US20100233480A1 - Process for producing fiber of ultra high molecular weight polyethylene - Google Patents
Process for producing fiber of ultra high molecular weight polyethylene Download PDFInfo
- Publication number
- US20100233480A1 US20100233480A1 US12/299,205 US29920507A US2010233480A1 US 20100233480 A1 US20100233480 A1 US 20100233480A1 US 29920507 A US29920507 A US 29920507A US 2010233480 A1 US2010233480 A1 US 2010233480A1
- Authority
- US
- United States
- Prior art keywords
- uhmwpe
- fiber
- solvent
- extruder
- emulsion mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D1/00—Treatment of filament-forming or like material
- D01D1/02—Preparation of spinning solutions
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/253—Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/298—Physical dimension
Definitions
- a method of preparing a high strength, high modulus polyethylene (PE) fiber from UHMWPE gel via drawing or stretching technology is disclosed in UK Patent Nos. GB2042414 and GB2051667, assigned to DSM Company, Netherlands in 1979. After that, this technology was industrialized by Allied Company from the U.S., Toyobo-DSM Company, a joint venture by Japan and Netherlands, as well as Mitsui Company from Japan. In 1982, Allied Company obtained U.S. Pat. No. 4,413,110, which covers a process of preparing UHMWPE fiber. Donghua University in China also obtained Chinese Patent Nos. 89107905 and 97106768 in this area.
- the PE powder having a relative MW of 1 million to 6 million is mixed with polar polymer and solvent in an appropriate ratio, and the resulting mixture is fed into an untwisting equipment to untwist, and thereby forming a uniform emulsion mixture.
- the solvent used is liquid under room temperature, and it may be alkane (or paraffin) or its derivative, cycloalkane (or cycloparaffin) or its derivative, aromatic hydrocarbon or its derivative, or mixtures thereof.
- UHMWPE Relative Average Molecule Weight 4.5M powder and #90 solvent white oil with a weight ratio of 1:8, were fed into an untwisting pan at room temperature, and underwent cutting for 10 minutes at a speed of 2000 S ⁇ 1 under N 2 protection, to form a homogeneous emulsion mixture.
- the extruded material was filtered, and spun into a gel filament through a spinnerette, then extracted and stretched at a stretch ratio of 35, to provide UHMWPE.
- UHMWPE Relative Average Molecule Weight 4.5M powder
- the extruded material was filtered, and spun into a gel filament through a spinnerette, then extracted and stretched at a draw ratio of 35, to produce UHMWPE with high adhesive properties.
- UHMWPE (Relative Average Molecule Weight 4.5M) powder and #90 solvent white oil with weight ratio of 1:8 were fed into an untwisting pan at room temperature, and further added polyoxyethylene with an amount of 4% by weight of the UHMWPE powder, and underwent cutting for 10 minutes under N 2 protection at a speed of 2000 S ⁇ 1 , to form a homogeneous emulsion mixture.
- the extruded material was filtered, and spun into a gel filament through a spinnerette, then extracted and stretched at a draw ratio of 35, to produce UHMWPE with high adhesive properties.
- UHMWPE (Relative Average Molecule Weight 4.5M) powder and #90 solvent white oil with a nominal concentration of 10% (wt) were fed into an untwisting pan at room temperature, and underwent cutting for 5 minutes under N 2 protection at a speed of 3000 S ⁇ 1 , to form a homogeneous emulsion mixture.
- UHMWPE (Relative Average Molecule Weight 4.5 M) powder and #70 solvent white oil with a nominal concentration of 10% (wt) were fed into an untwisting pan at room temperature, and further added 1% (wt) of epoxy modified silicone oil, and underwent cutting for 5 minutes under N 2 protection at a speed of 3000 S ⁇ 1 , to form a homogeneous emulsion mixture.
