TW200939962A - Pesticidal mixtures - Google Patents

Abstract

The present invention relates to synergistic mixtures comprising, as active components, an insecticidal compounds I selected from the nicotinic receptor agonists/antagonists compounds and one or two further fungicidal compounds in synergistic effective amounts.

Description

200939962 VI. Description of the Invention: [Technical Field] The present invention relates to a synergistic mixture comprising a synergistically effective amount of each of the following components as an active ingredient, 1) selected from the following nicotinic receptor agonist/antagonist compounds Insecticidal compound I: acetamiprid, clothianidin, dinotefuran, imidacloprid, "thiamethoxam, boring bite Nitenpyram; and 2) a fungicidal compound II selected from the group consisting of metalaxyl and dimethomorph; and 3) - selected from azoxystrobin, three A fungicidal compound III consisting of trifloxystrobin and oresastrobin. The invention further comprises a binary mixture comprising an insecticidal compound I selected from the group consisting of the following nicotinic receptor agonist/antagonist compounds: acetamiprid, cotinine, bunototerol, imidacloprid, thiophene Oxazine, nitenpyram and daxen (as compound II). The invention further relates to a binary fungicidal mixture comprising dafoxdine and atramine or trifluoro-sensitive as an active component. The above-mentioned mixture is also referred to as "the mixture of the present invention" hereinafter. Further, the present invention relates to a method for controlling pests (which means including animal pests and harmful fungi) using the mixture of the present invention, and Compound I and Compound II and Compound 111 (or (Compound I and Damten) or ( The use of dadphenin and atramine or trifluoro-sensitive) for the preparation of such mixtures, and compositions comprising the mixture of 138197.doc 200939962 and the like. In an embodiment, the invention provides a method of controlling an animal pest, such as an insect, a worm or a nematode, comprising causing the animal pest (Kun or its food source, habitat, breeding ground or its location and insecticidal effective amount = Mixture (except for the binary mixture comprising dafphene as the second component. In addition, in another embodiment, the invention also relates to a method of attacking or infesting insect pests (insects, cocci or nematodes): The plant, or the soil or water in which the plant is growing, is contacted with a pesticidally effective amount of a mixture of the invention (except for a binary mixture comprising dafphene as a second component). A method comprising protecting a plant propagation material from a eucalyptus fungus, comprising: contacting the plant propagation material with an insecticidally effective amount: a mixture of the invention. Further, the invention also encompasses a plant propagation material that is protected from harmful insects Or a method of attack by a nematode comprising contacting a mixture of the invention of the plant propagation material (in addition to a binary mixture comprising dafphene as a second component). The term "plant propagation material" means that all plant germ portions divided / thin such as seeds and vegetative plant propagation material, such as cutting work and the block ㈣㈣ with potatoes), which can be used for plant growth. This includes seeds, root fruits, tubers, bulbs, roots t_ Μ (4), including seedlings and young plants that are intended to be transplanted after germination or after emergence from the soil. Such young plants may also be protected by whole or partial treatment by dipping or pouring 138197.doc 200939962 prior to transplantation. In a particularly preferred embodiment, the term propagation material refers to a seed. Further, the present invention relates to a method for controlling harmful fungi using the mixture of the present invention, and Compound I and Compound II and Compound Hydrazine (or (Compound I and Damfin) or (Dafenfen and Atmomin or Trifluoro Sensitive)) The use for the preparation of such mixtures' and compositions comprising such mixtures. The invention further relates to a plant protection active ingredient mixture having synergistic enhancing effects of improved plant health and a method of applying such a mixture of the invention to a plant. [Prior Art] The compounds of the formulae I, II and III and the insecticidal action thereof and the method for producing the same are generally known. For example, commercially available compounds can be found in The Pesticide

Manual, 13th edition, British Crop Protection Council (2003) and other publications. As used herein, "Delta" is a fungicide comprising: statin; consisting of equal or greater than 50% by weight of the R enantiomer and equal to or less than 5% by weight of the S enantiomer. Destroy; a ruthenium consisting of more than 85 wt% of the enantiomer of r, less than 15% of the s enantiomer; from 92 wt% or more of the R enantiomer and less than 8 % The s-enantiomer consisting of genus; ruthenium consisting of 97% by weight or more of the R enantiomer, 3% or less of the s enantiomer; and mefenoxani (ie , 97.5% or more of the ruthenium or halalol-M and 2.5% or less of the S enantiomer). See for example

Pesticide Manual ’ 11th Edition (1997), The British Crop Protection Council, London, page 792; and pesticide 138197.doc 200939962

Manual, 11th edition (1997), The British Crop Protection Council, London, p. 794. A binary mixture comprising cotinine along with a large number of potential fungicidal mixed conjugates is disclosed in WO 99/63 826. It is disclosed in WO 96/3045 that it generally comprises thiamethoxam and clearly reveals a combination of imidacloprid together with a large number of potential fungicidal mixed conjugates. WO 06/069654, WO 06/089876, and WO 06/23899 disclose a mixture of a neonicotinoid and a strobilurin. WO 06/23 899 also discloses mixtures of imidacloprid with other fungicides. It is known (WO 98/53686, WO 2006/066810, WO 97/42821) a mixture of dasphenein with apigenin, baikemin, oriprozil and kresoxim-methyl. However, specific ternary and binary mixtures of the invention based on Compound I and Compound II and Compound III are not disclosed. In addition, there is no mention of a specific combination of Compound I and dafoxdine as defined above. A typical problem in the field of pest control is the need to reduce the dose rate of the active ingredient to reduce or avoid adverse environmental or toxicological effects while still allowing effective pest control. With respect to the present invention, the term pest includes animal pests and harmful fungi. Another problem faced is the need for pest control agents that are effective against a wide range of pests, such as animal pests and harmful fungi. There is also a need for a pest control agent that combines potent activity with long-term control (ie, rapid action and long-lasting action). 138197.doc 200939962 Another difficulty associated with the use of insecticides is that repeated and specialized application of individual insecticidal compounds in many cases leads to rapid selection of pests (which means that natural or adaptive resistance has been produced for the active compounds in question) Sexual animal pests and harmful fungi). Therefore, there is a need for control agents that help prevent or overcome resistance. • Another problem in this month is the need for a method of improving plant composition, commonly and hereinafter referred to as "plant health." ❹ 胄 Plant health contains various categories/improvements of plants not associated with pest control. For example, 'the advantageous characteristics that can be mentioned are improved crop characteristics' which include: emergene, crop yield, protein content, oil content 3; temple powder content, more developed root system (improved root growth) Improved stress tolerance (eg, resistance to drought, heat, salt, uv, water, cold), reduced ethylene (reduced production and/or inhibition of acceptance), increased drug addition by 7, increased plant height Larger leaves, less dead base leaves, stronger Zinc, more green color, pigment content, photosynthetic activity, require less input (such as fat or water), require less plant propagation material (preferably seed) ), more tillering, early flowering, early grain ripening, smaller plants falling (9) volts, enhanced bud growth, enhanced plant vigor, enhanced plant standing and better and better germination; or Any other potential familiar to those skilled in the art. 'A Summary of the Invention Accordingly, it is an object of the present invention to provide a solution to the problem of reducing the dosage rate and/or enhancing the range of activity and/or combining strong activity with long-term control and/or resistance management and/or promoting plant health. Pesticide mixture. 138197.doc 200939962 We have found that this goal is achieved, in part or in whole, by a complex mixture comprising the active compounds defined at the outset. In particular, it has been found that mixtures as defined at the outset exhibit significantly enhanced pest resistance compared to the possible control rates of individual compounds, and/or when applied to plants, parts of plants, plant propagation material (preferably seeds) Or suitable for improving plant health when it is grown. It has been found that the effects of the mixtures according to the invention are far more durable than the fungicidal and/or insecticidal and/or plant health improving effects of the active compounds present alone in the mixture. In addition, we have found that simultaneous (in combination or independent) administration of the compound oxime and the compound II and the compound III or the continuous administration of the compound and the compound and the compound 111 allow the pest to be compared with the possible control rate of the individual compound (which means the animal Enhanced control of pests and harmful fungi (collaboration mixture). In addition, 'we have found that simultaneous (in combination or independent) administration of Compound J with chlorhexidine (or damifene and atoroxin (or trifluoro-sensitive)) or continuous administration of Compound I with dafoxdine (or dafoxdine and sub- Tomin (or trifluoro) is an enhanced control (synergistic mixture) of pests (which means animal pests and harmful fungi) compared to the possible control rates of individual compounds. In addition, 'we have found that simultaneous (in combination or independent) application of Compound J and Compound II and the compound ΙΠ or the continuous application of the compound 丨 and the compound ΙΠ provide a plant health effect (co-mixture) enhanced compared to the possible plant health effects of the individual compounds. . Furthermore, 'we have found that simultaneous administration of Compound I and daxen (or daphtene and atoroxin (or trifluoro)) or continuous administration of the compound (in combination or independently)! And 138197.doc 200939962 dalvafene (or dafoxdine and atoroxin (or trifluoro-sensitive)) provides enhanced plant health effects (collaborative extracts) compared to the possible plant health effects of individual compounds. Preferably, the ternary mixture according to the present invention comprises cotinine, π-pyrazine, thiamethoxam or acetamiprid, more preferably nicotine, imidacloprid or thiamethoxam, optimal cotinine or " Insect as a compound I, in which cotinine is excellent. The preferred compound π of the ternary mixture is statin.

Preferred compound III is orimycin. The weight ratio of the respective ternary mixture comprising the nicotinic receptor agonist/antagonist compound J, the fungicidal compound^ and one of the other fungicides (1) is 1:100:100 to 1〇〇:1:1, Good 50:1:1 to 1:50:50, better 1:2〇2〇 to 20:1:1. The weight ratio of the binary mixture comprising the nicotinic receptor agonist/antagonist compound and dafoxdine as the active ingredient is from 1:100 to 100:1, preferably from 50:1 to 1:50, more preferably : 2〇 to 2〇. The weight ratio of the binary mixture comprising dafoxdine and atramine or trifluoro-sensitive as the active component is from 100:1 to 1:100, preferably from 2:1 to 1:2, especially ι::: With regard to its intended use, the following binary mixtures of Compound 1 and damastoin are preferred: dadefen and cotinine; dadmoff and thiamethoxam; dadifene and acetamiprid; and damastoin. More than insects. For the intended use thereof, the following ternary mixture of Compound I, Compound ^ and 138197.doc 200939962 Compound III in Table 1 below is more preferred. In addition to the abbreviations of Table 1, the following abbreviations are also used herein: I is a compound I II is a compound II 111 = a compound III TMX is a thiamethoxam I is a D ratio insect Lin C is a nicotine M = a halal DMM = Dafenfen 〇 = auricin T = trifluoro-sensitive Α = Atomin table 1

No. I II III R-1 C Μ 0 R-2 - - - R-3 C Μ T R-4 C Μ A R-5 C Μ A R-6 C DMM 0 R-7 - - R-8 C DMM T R-9 C DMM A R-10 C DMM A R-11 IM 0 R-12 - - - R-13 IMT R-14 IMA R-15 IMA R-16 I DMM 0 R-17 R-18 I DMM T R-19 I DMM A 138197.doc -10- 200939962

No. I II III R-20 I DMM A R-21 TMX M 0 R-22 - - R-23 TMX MT R-24 TMX MA R-25 TMX MA R-26 TMX DMM 0 R-27 - - R-28 TMX DMM T R-29 TMX DMM A R-30 TMX DMM A

Among such mixtures, the following mixtures are especially preferred: Rl, R-3, R-4, R-5, R-ll, R-13, R-14, R-15, R-21, R-23, R-24 and R-25. The mixtures of the invention may additionally contain one or more insecticides, fungicides, herbicides. For use in accordance with the present invention, the mixture according to the present invention can be converted into conventional formulations such as solutions, emulsions, suspensions, powders, powders, pastes and granules. The form of use will depend on the particular intended purpose; in each case, it should ensure a fine and uniform distribution of the mixture according to the invention. Formulations are prepared in a known manner (see US 3,060,084, EP-A 707 • 445 (Liquid Concentrate), Browning: "Agglomeration", Chemical

