KR830005267A - 티타니움 트리할라이드를 기초로한 화학조성물, 이들의 제조방법 및 조성물에 사용하는 불포화 화합의 중합 또는 공중합방법 - Google Patents
티타니움 트리할라이드를 기초로한 화학조성물, 이들의 제조방법 및 조성물에 사용하는 불포화 화합의 중합 또는 공중합방법 Download PDFInfo
- Publication number
- KR830005267A KR830005267A KR1019810000119A KR810000119A KR830005267A KR 830005267 A KR830005267 A KR 830005267A KR 1019810000119 A KR1019810000119 A KR 1019810000119A KR 810000119 A KR810000119 A KR 810000119A KR 830005267 A KR830005267 A KR 830005267A
- Authority
- KR
- South Korea
- Prior art keywords
- polymerization
- compound
- carried out
- general formula
- halogen
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/04—Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (11)
- 하기 일반식의 화학적 조성물TiX3.mM'YnqM"YpcAly"3-sR's식중에서X는 할로겐이고M'와 M"는 서로 상이한 금속이며Y,Y' 및 Y"는 서로 동일하거나 상이하 할로겐으로서X와 동일하거나 상이하며c는 항상 0보다 크고;n와 p는 0-3이며;R'는 10이하의 탄소원자를 가진 탄화수소임.
- M'와 M"가 및 Mg,Al,Ti,An,Mo,V,Mn 및 Zn으로부터 선택한 금속인 청구범위 1의 화학조성물
- 상기 청구범위에서 M'와 M"로 표시된 금속이나 금속들을 진공에서 증기화 시킨 다음 수득한 증기를 할로겐제공체의 존재하에 티타니움 화합물과 반응 시킨후 생성물을 하기 일반식의 유기금속 알루미늄 화합물로 처리함을 포함하는 상기 청구범위에서 청구된 화학조성물의 제조방법.Al R'3-yXy식중에서R'는 탄화수소기이고, X는 할로겐이며Y는 0-2의 수임
- 유기금속 알루미늄 화합물과의 처리가 -150°-+100℃의 온도에서 실시하는 상기 청구범위에서 청구한 바와 같은 방법.
- 유기금속 알루미늄 화합물과의 처리가 -70°-+30℃의 온도에서 실시하는 청구범위 3과 4의 방법.
- 불포화된 화합물이나 불포화 화합물들의 혼합물을 하기 일반식(i)와 (ⅱ)에 해당하는 화합물과 접촉시킴으로 구성된 불포화화합물의 중합 및 공중합 방법(i) 하기 일반식의 화합물Ti X3.mM'Yn.qM"Y'p.cAlY3-sR's(ⅱ) 일반식 AlR"pX3-p의 알루미늄 유도체 식중에서 R"는 탄화수소 잔유물이고 X는 할로겐이며 p'는 1-3의 수임,
- 중합반응을 20°-200℃의 온도에서 실시하는 상기 청구.
- 중합반응을 1-60기압에서 실시하는 상기 청구범위 6의 방법.
- 중합반응을 탄화수소 용매내에서 실시하는 청구범위 6의 방법.
- 중합반응을 기체상내에서 실시하는 청구범위 6의 방법
- 불포된 화합물이 에티렌이나 알파올레판과 에티렌의 혼합물이 상기 청구범위의 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT19619/80A IT1130243B (it) | 1980-02-01 | 1980-02-01 | Composizione chimica a base di titanio trialogenuro,metodo per la sua preparazione e processo di polimerizzazione o copolimerizzazione di composti insaturi impiegante la stessa |
Publications (2)
Publication Number | Publication Date |
---|---|
KR830005267A true KR830005267A (ko) | 1983-08-03 |
KR840001829B1 KR840001829B1 (ko) | 1984-10-22 |
Family
ID=11159704
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019810000119A KR840001829B1 (ko) | 1980-02-01 | 1981-01-17 | 티타니움 트리할라이드 화합물과 유기금속 알루미늄 화합물을 함께 사용한 불포화 화합물 촉매시스템의 제조방법 |
Country Status (34)
Country | Link |
---|---|
US (1) | US4379074A (ko) |
JP (1) | JPS56120520A (ko) |
KR (1) | KR840001829B1 (ko) |
AT (1) | AT369022B (ko) |
AU (1) | AU542379B2 (ko) |
BE (1) | BE887292A (ko) |
CA (1) | CA1162179A (ko) |
CH (1) | CH655082A5 (ko) |
DD (1) | DD156084A5 (ko) |
DE (1) | DE3103186A1 (ko) |
DK (1) | DK28181A (ko) |
ES (1) | ES8201599A1 (ko) |
FR (1) | FR2475049B1 (ko) |
GB (1) | GB2068389B (ko) |
GR (1) | GR73020B (ko) |
HU (1) | HU192062B (ko) |
IE (1) | IE50812B1 (ko) |
IL (1) | IL61962A (ko) |
IN (1) | IN153579B (ko) |
IT (1) | IT1130243B (ko) |
LU (1) | LU83093A1 (ko) |
NL (1) | NL8100477A (ko) |
NO (2) | NO158221C (ko) |
PH (1) | PH17029A (ko) |
PL (2) | PL134371B1 (ko) |
PT (1) | PT72429B (ko) |
RO (1) | RO81683B (ko) |
SE (1) | SE450575B (ko) |
SU (1) | SU1118276A3 (ko) |
TR (1) | TR21051A (ko) |
YU (2) | YU41762B (ko) |
ZA (1) | ZA8169B (ko) |
ZM (1) | ZM981A1 (ko) |
ZW (1) | ZW381A1 (ko) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1210855B (it) * | 1982-02-12 | 1989-09-29 | Assoreni Ora Enichem Polimeri | Polimeri dell'etilene a struttura lineare e processi per la loro preparazione. |
IT1176299B (it) * | 1984-06-22 | 1987-08-18 | Anic Spa | Metodo per la preparazione di un catalizzatore a base di zirconio o afnio e processo di polimerizzazione o copolimerizzazione di composti insaturi impiegante lo stesso |