- the extruded material was passed through a filter tank and a metering pump to get a measurement, and spun into a gel filament through a spinnerette, passed through a water bath containing 1.5wt % of epoxy modified silicone oil, followed by extraction, drying and stretching at a draw ratio of 40, to produce UHMWPE fiber with Rupture Strength of 35 cN/dtex and Young's Modulus of over 1050 cN/dtex.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Artificial Filaments (AREA)
- Chemical Treatment Of Fibers During Manufacturing Processes (AREA)
Applications Claiming Priority (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200610118076.X | 2006-11-08 | ||
CN200610118076XA CN101235551B (zh) | 2006-11-08 | 2006-11-08 | 一种高剪切超高分子量聚乙烯连续溶解纺丝新方法 |
CN200610147424.6 | 2006-12-18 | ||
CNA2006101474246A CN101205637A (zh) | 2006-12-18 | 2006-12-18 | 高强高模超高分子量聚乙烯扁平纤维制备方法 |
CN200710040678.2 | 2007-05-15 | ||
CNA2007100406782A CN101307509A (zh) | 2007-05-15 | 2007-05-15 | 一种超高分子量聚乙烯纤维纺丝新方法 |
CN200710043831.7 | 2007-07-16 | ||
CNA2007100438317A CN101348944A (zh) | 2007-07-16 | 2007-07-16 | 高粘接性超高分子量聚乙烯纤维的制造新方法 |
PCT/CN2007/002906 WO2008055405A1 (fr) | 2006-11-08 | 2007-10-09 | Procédé de production de fibre de polyéthylène de masse moléculaire très élevée |
Publications (1)
Publication Number | Publication Date |
---|---|
US20100233480A1 true US20100233480A1 (en) | 2010-09-16 |
Family
ID=39364173
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/299,205 Abandoned US20100233480A1 (en) | 2006-11-08 | 2007-10-09 | Process for producing fiber of ultra high molecular weight polyethylene |
Country Status (5)
Country | Link |
---|---|
US (1) | US20100233480A1 (fr) |
EP (1) | EP2080824B1 (fr) |
AT (1) | ATE478178T1 (fr) |
DE (1) | DE602007008600D1 (fr) |
WO (1) | WO2008055405A1 (fr) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20110276280A1 (en) * | 2010-05-07 | 2011-11-10 | Testing Machines, Inc. | Yarn entanglement strength tester |
US20120306109A1 (en) * | 2009-11-26 | 2012-12-06 | Ningbo Dacheng Advanced Material Co., Ltd. | Method For Evenly Preparing Filament By Using High-Shearing Solution of Ultrahigh-Molecular-Weight Polyethylene |
CN103590130A (zh) * | 2013-10-11 | 2014-02-19 | 杭州翔盛高强纤维材料股份有限公司 | 一种改善超高分子量聚乙烯纤维纺丝液流动性的方法 |
US20150164158A1 (en) * | 2013-12-13 | 2015-06-18 | Honeywell International Inc. | Protective overglove for glove-box gloves |
CN104846446A (zh) * | 2015-05-22 | 2015-08-19 | 江苏神鹤科技发展有限公司 | 交联的超高分子量聚乙烯纤维及其干式制备方法 |
US9296875B2 (en) | 2010-08-24 | 2016-03-29 | Beijing Tongyizhong Specialty Fibre Technology & Development Co., Ltd | Method for preparing spinning solution of ultra-high molecular weight polyethylene fiber |
WO2016089969A3 (fr) * | 2014-12-02 | 2016-08-25 | Braskem America, Inc. | Procédé et système continus pour la production d'au moins un fil polymère et fil polymère |
CN112725918A (zh) * | 2020-12-23 | 2021-04-30 | 中国纺织科学研究院有限公司 | 聚乙烯纤维的制备方法及纤维 |
CN112778598A (zh) * | 2019-11-08 | 2021-05-11 | 中国石油化工股份有限公司 | 一种聚烯烃组合物及其制备方法和应用 |
