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WO2008126743A1 - 触媒前駆体物質及びそれを用いた触媒 - Google Patents

触媒前駆体物質及びそれを用いた触媒 Download PDF

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Publication number
WO2008126743A1
WO2008126743A1 PCT/JP2008/056588 JP2008056588W WO2008126743A1 WO 2008126743 A1 WO2008126743 A1 WO 2008126743A1 JP 2008056588 W JP2008056588 W JP 2008056588W WO 2008126743 A1 WO2008126743 A1 WO 2008126743A1
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Prior art keywords
catalyst
precursor substance
fuel cell
water
gas shift
Prior art date
Application number
PCT/JP2008/056588
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English (en)
French (fr)
Inventor
Kozo Takatsu
Yoshimi Kawashima
Satoshi Nakai
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Idemitsu Kosan Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Idemitsu Kosan Co., Ltd. filed Critical Idemitsu Kosan Co., Ltd.
Priority to US12/594,983 priority Critical patent/US8088708B2/en
Priority to EP08739699.0A priority patent/EP2135673A4/en
Priority to KR1020097020951A priority patent/KR101484793B1/ko
Priority to CA2681411A priority patent/CA2681411C/en
Priority to CN2008800112599A priority patent/CN101652176B/zh
Priority to JP2009509278A priority patent/JP5421770B2/ja
Publication of WO2008126743A1 publication Critical patent/WO2008126743A1/ja

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
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    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
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    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0618—Reforming processes, e.g. autothermal, partial oxidation or steam reforming
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    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
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    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
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    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
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    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
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    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

　本発明は、銅、亜鉛およびアルミニウムを含み、特定の格子面間隔ｄ（Å）にブロードなX線回折ピークを示す触媒前駆体物質及び銅塩、亜鉛塩及びアルミニウム塩を含有する溶液とアルカリ金属又はアルカリ土類金属水酸化物を含有する溶液を混合して沈殿させることによる該触媒前駆体物質を製造し、該触媒前駆体を焼成して触媒を調製し、該触媒を水性ガスシフト反応用触媒とし、該触媒を用いて一酸化炭素を変成し、該変成方法により得られた水素を用いて燃料電池システムとすることにより、活性及び耐久性が高く、燃料電池に適用しても活性の低下が少なく、長期間使用できる水性ガスシフト反応用として有用な触媒及び該触媒を用いた一酸化炭素変成方法並びに該変成方法により得られた水素を用いる燃料電池システムを提供する。
PCT/JP2008/056588 2007-04-10 2008-04-02 触媒前駆体物質及びそれを用いた触媒 WO2008126743A1 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
US12/594,983 US8088708B2 (en) 2007-04-10 2008-04-02 Catalyst precursor substance, and catalyst using the same
EP08739699.0A EP2135673A4 (en) 2007-04-10 2008-04-02 CATALYST PREPARATION MATERIAL AND THIS USING CATALYST
KR1020097020951A KR101484793B1 (ko) 2007-04-10 2008-04-02 촉매 전구체 물질 및 그것을 이용한 촉매
CA2681411A CA2681411C (en) 2007-04-10 2008-04-02 Catalyst precursor substance, and catalyst using the same
CN2008800112599A CN101652176B (zh) 2007-04-10 2008-04-02 催化剂前体物质及使用该催化剂前体物质的催化剂
JP2009509278A JP5421770B2 (ja) 2007-04-10 2008-04-02 触媒前駆体物質及びそれを用いた触媒

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-102898 2007-04-10
JP2007102898 2007-04-10

Publications (1)

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WO2008126743A1 true WO2008126743A1 (ja) 2008-10-23

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PCT/JP2008/056588 WO2008126743A1 (ja) 2007-04-10 2008-04-02 触媒前駆体物質及びそれを用いた触媒

