KR930010074A - 수분산성 폴리이소시아네이트 혼합물, 이의 제조방법 및 2성분 수성 조성물에서의 이의 용도 - Google Patents
수분산성 폴리이소시아네이트 혼합물, 이의 제조방법 및 2성분 수성 조성물에서의 이의 용도 Download PDFInfo
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- KR930010074A KR930010074A KR1019920020745A KR920020745A KR930010074A KR 930010074 A KR930010074 A KR 930010074A KR 1019920020745 A KR1019920020745 A KR 1019920020745A KR 920020745 A KR920020745 A KR 920020745A KR 930010074 A KR930010074 A KR 930010074A
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- Prior art keywords
- weight
- ethylene oxide
- oxide units
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- water
- Prior art date
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- 229920001228 polyisocyanate Polymers 0.000 title claims abstract 10
- 239000005056 polyisocyanate Substances 0.000 title claims abstract 10
- 239000000203 mixture Substances 0.000 title claims abstract 9
- 238000002360 preparation method Methods 0.000 title abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract 10
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract 10
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims abstract 10
- 229920000570 polyether Polymers 0.000 claims abstract 10
- 238000000034 method Methods 0.000 claims abstract 2
- 125000001931 aliphatic group Chemical group 0.000 claims 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- PCHXZXKMYCGVFA-UHFFFAOYSA-N 1,3-diazetidine-2,4-dione Chemical group O=C1NC(=O)N1 PCHXZXKMYCGVFA-UHFFFAOYSA-N 0.000 claims 1
- 230000001476 alcoholic effect Effects 0.000 claims 1
- 125000001033 ether group Chemical group 0.000 claims 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 239000012948 isocyanate Substances 0.000 claims 1
- 150000002513 isocyanates Chemical class 0.000 claims 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000003973 paint Substances 0.000 abstract 2
- 239000004971 Cross linker Substances 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 210000003298 dental enamel Anatomy 0.000 abstract 1
- 239000004922 lacquer Substances 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 abstract 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000002966 varnish Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/798—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing urethdione groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6225—Polymers of esters of acrylic or methacrylic acid
- C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/703—Isocyanates or isothiocyanates transformed in a latent form by physical means
- C08G18/705—Dispersions of isocyanates or isothiocyanates in a liquid medium
- C08G18/706—Dispersions of isocyanates or isothiocyanates in a liquid medium the liquid medium being water
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims (6)
- a) 평균 이소시아네이트 작용가가 1.8 내지 4.2이고, b) (사이클로)지방족 결합된 이소시아네이트 그룹 (NCO로서 계산된 분자량:42)을 12.0 내지 21.5중량% 함유하고, c) 폴리에테르 쇄(여기서, 폴리에테르 쇄는 평균 5.0 내지 9.9개의 에틸렌 옥사이드 단위를 함유한다)내에 배열된 에틸렌 옥사이드 단위(C2H4O로서 계산된 분자량:44)를 2 내지 20중량% 함유하는 수분산성 폴리이소시아네이트 혼합물.
- 모든 이소시아네이트 그룹이 (사이클로) 지방족으로 결합되어 있는 하나 이상의 폴리이소시아네이트를 함유함 평균 이소시아네이트 작용가가 2.1 내지 4.4 인 폴리 이소시아네이트 성분(A)를 평균 5.0 내지 9.9개의 에틸렌 옥사이드 단위를 함유하는 1가 폴리알킬렌 옥사이드 폴리에테르 알콜(B) NCO/OH 당량비 4:1 내지 120:1로 반응시킴을 특징으로 하여, a) 평균 이소시아네이트 작용가가 1.8 내지 4.2이고 b) (사이클로) 지방족 결합된 이소시아네이트 그룹(NCO로서 계산된 분자량: 42)을 12.0 내지 21.5중량% 함유하고 c) 폴리에테트쇄(여기서, 폴리에테르 쇄는 평균 5.0 내지 9.9개의 에틸렌 옥사이드 단위를 함유한다)내에 배열된 에틸렌 옥사이드 단위(C2H4O로서 계산된 분자량: 44)를 2 내지 20중량% 함유하는 폴리이소시아네이트 혼합물을 제조하는 방법.
- 제2항에 있어서, 성분(A)가, 이소시아네이트 함량이 19 내지 24중량%이고 이소시아누레이트 그룹 및 임의로 우레트디온 그룹을 함유하며 1,6-디이소시아네이토헥산으로부터 제조된 폴리이소시아네이트를 포함하는 방법.
