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US20040040631A1 - Piston ring excellent in resistance to scuffing, cracking and fatigue and method for producing the same, and combination of piston ring and cylinder block - Google Patents

Piston ring excellent in resistance to scuffing, cracking and fatigue and method for producing the same, and combination of piston ring and cylinder block Download PDF

Info

Publication number
US20040040631A1
US20040040631A1 US10/333,326 US33332603A US2004040631A1 US 20040040631 A1 US20040040631 A1 US 20040040631A1 US 33332603 A US33332603 A US 33332603A US 2004040631 A1 US2004040631 A1 US 2004040631A1
Authority
US
United States
Prior art keywords
piston ring
nitriding
less
resistance
stainless steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/333,326
Other languages
English (en)
Inventor
Junya Takahashi
Toru Onuki
Shigeo Inoue
Mitsutaka Sasakura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Riken Corp
Tokusen Kogyo Co Ltd
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Assigned to KABUSHIKI KAISHA RIKEN, TOKUSEN KOGYO COMPANY LIMITED reassignment KABUSHIKI KAISHA RIKEN ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SASAKURA, MITSUTAKA, INOUE, SHIGEO, ONUKI, TORU, TAKAHASHI, JUNYA
Publication of US20040040631A1 publication Critical patent/US20040040631A1/en
Priority to US11/657,015 priority Critical patent/US20070187002A1/en
Abandoned legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
    • C21D8/065Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires of ferrous alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/40Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for rings; for bearing races
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/24Ferrous alloys, e.g. steel alloys containing chromium with vanadium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/26Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/24Nitriding
    • C23C8/26Nitriding of ferrous surfaces
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/008Martensite

Definitions

  • the present invention relates to a piston ring used in an internal combustion engine, particularly, a piston ring consisting of high chromium martensitic stainless steel with nitriding, having improved scuffing resistance (seizure resistance), cracking resistance (failure resistance) and fatigue resistance.
  • the present invention is also related to a production method of the piston ring.
  • High chromium martensitic stainless steel mainly used at present for the piston ring with nitriding is JIS SUS440B equivalent composition of C: 0.80 -0.95%, Cr: 17.0-18.0%; Si: 0.25-0.50%; Mn: 0.25-0.40%; Mo: 0.70-1.25%; V: 0.07-0.15%; and Fe in balance.
  • the nitrides in the nitriding layer are mainly compounds of Cr, V and Mo, which may contain the solute Fe. Chromium which is the main component of this steel, is dissolved in the iron matrix, and is also present in the form of Cr carbides.
  • Cr is a substitutional solute element in Fe. Cr not only improves the corrosion resistance but also induces the solution strengthening and hence improvement in the thermal setting resistance.
  • the thermal setting is a phenomenon that sealing property is deteriorated by tension decrease due to creep during operation of a piston ring at high temperature.
  • Cr reacts with C in steel and forms Cr carbides. These Cr carbides easily react with N, which intrudes from the surface during nitriding, and are converted to Cr nitrides.
  • the Cr nitrides are dispersed in the nitriding layer as the hard particles. The hard particles in the nitriding layer exceedingly enhance the wear resistance and the scuffing resistance of the sliding surface of a piston ring.
  • the super saturated C and N precipitate around the primary ⁇ grains in the form of lamellar M 23 C 6 and M 2 N precipitates.
  • the N content is less than 0.05%, the ⁇ phase crystallizes.
  • the N content is more than 0.50%, the amount of M 2 N precipitates in the form of a rod increases, so that the toughness is lowered.
  • the N content is, therefore. in a range of from 0.05 to 0.50%, more preferably in a range of from 0.10 to 0.30%.
  • the solute N in the matrix impedes the diffusion of C and also contributes to refining of the grain boundary compounds.
  • FIG. 3 a scuffing test sample in the form of Japanese katakana “]” having 45 mm of the total length is shown.
  • the wire material was shaped into scuffing test samples of two-pin integral type.
  • the opposite material was made of FC250 and was in the form of a disc of 60 mm in diameter and 12 mm in thickness.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Pistons, Piston Rings, And Cylinders (AREA)
  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)
US10/333,326 2000-07-17 2001-07-16 Piston ring excellent in resistance to scuffing, cracking and fatigue and method for producing the same, and combination of piston ring and cylinder block Abandoned US20040040631A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US11/657,015 US20070187002A1 (en) 2000-07-17 2007-01-24 Piston ring having improved scuffing, cracking and fatigue resistances, and its production method, as well as combination of piston ring and cylinder block