Engineering, December 4, 1967, 147-48, Perry's Chemical Engineer's Handbook, 4th edition, McGraw-Hill, New York, 1963, S. 8-57 and subsequent content, WO 91/13546, US 4,172,714, US 4,144,050 ' US 3,920,442, US 5,180,587 ' US 138197.doc -11 - 200939962 5,232,701 ' US 5,208,030 ' GB 2,095,558 > US 3,299,566, Klingman: Weed Control as a Science (J. Wiley & Sons, New York, 1961), Hance Etc.: Weed Control Handbook (8th edition, Blackwell Scientific, Oxford, 1989) and Mollet, H. and

Grubemann, A.: Formulation technology (Wiley VCH Verlag, Weinheim, 2001)). Agrochemical formulations may also be included in conventional adjuvants for use in agrochemical formulations. The auxiliaries used depend on the particular application form and the active substance. Examples of suitable auxiliaries are solvents, solid carriers, dispersants or emulsifiers (such as other solubilizers, protective colloids, surfactants and adhesives), organic and inorganic sizing agents, bactericides, antifreeze agents, defoaming agents The agent, if appropriate, is a colorant and a tackifier or binder (for example for seed treatment formulations). Suitable solvents are water, organic solvents such as mineral oils having a medium to high boiling point, such as kerosene or diesel, in addition to coal tar and oils of vegetable or animal origin; aliphatic, cyclic and aromatic hydrocarbons such as toluene, Diphenylbenzene, paraffin, tetrahydronaphthalene, alkylated naphthalene or derivatives thereof; alcohols such as methanol, ethanol, propanol, butanol and cyclohexanol; glycols; ketones such as cyclohexanone and gamma-butane Ester; fatty acid dimethylamine, fatty acids and fatty acid esters and strong polar solvents such as amines such as Ν-methyl. More than π each biting ketone. The solid carrier is mineral soil, such as phthalate, tannin, talc, kaolin, limestone, lime, white #, basalt, loess, clay, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate, magnesium oxide, Synthetic materials, fertilizers such as ammonium sulphate, ammonium phosphate, ammonium nitrate, urea and plant-derived products such as flour, bark, wood chips and nut shell powder, cellulose powder and other solid carriers of 138197.doc -12- 200939962. Suitable surfactants (adjuvants, wetting agents, tackifiers, dispersants or emulsifiers) are aromatic sulfonic acids (such as lignin continuous acid (Borresperse® type, Borregard, Norway), S-splitting acid, naphthalene yellow Acid (Morwet® type, Akzo Nobel, USA), dibutylnaphthalenesulfonic acid (Nekal® type, BASF, Germany) and metallurgical metals, soil test metals and ammonium salts; burnt stone yellow acid@ Aryl sulphuric acid vinegar, sulphuric acid sulphuric acid vinegar, lauryl ether sulphate, fatty alcohol sulphate and sulfated cetyl ester, heptadecyl ester and stearyl alcohol ester, sulfated fatty alcohol glycol ether, and further naphthalene Or a condensation product of naphthalenesulfonic acid with phenol and furfural, polyoxyethylene octylphenyl ether, ethoxylated isooctylphenol, octylphenol, nonylphenol, alkylphenyl polyglycol ether, three Butyl phenyl polyglycol ether, tristearyl phenyl polyglycol ether, alkyl aryl polyether alcohol, alcohol and fatty alcohol / ethylene oxide condensate, ethoxylated castor oil, polyethylene oxide Alkyl ether, ethoxylated polyoxypropylene, lauryl polyethylene glycol ether acetal, sorbitol ester, lignin sulfite waste And proteins, denatured proteins, polysaccharides (such as thioglycolic cellulose), hydrophobic modified starch, polyvinyl alcohol (Mowiol® type, Clariant, Switzerland), polyacids (Sokolan® type, BASF, Germany), The polysiloxane, the polyvinylamine (Lupasol® type, BASF, Germany), and the polyethylene ratio are each 0. Ketone and its copolymers. Examples of thickeners (i.e., compounds which impart a modified fluidity to the formulation, i.e., a compound having a high viscosity under static conditions and a low viscosity during agitation) are polysaccharides and organic and inorganic clays such as Sanxianjiao. (Xanthan gum) (Kelzan®, CP Kelco, USA), Rhodopol® 23 (Rhodia, 138197.doc -13- 200939962

France), Veegum® (R.T. Vanderbilt, U.S.A.) or Attaclay® (Engelhard Corp., NJ, USA). A bactericide may be added for the preservation and stabilization of the formulation. Examples of suitable bactericides are based on: bisphenol and benzyl alcohol hemiacetal (Proxel® from ICI or Acticide® RS from Thor Chemie and Kathon® MK from Rohm & Haas) and isothiazole Linoleone derivatives such as alkylisothiazolinones and benzisothiazolinones (from Acticide® MBS from Thor Chemie).

Examples of suitable antifreeze agents are ethylene glycol, propylene glycol 'urea and glycerol. Examples of deodorants/packages are polyoxo-oxygen emulsions (such as Silik〇n8sre, Wacker Germany or Rhodorsil®, Rh〇dia, (iv) (10)), long-chain alcohol oleic acid fatty acid salts, fluoroorganic compounds, and mixtures thereof.适 Suitable colorants are low water soluble pigments and water soluble dyes. Examples to be mentioned are the name rhodamin B, CI•pigment red i i2 'ci solvent red 1, pigment blue 15:4, pigment blue 15:3, pigment blue 15:2, pigment blue, Pigment blue 8〇, pigment yellow cloth pigment correction, pigment red (1), pigment red 48.2, pigment red 48:1, pigment red 57:1, pigment red 53:1, pigment dial 43, pigment orange 34, pigment orange 5, pigment Green 36, Pigment Green 7, Pigment White 6, Pigment Brown 25, Alkaline Violet 1 〇 '(4) Violet 49, 52, Acid Red 14, Bungee 鈇 0 ^ 1〇8. |, acid yellow 23, alkaline red 10, alkaline red sputum or adhesive agent is a mixture of polyethylene ketone ketone ketone 'polyacetate 曰杳 曰杳 (four) and cellulose bonds (Ding fine 8, (4) , j-. Agents, spreading materials and powders can be prepared by mixing or simultaneously grinding compound 138197.doc -14- 200939962 as a solid carrier to prepare I and / or II and (where appropriate) other active substances and at least Granules can be prepared by combining the active materials 盥15]駚#,, ο ..., solid carrier, such as coated granules, impregnated granules and W"heart granules. Examples of solid carriers are minerals. Soil, such as tannin, linoleate, - 円月岭土, American activated clay, limestone, lime, white to red basalt, loess, clay, dolomite, Shiyoshi, calcium sulfate, sulfuric acid „ lr Under magnesium magnesium oxide, ground synthetic material

Materials, fertilizers, such as sulphate, sulphate, ammonium nitrate, urea, and plant-derived products such as flour, bark, swarf and nut shell powder, cellulose powder and other solid carriers. Examples of formulation types are: 1. Compositions for dilution with water i) Water-soluble concentrates (SL, LS) The compounds of the inventive mixture of the weight-damaged are dissolved in 9 parts by weight of water or water-soluble In the solvent. Instead, a wetting agent or other auxiliaries are added. After dilution with water, the active substance is dissolved. In this way, a formulation having an active substance content of 10% by weight is obtained. (1) Dispersible concentrate (Dc) A 20 parts by weight of a compound of the present invention is dissolved in a cyclohexanone by weight, and a 1 part by weight of a dispersed backing of, for example, polyvinylpyrrolidone is added and diluted with water. Dispersions. The active substance content was 2% by weight. 1 Π emulsifiable concentrate (EC) 15 parts by weight of a compound of the invention mixture is dissolved in 75 parts by weight of one toluene' while adding calcium dodecylbenzene sulfonate and castor oil ethoxylated 138197 .doc • 15- 200939962 (5 parts by weight in each case). Dilute with water to give an emulsion. The composition has an active substance content of 15% by weight. Iv) Emulsion (EW, EO, ES) 25 parts by weight of a compound of the invention mixture is dissolved in 35 parts by weight of xylene' while adding calcium dodecylbenzenesulfonate and castor oil ethoxylate (at 5 parts by weight in each case). This mixture was added to 30 parts by weight of water using an emulsifying machine (mtraturrax) to prepare a homogeneous emulsion. Dilute with water to give an emulsion. The composition has an active substance content of 25% by weight.

v) Suspension (SC, 〇D, FS) In a spar ball mill, 2 〇 was weighed into a powder' while adding 10 parts by weight of water or an organic solvent to obtain a stable suspension of the active material in an amount of 20% by weight. A portion of the compound of the present invention is a dispersion of a dispersing agent and a wetting agent and a suspension of 7 parts by weight of a fine active substance. Dilute with water. The active substance content in the composition is vi) water-dispersible granules and water-soluble granules (wcj, sg) 50 parts by weight of the compound of the present invention are finely ground,