RU2471552C1 (ru) * | 2011-10-25 | 2013-01-10 | Российская Федерация, От Имени Которой Выступает Министерство Промышленности И Торговли Российской Федерации | Катализатор для получения сверхвысокомолекулярного полиэтилена |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3094568A (en) * | 1959-12-01 | 1963-06-18 | Gulf Research Development Co | Process for alkylating aromatics in the presence of a heavy metal halide, an organic halide and an organo aluminum halide |
NL164867C (nl) * | 1971-03-11 | 1981-02-16 | Stamicarbon | Werkwijze voor het polymeriseren van alfa-alkenen. |
NL7313158A (nl) * | 1973-09-25 | 1975-03-27 | Shell Int Research | Polymerisatie van ethylenisch onverzadigde koolwaterstoffen. |
JPS50113488A (ko) * | 1974-02-15 | 1975-09-05 | ||
US4194992A (en) * | 1976-01-30 | 1980-03-25 | Snamprogetti, S.P.A. | Method for the polymerization of olefines and means suitable thereto |
IL51283A (en) * | 1976-01-30 | 1979-11-30 | Snam Progetti | Process for preparing a co-catalyst for use in the polymerization of a-olefins,a co-catalyst prepared by the process,a catalytic system comprising such a co-catalyst and a process for polymerizing an a-olefin using such catalytic system |
FR2342306A1 (fr) * | 1976-02-25 | 1977-09-23 | Charbonnages Ste Chimique | Procede ameliore de polymerisation ionique de l'ethylene sous haute pression |
IT1081277B (it) * | 1977-06-30 | 1985-05-16 | Snam Progetti | Composizioni chimiche a base di titanio trialogenuro procedimento per la loro preparazione e loro impieghi |
IT1080687B (it) * | 1977-06-30 | 1985-05-16 | Snam Progetti | Composizioni chimiche a base di titanio trialogenuro,procedimento per la loro preparazione e loro impieghi |
-
1980
- 1980-02-01 IT IT19619/80A patent/IT1130243B/it active
- 1980-12-05 US US06/213,658 patent/US4379074A/en not_active Expired - Lifetime
-
1981
- 1981-01-06 ZA ZA00810069A patent/ZA8169B/xx unknown
- 1981-01-07 ZW ZW3/81A patent/ZW381A1/xx unknown
- 1981-01-08 AU AU66085/81A patent/AU542379B2/en not_active Ceased
- 1981-01-09 CA CA000368250A patent/CA1162179A/en not_active Expired
- 1981-01-13 GR GR63852A patent/GR73020B/el unknown
- 1981-01-13 IN IN32/CAL/81A patent/IN153579B/en unknown
- 1981-01-14 IE IE61/81A patent/IE50812B1/en unknown
- 1981-01-16 AT AT0016881A patent/AT369022B/de not_active IP Right Cessation
- 1981-01-17 KR KR1019810000119A patent/KR840001829B1/ko active
- 1981-01-19 CH CH326/81A patent/CH655082A5/it not_active IP Right Cessation
- 1981-01-20 GB GB8101600A patent/GB2068389B/en not_active Expired
- 1981-01-20 TR TR21051A patent/TR21051A/xx unknown
- 1981-01-22 DK DK28181A patent/DK28181A/da not_active Application Discontinuation
- 1981-01-22 IL IL61962A patent/IL61962A/xx unknown
- 1981-01-22 PH PH25124A patent/PH17029A/en unknown
- 1981-01-27 LU LU83093A patent/LU83093A1/fr unknown
- 1981-01-27 ES ES499476A patent/ES8201599A1/es not_active Expired
- 1981-01-27 YU YU217/81A patent/YU41762B/xx unknown
- 1981-01-28 FR FR8101605A patent/FR2475049B1/fr not_active Expired
- 1981-01-29 ZM ZM9/81A patent/ZM981A1/xx unknown
- 1981-01-29 BE BE0/203641A patent/BE887292A/fr not_active IP Right Cessation
- 1981-01-29 NO NO810307A patent/NO158221C/no unknown
- 1981-01-30 PT PT72429A patent/PT72429B/pt unknown
- 1981-01-30 RO RO103254A patent/RO81683B/ro unknown
- 1981-01-30 PL PL1981242659A patent/PL134371B1/pl unknown
- 1981-01-30 PL PL1981229458A patent/PL134043B1/pl unknown
- 1981-01-30 JP JP1178981A patent/JPS56120520A/ja active Pending
- 1981-01-30 HU HU81219A patent/HU192062B/hu unknown
- 1981-01-30 SE SE8100744A patent/SE450575B/sv not_active IP Right Cessation
- 1981-01-30 DD DD81227331A patent/DD156084A5/de unknown
- 1981-01-30 NL NL8100477A patent/NL8100477A/nl not_active Application Discontinuation
- 1981-01-30 SU SU813271399A patent/SU1118276A3/ru active
- 1981-01-30 DE DE19813103186 patent/DE3103186A1/de not_active Withdrawn
-
1983
- 1983-06-02 YU YU01226/83A patent/YU122683A/xx unknown
-
1985
- 1985-09-24 NO NO853742A patent/NO853742L/no unknown
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