[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

WO2003093209A1 - Procede de fabrication de carburants pour moteurs - Google Patents

Procede de fabrication de carburants pour moteurs Download PDF

Info

Publication number
WO2003093209A1
WO2003093209A1 PCT/RU2003/000188 RU0300188W WO03093209A1 WO 2003093209 A1 WO2003093209 A1 WO 2003093209A1 RU 0300188 W RU0300188 W RU 0300188W WO 03093209 A1 WO03093209 A1 WO 03093209A1
Authority
WO
WIPO (PCT)
Prior art keywords
gas
gasoline
dμe
sinτez
πρi
Prior art date
Application number
PCT/RU2003/000188
Other languages
English (en)
Russian (ru)
Inventor
Boris Tikhnovich Plachenov
Anatoly Anatolievich Barunin
Toomas Ernstovich Kekhva
Viktor Nikolaevich Lebedev
Stanislav Michailovich Andriushkin
Sergei Konstantinovich Petrov
Aleksandr Vasilievich Koveshnikov
Evgeny Sergeevich Mortikov
Vladilen Abramovich Machlin
Yuri Nikolaevich Filimonov
Vladimir Afanasievich Pinchuk
Valery Timofeevich Shevchuk
Valerian Vigdorovich Krasnik
Oleg Pavlovich Nikotin
Original Assignee
Zakrytoe Aktsionernoe Obschestvo 'departament Nauchno-Proizvodstvennich I Commercheskich Otnosheny'
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zakrytoe Aktsionernoe Obschestvo 'departament Nauchno-Proizvodstvennich I Commercheskich Otnosheny' filed Critical Zakrytoe Aktsionernoe Obschestvo 'departament Nauchno-Proizvodstvennich I Commercheskich Otnosheny'
Publication of WO2003093209A1 publication Critical patent/WO2003093209A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1022—Fischer-Tropsch products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1025—Natural gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4012—Pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Definitions

