TW201039856A - Two-pack type hair dye product - Google Patents

Abstract

Disclosed is a two-pack type hair dye product which is composed of a first preparation containing an alkali agent, a second preparation containing hydrogen peroxide, and a non-aerosol roamer container for discharging the liquid mixture of the first preparation and the second preparation in the form of a foam. The two-pack type hair dye product is characterized in that the liquid mixture contains the following components (A) and (B), and has a viscosity at 25 DEG C of 1-300 mPa.s. (A) 0.02-10% by mass of a mono-long chain aliphatic trimethyl ammonium salt (B) 0.5-10% by mass of an anionic surfactant Also disclosed is a twopack type hair dye product which is composed of a first preparation containing an alkali agent, a second preparation containing hydrogen peroxide, and a non-aerosol roamer container for discharging the liquid mixture of the first preparation and the second preparation in the form of a foam. The two-pack type hair dye product is characterized in that a foam of the liquid mixture right after being discharged from the non-aerosol roamer container has a specific kinematic viscoelasticity, namely a complex elastic modulus G* within the range of 50-600 as determined using a rheometer.

Description

201039856 VI. INSTRUCTIONS OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to a two-part hair dye. [Prior Art] Previously, as a hair bleaching agent, a hair dyeing agent, a liquid or a paste was more common, but evenly applying it to the hair was difficult for a raw hand. The reason is that 'to prevent dripping during placement, the viscosity of the mixture applied to the hair is adjusted to a height of about 1000 to 10000 mPa·s, and it is difficult to uniformly spread the agent, and it is difficult to fully spread the agent to The root of the hair. Further, when applied to the root or the back of the hair, it is necessary to be skilled in techniques such as blocking and contrast mirrors, and it takes a lot of time. On the other hand, it has been proposed to spray a two-part hair bleaching agent or a two-part hair dye in a bubble form from a non-aerosol type foam container (Patent Document 1). The hair bleaching agent or the hair dyeing agent is a mixture of the second agent and the second agent which is sprayed in a bubble form from a non-aerosol type foaming container, whereby the hair can be uniformly applied to the hair' and not completed. It produces color unevenness, especially for eliminating the color difference between the new part and the dyed part, regardless of gender, age, and support from a wide range of customers. However, the hair decoloring agent or the hair dye of the type described above is a "one-use type" in which the first agent and the second agent are all mixed at once in the nature of the product. At the same time, Gu Yiyi used all the mixed liquids by spraying the total amount of the products. The ratio of this If Φ w liquid phase to the amount of hair (bath ratio) has become 146962.doc 201039856 There is a residual condition of the local visible drip during the placement process after application. Therefore, a hair decoloring agent and a hair dye which are excellent in dyeability even when the foam applied by such a high bath ratio is not dripped, and which is sufficiently spread to the root portion. [PRIOR ART DOCUMENT] [Patent Document 1] [Patent Document 1] Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. The present invention comprises: a second agent containing an alkali agent, a second agent containing hydrogen peroxide, and a non-aerosol foaming container in which a mixture of the first agent and the second agent is sprayed in a bubble form; and in the mixed solution Contains the following components (A) and (B): (A) Single long chain aliphatic trimethyl sulfonate | Ansin: 〇〇2~1 〇% by mass, (B) Anionic surfactant: 〇·5~1〇 % by mass; and the viscosity of the mixture at 25t is 1 to 300 mPa.s. Further, in the present invention, the "second invention" provides a two-part type dyeing agent comprising: a first agent containing an alkali agent, a second agent containing hydrogen peroxide, and a first agent and a first agent a non-aerosol foaming container in which a mixture of two agents is sprayed in a bubble form; and a dynamic viscoelasticity of a bubble which is obtained by bubbling out the mixed liquid from a non-aerosol foaming container, in use flow When the gauge is measured under the following conditions, the complex elastic modulus G* is in the range of 50 to 600. Rheometer setting: The geometry is a 50 mm stainless steel parallel plate. 146962.doc 201039856 The temperature of the measuring section was maintained at 30 °C. Determination order: 1. The spoon is taken from the 4.5~5.5^ bubble to the base of the rheometer. 2. Adjust the gap to 2 mm and carefully remove the bubbles that overflow from the base. Ο 3. After the bubble was allowed to acclimate to the temperature of the measurement unit for 30 seconds, the dynamic deformation scan evaluation was started under the following conditions. Frequency: fixed at 2 edges, deformation: 1 ><1〇.3~1><1〇3% 4. According to the obtained data, (4) the value of the linear region as the G* with respect to the deformation. Furthermore, the present invention provides a hair dyeing method in which a mixture of the two-component hair dyes of the "the first month" or the second invention is sprayed from a non-aerosol foaming container in a bubble shape, and After applying the foamy mixture to the hair, it was foamed again on the hair. [Embodiment] The present invention is a two-part type hair dye of a non-aerosol type, which is applied to a placing process even in a state in which a higher bath ratio is applied to a short hair. There is no dripping in the middle, and the dyeability or decolorization is also good. The present inventors have found that by making a non-aerosol two-part blister hair dye = containing a specific amount of a single long chain aliphatic trimethylammonium salt and an anionic surfactant, respectively, m by mixing The liquid bubble has a specific viscoelasticity and can solve the above problems. I46962.doc 201039856 In the present invention, the "two-part hair dye" is a concept including both a dye-containing dyeing agent and a dye-free decolorizing agent. Further, when it is simply referred to as "the two-component hair dye of the present invention", it means a two-part type of hair dye of the above "first invention" and "second invention". Hereinafter, the "first invention" will be described. [(A): Single long-chain aliphatic trimethylammonium salt] The component used in the "first invention" (A) The long-chain aliphatic group in the monolong-chain aliphatic trimethylammonium salt may be straight Any of a chain and a branch,

'J is any of a singular group and an alkenyl group. 'The carbon number is preferably 丨6 to 22, more preferably 16 to 20, particularly preferably 16 to 18'. More preferably, it is an alkyl group, and, better. It is a straight chain. Specifically, as the long-chain aliphatic group, a cetyl group or a stearyl group is preferred. Further, examples of the counter ion of the ammonium ion of the component (A) include a halide ion (such as a chloride ion or a bromide ion) and an organic anion (a sulfhydryl sulfate ion, an ethyl sulfate ion, or a saccharin ion). Among them, preferred are vapor ions and bromide ions. In the "first invention", the content of the forming tool (A) in the mixed liquid of the second agent and the second agent is increased by the use of the anionic surfactant in combination with the component (B). The bath also improves the stability of the foam on the hair when used. From the viewpoint of suppressing the effect of dripping, it is preferably set to 〇〇2 to (7)% by mass, more preferably 0.05 to 5% by mass, especially preferably. It is 〇 1 to 2% by mass. [(B). Anionic surfactant] The component (8) used as an anionic surfactant in the "first invention" may, for example, be a sulfate-sulfate-based anionic surfactant such as a burnt-based sulfate or a burnt-based sulfate; _Mercapto-amino acid salt, N-fluorenyl-based amine 146962.doc 201039856 base acid salt, guanamine type N-decylamine acid salt, ether carboxylate, fatty acid salt, alkyl succinate or a carboxylic acid-based anionic surfactant such as a salt of an alkenyl succinate; a sulfosuccinate type, an isethionate type, a taurate type, a decylbenzenesulfonate type, an α-olefin sulfonate A sulfonic acid-based anionic surfactant such as a type or an alkanesulfonic acid type; an acid vinegar-based anionic surfactant such as a sulfonate or a burnt ether. Among these, 'the preferred one is a carboxylic acid type 'sulfate type, and particularly preferably a carboxylic acid type. Among the carboxylic acid anionic surfactants, preferred are an anthracene-mercaptoamino acid salt, a fluorenyl-fluorenyl-fluorene-alkylamino acid salt, and an ether carboxylic acid salt. Examples of the amino acid residue of the fluorenyl-mercaptoamine acid salt include glutamic acid, aspartic acid, and the like, and the amino acid residue of the fluorenyl-fluorenyl-hydrazine-alkylamino acid salt can be used. Listed are proline, glycine, β-alanine and the like. The sulfhydryl group of the hydrazine-mercapto-amino acid salt, the hydrazine-bristyl-hydrazine-alkylamino acid salt is preferably from 10 to 18, more preferably from 1 to 16 'and further preferably 1〇~14. The carbon number of the alkyl group of the oxime-based alkylamine salt is preferably (7) to 丨8, more preferably 10 to 16, and still more preferably 10 to 14. The ether carboxylate may, for example, be a polyglyceryl alkyl ether acetate or a myrioacetate represented by the following formula (1). RZ-(CH2CH20)a-CH2C02Y (I) [wherein, R represents a linear or branched alkyl or alkenyl group having a carbon number of 7 to 19, and Z represents -〇- or -CONH-, and Y represents a hydrogen atom, Alkali metal, triethanolamine or ammonium, a represents the number of ι~20]. In the above ether acetate, it is preferred that the carbon number of R is from 10 to 18, more preferably from U to 丨5, and a is preferably from 3 to 15, particularly preferably from 6 to 12. Among these, it is preferred to satisfy the range of the carbon number of R and the range of a at the same time. 146962.doc 201039856 In the "first invention", the content of the component (B) in the mixed solution of the first agent and the second agent is increased by the use of the cationic surfactant with the component, even in the case of a higher bath. From the viewpoint of improving the stability of the foam on the hair and suppressing the dripping effect, it is preferably 〇5 to 丨〇 mass%, and more preferably 1 to 8 mass. /. Especially good is 2 to 5 mass%. Regarding the mass ratio (B)/(A) of the component (B) to the component (A), the effect of suppressing the dripping of the foam on the hair is further enhanced, and the bubble is sufficiently spread throughout the root. In other words, it is preferably set to, and further preferably set to 2 to 50, and particularly preferably set to 4 to 2 inches. Further, in the case of the component (A) and the component (B), it is preferable to improve the storage stability, to improve the stability of the bubble by the mixing immediately before use, and to improve the drip suppression effect. It is separated and contained in the second agent and the second agent. In other words, it is preferred that the component (B) is contained in the first agent, and the component (A) is contained in the second agent, or the component (A) is contained in the first agent, and the component (8) is contained in the second agent, which is particularly preferable. The total amount of the component (B) is contained in the first agent, and the total amount of the component (A) is contained in the second agent, or the total amount of the component (A) is contained in the second agent, and the component is contained in the second agent (B). The total amount of the situation. [Other surfactant] The two-part hair dye of the "first invention" may further contain a surfactant other than the component (VIII) and the component (B). Such a surfactant activity is exemplified by a nonionic surfactant, an amphoteric surfactant, a semipolar surfactant, and a cationic surfactant other than the component (A). The nonionic surfactant "is exemplified by alkyl polyglucose, polyoxyalkylene alkyl ether, alkyl glyceryl ether and the like. As the alkyl polyglucoside is preferably 146962.doc 201039856 is the carbon number of the alkyl group is 8~18, better 疋8~14 of the lamp, especially good is 9~11, the good ^(4) is the thiol is straight Chain. The average degree of condensation of the Portuguese (4) is preferably 1 to 2 in the X 5 domain. As the polyoxynexene base, it is preferred that the carbon number of the base is .22, particularly preferably, the taste is, and preferably, the base is a linear one. Further, it is more preferable to use a polyoxyalkylene extension test, and it is preferred that the average addition molar number of the oxygen-extended ethyl group is (4), particularly preferably 4 to 30. As the base glycerin, it is preferred that the carbon number of the base is 8 to 18, particularly preferably 8 to 12, Ο

By. @^料料 The filament is branched as an amphoteric surfactant, and it can be exemplified by a betaine system having a carbon number (d), a dilute group or a sulfhydryl group, a guanamine beet (four), and a base beet test system. Beet (four) ', beet-based beet (four), phosphoric beet test system '(four) rust-based surfactant; among them, the sulphur-based beet test system surfactant, feed beet (four) interface heart _. The preferred amphoteric surfactants include lauric acid propyl beet test, coconut oil fatty acid allysyl propyl sweet, lauryl tris-family-ethyl acetonate, lauryl sulfobetaine, etc. . The semipolar surfactant may, for example, be an alkyl amine oxide or a alkylguanamine amine oxide. The cationic surfactant other than the component (A) may, for example, be a di-long-chain aliphatic dimethyl salt such as a dialkylmonomethylammonium salt. In the "first invention", the content of the surfactant other than the component (A) and the component (B) in the mixed solution of the first agent and the second agent further improves the foaming property and further improves the hair. The viewpoint of the stability of the bubble is 146962.doc 201039856, preferably 0.8% by mass, more preferably 〇5 to 6% by mass, particularly preferably 1 to 5% by mass. [Test] The test agent is contained in the fourth (four) dyeing agent of the present invention. As the test reagent, ammonia and its salts; monoethanolamine, isopropanolamine, 2-amino-2-nonylpropanol, 2-aminobutyric amine and salts thereof; hydrazine, 3_propyl A diamine or the like is a diamine and a salt thereof; a carbonate such as cesium carbonate, sodium sulphate, potassium carbonate or potassium hydrogencarbonate or the like. These alkali chemicals may be used in combination of two or more kinds, and in terms of sufficient dyeing and decolorizing effects, and reduction of hair damage or scalp irritation. The amount of 3 is preferably 〇 5 〜 15 mass 〇 / 中 in the mixed liquid, and further preferably 0. W0% by mass, particularly preferably 〇 2 to 5 % by mass. [Hydrogen peroxide] The content of hydrogen peroxide in the second agent of the two-part hair dye of the present invention is 疋19 mass. /〇 ‘ Especially good is 3~6 mass〇/. The content of hydrogen peroxide in the mixture of the second agent and the second agent is preferably 6% by mass, particularly preferably 2 to 5% by mass. Further, in order to suppress the decomposition of cerium peroxide, the pH of the second agent is preferably from 2 to 6, and particularly preferably, the pH is set to 2.5 to 4. [Dye] is a dyeing agent The two-part hair dye of the present invention is a hair bleaching agent which does not contain a dyeing agent and contains an oxidation dye intermediate or a direct dye in the first agent. (gasification dye intermediate) ^ Known amine

