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US20100233480A1 - Process for producing fiber of ultra high molecular weight polyethylene - Google Patents

Process for producing fiber of ultra high molecular weight polyethylene Download PDF

Info

Publication number
US20100233480A1
US20100233480A1 US12/299,205 US29920507A US2010233480A1 US 20100233480 A1 US20100233480 A1 US 20100233480A1 US 29920507 A US29920507 A US 29920507A US 2010233480 A1 US2010233480 A1 US 2010233480A1
Authority
US
United States
Prior art keywords
uhmwpe
fiber
solvent
extruder
emulsion mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US12/299,205
Other languages
English (en)
Inventor
Panpan Hu
Xiulan You
Zhaofeng Liu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CN200610118076XA external-priority patent/CN101235551B/zh
Priority claimed from CNA2006101474246A external-priority patent/CN101205637A/zh
Priority claimed from CNA2007100406782A external-priority patent/CN101307509A/zh
Priority claimed from CNA2007100438317A external-priority patent/CN101348944A/zh
Application filed by Individual filed Critical Individual
Publication of US20100233480A1 publication Critical patent/US20100233480A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/46Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D1/00Treatment of filament-forming or like material
    • D01D1/02Preparation of spinning solutions
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/253Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/298Physical dimension

Definitions

  • a method of preparing a high strength, high modulus polyethylene (PE) fiber from UHMWPE gel via drawing or stretching technology is disclosed in UK Patent Nos. GB2042414 and GB2051667, assigned to DSM Company, Netherlands in 1979. After that, this technology was industrialized by Allied Company from the U.S., Toyobo-DSM Company, a joint venture by Japan and Netherlands, as well as Mitsui Company from Japan. In 1982, Allied Company obtained U.S. Pat. No. 4,413,110, which covers a process of preparing UHMWPE fiber. Donghua University in China also obtained Chinese Patent Nos. 89107905 and 97106768 in this area.
  • the PE powder having a relative MW of 1 million to 6 million is mixed with polar polymer and solvent in an appropriate ratio, and the resulting mixture is fed into an untwisting equipment to untwist, and thereby forming a uniform emulsion mixture.
  • the solvent used is liquid under room temperature, and it may be alkane (or paraffin) or its derivative, cycloalkane (or cycloparaffin) or its derivative, aromatic hydrocarbon or its derivative, or mixtures thereof.
  • UHMWPE Relative Average Molecule Weight 4.5M powder and #90 solvent white oil with a weight ratio of 1:8, were fed into an untwisting pan at room temperature, and underwent cutting for 10 minutes at a speed of 2000 S ⁇ 1 under N 2 protection, to form a homogeneous emulsion mixture.
  • the extruded material was filtered, and spun into a gel filament through a spinnerette, then extracted and stretched at a stretch ratio of 35, to provide UHMWPE.
  • UHMWPE Relative Average Molecule Weight 4.5M powder
  • the extruded material was filtered, and spun into a gel filament through a spinnerette, then extracted and stretched at a draw ratio of 35, to produce UHMWPE with high adhesive properties.
  • UHMWPE (Relative Average Molecule Weight 4.5M) powder and #90 solvent white oil with weight ratio of 1:8 were fed into an untwisting pan at room temperature, and further added polyoxyethylene with an amount of 4% by weight of the UHMWPE powder, and underwent cutting for 10 minutes under N 2 protection at a speed of 2000 S ⁇ 1 , to form a homogeneous emulsion mixture.
  • the extruded material was filtered, and spun into a gel filament through a spinnerette, then extracted and stretched at a draw ratio of 35, to produce UHMWPE with high adhesive properties.
  • UHMWPE (Relative Average Molecule Weight 4.5M) powder and #90 solvent white oil with a nominal concentration of 10% (wt) were fed into an untwisting pan at room temperature, and underwent cutting for 5 minutes under N 2 protection at a speed of 3000 S ⁇ 1 , to form a homogeneous emulsion mixture.
  • UHMWPE (Relative Average Molecule Weight 4.5 M) powder and #70 solvent white oil with a nominal concentration of 10% (wt) were fed into an untwisting pan at room temperature, and further added 1% (wt) of epoxy modified silicone oil, and underwent cutting for 5 minutes under N 2 protection at a speed of 3000 S ⁇ 1 , to form a homogeneous emulsion mixture.
  • the extruded material was passed through a filter tank and a metering pump to get a measurement, and spun into a gel filament through a spinnerette, passed through a water bath containing 1.5wt % of epoxy modified silicone oil, followed by extraction, drying and stretching at a draw ratio of 40, to produce UHMWPE fiber with Rupture Strength of 35 cN/dtex and Young's Modulus of over 1050 cN/dtex.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Artificial Filaments (AREA)
  • Chemical Treatment Of Fibers During Manufacturing Processes (AREA)
US12/299,205 2006-11-08 2007-10-09 Process for producing fiber of ultra high molecular weight polyethylene Abandoned US20100233480A1 (en)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
CN200610118076.X 2006-11-08
CN200610118076XA CN101235551B (zh) 2006-11-08 2006-11-08 一种高剪切超高分子量聚乙烯连续溶解纺丝新方法
CN200610147424.6 2006-12-18
CNA2006101474246A CN101205637A (zh) 2006-12-18 2006-12-18 高强高模超高分子量聚乙烯扁平纤维制备方法
CN200710040678.2 2007-05-15
CNA2007100406782A CN101307509A (zh) 2007-05-15 2007-05-15 一种超高分子量聚乙烯纤维纺丝新方法
CN200710043831.7 2007-07-16
CNA2007100438317A CN101348944A (zh) 2007-07-16 2007-07-16 高粘接性超高分子量聚乙烯纤维的制造新方法
PCT/CN2007/002906 WO2008055405A1 (fr) 2006-11-08 2007-10-09 Procédé de production de fibre de polyéthylène de masse moléculaire très élevée