US11230797B2 (en) | 2011-12-14 | 2022-01-25 | Dsm Ip Assets B.V. | Ultra high molecular weight polyethylene multifilament yarn |
CN114100187A (zh) * | 2021-09-18 | 2022-03-01 | 江苏九九久科技有限公司 | 一种萃取槽 |
CN115054735A (zh) * | 2022-07-05 | 2022-09-16 | 首都医科大学附属北京口腔医院 | 多孔复合支架及其制备方法与应用、epl修饰支架及其制备方法与应用 |
CN115262015A (zh) * | 2022-07-28 | 2022-11-01 | 中国水产科学研究院东海水产研究所 | 一种持久高效抗菌纤维的制备方法 |
US11866849B2 (en) * | 2013-10-29 | 2024-01-09 | Braskem America, Inc. | System and method of dosing a polymer mixture with a first solvent, device, system and method of extracting solvent from at least one polymeric yarn, system and method of mechanical pre-recovery of at least one liquid in at least one polymeric yarn, and continuous system and method for producing at least one polymeric yarn |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9365953B2 (en) | 2007-06-08 | 2016-06-14 | Honeywell International Inc. | Ultra-high strength UHMWPE fibers and products |
US8747715B2 (en) | 2007-06-08 | 2014-06-10 | Honeywell International Inc | Ultra-high strength UHMW PE fibers and products |
CN102534838B (zh) * | 2010-12-07 | 2014-09-03 | 北京同益中特种纤维技术开发有限公司 | 一种超高分子量聚乙烯纤维纺丝原液及其制备方法 |
CN102580159A (zh) * | 2012-03-13 | 2012-07-18 | 中国矿业大学 | 一种自增强超高分子量聚乙烯髋关节臼的制备工艺 |
CN104790050B (zh) * | 2014-03-28 | 2019-05-21 | 上海斯瑞科技有限公司 | 一种超高分子量聚乙烯纤维的制备方法及水洗装置 |
CN109666976B (zh) * | 2017-10-16 | 2021-04-06 | 中国石油化工股份有限公司 | 提高超高分子量聚乙烯纤维产品性能的方法 |
CN109306061A (zh) * | 2018-06-06 | 2019-02-05 | 深圳大学 | 超高分子量聚乙烯纺丝溶液的制备方法和超高分子量聚乙烯纤维 |
CN109161978B (zh) * | 2018-09-03 | 2021-06-11 | 中国科学院宁波材料技术与工程研究所 | 一种高粘结、高强超高分子量聚乙烯纤维的制备方法及其产品 |
CN112111802B (zh) * | 2019-06-20 | 2022-06-10 | 李乾坤 | 一种超高强度超高分子量聚乙烯纤维及其制造方法 |
CN112281237B (zh) * | 2020-11-03 | 2022-09-27 | 北京复维新材科技有限公司 | 一种高模量抗蠕变超高分子量聚乙烯纤维及其制备方法 |
CN113668086B (zh) * | 2021-08-24 | 2022-08-16 | 盐城工学院 | 高界面粘附性超高分子量聚乙烯纤维及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4413110A (en) * | 1981-04-30 | 1983-11-01 | Allied Corporation | High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore |
US5741848A (en) * | 1995-03-08 | 1998-04-21 | Tonen Chemical Corporation | Method of manufacturing polyolefin solutions |
US6054086A (en) * | 1995-03-24 | 2000-04-25 | Nippon Petrochemicals Co., Ltd. | Process of making high-strength yarns |
Family Cites Families (23)
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US480136A (en) | 1892-08-02 | Shutter-bower | ||
US4020230A (en) | 1975-10-03 | 1977-04-26 | The Dow Chemical Company | Microporous polyethylene hollow fibers and process of preparing them |
NL177759B (nl) | 1979-06-27 | 1985-06-17 | Stamicarbon | Werkwijze ter vervaardiging van een polyetheendraad, en de aldus verkregen polyetheendraad. |
NL177840C (nl) | 1979-02-08 | 1989-10-16 | Stamicarbon | Werkwijze voor het vervaardigen van een polyetheendraad. |
JPH0246053B2 (ja) | 1983-06-16 | 1990-10-12 | Kogyo Gijutsu Incho | Chokobunshiryohoriechirenyoekinoseizohoho |