As the intermediate of the oxidative dye intermediate such as the drive and the coupling agent D, the common use of the dyeing agent can be used, for example, p-benzoquinone-2,5-diamine chloride-p-benzene. Diamine, N_decyloxyethyl-p-benzene 146962.doc 201039856 Diamine, N,N-bis(2-hydroxyethyl)-p-phenylenediamine, 2-(2-hydroxyethyl)-p- a fe ' 2,6-monomethyl-p-diamine, 4,4-diaminodiphenylamine, 1,3-bis(N-(2-hydroxyethyl)-N-(4-amine Phenyl)amino)-2-propanol, PEG (polyethylene glycol) _3,3,2'-p-phenylenediamine, pair

❹ Aminophenol, p-methylaminophenol, 3-methyl-4-aminophenol, 2-aminomethyl-4-aminophenol, 2-(2-hydroxyethylaminoguanidino)_4 _Amino phenol, o-aminophenol, 2-amino-5-nonyl phenol, 2-amino-6-nonyl phenol, 2-amino-5-acetamido phenol, 3,4- Diaminobenzoic acid, 5-aminosalicylic acid, 2,4,5,6-tetraaminopyrimidine, 2,5,6-triamino-4-hydroxypyrimidine, 4,5-diamino- 1-(4'-Chlorobenzyl)pyrazole, 4,5-diamino-indole-hydroxyethylpyrazole, and the like. Further, examples of the coupling agent include m-phenylenediamine, 2,4 phenoxyethanol, 2-amino-4-(2-hydroxyethylamino)anisole, and 2,4-amino-5. · Methyl phenyl _, 2, 4 · diamino _ 5 — (2 M ethoxy) toluene, 2,4-dimethoxy-1,3-diamino benzene, 2,6 bis (2 _hydroxyethylamino)toluene, 2,4-diamino-5-fluoromethyl succinyl bisdiaminophenoxy)propane, m-aminobenzene, 2·methyl-5-aminobenzene Age, 2·methyl_5_(2-transethylethylamino) silk, 2,4-dichloro-3-aminobenzoquinone, 2_gas_3_aminotoluene, 2-曱Base-4-gas _5_aminophenol, N_cyclopentyl-m-aminophenyl -4-indolyl acetophenethylamino) phenylpan, 2-methyl-2, gas-terminated benzene Stupid two, "base benzene two, heart chlorine benzene benzene: ^ naphthalene ^ dipyridyl naphthalene ... - dipyridyl naphthalene ... - di-base plant, 2 isopropyl 5-methyl phenol, 4_hydroxyindole, 5_hydroxyindole, · vial ", 7_«^, 6_-based benzophenanthrene, 3,4-methylenedioxy 146962.doc 201039856 base benzoquinone, 2-acting -4,5-arylene dioxybenzene, 3, mesotylene dioxyaniline, 1-(2-hydroxyethyl)amino group _3,4_methylene Benzobenzene, 2,6-dihydroxy-3,4-dimethylpyridine, 2,6-dimethoxy-3,5-diaminopyridine, 2,3-diaminotolyl pyridine, 2-mercaptoamino group Iamino-6-methoxypyridine' 2_amino-3-hydroxypyridine, 2,6-diaminopyridine, and the like, etc. The precursor and the coupling agent may also be used separately. The content of each of the precursor and the coupling agent is preferably from 1 to 5% by mass, particularly preferably from 0.1 to 4% by mass in the mixed liquid. (Direct dye) As the direct dye, an acid dye may be mentioned. , nitro dye, disperse dye, basic dye, etc. As the acid dye, blue nickname, purple 401, black 401, orange 2〇5, red (2), red ι〇6, yellow 203 No., acid lamp 3, etc., as the ruthenium dye, 2_stone-p-phenylenediamine, 2-amino-6_qi__nitrophenol, 3-nitro-p-hydroxyethylaminobenzene纷, 4· Shi Xiaoji· o-phenylenediamine, 4-amino-10 nitrobenzene, 4· propyl propylamino nitrophenol, HC Blue No. 2, HC Orange No. 1, HC red

No.l, HC Yellow No. 2, HC Yellow No. 4, HC Yellow No. 5, HC Red No. 3, N, N bis(2-hydroxyethyl)_2_nitro-p-phenylenediamine, etc. Examples of the disperse dye include disperse purpura, disperse blue sputum, disperse black 9, and the like. As the basic dye, basic blue 99 'alkaline brown 166, basic brown 17, alkaline red 76, and basic red 5 may be mentioned. 1, alkaline yellow 57, alkaline yellow 87, alkaline orange 3 丨 and so on. The direct dye may be used in combination of two or more kinds, or may be used in combination with an oxidative dye intermediate, and the content thereof is preferably from 0.ooi to 5% by mass, particularly preferably from 0.01 to 3% by mass, in the mixed solution. 146962.doc -12· 201039856 [Premier Alcohol] In the two-part hair dye of the invention, it is possible to further contain a higher alcohol in order to change the inhibitory effect of the drip of the bubble. The post-stage period as the higher alcohol' is preferably a hospital base or a thin base having a carbon number of μ::18, and among them, it is preferred to have a burnt base, especially a:::. For example, nutmeg, recorded alcohol, and stearin

= metamorphosis _, with alcohol, oleyl alcohol, etc. Preferably, two or three kinds of nutmeg, cetyl alcohol, and stearyl alcohol are used in combination. In the first month, the content of the higher alcohol in the mixed solution of the first agent and the second agent is foaming property, fineness, and recording of the bubble f, and the effect of suppressing the dripping during the standing period. In terms of t, it is preferably m. 5 mass%, more preferably O.lq mass%, and even more preferably 〇4 to 〇9 mass%. The main body is particularly preferably 〇6 to 〇8 mass%. Further, the content of the higher alcohol in the first agent in the case where the higher alcohol is contained in the Bu agent is preferably 〇〇 〜 2% by mass, more preferably 0.1 to 1.5% by mass, particularly preferably It is 〇2~lft%. In the case where the second agent contains a higher alcohol, the content of the higher alcohol in the second agent is preferably 0.01 to 2 by mass. /. Further preferably, it is 1 to 15% by mass, particularly preferably 0.5 to 1% by mass. [Polymer or copolymer of diallyl quaternary ammonium salt] In the two-part hair dye of the "first invention", it is easy to confirm the application of the smear after the application of the appropriate amount of the remaining amount of the foam after application to the hair. From the viewpoint of the effect of the treatment, a polymer or a copolymer of a diallyl quaternary ammonium salt may be further contained. As a specific example of the polymer or copolymer of diallyl quaternary ammonium salt, 146962.doc 201039856 may exemplify a gasified dimercaptopropylammonium polymer (Polyquternium-6, for example) Merquat 100; Nalco Company), Dimercaptopropylammonium chloride/acrylic acid copolymer (polytetraammonium _22, for example

Merquat 280, Merquat 295; Nalco), Dimercaptopropyl chloride/acrylic acid amine copolymer (polytetramine-7, such as Merquat 5 50; Nalco), dimethyldiene chloride Alkyl ammonium/acrylic acid/acrylamide copolymer (polyquaternary-39, such as Merquat plus 3 330, Merquat plus 3331, Nalco) and the like. Of these, preferred are dimethyldiallylammonium chloride polymer and dimercapto diallyl ammonium chloride/acrylic acid copolymer. In the "first invention", the content of the polymer or copolymer of the diallyl quaternary ammonium salt in the mixture of the second agent and the second agent is maintained at a suitable bubble retention after application to the hair. From the viewpoint of easily confirming the effect of the applied portion, it is preferably 1 to 3 mass%, more preferably 2 mass%, and particularly preferably (^~丨5 mass 0/〇 L. Non-Zenic Hydrophilic Solvent] Among the two-component hair dyes of the "first invention", it is preferred to further volatize the hydrophilic solvent in the right-handed body. When the bubble of the liquid is applied to the hair and placed in the hair, the irritating component such as phosphatase and the stimulating component are concentrated in the r:/r mixture, and the peroxy hydrophilic solvent is compared with the scalp of 4 ^. There is no defoaming in the base mouth or its lower grade (carbon number 1~4): 2 the ginseng alcohol is better as the Shijia 2~6, for example, the 疋 厌 厌 厌 】 】 】 glycerol, Diglycerin, propylene glycol, - and alcohol, 1,3-butanediol, y-propyl. 醢笙 from * - · hand, - ethylene glycol, isoprene, mountain yeast, etc. as a mountain of polyol:氐The alkyl ethers may, for example, be the above-mentioned polyols 146962.doc 201039856 mono-lower alkyl ethers or poly-lower alkyl ethers (e.g., di-lower alkyl ethers), etc. Among them, preferred are monomethyl ethers or monoethyl ethers of polyhydric alcohols. Specific examples thereof include ethylene glycol monomethyl mystery, ethylene glycol monoethyl ether, ethylene glycol monoterpene ether, and diethylene glycol diethyl ether. These may be used in combination of two or more.

In the "first invention", the content of the non-volatile hydrophilic solvent in the mixture of the second agent and the second agent reduces the effect of scalp irritation and also makes the foam good when the liquid temperature is low. For the reason, it is preferably 〜ι 4 mass/〇, more preferably 0.5 to 3 mass. /. Further, it is more preferably the quality of the second component [other optional components] The second agent of the two-part hair dye of the present invention and the second agent are water as a medium, and may be added as a raw material for cosmetics in addition to the above components. Other ingredients. Examples of such an optional component include animal and vegetable fats and oils, natural or synthetic polymers, Guan, egg (four) organisms, hydrolyzed proteins, amino acids, preservatives, chelating agents, stabilizers, antioxidants, botanical extracts, and natural substances. Drug extracts, vitamins 'perfume, UV absorbers. [pH] Regarding the pHft (25t>c) of the two-part hair dye of the present invention, in terms of decolorization and dyeing effect and skin irritation, it is preferably from 8 to 12 at the time of use (mixing). More preferably, it is 9 to 11, especially preferably 9 to 10. As the pH adjusting agent, in addition to the above-mentioned test, there may be mentioned inorganic acids such as hydrochloric acid and acid-filling, such as T% acid glycolic acid, organic acids such as lactic acid, phosphates such as potassium dihydrogen phosphate and disodium hydrogen phosphate. Wait. [Viscosity] The viscosity of the mixture of the first agent and the second agent of the agent type hair dye of the present invention is 146962.doc -15-201039856 is 1 to 300 mPa.s, preferably 5 to 200 mPa.s. Especially good is 10~100 mPa's. In addition, the viscosity here is at 25 ° C using a B-type rotational viscometer 'Using the rotor Νο·1 ' when the measurement object is 1 〇〇 mPa.s or less, at a speed of 60 rpm, 1 〇〇 In the case of ~2〇〇mPa.s, the measurement is performed at a rotation speed of 12 rpm at a rotation speed of 3 rpm and 200 mpa.s or more. The measurement is performed in order from the measurement of the large number of revolutions, and the measurement is completed at the time when the display can be measured without exceeding the scale, and the measurement of the subsequent rotation speed is not performed. By adjusting the viscosity of the mixture of the first agent and the second agent to the above range, the bubble volume which is easy to apply can be achieved, and dripping of the mixed solution onto the hair can be suppressed, and the squeeze foamer can be utilized. It is easy to squeeze when it is sprayed out. In order to adjust the viscosity of the mixed solution to the above range, a water-soluble solvent such as ethanol may be added, or the content or type of the surfactant, the polyol, the higher alcohol or the like may be appropriately adjusted. [Dynamic viscoelasticity] In the "I-th invention", a rheometer is used in the following conditions to form a stable foam which is applied to the hair and does not drip during the placement. When the dynamic viscoelasticity of the bubble after the mixture is sprayed in a bubble form is measured from a non-aerosol foaming container, it is preferred that the complex elastic modulus G* is in the range of 50 to 600. More preferably, G* is 7〇, W is better, and 100~400 is especially good, 120~300. Rheometer settings: Parallel plates made of stainless steel. The geometry is 50 mm in diameter and the temperature in the measuring section is maintained at 30 °C. 146962.doc -16· 201039856 Determination order: 1. Use a spatula to take a bubble of 4.5~5.5 cm3 to the base of the rheometer. 2_Adjust the gap to 2 mm and carefully remove the bubbles that overflow from the base. 3. After the bubble was allowed to stand for 30 seconds, the dynamic deformation scan evaluation was started under the following conditions. Frequency: fixed at 2 Hz, deformation: 1χ1〇-3~1χ1()3% Ο 4. According to the obtained f material, the value of the linear region relative to the deformation is used as G, from the non-aerosol foaming container. The bubble of the mixed liquid sprayed out may rupture with time, so it is preferably rapid (for example, within a minute, preferably within 3 seconds, and preferably within 10 seconds) for the above dynamic viscoelasticity. 2 Determination. As the measuring device used for the measurement of dynamic viscoelasticity, for example, MCR3® manufactured by Paar Physica Co., Ltd. can be used. In the present invention, a geometry of a flat plate type (50 mm in diameter and stainless steel) was used, and the temperature of the measuring portion was set to 30 °C. In addition, for the two-agent hair dye in the "i-th invention", the sprayed &amplitude has appropriate fluidity and appropriate elasticity, and spreads well to the root of the hair, and can be uniformly dyed. From the viewpoint of Mao, it is preferred that the bubble immediately after the ejection is in the above-mentioned order 4, and the value which becomes the linear region with respect to the deformation is used as the ratio of the storage elastic modulus G to the loss elastic modulus ^ (plus ^ When δ is in the range of 0.3 to 〇.8, it is better that 3 is 〇35~〇75, and particularly preferably 0.4~0.7. 146962.doc 17 201039856 [Gas-liquid mixing ratio] The mixing ratio of the α liquid of the foaming container of the foaming agent of the dosage type dyeing agent is preferably 7 to persuade one in terms of the ease of dyeing and ease of application of the hair to the hair dyeing agent. The L/g is further 'the gas-liquid mixture ratio here is determined by the following method. First, 'the σ ratio of gas and liquid is obtained by the weight and volume of the bubble ejected under the hunger. (10) (4) Adding liquid to the squeezing foaming container (Dahe canning machine S1 squeezing foaming device) volume 21 ,, mesh thickness (mesh) is mixed 150 to 150 mesh (150 grids per 1 hour (25·4 _)), 200 mesh in the front end), from the time when the remaining amount is 80 g, 20 g/pack is ejected in a cylinder of 1000 mL. The volume of the bubble was measured after a minute. The gas-liquid mixture ratio (mL/g) was determined by dividing the volume (mL) of the ejection bubble by the weight of 2 Gg. [Non-aerosol foaming container] The present invention The foaming container used in the present invention is a non-aerosol container and is used to mix a mixture of the first agent and the second agent with air and to eject it in a bubble form without using a propellant. The foam container can also obtain the effect of preventing the scattering of the sprayed agent. In particular, the container of the non-aerosol type can be manufactured at a lower cost than the container of the silicone type, and does not require the use of a propellant of a pressurized gas. 'Therefore, it can be operated safely during the circulation of the product. As a foaming container', a known pump foaming tank with a bubble jetting mechanism can be used to squeeze the foaming vessel, the electric bubbler, and the accumulator pump. A container, etc. More specifically, for example, foods and containers (vol. 35, 146962.doc • 1 8- 201039856