A 50-weight wound dispersant and wet mash are added and prepared as a water-dispersible or water-soluble granule using technical equipment (e.g., a pressure, spray tower 'fluidized bed). Dilution with water gives a stable dispersion or solution of the active substance. The combination has an active substance content of 50% by weight. σ vii) water dispersible powder and water-soluble powder (wp, sp, ss, grinding of 75 parts by weight of the mixture of the invention in a stator grinder, _^ plus 25 parts by weight of dispersant' humectant and Shi Xi Glue water to a stable dispersion or solution of the active substance. Composition 138197.doc •16- 200939962 The substance content is 75% by weight. viii) Gel (GF) In a stirred ball mill, 20 parts by weight The compound of the mixture of the present invention is pulverized while adding 10 parts by weight of a dispersing agent, a hydrazine part by weight of a gelling agent wetting agent, and 7 parts by weight of water or an organic solvent to obtain a fine suspension of the active material. • Dilution with water gives a stable suspension of the active substance, whereby a composition having 20% (w/w) active substance is obtained. 2. Type of the composition to be applied undiluted ix) Dust-producing powder (Dp, DS) 5 parts by weight of the compound of the present invention is finely ground and intimately mixed with % by weight of fine powdery kaolin to obtain A dusting composition having an active substance content of 5% by weight. X) Granules (GR, FG, GG, MG): The compound of the inventive mixture of the weight loss was finely ground and combined with 99.5 parts by weight of the carrier. The current method is squeezing, mist drying or fluidizing the φ bed' to obtain granules having an 5% content of the active substance content which is applied undiluted. Xi) ULV solution (ul) The compound of the mixture of the invention is dissolved in 9 parts by weight of an organic solvent (e.g., -® + , aben). This gave a composition in an undiluted form with an active substance content of 10% by weight. Agrochemical formulations are generally included in 〇·〇1 weight ° /. Between 95% by weight, preferably between 5% by weight and 90% by weight, optimally between 5% by weight and 9% by weight of active substance. The compound of the present invention is used in a purity of from 90% to 1%, preferably from 95% to 138197.doc 17 to 200939962 1 〇 〇 % (according to the N M R spectrum). The compound of the mixture of the present invention can be used as it is by spraying, atomizing, dusting, spreading, brushing, dipping or pouring, or in the form of a composition thereof, for example, as a direct sprayable solution, a powder, Suspensions, dispersions: used in the form of emulsions, oil dispersions, pastes, dusting products, spreading materials or granules. The form of application depends entirely on the intended purpose; it is desirable to ensure, in each case, the finest possible distribution of the compounds present in the mixtures of the invention. The aqueous application form can be prepared by adding water from an emulsion concentrate, a paste or a wettable powder (sprayable powder, oil dispersion). For the preparation of emulsions, pastes or oil dispersions, the substances which are as such or dissolved in an oil or solvent can be homogenized in water by means of a wetting agent, a tackifier, a dispersing agent or an emulsifier. Or it is possible to prepare a concentrate consisting of an active substance, a wetting agent, a tackifier, a dispersing agent or an emulsifier and, where appropriate, a solvent or oil, and such concentrates are suitable for dilution with water. The concentration of the active substance in the ready-to-use preparation can vary over a relatively wide range. Typically, from 0.0001% to 10%, preferably from 0.001% to 1%/0, based on the weight of the compound of the mixture of the invention. The compounds of the mixtures according to the invention can also be used successfully in the ultra-low volume process (ULV), which may apply a composition comprising more than 95% by weight of active substance, or even in the absence of additives. The active substance is applied. Various types of oils, wetting agents, adjuvants, herbicides, fungicides, other insecticides or fungicides can be added to the active compound, as appropriate, directly 138197.doc -18- 200939962 to be added immediately before use (slot mixing). The compound of the present invention may be mixed with the compound of the present invention in a weight ratio of 1:100 to 100:1, preferably 10 to 1〇:1. The composition of the present invention may also contain, for example, nitrate, a piece of 'Dick' It also fades the long-term phosphate fertilizer, plant toxins, plant growth regulators and safeners. It may be used in sequence or in combination with the above-mentioned compositions, and may be added only shortly before use (slot mixing p, for example, the plant may be sprayed with the composition of the present invention before or after treatment with fertilizer. The compounds contained in the defined mixture may be applied simultaneously (i.e., jointly or independently) or continuously. In the case of separate application, the sequence generally has no effect on the results of the control measures. According to the present invention, it is understood that the compound I And II and compound m (or (Compound I and Damfen) or (Dafenfen and Atomin or Tris), Compounds and Compounds (or (Compound 1 and S-Fenfen) or (Dafenfen) And Atomin or San Dunmin)) (or (Compound 1 and Damtenfin) or (Dafenfen and Atomin or Trifluoro)) means at least compounds 1 and 11 and compounds called or (compounds! Defenfen) or (Damfen and sub-(four) or trisodium sensit)), compounds r and η and compound ΙΙΙ (or (Compound I and Damfen) or (Dafenfen and Atomin or Tris (10))) Or (Compound 1 and Damfen) or (Dafenfen and Atomin or Triple I )) in an effective amount simultaneously at the site of action (ie pests, such as harmful fungi and animal pests to be controlled, known as aphids, spiders or nematodes, or their habitats, such as infected plants, plants A substance (especially a seed), a surface, a material or a soil, and a plant, plant propagation material (especially seed), soil, surface, material or space to be protected from fungi. ' 138197.doc -19- 200939962 This can be achieved by simultaneous (combination (for example in the form of a tank mixture) or independently) or continuous target compounds 1 and 11 and compound m (or (Compound I and damfin) or (达分分和亚托敏 or trifluoro-sensitive)), compound 丨 and 丨 and compound Η" or (chemical δ I and dawhen) or (da fenac and atorox or trifluoro-sensitive) ( Or (Compound 1 and dafoxen) or (Dafenfen and Atmomin or Trifluoromethylene), wherein the time interval between individual administrations is selected to ensure that the active substance administered first is administered with other active substances At the time, it is still present in a sufficient amount at the site of action. The order of application is not critical to the work of the present invention. The weight ratio of the compound in the mixture of the present invention and the quaternary mixture - the compound of the mixture of the present invention Depending on the nature of the compounds of the invention, the compounds of the invention may be used individually or together with one another or in combination to prepare a composition according to the invention. It is also possible to further combine the compositions (such as a partial kit). Form packaging and use. In the present invention In one embodiment, the kit can include one or more (including all) components that can be used to prepare the subject agrochemical composition. For example, the kit can include the compound compound m (or (the compound recognizes fenfen or ( Damethophen and Atropine or Trifluoro-sensitive)), Compounds] and hydrazine compounds 或 (or (Compound 1 and dafoxdine) or (Dafenfen and Atmomin or Trifluoro)) (or (Compound I) And daxenfene) or (damafen and actoamine or trifluoro-sensitive) and/or adjuvant groups and/or additional-drug compounds (eg insecticides or herbicides) and/or growth regulators One or more of the components may have been combined or pre-formulated. In embodiments in which two or more components are provided in the kit, the components may have been combined and served as they are. Packaged in a single container such as a vial, bottle, can, pouch, bag or can. In other embodiments, two or more components of the J38197.doc -20- 200939962 kit may be individually packaged, That is, it is not pre-provisioned. Therefore, the kit may include one or more separate containers, such as vials, cans, bottles, sachets, bags. Small cans, each container containing a separate component of an agrochemical composition. The components of the kit can be used in two forms separately or together with other components or in a combination composition according to the invention for preparing a composition according to the invention • Administration in the form of a component. The user typically applies the composition according to the invention from a predosage device, a knapsack sprayer, a spray tank or a sprayer. In this context, the agrochemical composition is comprised of water. And/or the buffer is formed to the desired application concentration, and if appropriate, other auxiliaries may be added, and thus a ready-to-use spray liquid or agrochemical composition according to the invention is obtained. 50 hectares to 5 liters per hectare of agricultural effective area 〇 liters, preferably 1 liter to 4 liters of ready-to-use spray liquid. According to one embodiment, the individual compounds of the inventive mixture formulated as a composition (or formulation), such as a portion of a kit or a φ portion of a ternary or quaternary mixture, may be mixed by the user himself in a spray tank, and suitably Additional auxiliaries (tank mix) can be added. In another embodiment, the individual compound or partially premixed component of the mixture of the invention formulated as a composition, for example, comprises the compound and the compound - hydrazine (or (Compound 1 and dafoxdine) or (Dafen and Yatto) Sensitive or trifluoro-sensitive)), Compounds I and II and Compound III (or (Compound! and Dafafen) or (Dafen and Amoximin or Trifluoro)) (or (Compound and Dafen) Or the components of (damafen and atmomin or trifluoro-sensitive) can be mixed by the user in a spray tank and other additives and additives (tank mix) can be added as appropriate. 138197.doc -21 - 200939962 In another embodiment, individual components or partially pre-mixed components of the compositions according to the invention, for example comprising components of compounds I and II and compound III, may be combined (for example in a tank) After mixing) or continuous application. As indicated above, the invention comprises a method of controlling pests (meaning animal pests and harmful fungi), wherein the pest, its habitat, the breeding ground, its location or the plant to be protected from pests are treated with a pesticidally effective amount of a mixture. , soil or seeds. Advantageously, the mixture according to the invention is suitable for controlling the following fungal plant diseases: ornamental plants, vegetables (for example Candida fuliginea ("· and hollyhocks (for example, Brassica chinensis) (White rust fungus (J. /Zjwgo spp.) (white mine); vegetables, canola (Alternaria alternata (3. or Brassica hay), beet (Alternaria alternata (丄, 丄, Fruits, rice, soybeans, potatoes (eg, Alternaria alternata (Α or P. affinis), 儿,番佑 (such as Alternaria solani or Alternaria alternata) and Alternaria on wheat Spp.) (Spirulina leaf spot); the silk sac of the beet and vegetables belongs to spp·); the genus Sputum (乂spp.) on cereals and vegetables, such as wheat blastin on wheat Ir(1)W) (anthrax) and barley (A /zori/ez·) on barley; corn (eg, Helminthosporium urticae (Ζλ, 榖 (eg, wheat root rot) (B. sorokiniana) 'spot disease', rice (such as snail snail (5_ orjzae)) and turf on the turf (valence po/arb spp.) and Helminthosporium spp.) (sexual type) Teleomorph): Helminthosporium spp.)); cereals on cereals (eg wheat or barley) 138197.doc -22- 200939962 Cobs powdery mildew (gra/wz • palpitations / wwer (4) (formerly known as White powdery mildew; fruits and berries (eg strawberry vegetables (eg 'Lettuce, Carrot, Celery and Cabbage'), rapeseed, flowers, vines, forest plants and Botrytis cinerea on wheat (5〇i〇; ^ . (Sexual type. Although Botrytis cinerea (5oir less / wcA: e / za«a): gray • mildew), lettuce on the island of premia / ac ^ wcae (Grass Disease (down;; m like ew)); broad-leaved trees and evergreen trees on the evergreen clam (Cerai<?c·^ along) (synonym long. Ottoman (OpWoWoma)) genus (rot or wilt) For example, the clams on the eucalyptus (C. w/w/) (Dutch eucalyptus); corn, rice, sugar beets (eg, beet brown spot (c ^zcc/a)), sweet vegetables, vegetables, coffee Soy (such as soybean gray spot pathogen (C 5〇y~a) or Kikuchi spot disease n (c. kikuchn)) on the rice cultivar (Cercospora SPP.) (soy leaf spot); tomato (for example tomato Mold fungus (C.: leaf mold) and sputum on the branch of spp.), such as C. AerkrMw (black ear) on wheat; Φ ergot (ergot); corn (c. arm), cereals (eg, Helminthosporium (c, anamorph: wheat root rot), and rice (eg Helminthosporium (C. m!>a6ea«t^), deformation: Cyclobalanopsis sinensis on rice root-knot nematode (Hou 72), deformation: Helminthosporium f also > 〇化/^)) genus (leaf spot); cotton (such as cotton thorn spores (d^^_〇), corn (such as sphaerocephala (C, soft fruit, potato (such as ball spurs) Spores (C_ coccoi/es): dark spots), beans (eg, Phytophthora sojae (c / zWemwW mail)) and soybeans (eg, sphaerocephala (c) (4) (10) (10)) or 138197.doc • 23- 200939962 A genus (charcoal smear) (c〇net〇trickumK serotype: anthracnose (6) 〇_βίΐα)). Phytophthora (Comw Wmw spp), such as Fusarium oxysporum f. (C. outer sheath blight); multi-sporobacteria (10) sinensis (spot) on soybeans and ornamental plants; Cone genus (/〇__ spp_), such as the olive peacock plaque on the eucalyptus tree (c 〇 / ea # (10)...; fruit trees, vines (such as Liriodendron rugulosa (c / z) z. 〇 “w^〇, Sexuality · Neonectha liri〇dendri: Black Foot Disease) and Cylindrosperm on ornamental plants (eg if tree decay or young rat vines decline) , sexual type: spp) or iVeowecirz'a spp.); Dematophora necatfix (sexual type: genus genus (R〇) seUiniay} (root and sitting rot), Phytophthora Spp.), such as soybean black spot disease (/) corpse/^e<9/or_) (damping off), corn, glutinous rice Classes (such as barley (such as barley pathogens (netieres), net blotch) and wheat (such as wheatella (2). brown spots), rice and turf on the umbilical cord snail (synonymous snail) Spore Sex type: genus genus; Esca on the vine (top blight, stroke), which is called ForwziboWa pwwc/aia (synonym: P/je /Zz.Azw punctata), Proteus mediterranean (E mec?z7err<3«ea), Pseudomonas spp. (/>/1«60 speaks 0«化//<3£;/ 1/<2»7 less (^057?〇厂(2) (formerly known as Phaeoacremonium chlamydosporum), parasitic abandoned Phaeoacremonium α/eop/u'/Mm) and/or flat Caulis 138197.doc -24- 200939962 caused; pome fruit (Pythium sinensis (five/>_yr〇), soft fruit (Raspberry sclerotium (five veweia): anthracnose) and vine Plant (black acne sputum 〇 \ \ 匀 匀 匀 匀 匀 匀 匀 匀 匀 匀 匀 疽 疽 疽 £ ( £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ £ Black bacterium (^z'coccwm spp.) (black mold); sweet • vegetable (beet powdery mildew (5. heart (6))) ' vegetables (such as pea powdery mildew (Ugly (1))), such as cucurbitaceae (eg, white powdery mildew (five dadorc^arwm)), cabbage, oil (eg, Brassicaceae (five crMC^mrWm)) on the genus of powdery mildew (five '(10)^ spp) (powder disease); fruit trees, vines and ornamental trees on the side of Curvularia (£·Μί7) ?α /βία) (Eutypa canker or top blight, deformation: Lata pseudocysts "•like (4), synonym of Baifu disco (5) heart coffee - bUphahs)), the sudden on the corn Exter〇hUum (synonymous genus) (eg, Helminthosporium umbellatus (Wan iKrcz.CMW); Phytophthora CMVr/Mm on various plants) (sexual type: Gibberella ( Gz7)Z^re/(4)) genus (wild wilt disease, root or rot disease), such as F. graminearum on the cereal (such as wheat or barley), F. culm〇 Rum) (plate rot, spot disease or head withered), Fusarium oxysporum on tomato (plant-like ppor), Fusarium solani on soybean (F·5〇/Curry and Fusarium oxysporum on corn ( Plant verWcz7/Wi^); cereals (such as wheat or barley) and Capsella serrata on corn (g postal (four) (10) town (10) (full name (^ke_all)); mites (such as geranium gramine G· zeae)) and rice (eg, the red genus of the rice eclipse (C?·. Bakanae disease)) (G/Mere/h spp.); vines, pome fruits And other plants on the perimeter 138197.doc -25- 200939962 Small Phytophthora (G7owere / / ac / wgw / αίβ) and cotton anthracnose (G. gow_ypz7); rice grain dyeing (Grainstaining) complex Staphylococcus aureus (Gw/gwarAa black rot) on the vine; Rosaceae and the genus spp. on the cypress, such as Sabina rust on the pear (G. (rust) Corn, cereals and long worms on rice (synonym umbilical genus, genus: Helminthosporium); rust genus, such as coffee on coffee rust rust (//. να·?ίβίΓζ ·χ)(coffee leaf recorded disease); Phytophthora capsici (cMWspora) on vine (synonymous buddha (C/izt/oMoWwm Wi/5·)); soybean and cotton peas /zi^eo/ha) (synonym Bean globulin root and stem rot); Fusarium oxysporum (Microi/oc/Him wivct/e) on cereals (eg wheat or barley) (synonymous Fusarium oxysporum (i) ^wsarz'wm nzWe)) (pink snow mold); powdery mildew of soybean powder on soybean; brown rot spp.), for example, stone fruit rot and other brown rot fungi on Rosaceae (M. /&lt ; 3X (2), fruit plexus spores (Af. and brown rot fungus (M. / rwcHgewa) (flowers and twigs withered, brown rot); scorpion, banana, soft fruit and ball on the groundnut Mjcow/mere/Za spp., such as the root knot nematode (M. graw/«z'co/a) on wheat (deformation: S. cerevisiae (SepioWa ir)/shell needle) Ficus vaginalis (M. black banana leaf spot) on spores or fragrant parties; cabbage (eg, Phyllostachys pubescens), rapeseed (eg parasitic phoenix (P. paraWi/ca) )), onions (such as P. ί / eWrwcior), tobacco (tobacco cream (Mfeaciwa)) and soybeans (such as P. maws / iwrZca) frost 138197. Doc -26- 200939962 Mycoplasma ^ (4) ^ / ^ ~ ^ ^ household with grape downy mildew "Phakopsora pachyrhizi" soybean P. meibomiae (: K bean rust ); for example, in vines P. tracheiphila and R ieira (o), and soybeans (such as Pha/op/iora spp. on Peanut rot fungus (corpse: stem rot)). ); black rot fungus (P/ioma "«gam) (root and stem rot) on rapeseed and cabbage and beet polymyxa on sugar beet (P. (root rot, leaf spot and moist rot); sunflower, Liana (eg, Phytophthora sinensis (Whco/a): stalks and leaf spots) and soybeans (eg stem rot: Phytophthora sojae (corpse ρΛακο//), sexual type: soybean black spot disease (Z ) i_a;? orMe p/jaseo/orww)) on the genus Pseudomonas (corpse spp.); corn brown spot on the corn (PA less soi / erma way mountain * *?) (brown spot disease); Various plants, such as red pepper and cucurbitaceae (such as P. ca_pdc〇, soybean (such as P. megaverma, synonym P. soyae), potato and tomato ( For example, Phytophthora infestans (P.: late blight) and broad-leaved trees (such as Phytophthora infestans (corpse ramon/m): oak dying) on Phytophthora (_PAyio/?Ai/zora spp.) >Weeds, roots, leaves, fruits and stem rot;) Cruciferous rhizobial pathogens in cabbage, rape, radish and other plants (housekeeping called raw山^rawicae) (root nodule); uniaxial mold Genus (associator/aswopara spp.), such as Phytophthora platensis on P. chinensis (P. W with coM) (vinevine grape downy mildew) and sunflower on the sunflower (corpse. Aa/Wet/ζ 'Ο; Rosaceae, hops, pears and soft fruits on the genus Poi/ov/mera spp. (powder disease), such as apple powdery mildew on apples (corpse 138197.doc -27- 200939962 /eMCO; for example, genus of cockroaches (such as barley and wheat (polymyxa sinensis (/>. and beet (polysaccharide beetle (10))) (P〇/ _yWFa Spp.) and viral diseases transmitted by it; wheat-based rot disease (Pseudocercosporeila) on cereals (such as wheat) (eyes, sexual type: blast fungus (7^e& _ya//MWae) )); fake downy mildew grape cream on various plants), such as Cuban fake downy mildew on cucurbitaceae (corpse. or psyllium on hops) (p hW&Quot;); vines on the vines of the horns of the plaques of the fire disease "fire disease" or Roche disease (r〇tbrenner'), deformation: bottle of mold (ρ / π · β / ορ; ^ β)); Rust fungi (household Mcc/'spp.) (rust) on various plants, such as mites (such as wheat, barley or rye) and asparagus (such as P. sylvestris var. Brown rust (p (brown or leaf recorded disease), Puccinia striiformis (ρ_stripes or yellow rust), barley stalks (P. Aori/e/) (dwarf smut), stalk ore (p (stem or black recorded disease) or leaf rust (P. rec〇Aii/aa) (brown or leaf rust); wheat sclerotium iWiz.cz._re^ewn_5) (deformation: inner snail抱) (sepia spots) or P. nucleus (p iere5) (net spot) on barley; Pjhcw/arifl spp., such as rice blast fungus (corpus. or_yzae) on rice Sexual type. Rice cancer disease (shooting, rice fever) and rice blast fungus (Ρ·grbea) on turf and cereal; turf, rice, corn, wheat, cotton, rape, geranium, soybean, beet, vegetable And various other plants on Pythium Is spp_) (wet rot) (such as the ultimate rot (_P. w / i / speak mw) or melon and fruit bond (/3. αρΛβΛ / ί / ermaZM / w)); column 138197.doc -28- 200939962 Phytophthora sPP.), for example, Gypsophila sinensis on the barley (Sacral sclerotium leaf spot, physiological leaf spot) and beet column on the beet (brother; cotton, rice, horse yam , turf, corn, rapeseed, potatoes, beets, vegetables, and various other plants of the genus Rhizoctonia (Xianxin (10) heart SPP.), such as Rhizoctonia solani on the soybean (brother μ / «« 〇 (root and Stem rot), Rhizoctonia solani (external sheath wilt) on rice or stalk nucleus on wheat or barley (and cerea/z.5)

