RU93004865A - Способы получения диоксида хлора - Google Patents
Способы получения диоксида хлораInfo
- Publication number
- RU93004865A RU93004865A RU93004865/26A RU93004865A RU93004865A RU 93004865 A RU93004865 A RU 93004865A RU 93004865/26 A RU93004865/26 A RU 93004865/26A RU 93004865 A RU93004865 A RU 93004865A RU 93004865 A RU93004865 A RU 93004865A
- Authority
- RU
- Russia
- Prior art keywords
- chlorine dioxide
- methods
- chloric acid
- chlorate
- producing chlorine
- Prior art date
Links
- OSVXSBDYLRYLIG-UHFFFAOYSA-N Chlorine dioxide Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims 6
- 239000004155 Chlorine dioxide Substances 0.000 title claims 3
- 235000019398 chlorine dioxide Nutrition 0.000 title claims 3
- XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims 5
- YZHUMGUJCQRKBT-UHFFFAOYSA-M Sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 claims 3
- 229940005991 chloric acid Drugs 0.000 claims 3
- 229940080281 sodium chlorate Drugs 0.000 claims 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 1
- 239000012431 aqueous reaction media Substances 0.000 claims 1
- 239000007864 aqueous solution Substances 0.000 claims 1
- 239000007844 bleaching agent Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- PMZURENOXWZQFD-UHFFFAOYSA-L na2so4 Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 1
- 239000012429 reaction media Substances 0.000 claims 1
- 229910052938 sodium sulfate Inorganic materials 0.000 claims 1
- 235000011152 sodium sulphate Nutrition 0.000 claims 1
- 238000005670 sulfation reaction Methods 0.000 claims 1
- 239000002699 waste material Substances 0.000 claims 1
Claims (1)
- Диоксид хлора, применяемый в качестве отбеливателя, получают без отходов, содержащих сульфат натрия, от которого нужно избавляться, путем восстановления хлорноватой кислоты в водной реакционной среде в реакционной зоне с общей нормальностью кислоты до 7 H при реальном отсутствии сульфатиона и в присутствии холостой загрузки хлората натрия, добавляемой и затем удаляемой из реакционной среды. Хлорноватую кислоту для процесса получают электролитическим способом из водного раствора холостой загрузки хлората натрия и хлората натрия, добавленного для возмещения расхода хлората. Восстановление хлорноватой кислоты с целью получения диоксида хлора можно осуществить с использованием метанола или электролитически.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2023733 | 1990-08-21 | ||
CA002023733A CA2023733C (en) | 1990-08-21 | 1990-08-21 | Chlorine dioxide generation from chloric acid |
PCT/CA1991/000245 WO1992003374A1 (en) | 1990-08-21 | 1991-07-11 | Chlorine dioxide generation from chloric acid |
Publications (2)
Publication Number | Publication Date |
---|---|
RU93004865A true RU93004865A (ru) | 1997-02-20 |
RU2112817C1 RU2112817C1 (ru) | 1998-06-10 |
Family
ID=4145789
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU93004865A RU2112817C1 (ru) | 1990-08-21 | 1991-07-11 | Способы получения диоксида хлора |
Country Status (15)
Country | Link |
---|---|
US (1) | US5174868A (ru) |
EP (1) | EP0544686B1 (ru) |
JP (1) | JPH07112924B2 (ru) |
CN (1) | CN1062032C (ru) |
AT (1) | ATE123477T1 (ru) |
AU (1) | AU651359B2 (ru) |
BR (1) | BR9106778A (ru) |
CA (1) | CA2023733C (ru) |
DE (1) | DE69110288D1 (ru) |
ES (1) | ES2073168T3 (ru) |
FI (1) | FI111705B (ru) |
MX (1) | MX9100763A (ru) |
RU (1) | RU2112817C1 (ru) |
WO (1) | WO1992003374A1 (ru) |
ZA (1) | ZA915600B (ru) |
Families Citing this family (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5348683A (en) * | 1990-02-06 | 1994-09-20 | Olin Corporation | Chloric acid - alkali metal chlorate mixtures and chlorine dioxide generation |
US5258105A (en) * | 1990-02-06 | 1993-11-02 | Olin Corporation | Chloric acid - alkali metal chlorate mixtures and chlorine dioxide generation |
US5242554A (en) * | 1990-02-06 | 1993-09-07 | Olin Corporation | Electrolytic production of chloric acid and sodium chlorate mixtures for the generation of chlorine dioxide |