- 제2항 또는 제3항에 있어서, 폴리에테르 알콜이 평균 6.0 내지 8.0개의 에틸렌 옥사이드 단위를 함유하는 방법.
- I) a) 평균 이소시아네이트 작용가가 1.8 내지 4.2이고, b) (사이클로) 지방족 결합된 이소시아네이트 그룹(NCO로서 계산된 분자량: 42)를 12.0 내지 21.5중량% 함유하고, c) 폴리에테르 쇄(여기서, 폴리에테르쇄는 평균 5.0 내지 9.9개의 에틸렌 옥사이드 단위를 함유한다)내에 배열된 에틸렌 옥사이드 단위를 함유한다)내에 배열된 에틸렌 옥사이드 단위(C2H4O로서 계산된 분자량: 44)를 2내지 20중량% 함유하는 수분산성 폴리이소시아네이트 혼합물 및 II) 이소시아네이트 반응성 그룹을 함유하는 수용성 또는 수분산성 수성 수지를 포함하는 조성물.
- 제5항에 있어서, 이소시아네이트 반응성 그룹이 알콜성 하이드록실 그룹을 포함하는 조성물.※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4136618A DE4136618A1 (de) | 1991-11-07 | 1991-11-07 | Wasserdispergierbare polyisocyanatgemische |
DEP4136618.2 | 1991-11-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR930010074A true KR930010074A (ko) | 1993-06-22 |
KR100237954B1 KR100237954B1 (ko) | 2000-01-15 |
Family
ID=6444255
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019920020745A KR100237954B1 (ko) | 1991-11-07 | 1992-11-06 | 수분산성 폴리이소시아네이트 혼합물, 이의 제조방법 및 2성분 수성 조성물에서의 이의 용도 |
Country Status (9)
Country | Link |
---|---|
US (1) | US5252696A (ko) |
EP (1) | EP0540985B1 (ko) |
JP (1) | JP2961475B2 (ko) |
KR (1) | KR100237954B1 (ko) |
AT (1) | ATE132515T1 (ko) |
DE (2) | DE4136618A1 (ko) |
ES (1) | ES2084242T3 (ko) |
MX (1) | MX9206275A (ko) |
ZA (1) | ZA928557B (ko) |
Families Citing this family (193)
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DE4207851A1 (de) * | 1992-03-12 | 1993-09-16 | Bayer Ag | Mittel und verfahren zur ausruestung von textilien |
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DE19506534A1 (de) * | 1995-02-24 | 1996-08-29 | Bayer Ag | Wasserdispergierbare Polyisocyanatgemische |
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EP4279519A1 (en) * | 2022-05-19 | 2023-11-22 | Covestro Deutschland AG | A two-component coating composition |
CN119301171A (zh) | 2022-05-17 | 2025-01-10 | 科思创有限公司 | 延长操作时间的聚天冬氨酸类地板涂料配制物 |
EP4279522A1 (de) | 2022-05-17 | 2023-11-22 | Covestro Deutschland AG | In wasser dispergierbare polyisocyanate mit aldehydblockierung und daraus erhältliche wässrige zusammensetzungen |
EP4321551A1 (en) | 2022-08-09 | 2024-02-14 | Covestro LLC | Extended work time polyaspartic floor coating formulations |
TW202419163A (zh) * | 2022-08-30 | 2024-05-16 | 日商日信商事股份有限公司 | 彩色鋼板之製造方法 |
WO2024115350A1 (de) | 2022-11-29 | 2024-06-06 | Covestro Deutschland Ag | Polyisocyanatgemisch |
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GB1444933A (en) * | 1973-04-03 | 1976-08-04 | Ici Ltd | Emulsions of organic isocyanates |
GB1417618A (en) * | 1973-04-03 | 1975-12-10 | Ici Ltd | Surface active urethanes |
GB1417276A (en) * | 1973-04-03 | 1975-12-10 | Ici Ltd | Surface active agents |
GB1502777A (en) * | 1974-09-12 | 1978-03-01 | Ici Ltd | Polyurethane foams |
GB1523601A (en) * | 1975-03-12 | 1978-09-06 | Ici Ltd | Sheets or moulded bodies |
DE2708442C2 (de) * | 1977-02-26 | 1984-10-25 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von modifizierten wäßrigen Kunststoff-Dispersionen |
GB2018796B (en) * | 1978-03-29 | 1982-07-28 | Ici Ltd | Emulsifiable compositions |
JPS557472A (en) * | 1978-07-04 | 1980-01-19 | Mitsubishi Electric Corp | Forming method for thermal recording head |
