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WO2008123323A1 - Process for producing polyol and the polyol - Google Patents

Process for producing polyol and the polyol Download PDF

Info

Publication number
WO2008123323A1
WO2008123323A1 PCT/JP2008/055777 JP2008055777W WO2008123323A1 WO 2008123323 A1 WO2008123323 A1 WO 2008123323A1 JP 2008055777 W JP2008055777 W JP 2008055777W WO 2008123323 A1 WO2008123323 A1 WO 2008123323A1
Authority
WO
WIPO (PCT)
Prior art keywords
polyol
castor oil
group
compounds
initiator
Prior art date
Application number
PCT/JP2008/055777
Other languages
French (fr)
Japanese (ja)
Inventor
Chitoshi Suzuki
Yasuyuki Sasao
Shigeru Ikai
Original Assignee
Asahi Glass Company, Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Glass Company, Limited filed Critical Asahi Glass Company, Limited
Priority to JP2009509151A priority Critical patent/JP5206671B2/en
Publication of WO2008123323A1 publication Critical patent/WO2008123323A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4891—Polyethers modified with higher fatty oils or their acids or by resin acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/08—Saturated oxiranes
    • C08G65/10—Saturated oxiranes characterised by the catalysts used
    • C08G65/12—Saturated oxiranes characterised by the catalysts used containing organo-metallic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
    • C08G65/2615—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen the other compounds containing carboxylic acid, ester or anhydride groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2654—Aluminium or boron; Compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polyethers (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

A process for producing a polyol having a high biomass proportion by causing ethylene oxide to evenly undergo ring-opening addition to castor oil or a castor oil condensate as an initiator in the presence of a catalyst and forming primary hydroxyl groups at a high efficiency while preventing the initiator from decomposing and thereby generating a low-molecular by-product. Also provided is a polyol produced by the process. The process for polyol production comprises causing one or more heterocyclic compounds to undergo ring-opening addition to at least one initiator selected among castor oil and castor oil condensates in the presence of a catalyst for cationic polymerization. It is characterized in that the heterocyclic compounds are one or more compounds selected from the group consisting of cyclic ethers and cyclic esters, at least part thereof being ethylene oxide, and that the cationic-polymerization catalyst is at least one member selected from the group consisting of aluminum compounds and boron compounds each having a fluoroaryl group or fluoroaryloxy group.
PCT/JP2008/055777 2007-03-28 2008-03-26 Process for producing polyol and the polyol WO2008123323A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009509151A JP5206671B2 (en) 2007-03-28 2008-03-26 Method for producing polyol and the polyol

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-085610 2007-03-28
JP2007085610 2007-03-28

Publications (1)

Publication Number Publication Date
WO2008123323A1 true WO2008123323A1 (en) 2008-10-16

Family

ID=39830811

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/055777 WO2008123323A1 (en) 2007-03-28 2008-03-26 Process for producing polyol and the polyol

Country Status (3)

Country Link
JP (1) JP5206671B2 (en)
TW (1) TW200904852A (en)
WO (1) WO2008123323A1 (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012201749A (en) * 2011-03-24 2012-10-22 Dai Ichi Kogyo Seiyaku Co Ltd Method for manufacturing polyoxyalkylene derivative and polyoxyalkylene derivative obtained by the method
US20130261205A1 (en) * 2010-11-22 2013-10-03 Bater Intellectual Property GmbH Process for the preparation of polyricinoleic acid ester polyols having primary hydroxyl end groups
US8642668B2 (en) 2007-06-22 2014-02-04 Asahi Glass Company, Limited Polymer-dispersed polyol and process for producing flexible polyurethane foam
JP2016532736A (en) * 2013-10-10 2016-10-20 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Novel functional fluid composition
JP2017531719A (en) * 2014-10-22 2017-10-26 ダウ グローバル テクノロジーズ エルエルシー Dual catalyst system for high primary hydroxyl polyols
JP2017222625A (en) * 2016-06-17 2017-12-21 三菱ケミカル株式会社 Diol compound, and polycarbonate resin, polycarbonate polyol resin, polyester resin, polyester polyol resin and polyurethane resin produced from the diol compound
WO2019055725A1 (en) * 2017-09-14 2019-03-21 Northwestern University Process of manufacturing polyols
WO2019055727A1 (en) * 2017-09-14 2019-03-21 Dow Global Technologies Llc Process of manufacturing polyols
WO2019055740A1 (en) * 2017-09-14 2019-03-21 Dow Global Technologies Llc Lewis acid polymerization catalyst
JP2019218267A (en) * 2018-06-14 2019-12-26 株式会社日本触媒 Composition containing triaryl boron compound