US5322598A (en) * | 1990-02-06 | 1994-06-21 | Olin Corporation | Chlorine dioxide generation using inert load of sodium perchlorate |
US5284553A (en) * | 1990-08-22 | 1994-02-08 | Sterling Canada, Inc. | Chlorine dioxide generation from chloric acid |
US5486344A (en) * | 1992-06-09 | 1996-01-23 | Eka Nobel Inc. | Method of producing chlorine dioxide |
US5487881A (en) * | 1993-02-26 | 1996-01-30 | Eka Nobel Inc. | Process of producing chlorine dioxide |
GB9309769D0 (en) * | 1993-05-12 | 1993-06-23 | Sterling Pulp Chem Ltd | Chlorine dioxide generation for water treatment |
US5480516A (en) * | 1993-05-12 | 1996-01-02 | Sterling Pulp Chemicals, Ltd. | Electrolytic production of acid |
US5478446A (en) * | 1993-07-02 | 1995-12-26 | Eka Nobel Inc. | Electrochemical process |
WO1995001466A1 (en) * | 1993-07-02 | 1995-01-12 | Eka Nobel Ab | Electrochemical process |
US5407547A (en) * | 1993-10-06 | 1995-04-18 | Eka Nobel Ab | Process for production of acidified process streams |
SE9402856L (sv) * | 1994-08-26 | 1995-11-27 | Eka Nobel Ab | Process of producing chlorine dioxide |
US5599518A (en) * | 1994-12-01 | 1997-02-04 | Olin Corporation | Catalytic process for chlorine dioxide generation from chloric acid |
US5965004A (en) * | 1996-03-13 | 1999-10-12 | Sterling Pulp Chemicals, Ltd. | Chlorine dioxide generation for water treatment |
US5792441A (en) * | 1996-10-11 | 1998-08-11 | Pulp And Paper Research Institute Of Canada | Fixed-resin bed technologies for the treatment of the chlorine dioxide generator effluent and feeds stream |
US6322768B1 (en) | 1998-09-29 | 2001-11-27 | International Paper Company | Recovery of chlorine dioxide from gas streams |
KR100817730B1 (ko) | 2007-04-26 | 2008-03-31 | 주식회사 대한이엔비 | 이산화염소 발생장치 및 제조방법 |
WO2010074686A1 (en) * | 2008-12-23 | 2010-07-01 | Calera Corporation | Low-energy electrochemical hydroxide system and method |
TWI447065B (zh) * | 2007-07-13 | 2014-08-01 | Akzo Nobel Nv | 二氧化氯之製造方法 |
US20100239467A1 (en) | 2008-06-17 | 2010-09-23 | Brent Constantz | Methods and systems for utilizing waste sources of metal oxides |
JP5373079B2 (ja) | 2008-07-16 | 2013-12-18 | カレラ コーポレイション | 電気化学システム中でのco2の利用 |
US8869477B2 (en) | 2008-09-30 | 2014-10-28 | Calera Corporation | Formed building materials |
AU2010201005A1 (en) | 2009-02-10 | 2010-08-26 | Calera Corporation | Low-voltage alkaline production using hydrogen and electrocatlytic electrodes |
BRPI1009150A2 (pt) | 2009-03-02 | 2016-03-01 | Calera Corp | sistemas de controle de multi-poluentes de fluxos de gás e métodos |
US9546427B2 (en) * | 2011-06-10 | 2017-01-17 | Michael Lumetta | System and method for generating a chlorine-containing compound |
US11279617B2 (en) | 2011-11-25 | 2022-03-22 | Juan Carlos Baselli | Portable chlorine dioxide generator |
US20130136685A1 (en) | 2011-11-25 | 2013-05-30 | Juan Carlos Baselli | Portable Chlorie Dioxide Generator |
JP6359344B2 (ja) * | 2014-05-13 | 2018-07-18 | 医療環境テクノ株式会社 | 二酸化塩素を含む水溶液製造方法及び水蒸気発生装置 |
ES2676493T3 (es) * | 2014-07-17 | 2018-07-20 | Industrie De Nora S.P.A. | Generación electrocatalítica de dióxido de cloro |
TWI534300B (zh) * | 2014-12-24 | 2016-05-21 | Shen Zheng Cang | Efficient production of chlorine dioxide electrolysis device |
CN104891442A (zh) * | 2015-05-06 | 2015-09-09 | 湖北南五洲生化科技有限公司 | 制备高纯度二氧化氯的方法 |
Family Cites Families (29)
Publication number | Priority date | Publication date | Assignee | Title |
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US2811420A (en) * | 1954-11-17 | 1957-10-29 | Hooker Electrochemical Co | Chlorine dioxide generation |
US3864456A (en) * | 1964-08-13 | 1975-02-04 | Electric Reduction Co | Manufacture of chlorine dioxide, chlorine and anhydrous sodium sulphate |
US3810969A (en) * | 1971-06-22 | 1974-05-14 | Hooker Chemical Corp | Process for the production of chlorine dioxide |
US4024043A (en) * | 1975-12-31 | 1977-05-17 | Allied Chemical Corporation | Single film, high performance bipolar membrane |