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2000-216255 2000-07-17
JP2000216255A JP4724275B2 (ja) 2000-07-17 2000-07-17 耐スカッフィング性、耐クラッキング性及び耐疲労性に優れたピストンリング及びその製造方法
PCT/JP2001/006127 WO2002006546A1 (fr) 2000-07-17 2001-07-16 Segment de piston presentant une resistance elevee a l'erosion, a la fissuration et a la fatigue, procede permettant de produire ce segment et combinaison segment de piston et bloc-cylindres

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US11/657,015 Continuation US20070187002A1 (en) 2000-07-17 2007-01-24 Piston ring having improved scuffing, cracking and fatigue resistances, and its production method, as well as combination of piston ring and cylinder block

Publications (1)

Publication Number Publication Date
US20040040631A1 true US20040040631A1 (en) 2004-03-04

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Family Applications (2)

Application Number Title Priority Date Filing Date
US10/333,326 Abandoned US20040040631A1 (en) 2000-07-17 2001-07-16 Piston ring excellent in resistance to scuffing, cracking and fatigue and method for producing the same, and combination of piston ring and cylinder block
US11/657,015 Abandoned US20070187002A1 (en) 2000-07-17 2007-01-24 Piston ring having improved scuffing, cracking and fatigue resistances, and its production method, as well as combination of piston ring and cylinder block

Family Applications After (1)

Application Number Title Priority Date Filing Date
US11/657,015 Abandoned US20070187002A1 (en) 2000-07-17 2007-01-24 Piston ring having improved scuffing, cracking and fatigue resistances, and its production method, as well as combination of piston ring and cylinder block

Country Status (10)

Country Link
US (2) US20040040631A1 (de)
EP (1) EP1304393B1 (de)
JP (1) JP4724275B2 (de)
KR (1) KR100507424B1 (de)
CN (1) CN1210427C (de)
AR (1) AR029730A1 (de)
BR (1) BR0112573B1 (de)
DE (1) DE60122164T2 (de)
TW (1) TW521093B (de)
WO (1) WO2002006546A1 (de)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060191508A1 (en) * 2003-03-31 2006-08-31 Koki Otsuka Internal engine piston and its production method
US20080053396A1 (en) * 2006-08-31 2008-03-06 Nippon Piston Ring Co., Ltd. Combination of a cylinder liner and a piston ring
US20100054649A1 (en) * 2008-09-01 2010-03-04 Hiroshi Yamada Martensitic stainless steel and antifriction bearing using the same
US20130049304A1 (en) * 2009-12-29 2013-02-28 Mahle International Gmbh Nitrided piston ring resistant to the propagation of cracks
US9091345B2 (en) 2011-11-30 2015-07-28 Federal-Mogul Corporation High modulus wear resistant gray cast iron for piston ring applications
US20160305014A1 (en) * 2013-12-06 2016-10-20 Mahle Metal Leve S/A Process for coating a cylinder of an internal combustion engine and engine cylinder/liner
US9731345B2 (en) 2010-12-27 2017-08-15 Posco Martensitic stainless steel highly resistant to corrosion, and method for manufacturing same
CN107109614A (zh) * 2014-10-20 2017-08-29 马勒金属立夫有限公司 活塞圈和内燃机
US9816163B2 (en) 2012-04-02 2017-11-14 Ak Steel Properties, Inc. Cost-effective ferritic stainless steel
US10196718B2 (en) * 2015-06-11 2019-02-05 Hitachi Metals, Ltd. Steel strip for cutlery
CN113265592A (zh) * 2020-02-17 2021-08-17 现代自动车株式会社 可变油泵的外环及其制造方法
WO2021165462A1 (de) * 2020-02-21 2021-08-26 Federal-Mogul Burscheid Gmbh Gleitelement, insbesondere kolbenring, und verfahren zur herstellung desselben
CN115109891A (zh) * 2022-07-14 2022-09-27 中北大学 一种高碳高铬含氮马氏体不锈钢及其碳化物细化方法