Rhizoctonia spring blight); Rhizopus oryzae on strawberry, carrot, cabbage, vine and tomato (like 55i〇/〇w(/^) (black mold, soft rot); barley 'rye And Rhizophora vulgaris (Rhynchosporium wca/b) on the black wheat (sunburn); the stalk of the stalk of the stalk of the stalk of the stalk of the stalk of the stalk of the stalk of the stalk of the stalk of the stalk and the stalk of the stalk of the stalk of the stalk Bacteria Spp·) (stem rot or white mold) 'such as rapeseed, stalking (such as Sclerotinia sclerotiorum (S. sc/er〇ii〇rMm)) and soybean (for example, sclerotium (iS·(7)(7) Or Sclerotinia sclerotiorum), a variety of plants on the shell of the genus spp.), such as soybean brown stalk (*S. brown spot), wheat on the wheat shell needle (5 * · kg out ( <<>><2> (Stagonospora blotch); the squid-like synonym of powdery sinensis on the vine plant, recorded edge (^ecaic> r) (powder disease, deformation: grape powder spore (9/mountain) _wm iwckrz·)); corn (for example <>> "rdcwm", synonymous with Helminthosporium iwrcicww) and Phytophthora genus 138197.doc -29- 200939962 spp.) (corn blight); corn (eg silk Black powder pathogen α ··Silk smut) 'Sorghum and Gansong's axis black powder genus _

Spp.) (Smut) / Cnidium monofilament shell on the Cucurbitaceae plant (5 > k (four) ca ca powdery mildew); potato powdery mildew on the potato (dosage) and the virality transmitted thereby Disease; genus of the genus Pleurotus ostreatus on the grain (5) sing 〇^〇spp.) 'For example, the sclerotium of the stalk of the stalk (sw〇^〇yMw) on the wheat Sexual type · wheat ascomycetes [synonymous wheat leaf blight bacteria ^ do ^ (9) printed ^ ^ to (four) such as ~ (4) Bu Maling on the potato cancer pathogen (5 > wc / ^ rz • please e « c / 〇 6/oMcwm) (potato cancer); ectoparasite spp.), such as the abnormal cysticercosis on the peach (Γ. leaf curl disease) and the outer bacterium of the plum on the plum (r pr_.) (Li bag fruit) disease). TTnWaWopb spp. (black root rot) on tobacco, pome fruits, vegetables, soybeans and cotton, such as Rhizopus oryzae (r △ asz'co/a) (synonym string beaded emblem (c/) Ra/ara e/egaw)); genus Phytophthora on the cereal (77// buckle·α spp.) (common smut smut) (such as wheat black on wheat) Powder fungus (synonymous wheat smut (Γ_caWes) 'wheat smut (wheat bun (1) and dwarf smut (77. versa) (dwarf bunt) ); wheat on the barley or wheat, snow rot, brown sclerotia, z_«car«a/a) (grey snow emblem); genus genus (price 0 £^ along spp), such as rye Helicobacter sphaeroides ([/· occw/ia) (stem smut); vegetables on the genus rust (t/romyces spp.) (rust), such as beans (such as kidney beans) Rust (C/. appen mountain · 〇Μ / αίΜ · 5), the synonym of Puccinia solani ([/. 138l97.doc -30· 200939962 household office like 60 ^)) and beets (such as sweet menu spore rust ( t/.心仏6)); cereals (such as barley powder black powder fungus ([/·仙如) And oat sylvestris (tz avaenae) 'corn (for example, maize smut (t/_: corn smut) and black genus (f/W/ago spp.) on sugar cane (dark black powder) Disease); apples (such as apple black fungus (K and Pseudostellaria (r. SPP.) (sickness), and various plants of Verticillium spp.) (fused disease) Plants such as fruits and ornamentals, vines, soft fruits, vegetables and field crops such as strawberries, canola, potatoes and tomatoes on Verticillium dahliae (Κί/αΑ/ζ.ββ). Control harmful fungi in the protection of materials such as wood, paper, paint dispersions, fibers or fabrics and in the protection of stored products. As for the protection of wood and building materials, pay particular attention to the following harmful fungi: ascomycetes, Such as Ophiostoma spp., Ceratocystis spp., Aureobasidium pullulan, Sclerophoma SPP., Chaetomium spp .), Humicola spp., Petriella spp., Trichurus SPP.; Basidiomycetes, such as Coniophora spp., c〇riolus spp., Gloeophyllum spp. , Lentinus spp., Pleurotus spp_, poria Spp., serpUia SPP· and Tyromyces spp., deuteromycetes ), such as Aspergillus spp., Cladosporium spp., Peniciiiiuin spp., Trichoderma 138197.doc -31 - 200939962 (Trichorma spp.), Alternaria (Alternaria spp.), Paecilomyces spp., and Zygomycetes, such as Mucor spp., and additionally in the protection of stored products, the following yeasts are worth noting: false silk Candida spp. and Saccharomyces cerevisae ° for controlling various cultivated plants (such as bananas, cotton, vegetable species (such as cucumber, beans and oysters), barley, grass, oats, coffee, Potato, corn, fruit species, , On rye, Dali, tomato, grape vine, wheat, ornamentals, sugar cane) and a large number of fungi on the (preferably seed) is particularly important in a large number of plant propagation material. The mixture of the invention also exhibits a significant effect against animal pests from the following species: from lepidoptera (/e/j/i/opieraw, insects such as small tigers (乂客(7) along, yellow tiger (7) along "segeiMm") , cotton leaf moth leaf moth 4/a6ama, limwaia/is), nesting moth (JrgyresM/a, JwiogrflpAfl gamma, pine tree care / 7/m'arz'ws) , Leaf moth (Cacoec/fl, cotton brown moth (Ca/? Ma reticulana) ' winter moth (CAez.maioZj/a, spruce leaf moth (CAorbiowewra / "mi/era«a", western Chorstoneura occidentalism, Cirphis unipuncta, apple moth (C Shaoshan a;?omo«e//a), European pine caterpillar ρζ·«ζ·), melon field filling ( Ζ)ζ·α/>Αα«ζ·α nWWa/b)' Giant corn fill (£)ζ·α with aefl, Egyptian diamond insulana), small corn fill 138197.doc -32- 200939962 (Elasmopalpus lignosellus) Grape moth (five