JPS61124621A (ja) * | 1984-11-19 | 1986-06-12 | Ntn Toyo Bearing Co Ltd | 超高分子量ポリエチレン繊維の製造方法 |
WO1986004936A1 (fr) | 1985-02-15 | 1986-08-28 | Toray Industries, Inc. | Fil multifilament en polyethylene |
CN1004364B (zh) | 1985-02-15 | 1989-05-31 | 斯塔米卡本公司(Dsm附属公司) | 连续制备均匀的高分子聚合物溶液的方法 |
DE3675079D1 (de) | 1985-06-17 | 1990-11-29 | Allied Signal Inc | Polyolefinfaser mit hoher festigkeit, niedrigem schrumpfen, ultrahohem modul, sehr niedrigem kriechen und mit guter festigkeitserhaltung bei hoher temperatur sowie verfahren zu deren herstellung. |
JPS6315838A (ja) | 1986-07-08 | 1988-01-22 | Nippon Petrochem Co Ltd | 超高分子量ポリエチレン溶液 |
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CN1056544A (zh) * | 1990-05-14 | 1991-11-27 | 中国纺织大学 | 高强、高模聚乙烯纤维的制备方法 |
DE69117175T2 (de) | 1990-11-28 | 1996-10-24 | Mitsubishi Rayon Co | Poröse hohlfasermembran aus polyethylen und ihre herstellung |
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CN1060543C (zh) * | 1997-01-02 | 2001-01-10 | 中国纺织科学研究院 | 超高分子量聚乙烯纤维连续制备方法和设备 |
KR100302209B1 (ko) | 1999-04-27 | 2001-09-22 | 주덕영 | 순환연신법에 의한 고밀도 폴리에틸렌 중공사 분리막의 제조방법 및 그 장치 |
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CN100410431C (zh) * | 2002-12-10 | 2008-08-13 | 帝斯曼知识产权资产管理有限公司 | 制造和转化聚烯烃纤维的方法 |
JP4578483B2 (ja) * | 2004-01-01 | 2010-11-10 | ディーエスエム アイピー アセッツ ビー.ブイ. | 高性能ポリエチレンマルチフィラメント糸の製造方法 |
CN100395386C (zh) | 2005-05-10 | 2008-06-18 | 东华大学 | 一种提高超高相对分子量聚乙烯纤维表面粘结性能的方法 |
EP1746187A1 (fr) | 2005-07-18 | 2007-01-24 | DSM IP Assets B.V. | Fil multifilament en polyéthylène |
-
2007
- 2007-10-09 WO PCT/CN2007/002906 patent/WO2008055405A1/fr active Application Filing
- 2007-10-09 EP EP07816520A patent/EP2080824B1/fr not_active Not-in-force
- 2007-10-09 AT AT07816520T patent/ATE478178T1/de not_active IP Right Cessation
- 2007-10-09 DE DE602007008600T patent/DE602007008600D1/de active Active
- 2007-10-09 US US12/299,205 patent/US20100233480A1/en not_active Abandoned
Patent Citations (3)
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US4413110A (en) * | 1981-04-30 | 1983-11-01 | Allied Corporation | High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore |
US5741848A (en) * | 1995-03-08 | 1998-04-21 | Tonen Chemical Corporation | Method of manufacturing polyolefin solutions |
US6054086A (en) * | 1995-03-24 | 2000-04-25 | Nippon Petrochemicals Co., Ltd. | Process of making high-strength yarns |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120306109A1 (en) * | 2009-11-26 | 2012-12-06 | Ningbo Dacheng Advanced Material Co., Ltd. | Method For Evenly Preparing Filament By Using High-Shearing Solution of Ultrahigh-Molecular-Weight Polyethylene |
US9581531B2 (en) * | 2010-05-07 | 2017-02-28 | Lawson Hemphill, Inc. | Yarn entanglement strength tester |
US8131483B2 (en) * | 2010-05-07 | 2012-03-06 | Testing Machines, Inc. | Yarn entanglement strength tester |
US20120125119A1 (en) * | 2010-05-07 | 2012-05-24 | Testing Machines, Inc. | Yarn entanglement strength tester |
