PL3548522T3 - Sposób wytwarzania obiektu z prekursora i zastosowanie żywicy sieciowalnej rodnikowo w sposobie wytwarzania addytywnego - Google Patents
Sposób wytwarzania obiektu z prekursora i zastosowanie żywicy sieciowalnej rodnikowo w sposobie wytwarzania addytywnegoInfo
- Publication number
- PL3548522T3 PL3548522T3 PL17805235.3T PL17805235T PL3548522T3 PL 3548522 T3 PL3548522 T3 PL 3548522T3 PL 17805235 T PL17805235 T PL 17805235T PL 3548522 T3 PL3548522 T3 PL 3548522T3
- Authority
- PL
- Poland
- Prior art keywords
- precursor
- resin
- making
- additive production
- production method
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title 2
- 239000000654 additive Substances 0.000 title 1
- 230000000996 additive effect Effects 0.000 title 1
- 239000002243 precursor Substances 0.000 title 1
- 239000011347 resin Substances 0.000 title 1
- 229920005989 resin Polymers 0.000 title 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
- B29C64/112—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using individual droplets, e.g. from jetting heads
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
- B29C64/124—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
- B29C64/129—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
- B29C64/135—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/30—Auxiliary operations or equipment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y40/00—Auxiliary operations or equipment, e.g. for material handling
- B33Y40/20—Post-treatment, e.g. curing, coating or polishing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
- B33Y70/10—Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
- C08F220/36—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate containing oxygen in addition to the carboxy oxygen, e.g. 2-N-morpholinoethyl (meth)acrylate or 2-isocyanatoethyl (meth)acrylate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
- B29C64/124—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2071/00—Use of polyethers, e.g. PEEK, i.e. polyether-etherketone or PEK, i.e. polyetherketone or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/0002—Condition, form or state of moulded material or of the material to be shaped monomers or prepolymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/24—Condition, form or state of moulded material or of the material to be shaped crosslinked or vulcanised
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
- C08F220/343—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate in the form of urethane links
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
- C08G18/6715—Unsaturated monofunctional alcohols or amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/81—Unsaturated isocyanates or isothiocyanates
- C08G18/8141—Unsaturated isocyanates or isothiocyanates masked
- C08G18/815—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen
- C08G18/8158—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen
- C08G18/8175—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen with esters of acrylic or alkylacrylic acid having only one group containing active hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Mechanical Engineering (AREA)
- Structural Engineering (AREA)
- Composite Materials (AREA)
- Civil Engineering (AREA)
- Ceramic Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP16202219 | 2016-12-05 | ||
PCT/EP2017/081365 WO2018104223A1 (de) | 2016-12-05 | 2017-12-04 | Verfahren zur herstellung eines gegenstandes aus einem vorläufer und verwendung eines radikalisch vernetzbaren harzes in einem additiven fertigungsverfahren |
Publications (1)
Publication Number | Publication Date |
---|---|
PL3548522T3 true PL3548522T3 (pl) | 2023-01-16 |
Family
ID=57485376
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PL17805235.3T PL3548522T3 (pl) | 2016-12-05 | 2017-12-04 | Sposób wytwarzania obiektu z prekursora i zastosowanie żywicy sieciowalnej rodnikowo w sposobie wytwarzania addytywnego |
Country Status (8)
Country | Link |
---|---|
US (1) | US20210054125A1 (pl) |
EP (1) | EP3548522B1 (pl) |
JP (1) | JP7138105B2 (pl) |
KR (1) | KR102411146B1 (pl) |
CN (1) | CN110023348B (pl) |
ES (1) | ES2927047T3 (pl) |
PL (1) | PL3548522T3 (pl) |
WO (1) | WO2018104223A1 (pl) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2021146668A (ja) * | 2020-03-23 | 2021-09-27 | 株式会社リコー | 造形液、立体造形用キット、及び立体造形物の製造方法 |
EP4092064A1 (en) | 2021-05-17 | 2022-11-23 | Covestro Deutschland AG | Photo- and thermally curable resin useful for additive manufacturing |
US20220411563A1 (en) | 2021-06-28 | 2022-12-29 | Covestro Llc | Novel dual cure 3d printing resins |