, Summer hawk moth (five veir/α 6〇ί//ζ·α«α), Feltia subterranea, Galleria mellonella, Li'}, Grapholitha funebrana , pear, i, heartworm ^Graph〇litha moiesta), cotton aphid (Heiiothis armigera, budworm), yellow bollworm, Hellula undalis, Hibernia defoliaria , American white moth cwwea), apple moth (Hypowomewia mfl/heZ/ws), tomato moth (foot ez/er/fl /j; co;?em.ce//a), hemlock shaman (Lambdina fiscellaria ), Laphygma exigMa, coffee leaf miner, Zewco/^era scitella, Lithocolletis blancardella, grape fruit moth, yellow green 绦Z^jcowege sticticalis), Gypsy moth mountain ipar) 'Lymantria monacha> > Narrow-winged leaf miner c/erA:e//a), celestial hair. worm (Μ<3/αί:〇5Ό»ΐβ wewWrz'a), Mameiira brassicae ' Douglas sinensis moth (C) rg_yz'〇!, European corn tower (Ostrinia nubilalis), winter nocturnal moth (Panolis fla Mmea), ginseng blast (Peciinop/iora g〇ss3;; n'e//a), variegated tiger (corpus erMroma SflMcia), stalked moth 6wce/7々a/a), potato tubers Moth {Phthorimaea operculella) 'Phyllocnistis cHre//a), large cabbage butterfly (ρζ·αζ··5 6rawz_cae), Plathenia scabra, 4, I moth (Plutella xylostella), big chaos Moth (Pseudoplusia z'/ic/wi/ens), Pinus sylvestris 138197.doc -33- 200939962 /Vwsirizwa), potato tuber moth (Scrc^^ja/pw/a aho/wia), wheat moth (Sitotroga cerealella), S. cerevisiae (Sparganothis /?/"eWa«a), grass worm (iSpoc/opiera /Vmrong z'/> eri/a), Spodoptera litre (Spodoptefalittoralisj' MflSi^j^lSpodopteralitura, ^^, a heterosexual moth (77iawmaio;?oea pz^ocampa), a green leaf moth (7briWx Wr/t/a«a), a pink-spotted moth (7Wc/?o/> /wWa «/) and Spruce Leaf Roller {Zeiraphera canadensis) 5

Beetle (Lehidae (Co/eopier<2)), such as Pear Changjiding sinuatus) 'JgWoies //«eaiM·?), Agriotes obscurus, Amphimallus solstitialis ), European name insect dispar), constitutive age, (Anthonomus grawd/i), arborvitae (d«M〇«C»WW5· />0/W£?, MW), side spurs Genus [Aphthona euphoridae), Red Mu 叩气{Athous haemorrhoidalis, JiowaWa linearis, Dasong, h stupid ABlastophagus piniperda), Day I dead leaf moth (Blitophaga, broad bean ❹ [Bruchus rufimanus), glimpse { Bruchus pisorum), 支) branch (5rMcAwi /e«"\s), rhyme leaf 曱fteiw/ae), beet big turtle (CauWa «eftw/osa), bean leaf (Cerc^oma iW) /wrcaia), Golden Flower Tortoise (Ceiow/fl izwraifl), Cabbage Elephant (CeMiAorrA_ywc/iM·? 'Dark 曱 曱 (OwMorrAywcAMS «α/?〇, Beet cn { { {Chaetocnema tibialis), 萆 萆 金 金(Conoderus vespeWz'wws), Aspartic Loach (CWocer/s like /iaragi), Rhododendron (Cienz'cera μ/)·), Longhorned Leafhopper (Dz'a) 6roi/ca /owgz'comb), half-star leaf (Ζ)ίαΖ?γ〇"·£:ύ!, twelve-star leafhopper (Zh'a6ro"'ca 138197.doc -34- 200939962, South American leaf曱 (仏 〇 r〇 / z. Cfl print, corn root leaf f (Diabrotica virgifera), Mexican bean ladybug (£pilachna vahveWb), tobacco jumper (坳 坳, Brazilian brown bat (Eutinobothrus brasiliensis, pine 曱{Hylobius βΖ>ζ·βίζ··5), Egyptian 苜蓿 甲 (//义, 苜蓿叶象曱 (if less /> eroi ^osi/ca), spruce eight teeth small 蠹 (chemical 5, sigh ~ 尸 Μ ) )), with a negative worm (Zewa bilineata) ^ black horn negative worm 〇 ^ ma me / ano / ^ w ·?), potato beetle heart Cew / / wea, a), beet golden worm Ca/^/brm'cw·?), rice elephant

, cotton nematode, rapeseed (Meligethes aewew), fledgling horned golden tortoise (Μβ/σ/ο„Μα hippocastani), western 1 steam galactic gas (Melolontha melolontha) 'rice negative worm (0w/ema or less Zae), grape root weevil sw/caiws), strawberry root weevil ((9iz'orrA less nc/ίΜ·? οναίΜ·?), horseradish beetle (PAaei/ow cocA/eaWae), pear leaf image ( ΡΑ_);//〇6ζ·μ·5 /? Less W), Phyllotreta chrysocephala, Phyllophaga sp., Phyllopertha horticola ' 芜 淡Jumping armor (PA less / oireia wemorwm), Phyllotreta striolata 'Japow/ca', Japonish leaf (<S7io«a //«eaiws) and Guxiang (* S7iopA!7w·? grawarifl), rope, mosquito (Diptera), such as Aedes aegypti (Jei/e·? aegjpiz·), Aedes aegypti (dedes a/Zjop/ciM·?), 剌Aedes mosquitoes (dei/es vexans) 'Mexico orange rope/wi/ews), Anopheles sinensis {Anopheles maculipennis) Anopheles sinensis (Anopheles 138197.doc -35- 200939962 crwcz'aw·?), white foot press Mosquito α/Ζπ·α Μ · 5), Anopheles gambiae (? JwojoAe / e · Fr Anopheles (^ 4 «o / > Ae / e5 / ree6or« i), white

Anopheles sinensis, Anopheles minimus (^4«o/>/ie/e5· minimus) ' E9 ^1 {Anopheles quadrimaculatus), lx 头丽绳 (Ca//(pAora νζϋα), Mediterranean real 41 (0, ""·"·«? capWaia), calorie golden rope (CArjv^omja bezziana) 'American golden rope Aomi/aivorax), American rice water rope (CArj^omja mace//aWfl), Zhongfang Baihongshan '"sca/z··?), static spotted rainbow: (CAr less "sops si/acea", Atlantic yellow rainbow: (CAr less jo /»·? ai/flwizcrw), spiral rope (Coc / i / zo / n>^ hominivorax), ^ # i5t (Contarinia sorghicoia), Cordylobia anthropophaga, Culicoides / mmw, Culex pipiens pallens (Cw/ex corpse), ring pattern Culex pipiens (Cw/ex nigripalpus) 'C. sinensis (Cw/ex bifurcation / η^τΜβ/απίαίΜί), Culex pipiens pallens (Cw/ex ίααα/), and yellow-tailed mosquitoes (Cw/ise/ z z«or«aia), black-tailed mosquitoes (Cw/keifl me/a«wra), melon ropes (£)acMiS cwcwrWiae), scorpion scorpion CDacw o/eae, sphagnum moss Eura

Brassicae), onion fly {Delia antique), wheat seed rope {Delia coarctata), seed fly (De/z'a platura), cabbage (worm) and worm radicum) ' Derm a ίο 厶/<z hominis Yellow belly rope (Fawm.a caWcw/ar), potato fly (Geomyza 7WpWWCiaia), Malaysian stomach (Gasterophilus intestinalis), Glossina morsitans, whisker rope (G/owz>za palpalis) ), bow | -g- 43⁄4 (Glossina fuscipes), tongue rope (G/ow/wfl 仏<^//2〇/^^5), Haematobia irritans, Phalaenopsis dive rope (i /a;?/0山·;7/0>sk 138197.doc -36- 200939962 equestris), dive [Hippelates s/?/?·), seed rope platura) 'skin cans (_f/y/7c&gt ;i/erma lineata), black worm ({Leptoconops torrens), ^;f- 43⁄4 (Liriomyza sativae) > three-leaf stalk rope (Z/nfom less ziz iW/b/z·/), goat green rope ( ZMCi'/k caprina), Lucilia cuprina, $& Lucilia jer/caia, Zjcoriiz, itching