  • the process is carried out in two investigative processes at a pressure of 0.5-10.0 without any interventions.
  • the synthesis gas is converted to one or more catalysts that turn off the synthesis gas at a temperature of 150-400 ° C or less.
  • the main disadvantage of the method for the CCC ⁇ »632296 is the low yield of liquid hydrocarbon fractions based on the converted carbon dioxide.
  • the process for the production of gasoline from the synthesis gas is known, while the synthesis gas is converted to gasoline through the liquid phase, the process is used for the process of the process C07C 001 / 04.1995.
  • the dimethyl ether is converted to gasoline on the whole catalytic converter ⁇ ⁇ -5 at a temperature of 340-540 ° ⁇ .
  • the disadvantage of this process is the lack of means to prevent the allocation of fines as a target product.
  • No. 2143417 is not a high yield of ⁇ , but, consequently, a gasoline fraction, calculated on the supplied carbon oxides. This is due to the fact that after the first stage of the process, one of the gaseous fluids, which does not contain the converted synthesis gas components, is inhibited. It returns to the same reaction of the synthesis of DEP of the first stage, mixing with the original synthesis gas. It is known that, due to the synthesis of DEP, non-reactive synthesis gas is burned with carbon dioxide.
  • the objective of the claimed method for the sale of industrial fuel is to increase the output of diesel fuel and, accordingly, the gasoline fraction based on the processed carbon dioxide.
  • the synthesis gas is produced in the form of a mixture of ⁇ , ⁇ 2 , ⁇ 0 2 and 2 in the process of direct non-catalytic oxidized gas (an atmospheric gas)
  • ⁇ For the production of gasoline fractions, ⁇ gives rise to a catalytic reaction of gasoline; Such as ⁇ , ⁇ notes 2 0, oxides of rare-earth metals and converting diesel to gasoline, gaseous hydrocarbons, and aqueous fractions, with the following investigation.
  • the gas supply after an additional catalytic process 4 of the DDE synthesis cools and absorbs the absorber while supplying it with zhid ⁇ im me ⁇ an ⁇ l ⁇ m in s ⁇ ubbe ⁇ e 5 ⁇ azdelyaya gaz ⁇ vy ⁇ on zhid ⁇ uyu and gaz ⁇ vuyu ⁇ azu, ⁇ i e ⁇ m from gaz ⁇ v ⁇ g ⁇ ⁇ a ⁇ ndensi ⁇ uyu ⁇ zhid ⁇ ie ⁇ du ⁇ y - v ⁇ du and D ⁇ E and gaz ⁇ vuyu ⁇ azu, ⁇ eds ⁇ avlyayuschuyu s ⁇ b ⁇ y ⁇ s ⁇ a ⁇ i not ⁇ eagi ⁇ - vavshi ⁇ ⁇ m ⁇ nen ⁇ v sin ⁇ ez gas from vyv ⁇ dya ⁇ technological process.
  • Sources of raw materials Composition of air,% of the product: Quarter - 78.09%; Acidum - 20.95%; ⁇ Vietnamese - 0.93%; unspecified gases - other.
  • ⁇ high temperature treatment ( ⁇ ) 1 supplies natural gas and exhaust and temperature of 1450 ° C and a pressure of 5.20 psi and direct non-catalytic
  • ⁇ high temperature treatment 1 supplies natural gas and exhaust and temperature of 1450 ° C and a pressure of 5.20 psi and direct non-catalytic
  • a quick gas-oxidized conversion produces a synthesis gas system (as a result of dry gas):
  • the carbon conversion of the original hydrocarbons in the carbon dioxide oxide is 89%.
  • the resulting synthesis gas gives rise to a catalytic reaction 2 of the dimethyl ester, where the synthesis gas enters the medium, which is very volatile
  • the source of the initial oxide of carbon dioxide in D ⁇ E is 58.3%.
  • the source of carbon dioxide in the methane is 1%.
  • P ⁇ luchennuyu gaz ⁇ vuyu ⁇ lazhdayu ⁇ d ⁇ mixture was 50 ° C and in liquid ⁇ azdelyayu ⁇ ⁇ uyu and gaz ⁇ vuyu ⁇ azu ⁇ i ⁇ dache ⁇ iv ⁇ m with zhid ⁇ im me ⁇ an ⁇ l ⁇ m in s ⁇ ub- be ⁇ e 3 ⁇ i pressure 5.1 ⁇ Pa, ⁇ b ⁇ gaschenny dime ⁇ il ⁇ vym e ⁇ i ⁇ m me ⁇ an ⁇ l na ⁇ avlyayu ⁇ on ⁇ delenie D ⁇ E in ⁇ e ⁇ i ⁇ i ⁇ atsi ⁇ nnuyu ⁇ l ⁇ nnu 6 ⁇ i pressure a helmet of 1.2 ⁇ Pa and a temperature of 60 C, after which D ⁇ E is transferred to the drive 7, and the methane is returned to the technological process.
  • the gas obtained in React 4 has the following compositions (ob.>): Component of the beginning of the synthesis The end of the synthesis After removing the DEC
  • the difference between the previous pressure and the temperature of the synthesis gas is a little higher.
  • the composition of the catalyst is similar.
  • the difference in type 1 at the stage of the conversion of diesel fuel to gasoline fractions is the use of a catalyst containing 65% ⁇ and 35%> ⁇ - ⁇ 1 2 0 3 ⁇ 38 ° C, 1975 ° C.
  • the inventive method for the production of industrial fuel from the natural gas is used to increase the output of diesel fuel and, accordingly, the gasoline-fueled energy consumption is increased.
  • Using this product requires the use of synthesis gas and the production of synthesis gas.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention concerne un procédé de fabrication de carburants pour moteurs. Selon l'invention, on fabrique du gaz de synthèse par la conversion à oxygénation non catalytique en phase gazeuse en utilisant l'oxygène contenu dans l'air, à une température entre 800 et 1500 °C et à une pression entre 1 et 10 MPa. On effectue ensuite la conversion catalytique du gaz de synthèse dans un réacteur de synthèse d'éther diméthylique, la phase gazeuse étant ensuite refroidie et séparée en phases liquide et gazeuse. On produit à partir de la phase gazeuse de l'éther diméthylique qui est envoyé dans un réacteur catalytique de synthèse d'essence; la phase gazeuse contenant des composants non transformés du gaz de synthèse sont soumis à une deuxième conversion catalytique, dans un réacteur supplémentaire de synthèse d'éther diméthylique, sans mélangeage avec le gaz de synthèse de départ. L'invention permet ainsi d'augmenter la production de l'éther diméthylique et, partant, de la fraction d'essence, et de réduire ainsi les frais grâce à l'utilisation de l'oxygène contenu dans l'air.
PCT/RU2003/000188 2002-04-30 2003-04-22 Procede de fabrication de carburants pour moteurs WO2003093209A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2002112366 2002-04-30
RU2002112366/04A RU2226524C2 (ru) 2002-04-30 2002-04-30 Способ получения моторных топлив

Publications (1)

Publication Number Publication Date
WO2003093209A1 true WO2003093209A1 (fr) 2003-11-13

Family

ID=29398632

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/RU2003/000188 WO2003093209A1 (fr) 2002-04-30 2003-04-22 Procede de fabrication de carburants pour moteurs

Country Status (2)

