RO81212B - Procedeu pentru prepararea unor 2', 6'-dialchil-n-(alcoximetil)-2-cloracetanilide - Google Patents
Procedeu pentru prepararea unor 2', 6'-dialchil-n-(alcoximetil)-2-cloracetanilideInfo
- Publication number
- RO81212B RO81212B RO100898A RO10089880A RO81212B RO 81212 B RO81212 B RO 81212B RO 100898 A RO100898 A RO 100898A RO 10089880 A RO10089880 A RO 10089880A RO 81212 B RO81212 B RO 81212B
- Authority
- RO
- Romania
- Prior art keywords
- general formula
- dialkyl
- same
- dialkylaniline
- reaction
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C233/00—Carboxylic acid amides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C233/00—Carboxylic acid amides
- C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
- C07C233/24—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring
- C07C233/25—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of an acyclic saturated carbon skeleton
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Dentistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Inventia se refera la un procedeu pentru prepararea unor 2',6-dialchil-N-(alcoximetil)-2-cloracetanilide cu formula generala I: (vezi formula) în care R1, R2 si R3, care pot fi identici sau diferiti, reprezinta radicali alchil liniari sau ramificati cu 1 pîna la 4 atomi de carbon, pornind de la 2,6-dialchilanilina cu formula generala II: (vezi formula) în care R1 si R2 au semnificatiile de mai sus, trecînd printr-o baza Schiff cu formula generala III: (vezi formula) în care R1 si R2 au semnificatiile de mai sus, prin reactia 2,6-dialchilanilinei avînd formula generala II într-un mediu de solvent apolar, la temperaturi ridicate, cu o solutie de formaldehida în exces, reactia bazei Schiff avînd formula generala III cu clorura de cloracetil în aceleasi mediu de solvent apolar cu formarea 2,6-dialchil-N-(clormetil)-2-cloracetaninei corespunzatoare avînd formula generala IV: (vezi formula) în care R1 si R2 au semnificatiile de mai sus si reactia într-o treapta a ultimului compus în acelasi mediu avînd formula generala V: (vezi formula) în care R3 are semnificatiile de mai sus, într-un exces suficient pentru legarea acidului clorhidric format fara adaugarea unui acceptor de acid.........
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
HU79NI225A HU177876B (en) | 1979-04-24 | 1979-04-24 | Process for preparing 2,6-dialkyl-n-/alkoxy-methyl/-chloro-acetanilide derivatives |
Publications (2)
Publication Number | Publication Date |
---|---|
RO81212A RO81212A (ro) | 1983-02-15 |
RO81212B true RO81212B (ro) | 1983-02-28 |
Family
ID=11000009
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RO100898A RO81212B (ro) | 1979-04-24 | 1980-04-19 | Procedeu pentru prepararea unor 2', 6'-dialchil-n-(alcoximetil)-2-cloracetanilide |
Country Status (31)
Country | Link |
---|---|
US (1) | US4399306A (ro) |
JP (1) | JPS55143942A (ro) |
AR (1) | AR222075A1 (ro) |
AT (1) | AT367739B (ro) |
AU (1) | AU532840B2 (ro) |
BE (1) | BE880509A (ro) |
BG (1) | BG34610A3 (ro) |
BR (1) | BR8002193A (ro) |
CA (1) | CA1130317A (ro) |
CH (1) | CH647500A5 (ro) |
CS (1) | CS215057B2 (ro) |
DD (1) | DD150741A5 (ro) |
DE (1) | DE3015641C2 (ro) |
DK (1) | DK153543C (ro) |
ES (1) | ES8200327A1 (ro) |
FR (1) | FR2455032A1 (ro) |
GB (1) | GB2048868B (ro) |
GR (1) | GR74072B (ro) |
HU (1) | HU177876B (ro) |
IE (1) | IE49091B1 (ro) |
IL (1) | IL58529A (ro) |
IN (1) | IN151405B (ro) |
IT (1) | IT1146228B (ro) |
LU (1) | LU82242A1 (ro) |
NL (1) | NL185920C (ro) |
NO (1) | NO150601C (ro) |
PL (1) | PL122687B1 (ro) |
PT (1) | PT70537A (ro) |
RO (1) | RO81212B (ro) |
TR (1) | TR20505A (ro) |
YU (1) | YU41899B (ro) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5155272A (en) * | 1976-12-29 | 1992-10-13 | Monsanto Company | Process for the production of haloacylamides |
HU190681B (en) * | 1982-01-15 | 1986-10-28 | Eszakmagyar Vegyimuevek | Process for production of n-alcoxi-alkyl-2,6-dialkylchlor-acetanilids |
DE69220221T2 (de) * | 1991-04-04 | 1997-09-18 | Zeneca Ltd | Verfahren zur durchfuehrung von chemischen reaktionen mit formaldehyd |
DE69609849T2 (de) * | 1995-09-22 | 2000-12-21 | Zeneca Ltd., London | Verfahren zur herstellung von azomethinen und alpha-haloacetaniliden |
JP4957768B2 (ja) | 2009-09-02 | 2012-06-20 | トヨタ自動車株式会社 | 冷却風導入構造 |
CN107868020A (zh) * | 2017-10-30 | 2018-04-03 | 安徽富田农化有限公司 | 一种甲草胺的制备方法 |
CN109970599A (zh) * | 2017-12-28 | 2019-07-05 | 山东侨昌化学有限公司 | 一种连续合成乙草胺中间体n-2-甲基-6-乙基苯基甲亚胺的方法 |