(Mansonia titillanus), Hessian straw fly (Mfl less eiz'o/ai/es/rMcior), home rope (Mwsca c/omes'iica), waste rot rope (Mwsci'na, sheep nose rope ονζ·4, Huanghe rope (C^o/wyza //orwm), Swedish wheat rope/Hi), beet leaf (rope egomya / ij^ocyamz·), ocean; |, rope (P; i〇r6ia aniigwa), Phorbia brassicae, Phorbia coarctata, silver foot white carp (i^/eZ?oic»WMS argeWz>ei), Columbia spleen mosquito (PsoropAora co/wwWae), carrot rope (Ρί/Ζα Rosaae), Psorophora discolor, Prosimulium mixtum, cherry solid rope (and hgo/e along ceran), apple solid rope (/?/jag0/e along pomonella) ' |x 4, 13⁄4 (Sarcophaga haemorrhoidalis) > ^ genus (iSVzrco/^agfl ί/>·), belt 蚋 (<S7/nM"Mm vz'"aiwm), waste reins (5Vomox less i ca /c/iraw), cow feoWwws), black horse rope (rah/iMS airaiws), striped horse ί1 (Γα6αΜΜ·5 h'neo/α) and similar to {Tabanus, cabbage (77pw/a σ/eracea) and European mosquito {Tipula paludosa), hummer r/ijscmopiera)), for example, Dichromothrips corbetti, 1花1 蓟马亚楂 (Dichromothrips 138197.doc -37- 200939962 ssp) 'Tobacco brown horse/wsca), 苜 |||j 焉 (Frankliniella Occidentalis), flower, 15 horse (Frankliniella, orange 蓟 czW), rice ||j horse (2^ buckle oryzae), southern yellow horse (ΓΑγζ>·5 and smoked horse (2"heart_tabaci), Termites (Isoptera), such as European wood termites ((: 0/0 chemical ^ „ flavicollis, breast augmentation {Leucotermes flavipes, golden scented 吟 {Heterotermes awrew·?), yellow chest Termites (7^wCM/zierWa/Yizvipes), Virginia termites (AeHcwhiermes vz'rgzWCMiS), southern European netted termites (and eHcw/iiermes lucifugus), golden flowers i white weaves (Termes natalensis, anti-home weaving {Coptotermes formosanus, , B (Blattaria-Blattodea), such as Blattelia germanica, Blattella asahinae, American cockroach (corpus erz>/aneia americana) 'Japanese cockroach (Per(p/ a«eia japonica), brown spot: K exhaust: (Periplaneta b Runnea), Black-breasted Stork {Periplaneta fuligginosa) 'Periplaneta australasiae' (Blatta orientalis), true 蝽 (Hemiptera), such as green Λζ Λζ '/are), hairy Long wall/ewco/Jierws), Cyrtopeltis notatus, Dysdercus cingulatus, sdercMS intermedius Brown bee im/n'ci/vewiW·?), leaf foot bee (Zepiog/oMws less "ο/?μ·5), pasture blind bee (Z_ygw*s, green blind owl (Lygws /Jraiewhs), rice Green bee (TVezara WWdw/α), sweet rack 138197.doc -38- 200939962 Checke quadrata, Solubea insularis, Thyanta perditor, Acyrthosiphon, larch ball均/aWcb), buckwheat horse 钤 财 « «flWwr"·/), broad bean money, strawberry root wealth / orZ^wV, apple money pom /), cotton money (but / π) art ow right 〆ζ ),) Gooseberry (groww/ar/ae), Rat Lee Square (々>/π·>? scAwez'c/en·), Spiraea Square «pDInk aeco/α), Elderberry sambuci) , voyeur I field (Acyrthosip Hon /^wm), Aulacorthum solani, Bemisia argentifolii, Short-tailed (5rac/^cawi/w5 carc/wi), Ae/icAr less h), peach Black Short-tailed Finance/>em'cae), Meicai {Brachycaudus prunicola) '-^r (Brevicoryne brassicae) 'Capitophorus hornf, constitutive field (Cerosipha gowjl^z·/), strawberry capillary (CAaeioWp/^n /ragae/o/z·/), 蘼 蘼 蘼 额 rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib rib , Apple cut-off wealth (Z) less ra ^ Z / co / a), class fruit ditch without net money, phase pink bad wealth, pear tree awning 蚜 (Ζ ^ αρ / π) skill; W), broad bean micro-leaf蝉(£:7np0aiCa /a6ae), Mei Taiwei (//less α/ο ierws /?γμ«〇, tea recommended bitter 蚜 (//less er0Wlyzw>y /aciwcae), Maichangguan avewfle ), Macrosiphum euphorbiae, Macrosiphon rowe, Megahoura Wcz.ae, Pyrrarius, Metopolophium dirhodum, 138197 .doc -39- 200939962 (Μ少,冬葱财(Μ Ζμ·5 wca/owicM·?), cherry melanoma (Myzws cerwz·), flower butterfly lamp (small zws varkw«s), sauerkraut (Nasonovia fibis-nigri, field box good [Nilaparvata Lugens), 苣 瘿 财 财 Z Z 、 、 ya ya ya ya ya ya ya ya ya ya ya _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ ML (Psylla piri), Rhopalomyzus ascalonicus, Yuzhuo Pipe Farm (Rhopalosiphum zwaii/I), Heguyi Guanfang/?αί/ζ·), Apple Grass (Rhopalosiphum insertum), Horse Sappaphis mala, ΟMali round tail (<^α/7/?β/?/π··5 ma/z_), Mai Erchai (ScA/zapAz··? graminum) ' ^ % ^ {Schizoneura lanuginosa) ^ ^ -h ψ (Sitobion avenae), greenhouse (Trialeurodes vaporariorum), big orange wealth aurantiiand) 'grass roots (Fz'ieMS v/i (/b/z'z·), Temperate bed bugs (C7me:c /eciw/ar/Ms), tropical bed bugs (Cz'mex Aembierws), old age bee seAuD), cone genus (TWaioma and wheeled falconry 4r"M5·cW/aiw·?) ,

Q Ants, bees, wasps, ores (Hymenoptera), such as Xinjiang leaf bee, tropical leaf-cutting ant cepAa/oies, leopard-cutting ants ca/>igwflra), tropical leaf-cutting ants, smooth Cut leaves (Αία /aeWgaia), strong cut leaf ants (roZjwWa), six-hole cut leaf ants (^4ίία sejcdews), Texas cut leaf ants (Αία iexawa), genus genus (Cre/waiogwier sp;?.), Li Shi bee (/^op/ocawipa mi«wia), apple bee [Hoplocampa testudinea), kitchen ant (Monomorium household / iarizowb), fire ant ("So/eno;?·^ gemkaia", external red fire ant 138197.doc -40- 200939962 (Solenopsis invicta), black, scouring (Solenopsis richteri), southern fire ant ("So/ewopik λ:3; /ο«ϊ·), red ants (corpse, California red harvest ant ( The corpse is less rmex ca/(/br is 'cws), tropical ant (Pheidole megacephala), XDasymutilla occidentalis, bumblebee (5c»w6w5· 577/?.), southern wasp (Fes/ίΜ/β, ordinary

Wasp (Carcass βΓ<2ν6·5/>Μ/β vw/garb), Western Wasp (Pizravejpw/a pennsylvanica) 'De, National Wasp (Paravespula germanica) 'Apis (Do/z'cAoves/iw/fl macw) /αία), Wasps craZ^ro), Po/bie·? rubiginosa, Camponotus floridanus, Linepithema humile, moth, scorpion, yellow worm Orthoptera, such as Acheta domestica, Gryllotalpa gryllotalpa, ZocwWa w/graiorz'a, and double-belt (Me/awop/wi· ZH' WiifliM·?), red-legged fierce (Me/awop/w·? /ewMrrwfcrMW), Mexican monument {Melanoplus weja'cawws), migratory Me猛 (Me/awop/Mi·sanguinipes) 'Rocky Mountain 蚱 蚱 (Me /awop/ws, Red-winged owl {Nomadacris se/Jie/n/asckia), American 蚱 ( (•Sc/f/Wocercat americana) 'IscAbiocerca gregarz_a, Moroccan Python worm (Docz'oWaMrw·? Maroccaww·?), greenhouse total 螽 (racAycke·? asynamorus) 'Senegal locust Meng (Oei/a/ews «sewega/aW·?), variegated 乍 { {Zonozeru s variegatus), rice worms {Hieroglyphus, Indian sylvestris (iTrflwwaWa a«gw///era), Italian made (Calliptamus italicus) 'CAoHoz'ceies terminifera à ostustana pardalina, 138197. Doc -41 - 200939962 Arachnoidea, such as the lack of 1 arachnid (Acarina), such as Argasidae, Ixodidae, and Sarcopterida, such as : America 匕蜱 匕蜱 flmeWcawwm) 'Amblyomma maculatum', 'Arbas persicus', 具 per ( ( (5οο/>/π7μ·5, achromatic cattle monument (10,000 ί/eco/oraiws), tiny cattle monument, Dermacentor silvarum, Dermacentor anc^f"soni, Dermacentor variabilis, arm scorpion {Hyalomma truncatum, sheep Hard monument (/χοί/α Wc/ww*y), South African hemorrhoids monument rMhcwwdMs), black foot hard 蜱 (/χσΑ·? wa/?M/aWs), full ring hard 蜱 (/jcoi/es Ao/oc Less c/ws), Pacific hard 蜱 (/ heart 5 pacWcM·?), 喙蜱 (Ornithodorus moubata), 输姆Ornithodorus hermsi, Orwh/ioi/orw·? iwricaia, Ornithonyssus bacoti, Otobius megnini, $% skinworm (_Derma« less "5· , or op 茜 / (/^oropies oW > s), Rhipicephalus sanguineus, Rhipicephalus appendiculatus, Rhipicephalus everisz, squeezing (Sarco/Jies scaZHW) ; and 瘿瞒 ( (£ > ζ · ο / > / ^ ζ · ί / < 2β s /? /».), such as 瘿 瘿 蜗 蜗 (Jcm / ws π / ι / π Α β β / ίί / ///), Phyllocoptrata oleivora and citrus (Eriophyes sAe/i/owi); velvet (TVzrsowem/i/ae ί/τ?·), such as Phytonemus Pallidus) Polyphagotarsonemus latus ·, genus Tenuipalpidae spp., such as purple short scorpion 138197.doc -42- 200939962 (Brevipalpus phoenicis) ·, Tetranychidae spp. ' Such as cinnabar worm, Aesculus sylvestris A: a«wwin·), Pacific red snail "less dws joacWcws", cotton red spider (JWra «less cAws ie / ar / Ws) and cotton leaf worm (JWrfl«_ycAw«s wr"cae), apple red insect known spider (corpse awo^ycAw·? m/like), orange full claw insect 茜 (corpse a«o«_yc々w5· Cz'ir/) and grassland melon (<9//g〇«_ydw5/>raie«>sz·*?); lack of Araneida, such as black-raising ball-web spider (• Liziroi/ee/MS maciaws) and brown concealed spider (Zoxosce/ei1 rec/Μία),

❹ 蚤 蚤 (Siphonaptera), for example, 栉 栉 蚤 (CYewoce/^fl/zWe·? /e/b), canine 栉 蚤 (Ciewcice/^a/ic/es, Indian groin (Χβ) «ο_ρ·53;//β c/ieo/n's), Pw/ex irriians, Tunga penetrans^ %: {Nosopsyllus fasciatus) 5 Silverfish, home fish ( Firebrat) (Thysanura), for example, sinensis, anti-spot farming, {Thermobia domestica), entertainment law (Chilopoda), such as aunt (*ScMhgeri2 coleoptrata) » Millipede (multiple feet) Diplopoda, such as TVarcews spp., Dermaptera, such as the European ball (/br/Zcw/a auricularia) » Wind (II) (Phthiraptera) ), for example, Pes (cw/ms humanus capitis), Pediculus humanus corporis, and Pthirus pubis, bovine blind wind (Haematopinus 138197.doc -43- 200939962 eurysternus), pig blood Wind suis), long headed cow wind (Zz.wogwai/iws Wiw/z·), cattle bite bite (square 〇 Wc〇/a feoWs), chicken wind (Me«o/?c»«, chicken body chaotic siramz .wet^) and 4, Solenopotes capillatus 'plant parasitic nematodes' such as root nodule nematodes, groundnut nodule nematodes (Me / oWogywe are « aWa), strange wood root nodule C ^ ^ WOOi / /), short nodule nematode ejn 'g Mfl), north Meloidogyne hapla, Meloidogyne z'wcogwha, Caenorhabditis elegans (Me/o/i/og;; we / avaWca) and other nodule nematodes, cyst nematode, golden nematode ( G/oZ?〇i/er<3, potato cyst nematode (G/ofeof/era pa//Wa), tobacco cyst nematode (G/ohi/era io^acwm) and other cyst nematodes; wheat cells Cystic nematodes (dan eeiero/era ave«ae), soybean cyst nematode {Heterodera glycines), sugar beet cyst nematode (i/e/eroi/era scAac/m·/), clover cyst nematode (//eier〇£ /era(7)y,〇/zz) and other cyst nematodes (/i/Wer〇i/era), species nematode, nematode nematode/wweWa), wheat worms and other nematodes, larvae, leaf buds Beauty (Apheienchoides △ ewe less /), strawberry serrata (yl household Ae / ewc / zo / i / es / Vagar / ae), chrysanthemum leaf nematode W匕ewaZjo magic ·) and Leaf bud nematode, whole thorn nematode 'nematode (5β/〇«σ/ίΠ·ΛίΜ5· /owg/cawi/aiw·?) and other thorn nematodes, pine nematode, pine wood nematode (JBursaphelenchua xy/op/u/ Mj) and other species of E. serrata (^w^si^/ie/ewc/iM·?); ringworm, ringworm (Cr/co«ema), and nematode (Crict>«eme// a) 138197.doc -44- 200939962