CA1080433A (en) * | 1976-03-19 | 1980-07-01 | Erco Industries Limited | High efficiency chlorine dioxide production at low acidity |
CA1090091A (en) * | 1976-03-19 | 1980-11-25 | Richard Swindells | Production of chlorine dioxide from buffered reaction media |
US4057481A (en) * | 1976-05-24 | 1977-11-08 | Allied Chemical Corporation | High performance, quality controlled bipolar membrane |
US4116889A (en) * | 1976-08-19 | 1978-09-26 | Allied Chemical Corporation | Bipolar membranes and method of making same |
GB1544774A (en) * | 1977-01-24 | 1979-04-25 | Secr Defence | Radio identification systems |
US4253900A (en) * | 1977-02-28 | 1981-03-03 | Allied Chemical Corporation | Method of making novel two component bipolar ion exchange membranes |
US4355116A (en) * | 1980-12-29 | 1982-10-19 | Allied Corporation | Stable high performance bipolar membrane with cross-linked functional groups |
US4426263A (en) * | 1981-04-23 | 1984-01-17 | Diamond Shamrock Corporation | Method and electrocatalyst for making chlorine dioxide |
US4465658A (en) * | 1983-06-13 | 1984-08-14 | Erco Industries Limited | Chlorine dioxide process |
US4473540A (en) * | 1983-07-07 | 1984-09-25 | Erco Industries Limited | High efficiency chlorine dioxide process |
US4584246A (en) * | 1983-11-23 | 1986-04-22 | Chinese Petroleum Corp. | Bipolar membranes |
US4673454A (en) * | 1983-11-23 | 1987-06-16 | Chinese Petroleum Corp. | Process for preparing bipolar membranes |
US4627969A (en) * | 1984-09-05 | 1986-12-09 | Tenneco Canada Inc. | Production of chlorine dioxide |
CA1287815C (en) * | 1987-05-29 | 1991-08-20 | Marek Lipsztajn | Electrolytic production of chlorine dioxide |
US4767510A (en) * | 1987-06-03 | 1988-08-30 | Tenneco Canada Inc. | Electrolytic protection of chlorine dioxide |
US4798715A (en) * | 1988-02-05 | 1989-01-17 | Eltech Systems Corporation | Producing chlorine dioxide from chlorate salt |
JPH021917A (ja) * | 1988-06-09 | 1990-01-08 | Nec Corp | 半導体集積回路 |
SE463669B (sv) * | 1988-06-17 | 1991-01-07 | Eka Nobel Ab | Foerfarande foer framstaellning av klordioxid |
JPH0232356A (ja) * | 1988-07-21 | 1990-02-02 | Fujitsu Ltd | 半導体装置の製造方法 |
US4806215A (en) * | 1988-07-27 | 1989-02-21 | Tenneco Canada Inc. | Combined process for production of chlorine dioxide and sodium hydroxide |
SE463670B (sv) * | 1988-10-11 | 1991-01-07 | Eka Nobel Ab | Foerfarande foer framstaellning av klordioxid |
US4915927A (en) * | 1988-10-21 | 1990-04-10 | Tenneco Canada Inc. | Production of chloric acid |
US5084148A (en) * | 1990-02-06 | 1992-01-28 | Olin Corporation | Electrochemical process for producing chloric acid - alkali metal chlorate mixtures |
US5089095A (en) * | 1990-03-30 | 1992-02-18 | Olin Corporation | Electrochemical process for producing chlorine dioxide from chloric acid |
JPH04326370A (ja) * | 1991-04-26 | 1992-11-16 | Ricoh Co Ltd | 電子写真プロセス制御装置 |
-
1990
- 1990-08-21 CA CA002023733A patent/CA2023733C/en not_active Expired - Lifetime
- 1990-08-22 US US07/570,791 patent/US5174868A/en not_active Expired - Lifetime
-
1991
- 1991-07-11 DE DE69110288T patent/DE69110288D1/de not_active Expired - Lifetime
- 1991-07-11 WO PCT/CA1991/000245 patent/WO1992003374A1/en active IP Right Grant
- 1991-07-11 BR BR919106778A patent/BR9106778A/pt not_active IP Right Cessation
- 1991-07-11 EP EP91912606A patent/EP0544686B1/en not_active Expired - Lifetime
- 1991-07-11 AT AT91912606T patent/ATE123477T1/de active
- 1991-07-11 JP JP3511596A patent/JPH07112924B2/ja not_active Expired - Fee Related
- 1991-07-11 ES ES91912606T patent/ES2073168T3/es not_active Expired - Lifetime
- 1991-07-11 AU AU81805/91A patent/AU651359B2/en not_active Expired
- 1991-07-11 RU RU93004865A patent/RU2112817C1/ru active
- 1991-07-17 ZA ZA915600A patent/ZA915600B/xx unknown
- 1991-08-21 MX MX9100763A patent/MX9100763A/es unknown
- 1991-08-21 CN CN91105818A patent/CN1062032C/zh not_active Expired - Lifetime
-
1993
- 1993-02-19 FI FI930763A patent/FI111705B/fi not_active IP Right Cessation
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