Publications (1)

Publication Number Publication Date
US20100233480A1 true US20100233480A1 (en) 2010-09-16

Family

ID=39364173

Family Applications (1)

Application Number Title Priority Date Filing Date
US12/299,205 Abandoned US20100233480A1 (en) 2006-11-08 2007-10-09 Process for producing fiber of ultra high molecular weight polyethylene

Country Status (5)

Country Link
US (1) US20100233480A1 (fr)
EP (1) EP2080824B1 (fr)
AT (1) ATE478178T1 (fr)
DE (1) DE602007008600D1 (fr)
WO (1) WO2008055405A1 (fr)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110276280A1 (en) * 2010-05-07 2011-11-10 Testing Machines, Inc. Yarn entanglement strength tester
US20120306109A1 (en) * 2009-11-26 2012-12-06 Ningbo Dacheng Advanced Material Co., Ltd. Method For Evenly Preparing Filament By Using High-Shearing Solution of Ultrahigh-Molecular-Weight Polyethylene
CN103590130A (zh) * 2013-10-11 2014-02-19 杭州翔盛高强纤维材料股份有限公司 一种改善超高分子量聚乙烯纤维纺丝液流动性的方法
US20150164158A1 (en) * 2013-12-13 2015-06-18 Honeywell International Inc. Protective overglove for glove-box gloves
CN104846446A (zh) * 2015-05-22 2015-08-19 江苏神鹤科技发展有限公司 交联的超高分子量聚乙烯纤维及其干式制备方法
US9296875B2 (en) 2010-08-24 2016-03-29 Beijing Tongyizhong Specialty Fibre Technology & Development Co., Ltd Method for preparing spinning solution of ultra-high molecular weight polyethylene fiber
WO2016089969A3 (fr) * 2014-12-02 2016-08-25 Braskem America, Inc. Procédé et système continus pour la production d'au moins un fil polymère et fil polymère
CN112725918A (zh) * 2020-12-23 2021-04-30 中国纺织科学研究院有限公司 聚乙烯纤维的制备方法及纤维
CN112778598A (zh) * 2019-11-08 2021-05-11 中国石油化工股份有限公司 一种聚烯烃组合物及其制备方法和应用
US11230797B2 (en) 2011-12-14 2022-01-25 Dsm Ip Assets B.V. Ultra high molecular weight polyethylene multifilament yarn
CN114100187A (zh) * 2021-09-18 2022-03-01 江苏九九久科技有限公司 一种萃取槽
CN115054735A (zh) * 2022-07-05 2022-09-16 首都医科大学附属北京口腔医院 多孔复合支架及其制备方法与应用、epl修饰支架及其制备方法与应用
CN115262015A (zh) * 2022-07-28 2022-11-01 中国水产科学研究院东海水产研究所 一种持久高效抗菌纤维的制备方法
US11866849B2 (en) * 2013-10-29 2024-01-09 Braskem America, Inc. System and method of dosing a polymer mixture with a first solvent, device, system and method of extracting solvent from at least one polymeric yarn, system and method of mechanical pre-recovery of at least one liquid in at least one polymeric yarn, and continuous system and method for producing at least one polymeric yarn