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11421077B2 (en) * 2020-06-12 2022-08-23 Bionanofoam Llc Bio-based and hydrophilic polyurethane prepolymer

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000344881A (en) * 1998-07-10 2000-12-12 Sanyo Chem Ind Ltd Novel polyoxyalkylene polyol and production of ring- opening polymer
JP2003183383A (en) * 2001-12-14 2003-07-03 Nippon Shokubai Co Ltd Manufacturing method of cyclic ether adduct of alcohol with less smell
JP2005082732A (en) * 2003-09-10 2005-03-31 Sanyo Chem Ind Ltd Method for producing ring-opening polymerization polymer
JP2005320437A (en) * 2004-05-10 2005-11-17 Honda Motor Co Ltd Urethane foam for automobile seat
JP2006104404A (en) * 2004-10-08 2006-04-20 Toyota Boshoku Corp Polyurethane pad for vehicle seat

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000344881A (en) * 1998-07-10 2000-12-12 Sanyo Chem Ind Ltd Novel polyoxyalkylene polyol and production of ring- opening polymer
JP2003183383A (en) * 2001-12-14 2003-07-03 Nippon Shokubai Co Ltd Manufacturing method of cyclic ether adduct of alcohol with less smell
JP2005082732A (en) * 2003-09-10 2005-03-31 Sanyo Chem Ind Ltd Method for producing ring-opening polymerization polymer
JP2005320437A (en) * 2004-05-10 2005-11-17 Honda Motor Co Ltd Urethane foam for automobile seat
JP2006104404A (en) * 2004-10-08 2006-04-20 Toyota Boshoku Corp Polyurethane pad for vehicle seat