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TWI258547B (en) * 2002-08-27 2006-07-21 Riken Co Ltd Side rails for combined oil control ring and their nitriding method
SE526805C8 (sv) * 2004-03-26 2006-09-12 Sandvik Intellectual Property Stållegering
CN100363524C (zh) * 2005-03-17 2008-01-23 上海材料研究所 一种耐腐蚀磨损的马氏体不锈钢及其制造方法及用途
JP4648094B2 (ja) * 2005-05-31 2011-03-09 株式会社神戸製鋼所 耐疲労割れ性に優れた高Cr鋳鉄およびその製造方法
JP4844902B2 (ja) 2006-04-20 2011-12-28 日立金属株式会社 内燃機関用ピストンリング材
DE102006038669A1 (de) * 2006-08-17 2008-02-28 Federal-Mogul Burscheid Gmbh Stahlwerkstoff, insbesondere zur Herstellung von Kolbenringen
DE102008032884B4 (de) * 2008-07-14 2018-09-20 Mahle International Gmbh Ventileinrichtung, Wärmetauscher und Aufladesystem zur Aufladung einer Brennkraftmaschine mit einem Ladefluid
JP5676146B2 (ja) * 2010-05-25 2015-02-25 株式会社リケン 圧力リング及びその製造方法
US10053763B2 (en) 2011-06-02 2018-08-21 Aktiebolaget Skf Carbo-nitriding process for martensitic stainless steel and stainless steel article having improved corrosion resistance
KR101268736B1 (ko) 2011-06-24 2013-05-29 주식회사 포스코 마르텐사이트계 스테인리스강 및 이의 제조 방법
CN103866202B (zh) * 2012-12-14 2016-08-17 钟庆辉 采用改性不锈钢材料制作发动机活塞环气环方法
KR102005580B1 (ko) * 2012-12-17 2019-07-30 두산인프라코어 주식회사 플랜지 타입의 슬라이딩 베어링, 이를 구비하는 슬라이딩 베어링 조립체 및 건설기계용 관절 조립체
DE102013010807A1 (de) * 2013-06-27 2014-12-31 Liebherr-Aerospace Lindenberg Gmbh Bauteil eines Luftfahrzeuges
JP6010508B2 (ja) * 2013-07-03 2016-10-19 ボーグワーナー インコーポレーテッド 摺動部材の製造方法、ならびにチェーン用リンクの製造方法および当該リンクを備えたチェーンの製造方法
US9745736B2 (en) * 2013-08-27 2017-08-29 University Of Virginia Patent Foundation Three-dimensional space frames assembled from component pieces and methods for making the same
JP5890946B2 (ja) * 2014-01-31 2016-03-22 Tpr株式会社 圧力リングおよび圧力リング用母材
WO2015124169A1 (de) * 2014-02-18 2015-08-27 Schmiedewerke Gröditz Gmbh CHROMSTAHL FÜR STARK VERSCHLEIßBEANSPRUCHTE MASCHINENTEILE, INSBESONDERE PELLETIERMATRIZEN
JP5859048B2 (ja) * 2014-03-20 2016-02-10 サンコール株式会社 ピストンリング及びピストンリング用金属製平角線
CN104018083B (zh) * 2014-06-20 2016-01-06 重庆材料研究院有限公司 含氮不锈轴承钢及制备方法
JP6139605B2 (ja) * 2015-07-17 2017-05-31 株式会社リケン ピストンリング及びその製造方法
WO2017021330A1 (en) * 2015-08-03 2017-02-09 Mahle International Gmbh Piston rings of nitridable cast steels and process of production
BR102015027438B8 (pt) 2015-10-29 2021-12-21 Inst De Pesquisas Tecnologicas Do Estado De Sao Paulo S/A Anéis de pistão em aços-ferramenta fundidos e seu processo de fabricação
CN106053053B (zh) * 2016-08-10 2018-08-03 三峡大学 一种活塞环疲劳试验机及疲劳试验方法
CN106119729A (zh) * 2016-08-18 2016-11-16 娄土岭 一种精密铸造轴承钢
CN106619032A (zh) * 2016-11-25 2017-05-10 天津文康科技有限公司 一种机电一体化医疗护理装置
CN106555129A (zh) * 2016-12-02 2017-04-05 机械科学研究总院青岛分院 一种含氮不锈轴承钢及制备方法
CN107326272A (zh) * 2017-05-27 2017-11-07 苏州铭晟通物资有限公司 一种钢材
JP7404792B2 (ja) 2018-12-04 2023-12-26 株式会社プロテリアル マルテンサイト系ステンレス鋼部品およびその製造方法
CN114962460A (zh) 2021-02-25 2022-08-30 斯凯孚公司 经热处理的滚子轴承圈
CN113528941A (zh) * 2021-06-16 2021-10-22 中国兵器科学研究院宁波分院 一种含氮马氏体不锈轴承钢及其制备方法
CN114196875B (zh) * 2021-09-25 2022-10-28 浙江吉森金属科技有限公司 一种阀片用不锈钢及其热处理方法