US20110276280A1 (en) * | 2010-05-07 | 2011-11-10 | Testing Machines, Inc. | Yarn entanglement strength tester |
US9296875B2 (en) | 2010-08-24 | 2016-03-29 | Beijing Tongyizhong Specialty Fibre Technology & Development Co., Ltd | Method for preparing spinning solution of ultra-high molecular weight polyethylene fiber |
US11746442B2 (en) | 2011-12-14 | 2023-09-05 | Avient Protective Materials B.V. | Ultra high molecular weight polyethylene multifilament yarn |
US11230797B2 (en) | 2011-12-14 | 2022-01-25 | Dsm Ip Assets B.V. | Ultra high molecular weight polyethylene multifilament yarn |
CN103590130A (zh) * | 2013-10-11 | 2014-02-19 | 杭州翔盛高强纤维材料股份有限公司 | 一种改善超高分子量聚乙烯纤维纺丝液流动性的方法 |
US12031234B2 (en) * | 2013-10-29 | 2024-07-09 | Braskem America, Inc. | System and method of dosing a polymer mixture with a first solvent, device, system and method of extracting solvent from at least one polymeric yarn, system and method of mechanical pre-recovery of at least one liquid in at least one polymeric yarn, and continuous system and method for producing at least one polymeric yarn |
US20240026571A1 (en) * | 2013-10-29 | 2024-01-25 | Braskem America, Inc. | System and method of dosing a polymer mixture with a first solvent, device, system and method of extracting solvent from at least one polymeric yarn, system and method of mechanical pre-recovery of at least one liquid in at least one polymeric yarn, and continuous system and method for producing at least one polymeric yarn |
US11866849B2 (en) * | 2013-10-29 | 2024-01-09 | Braskem America, Inc. | System and method of dosing a polymer mixture with a first solvent, device, system and method of extracting solvent from at least one polymeric yarn, system and method of mechanical pre-recovery of at least one liquid in at least one polymeric yarn, and continuous system and method for producing at least one polymeric yarn |
US20150164158A1 (en) * | 2013-12-13 | 2015-06-18 | Honeywell International Inc. | Protective overglove for glove-box gloves |
WO2016089969A3 (fr) * | 2014-12-02 | 2016-08-25 | Braskem America, Inc. | Procédé et système continus pour la production d'au moins un fil polymère et fil polymère |
CN104846446A (zh) * | 2015-05-22 | 2015-08-19 | 江苏神鹤科技发展有限公司 | 交联的超高分子量聚乙烯纤维及其干式制备方法 |
CN112778598A (zh) * | 2019-11-08 | 2021-05-11 | 中国石油化工股份有限公司 | 一种聚烯烃组合物及其制备方法和应用 |
CN112725918A (zh) * | 2020-12-23 | 2021-04-30 | 中国纺织科学研究院有限公司 | 聚乙烯纤维的制备方法及纤维 |
CN114100187A (zh) * | 2021-09-18 | 2022-03-01 | 江苏九九久科技有限公司 | 一种萃取槽 |
CN115054735A (zh) * | 2022-07-05 | 2022-09-16 | 首都医科大学附属北京口腔医院 | 多孔复合支架及其制备方法与应用、epl修饰支架及其制备方法与应用 |
CN115262015A (zh) * | 2022-07-28 | 2022-11-01 | 中国水产科学研究院东海水产研究所 | 一种持久高效抗菌纤维的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
EP2080824B1 (fr) | 2010-08-18 |
DE602007008600D1 (de) | 2010-09-30 |
EP2080824A4 (fr) | 2009-12-23 |
WO2008055405A1 (fr) | 2008-05-15 |
EP2080824A1 (fr) | 2009-07-22 |
ATE478178T1 (de) | 2010-09-15 |
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