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RU2006127039A - Способ применения полимеров, функционализированных альдегидом, для улучшения обезвоживания в бумагоделательных машинах - Google Patents

Способ применения полимеров, функционализированных альдегидом, для улучшения обезвоживания в бумагоделательных машинах Download PDF

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Publication number
RU2006127039A
RU2006127039A RU2006127039/12A RU2006127039A RU2006127039A RU 2006127039 A RU2006127039 A RU 2006127039A RU 2006127039/12 A RU2006127039/12 A RU 2006127039/12A RU 2006127039 A RU2006127039 A RU 2006127039A RU 2006127039 A RU2006127039 A RU 2006127039A
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Prior art keywords
aldehyde
functionalized
mol
monomers
copolymer
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RU2006127039/12A
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English (en)
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RU2361977C2 (ru
Inventor
ДЖОН Майкл Р. СЕНТ (US)
ДЖОН Майкл Р. СЕНТ
Энджел П. ЗАГАЛА (US)
Энджел П. ЗАГАЛА
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Налко Компани (Us)
Налко Компани
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Application filed by Налко Компани (Us), Налко Компани filed Critical Налко Компани (Us)
Publication of RU2006127039A publication Critical patent/RU2006127039A/ru
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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03Non-macromolecular organic compounds
    • D21H17/05Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/06Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H3/00Paper or cardboard prepared by adding substances to the pulp or to the formed web on the paper-making machine and by applying substances to finished paper or cardboard (on the paper-making machine), also when the intention is to impregnate at least a part of the paper body
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/46Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/54Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
    • D21H17/55Polyamides; Polyaminoamides; Polyester-amides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/28Condensation with aldehydes or ketones
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/06Paper forming aids
    • D21H21/10Retention agents or drainage improvers
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/18Reinforcing agents
    • D21H21/20Wet strength agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/10Copolymer characterised by the proportions of the comonomers expressed as molar percentages
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • D21H17/375Poly(meth)acrylamide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Paper (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Claims (14)

1. Способ улучшения обезвоживания бумажного листа на бумагоделательной машине, отличающийся тем, что он включает добавление к бумажному листу от примерно 0,05 до примерно 15 фунт/т в расчете на сухое волокно одного или нескольких полимеров, функционализованных альдегидом, содержащих амино- или амидогруппы, где по меньшей мере примерно 15 моль.% амино- или амидогрупп функционализованы путем реакции с одним или несколькими альдегидами и где полимеры, функционализованные альдегидом, имеют средневесовой молекулярный вес по меньшей мере примерно 100000 г/моль.
2. Способ по п.1, отличающийся тем, что функционализованные альдегидом полимеры выбраны из группы, состоящей из полиаминов, функционализованных альдегидом, и полиамидов, функционализованных альдегидом, а альдегиды выбраны из формальдегида, параформальдегида, глиоксаля и глутаральдегида.
3. Способ по п.1, отличающийся тем, что функционализованный альдегидом полимер является функционализованным альдегидом полиамидом и данный функционализованный альдегидом полимер содержит 100 моль.% одного или нескольких неионных мономеров.
4. Способ по п.2, отличающийся тем, что функционализованный альдегидом полиамид является функционализованным альдегидом сополимером, содержащим от 5 до 99 моль.% одного или нескольких акриламидных мономеров и от 95 до 1 моль.% одного или нескольких катионных, анионных или цвиттер-ионных мономеров, или их смеси.
5. Способ по п.6, отличающийся тем, что функционализованный альдегидом полиамид является функционализованным альдегидом сополимером, содержащим от 1 до 50 моль.% процентов одного или нескольких анионных мономеров и от 99 до 50 моль.% одного или нескольких неионных мономеров.
6. Способ по п.4, отличающийся тем, что функционализованный альдегидом полиамид является функционализованным альдегидом сополимером, содержащим от 1 до 30 моль.% одного или нескольких анионных мономеров и от 99 до 70 моль.% одного или нескольких неионных мономеров.
7. Способ по п.4, отличающийся тем, что функционализованный альдегидом сополимер является функционализованным альдегидом амфотерным полимером, содержащим до 40 моль.% одного или нескольких катионных мономеров и до 20 моль.% одного или нескольких анионных мономеров.
8. Способ по п.4, отличающийся тем, что функционализованный альдегидом сополимер является функционализованным альдегидом цвиттер-ионным полимером, содержащим от 1 до 95 моль.% одного или нескольких цвиттер-ионных мономеров.
9. Способ по п.4, отличающийся тем, что функционализованный альдегидом полиамид является функционализованным альдегидом сополимером, содержащим от 50 до 99 моль.% одного или нескольких акриламидных мономеров и от 50 до 1 моль.% одного или нескольких катионных мономеров, и по меньшей мере 20 моль.% амидных групп полиамида прореагировали с альдегидом.
10. Способ по п.1, отличающийся тем, что функционализованный альдегидом полимер является сополимером, содержащим от 50 до 99 моль.% одного или нескольких акриламидных мономеров и от 50 до 1 моль.% одного или нескольких катионных мономеров, где данный сополимер функционализирован глиоксалем, а катионный мономер является (диаллил-N,N-дизамещенный аммоний)галогенидным мономером, причем от 20 до 50 моль.% амидных групп сополимера прореагировали с глиоксалем.
11. Способ по п.10, отличающийся тем, что неионный мономер является акриламидом, а (диаллил-N,N-дизамещенный аммоний)галогенидный мономер является диаллилдиметиламмонийхлоридом с молекулярным весом по меньшей мере 300000 г/моль.
12. Способ по п.11, отличающийся тем, что функционализованный альдегидом полимер является сополимером, содержащим от 70 до 99 моль.% акриламида и от 1 до 30 моль.% диаллилдиметиламмонийхлорида, функционализованного глиоксалем.
13. Способ по п.12, отличающийся тем, что в бумажный лист добавляют от примерно 0,5 до примерно 3 фунт/т в расчете на сухое волокно глиоксилированного сополимера.
14. Способ по п.1, отличающийся тем, что функционализованный альдегидом полимер напыляют на бумажный лист до прессового обезвоживания.
RU2006127039/12A 2004-01-26 2005-01-21 Способ применения полимеров, функционализированных альдегидом, для улучшения обезвоживания в бумагоделательных машинах RU2361977C2 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/764,935 US7641766B2 (en) 2004-01-26 2004-01-26 Method of using aldehyde-functionalized polymers to enhance paper machine dewatering
US10/764,935 2004-01-26

Publications (2)

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RU2006127039A true RU2006127039A (ru) 2008-02-10
RU2361977C2 RU2361977C2 (ru) 2009-07-20

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US (4) US7641766B2 (ru)
EP (2) EP1709246B1 (ru)
JP (1) JP4833861B2 (ru)
KR (2) KR101243047B1 (ru)
CN (2) CN1914375A (ru)
AT (1) ATE548506T1 (ru)
AU (1) AU2005208709B2 (ru)
BR (1) BRPI0506686B1 (ru)
CA (1) CA2551160C (ru)
ES (2) ES2381793T3 (ru)
NO (1) NO340993B1 (ru)
NZ (1) NZ548349A (ru)
RU (1) RU2361977C2 (ru)
TW (1) TWI385290B (ru)
WO (1) WO2005072185A2 (ru)
ZA (1) ZA200605581B (ru)

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CN1914375A (zh) 2007-02-14
USRE44936E1 (en) 2014-06-10
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CA2551160C (en) 2015-06-16
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