CN114031519B (zh) * | 2021-12-08 | 2024-04-26 | 浙江工业大学 | 一种合成n-芳基亚胺的方法 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3347858A (en) * | 1967-10-17 | Tertiary aminoethyl | ||
US2863752A (en) * | 1953-10-30 | 1958-12-09 | Monsanto Chemicals | Herbicides |
NL142872C (ro) * | 1963-03-28 | |||
FR1458932A (fr) * | 1963-08-22 | 1966-04-29 | Monsanto Co | Procédés de préparation d'azométhines et de leurs dérivés et nouveaux produits ainsi obtenus |
US3268324A (en) * | 1965-10-11 | 1966-08-23 | Monsanto Co | Herbicidal composition and method employing oxa aliphatic acetamide |
US3442945A (en) * | 1967-05-22 | 1969-05-06 | Monsanto Co | Phytotoxic alpha-halo-acetanilides |
US3547620A (en) * | 1969-01-23 | 1970-12-15 | Monsanto Co | N-(oxamethyl)alpha-halo-acetanilide herbicides |
DE1903198A1 (de) * | 1969-01-23 | 1970-08-06 | Basf Ag | Substituierte Anilide |
US3630716A (en) * | 1969-09-03 | 1971-12-28 | Monsanto Co | Herbicidal compositions |
US3637847A (en) * | 1969-09-03 | 1972-01-25 | Monsanto Co | N-haloalkyl-anilides |
BE788215A (fr) * | 1971-09-01 | 1973-02-28 | Ciba Geigy | Haloacetanilides utiles comme herbicides |
US3952056A (en) * | 1972-02-07 | 1976-04-20 | Ciba-Geigy Corporation | Plant growth regulating agent |
BE795197A (fr) * | 1972-02-11 | 1973-08-09 | Ciba Geigy | Acylamines d'hydrocarbures bicycliques agissant sur la croissance des plantes |
US3937730A (en) * | 1972-06-06 | 1976-02-10 | Ciba-Geigy Corporation | Plant growth regulating agent |
US4070179A (en) * | 1973-02-07 | 1978-01-24 | Ciba-Geigy Corporation | Plant growth regulation with N-(2-alkoxy-ethyl)-N-chloroacetyl-2,3,6-trimethyl-anilines |
CH579348A5 (ro) * | 1973-02-08 | 1976-09-15 | Ciba Geigy Ag | |
PL103793B1 (pl) * | 1976-03-19 | 1979-07-31 | Monsanto Co | Srodek chwastobojczy |
ES465723A1 (es) * | 1976-12-29 | 1978-10-01 | Monsanto Co | Procedimiento para la preparacion y recuperacion de haloge- noacilamidas. |
FR2376801A1 (fr) * | 1977-01-07 | 1978-08-04 | Lequeux Christian | Perfectionnements aux dispositifs de protection mecanique des tranches annulaires de tubes ou embouts tubulaires |
US4261733A (en) * | 1978-11-30 | 1981-04-14 | Monsanto Company | Herbicidal compounds and method of preparation and use |
ZA811810B (en) * | 1980-03-25 | 1982-04-28 | Monsanto Co | A process for the in-solvent,in-situ generation of haloalkyl alkyl ethers useful ot produce n-subsituted-2-haloacetanilides |
-
1979
- 1979-04-24 HU HU79NI225A patent/HU177876B/hu unknown
- 1979-10-22 IL IL58529A patent/IL58529A/xx unknown
- 1979-10-23 IE IE2029/79A patent/IE49091B1/en unknown
- 1979-11-13 JP JP14614179A patent/JPS55143942A/ja active Granted
- 1979-11-27 NL NLAANVRAGE7908591,A patent/NL185920C/xx not_active IP Right Cessation
- 1979-12-03 PT PT70537A patent/PT70537A/pt unknown
- 1979-12-07 YU YU2987/79A patent/YU41899B/xx unknown
- 1979-12-10 BE BE1/9639A patent/BE880509A/fr not_active IP Right Cessation
- 1979-12-10 FR FR7930184A patent/FR2455032A1/fr active Granted
- 1979-12-18 US US06/104,918 patent/US4399306A/en not_active Expired - Lifetime
- 1979-12-26 IN IN1342/CAL/79A patent/IN151405B/en unknown
-
1980
- 1980-01-21 CA CA344,036A patent/CA1130317A/en not_active Expired
- 1980-02-04 GR GR61118A patent/GR74072B/el unknown
- 1980-02-26 TR TR20505A patent/TR20505A/xx unknown
- 1980-03-11 LU LU82242A patent/LU82242A1/de unknown
- 1980-03-18 CH CH2104/80A patent/CH647500A5/de not_active IP Right Cessation
- 1980-04-01 AT AT0175880A patent/AT367739B/de not_active IP Right Cessation
- 1980-04-07 ES ES490316A patent/ES8200327A1/es not_active Expired
- 1980-04-09 BR BR8002193A patent/BR8002193A/pt not_active IP Right Cessation
- 1980-04-17 AR AR280715A patent/AR222075A1/es active
- 1980-04-17 CS CS802717A patent/CS215057B2/cs unknown
- 1980-04-18 DD DD80220560A patent/DD150741A5/de not_active IP Right Cessation
- 1980-04-19 RO RO100898A patent/RO81212B/ro unknown
- 1980-04-22 GB GB8013234A patent/GB2048868B/en not_active Expired
- 1980-04-22 IT IT48476/80A patent/IT1146228B/it active
- 1980-04-22 PL PL1980223655A patent/PL122687B1/pl unknown
- 1980-04-23 AU AU57722/80A patent/AU532840B2/en not_active Ceased
- 1980-04-23 DK DK174380A patent/DK153543C/da not_active IP Right Cessation
- 1980-04-23 NO NO801179A patent/NO150601C/no unknown
- 1980-04-23 DE DE3015641A patent/DE3015641C2/de not_active Expired
- 1980-04-24 BG BG047518A patent/BG34610A3/xx unknown
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