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9365953B2 (en) 2007-06-08 2016-06-14 Honeywell International Inc. Ultra-high strength UHMWPE fibers and products
US8747715B2 (en) 2007-06-08 2014-06-10 Honeywell International Inc Ultra-high strength UHMW PE fibers and products
CN102534838B (zh) * 2010-12-07 2014-09-03 北京同益中特种纤维技术开发有限公司 一种超高分子量聚乙烯纤维纺丝原液及其制备方法
CN102580159A (zh) * 2012-03-13 2012-07-18 中国矿业大学 一种自增强超高分子量聚乙烯髋关节臼的制备工艺
CN104790050B (zh) * 2014-03-28 2019-05-21 上海斯瑞科技有限公司 一种超高分子量聚乙烯纤维的制备方法及水洗装置
CN109666976B (zh) * 2017-10-16 2021-04-06 中国石油化工股份有限公司 提高超高分子量聚乙烯纤维产品性能的方法
CN109306061A (zh) * 2018-06-06 2019-02-05 深圳大学 超高分子量聚乙烯纺丝溶液的制备方法和超高分子量聚乙烯纤维
CN109161978B (zh) * 2018-09-03 2021-06-11 中国科学院宁波材料技术与工程研究所 一种高粘结、高强超高分子量聚乙烯纤维的制备方法及其产品
CN112111802B (zh) * 2019-06-20 2022-06-10 李乾坤 一种超高强度超高分子量聚乙烯纤维及其制造方法
CN112281237B (zh) * 2020-11-03 2022-09-27 北京复维新材科技有限公司 一种高模量抗蠕变超高分子量聚乙烯纤维及其制备方法
CN113668086B (zh) * 2021-08-24 2022-08-16 盐城工学院 高界面粘附性超高分子量聚乙烯纤维及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4413110A (en) * 1981-04-30 1983-11-01 Allied Corporation High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore
US5741848A (en) * 1995-03-08 1998-04-21 Tonen Chemical Corporation Method of manufacturing polyolefin solutions
US6054086A (en) * 1995-03-24 2000-04-25 Nippon Petrochemicals Co., Ltd. Process of making high-strength yarns