DE2921726A1 (de) * | 1979-05-29 | 1980-12-11 | Bayer Ag | Waessrige isocyanat-emulsionen sowie deren verwendung als bindemittel in einem verfahren zur herstellung von formkoerpern |
DE2921681A1 (de) * | 1979-05-29 | 1980-12-11 | Bayer Ag | Neue emulgatoren, diese emulgatoren enthaltende waessrige isocyanat-emulsionen sowie deren verwendung als bindemittel in einem verfahren zur herstellung von formkoerpern |
JPS56143280A (en) * | 1980-04-10 | 1981-11-07 | Nippon Urethane Service:Kk | Water-resisting adhesive |
JPS5856580B2 (ja) * | 1980-04-25 | 1983-12-15 | 第一工業製薬株式会社 | 熱反応性ポリウレタンエマルジヨンの製造方法 |
JPS572325A (en) * | 1980-05-02 | 1982-01-07 | Ici Ltd | Isocyanate emulsion and manufacture of sheet and formed body |
GB2075038A (en) * | 1980-05-02 | 1981-11-11 | Ici Ltd | Isocyanate-containing emulsions and their use in a process for manufacturing sheets or moulded bodies |
DE3112117A1 (de) * | 1981-03-27 | 1982-10-07 | Bayer Ag, 5090 Leverkusen | Verwendung von in wasser dispergierbaren polyisocyanat-zubereitungen als zusatzmittel fuer waessrige klebstoffe |
JPS57183753A (en) * | 1981-05-06 | 1982-11-12 | Mitui Toatsu Chem Inc | Novel isocyanate composition |
EP0095594B1 (en) * | 1982-05-28 | 1986-08-27 | The Dow Chemical Company | Stable aqueous polyisocyanate emulsions |
DE3521618A1 (de) * | 1985-06-15 | 1986-12-18 | Bayer Ag, 5090 Leverkusen | In wasser dispergierbare polyisocyanat-zubereitung und ihre verwendung als zusatzmittel fuer waessrige klebstoffe |
DE3529249A1 (de) * | 1985-08-16 | 1987-02-26 | Bayer Ag | Verwendung von polyisocyanaten oder von polyisocyanatgemischen als zusatzmittel fuer waessrige dispersionsfarben |
JPH0680104B2 (ja) * | 1985-12-26 | 1994-10-12 | 三菱化成株式会社 | 水性ウレタンエマルジヨン |
DE3829587A1 (de) * | 1988-09-01 | 1990-03-15 | Bayer Ag | Beschichtungsmittel, ein verfahren zu ihrer herstellung und die verwendung von ausgewaehlten zweikomponenten-polyurethansystemen als bindemittel fuer derartige beschichtungsmittel |
US5200489A (en) * | 1992-02-27 | 1993-04-06 | Miles Inc. | Water dispersible polyisocyanates |
-
1991
- 1991-11-07 DE DE4136618A patent/DE4136618A1/de not_active Withdrawn
-
1992
- 1992-10-27 DE DE59204910T patent/DE59204910D1/de not_active Expired - Lifetime
- 1992-10-27 EP EP92118337A patent/EP0540985B1/de not_active Expired - Lifetime
- 1992-10-27 AT AT92118337T patent/ATE132515T1/de active
- 1992-10-27 ES ES92118337T patent/ES2084242T3/es not_active Expired - Lifetime
- 1992-10-30 MX MX9206275A patent/MX9206275A/es unknown
- 1992-11-04 US US07/971,491 patent/US5252696A/en not_active Expired - Lifetime
- 1992-11-05 JP JP4319271A patent/JP2961475B2/ja not_active Expired - Lifetime
- 1992-11-06 KR KR1019920020745A patent/KR100237954B1/ko not_active IP Right Cessation
- 1992-11-06 ZA ZA928557A patent/ZA928557B/xx unknown
Also Published As
Publication number | Publication date |
---|---|
DE4136618A1 (de) | 1993-05-13 |
JPH05222150A (ja) | 1993-08-31 |
KR100237954B1 (ko) | 2000-01-15 |
JP2961475B2 (ja) | 1999-10-12 |
EP0540985B1 (de) | 1996-01-03 |
US5252696A (en) | 1993-10-12 |
ATE132515T1 (de) | 1996-01-15 |
EP0540985A1 (de) | 1993-05-12 |
DE59204910D1 (de) | 1996-02-15 |
MX9206275A (es) | 1993-05-01 |
ZA928557B (en) | 1993-05-05 |
ES2084242T3 (es) | 1996-05-01 |
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