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WO2008099354A3 - Process of conversion of sulfur dioxide into salts of commercial interest - Google Patents

Process of conversion of sulfur dioxide into salts of commercial interest Download PDF

Info

Publication number
WO2008099354A3
WO2008099354A3 PCT/IB2008/050524 IB2008050524W WO2008099354A3 WO 2008099354 A3 WO2008099354 A3 WO 2008099354A3 IB 2008050524 W IB2008050524 W IB 2008050524W WO 2008099354 A3 WO2008099354 A3 WO 2008099354A3
Authority
WO
WIPO (PCT)
Prior art keywords
alkaline
metal
alkaline earth
earth metal
ammonium sulfite
Prior art date
Application number
PCT/IB2008/050524
Other languages
French (fr)
Other versions
WO2008099354B1 (en
WO2008099354A2 (en
Inventor
Holmer Victorio Angelini
Alberto Enrique Tramannoni
Original Assignee
Holmer Victorio Angelini
Alberto Enrique Tramannoni
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Holmer Victorio Angelini, Alberto Enrique Tramannoni filed Critical Holmer Victorio Angelini
Priority to MX2009008722A priority Critical patent/MX2009008722A/en
Priority to BRPI0807250A priority patent/BRPI0807250A2/en
Publication of WO2008099354A2 publication Critical patent/WO2008099354A2/en
Publication of WO2008099354A3 publication Critical patent/WO2008099354A3/en
Publication of WO2008099354B1 publication Critical patent/WO2008099354B1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
    • B01D53/502—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific solution or suspension
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/62—Methods of preparing sulfites in general
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/62—Methods of preparing sulfites in general
    • C01B17/625—Methods of preparing sulfites in general metabisulfites or pyrosulfites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
    • C01D5/14—Preparation of sulfites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
    • C01D5/14—Preparation of sulfites
    • C01D5/145—Pyrosulfites or metabisulfites

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Treating Waste Gases (AREA)

Abstract

A conversion process of SO2 into salts of commercial interest comprising the steps. of : a) carry out a first absorption stage comprising contacting an input gaseous stream (1) comprising SO2 with a first absorption phase (2) comprising alkaline metal, alkaline earth metal, or ammonium sulfite and bisulfite at a pH ranging between 8 and 4.5, b) oversaturate the phase comprising alkaline metal, alkaline earth metal, or ammonium sulfite and bisulfite, and induce precipitation of alkaline metal, alkaline earth metal, or ammonium metabisulf ite crystals, c) carry out a second absorption stage comprising contacting the output gaseous steam (1') from the first absorption stage (a) with a second absorption phase (6) comprising alkaline metal, alkaline earth metal, or ammonium sulfite at a pH between 9 and 7, and d) oversaturate the phase comprising alkaline metal, alkaline earth metal, or ammonium sulfite, and induce alkaline metal, alkaline earth metal, or ammonium sulfite crystal precipitation.
PCT/IB2008/050524 2007-02-15 2008-02-13 Process of conversion of sulfur dioxide into salts of commercial interest WO2008099354A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
MX2009008722A MX2009008722A (en) 2007-02-15 2008-02-13 Process of conversion of sulfur dioxide into salts of commercial interest.
BRPI0807250A BRPI0807250A2 (en) 2007-02-15 2008-02-13 "process of conversion of so² to salts of commercial interest"

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ARP070100643A AR059455A1 (en) 2007-02-15 2007-02-15 PROCESS OF CONVERSION OF SULFUR DIOXIDE IN SALTS OF COMMERCIAL INTEREST
ARP20070100643 2007-02-15

Publications (3)

Publication Number Publication Date
WO2008099354A2 WO2008099354A2 (en) 2008-08-21
WO2008099354A3 true WO2008099354A3 (en) 2008-10-23
WO2008099354B1 WO2008099354B1 (en) 2008-12-11

Family

ID=39272792

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2008/050524 WO2008099354A2 (en) 2007-02-15 2008-02-13 Process of conversion of sulfur dioxide into salts of commercial interest

Country Status (4)

Country Link
AR (1) AR059455A1 (en)
BR (1) BRPI0807250A2 (en)
MX (1) MX2009008722A (en)
WO (1) WO2008099354A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109316964A (en) * 2018-11-15 2019-02-12 中石化炼化工程（集团）股份有限公司 A kind of method of catalytic cracking flue gas desulfurization recycling sodium sulfite
CN112978768B (en) * 2019-12-13 2022-11-08 南京工业大学 System for producing sodium metabisulfite and preparation method
CN113069901B (en) * 2021-04-15 2022-09-30 江苏乾宏能源科技有限公司 Desulfurizing tower for semidry flue gas purification of circulating fluidized bed and purification method
CN114159941A (en) * 2021-11-29 2022-03-11 启东亚太药业有限公司 Method and equipment for synthesizing ammonium bisulfite

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3361524A (en) * 1963-04-05 1968-01-02 Basf Ag Production of pure sodium metabisulfite and sodium sulfite
US3615198A (en) * 1969-05-15 1971-10-26 Wellman Lord Inc Process employing potassium sulfite for recovering sulfur dioxide from gases containing same
US3995015A (en) * 1975-03-27 1976-11-30 Allied Chemical Corporation Process for making sodium metabisulfite
US4834959A (en) * 1986-03-10 1989-05-30 The Dow Chemical Company Process for selectively removing sulfur dioxide
US5593651A (en) * 1994-03-16 1997-01-14 Rhone-Poulenc Chimie Conversion of SO2 gaseous effluents into solutions of ammonium or alkali/alkaline earth metal bisulfites

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3361524A (en) * 1963-04-05 1968-01-02 Basf Ag Production of pure sodium metabisulfite and sodium sulfite
US3615198A (en) * 1969-05-15 1971-10-26 Wellman Lord Inc Process employing potassium sulfite for recovering sulfur dioxide from gases containing same
US3995015A (en) * 1975-03-27 1976-11-30 Allied Chemical Corporation Process for making sodium metabisulfite
US4834959A (en) * 1986-03-10 1989-05-30 The Dow Chemical Company Process for selectively removing sulfur dioxide
US5593651A (en) * 1994-03-16 1997-01-14 Rhone-Poulenc Chimie Conversion of SO2 gaseous effluents into solutions of ammonium or alkali/alkaline earth metal bisulfites

Also Published As

Publication number Publication date
WO2008099354B1 (en) 2008-12-11
AR059455A1 (en) 2008-04-09
WO2008099354A2 (en) 2008-08-21
MX2009008722A (en) 2009-11-23
BRPI0807250A2 (en) 2016-07-19

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