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US480136A (en) 1892-08-02 Shutter-bower
US4020230A (en) 1975-10-03 1977-04-26 The Dow Chemical Company Microporous polyethylene hollow fibers and process of preparing them
NL177759B (nl) 1979-06-27 1985-06-17 Stamicarbon Werkwijze ter vervaardiging van een polyetheendraad, en de aldus verkregen polyetheendraad.
NL177840C (nl) 1979-02-08 1989-10-16 Stamicarbon Werkwijze voor het vervaardigen van een polyetheendraad.
JPH0246053B2 (ja) 1983-06-16 1990-10-12 Kogyo Gijutsu Incho Chokobunshiryohoriechirenyoekinoseizohoho
JPS61124621A (ja) * 1984-11-19 1986-06-12 Ntn Toyo Bearing Co Ltd 超高分子量ポリエチレン繊維の製造方法
WO1986004936A1 (fr) 1985-02-15 1986-08-28 Toray Industries, Inc. Fil multifilament en polyethylene
CN1004364B (zh) 1985-02-15 1989-05-31 斯塔米卡本公司(Dsm附属公司) 连续制备均匀的高分子聚合物溶液的方法
DE3675079D1 (de) 1985-06-17 1990-11-29 Allied Signal Inc Polyolefinfaser mit hoher festigkeit, niedrigem schrumpfen, ultrahohem modul, sehr niedrigem kriechen und mit guter festigkeitserhaltung bei hoher temperatur sowie verfahren zu deren herstellung.
JPS6315838A (ja) 1986-07-08 1988-01-22 Nippon Petrochem Co Ltd 超高分子量ポリエチレン溶液
US5039549A (en) 1989-10-17 1991-08-13 Allied-Signal Inc. Treatment of ultrahigh molecular weight polyolefin to improve adhesion to a resin
CN1056544A (zh) * 1990-05-14 1991-11-27 中国纺织大学 高强、高模聚乙烯纤维的制备方法
DE69117175T2 (de) 1990-11-28 1996-10-24 Mitsubishi Rayon Co Poröse hohlfasermembran aus polyethylen und ihre herstellung
US5230854A (en) * 1991-12-09 1993-07-27 Allied-Signal Inc. Method for removal of spinning solvent from spun fiber
US5695702A (en) 1994-07-01 1997-12-09 Millipore Corporation Thermoplastic hollow fiber membrane module and method of manufacture
US5755913A (en) 1996-12-06 1998-05-26 Liaw; Der-Jang Adhesive-free adhesion between polymer surfaces
CN1060543C (zh) * 1997-01-02 2001-01-10 中国纺织科学研究院 超高分子量聚乙烯纤维连续制备方法和设备
KR100302209B1 (ko) 1999-04-27 2001-09-22 주덕영 순환연신법에 의한 고밀도 폴리에틸렌 중공사 분리막의 제조방법 및 그 장치
US6448359B1 (en) 2000-03-27 2002-09-10 Honeywell International Inc. High tenacity, high modulus filament
CN100410431C (zh) * 2002-12-10 2008-08-13 帝斯曼知识产权资产管理有限公司 制造和转化聚烯烃纤维的方法
JP4578483B2 (ja) * 2004-01-01 2010-11-10 ディーエスエム アイピー アセッツ ビー.ブイ. 高性能ポリエチレンマルチフィラメント糸の製造方法
CN100395386C (zh) 2005-05-10 2008-06-18 东华大学 一种提高超高相对分子量聚乙烯纤维表面粘结性能的方法
EP1746187A1 (fr) 2005-07-18 2007-01-24 DSM IP Assets B.V. Fil multifilament en polyéthylène

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4413110A (en) * 1981-04-30 1983-11-01 Allied Corporation High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore
US5741848A (en) * 1995-03-08 1998-04-21 Tonen Chemical Corporation Method of manufacturing polyolefin solutions
US6054086A (en) * 1995-03-24 2000-04-25 Nippon Petrochemicals Co., Ltd. Process of making high-strength yarns