No.10, p588^593 (1994); vol.35, No.li, p624~627 (1994); ν〇1·36, No, 3, pl54~158 (1995)) Type of 耵, pump type F2 (manufactured by Daiwa Can Co., Ltd.), extrusion foamer (manufactured by Daiwa Can Co., Ltd.), electric bubbler (made by Matsushita Electric Works Co., Ltd.), jet foamer ( Airspray lnternati0nal company) and so on. As the foaming container used for the two-part type of hair dye of the present invention, it is preferable to use a fruit foaming container and a squeeze foam container in terms of inexpensive and convenient use. The pump foaming container or the extrusion foaming container has a bubble generating portion such as a mesh, and it is preferable to have a thin mesh when the mixture of the agent and the two agents is dried and solidified to cause clogging. At the next ejection, the clogging can be eliminated by immediately dissolving the cured product by the flow of the bubbles. At this time, as the mesh of the network, it is preferably 50 to 280 mesh, more preferably 9 to 25 mesh, and more preferably 130 to 220 mesh. Here, the term "net" refers to the number of meshes per inch. Milky bubbles can be produced by using a mesh of meshes of this range. Further, as a material of such a mesh, a nylon 'polyester or the like can be preferably exemplified. The foaming container used in the two-component hair dye of the present invention is provided with a plurality of sheets, preferably a plurality of sheets, particularly in terms of economy, stability of foam, etc., preferably Equipped with 2 nets. In the foamed container, the portion in contact with the contents (the inner wall of the container, the inner wall of the bubble ejecting mechanism, etc.) is preferably permeable to oxygen which is not corroded by alkali and argon peroxide and which is decomposed by hydrogen peroxide. Made up of materials. As a product form of the two-part type hair dye of the present invention comprising the first agent, the second agent and the foaming container, the first agent or the second group can be filled with the foaming capacity of 146962.doc -19- 201039856, respectively. Different containers t' and transfer the two doses into the foaming container for mixing during use; the agent may be filled in the foaming container and the other agent is filled in the other container' and will be used The other agent is transferred to a foaming container. In this case, in order to prevent the pressure generated in the container from rising due to the oxygen generated by the decomposition of hydrogen peroxide, it is preferable to fill the container having gas permeability, in particular, a material having oxygen permeability. In a foamed container formed by (for example, polyethylene). On the other hand, in order to prevent oxidation of the oxidative dye, it is necessary to use a container in which oxygen is difficult to permeate. Hereinafter, a description will be given of a squeeze foam container as a preferred embodiment with reference to the drawings. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a view showing the state of one of the two-part dyeing agents of the second invention of the present invention, and shows the state before mixing of the first agent and the second agent. The two-part type hair dye 1 includes a first agent 八 filled in the i-th container 2, a second agent A2 filled in the second container 3, and a squeeze foamer 5. The container body 4 of the second container 3 is also a container body of the squeeze container, and the container body 4 and the squeeze foamer 5 constitute a squeeze container. On the other hand, the squeezing container which blisters the two-part dyeing agent has the same basic structure as the known squeezing container described in Japanese Laid-Open Patent Publication No. Hei 7-215352, and the like. The flexible container body 4 and the squeeze foamer 5. The squeeze foamer 5 includes an opening that is coated to the container body 4. The lid portion 7 on the upper side and the head portion 8 attached to the lid portion 7 are covered. The product 10 covers the cover 7 and hangs down. The inside of the mixer 1 is provided with a gas-liquid junction chamber 11 and an air introduction path 12 for connecting the internal space in the container body 4 to the gas-liquid junction 11 to 11 . Further, the impregnation tube 13 extends into the container body 146962.doc -20-201039856 4 and is fitted into the mixer 1〇, and the female watch has a liquid passage 15 as a bubble homogenization mechanism. Further, in the top surface of the gas-liquid mixing chamber 11, the head of the bubble homogenizing mechanism 14

At the head. Μ Μ 置 置 与 盖 盖 盖 盖 盖 盖 盖 盖 盖 盖 $ $ $ $ $ $ $ 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通 连通Ϊ́8's network. In the present invention, the bubble homogenizing means 14 18 on the gas-liquid mixing chamber side and the discharge port side is not limited to a mesh, and a porous material such as a sponge or a sintered body may be used. In order to reduce the pressing force necessary for squeezing the container body 4 and to improve the recovery of the damped container body 4, the container body 4 is preferably made of polypropylene, high density polyethylene, medium density polyethylene, A polyolefin resin such as low density polyethylene or linear low density polyethylene is formed, and it is particularly preferably formed of polypropylene. Further, in the case where the container body 4 is formed of such a polyolefin resin, it is preferred to use the resin amount w (g) of the container body 4 and the internal volume V (mL) of the container body 4 by 2/3 of the square. &(w/V2/3;) means that the "2/3 power factor" is set to 0.40 to 0_60, and it is better to set it to ο."~〇·55. Incidentally, when the internal volume of the container body 4 is 210 mL, the amount of the resin is preferably 14 to 2 〇 g, more preferably 16 to 18 g. Thereby, the pressing force necessary for the pressing can be lowered, and the recovery can be improved while the continuous pressing is performed. Further, in order to further improve the foam quality of the bubble of the mixed liquid A3 ejected from the self-pressing container, it is preferable to open the opening area of the narrowest portion of the air introduction path 12 and the cross-sectional area of the flow path of the dip-beet tube 13. The ratio (opening area of the narrowest portion/sectional area of the flow path) is set to 0.05 to 0.4, more preferably 0.055 to 0.35, and particularly preferably 146962.doc -21 - 201039856 0·060 to 0.3. Furthermore, when a plurality of air guides are formed in the squeeze foamer $, the total value of the open area of the narrowest portion is impregnated

The ratio of the 1J area of the intersection is set as the above-mentioned brother. The number of the air introduction paths U is preferably from 2 to 6 and more preferably from 3 to 4 in terms of ease of molding and foam quality. Further, when the cross-sectional area of the flow path of the impregnation tube 13 is narrow, the cross-sectional area of the flow path using the narrowest portion is calculated. The thickness of the net of the bubble homogenizing mechanism 14 constituting the U-side of the gas-liquid mixing chamber is preferably 50 rhymes, more preferably 9 to 195 mesh, and more preferably 130 to 170 mesh, which constitutes the discharge port 17 side. The coarseness of the net of the bubble homogenization mechanism 18 is (10) 28_ mesh, and more preferably _~2 side, and thus a good 疋180~220 mesh. Here, the so-called mesh refers to the number of meshes per inch. The method for using the wood wool agent 1 is to firstly transfer the total amount of the first agent A1 in the first solution to the container body 4 filled with the second agent Α2, to prepare a mixed liquid. A3. Therefore, the volume of the second agent of the i-th agent disk becomes the container amount. The mixing of the first _A1 and the second agent to the sputum to the sputum (four) and the mixing of the agent A2 are preferably carried out in such a manner that they foam as much as possible or do not foam themselves. Here, the case where the straight bubble is not caused or the hair is not emitted is &#;&, the material is arranged to be used; and the case of the & is included in the case where the bubble is not intentionally generated during the mixing, for example, the package _