Cited By (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8642668B2 (en) 2007-06-22 2014-02-04 Asahi Glass Company, Limited Polymer-dispersed polyol and process for producing flexible polyurethane foam
US20130261205A1 (en) * 2010-11-22 2013-10-03 Bater Intellectual Property GmbH Process for the preparation of polyricinoleic acid ester polyols having primary hydroxyl end groups
US9328196B2 (en) * 2010-11-22 2016-05-03 Bayer Materialscience Ag Process for the preparation of polyricinoleic acid ester polyols having primary hydroxyl end groups
JP2012201749A (en) * 2011-03-24 2012-10-22 Dai Ichi Kogyo Seiyaku Co Ltd Method for manufacturing polyoxyalkylene derivative and polyoxyalkylene derivative obtained by the method
JP2016532736A (en) * 2013-10-10 2016-10-20 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Novel functional fluid composition
US10941367B2 (en) 2013-10-10 2021-03-09 Basf Se Functional fluid composition
JP2017531719A (en) * 2014-10-22 2017-10-26 ダウ グローバル テクノロジーズ エルエルシー Dual catalyst system for high primary hydroxyl polyols
JP2017222625A (en) * 2016-06-17 2017-12-21 三菱ケミカル株式会社 Diol compound, and polycarbonate resin, polycarbonate polyol resin, polyester resin, polyester polyol resin and polyurethane resin produced from the diol compound
JP2020534391A (en) * 2017-09-14 2020-11-26 ノースウェスタン ユニバーシティ Polyol manufacturing process
US11001669B2 (en) 2017-09-14 2021-05-11 Dow Global Technologies Llc Lewis acid polymerization catalyst
WO2019055742A1 (en) * 2017-09-14 2019-03-21 Dow Global Technologies Llc Process of manufacturing surfactants and lubricants
WO2019055740A1 (en) * 2017-09-14 2019-03-21 Dow Global Technologies Llc Lewis acid polymerization catalyst
WO2019055731A1 (en) * 2017-09-14 2019-03-21 Northwestern University Process of manufacturing polyols
WO2019055734A1 (en) * 2017-09-14 2019-03-21 Dow Global Technologies Llc Process of manufacturing polyols
US11970574B2 (en) 2017-09-14 2024-04-30 Dow Global Technologies Llc Process of manufacturing surfactants and lubricants
KR20200047678A (en) * 2017-09-14 2020-05-07 다우 글로벌 테크놀로지스 엘엘씨 Lewis acid polymerization catalyst
KR20200052900A (en) * 2017-09-14 2020-05-15 다우 글로벌 테크놀로지스 엘엘씨 Method for preparing polyol
KR20200053530A (en) * 2017-09-14 2020-05-18 다우 글로벌 테크놀로지스 엘엘씨 Method for preparing polyol
KR20200055742A (en) * 2017-09-14 2020-05-21 노쓰웨스턴유니버시티 Method for preparing polyol
KR20200055739A (en) * 2017-09-14 2020-05-21 노쓰웨스턴유니버시티 Method for preparing polyol
CN111225938A (en) * 2017-09-14 2020-06-02 陶氏环球技术有限责任公司 Process for making surfactants and lubricants
CN111263785A (en) * 2017-09-14 2020-06-09 陶氏环球技术有限责任公司 Lewis acid polymerization catalysts
CN111263784A (en) * 2017-09-14 2020-06-09 陶氏环球技术有限责任公司 Process for producing polyol
JP2020534387A (en) * 2017-09-14 2020-11-26 ダウ グローバル テクノロジーズ エルエルシー Polyol manufacturing process
WO2019055741A1 (en) * 2017-09-14 2019-03-21 Northwestern University Process of manufacturing surfactants and lubricants
JP2020534388A (en) * 2017-09-14 2020-11-26 ダウ グローバル テクノロジーズ エルエルシー Lewis acid polymerization catalyst
JP2020534395A (en) * 2017-09-14 2020-11-26 ダウ グローバル テクノロジーズ エルエルシー Polyol manufacturing process
JP2020534390A (en) * 2017-09-14 2020-11-26 ノースウェスタン ユニバーシティ Polyol manufacturing process
WO2019055725A1 (en) * 2017-09-14 2019-03-21 Northwestern University Process of manufacturing polyols
WO2019055727A1 (en) * 2017-09-14 2019-03-21 Dow Global Technologies Llc Process of manufacturing polyols
US11186683B2 (en) 2017-09-14 2021-11-30 Dow Global Technologies Llc Process of manufacturing surfactants and lubricants
US11198760B2 (en) 2017-09-14 2021-12-14 Dow Global Technologies Llc Process of manufacturing polyols
US11479642B2 (en) 2017-09-14 2022-10-25 Dow Global Technologies Llc Process of manufacturing polyols
US11958936B2 (en) 2017-09-14 2024-04-16 Dow Global Technologies Llc Process of manufacturing polyols
JP7263322B2 (en) 2017-09-14 2023-04-24 ダウ グローバル テクノロジーズ エルエルシー Lewis acid polymerization catalyst
JP7263323B2 (en) 2017-09-14 2023-04-24 ノースウェスタン ユニバーシティ Polyol manufacturing process
CN111263784B (en) * 2017-09-14 2023-05-12 陶氏环球技术有限责任公司 Method for producing polyols
CN111263785B (en) * 2017-09-14 2023-06-09 陶氏环球技术有限责任公司 Lewis acid polymerization catalyst
CN111225938B (en) * 2017-09-14 2023-06-16 陶氏环球技术有限责任公司 Method for producing surfactants and lubricants
JP7315539B2 (en) 2017-09-14 2023-07-26 ダウ グローバル テクノロジーズ エルエルシー Polyol manufacturing process
JP7372636B2 (en) 2017-09-14 2023-11-01 ノースウェスタン ユニバーシティ Polyol manufacturing process
KR102603181B1 (en) 2017-09-14 2023-11-16 다우 글로벌 테크놀로지스 엘엘씨 How to make polyol
KR102602895B1 (en) 2017-09-14 2023-11-16 다우 글로벌 테크놀로지스 엘엘씨 How to make polyol
KR102603166B1 (en) 2017-09-14 2023-11-16 노쓰웨스턴유니버시티 How to make polyol
KR102603117B1 (en) 2017-09-14 2023-11-17 노쓰웨스턴유니버시티 How to make polyol
KR102603979B1 (en) 2017-09-14 2023-11-21 다우 글로벌 테크놀로지스 엘엘씨 Lewis acid polymerization catalyst
US11912822B2 (en) 2017-09-14 2024-02-27 Dow Global Technologies Llc Process of manufacturing polyols
JP7163078B2 (en) 2018-06-14 2022-10-31 株式会社日本触媒 Compositions containing triarylboron compounds
JP2019218267A (en) * 2018-06-14 2019-12-26 株式会社日本触媒 Composition containing triaryl boron compound

Also Published As

Publication number Publication date
TW200904852A (en) 2009-02-01
JP5206671B2 (en) 2013-06-12
JPWO2008123323A1 (en) 2010-07-15

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