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Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7503304B2 (en) * 2003-03-31 2009-03-17 Hitachi Metals, Ltd. Internal engine piston and its production method
US20060191508A1 (en) * 2003-03-31 2006-08-31 Koki Otsuka Internal engine piston and its production method
US20080053396A1 (en) * 2006-08-31 2008-03-06 Nippon Piston Ring Co., Ltd. Combination of a cylinder liner and a piston ring
US7493882B2 (en) * 2006-08-31 2009-02-24 Nippon Piston Ring Co., Ltd. Combination of a cylinder liner and a piston ring
US20100054649A1 (en) * 2008-09-01 2010-03-04 Hiroshi Yamada Martensitic stainless steel and antifriction bearing using the same
US8591673B2 (en) 2008-09-01 2013-11-26 Minebea Co., Ltd. Martensitic stainless steel and antifriction bearing using the same
US20130049304A1 (en) * 2009-12-29 2013-02-28 Mahle International Gmbh Nitrided piston ring resistant to the propagation of cracks
US8561998B2 (en) * 2009-12-29 2013-10-22 Mahle International Gmbh Nitrided piston ring resistant to the propagation of cracks
US9731345B2 (en) 2010-12-27 2017-08-15 Posco Martensitic stainless steel highly resistant to corrosion, and method for manufacturing same
US9091345B2 (en) 2011-11-30 2015-07-28 Federal-Mogul Corporation High modulus wear resistant gray cast iron for piston ring applications
US9816163B2 (en) 2012-04-02 2017-11-14 Ak Steel Properties, Inc. Cost-effective ferritic stainless steel
US20160305014A1 (en) * 2013-12-06 2016-10-20 Mahle Metal Leve S/A Process for coating a cylinder of an internal combustion engine and engine cylinder/liner
CN107109614A (zh) * 2014-10-20 2017-08-29 马勒金属立夫有限公司 活塞圈和内燃机
US10487405B2 (en) 2014-10-20 2019-11-26 Mahle Metal Leve S/A Piston ring and internal combustion engine
US10196718B2 (en) * 2015-06-11 2019-02-05 Hitachi Metals, Ltd. Steel strip for cutlery
CN113265592A (zh) * 2020-02-17 2021-08-17 现代自动车株式会社 可变油泵的外环及其制造方法
US20210252595A1 (en) * 2020-02-17 2021-08-19 Hyundai Motor Company Outer ring for variable oil pump and manufacturing method thereof
WO2021165462A1 (de) * 2020-02-21 2021-08-26 Federal-Mogul Burscheid Gmbh Gleitelement, insbesondere kolbenring, und verfahren zur herstellung desselben
CN115109891A (zh) * 2022-07-14 2022-09-27 中北大学 一种高碳高铬含氮马氏体不锈钢及其碳化物细化方法

Also Published As

Publication number Publication date
CN1458983A (zh) 2003-11-26
TW521093B (en) 2003-02-21
CN1210427C (zh) 2005-07-13
AR029730A1 (es) 2003-07-10
JP2002030394A (ja) 2002-01-31
JP4724275B2 (ja) 2011-07-13
EP1304393B1 (de) 2006-08-09
BR0112573B1 (pt) 2009-01-13
KR100507424B1 (ko) 2005-08-10
WO2002006546A1 (fr) 2002-01-24
EP1304393A4 (de) 2005-08-03
DE60122164D1 (de) 2006-09-21
KR20030025275A (ko) 2003-03-28
BR0112573A (pt) 2003-07-01
US20070187002A1 (en) 2007-08-16
EP1304393A1 (de) 2003-04-23
DE60122164T2 (de) 2007-10-11

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