The specific method shown below is used to mix people with the result of agitation. As long as there is no foaming during mixing, the system can be exemplified by the method of mixing the test tubes or placing the container body 4 from a substantially erect state. Inverted or traversed two 146962.doc •22- 201039856 and then restored to a roughly symmetrical state. More specifically, the lid of the second container 3 is placed on the container body 4 in which the phantom and the first container are placed, and the container body 4 is placed in an upright or inverted state from the substantially erect state. In the erect state, it is sufficient to perform the above-mentioned cycle of 1 30-person, preferably 15 to 2 times, and preferably 2 times in 1 Gsec. The operation system that returns to the substantially erect state after being placed in an upright or inverted state is 丨~15 times, preferably 2 to 1 〇: owed, preferably 3 to 7 times. Thus, even if the container body 4 is gently shaken, the 'A1 and the second agent 八2 used in the present invention are also in a form having a viscosity much lower than that of a gel or a paste, so that a mixture of the smear can be easily obtained. A3, and no bubbles. After the first agent A1 and the second agent A2 are mixed, the squeeze foamer 5 is placed on the container body 4. Further, when the first #iA1 and the second agent 八2 are mixed, the total amount of the first agent A1 may be transferred to the container body 4 filled with the second container of the second agent A2, and then applied to the stalk body. 4, the squeeze foamer ^ is attached to replace the cover of the second container 3, and the container body * is slowly oscillated by a mixing method such as (4) test tube. [Method of use] It is preferred to pre-hair the hair when dyeing hair (especially hair) using the two-part hair dye of the present invention. Thereby, the hair is not easily entangled during the process of re-foaming described later, so there is no fear that the mixed liquid will scatter. Further, it is preferred that the partitioning operation which is common when the hair dye composition is applied is not required after the hair is combed, and the partitioning operation is not further performed. Thereby, the operation of applying the hair dye composition to the hair described later or re-foaming is 146962.doc • 23- 201039856. Then, the first agent and the second agent of the one-component hair dye of the present invention can be mixed in a foaming container, and the foaming agent sprayed from the time to the benefit can be directly applied to the hair, and can also be used.丰^ . Apply to your hair with a hand or brush. After smearing, place it for 3 to 60 minutes, and the weight is 5 to 45 minutes, and wash it off. Thereafter, appropriate shampooing, AI and °, only after washing, the water is washed to dry the hair. The hair is sprayed on the head and the mixture of the second agent and the second agent is applied to the head, so that the applied foam is foamed on the hair again, thereby further preventing application to the hair until the washing is completed. During the period of the drip, it is also possible to avoid smearing or smearing. ^ ^ When J Dan has been foaming for a long time, it can also be injected into a device such as a vibrating machine or a brush, or you can use the hand s ' Better yet, use your fingers. Here, the period of the heart can be changed after the bubble disappears, or the bubble disappears. ', 'The needle that changes... can be the bubble that is applied. Alternatively, it may be administered in all ranges within which the foam is to be applied: Bi^ may also be between (4). The re-foaming operation can be carried out continuously for one person or intermittently. According to this method, the smear is applied to the hair of the back brain, such as _p, and the person is foamed. Therefore, it is difficult to confirm the part, and the two-part type is unevenly applied, and further, the smear remains. Or apply it to the roots of the hair. The "second invention" will be described only once. [Dynamic viscoelasticity] in "Second invention" + 'mixed from non-aerosol foaming container 146962.doc •24- 201039856 The bubble of the liquid mixture will rupture with time, so it is rapid (for example, within 1 minute) 'It is preferably within 30 seconds, and further preferably within 1 second." It is used for the measurement of dynamic viscoelasticity shown below. As the measuring device used for the measurement of dynamic viscoelasticity, for example, MCR300 manufactured by Paar Physica Co., Ltd. can be used. In the present invention, a geometry of a parallel plate type (50 mm in diameter and made of stainless steel) was used, and the temperature of the measuring portion was set to 30 °C. The order of measurement is as follows. Ο Use a spatula to take a bubble of 4.5 to 5.5 cm3 to the base of the rheometer. 2. Adjust the gap to 2 mm and remove it. The bubbles overflowing between the susceptors were carefully held for 30 seconds to allow the bubbles to adapt to the temperature of the measuring portion, and then the dynamic deformation scanning evaluation was started under the following conditions.频率 Frequency: fixed at 2 Hz, deformation: 4. According to the data obtained, the value of the domain is used as G*. lxlO'3~lxl〇3〇/0 The two-component type dyeing agent in the "second invention" which is a linear region with respect to deformation is a complex elastic modulus G* of 50 to 60 by the bubble immediately after ejection. () s + L l week § value 'has a stable foam that does not drip during application after application to the hair. Better to delete 'and thus better H gamma, especially good for the "second invention" which has both proper fluidity and proper blistering, and can be evenly dyed = well throughout The hair ', 観 4 and $, preferably the bubble immediately after the ejection 146962.doc 25- 201039856 In the above sequence 4, the value which becomes a linear region with respect to the deformation is used as the storage elastic modulus G' and the loss elasticity When the modulus G" ratio (plus δ) is added, the § is in the range of 3 0.8. Further, the quotation is 〇35~〇 75, especially preferably 0.4~0.7. In the two-component hair dye of the "oil agent", the mixture of the first agent and the second agent is foamed in a range of (Τ = 50 to 600 to form a stable foam, In the case of using a higher bath ratio, the liquid is not dripped, and the root of the hair is uniformly dyed to the tip of the hair. It is preferred to formulate the oil containing 〇·01~3 mass% in the mixture. Further, it is preferably contained in the range of Q G 3 to 25% by mass, particularly preferably 0.05 to 2% by mass. As such an oil agent, there may be mentioned an angle of an ene, a wide angle, a liquid stone butterfly, and a liquid isomerized paraffin. Hydrocarbons such as naphthenes; glycerides such as castor oil, cocoa butter, eucalyptus oil, avocado oil, and eucalyptus oil; waxes such as beeswax, cetyl wax, lanolin, and Brazilian brown wax; isopropyl palmitate , isopropyl myristate, octyldodecyl myristate, hexyl laurate, cetyl lactate, propylene glycol monostearate, oleic acid ester, hexadecyl 2-ethylhexanoate , isodecyl isononanoate, tridecyl isononate and other esters; tannic acid, lauric acid 'myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, coconut oil Higher fatty acids such as fatty acids, isostearic acid, isopalmitic acid, etc.; higher alcohols such as myristyl alcohol, cetyl alcohol, stearyl alcohol, camellia alcohol, 2-octyl dodecanol, and stearyl alcohol; Further, an isostearyl glycerin bond, a polyoxyl propyl butyl ether, etc. may be mentioned. Among them, preferred are higher alcohols, particularly preferably myristyl alcohol, cetyl alcohol, and stearyl alcohol. 146962.doc •26· 201039856 [Water-soluble polymer] In the two-component hair dye of the "second invention", the bubble of the mixture of the first agent and the second agent is also G*=50-600. In the range of the stable foam, even if the bath is used at a higher bath ratio, and the root of the hair is dyed to the tip of the hair, it is preferred that the mixture contains strontium. The formula of the water/gluten polymer in the mixture. The amount of the water-soluble polymer contained in the mixture varies depending on the molecular weight thereof, and when the ❹ y y is contained, the tan δ is reduced to make the bubble It is elastic, and when it is contained, G is increased to become a stable bubble. From this point of view, it is preferable to mix. 〇·〇ΐ~3 mass%, and further preferably 〇丨~2 mass ❶/❶, particularly preferably 0·2 to 1.5% by mass. As a water > gluten polymer, a cationic polymer may also be used. Any one of an amphoteric polymer, an anionic polymer, and a nonionic polymer. ～ As a cationic polymer, it may be mentioned that a side chain of the polymer chain contains a ～ group or an ammonium group, or a diallyl group. The dibasic salt is used as a constituent unit, and the polymer main chain is repeated by a constituent unit containing a quaternary bond group, and examples thereof include a cationized cellulose, a cationic starch, a cationized sputum, and a dipropyl propyl group. a polymer or copolymer of a dialkylammonium salt, a quaternary copolymer of ethylene, and a quaternary ammonium polymer comprising a repeating unit represented by the following formula (A), comprising a formula of 3 or less ( B) A quaternary ammonium polymer or the like of the repeating unit represented.平b [化1] i -¥ ΟΓ13 lPCH2)^NH^C〇^nh_(ch^^^ 3 CH, T3 CH, (A) 2X' 146962.doc -27- 201039856 [wherein P represents 1~ An integer of 6, where D represents a bond or *_(cH2)rC0-(r represents 4 or 7), and X represents an anion.] [Chemical 2] (Β) 2Χ [wherein, R1 to R4 may be the same or Different, it means an alkyl group or a hydroxyalkyl group having a carbon number of 4, η and m each represent an integer of 2 to 20, and Χ- represents an anion.] As the cationized cellulose, as Le 〇gard 〇, Leogard GP Commercially available polytetra-ammonium-10 (Lion & 3), p〇iymerjR__125, p〇lymer JR_400, Polymer JR-30M (D〇W Chemical), etc., as Cellcoat H-100, Cellcoat L-200 (Nati 〇nal

Starch and Chemical Company) and other commercially available hydroxyethyl cellulose gasification - monomethyl '- propyl propyl (poly quaternary record 4). As the cationized gum, it can be cited as Jaguar c_13s,

Jaguar C-14S, C-17 (Rh〇dia), etc., commercially available Guaya gum gasification hydroxytrimethylammonium. Examples of the polymer or copolymer of the diallyldialkylammonium salt include polyaminated dimercaptopropylammonium (polytetraamethylene-6) which is commercially available as Merquat 100 (Nalco Co., Ltd.) or the like. An emulsified monomethyldiallyl-acrylamide copolymer commercially available as Merquat 550 (Nalco Co., Ltd.) or the like (Polyquarium _7). As a quaternized copolymer of vinylpyrrolidone, it can be mentioned as:

Gafquat 734, Gafquat 755, GafqUat 755N (ISP company), etc. 146962.doc -28- 201039856 Sale of the fourth grade of money-11; as a Luviquat FC307, Luviquat FC550, Luviquat FC905 (BASF company) and other commercially available Grade IV-16; Polytetramine-28 commercially available as Gafquat HS-100 (ISP). Examples of the quaternary ammonium polymer containing the repeating unit represented by the above formula (A) include polytetrazide-2 which is commercially available as Mirapol A15 (Rhodia Co., Ltd.), etc.; and Mirapol ADl (Rhodia Corporation) and the like. The commercially available poly quaternary -1 7 ; polytetracycline-1 8 commercially available as Mirapol AZ1 (Rhodia Corporation). 〇 As the quaternary ammonium polymer containing the repeating unit represented by the above formula (B), polytetracycline-34 which is commercially available as Mexomere PAK (Sysmex Corporation) or the like can be mentioned. Examples of the amphoteric polymer include a copolymer of a monomer having an anionic group such as a sulfonic acid group or a carboxyl group, a copolymer of a monomer having an amine group or an ammonium group, a polymer or a copolymer of a betaine type monomer, and a sulfonate. An anion group such as an acid group or a carboxyl group is introduced into a cationic polymer or the like. Specific examples thereof include a gasified dimethyl diallyl ammonium-acrylic acid copolymer (Polyquarium -22) commercially available as Merquat 280, Merquat 295 (Nalco Co., Ltd.), etc.; as Merquat plus 3330, Merquat A commercially available acrylamide-acrylic acid-dimethyldiallyl ammonium chloride copolymer (polytetra-ammonium-39), which is commercially available as Merquat 2001 (Nalco Co., Ltd.), etc., in addition to 3331 (Nalco Corporation). Acrylic acid-methyl acrylate-methyl methacrylate decyl propyl tridecyl bond copolymer (poly quaternary ammonium-47); commercially available methacryl fluorenyl group as Yukaformer M-75 (Mitsubishi Chemical Co., Ltd.) Ethyl betaine-acrylate copolymer; copolymerized as octyl acrylamide-acrylate-mercaptoethyl butyl amide as commercially available from Amphomer (National Starch and Chemical Co., Ltd.), 146962.doc -29-201039856 Commercially available poly(decylmercaptoethylbetaine) (polytetra-ammonium-50) commercially available as Plas Size L401 (mutual chemical company), etc.; commercially available as Plas Size L440 (mutual chemical company), etc. Mercapto-based acryloylethylbetaine _ gasification methacryl oxime ethyltrimethylammonium A methoxypolyethylene glycol copolymer (polytetra-ammonium-49); a commercially available methyl methacrylate ethyl betaine-mercaptopropene propylene as a Plas Size L450 (mutual chemical company) Styrene ethyl trimethyl ammonium- 2-hydroxyethyl methacrylate copolymer (polytetra-ammonium-48) and the like. Examples of the anionic polymer include synthetic or natural or semi-synthetic anionic polymers. Examples of the synthetic anionic polymer include a polymer or a copolymer obtained by polymerizing an acidic ethylene monomer or a salt thereof, and may also be used. Union. The acid vinyl monomer is a compound having a carboxyl group, a sulfonic acid group, a phosphoric acid group, and a polymerizable ethylene group, and examples thereof include acrylic acid, methacrylic acid, butyric acid, and ethylene benzoic acid. 2, acrylamide 2_ methyl propyl acid, styrene, ethylene acid, propyl methic acid, methacryl fluorenyl gram, 3 methacryl fluorenyl propyl acid, etc. Acid, itaconic acid, cis-butyl diacid, anti-butanyl diacid and other unsaturated dibasic acids and such single vinegar. Further, it is also possible to copolymerize pens with other ethylene monomers which can be copolymerized as other ethylene monomers, and examples thereof include methyl propionate and propionic acid ethylenic acid S, and methyl acrylic acid &quot , methacrylic acid, acetonitrile, styrene, vinyl ether, vinyl acetate, etc. Specifically, it can be cited as a commercially available product as carbomer (as a commercial product (5), (10) 146962.doc -30·201039856 980, Carbopol 981 (Noveon)), Stabileze QM (ISP company), etc. a vinylidene ether/maleic anhydride decadiene crosslinked polymer; a commercially available propionic acid-alkyl methacrylate copolymer as Aculyn 22 (Rohm and Hass), etc. as a natural or semi-synthetic Examples of the anionic polymer include: Sanxianjiao, propyl propyl linquid, carrageenan, sodium alginate, pectin, red algae, gum arabic, ghatti gum, karaya gum Brunei

Welan gum, tragacanth, carboxymethyl cellulose, carboxydecyl hydroxyethyl cellulose, and the like. Examples of the nonionic polymer include natural, semi-synthetic or synthetic nonionic polymers. Examples of natural nonionic polymers include cellulose, guar gum, agar, and starch. As a semi-synthetic non-ionic poly. The substance may, for example, be methyl cellulose, ethyl cellulose, phenylethyl cellulose, hydroxypropyl cellulose or hydroxypropyl methyl cellulose. The synthetic nonionic polymer 'is exemplified by polypropylene decylamine, polyacrylic acid ethene, polyhexenol, polyethylene diacetate, polypropylene glycol, polyoxyethylene-polyoxypropylene copolymer, and the like. Among these polymers, 'preferably as a polymer or copolymer of diallyl 4 base salt, poly quaternary _6, poly quaternary ammonium -7, poly quaternary 22 · poly 4 Grade ammonium · 39, especially good is the fourth grade of money, as a commercial product - 〇) and poly quaternary ammonium _ 22 (as the heart of the market (four) 295). [Cational surfactant] Further, in the "second invention", in the two-agent type dyeing agent of the first agent and the second agent, the mixture of the oil emulsion is bubbled at G*=50~ Within the range of 6〇〇 146962.doc • 31 - 201039856 and the formation of a stable foam, the bath in ★ 2 is more than 1 亦 will not drip when used, and from the root of the hair J wood main pick From the point of view, 'the better 疋 mixed liquid contains 〇~5 詈k π / 〇 more preferably 0·1~4% by mass, especially preferably 0.5~3 mass 〇/0 嗒 2 2 % ionic surfactant. The above effects can be obtained especially when used in combination with the following anionic surfactant. As a cation interfacial activity, it is known that a single long-chain alkyl group is a four-stage singularity. Specifically, it can be listed as a ruthenium, prepared, cyanide, cetyltrimethylammonium chloride, stearyl dimethyl Money, chlorinated behenyl dimethyl #一俞丞 monomethylammonium, etc., more preferably chlorinated stearin

