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KR900018337A - 향상된 액체/액체 촉매 연화방법 - Google Patents

향상된 액체/액체 촉매 연화방법 Download PDF

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Publication number
KR900018337A
KR900018337A KR1019900007419A KR900007419A KR900018337A KR 900018337 A KR900018337 A KR 900018337A KR 1019900007419 A KR1019900007419 A KR 1019900007419A KR 900007419 A KR900007419 A KR 900007419A KR 900018337 A KR900018337 A KR 900018337A
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KR
South Korea
Prior art keywords
quaternary ammonium
group
mercaptan
liquid
ammonium compound
Prior art date
Application number
KR1019900007419A
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English (en)
Other versions
KR930011064B1 (ko
Inventor
씨.브릭커 제프리
알 프레임 로버트
엘.베네딕트 브리안
엘.폴라스트리니 셀라
Original Assignee
원본미기재
유오피
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Publication of KR900018337A publication Critical patent/KR900018337A/ko
Application granted granted Critical
Publication of KR930011064B1 publication Critical patent/KR930011064B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/06—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of alkaline solutions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/10—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of metal-containing organic complexes, e.g. chelates, or cationic ion-exchange resins

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

내용 없음

Description

향상된 액체/액체 촉매 연화방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. 산화제의 존재하에 메르갑탄 함유의 황화 탄화수분 분액을 금속 킬레이트를 함유하는 알칼리 용액과 접촉시키는 것을 포함하는 메르캅탄을 함유하는 황화 탄화수소 분액을 촉매적으로 연화시키는 방법에 있어서, 알칼리 용액을 하기 구조의 4차 암모늄 화합물에 첨가하는 것을 특징으로 하는 메르캅탄 함유의 황화 탄화수소 분액의 촉매적 연화방법.
    상기식에서, R은 알킬, 시클로알킬, 아릴, 알카릴 및 아르알킬로 구성되는 그룹으로 부터 선택되는 약 20까지의 탄소원자를 함유하는 탄화수소기이며, R1은 약 5내지 20탄소원자를 함유한 직쇄의 알킬기이며, R2아릴, 알카릴 및 아르알킬로 구성되는 그룹으로부터 선택된 탄화수소기이며, X는 할라이드, 히드록사이드, 니트레이트, 설페이트, 포스페이트, 아세테이트, 시트레이트 및 타르트레이트이다.
  2. 제1항에 있어서, 상기 금속 킬레이트는 금속 프탈로시아닌 임을 특징으로 하는 방법.
  3. 제2항에 있어서, 상기 알칼리 용액은 약 0.1내지 25중량%의 수산화나트륨을 함유한 수산화나트륨 용액이며, 금속 프탈로시안은 코발트 프탈로시아닌으로서, 약 0.1내지 약2000ppm의 농도로 존재하며, 4차 암모늄 화합물은 약 1내지 약 5000 ppm 의 농도로 존재함을 특징으로 하는 방법.
  4. 제2항 또는 제3항에 있어서, 4차 암모늄 화합물은 계면 활성의 4차 암모늄 화합물임을 특징으로 하는 방법.
  5. 제1항 내지 제4항중 어느 한 항에 있어서, X는 히드록사이드인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900007419A 1989-05-22 1990-05-21 향상된 액체/액체 촉매적 스위트닝(sweetening)법 KR930011064B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US354,966 1989-05-22
US07/354,966 US4923596A (en) 1989-05-22 1989-05-22 Use of quaternary ammonium compounds in a liquid/liquid process for sweetening a sour hydrocarbon fraction

Publications (2)

Publication Number Publication Date
KR900018337A true KR900018337A (ko) 1990-12-21
KR930011064B1 KR930011064B1 (ko) 1993-11-20

Family

ID=23395657

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900007419A KR930011064B1 (ko) 1989-05-22 1990-05-21 향상된 액체/액체 촉매적 스위트닝(sweetening)법

Country Status (8)

Country Link
US (1) US4923596A (ko)
EP (1) EP0399702A1 (ko)
JP (1) JPH0643586B2 (ko)
KR (1) KR930011064B1 (ko)
CN (1) CN1022042C (ko)
AU (1) AU629930B2 (ko)
CA (1) CA2016416A1 (ko)
ZA (1) ZA903748B (ko)

