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WO2009041479A1 - プロトン伝導膜およびプロトン伝導膜の製造方法 - Google Patents

プロトン伝導膜およびプロトン伝導膜の製造方法 Download PDF

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Publication number
WO2009041479A1
WO2009041479A1 PCT/JP2008/067273 JP2008067273W WO2009041479A1 WO 2009041479 A1 WO2009041479 A1 WO 2009041479A1 JP 2008067273 W JP2008067273 W JP 2008067273W WO 2009041479 A1 WO2009041479 A1 WO 2009041479A1
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WIPO (PCT)
Prior art keywords
acid
proton conducting
conducting membrane
oxygen
precursor
Prior art date
Application number
PCT/JP2008/067273
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English (en)
French (fr)
Inventor
Toyoki Kunitake
Yuanzhi Li
Yoshitaka Aoki
Emi Muto
Original Assignee
Riken
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Filing date
Publication date
Application filed by Riken filed Critical Riken
Priority to US12/680,174 priority Critical patent/US8398754B2/en
Priority to KR1020107007942A priority patent/KR101454058B1/ko
Priority to CN2008801089015A priority patent/CN101809677B/zh
Priority to JP2009534349A priority patent/JP5322236B2/ja
Priority to EP08834041A priority patent/EP2194537A4/en
Publication of WO2009041479A1 publication Critical patent/WO2009041479A1/ja

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0048—Inorganic membrane manufacture by sol-gel transition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/024—Oxides
    • C—CHEMISTRY; METALLURGY
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    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
    • C04B35/486—Fine ceramics
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    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/624—Sol-gel processing
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/124—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
    • H01M8/1246—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/14—Membrane materials having negatively charged functional groups
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C04B2235/3225—Yttrium oxide or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
    • C04B2235/421—Boron
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/441—Alkoxides, e.g. methoxide, tert-butoxide
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/447—Phosphates or phosphites, e.g. orthophosphate or hypophosphite
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/449—Organic acids, e.g. EDTA, citrate, acetate, oxalate
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    • H01M2300/0068—Solid electrolytes inorganic
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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Conductive Materials (AREA)
  • Fuel Cell (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

　金属酸化物中の酸素原子と、－Ｂ（Ｏ）３－、－Ｓ（＝Ｏ）２（Ｏ）２－、－Ｐ（＝Ｏ）（Ｏ）３－、－Ｃ（＝Ｏ）（Ｏ）２－および－Ｎ（Ｏ）３－の少なくとも１種の酸素酸由来の基とが酸素原子を介して結合したセラミック構造体（但し、金属酸化物中の酸素原子と酸素酸由来の基の酸素原子の一部は兼ねる構成である）を主成分とし、酸素酸またはその前駆体と、金属酸化物前駆体とをゾルゲル反応させた後、加熱させてなるものであり、前記酸素酸またはその前駆体は、ホウ酸、硫酸、リン酸、炭酸および硝酸、ならびにこれらの前駆体であり、ゾルゲル反応をさせた後、１００～６００°Cで加熱させてなるものであるプロトン伝導膜。これにより、新たなプロトン伝導膜を提供する。
PCT/JP2008/067273 2007-09-28 2008-09-25 プロトン伝導膜およびプロトン伝導膜の製造方法 WO2009041479A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US12/680,174 US8398754B2 (en) 2007-09-28 2008-09-25 Proton conducting membrane and method for producing proton conducting membrane
KR1020107007942A KR101454058B1 (ko) 2007-09-28 2008-09-25 프로톤 전도막 및 프로톤 전도막의 제조 방법
CN2008801089015A CN101809677B (zh) 2007-09-28 2008-09-25 质子传导膜及其制造方法
JP2009534349A JP5322236B2 (ja) 2007-09-28 2008-09-25 プロトン伝導膜およびプロトン伝導膜の製造方法
EP08834041A EP2194537A4 (en) 2007-09-28 2008-09-25 PROTON-CONDUCTIVE MEMBRANE AND METHOD FOR PRODUCING THE PROTON-CONDUCTIVE MEMBRANE

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-253611 2007-09-28
JP2007253611 2007-09-28

Publications (1)

Publication Number Publication Date
WO2009041479A1 true WO2009041479A1 (ja) 2009-04-02

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PCT/JP2008/067273 WO2009041479A1 (ja) 2007-09-28 2008-09-25 プロトン伝導膜およびプロトン伝導膜の製造方法