Base 曱 曱 钱 、 、 氯化 = = = = = = = = = = = = = = # # As a commercial product of a cationic surfactant, it can be listed as ^ ^ ^ · Q ar amin 86W, Quartamin 86Ρ Cone, Quartamin 60W (made by Huawang Company on the Helmet r τΑ 1), Nikkol CA-2580 (Nih〇) n "Second Invention" In the "second invention", in order to make the bubble of the mixture of the second agent and the second agent: = 5 〇 ~ _, it is preferable to satisfy the above i) Oily agent

Amount, ii) a combination of a water-soluble polymer I 1 111) a content of a cationic surfactant. Among the three conditions i), a better and a wilder one meets one of the other two conditions, particularly preferably All three conditions are met. [Surfactant] In the second invention, the bubble is easily formed by mixing the air with the hair cosmetic by the bubble outlet mechanism of the non-aerosol foaming container, and the bubble is stabilized. In addition to the above-mentioned cation interface activity (4) m, either or both of the agent and the second agent may contain a negative surfactant, a surfactant, or a nonionic surfactant. As an anionic surfactant, a pyridyl sulfate, a base is called 146962.doc • 32· 201039856

硫酸 Sulfate surfactants such as sulfate; fatty acid salts, Ν-mercaptoamino acid salts (Ν-mercaptomusine, Ν-mercapto glutamate, Ν-mercapto-glycinate, etc.) a oxonium-fluorenyl-hydrazine-alkylamino acid salt, an alkyl succinate or a succinic acid salt, an alkyl ether carboxylate, a fatty acid guanamine ether acetate, etc.; Phosphate ester surfactants such as phosphates, alkyl ether phosphates; sulfosuccinates, isethionates, taurates, alkyl acid sulphonates, alpha olefin sulfonates, alkane sulfonic acids An anionic surfactant such as a sulfonic acid surfactant such as a salt. Examples of the salt include sodium, potassium, lithium, ethanol, and various salts such as 'monoethanolamine and diethanolamine (hereinafter referred to as TEA). Preferably, the alkyl sulfate or polyoxyalkylene alkyl sulfate is preferably a carbon number of the alkyl group of 10 to 24, particularly preferably a carbon number of 12 to 18, and more preferably The 疋shai burning base is a direct key. Further, more preferred is a polyoxyalkylene alkyl sulfate, particularly preferably a polyoxyalkylene ethyl sulfate, wherein it is preferred that the average molar addition of the oxygen to the ethyl group is 丨~ 1〇, especially good is 2~5. Further, N-decylamino acid salt, N-fluorenyl-N-alkylamino acid salt, and ether carboxylate are also preferred. Here, 'as the amino acid residue of the (IV)-based amino acid salt, acetamino acid, aspartic acid, etc. can be cited as 'amino acid residues of N•nonyl-n•alkylamino acid salt'. Examples thereof include glutamic acid, glycine, and amphetamine. Further, examples of the alkyl group of the indenyl-fluorenyl-fluorene-alkylamino acid salt include a methyl group, an ethyl group, a propyl group, and a propyl group. Further, it is preferred that the carbon number of the base of the (tetra) s-amino acid salt of the hydrazine-bromide-mulyl amino acid salt is 1 as a preferable specific example, and the hydrazine, the amide group (IV) can be escaped. Laurel lysine 146962.doc -33- 201039856 salt, N-myristyl decyl amide, N_cocoyl decyl amide, etc., N_ aryl-N-alkylamino acid salt Examples thereof include N_lauryl _N_isopropylglycinate, N-lauroyl sarcosinate, N_myristyl sarcosinate, N-palmitory sarcosinate, N-lauroyl _N_mercapto_β_alanine and the like. As the mystery carboxylate, a polyglyceryl alkyl ether acetate or an ether acetate represented by the following formula (1): RZ-(CH2CH20)a-CH2C02Y (1) [wherein R represents a carbon number of 7~ a linear or branched alkyl or alkenyl group of 19,

Not -〇- or -CONH-, Y represents a hydrogen atom, an alkali metal, a triethanolamine or a 'a represents a number from 1 to 20]. Among the above ether acetates, it is preferred that the carbon number of R is from 10 to 18, more preferably from 11 to 15. Further, a is preferably from 3 to 15, and particularly preferably from 6 to 丨2. Specific examples thereof include: #oxy-extension ethyl (10) lauryl ether acetic acid (RC丨2H25, z=-〇_, a=1〇 in the formula (1)), polyoxy-extension ethyl (8) myristate ether acetate ( In the formula (1), R = Cl4H29, z, a = 8), lauric acid polyoxyethylene (6) mystery acetic acid (in the formula (1), R = cllH23, z = CONH, a = 6), lauric acid Polyoxyethylene (10), and acetic acid (in the formula (1), R = CmH23, Z = -CONH-, a = i 〇) and the like. Further, the degree of neutralization is preferably from 60 to 120%, and as the relative ion γ, a preferred alkali metal is preferably potassium. Examples of the acetate include polyethylidene lauryl ether acetate and polyoxyethylidene ether acetate. Examples of the salt include a sodium salt and a potassium salt. The anionic surfactant is also used in combination with two or more kinds, and the content of the first agent and the second agent is preferably 疋0·01~8 by 1%, more preferably 〇1~6 146962. Doc -34- 201039856 % by weight, especially preferably 1 to 5% by weight. Examples of the amphoteric surfactant include a carbonyl betaine having a carbon group of 8 to 24, an alkenyl group or a mercapto group, a guanamine betaine system, a contiguous betaine system, and a hydroxysulfobetaine system. A guanamine sulfobetaine system, a phospholipid test system, and an imidazolium-based surfactant; among them, a succinyl betaine surfactant and a sulfobetaine surfactant are preferred. As a preferred amphoteric surfactant, lauric acid propylamine betaine, coconut oil

Fatty acid guanamine propyl betaine, lauryl dimethyl amino acetic acid betaine, lauryl hydroxy sulfobetaine, and the like. The amphoteric surfactant may be used in combination of two or more kinds, and the content of the first agent and the second agent is preferably 0.001 to 5% by weight, more preferably ο.ομμ% by weight, particularly preferably 0.01. ~0.4% by weight. As a nonionic surfactant 1, it is an alkyl polyglucoside, a polyoxyalkylene group, and the like. As the polydextrose bud, it is preferred that the alkyl group has a carbon number of 8 to 18, more preferably 8 to 14, particularly preferably 9 to 1; more preferably, the alkyl group is Straight chain. The average of glucose: The better combination is Bu 5, especially the Bu 2. As the polyoxyalkylene alkyl ether, it is preferred that the alkyl group has a carbon number of 10 to 22, particularly preferably i2 to i8, and preferably (d) the alkyl group is a linear one. χ, more (4) is a polyoxyethylene ethyl sulphate scale, # is better is the average addition molar number of oxygen ethyl ester: 1 ~ 40, especially good 4 ~ 3 〇. The hexanyl glyceryl ether is preferably an alkane number of from 8 to 18, particularly preferably from 8 to 12, and more preferably, the alkyl group is a branched chain. In the "second invention", the nonionic surfactant may be used in combination of two or more kinds, and the content of the mixture of the first agent and the second agent is 146962.doc • 35· 201039856 1 5 weight "/ ' and further It is 44 to 8% by weight, and it is particularly preferable that [the spectreed oxygen type] in the second invention, in the case of the spray-type 1 type of hair, it is possible to maintain the bubble for a long time, In the mixed liquid containing the first agent and the second agent, the hair is smoothly and affinity-affected to the hair, and the hair is adjusted to the hair, and the poly-stone is also contained in the range of Juxixi oxygen, can be listed as · dimethyl poly, methyl phenyl modified poly-crushed oxygen, amine-based modified poly-rich ... Lin modified (four) and other 'suppressed surfactants to make these scattered in the water /night, in the case of not using the tackifier, it can be stably dispersed in the water. _ Point & a h, M · point and Lu 'Car father is good to scream and change the boulder eve Milk, amine-based modified polyfluorene and these emulsions. Polyether modified poly-oxygen includes end-modification and side-chain modification, such as side comb type), two-end modification, single-end modification Qualitative type. As such a 'kappa oxy-oxygen, dimethyl oxazepine-methyl (polyoxy-extended ethyl) shixi 2' element, polymer, -methyl shixi oxygenator _ methyl (Polyoxyl extended propyl) Shixi oxygen institute copolymerization X, dimethyl shixi oxygenator-methyl (polyoxy-extension ethyl _ poly-extension propyl) Shixi oxygen burning total = object, etc. as a poly-shock modification Polyphenylene oxide has a hydrolytic HLB (Hydrophilic-lipophilic balance) of 10 or more in terms of compatibility with water, and particularly preferably (4) is fine. This B is based on thirst. The value obtained by the point (cloud point: the index related to hlb, applied to the ether type nonionic surfactant) is obtained as an amine-based modified polysulfide, as long as it has an amine group or a money base. 146962.doc -36 - 201039856 It is preferred that the amino group is a 1P polyoxane. When the content of the polyoxo oxygen in the first agent and the second agent is added to the liquid, the case is added to the liquid. And for the hair to ride higher: make the bubble smooth and friendly under the head, preferably 0.005~lf Dan. / It is better to 2% by mass in [medium]. Especially good is 0.01~0.5 quality %. Right second invention "in the two formulas of the wood wool jealous cold agent, water and optionally

Organic/treat as a medium. As the ancient glutinous rice, 々才 I, as an organic gluten agent, may be exemplified by lower alcohols such as ethanol and 2-propanol, and aromatic alcohols such as benzyl alcohol and 7-m-benzyloxyethanol, propanol, and 1 , 3-butanediol, two 7

Polyhydric alcohols such as hydrazine, glycerin, ethyl cellosolve, butyl cellosolve, benzyl A. ^ 卞I, synthesizer 荨 cellosolve, carbitol, butyl carbitol and other carbitol. In the "second invention", the test, the nitrogen peroxide, the dye, other optional components, the pH, the viscosity, the gas-liquid mixture ratio, and the method of use are completely the same as those of the "first invention" described above. EXAMPLES Examples 1 to 11 and Comparative Examples 1 to 4 The first agent and the second agent having the blending composition (% by mass) shown in Tables 1 to 3 were prepared and mixed at a mass ratio of 1.5 to 1.5 to prepare a mixed solution. These "sprayability", "dropping suppression effect" and "decoloring power" were evaluated. The results are shown together in Tables 1 to 3. In addition, 'as a foaming container' is a squeeze foamer (Dahe Can Co., Ltd.' S1 extrusion foamer, the mesh thickness is 150 mesh of the mixing chamber, 200 mesh at the front end, and the narrowest part of the air introduction path. The total area of the opening area is 146962.doc -37- 201039856 0.27 mm2, and the inner diameter of the impregnation is adjusted to adjust the stability of the bubble or the burning of the bubble. In Examples 1 to 6 and Comparative Examples 1 to 4, η ^ is 2. 〇 mm, and in Examples 7 to u is y 7 瓜 ^). The squeezed flexible container is made of τ μ 1糸, which is made of propylene and has an internal volume of 210 mL. (Evaluation method) • Spontaneous (foaming property) of the sputum

The mixture was placed in a foaming container of g:h A erect, and the bubbles ejected by the extrusion were visually observed by three inspectors, and evaluated by the following criteria. Tables 1 to 3 show that if two or more of the above-mentioned mussels are not used, or if the evaluation of the three digits is different, an intermediate evaluation is made. A: uniform and delicate bubble B: substantially uniform and delicate bubble C: slightly thicker texture bubble D. produces a portion where no bubble is formed, mixed with liquid/dropping suppression effect for each of the fourth embodiment, respectively Prepare four short hair wigs that cut the hair along the collar (Beaulax, Ng 775Sm 整体 total hair volume of about 70 g). Add the mixture to the foam container of the vertical position, apply 50 mwg of the sprayed bubble to the wig, and observe the presence or absence of dripping after 3 minutes. There is a slight A in the case of applying 100: even if it is applied 1 〇〇g, there is no dripping liquid B: even if 85 g is applied, there is no drop of liquid c: even if 70 g is applied, there is no dripping liquid to apply 85 g, there is a slight 146962. Doc -38- 201039856 Drop D: Even if 50 g is applied, there is no dripping. When 7 〇g is applied, there is a slight drop of liquid E. When 5 〇g is applied, there is dripping. Decoloring force 〇 According to the above drip suppression Evaluation of the effect, the bath ratio (the amount of hair: the mass ratio of the amount of foam of the mixed solution) was changed, and the decolorizing power in the case where the amount of the drip-free liquid was applied to each of the examples and the comparative examples was compared. The bath based on the evaluation of the drip suppression effect is as follows. Evaluation A is bath ratio 丨: 丨4, evaluation B is bath ratio 丨: 12, evaluation C is bath ratio 1: 丨, evaluation d is bath ratio 丨: 〇 7, and evaluation E is bath ratio 丨: 〇 5. The evaluation of the decolorizing power was carried out by spraying a decoloring agent of each mixed solution in the form of a bubble onto a 10 g Chinese black straight hair at a predetermined bath ratio, and standing in a constant temperature tank of 3 Torr for 30 minutes. Then, after washing in 4 (rc warm water, shampooing, hair care, 'drying with a hair dryer.) By comparing the brightness of the hair according to the standard, the three-person inspector enters A: a standard Bright multi-B: lighter than standard c: lighter than standard D: roughly equivalent to standard E: visual observation according to standard dark line, silk is evaluated according to the following criteria. Table (1) shows the following on the U-bit Evaluation, or the difference between the tops of the three figures shows 4 pings in the middle. 146962.doc -39- 201039856 [Table η