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US5039398A (en) * 1990-03-19 1991-08-13 Uop Elimination of caustic prewash in the fixed bed sweetening of high naphthenic acids hydrocarbons
US5180484A (en) * 1990-08-27 1993-01-19 Uop Caustic free liquid/liquid process for sweeting a sour hydrocarbon fraction
US5204306A (en) * 1990-08-27 1993-04-20 Uop Caustic free catalyst for use in a liquid/liquid process for sweetening a sour hydrocarbon fraction
US5273646A (en) * 1990-08-27 1993-12-28 Uop Process for improving the activity of a mercaptan oxidation catalyst
US5093296A (en) * 1990-08-27 1992-03-03 Uop Caustic free liquid/liquid process for sweetening a sour hydrocarbon fraction
US5200062A (en) * 1991-06-17 1993-04-06 Exxon Research And Engineering Company Process for removing elemental sulfur from fluids
US6488840B1 (en) * 2000-04-18 2002-12-03 Exxonmobil Research And Engineering Company Mercaptan removal from petroleum streams (Law950)
US7223332B1 (en) 2003-10-21 2007-05-29 Uop Llc Reactor and process for mercaptan oxidation and separation in the same vessel
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JP4709737B2 (ja) * 2006-12-27 2011-06-22 花王株式会社 縮毛矯正組成物
JP4769947B2 (ja) * 2007-03-02 2011-09-07 国立大学法人神戸大学 ポインティングシステム及びポインティング方法
US20080230445A1 (en) * 2007-03-19 2008-09-25 Baker Hughes Incorporated Method of scavenging mercaptans from hydrocarbons
US8679203B2 (en) * 2007-03-19 2014-03-25 Baker Hughes Incorporated Method of scavenging mercaptans from hydrocarbons
RU2458968C1 (ru) * 2011-02-09 2012-08-20 Ооо "Фотохим" Каталитическая композиция для демеркаптанизации нефти и нефтепродуктов
CN102513160B (zh) * 2011-11-29 2013-04-03 长春惠工净化工业有限公司 用于固定床汽油中硫醇氧化转化催化剂及其制备方法
CN103374382B (zh) * 2012-04-26 2015-05-20 中国石油化工股份有限公司 轻质油品脱臭的方法
CN103768913B (zh) * 2012-10-22 2016-04-27 中国石油化工股份有限公司 一种脱除气体中硫化氢和硫醇的方法
CN104549337B (zh) * 2013-10-15 2017-01-25 中国石油化工股份有限公司 轻质油品中硫醇氧化催化剂及其制备方法和应用
CN104588097B (zh) * 2013-10-30 2019-05-21 中国石油化工股份有限公司 一种硫醇氧化催化剂的制备方法
WO2017011242A1 (en) 2015-07-15 2017-01-19 Uop Llc Oxidation catalyst and processes for using same
RU2656100C2 (ru) * 2016-11-21 2018-05-31 Закрытое акционерное общество "ИВКАЗ" Каталитическая композиция для демеркаптанизации нефти и газоконденсата
CN110628475B (zh) * 2018-06-21 2020-11-13 中国石油化工股份有限公司 炼厂富气的预处理方法以及干气和/或液化气的脱硫方法
CN110628476B (zh) * 2018-06-21 2020-11-13 中国石油化工股份有限公司 炼厂富气预处理方法、净化剂以及干气和/或液化气的脱硫方法
RU2750214C1 (ru) * 2020-10-01 2021-06-24 Общество с ограниченной ответственностью "Синтез" Каталитическая композиция для окислительной демеркаптанизации нефти и нефтепродуктов

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Also Published As

Publication number Publication date
AU629930B2 (en) 1992-10-15
JPH0643586B2 (ja) 1994-06-08
EP0399702A1 (en) 1990-11-28
AU5455990A (en) 1990-11-22
US4923596A (en) 1990-05-08
JPH03103491A (ja) 1991-04-30
KR930011064B1 (ko) 1993-11-20
CA2016416A1 (en) 1990-11-22
CN1047523A (zh) 1990-12-05
ZA903748B (en) 1991-04-24
CN1022042C (zh) 1993-09-08

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