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20120306109A1 (en) * 2009-11-26 2012-12-06 Ningbo Dacheng Advanced Material Co., Ltd. Method For Evenly Preparing Filament By Using High-Shearing Solution of Ultrahigh-Molecular-Weight Polyethylene
US9581531B2 (en) * 2010-05-07 2017-02-28 Lawson Hemphill, Inc. Yarn entanglement strength tester
US8131483B2 (en) * 2010-05-07 2012-03-06 Testing Machines, Inc. Yarn entanglement strength tester
US20120125119A1 (en) * 2010-05-07 2012-05-24 Testing Machines, Inc. Yarn entanglement strength tester
US20110276280A1 (en) * 2010-05-07 2011-11-10 Testing Machines, Inc. Yarn entanglement strength tester
US9296875B2 (en) 2010-08-24 2016-03-29 Beijing Tongyizhong Specialty Fibre Technology & Development Co., Ltd Method for preparing spinning solution of ultra-high molecular weight polyethylene fiber
US11746442B2 (en) 2011-12-14 2023-09-05 Avient Protective Materials B.V. Ultra high molecular weight polyethylene multifilament yarn
US11230797B2 (en) 2011-12-14 2022-01-25 Dsm Ip Assets B.V. Ultra high molecular weight polyethylene multifilament yarn
CN103590130A (zh) * 2013-10-11 2014-02-19 杭州翔盛高强纤维材料股份有限公司 一种改善超高分子量聚乙烯纤维纺丝液流动性的方法
US12031234B2 (en) * 2013-10-29 2024-07-09 Braskem America, Inc. System and method of dosing a polymer mixture with a first solvent, device, system and method of extracting solvent from at least one polymeric yarn, system and method of mechanical pre-recovery of at least one liquid in at least one polymeric yarn, and continuous system and method for producing at least one polymeric yarn
US20240026571A1 (en) * 2013-10-29 2024-01-25 Braskem America, Inc. System and method of dosing a polymer mixture with a first solvent, device, system and method of extracting solvent from at least one polymeric yarn, system and method of mechanical pre-recovery of at least one liquid in at least one polymeric yarn, and continuous system and method for producing at least one polymeric yarn
US11866849B2 (en) * 2013-10-29 2024-01-09 Braskem America, Inc. System and method of dosing a polymer mixture with a first solvent, device, system and method of extracting solvent from at least one polymeric yarn, system and method of mechanical pre-recovery of at least one liquid in at least one polymeric yarn, and continuous system and method for producing at least one polymeric yarn
US20150164158A1 (en) * 2013-12-13 2015-06-18 Honeywell International Inc. Protective overglove for glove-box gloves
WO2016089969A3 (fr) * 2014-12-02 2016-08-25 Braskem America, Inc. Procédé et système continus pour la production d'au moins un fil polymère et fil polymère
CN104846446A (zh) * 2015-05-22 2015-08-19 江苏神鹤科技发展有限公司 交联的超高分子量聚乙烯纤维及其干式制备方法
CN112778598A (zh) * 2019-11-08 2021-05-11 中国石油化工股份有限公司 一种聚烯烃组合物及其制备方法和应用
CN112725918A (zh) * 2020-12-23 2021-04-30 中国纺织科学研究院有限公司 聚乙烯纤维的制备方法及纤维
CN114100187A (zh) * 2021-09-18 2022-03-01 江苏九九久科技有限公司 一种萃取槽
CN115054735A (zh) * 2022-07-05 2022-09-16 首都医科大学附属北京口腔医院 多孔复合支架及其制备方法与应用、epl修饰支架及其制备方法与应用
CN115262015A (zh) * 2022-07-28 2022-11-01 中国水产科学研究院东海水产研究所 一种持久高效抗菌纤维的制备方法

Also Published As

Publication number Publication date
EP2080824B1 (fr) 2010-08-18
DE602007008600D1 (de) 2010-09-30
EP2080824A4 (fr) 2009-12-23
WO2008055405A1 (fr) 2008-05-15
EP2080824A1 (fr) 2009-07-22
ATE478178T1 (de) 2010-09-15

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