EXAMPLES Comparative Example (% by mass, all contents are effective ΐ) 1 2 3 4 1 2 First dose of ammonia 1.68 1.68 1.68 1.68 1.68 1.68 Ammonium hydrogencarbonate 10.5 10.5 10.5 10.5 10.5 10.5 (8) Gasified stearyl trimethylammonium 0.06 0.11 0.22 0.45 0 0.03 (B) Polyoxyethylene ethyl (2) sodium lauryl ether sulfate 2.7 2.7 2.7 2.7 2.7 2.7 fluorenyl poly(1.4) glucoside 6.2 6.2 6.2 6.2 6.2 6.2 polyoxylated ethyl (23) lauryl ether 2.0 2.0 2.0 2.0 2.0 2.0 Polyoxyethylene ethyl (9) tridecyl ether 0.5 0.5 0.5 0.5 0.5 0.5 Myristyl 0.2 0.2 0.2 0.2 0.2 0.2 Gasified dimethyl diallyl money-acrylamide copolymer (*1) 0.5 0.5 0.5 0.5 0.5 0.5 gasified dimethyl diallyl money-acrylic acid copolymer (*2) 0.5 0.5 0.5 0.5 0.5 0.5 propylene glycol 4.0 4.0 4.0 4.0 4.0 4.0 ethanol 9.5 9.5 9.5 9.5 9.5 9.5 anhydrous sodium sulfite 0.5 0.5 0.5 0.5 0.5 0.5 water (the first agent is the total amount of 100) Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount 2nd agent hydrogen peroxide 5.7 5.7 5.7 5.7 5.7 5.7 (B) Polyoxyethylene (2) Sodium lauryl sulfate 0.62 0.62 0.62 0.62 0.62 0.62 Myristyl 0.48 0.48 0.48 0.48 0.48 0.48 Cetearyl alcohol 0.28 0.28 0.28 0.28 0.28 0.28 8-hydroxyquinoline sulfate 0.04 0.04 0.04 0.04 0.04 0.04 Etidronic acid 0.08 0.08 0.08 0.08 0.08 0.08 sodium hydroxide *3 *3 *3 *3 *3 *3 Water (the second dose is the total amount of 100) Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount The content of the component (A) in the mixed solution (% by mass) 0.024 0.044 0.088 0.18 0 0.012 Content of component (B) in the mixed solution (% by mass) 1.452 1.452 1.452 1.452 1.452 1.452 Mass ratio (B)/(A) 60.5 33 16.5 8.1 - 121 Viscosity of mixed solution (25 ° C, niPa-s) 12 12 12 12 12 12 Ejection Β Β Β Β Β Β Evaluation of drip suppression effect Β Β Β DD DD Decolorization power Β Β Β DD *1 : Merquat550 (Nalco) *2 : Merquat280 (Nalco) *3 : Adjust the pH of the second agent to 3.5. 40-146962.doc 201039856 [Table 2]

(% by mass; all contents are effective amounts) Example Comparative Example 5 6 3 4 First dose of ammonia 1.68 1.68 1.68 1.68 Ammonium hydrogencarbonate 10.5 10.5 10.5 10.5 (B) Polyoxyethylene ethyl (2) sodium lauryl ether sulfate 2.7 2.7 2.7 2.7 Mercapto poly(1.4) glucoside 6.2 6.2 6.2 6.2 Polyoxyethylene ethyl (23) lauryl ether 2.0 2.0 2.0 2.0 Polyoxyethylene ethyl (9) tridecyl ether 0.5 0.5 0.5 0.5 Myristyl 0.2 0.2 0.2 0.2 Didecyl diallyl ammonium chloride-acrylamide copolymer (*1) 0.5 0.5 0.5 0.5 Gasified dimercaptopropyl ammonium-acrylic acid copolymer (*2) 0.5 0.5 0.5 0.5 Propylene glycol 4.0 4.0 4.0 4.0 Ethanol 9.5 9.5 9.5 9.5 edetate tetrasodium salt dihydrate 0.1 0.1 0.1 0.1 water (to make the first agent a total of 100) Residual amount remaining amount remaining amount of the second dose of hydrogen peroxide 5.7 5.7 5.7 5.7 (8) Gasified stearyl trimethylammonium 1.1 - - - (VIII) Gasification cetyltrimethylmethane - 1.1 - - (VIII), gasified dialkyl (12-18) dimethylammonium - - 1.1 - (A)' gasified benzyl alkyl (12-16) dimethyl ammonium - - - 1.1 8- 喧 硫酸 硫酸 sulfate 0.04 0.04 0.04 0.04 etidronic acid 0.0 8 0.08 0.08 0.08 sodium hydroxide*3 *3 *3 *3 water (the amount of the second agent is 100 in total) Residual amount remaining amount Remaining amount Residual amount of the component (A) in the mixed solution (% by mass) 0.66 0.66 0.66 0.66 Content of component (B) in the mixed solution (% by mass) 1.08 1.08 1.08 1.08 Mass ratio (B)/(A) or (B)/(A)' 1.6 1.6 1.6 1.6 Viscosity of mixed solution (25° C, mPa_s) 12 12 12 12 Evaluation of spouting BBCC drip suppression effect BBDD Decolorization force BBDD *1 : Merquat550 (Nalco) *2 : Merquat280 (Nalco) *3 : Adjust the pH of the second dose to 3.5 The amount -41 - 146962.doc 201039856 [Table 3]

(% by mass; all contents are effective amounts) Example 7 8 9 10 11 First dose of ammonia 1.68 L68 1.68 1.68 1.68 Monoethanolamine 2.4 2.4 2.4 2.4 2.4 Ammonium hydrogencarbonate 8.0 8.0 8.0 8.0 8.0 (B) Polyoxyethylene ethyl ( 5) Sodium lauryl acetate 2.0 2.0 2.0 2.0 2.0 (B) N-cocoyl-L-glutamate 6.0 6.0 6.0 6.0 6.0 Mercapto poly(1.4) glucoside 2.0 2.0 2.0 2.0 2.0 Polyoxygen (23) lauryl ether 2.0 2.0 2.0 2.0 2.0 polyoxyethylene ethyl (9) tridecyl ether 0.5 0.5 0.5 0.5 0.5 myristyl alcohol 0.2 0.2 0.2 0.2 0.2 gasified dimethyl diallyl ammonium-acrylic acid copolymer (*4) 1.2 1.2 1.2 1.2 1.2 Propylene glycol 4.0 4.0 4.0 4.0 4.0 Ethanol 9.5 9.5 9.5 9.5 9.5 edetate tetrasodium salt dihydrate 0.1 0.1 0.1 0.1 0.1 water (the first dose is 1 总计 total) Remaining amount Remaining amount Remaining amount Remaining amount Part 2 Hydrogen peroxide 5.7 5.7 5.7 5.7 5.7 (VIII) Gasification stearyl tridecyl group 0.084 0.21 0.42 0.84 1.82 Polyoxyethylene ethyl (40) cetyl ether 0.55 0.55 0.55 0.55 0.55 Myristyl 0.025 0.025 0.025 0.025 0.025 Cetearyl alcohol 0.088 0.088 0.088 0.088 0.088 8-Calendine Sulfate 0.04 0.04 0.04 0.04 0.04 Etidronic acid 0.04 0.04 0.04 0.04 0.04 Sodium hydroxide or phosphoric acid*3 *3 *3 *3 *3 Water (to make the second agent a total of 100 Quantity) Remaining amount 剩余 remaining amount remaining amount remaining amount remaining amount of the component (A) in the mixed solution (% by mass) 0.0504 0.126 0.252 0.504 1.092 Content of the component (B) in the mixed solution (% by mass) 3.2 3.2 3.2 3.2 3.2 Mass ratio (B) / (A) 63.5 25.4 12.7 6.3 2.9 Viscosity of mixed solution (25 ° C, mPa-s) 40 42 44 48 76 Spraying AAAAA Evaluation of drip suppression effect BAAAA Decolorization force BAAAA *3 : Will The pH of the two doses was adjusted to 3.5. *4: Merquat 295 (Nalco) Examples 12 to 15 The first and second agents shown in Table 4 were prepared in the same manner as the above, with a mass of 1:1.5. After mixing and mixing, the mixture is placed in a squeeze foaming container. The inner diameter of the impregnation tube of the extrusion foamer was φ ΐ 3.3 mm in Example 12 and Example 13, and φ ΐ 6 mm in Example 14 and Example 15. -42- 146962.doc 201039856 The "sprayability", "dropping suppression effect" and "dyeing power" were evaluated in the same manner as above, and the results were all good. [Table 4] (% by mass; all contents are effective amounts) Example 12 13 14 15 First agent (B) Polyoxyethylene ethyl lauryl ether acetate 2.00 2.00 2.00 2.00 (B) Cocoyl glutamine 6.00 6.00 6.00 6.00 Alkyl (8~16) glucoside 2.00 2.00 2.00 2.00 Polyoxyethylene ethyl lauryl ether (23ΕΌ.) 2.00 2.00 2.00 2.00 Polyoxynexyl (9) tridecyl ether 0.50 0.50 0.50 0.50 Kidney Beans Mentha 0.20 0.20 0.20 0.20 Propylene Glycol 4.00 4.00 4.00 4.00 Ethanol 9.50 9.50 9.50 9.50 Gasified dimethyldiallyl-acrylic acid copolymer (Merquat 295, manufactured by NALCO) 1.20 1.20 1.20 1.20 Ammonia 0.84 0.84 1.68 1.68 Carbonated milk 2.50 2.50 8.00 5.25 monoethanolamine - - 2.40 2.40 toluene-2,5-diamine 1.70 1.70 0.11 0.21 p-aminophenol 0.26 0.26 0.15 - resorcinol 1.67 1.67 - - m-aminophenol - - - 0.04 5-aminol Phenol 0.15 0.15 0.48 0.10 Hydrochloric acid 2,4-diaminophenoxyethanol - - - 0.14 Purified water (to make the first agent a total of 100) Remaining amount Remaining amount Remaining amount Residual amount 2nd agent (A) Gasification Stearyltrimethylammonium 0.21 0.42 0.70 0.70 Polyoxyethylene Ethyl (40) Whale Mystery 0.14 0.28 0.46 0.46 Cetyl Alcohol 0.22 0.44 0.74 0.74 Myristyl _ 0.06 0.13 0.21 0.21 Hydroxyethane Diphosphonic Acid 0.03 0.03 0.03 0.03 Sodium Hydroxide or Phosphoric Acid * * * * Nitrogen peroxide 5,7 5.7 5.7 5.7 Purified water (the amount of the second agent is 100 in total) Residual amount Remaining amount Remaining amount Residual amount of the component (A) in the mixture (% by mass) 0.126 0.252 0.42 0.42 Mixture Content (B%) of the component (B) 3.2 3.2 3.2 3.2 Mass ratio (B)/(A) 25.4 12.7 7.6 7.6 Viscosity of the mixed solution (25 ° C, mPa_s) 20 23 28 25