Species, CVco«ewo/i/e>s and MesocWcowemfl; Stem and bulb nematodes, Ditylenchus destructor, Jade 1 (Ditylenchus iZ/^^acz· ), the fungus Stem nematode w and other stem nematode species; cone nematode, cone nematode (Do/ZcAoi/orw·?) species; spiral nematode, Spirulina elegans i (Helicotylenchus dihystera), multi-snail, snail (Helicotylenchus multicinctus) against other spiral nematodes (i/e//coi_y/e«cAw>s); Rotylenchus robustus and other A. elegans (Aoiy/ewcAM·?) species; Nematode (//em/c_yc/bj:?Aora) and Hemicriconemoides species Hirshmanniella, Spearworm, Coleoptera cc»/wmZ?w5·), Gram C. elegans ga/eaiwi·) and other spore-shaped nematodes; pseudo-root nodule, abnormal pearl nematode (TV^coMws and other pearl nematodes; needle nematodes, aphid (Zowgii/orws e/owgaies) and other nematodes Species; N. elegans, N. elegans (Parae/ewcAw·?) species; root rot nematodes, short root rot lines Insects (Prae/ewcAws bracAywrM·?), coffee short-lived nematode i (Pratylenchus coj/eae), curved needle nematode (Prai less cwrWiaiws), gangrenous nematode (Praiy/ewc/iMS gooc/eyi·), California root rot nematode ( iVtzi less /ewcws weg/eciw*?), puncture root rot nematode (Praiy/ewcJiw·? /jeweiraw·?), short-lived nematode (Praiy/ewcAws scWZmeW), disabled root rot nematode vw/wws), corn Short-body nematode (iVaij/ewcAws zeae) and other root rot nematodes (Priziy/ewc/zws); coconut red-wheel nematode (and coco/?Az7wi·) and other thin rods are slippery 138197.doc -45- 200939962 刃(Λα山·“ap/ie/ewc/iw·?) species; perforated nematodes, similar to perforated nematodes (and other nematodes) (extinction; kidney-shaped sputum, sage-sex line A (Roty! enchulus) Reniformis) and other species of the genus Nematode (and oO^/ewcAw/Ms); Shieldworm (ScwieZ/owema); Residual nematode, primitive burr nematode (7WcA〇i/orw5· /jrz'mzWvwi·) and others After Trichodorus: Ptzrairz'cAoi/orMi whor and other species of P. elegans (parfl^r/cA〇i/orMiS); Dwarf nematode 'teeth Dwarf nematodes (Ty/ewcAor/z^ywcAMS c/fl_yio«z·), ducted dwarf nematodes (T^/eWcAor/^ncAws ί/ΜΖ)/Μ5) and other dwarf nematodes (TV/ewc/ior/ ^nc/iM5) species and Merlin worm (Mer/Ww) species; citrus nematode 'sweet orange half-pricked root nematode-like) and other citrus nematodes (do / enc / iw / w) species; sword nematode, American sword Nematodes (Xiphinema americanum), A[Xiphinema index], C. elegans (^7p/u.«ewa and other species of the nematode; and other plant parasitic nematodes). [Embodiment]

The mixture according to the invention can be applied to any and all developmental stages of pests such as prints, larvae, pupa and adults. The pest can be controlled by contacting the target pest, its R source, the breeding ground, or its locus in a pesticidally effective amount of the inventive mixture or a composition comprising the mixture. “Location” means a plant, plant propagation material (preferably seed), soil, area, material or environment in which the pest is growing or growing. In a nutshell, "insecticidally effective amount" means achieving an observable impact on life, including necrosis, death, delay, interest prevention and removal, destruction or 138197.doc •46· 200939962 Other ways to reduce The effect of the rate of occurrence and activity of the target organism, the amount of the mixture of the invention or the composition comprising the mixture. The pesticidally effective amount is variable for the various mixtures/compositions used in the present invention. The pesticidally effective amount of the mixture/composition should also vary depending on the general conditions such as the desired insecticidal effect and duration, weather, target species, location, mode of administration, and the like. ^ As described above, the present invention comprises a method for improving the health of a plant, wherein the plant, the place where the plant is growing or expected to grow, or the plant propagation material from which the plant is grown is mixed with the plant in a healthy and effective amount of the present invention. . The term "plant effective amount" means an amount of the mixture of the present invention sufficient to achieve a plant health effect as defined below. More illustrative information regarding amounts, modes of administration, and suitable ratios to be used are given below. In summary, it is well known to those skilled in the art that this amount can vary over a wide range and depends on various factors, such as the cultivated plant or material being treated and the climatic conditions. © When preparing a mixture, it is preferred to use a purely active compound, depending on the need, adding other active compounds against pests (such as insecticides, herbicide fungicides) or other herbicidal or growth regulating compounds or fertilizers. Other active ingredients. The mixture of the invention is employed by treating a fungus or plant, a plant colony (preferably a seed), a material to be protected from fungal attack or soil with an insecticidally effective amount of the active compound. Or plant propagation material (preferably seed) can be carried out before and after infection by pests. Method for combating harmful fungi depending on the type of the object and the desired effect 138197.doc -47. 200939962 The application rate of the inventive mixture is 〇, 3 g/ha to 2 g/ha, preferably 5 g/ha to 2000 g/ha, more preferably 5 g/ha to 900 g/ha, especially 50 g / hectare to 75 gram / hectare. In the method of combating animal pests (insects, cocci or nematodes) depending on the type of compound and the desired effect, the application rate of the mixture according to the invention is Ο. Δg/ha to 2 〇〇〇g/ha' is preferably 5 gram/ha to 2 gram/g

It is preferably 50 gram/ha to 900 gram/ha, especially 5 gram/h to 750 gram/ha. The mixtures of the invention or compositions of such mixtures may also be used to protect plants from attack or infestation by X animal pests (insects, mites or nematodes), including contact plants, or soil or water in which the plants are growing. In the context of the present invention, the term plant refers to a whole plant, a part of a plant or a propagation material of a plant.

Plants which can be treated with the mixtures of the invention and propagation plants of such plants include all genetically modified plants or genetically modified plants, for example tolerant to herbicides or fungicides or insecticides by breeding (including genetic engineering methods). The crop used 'or has a modified characteristic compared to an existing plant' which can be produced, for example, by conventional breeding methods and/or recombination procedures. Flying wrong, the mixture according to the invention can be applied (for example, ~, ~ ~ mouth W 々 also used (from seed-type, spray treatment form, in the plough gully or worse by any other means) ; ί Plants modified by monthly genetic engineering using mutations, including (but not limited to) being sold or 'in the development of agricultural biotechnology products' 138197.doc -48· 200939962 http: //www.bio.org/speeches/pubs/er/agri_products.asp). Genetically modified plants are genetic material that has been modified by recombinant DNA techniques to allow for natural breeding by cross-breeding, mutation or natural recombination. Plants that are readily available. One or more genes have generally been integrated into the genetic material of a genetically modified plant to modify certain characteristics of the plant. Such genetic modifications also include, but are not limited to, for example, by Glycosylation or polymer addition A post-translational modification of a protein, oligopeptide or polypeptide, such as prenylation, a bupropion or a farnesylated moiety or a PEG moiety.

As a result of conventional methods of breeding or genetic engineering, plants that have been modified by breeding, mutation induction or genetic engineering have, for example, been rendered tolerant to the application of particular classes of herbicides such as hydroxyphenylpyruvate Dioxygenase (HPPD) inhibitor; acetaminolate synthase (ALS) inhibitor, such as sulfonium urea (see, for example, US 6,222,100 'WO 01/82685 'WO 00/26390 'WO 97/41218, WO 98/02526 WO 98/02527, WO 04/106529, WO 05/20673, WO 03/14357, WO φ 03/13225, WO 03/14356, WO 04/16073) or imidazolidinone (see, for example, US 6,222,100 'WO 01/ 82685, WO 00/026390, WO 97/41218, WO 98/002526, WO 98/02527, WO

• 04/106529, WO 05/20673, WO 03/014357, WO 03/13225, WO 03/14356, WO 04/16073); enolpyruvyl oxalate-3-phosphate synthase (enolpyruvylshikimate-3-phosphate) Synthase, EPSPS) inhibitors, such as glyphosate (see, for example, WO 92/00377); glutamine amine synthase (GS) inhibitors, such as glufosinate (see, for example, EP-A 242 236) , EP-A 242 246) 138197.doc -49· 200939962 or dibenzonitrile weeding

M (oxynil herbicide) (see, for example, US 5,559,024). A number of planted plants have been tolerant to weeding by the conventional method of cultivating % (mutation induced)

Μ ‘ For example, Clearfield® Summer Canola (Canola, BASF SB P ’ Germany) is a pair of microphones. Sedentary ketones, such as imazamox, have been used to make plants such as soybeans, cotton, corn, sugar beets and harvested plants tolerant to herbicides such as glyphosate and glufosinate. , _ some of these are trademarked RoundupReady® (glyphosate, Monsanto, ^ and LibertyLink®)

Bayer CropScience, n berinany) is commercially available. In addition, plants that can synthesize one or more insecticidal proteins by using recombinant DNA technology are also included. ~ Read·' or a variety of insecticidal proteins, especially from the genus Bacteroides, especially since Φ is Bacillus thuringiensis Knowers, such as δ-endotoxic Qin I' such as CrylA (b), CrylA (c), CrylF,

CryIF (a2), CryIIA (b), CrymA, CryIIIB (bl) or Cry9c; plant-based insecticidal protein (Vlp), such as VIpl, VIP2, VIP3 or VIP3A; insecticidal proteins of the bacterial nematode, such as the photobacterium spp .) or X. elegans Spp.); toxins produced by animals such as toxins, block f spider toxins, wasp toxins or other insect-specific neurotoxins; toxins produced by fungi, such as streptomyces toxins, plant lectins (plant lectin), such as cowpea or barley lectin; agglutinin; protease inhibitors such as trypsin inhibitor, serine protease inhibitor, potato patatin, cystatin Or papain inhibitor; ribosome deactivating protein (RIP), such as ricin, corn _RIP, acacia toxin 138197.doc -50- 200939962

(abrin), loofin, saporin or bryo din; steroid metabolism enzymes such as 3-amino steroid oxidase, quercetin-IDP-glycosyl- Transferase, cholesterol oxidase, ecdysone inhibitor or HMG-CoA reductase; ion channel blocker, such as sodium or calcium channel blocker; juvenile hormone esterase; diuretic hormone receptor (helicokinin receptor); Stilben synthase, bibenzyl synthase, chitinase or glucanase. In the context of the present invention, it should also be clearly understood that such pesticidal proteins or toxins are pre-toxin, hybrid proteins, proteins which have been cleaved or otherwise modified. Hybrid proteins are characterized by a new combination of protein domains (see, for example, WO 02/015701). Such toxins can be synthesized or synthesized in EP-A 374 Other examples of genetically modified plants. Methods of making such genetically modified plants are generally known and described by those skilled in the art and are described, for example, in the above publication. The genetically modified plants contain such insecticidal proteins that confer to the plants producing the proteins harmful pests to all taxa from the arthropods, especially to beetles (Coeloptera), two-winged insects (Diptera) and moth (Lepidoptera) and tolerance to nematodes (Nematodes). Genetically modified plants capable of synthesizing one or more pesticidal proteins are described, for example, in the above publication, and some of them are commercially available, such as YieldGard® (a corn-carrying variety that produces CrylAb toxin), and YieldGard® Plus (which produces Cryl Ab). And Cry3Bbl toxin corn carrier variety), Starlink® (Cry9c toxin-producing corn-borne product 138197.doc -51 · 200939962), Herculex® RW (production of Cry34Abl, Cry35Abl and enzymatic phosphonium-N-ethylidene) Transferable enzymes [Phosphinothricin-N-Acetyltransferase, PAT] in corn-cultured varieties); NuCOTN® 33B (cotton-produced varieties producing CrylAc toxin), Bollgard® 1 (cotton-produced varieties producing Cryl Ac toxin), Bollgard® 11 (cotton-carrying varieties producing Cryl Ac and Cry2Ab2 toxins); VIPCOT® (cotton-producing varieties producing VIP toxins); NewLeaf8 (potato-cultivated varieties producing Cry3A toxins); Bt-Xtra®, NatureGard®, KnockOut®, BiteGard®, Protecta®,