Country Link
RU (1) RU2226524C2 (fr)
WO (1) WO2003093209A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2286327C1 (ru) * 2005-08-04 2006-10-27 ООО "Компания по освоению новых технологий в топливно-энергетическом комплексе-"КОНТТЭК" Способ получения моторных топлив
RU2649629C1 (ru) * 2016-11-24 2018-04-05 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Способ получения синтетической нефти из природного или попутного нефтяного газа (варианты)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU632296A3 (ru) * 1973-08-09 1978-11-05 Мобил Ойл Корпорейшн (Фирма) Способ получени синтетического бензина
US4481305A (en) * 1982-09-07 1984-11-06 Haldor Topsoe A/S Process for the preparation of hydrocarbons
US4520215A (en) * 1984-04-16 1985-05-28 Mobil Oil Corporation Catalytic conversion of olefinic Fischer-Tropsch light oil to heavier hydrocarbons
RU2089533C1 (ru) * 1994-07-04 1997-09-10 Конструкторско-технологический институт каталитических и адсорбционных процессов на цеолитах "Цеосит" СО РАН Способ получения углеводородов бензиновых фракций
RU2143417C1 (ru) * 1998-07-27 1999-12-27 Институт катализа им.Г.К.Борескова СО РАН Способ получения моторных топлив из углеродсодержащего сырья

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU632296A3 (ru) * 1973-08-09 1978-11-05 Мобил Ойл Корпорейшн (Фирма) Способ получени синтетического бензина
US4481305A (en) * 1982-09-07 1984-11-06 Haldor Topsoe A/S Process for the preparation of hydrocarbons
US4520215A (en) * 1984-04-16 1985-05-28 Mobil Oil Corporation Catalytic conversion of olefinic Fischer-Tropsch light oil to heavier hydrocarbons
RU2089533C1 (ru) * 1994-07-04 1997-09-10 Конструкторско-технологический институт каталитических и адсорбционных процессов на цеолитах "Цеосит" СО РАН Способ получения углеводородов бензиновых фракций
RU2143417C1 (ru) * 1998-07-27 1999-12-27 Институт катализа им.Г.К.Борескова СО РАН Способ получения моторных топлив из углеродсодержащего сырья

Also Published As

Publication number Publication date
RU2226524C2 (ru) 2004-04-10

Similar Documents

Publication Publication Date Title
US5620670A (en) Process for the production of hydrocarbons
US5500449A (en) Process for the production of hydrocarbons
US5324335A (en) Process for the production of hydrocarbons
JP5127229B2 (ja) 二重機能性合成ガス変換の使用によるフィッシャートロプシュ設備からのｃｏ２放出の制御
US4115075A (en) Process for the production of fuel values from carbonaceous materials
JP2832492B2 (ja) 天然ガスからのアルキル芳香族炭化水素の製造方法
JPS63275691A (ja) 抽出を伴なう粗メタノールのガソリンへの転化方法
JPH06506482A (ja) 炭化水素クラッキングとメタンカップリングとを組合わせたオレフィンプロセス
US4263141A (en) Process of producing gasoline from synthesis gas
WO2007108014A1 (fr) Procédé de production de carburant liquide à partir de dioxyde de carbone et d'eau
US8932456B2 (en) Integrated process for the manufacture of olefins and intermediates for the productions of ammonia and urea
US6627666B1 (en) Fischer-Tropsch synthesis using industrial process off gas feedstreams
AU668483B2 (en) Method of coal liquefaction
US2234941A (en) Method of synthesizing hydrocarbons
US4857667A (en) System for conversion of crude oxygenate to gasoline with feedstock extraction
AU2010265170A1 (en) Process for the preparation of hydrocarbons from synthesis gas
AU783766B2 (en) Process for the preparation of lower olefins
AU2010201108A1 (en) Process for the preparation of hydrocarbons from oxygenates
US9034208B1 (en) Process to convert natural gas into liquid fuels and chemicals
WO2003093209A1 (fr) Procede de fabrication de carburants pour moteurs
RU2196761C2 (ru) Способ получения бензина из углеводородного газового сырья
US6433235B1 (en) Method for converting methane-containing gaseous hydrocarbon mixtures to liquid hydrocarbons
WO2003083013A1 (fr) Synthese fischer-tropsch utilisant des flux d'alimentation de degagement gazeux resultant de procedes industriels
RU2539656C1 (ru) Способ получения жидких углеводородов из углеводородного газа и установка для его осуществления
JPS6130540A (ja) ジアルキルカ−ボネ−トあるいはジアルキルオキサレ−トとｔｅｒｔ−ブタノ−ルとを併産する方法

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AT AZ BG BR BY CA CH CN CZ DE DK ES FI GB HU JP KG KR KZ LT LV MK MX NO PL PT RU SE SK TR UA US UZ VN

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT RO SE SI SK TR

121 Ep: the epo has been informed by wipo that ep was designated in this application
122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: JP

WWW Wipo information: withdrawn in national office

Country of ref document: JP