: The pH of the second agent was adjusted to 3.6. Examples 16 to 26, Comparative Examples 5 to 11 The first agent and the second agent shown in Tables 5 and 6 were prepared and placed in a squeeze foaming container - 43 - 146962.doc 201039856, the dynamic viscoelasticity (G, tan δ) is measured by a rheometer for the bubble of the mixed liquid, and the "dropping", "decolorization" and "uniformity of discoloration" are measured. Conduct an evaluation. As shown in Fig. 1, 40 g of the first agent A1 was filled into the first container 2, and 60 g of the second agent A2 was filled into the second container 3 (the container body 4 which also served as a squeeze container; the internal volume 210) In mL). Further, a squeeze foamer 5 (si squeeze foamer manufactured by Daiwa Can Co., Ltd.) was prepared, and the mesh thickness was a mixed chamber ι5 mesh, front end 200 mesh. The total open area of the narrowest portion of the air introduction path was 0.27 mm2 in all measurements. On the other hand, the inner diameter of the impregnation tube is prepared to be φ 1.3 mm, φ 1.6 mm, and φ2 _0 mm. By changing the inner diameter of the read collimator, the amount of liquid mixed in the bubble can be adjusted to adjust the stability of the bubble or the uniformity of the bubble. In each of the examples and comparative examples, the impregnation tube which is most suitable for the uniformity of the bubble is selected. The total amount of the first agent is added to the container body 4 (the first agent: the second agent = 1: 1.5 (mass ratio)), the lid is closed, and the erect state is placed in the inverted state in one second. After the state is returned to the erect state, the operation is repeated one by one, thereby mixing without blistering, and then the squeeze foamer 5 is placed to be in the state of Fig. 2 . The mixed liquid was ejected in a bubble form from the foaming container, and the evaluation shown below was carried out. Furthermore, the same result can be obtained even with a pump foamer. (Method for Measuring Dynamic Viscoelasticity of Bubbles) The dynamic viscoelasticity, tan δ), was measured in the following manner for the bubbles of the mixed liquid which was immediately ejected from the nozzle after the foaming container was extruded. Rheometer: MCR3 manufactured by Paar Physica 146962.doc •44· 201039856 The geometry uses a parallel plate with a diameter of 50 mm and stainless steel. The temperature of the measuring unit was maintained at 30 °C. Measurement order: i• Use a spatula to take a bubble of 4.5 to 5.5 cm3 to the base of the rheometer. 0 2. Adjust the gap to 2 mm' to carefully remove the bubbles that overflow from the base. Ο ❹ 3. After the bubble was allowed to acclimate to the temperature of the measurement unit for 30 seconds, the dynamic deformation scan evaluation was started under the following conditions. Frequency: fixed to 2 1^, deformation: 1 ><1 () - 3 to 1 >< 1 () 3% 4. According to the obtained poor material 'takes the value of the linear region with respect to deformation As tan δ and G*. (Evaluation method of drip) The hair of Wig N〇775S manufactured by BeauUx was cut into short hair in a manner that the hair mass was about 70 g. The quality of the mixture was usually set to 70 g (the same as the hair quality). Bath ratio: mass of the agent/mass of the hair but was set to (10) g (bath ratio = 143) in the evaluation, and was applied after the application, and the generation of the drip with time was evaluated according to the following evaluation criteria. Even if it is left for 45 minutes, it will not drip. 〇. Even if it is left for 30 minutes, it will not drip, but it can be seen for 45 minutes. Liquid △• Even if it is placed for 2G minutes, it will not drop & 'but it will be dripped for 3 minutes. 146962.doc -45- 201039856 χ : Dropping liquid is also visible for 20 minutes. (Evaluation method for decolorization and uniformity of discoloration) The hair of Wig No. 775s manufactured by Beaulax is about 7 〇g of the whole hair. In the manner of cutting into short hair, the mass of the mixture is usually set to 70 g (bath ratio = 1) which is the same as the mass of the hair. However, in the evaluation, it is set to (10) g (bath ratio to spit 43) for application. After a minute _ wash, shampoo, hair care, For ㈣f: Order intake uniformity discoloration and decoloration, said inlet by panelists, the master made and evaluated according to the following criteria evaluation test, Pan

A Good B Slightly better C Slightly worse D Poor 146962.doc i

J 46- 201039856 ο ο [ln<] Example Ό (Ν 2.00 6.00 2.00 2.00 0.50 0.20 4.00 9.50 3.60 | 1.68 I 8.00 2.40 Remaining amount I 0.28 I 0.44 0.13 | 0.03 1 Meal 1 Remaining amount 1 0.58 247.9 <<<<<<<> Ν 2.00 6.00 2.00 2.00 0.50 0.20 4.00 9.50 3.60 8.00 2.40 Remaining amount 0.98 : ! 0.28 1 0.44 I 0.13 0.03 * Bu remaining amount Ο (Ν' 0.56 223.8 <<< 2.00 6.00 2.00 2.00 ; 0.50 I 0.20 I 4.00 | 9.50 II 3.60 I 1.68 I 8.00 | 2.40 I 1 Remaining 1 — 1.40 1 1 1 1 * Bu 1 Remaining I 0.51 139.9 <<<< ΓΛ (Ν 2.00 6.00 2.00 2.00 0.50 0.20 4.00 9.50 1 3.60 1.68 8.00 2.40 I Remaining | | 0.42 | 0.28 1 0.44 0.13 0.03 * Bu remaining amount VO 0.49 174.8 <<<< (Ν 2.00 6.00 2.00 2.00 0.50 0.20 ! I 4.00 | 9.50 1 3.60 ! 1.68 8.00 1 2.40 I Remaining amount L〇-21 0.14 1 0.22 I 0.06 0.03 * Bu 1 remaining amount 0.36 107.6 CQ << 2.00 6.00 2.00 2.00 0.50 0.20 4.00 | 9.50 1 1.20 1.68 I 8.00 | 丨 2.40 1 Remaining amount 1 0.28 0.44 0.13 0.03 meal remaining amount 'Ο 0.58 195.9 < &l t; 2.00 6.00 2.00 2.00 0.50 0.20 : | 4.00 | | 9.50 1 | 1.68 | | 8.00 | 2.40 | 1 Remaining | 0.98 0.28 0.44 0.13 0.03 * Remaining amount ο CN 0.55 180.1 <<< ON 2.00 6.00 2.00 2.00 ! | 0.50 | | 0.20 | | 4.00 | | 9.50 | 1 1.2〇I 1.68 | [8.00 | 2.40 | 1 Remaining I 1.40 1 1 1 1 * Bu remaining amount cn 0.55 127.2 <<<c 〇〇 2.00 6.00 2.00 2.00 0.50 ; 0.20 ί 4.00 | 9.50 1 1 1-2Q 丨1.68 | 8.00 | 2.40 | Remaining amount! 0.42 0.28 0.44 0.13 0.03 * Γ- wS Remaining amount ΓΟ 1—^ 0.41 126.2 <<< 2.00 6.00 2.00 2.00 0.50 ! | 0.20 i | 4.00 | 1 9.50 ! § I 8.00 I 丨 2.40 | 1 Remaining amount I 0.21 1 0-14 1 0.22 0.06 0.03 * Bu iri Remaining amount 0.47 93.3 PQ << Ό 1 -^ 2.00 6.00 2.00 2.00 0.50 0.20 | 4.00 | 9.50 1 1 I 1.68 | | 8.00 | 2.40 | 1 Remaining | 1 0-42 | 0*28 0.44 0.13 0.03 * Bu remaining 0.62 125.9 C <<%; all content is effective amount) Polyoxyethylene ethyl (5) sodium lauryl acetate, sodium cocoyl sulfonate, sodium citrate alkyl (8 ~ 16) glucoside polyoxyethylene ethyl lauryl ether (23E.O. Polyoxyethylene ethyl (9) tridecyl ether myristyl alcohol 1 propanediol oxime | gasified dimethyl diallyl ammonium-acrylic acid copolymer (Merquat 295, manufactured by NALCO) | hydrogenated monoethanolamine purified water (The first agent is 100) Gasified stearyl trimethylammonium polyoxyethylene ethyl (40) residual wax ether cetyl alcohol myristyl alcohol hydroxyethane diphosphonic acid sodium hydroxide or hydrogen phosphate hydrogen peroxide Purified water (the amount of the second agent is 100) The inner diameter of the impregnated tube (φ mm) tan δ *α Dropping liquid i Decolorization and decolorization uniformity SB rtf ti Evaluation - City (N Wei ί 1^9T^^ S^HCLW A #CN城檠:* 146962.doc • 47· 201039856 [Table 6]

(% by mass; all contents are effective amounts) Comparative Example 5 6 7 8 9 10 11 First dose polyoxyethylene ethyl (5) sodium lauryl acetate 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Cocoyl glutamine sodium 6.00 6.00 6.00 6.00 6.00 6.00 6.00 Alkyl (8~16) glucoside 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Polyoxyethylene ethyl lauryl ether (23E.O.) 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Polyoxyethylene (9) Alkyl ether 0.50 0,50 0.50 0.50 0.50 0.50 0.50 Myristyl alcohol 0.20 0.20 0.20 0.20 0.20 0.20 0.20 Propylene glycol 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Ethanol 9.50 9.50 9.50 9.50 9.50 9.50 9.50 Gasified dimethyl diallyl ammonium-acrylic acid Copolymer (Merquat 295, manufactured by NALCO) - 1.20 1.20 1.20 3.60 3.60 3.60 Ammonia 1.68 1.68 1.68 1.68 1.68 1.68 1.68 Ammonium bicarbonate 8.00 8.00 8.00 8.00 8.00 8.00 8.00 Monoethanolamine 2.40 2.40 2.40 2.40 2.40 2.40 2.40 Purified water (1st The amount of the agent is 100.) Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount 2nd agent Gasification stearyl trimethylammonium 0.08 - 0.08 0.56 - 0.08 0.56 Polyoxyethylene (40) whale Ether 0.06 - 0.06 - - 0.06 - Cetyl alcohol 0.09 - 0.09 - - 0.09 - Myristyl 0.03 - 0.03 - 0.03 - Hydroxyethane diphosphonic acid 0.03 - 0.03 - - 0.03 - Sodium hydroxide or phosphate fortunately wood* This hydrogen peroxide 5.7 5.7 5.7 5.7 5,7 5.7 5.7 Purified water (the amount of the second agent is 100) Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Iriding tube inner diameter (φ mm) 1.3 1.6 1.3 1.3 1.6 1.6 1.6 Dynamic viscoelasticity tan5 0.78 0.26 0.35 0.43 0.20 0.27 0.34 G* 20.2 37.0 31.0 37.1 38.8 44.8 44.4 Evaluation of dripping DCCCCCC Decolorization AAAAAAA Decolorization uniformity AAAAAAA * : Adjusting the pH of the second agent to 3_6 Examples 27 to 30 The first agent and the second agent shown in Table 7 were prepared and placed in an extrusion foaming vessel in the same manner as described above, and the bubble of the discharged mixture was measured by a rheometer. Dynamic viscoelasticity (G*, tan δ). Further, the "dropping liquid", "dyeability" and "uniformity of dyeing" were evaluated in the same manner as above, and the results were all good. •48- 146962.doc 201039856 [Table 7]

(% by mass; all contents are effective amounts) Example 27 28 29 30 First dose polyoxyethylene ethyl lauryl ether acetate 2.00 2.00 2.00 2.00 Cocoyl glutamine sodium 6.00 6.00 6.00 6.00 alkyl (8~16 Glucosin 2.00 2.00 2.00 2.00 Polyoxyethylene ethyl lauryl ether (23E.O·) 2.00 2.00 2.00 2.00 Polyoxyethylene ethyl (9) tridecyl ether 0.50 0.50 0.50 0.50 Myristyl alcohol 0.20 0.20 0.20 0.20 Propylene glycol 4.00 4.00 4.00 4.00 Ethanol 9.50 9.50 9.50 9.50 Gasified dimethyl diallyl ammonium-acrylic acid copolymer (Merquat 295, manufactured by NALCO) 1.20 1.20 1.20 1.20 Ammonia 0.84 0.84 1.68 1.68 Ammonium bicarbonate 2.50 2.50 8.00 5.25 Monoethanolamine - - 2.40 2.40 A stupid-2,5-diamine 1.70 1.70 0.11 0.21 p-aminophenol 0.26 0.26 0.15 - resorcinol 1.67 1.67 - - m-aminophenol - - - 0.04 5-amino-o-nonylphenol 0.15 0.15 0.48 0.10 hydrochloric acid 2,4-Diaminophenoxyethanol - - - 0.14 Purified water (the amount of the first agent is 100) Remaining amount Remaining amount Remaining amount Residual amount 2nd agent gasification stearyl tridecyl ammonium 0.21 0.42 0.70 0.70 polyoxy-extension ethyl (40) recorded wax ether 0.14 0.28 0.46 0.46 cetyl alcohol 0.22 0.44 0.74 0.74 myristyl 0.06 0.13 0.21 0.21 hydroxyethane diphosphonic acid 0.03 0.03 0.03 0.03 sodium hydroxide or tartaric acid * wood * * hydrogen peroxide 5.7 5.7 5.7 5.7 purified water (making the second agent Remaining amount remaining amount remaining amount of the inner diameter of the impregnation pipe (Φ mm) 1.3 1.3 1.6 1.6 Dynamic viscoelasticity tan δ 0.48 0.55 0.54 0.56 G* 53.4 197.7 232.2 265.4 * : pH of the second agent The value was adjusted to 3.6. Comparative Example 12 (Removal of the dye from the formulation of Table 3 of JP-A-2004-339216) Preparation of a two-agent hair dye containing the first agent and the second agent of the following formulation It was placed in the above-mentioned extruded foam container at a mass ratio of 1:1.5. The inner diameter of the impregnation tube is set to φ2·0 mm (all the same below). Then, the dynamic viscoelasticity was measured in accordance with the above method. As a result, G, 36.8, and tan δ = 0.30. -49- 146962.doc 201039856 1st agent (% by mass) Strong ammonia water (28% by mass) 8.0 Ammonium hydrogencarbonate 14.0 Ethyl p-hydroxybenzoate 0.1 Perfume 0.5 Ascorbic acid 0.3 Anhydrous sodium sulfite 0.4 Water remaining amount 2nd agent (Quality %) Polyoxyethylene ethyl (2.5) sodium lauryl ether sulfate 1.9 Laurel propyl propyl betaine 0.05 Lauryl hydroxy sulphobetaine 0.05 Lauric acid 0.04 Phosphoric acid (75% by mass) Adjust the pH of the second agent to 3 8 glycerol 30.0 hydrogen peroxide water (35 mass%) 16.3 water remaining amount Comparative Example 13 (manufacture of the dye removed from the formulation of Example 1 of JP-A-2006-124279) Preparation The following formulation was prepared. The first dose and the second dose of the two-part dyeing agent were placed in the above-mentioned extruded foam container at a mass ratio of 1:1.5, and the dynamic viscoelasticity was measured in accordance with the above method. As a result, G, 11.3, and tan δ = 0.92. First dose (% by mass) Strong ammonia water (28% by mass) 8.5 146962.doc •50· 201039856 Carbonic acid nitrogen 8.0 Mercapto poly(1.4) glucoside 3.2 Polyoxyethylene ethyl (23) lauryl ether 2.0 Propylene glycol 4.0 Chlorination Dimethyldiallyl ammonium-acrylic acid copolymer 0.4 Polyether modified polyfluorene (KF6005, manufactured by Shin-Etsu Chemical Co., Ltd.) 1.0