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Country Link
US (1) US8088708B2 (ja)
EP (1) EP2135673A4 (ja)
JP (1) JP5421770B2 (ja)
KR (1) KR101484793B1 (ja)
CN (1) CN101652176B (ja)
CA (1) CA2681411C (ja)
TW (1) TWI433723B (ja)
WO (1) WO2008126743A1 (ja)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011048976A1 (ja) * 2009-10-23 2011-04-28 三菱瓦斯化学株式会社 メタノール合成触媒
JP2011194362A (ja) * 2010-03-23 2011-10-06 Idemitsu Kosan Co Ltd 一酸化炭素転換用触媒の製造方法
JP2012139637A (ja) * 2010-12-28 2012-07-26 Idemitsu Kosan Co Ltd 銅−亜鉛−アルミニウム触媒、その製造方法、一酸化炭素変成方法、及び水素製造方法
JP2014524836A (ja) * 2011-07-27 2014-09-25 サウジ アラビアン オイル カンパニー 気体炭化水素から硫黄化合物を除去するのに有用な触媒組成物、その製造方法およびその使用
JP2015505799A (ja) * 2011-12-02 2015-02-26 レール・リキード−ソシエテ・アノニム・プール・レテュード・エ・レクスプロワタシオン・デ・プロセデ・ジョルジュ・クロード 中温で作用する水性ガスシフト触媒およびその調製のための方法

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JP5886833B2 (ja) * 2010-04-21 2016-03-16 エスケー イノベーション カンパニー リミテッド ナノメートルサイズの銅系触媒、その製造方法、及びそれを用いたカルボン酸の直接水素化によるアルコール製造方法
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US8906227B2 (en) 2012-02-02 2014-12-09 Suadi Arabian Oil Company Mild hydrodesulfurization integrating gas phase catalytic oxidation to produce fuels having an ultra-low level of organosulfur compounds
US20130217568A1 (en) * 2012-02-20 2013-08-22 Saudi Basic Industries Corporation Oxidative dehydrogenation of olefins catalyst and methods of making and using the same
KR102008352B1 (ko) * 2012-09-18 2019-08-07 차이나 페트로리움 앤드 케미컬 코포레이션 사이클로헥사놀 및 알카놀을 동시생산하는 방법 및 장치
US9889429B2 (en) 2012-10-16 2018-02-13 Bill W. Helton Hydrogen production catalysts and associated systems and methods
US8920635B2 (en) * 2013-01-14 2014-12-30 Saudi Arabian Oil Company Targeted desulfurization process and apparatus integrating gas phase oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds
CA2918039C (en) * 2013-07-31 2022-07-12 Srikant Gopal Nitrous oxide decomposition catalyst
CN104560251B (zh) * 2013-10-28 2017-04-19 中国石油化工股份有限公司 净化剂及其用途
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WO2018015824A1 (en) * 2016-07-18 2018-01-25 Sabic Global Technologies B.V. Process for high-pressure hydrogenation of carbon dioxide to syngas in the presence of a copper/zinc/zirconium mixed metal oxide catalyst
EP3305404A1 (en) * 2016-10-10 2018-04-11 National Petrochemical Company Copper/zinc/aluminium catalyst for the methanol synthesis prepared from a binary zinc-aluminium precursor solution
WO2018216555A1 (ja) * 2017-05-25 2018-11-29 大阪瓦斯株式会社 ガスの脱硫剤および脱硫方法
CN108435182B (zh) * 2017-08-16 2021-01-15 西安向阳航天材料股份有限公司 一种铜系低温变换催化剂的制备方法
KR102233613B1 (ko) * 2018-10-15 2021-03-30 재단법인 포항산업과학연구원 중온용 수성가스 전환 반응 촉매, 이의 제조방법, 및 이를 이용한 수소 제조방법
KR102199485B1 (ko) * 2018-10-18 2021-01-06 연세대학교 원주산학협력단 일단 수성가스 전이 반응을 위한 촉매의 제조 방법
CN112206763A (zh) * 2019-07-12 2021-01-12 中石化南京化工研究院有限公司 一种铜系低温变换催化剂及其制备方法
KR102628005B1 (ko) * 2019-11-27 2024-01-19 에스케이가스 주식회사 알칸족 가스로부터 올레핀 제조용 탈수소촉매 및 그 제조방법
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