unter Druck verbrannt und die Verbrennung in einem Kombiprozess mit Gasturbine, Dampferzeugung und Dampfturbine zur Erzeugung von Strom genutzt. Der Prozess besitzt damit einen erhöhten Wirkungsgrad. Die Erfindung betrifft auch eine Vorrichtung, mit der sich das erfindungsgemäße Verfahren ausführen läßt.
PCT/EP2009/003470 2008-06-02 2009-05-15 Modifizierter gas- und dampfturbinenprozess mit integrierter kohledruckvergasung WO2009146784A2 (de)

Priority Applications (8)

Application Number Priority Date Filing Date Title
EP09757167A EP2286072A2 (de) 2008-06-02 2009-05-15 Modifizierter gas- und dampfturbinenprozess mit integrierter kohledruckvergasung
CA2725503A CA2725503A1 (en) 2008-06-02 2009-05-15 Modified gas and steam turbine process with integrated coal gasification under pressure
AU2009254315A AU2009254315A1 (en) 2008-06-02 2009-05-15 Modified gas and steam turbine process having integrated coal gasification under pressure
BRPI0913260A BRPI0913260A2 (pt) 2008-06-02 2009-05-15 processo modificado para turbinas a gás e a vapor com gaseificação de carvão sob pressão integrada
RU2010154458/05A RU2528998C2 (ru) 2008-06-02 2009-05-15 Модифицированный процесс с использованием газовой и паровой турбины с интегрированной газификацией угля под давлением
CN2009801206367A CN102149795A (zh) 2008-06-02 2009-05-15 具有整体煤加压气化的经改进的燃气和蒸汽涡轮工艺
US12/737,032 US8951316B2 (en) 2008-06-02 2009-05-15 Modified gas and steam turbine process with integrated coal gasification under pressure
ZA2010/08639A ZA201008639B (en) 2008-06-02 2010-12-01 Modified gas and steam turbine process with integrated coal gasification under pressure

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102008026267.6 2008-06-02
DE102008026267A DE102008026267A1 (de) 2008-06-02 2008-06-02 Modifizierter Gas- und Dampfturbinenprozess mit integrierter Kohledruckvergasung

Publications (2)

Publication Number Publication Date
WO2009146784A2 WO2009146784A2 (de) 2009-12-10
WO2009146784A3 true WO2009146784A3 (de) 2011-01-06

Family

ID=41254001

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2009/003470 WO2009146784A2 (de) 2008-06-02 2009-05-15 Modifizierter gas- und dampfturbinenprozess mit integrierter kohledruckvergasung

Country Status (12)

Country Link
US (1) US8951316B2 (de)
EP (1) EP2286072A2 (de)
KR (1) KR101606601B1 (de)
CN (1) CN102149795A (de)
AU (1) AU2009254315A1 (de)
BR (1) BRPI0913260A2 (de)
CA (1) CA2725503A1 (de)
DE (1) DE102008026267A1 (de)
RU (1) RU2528998C2 (de)
UA (1) UA99769C2 (de)
WO (1) WO2009146784A2 (de)
ZA (1) ZA201008639B (de)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ596307A (en) * 2009-05-22 2013-04-26 Sasol Tech Pty Ltd Process for co-producing synthesis gas and power using an oxygen enriched permeate stream from itm oxygen enrichment for synthesis gas generation and oxygen depleated air from itm as a high temprature heatsink for synthesis gas
DE102010045537A1 (de) 2010-09-15 2012-03-15 Uhde Gmbh Verfahren zur Erzeugung von Synthesegas
DE102011114171A1 (de) * 2011-09-19 2013-03-21 Thyssenkrupp Uhde Gmbh Verfahren zur Herstellung von Synthesegas durch Vergasung einer Biomasse in einer Wirbelschicht
US9816401B2 (en) * 2015-08-24 2017-11-14 Saudi Arabian Oil Company Modified Goswami cycle based conversion of gas processing plant waste heat into power and cooling
KR20180044377A (ko) * 2015-09-01 2018-05-02 8 리버스 캐피탈, 엘엘씨 내포된 이산화탄소(co2) 사이클들을 이용하는 동력 생산을 위한 시스템들 및 방법들
US11261783B2 (en) * 2017-10-30 2022-03-01 Doosan Heavy Industries & Construction Co., Ltd. Combined power generation system employing pressure difference power generation

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US3762134A (en) * 1971-04-01 1973-10-02 Vulcan Materials Co Prevention of air pollution by using solid adsorbents to remove particulates of less than 0.5 microns in size from flue gases
GB1587490A (en) * 1977-06-25 1981-04-01 Coal Industry Patents Ltd Purification system
US4340399A (en) * 1980-12-22 1982-07-20 General Electric Company Method of removing alkali metal contamination from a gaseous stream
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WO2003099965A2 (en) * 2002-05-22 2003-12-04 Manufacturing And Technology Conversion International, Inc. Pulse gasification and hot gas cleanup apparatus and process
US20060045827A1 (en) * 2004-08-31 2006-03-02 Sprouse Kenneth M Method and apparatus for coal gasifier

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DE4318385C2 (de) * 1993-06-03 1997-04-10 Metallgesellschaft Ag Verfahren zum Abscheiden von Schlacketröpfchen aus einem Rohgas aus der Verbrennung oder Vergasung fester oder flüssiger Brennstoffe
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DE19512939A1 (de) * 1995-04-06 1996-10-10 Harald Dr Ing Lorson Verfahren und Anlagen zur Heißgasreinigung von staubbeladenen Rauchgasströmen bei Temperaturen um 1600 DEG C
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Publication number Priority date Publication date Assignee Title
US3762134A (en) * 1971-04-01 1973-10-02 Vulcan Materials Co Prevention of air pollution by using solid adsorbents to remove particulates of less than 0.5 microns in size from flue gases
GB1587490A (en) * 1977-06-25 1981-04-01 Coal Industry Patents Ltd Purification system
US4340399A (en) * 1980-12-22 1982-07-20 General Electric Company Method of removing alkali metal contamination from a gaseous stream
US4920898A (en) * 1988-09-15 1990-05-01 Trw Inc. Gas turbine slagging combustion system
WO1999014473A1 (en) * 1997-09-12 1999-03-25 Texaco Development Corporation Synthesis gas expander located immediately upstream of combustion turbine
WO2003099965A2 (en) * 2002-05-22 2003-12-04 Manufacturing And Technology Conversion International, Inc. Pulse gasification and hot gas cleanup apparatus and process
US20060045827A1 (en) * 2004-08-31 2006-03-02 Sprouse Kenneth M Method and apparatus for coal gasifier

Also Published As

Publication number Publication date
BRPI0913260A2 (pt) 2016-01-19
WO2009146784A2 (de) 2009-12-10
RU2010154458A (ru) 2012-07-20
CA2725503A1 (en) 2009-12-10
US8951316B2 (en) 2015-02-10
ZA201008639B (en) 2011-09-28
EP2286072A2 (de) 2011-02-23
US20110120139A1 (en) 2011-05-26
AU2009254315A1 (en) 2009-12-10
DE102008026267A1 (de) 2009-12-03
CN102149795A (zh) 2011-08-10
RU2528998C2 (ru) 2014-09-20
KR20110022580A (ko) 2011-03-07
UA99769C2 (ru) 2012-09-25
KR101606601B1 (ko) 2016-03-25

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