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WO2007062790A3 - Transition metal compound, ligand system, catalyst system and process for preparing polyolefins - Google Patents

Transition metal compound, ligand system, catalyst system and process for preparing polyolefins Download PDF

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Publication number
WO2007062790A3
WO2007062790A3 PCT/EP2006/011343 EP2006011343W WO2007062790A3 WO 2007062790 A3 WO2007062790 A3 WO 2007062790A3 EP 2006011343 W EP2006011343 W EP 2006011343W WO 2007062790 A3 WO2007062790 A3 WO 2007062790A3
Authority
WO
WIPO (PCT)
Prior art keywords
carbon atoms
group
organic
transition metal
radical
Prior art date
Application number
PCT/EP2006/011343
Other languages
French (fr)
Other versions
WO2007062790A2 (en
Inventor
Shahram Mihan
Benno Bildstein
Alexander Solchinger
Lars Koelling
Original Assignee
Basell Polyolefine Gmbh
Shahram Mihan
Benno Bildstein
Alexander Solchinger
Lars Koelling
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine Gmbh, Shahram Mihan, Benno Bildstein, Alexander Solchinger, Lars Koelling filed Critical Basell Polyolefine Gmbh
Priority to JP2008542646A priority Critical patent/JP2009518291A/en
Priority to EP06829139A priority patent/EP1954726A2/en
Priority to US12/085,611 priority patent/US7868108B2/en
Publication of WO2007062790A2 publication Critical patent/WO2007062790A2/en
Publication of WO2007062790A3 publication Critical patent/WO2007062790A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/54—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings condensed with carbocyclic rings or ring systems
    • C07D231/56—Benzopyrazoles; Hydrogenated benzopyrazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/06—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/06—Cobalt compounds
    • C07F15/065—Cobalt compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

The present invention relates to transition metal compounds of the formula (I); where M is an element of group 3, 4, 5, 6, 7, 8, 9 or 10 of the Periodic Table of the Elements or the lanthanide’s, the radicals X are identical or different and are each an organic or inorganic radical, with two radicals X also being able to be joined to one another to form a divalent radical, is 1 , 2, 3 or 4, L1 is an organic or inorganic uncharged ligand, is an integer from 0 to 4, R1 is an organic radical having from 1 to 40 carbon atoms, R2 is hydrogen or an organic radical having from 1 to 40 carbon atoms, or R1 and R2 together form a divalent organic group T1 which has from 2 to 40 carbon atoms and together with the atoms connecting its ends forms a monocyclic or polycyclic ring system which may in turn be substituted and may comprise one or more further heteroatoms selected from the group consisting of the elements O, S, Se, Te, N, P and As in the ring system, R3 is hydrogen or an organic radical having from 1 to 40 carbon atoms, R4 is hydrogen or an organic radical having from 1 to 40 carbon atoms, or R3 and R4 together form a divalent organic group T2 which has from 2 to 40 carbon atoms and together with the atoms connecting its ends forms a monocyclic or polycyclic ring system which may in turn be substituted and may comprise one or more heteroatoms selected from the group consisting of the elements O, S, Se, Te, N, P and As in the ring system, R5 is an uncharged or negatively charged organic radical which has from 1 to 40 carbon atoms and may comprise a heteroatom selected from the group consisting of the elements N, O, P, S, As and Sb, and m is an integer from 1 to 10, ligand systems having such a substitution pattern, ligand systems comprising at least one of the transition metal compounds according to the invention, a process for preparing polyolefins by polymerization or copolymerization of at least one olefin in the presence of at least one of the catalyst systems according to the invention and the use of the ligand systems according to the invention for preparing transition metal compounds.
PCT/EP2006/011343 2005-11-30 2006-11-27 Transition metal compound, ligand system, catalyst system and process for preparing polyolefins WO2007062790A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2008542646A JP2009518291A (en) 2005-11-30 2006-11-27 Transition metal compound, ligand system, catalyst system, and method for producing polyolefin
EP06829139A EP1954726A2 (en) 2005-11-30 2006-11-27 Transition metal compound, ligand system, catalyst system and process for preparing polyolefins
US12/085,611 US7868108B2 (en) 2005-11-30 2006-11-27 Transition metal compound, ligand system, catalyst system and process for preparing polyolefins

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE102005057559A DE102005057559A1 (en) 2005-11-30 2005-11-30 New transition pyrazole metal compound useful for e.g. the oligomerization, polymerization or copolymerization of polyolefin, preferably ethylene
DE102005057559.5 2005-11-30
US75327205P 2005-12-22 2005-12-22
US60/753,272 2005-12-22

Publications (2)

Publication Number Publication Date
WO2007062790A2 WO2007062790A2 (en) 2007-06-07
WO2007062790A3 true WO2007062790A3 (en) 2007-07-19

Family

ID=38037848

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2006/011343 WO2007062790A2 (en) 2005-11-30 2006-11-27 Transition metal compound, ligand system, catalyst system and process for preparing polyolefins

Country Status (5)

Country Link
US (1) US7868108B2 (en)
EP (1) EP1954726A2 (en)
JP (1) JP2009518291A (en)
DE (1) DE102005057559A1 (en)
WO (1) WO2007062790A2 (en)

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US9352270B2 (en) 2011-04-11 2016-05-31 ADA-ES, Inc. Fluidized bed and method and system for gas component capture
US8664461B2 (en) 2012-03-19 2014-03-04 Exxonmobil Chemical Patents Inc. Catalysts for producing polyalpha-olefins and processes related thereto
CN104812467B (en) 2012-09-20 2017-05-17 Ada-Es股份有限公司 Method and system to reclaim functional sites on sorbent contaminated by heat stable salts
ITMI20122199A1 (en) * 2012-12-20 2014-06-21 Versalis Spa PROCEDURE FOR THE PREPARATION OF (CO) POLYMERS OF DIENES CONJUGATED IN THE PRESENCE OF A CATALYTIC SYSTEM INCLUDING A BIS-IMMINICO DI COBALTO COMPLEX
CN105562088B (en) * 2014-10-13 2017-11-07 中国石油化工股份有限公司 A kind of ethylene oligomerisation catalyst composition and ethylene oligomerization method
CN105503763B (en) * 2014-10-17 2020-11-03 上海中科康润新材料科技有限公司 Polyolefin oil catalyst and application thereof
JP6790393B2 (en) * 2016-03-16 2020-11-25 三菱ケミカル株式会社 Method for producing α-olefin low polymer
JP6821932B2 (en) * 2016-03-22 2021-01-27 三菱ケミカル株式会社 Method for producing α-olefin low polymer
BR112021001125B1 (en) * 2018-07-31 2024-01-30 Dow Global Technologies Llc CATALYST SYSTEM AND POLYMERIZATION PROCESS
CN109569724B (en) * 2018-11-02 2021-11-02 中山大学 Saturated polyolefin lubricating oil base oil and preparation method thereof

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Also Published As

Publication number Publication date
WO2007062790A2 (en) 2007-06-07
JP2009518291A (en) 2009-05-07
US7868108B2 (en) 2011-01-11
DE102005057559A1 (en) 2007-05-31
US20090156768A1 (en) 2009-06-18
EP1954726A2 (en) 2008-08-13

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