US11891469B2 (en) | 2021-06-28 | 2024-02-06 | Stratasys, Inc. | Urethane acrylate composition |
EP4116348A1 (en) | 2021-07-09 | 2023-01-11 | Covestro Deutschland AG | Photo- and thermally curable resin useful in additive manufacturing processes |
CN113583211A (zh) * | 2021-07-30 | 2021-11-02 | 浙江大学 | 一种聚脲丙烯酸酯齐聚物及其制备方法与应用方法 |
EP4166331A1 (en) | 2021-10-12 | 2023-04-19 | Covestro Deutschland AG | Photo- and thermally curable resin useful in additive manufacturing processes |
CN115043987B (zh) * | 2022-07-26 | 2024-02-02 | 珠海赛纳三维科技有限公司 | 一种3d打印用组合物、打印方法和装置 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4337130A (en) | 1980-06-25 | 1982-06-29 | E. I. Du Pont De Nemours And Company | Photocurable polyurethane film coatings |
DE3521618A1 (de) | 1985-06-15 | 1986-12-18 | Bayer Ag, 5090 Leverkusen | In wasser dispergierbare polyisocyanat-zubereitung und ihre verwendung als zusatzmittel fuer waessrige klebstoffe |
DE4136618A1 (de) | 1991-11-07 | 1993-05-13 | Bayer Ag | Wasserdispergierbare polyisocyanatgemische |
FR2699182B1 (fr) * | 1992-12-15 | 1995-07-13 | Rhone Poulenc Chimie | Monomere presentant au moins une fonction isocyanate et une insuturation son procede de synthese et (co)polymeres en decoulant. |
DE19853569A1 (de) * | 1998-11-20 | 2000-05-25 | Bayer Ag | Neue Urethanacrylate, Verfahren zu ihrer Herstellung sowie ihre Verwendung |
DE10260270A1 (de) * | 2002-12-20 | 2004-07-01 | Bayer Ag | Hydrophile Polyurethan-Polyharnstoff-Dispersion |
DE102004043540A1 (de) * | 2004-09-09 | 2006-03-30 | Bayer Materialscience Ag | Niedrigviskose Allophanate mit aktinisch härtbaren Gruppen |
DE102005008930A1 (de) * | 2005-02-24 | 2006-08-31 | Basf Ag | Mit strahlungshärtbarem Polyurethan zumindest partiell umhüllte Pigmente, ihre Herstellung und Verwendung |
AT502110B1 (de) * | 2005-06-30 | 2008-09-15 | Univ Wien Tech | Mit strahlung härtbare, in organischen lösungsmitteln lösliche zusammensetzung und deren verwendung für rapid prototyping verfahren |
DE102005044920A1 (de) * | 2005-09-20 | 2006-04-06 | Daimlerchrysler Ag | Verfahren zur Herstellung eines dreidimensionalen Gegenstandes, Materialsystem dafür sowie damit hergestellter Gegenstand |
GB2435472A (en) * | 2006-02-23 | 2007-08-29 | 3M Innovative Properties Co | Method for forming an article having a decorative surface |
DE102006051897A1 (de) * | 2006-10-31 | 2008-05-08 | Bayer Materialscience Ag | Bedruckte, verformbare Folien |
US8609204B2 (en) * | 2008-06-05 | 2013-12-17 | Stratasys Ltd. | Apparatus and method for solid freeform fabrication |
CN101381446A (zh) * | 2008-09-10 | 2009-03-11 | 中国科学技术大学 | 一种封闭型可紫外光固化水性聚氨酯树脂及其制备方法 |
JP5674041B2 (ja) | 2011-08-11 | 2015-02-18 | 株式会社ダイフク | 物品搬送設備 |
US9360757B2 (en) | 2013-08-14 | 2016-06-07 | Carbon3D, Inc. | Continuous liquid interphase printing |
NL2012087C2 (en) * | 2014-01-15 | 2015-07-16 | Admatec Europ B V | Additive manufacturing system for manufacturing a three dimensional object. |
EP3540017B1 (en) * | 2014-06-04 | 2021-10-27 | 3D Systems, Inc. | Inks comprising gellants for 3d printing |
AU2015280230B2 (en) * | 2014-06-23 | 2019-05-16 | Carbon, Inc. | Polyurethane resins having multiple mechanisms of hardening for use in producing three-dimensional objects |
EP2993202A1 (de) * | 2014-09-08 | 2016-03-09 | Evonik Degussa GmbH | Composite-Halbzeuge und daraus hergestellte Formteile sowie direkt hergestellte Formteile auf Basis von hydroxyfunktionalisierten (Meth)Acrylaten und Uretdionen, die duroplastisch vernetzt werden |
-
2017
- 2017-12-04 PL PL17805235.3T patent/PL3548522T3/pl unknown
- 2017-12-04 JP JP2019529878A patent/JP7138105B2/ja active Active
- 2017-12-04 US US16/463,627 patent/US20210054125A1/en active Pending
- 2017-12-04 KR KR1020197015797A patent/KR102411146B1/ko active IP Right Grant
- 2017-12-04 CN CN201780075457.0A patent/CN110023348B/zh active Active
- 2017-12-04 EP EP17805235.3A patent/EP3548522B1/de active Active
- 2017-12-04 ES ES17805235T patent/ES2927047T3/es active Active
- 2017-12-04 WO PCT/EP2017/081365 patent/WO2018104223A1/de active Application Filing
Also Published As
Publication number | Publication date |
---|---|
CN110023348A (zh) | 2019-07-16 |
KR102411146B1 (ko) | 2022-06-21 |
CN110023348B (zh) | 2021-12-28 |
KR20190089897A (ko) | 2019-07-31 |
EP3548522B1 (de) | 2022-07-06 |
EP3548522A1 (de) | 2019-10-09 |
US20210054125A1 (en) | 2021-02-25 |
JP7138105B2 (ja) | 2022-09-15 |
JP2020500746A (ja) | 2020-01-16 |
WO2018104223A1 (de) | 2018-06-14 |
ES2927047T3 (es) | 2022-11-03 |
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