Ethyl p-hydroxybenzoate ^ edetate tetrasodium salt dihydrate perfume ascorbic acid anhydrous sodium sulfite water 2nd agent polyoxyethylene ethyl (2.5) lauryl ether sulfate sodium lauryl propylamine betaine lauryl hydroxy sulfobetaine Lauric acid benzyl alcohol 1-hydroxyethane-1,1-diphosphonic acid phosphoric acid (75% by mass) Sodium hydroxide liquid (48% by mass) Sulfuric acid modified by quinone-amine-based polyoxyl (SM8704C, 0.1 0.1 0.5 0.3 0.4 Remaining amount (% by mass) 1.9 0.05 0.05 0.04 1.5 0.04 Adjust the pH of the second agent to 3.8. 0.01 0.04 1.0 Toray Dowing Co., Ltd.) 146962.doc -51 - 201039856 Glycerin 5.0 Hydrogen peroxide water (35 mass%) 16.3 Water remaining amount Comparative Example 14 (Removal of the dye from the formulation of Example 5 of JP-A-2006-124279) Preparation of the first agent and the second formulation containing the following formulation The two-part dyeing agent was placed in the above-mentioned extruded foam container at a mass ratio of 1:1.5, and the dynamic viscoelasticity was measured according to the above method. As a result, G, 43.8, and tan δ = 0.39. First agent (% by mass) Strong ammonia water (28% by mass) 8.5 Hydrogen carbonate 8.0 Mercapto poly(1.4) glucoside 3.2 Polyoxyethylene ethyl (23) lauryl ether 2.0 Propylene glycol 4.0 Dimethyl diallyl chloride Ammonium-acrylic acid copolymer 0.4 Polyether modified polyfluorene (KF6005, manufactured by Shin-Etsu Chemical Co., Ltd.) 1.0 Methyl p-hydroxybenzoate 0.1 Tetrasodium edetate dihydrate 0.1 Perfume 0.5 Ascorbic acid 0.3 Anhydrous sodium sulfite 0.4 Water Remaining amount 2nd agent (% by mass) Polyoxyethylene ethyl (2.5) sodium lauryl ether sulfate 1.9 146962.doc -52 201039856 Laurolide propyl betaine 0.05 Laurol hydroxysultaine 0.05 Lauric acid 0.04 Recording alcohol 2.25 1-Hydroxyethane-1,1-diphosphonic acid 0.04 Phosphoric acid (75% by mass) The pH of the second agent was adjusted to 3.8. The amount of sodium hydroxide liquid (48% by mass) 0.01 Sulfuric acid via π 奎奎琳 0.04 Amine-based modified polyfluorene (SM8704C, 1.0 manufactured by Toray Dow Corning Co., Ltd.) Glycerin 5.0 Hydrogen peroxide water (35 mass%) 16.3 Water remaining amount Comparative Example 15 (Comparative Example from Japanese Patent Laid-Open Publication No. 2007-29101 No. 5) The formula for removing the dye in the formulation of 2) The first side of the two agents of formula 2 of the hair dye, a mass ratio of 1: Add to squeeze foamer vessel above 1.5, measured dynamic viscoelasticity according to the above method. As a result, G+ = 20.0 and tan δ = 0.70. First dose (% by mass) Strong ammonia water (28% by mass) 6.0 Ammonium hydrogencarbonate 10.0 Mercapto poly(1.4) glucoside 23.8 Propylene glycol 4.0 Tetraic acid tetrasodium salt dihydrate 0.1 146962.doc -53- 201039856 Ascorbic acid 0.4 Anhydrous Sodium sulfite 0.5 Water remaining amount 2nd agent (% by mass) Hydrogen peroxide water (35 mass%) 16.3 Polyoxyethylene ethyl (2.5) sodium lauryl sulfate 2.8 Recording pterol 0.6 8-Salina sulfate 0.03 1-hydroxyl Ethane-1,1-diphosphonic acid 0.08 Sodium hydroxide The pH of the second agent was adjusted to 3.5. The amount of water remaining Comparative Example 16 (Comparative Example 4 of JP-A-2007-291 01 5) To remove the dye from the formulation) Prepare a two-part hair dye containing the first agent and the second agent of the following formulation, and put it into the above-mentioned extruded foam container at a mass ratio of 1:1.5, and measure the dynamic viscosity according to the above method. elasticity. As a result, G* = 23.0 and tan 5 = 0.47. First dose (% by mass) Strong ammonia water (28% by mass) 6.0 Carbonic acid nitrogen money 10.0 Mercapto poly(I.4) glucoside 8.5 Propylene glycol 4.0 edetate tetrasodium salt dihydrate 0.1 Ascorbic acid 0.4 Anhydrous sulfite 0.5 146962 .doc -54- 201039856

Water remaining amount 2nd agent (% by mass) Hydrogen peroxide water (35 mass%) 16.3 Polyoxyethylene ethyl (2.5) sodium lauryl ether sulfate 1.0 Recording alcohol 2.0 8-Calendine sulfate 0.03 1-Hydroxyethane -1,1-diphosphonic acid 0.08 sodium hydroxide The pH of the second agent was adjusted to 3.5. The amount of water remaining. Comparative Example 17 (Removal of the dye from the formulation of Example 1 of JP-A-2007-291016 A two-part type hair dye containing the first agent and the second agent of the following formulation was prepared and placed in the above-mentioned squeeze foam container at a mass ratio of 1:1.5, and dynamic viscoelasticity was measured according to the above method. The result is G* = 18.0 and tan 5 = 0.34. First dose (% by mass) Strong ammonia water (28% by mass) 8.0 Ammonium hydrogen phosphate 14.0 Mercapto poly(1.4) glucoside 3.2 Polyoxyethylene ethyl (23) lauryl ether 2.0 Methylparaben 0.1 Fragrance 0.5 Water Remaining amount 2nd agent (% by mass) Gasified triterpene stearyl bond 1.2 146962.doc •55- 201039856 Phosphoric acid (75% by mass) Adjust the pH of the second agent to 3.8 glycerol 3.5 Hydrogen peroxide water (35 mass%) 16.3 Water remaining amount Comparative Example 18 (manufacture of the dye removed from the formulation of Example 2 of JP-A-2007-291 016) Preparation of the first agent and the second agent containing the following formulation The agent type hair dye was placed in the above-mentioned extruded foam container at a mass ratio of 1:1.5, and the dynamic viscoelasticity was measured in accordance with the above method. As a result, G, 20.0, and tan δ = 0.63. First dose (% by mass) Strong ammonia water (28% by mass) 6.0 Hydrogen carbonate 1 amp 10.0 Mercapto poly(1.4) glucoside 11.0 Polyoxyethylene ethyl (23) lauryl ether 1.0 Propylene glycol 4.0 Dimethyl propylene dichloride Alkyl ammonium-acrylamide copolymer 0.5 dinadiium salt dihydrate 0.1 ascorbic acid 0.4 anhydrous sodium sulfite 0.5 perfume 0.5 water remaining amount second agent (% by mass) hydrogen peroxide water (35 mass%) 16.3 chlorination Stearyltrimethylammonium 0.3 146962.doc -56 201039856 Gasified dialkyl (12-18) dimethylammonium monodecyl polysulfide (20 mm2 / s) cetyl stearyl alcohol 1- Hydroxyacetone-1,1-diphosphonic acid hydroxide steel 0.1 0.01 0.4 0.2 0.08 Adjust the pH of the second agent to 35

Comparative Example 19 (manufacture of the dye removed from the formulation of Example 5 of JP-A-2007-3 14523) Preparation of a two-part hair dye comprising the first agent and the second agent of the following formulation in a mass ratio 1 : 1.5 was placed in the above-mentioned extruded foam container, and the dynamic viscoelasticity was measured in accordance with the above method. As a result, G*=26.2 and tan δ=0.27. First dose (% by mass) Strong ammonia water (28% by mass) 6.0 Hydrogen fluoride money 10.0 Mercapto poly(1.4) glucoside 6.0 Polyoxyethylene ethyl (23) lauryl ether 2.0 Propylene glycol 4.0 Ethanol 7.0 Ratified monothiol Propyl ammonium _ acrylamide copolymer 0.5 emulsified monomethyl dimethyl propyl-acrylic acid copolymer 0.4 edetate tetrasodium salt dihydrate 0.1 ascorbic acid 0.3 anhydrous sodium sulfite 0.4 146962.doc -57- 201039856 spice 0.5 Water remaining amount 2nd agent (% by mass) Hydrogen peroxide water (35 mass%) 16.3 Polyoxyethylene ethyl (2.5) sodium lauryl ether sulfate 0.5 Glycerol mono-2-ethylhexyl ether 0.1 Laurolide propyl betaine 0.05 Lauryl by basestone yellow base sweet test 0.05 lauric acid 0.01 recorded butterfly alcohol 0.58 stearyl alcohol 0.15 sulfuric acid via quinine 0.054 1-hydroxyethane-1,1-diphosphonic acid 0.08 sodium hydroxide will be the second agent The remaining amount of water whose pH is adjusted to 3.5 [Simplified description of the drawings] Fig. 1 is a view showing the state before the first agent and the second agent of the two-part hair dye of the present invention are mixed. Figure 2 is a longitudinal sectional view of the squeeze container. [Description of main component symbols] 1 Components of two-component dyeing agent 2 First container 3 Second container 4 Container body for squeezing container 146962.doc -58- 201039856 5 7 8 10 11 12 13 14 Ο 15 16 17 18 A1 Α2 A3 Squeeze foamer cap head mixer gas-liquid mixing chamber air introduction road immersion bulb homogenization mechanism through liquid passage liquid passage spout bubble homogenization mechanism first agent second agent mixture

146962.doc -59

Claims (1)

201039856 VII. Scope of application: 1. A one-part hair dye comprising: a first agent containing a test agent, a second agent containing hydrogen peroxide, and a mixture of the first agent and the second agent The liquid is sprayed into a non-aerosol foaming container; and the mixture contains the following components (A) and (B): (A) Single long chain aliphatic trimethylammonium salt: 0.02 to 1 〇 mass 〇 /〇, (B) Anionic surfactant: 〇·5~1〇% by mass; and the mixture is at 25. (The viscosity underneath is 1 to 300 mPa.s. 〇 2. The dyeing agent according to claim 1 bis, wherein the mass ratio of component (B) to component (A) is (B)/(A) is 1. 〜100. 3. The dyeing agent according to claim 1 or 2, which further comprises a higher alcohol. 4' The dye of the second dosage form according to any one of claims 1 to 3, which further comprises a dilute A polymer or copolymer of a propyl quaternary ammonium salt. 5. A two-part hair dye according to any one of claims 1 to 4, which further comprises a non-volatile hydrophilic solvent. A two-part hair dye according to any one of the items 5, wherein the component (A) is a ruthenium-trimethylammonium salt or a stearyltrimethylammonium salt. - The two-part dyeing agent, wherein the component (Β) is a phthalic acid-based anionic surfactant. 8· * The two-component hair dye of any one of items 1 to 7 is a component ( Α) is separated from the component (Β) and contained in the first agent and the second agent. 9. A two-part hair dye comprising: a first agent containing an alkali agent and a second agent containing chlorine peroxide Agent, U and the mixture of the first agent and the second #丨 are sprayed in a bubble form. a sol-type foaming container; and the dynamic viscoelasticity of the bubble immediately after the mixture is sprayed in a non-aerosol 146962.doc 201039856 type foaming container, when measured by the rheometer under the following conditions, The modulus of elasticity is in the range of 50~600; the setting of the rheometer: The temperature of the measurement unit is maintained at 30 ° C. Measurement order: (1) The bubble of 4·5~5·5 cm3 is taken to the base of the rheometer by the spatula (2). The gap is adjusted to 2 mm. The bubbles overflowing between the susceptors were carefully removed. (3) After the bubbles were allowed to acclimate to the temperature of the measurement unit for 30 seconds, the dynamic deformation scan evaluation was started under the following conditions. The frequency was fixed at 2 Hz, and the deformation was: J χ1 〇3%, (4) According to the value of the obtained data area as G*. It is 0.3~〇·8. 0.3 is linear with respect to deformation The mixture contains 〇.01 to 3 mass% of an oil agent. The agent type hair dye according to any one of claims 9 to 11, wherein the first agent 146962.doc 201039856 and the second agent mixture contain 〇.〇1~3 mass% of water-soluble polymerization. Things. 13. The two-part hair dye according to any one of claims 9 to 12, wherein the mixture of the first and second agents contains 〇5 mass% of a cationic interfacial activity. 14供为... The secondary value (25°c) when mixed with the second agent is 8~12 15·-A hair dyeing method', which is a two-component dyeing agent according to any one of the claims The mixed solution was sprayed from the non-aerosol foaming container in a bubble form, and the foamed mixed solution was applied to the hair sputum and rubbed again on the hair. 146962.doc