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Country Link
US (1) US8398754B2 (ja)
EP (1) EP2194537A4 (ja)
JP (1) JP5322236B2 (ja)
KR (1) KR101454058B1 (ja)
CN (1) CN101809677B (ja)
WO (1) WO2009041479A1 (ja)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011018908A1 (ja) * 2009-08-13 2011-02-17 国立大学法人 東京工業大学 強酸性ジルコニウム粒子の製造方法、プロトン伝導性材料、プロトン伝導性膜の製造方法、プロトン伝導性膜、燃料電池用電極、膜－電極接合体、燃料電池
WO2011125532A1 (ja) * 2010-03-31 2011-10-13 セントラル硝子株式会社 酸化物成形体及びその製造方法
WO2021201194A1 (ja) * 2020-03-31 2021-10-07 大阪瓦斯株式会社 塗料組成物の製造方法、イットリア安定化ジルコニア層、電気化学素子、電気化学モジュール、電気化学装置、エネルギーシステム、固体酸化物形燃料電池及び固体酸化物電解セル

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114014285B (zh) * 2020-07-16 2023-01-13 中国科学院金属研究所 基于含金属空位的二维材料的离子传导膜及其制备方法

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JP2003146665A (ja) * 2001-11-20 2003-05-21 Toyota Motor Corp ゾルゲル法によるゲル材の製造方法
JP2003168446A (ja) * 2001-11-29 2003-06-13 Toyota Motor Corp 燃料電池及びその製造方法
JP2003313233A (ja) * 2002-04-26 2003-11-06 Toyota Motor Corp ゾルゲル法による有機無機複合体の製造方法
WO2007029346A1 (ja) * 2005-08-19 2007-03-15 The University Of Tokyo プロトン伝導性ハイブリッド材料及びそれを用いた燃料電池用触媒層

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JP2003146665A (ja) * 2001-11-20 2003-05-21 Toyota Motor Corp ゾルゲル法によるゲル材の製造方法
JP2003168446A (ja) * 2001-11-29 2003-06-13 Toyota Motor Corp 燃料電池及びその製造方法
JP2003313233A (ja) * 2002-04-26 2003-11-06 Toyota Motor Corp ゾルゲル法による有機無機複合体の製造方法
WO2007029346A1 (ja) * 2005-08-19 2007-03-15 The University Of Tokyo プロトン伝導性ハイブリッド材料及びそれを用いた燃料電池用触媒層

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See also references of EP2194537A4

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011018908A1 (ja) * 2009-08-13 2011-02-17 国立大学法人 東京工業大学 強酸性ジルコニウム粒子の製造方法、プロトン伝導性材料、プロトン伝導性膜の製造方法、プロトン伝導性膜、燃料電池用電極、膜－電極接合体、燃料電池
WO2011018905A1 (ja) * 2009-08-13 2011-02-17 国立大学法人 東京工業大学 強酸性ジルコニウム粒子の製造方法及びプロトン伝導性材料、プロトン伝導性膜の製造方法及びプロトン伝導性膜
WO2011125532A1 (ja) * 2010-03-31 2011-10-13 セントラル硝子株式会社 酸化物成形体及びその製造方法
CN102834351A (zh) * 2010-03-31 2012-12-19 中央硝子株式会社 氧化物成型体及其制造方法
KR101396081B1 (ko) 2010-03-31 2014-05-15 샌트랄 글래스 컴퍼니 리미티드 산화물 성형체 및 그의 제조방법
WO2021201194A1 (ja) * 2020-03-31 2021-10-07 大阪瓦斯株式会社 塗料組成物の製造方法、イットリア安定化ジルコニア層、電気化学素子、電気化学モジュール、電気化学装置、エネルギーシステム、固体酸化物形燃料電池及び固体酸化物電解セル

Also Published As

Publication number Publication date
US20100284880A1 (en) 2010-11-11
CN101809677B (zh) 2013-01-09
EP2194537A1 (en) 2010-06-09
CN101809677A (zh) 2010-08-18
KR101454058B1 (ko) 2014-10-27
US8398754B2 (en) 2013-03-19
EP2194537A4 (en) 2012-12-26
KR20100063117A (ko) 2010-06-10
JPWO2009041479A1 (ja) 2011-01-27
JP5322236B2 (ja) 2013-10-23

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