Bt 11 (eg Agrisure® CB) and Btl76 from Syngenta Seeds SAS, 〇France (a corn-carrying variety producing Cryl Ab toxin and PAT enzyme), MIR604 from Syngenta Seeds SAS, France (a corn producing a modified version of Cry3A toxin) For the cultured varieties, see WO 03/018810), MON 863 from Monsanto Europe SA, Belgium (a corn-carrying variety producing Cry3Bbl toxin), IPC 531 from Monsanto Europe SA, Belgium (a cotton producing a modified type of CrylAc toxin) Containing varieties) and from Pioneer Overseas Corporation, Belgium ❹ 1507 (a corn-carrying variety that produces Cry IF toxin and PAT enzyme). Also included are plants which are capable of synthesizing one or more proteins by using recombinant DNA techniques to enhance the resistance or tolerance of their plants to bacterial, viral or fungal pathogens. Examples of such proteins are the so-called "pathogenesis-related proteins" (PR proteins, see for example EP-A 392 225), plant disease resistance genes (for example, the performance against Phytophthora rainfeet (Phytophthorainfestan) is derived from Mexican wild horses. A potato-cultivated variety of potato (Solanum 13\111) 00381 Wang 1111111) or Ding 4 lysozyme 138197.doc -52- 200939962 (for example, capable of synthesizing these resistant bacteria ( A horse-fed potato-cultivated variety of a protein such as the resistant protein of Erwinia amylvora). Methods of making such genetically modified plants are generally known to those skilled in the art and are described, for example, in the above publications. In addition, it is also possible to synthesize one or more proteins by using recombinant DNA technology to increase productivity (eg, biomass yield, grain yield, starch content, oil content or protein content), for drought, salinity or other growth. Plants that limit the tolerance of environmental factors or tolerance to pests and fungal, bacterial or viral pathogens of their plants. In addition, it also encompasses plants which contain varying amounts of substances or novel substances by using recombinant DNA techniques, especially for improving human or animal nutrition, such as the production of pro-healthy long-chain omega-3 fatty acids or unsaturated omega-9 fatty acids (eg Nexera® canola, DOW Agro Sciences, Canada) oil crop. In addition, plants containing varying amounts of material or novel substances, especially for improving the yield of raw materials, by using recombinant DNA techniques, such as horseshoes producing increased amounts of amylopectin (eg Amflora® potato, BASF SE, Germany) are also contemplated. ). For the purpose of treating plant-propagating substances (especially seeds), water-soluble concentrates (LS), flowable concentrates (FS), powders for anhydrous treatment (DS), and slurry treatment (WS) are usually used. Water dispersible powders, water soluble powders (SS), emulsions (ES), emulsifiable concentrates (EC) and gels (GF). In a preferred embodiment of the invention, the mixture of the invention is used to protect plant propagation material, preferably roots and shoots of the seedlings, preferably seeds. 138197.doc -53- 200939962 Seed treatment can be carried out in a seed box and subsequently planted in the field. For the purpose of seed treatment, the weight quantification in the ternary and quaternary mixtures of the present invention will generally depend on the characteristics of the compound of the mixture of the invention. Compositions particularly suitable for seed treatment are, for example: A soluble concentrate (SL, LS) D emulsion (EW, EO, ES) E suspension (SC, OD, FS) F water dispersible granules and Water-soluble granules (WG, SG)

G water dispersible powder and water-soluble powder (wp, sp, WS) Η gel formulation (GF) I dusting powder (DP, DS)

These compositions can be applied to the plant breeding "Bei", especially seeds, in diluted or undiluted form. Such compositions may be applied in diluted or undiluted form; The compositions in question are obtained at a concentration of from 0.01% to 60% by weight, preferably from 0.1% to 4% by weight, in the ready-to-use preparation after a two-fold ten-fold dilution. Administration can be carried out before or during the sowing. The method of applying or arranging the agricultural compound and the composition thereof to the vegetable gene f (especially the seed) is the method of the present invention, and includes the number of the propagation material, coating, spheronization, dusting and Old =: (and in the treatment of Cuigou). In the preferred embodiment, the method of sputum and sputum S is indicated, for example, by seed dressing, balling, and coating. 'When a compound or a composition thereof is applied separately to a plant propagation material to a mixture of the invention, when treating a plant propagation material, preferably a seed, 138197.doc -54 - 200939962 application rate is generally used for formulated products (which typically comprise 10 §/1 to 75〇 active substances) The present invention also relates to plant reproductive products, and in particular to (ie coated and/or contain) a mixture as defined above or containing two or more active ingredients A composition of a mixture of the mixture or a mixture of two or more of the compositions (one of each providing - one of the active ingredients). The plant propagation material, preferably the seed, comprises a mixture of the invention in an amount of from § to 1 〇 kg per 100 kg of plant propagation material, preferably seed. For example, the weight of the compound I herein is preferably from 0 to 1 200 g per 100 kg of plant propagation material (preferably seed), more preferably 1 to 4 plant propagation material (preferably seed to 200 g). And preferably between 1 and 100 g per 100 kg of plant propagation material (preferably seed). For example, the weight of compound 11 (nordazide, daxen) is better in each 100 kg plant propagation material. (preferably seed}1_2〇〇g, more preferably 5 to 200 g per 100 kg of plant propagation material (preferably seed), and optimally 100 kg of plant propagation material (preferably seed) per 5 to 100 g For example, the weight of the compound „1 (Atropin, Trifluoromethylene or Orystromin (especially orientizidine)) is preferably in the amount of 1 〇〇kg of plant propagation material (preferably Seed) 1_2〇〇g, more preferably 1 to 50 g per 1 kg of plant propagation material (preferably seed) and optimally per 100 kg of plant propagation material (preferably between the seed mouth and 20 g. Independent or A compound for the combined application of the mixture of the invention is by before or after plant sowing or before or after plant sprouting Spraying or dusting seeds, seedlings, plants or soil. 138197.doc -55- 200939962 The mixture of the invention is contacted (via soil, glass, wall, bed net, carpet, plant part or animal part) and ingested ( _ or plant illusion and effective through feeding and transfer. The preferred method of application is to enter the body of water, through soil, cracks and gaps, grazing 2 fertilizer piles, sewers, into the water, on the floor, on the wall, or by spraying around According to another preferred embodiment of the present invention, the mixture of the present invention is prepared for use against non-crop pests such as ants, termites, wasps, ropes, mosquitoes, worms, worms or cockroaches. It is a bait preparation. The bait can be a liquid, solid or semi-solid preparation (such as a gel). The bait used in the composition is sufficiently attractive to attract such as ants, termites, wasps, flies, mosquitoes, cockroaches, etc. Insects to eat their products. 2 The attractant may be selected from the pheromone and/or sex pheromone known in the art. The mixture of the present invention and its individual The method of controlling infectious diseases transmitted by insects (such as malaria, dengue and yellow fever, lymphatic filariasis and leishmaniasis) also includes treatment of sheds and house surfaces, air spray and Dipping curtains, tents, articles of clothing, bed nets, tsetse fly traps or the like. The insecticidal composition applied to fibers, fabrics, knits, non-woven fabrics, mesh materials or pigs and tarpaulins preferably comprises A composition comprising a mixture of the invention, optionally a repellent, and at least one binder. The mixture of the invention and compositions comprising the same can be used to protect wooden materials such as trees, plank fences, sleepers, etc., and such as houses, 138197.doc -56- 200939962 Factory buildings' and building materials, furniture, leather, fibers, baked goods, wires and cables are protected from ants and/or termites, and are used to control ants and termites from crops. Or human hazards (such as when pests invade houses and public facilities). - In the case of soil treatment or application to pest houses or nests, the amount of active ingredient ~ is from 0001.0001 g/1〇〇m2 to 500^00 m2, preferably 0.001 g/1〇〇m2 to 20g/100m2 Within the scope. In material protection, the usual application rate is, for example, 每_〇1 g to 1000 g of active compound per square meter of treated material, ideally 〇 ^ g to 50 g per square meter. The pesticidal composition for the impregnated material generally contains from 〇〇〇丨% by weight to 95% by weight, preferably from 0.1% by weight to 45% by weight, and more preferably from 3% by weight to 25% by weight, of at least one repellent. And / or pesticides. For use in a bait composition, the active ingredient is typically present in an amount from 〇〇〇 〇〇〇 to 15% by weight, desirably from 1% to 5% by weight of the activated conjugate. The compositions used may also contain other additives such as active ingredients/mixtures, flavoring agents, preservatives, dyes or bitter agents. Its appeal can also be enhanced by a specific color, shape or texture. • The content of the mixture of the active ingredients used in the mouth spray composition is 0.001% by weight. /. To 8% by weight, preferably 〇1% by weight to 5% by weight and most preferably from 0.01% by weight to 15% by weight. 138197.doc •57-

Claims (1)

200939962 VII. Scope of Application: 1. A mixture comprising a synergistically effective amount of the following components as an active ingredient: 1) an insecticidal compound selected from the following nicotinic receptor agonist/antagonist compounds: D Acetamiprid, clothianidin, dinotefuran, imidacloprid, thiamethoxam, nitenpyram; and 2 Selecting the fungicidal compound II of the group of metalaxyl and dimethomorph; and 3) selecting azoxystrobin, trifloxystrobin, oryzanamide (orysastrobin) a group of fungicidal compounds III. 2. A mixture according to claim 1 which comprises cotinine, imidacloprid or thiamethoxam as compound I. 3. A mixture according to claim 1 which comprises statin as compound II. 4. A mixture according to any one of claims 1 to 2 which comprises oritamycin as compound III. ❹ 5. A mixture comprising a synergistically effective amount of the following as an active ingredient: 1) an insecticidal compound selected from the group consisting of the following nicotinic receptor agonist/antagonist compounds: acetamiprid lung, cotinine , Dinnotfuran, imidacloprid, thiamethoxam, dilute π-amylin, and 2) damasfen. 6. A mixture comprising a synergistically effective amount of each of the following as active ingredients: 138197.doc 200939962 1) Atramine or trifluoro-sensitive; and 2) damassol. 7. The mixture of claim 1, which comprises as a compound guanidine, as a compound II, a chlorhexidine, and as a compound oxime. 8. A pesticidal composition comprising a liquid or solid carrier and a mixture according to any one of claims 1 to 7. 9 · A method of controlling pests and/or improving plant health, wherein (a) the pest, its habitat, breeding ground, its location or plants, soil or plant propagation material that is awaiting protection from pests; or (b) The plant, the locus where the plant is growing or expected to grow, or the plant-producing material from which the plant is grown; is treated with an effective amount of a mixture of any one of claims 1-5. 10. A method of controlling harmful fungi and/or improving the health of a plant, wherein (8) the true product, its habitat, the breeding ground, its location or a plant, soil or plant propagation material that is awaiting protection against fungal attack; or (b) The plant, the locus where the plant is growing or expected to grow, or the plant propagation material from which the plant is grown; treated with an effective amount of a mixture according to any one of claims 6 or 7. 11. A method of protecting plant propagation material f from pest infestation comprising contacting the plant propagation material with a pesticidally effective amount of a mixture of any one of claims 7-14. 12. The method of claim 月i, wherein the mixture of any one of claims 丨 to 8 is applied in an amount of 001 § to 1 每 1 ^ per plant propagation material. The method of any one of items 9 to 12, wherein the 138197.doc 200939962, the defined compound I and the compound II are simultaneously, i.e., combined or independently, or continuously administered, as claimed in any one of the claims 1-4. A mixture of any one of claims 1 to 7 in an amount of from 0.01 g to 10 kg per 100 kg of plant propagation material. 138197.doc 200939962 IV. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbol of the symbol of the representative figure is simple: 5. If there is a chemical formula in this case, please reveal the best indication of the characteristics of the invention. Chemical formula: (none) 138197.doc