KR20130110748A - Light emitting device and method of manufacturing the same - Google Patents
Light emitting device and method of manufacturing the same Download PDFInfo
- Publication number
- KR20130110748A KR20130110748A KR1020120032953A KR20120032953A KR20130110748A KR 20130110748 A KR20130110748 A KR 20130110748A KR 1020120032953 A KR1020120032953 A KR 1020120032953A KR 20120032953 A KR20120032953 A KR 20120032953A KR 20130110748 A KR20130110748 A KR 20130110748A
- Authority
- KR
- South Korea
- Prior art keywords
- layer
- temperature
- barrier layer
- quantum well
- barrier
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title abstract description 9
- 230000004888 barrier function Effects 0.000 claims abstract description 102
- 239000004065 semiconductor Substances 0.000 claims abstract description 66
- 239000000758 substrate Substances 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims description 8
- 238000005191 phase separation Methods 0.000 abstract description 9
- 238000010030 laminating Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 272
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 13
- 229910052733 gallium Inorganic materials 0.000 description 13
- 239000000463 material Substances 0.000 description 11
- 239000012535 impurity Substances 0.000 description 10
- 229910052757 nitrogen Inorganic materials 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 8
- 150000004767 nitrides Chemical class 0.000 description 8
- 229910052738 indium Inorganic materials 0.000 description 7
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- 230000007547 defect Effects 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 229910002704 AlGaN Inorganic materials 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- XCZXGTMEAKBVPV-UHFFFAOYSA-N trimethylgallium Chemical compound C[Ga](C)C XCZXGTMEAKBVPV-UHFFFAOYSA-N 0.000 description 4
- -1 GaN Chemical class 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- RGGPNXQUMRMPRA-UHFFFAOYSA-N triethylgallium Chemical compound CC[Ga](CC)CC RGGPNXQUMRMPRA-UHFFFAOYSA-N 0.000 description 3
- 239000004020 conductor Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000006798 recombination Effects 0.000 description 2
- 238000005215 recombination Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 230000003685 thermal hair damage Effects 0.000 description 2
- OTRPZROOJRIMKW-UHFFFAOYSA-N triethylindigane Chemical compound CC[In](CC)CC OTRPZROOJRIMKW-UHFFFAOYSA-N 0.000 description 2
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 2
- IBEFSUTVZWZJEL-UHFFFAOYSA-N trimethylindium Chemical compound C[In](C)C IBEFSUTVZWZJEL-UHFFFAOYSA-N 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910005540 GaP Inorganic materials 0.000 description 1
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 1
- 229910010199 LiAl Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910019897 RuOx Inorganic materials 0.000 description 1
- 229910003087 TiOx Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000002248 hydride vapour-phase epitaxy Methods 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- VRIVJOXICYMTAG-IYEMJOQQSA-L iron(ii) gluconate Chemical compound [Fe+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O VRIVJOXICYMTAG-IYEMJOQQSA-L 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- QBJCZLXULXFYCK-UHFFFAOYSA-N magnesium;cyclopenta-1,3-diene Chemical compound [Mg+2].C1C=CC=[C-]1.C1C=CC=[C-]1 QBJCZLXULXFYCK-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000005693 optoelectronics Effects 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- HLLICFJUWSZHRJ-UHFFFAOYSA-N tioxidazole Chemical compound CCCOC1=CC=C2N=C(NC(=O)OC)SC2=C1 HLLICFJUWSZHRJ-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/005—Processes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/02—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
- H01L33/04—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a quantum effect structure or superlattice, e.g. tunnel junction
- H01L33/06—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a quantum effect structure or superlattice, e.g. tunnel junction within the light emitting region, e.g. quantum confinement structure or tunnel barrier
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/02—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
- H01L33/20—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a particular shape, e.g. curved or truncated substrate
- H01L33/24—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a particular shape, e.g. curved or truncated substrate of the light emitting region, e.g. non-planar junction
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Led Devices (AREA)
Abstract
Description
The present invention relates to a light emitting device and a method for manufacturing the same, and more particularly to a light emitting device using a nitride and a method for manufacturing the same.
In general, nitrides such as GaN, AlN, InN, and the like have a high thermal stability and have a direct transition type energy band structure, which has recently attracted much attention as a material for optoelectronic devices. In particular, GaN can be used in high temperature high power devices because the energy bandgap is very large at 3.4 eV at room temperature.
A light emitting device (LED) using nitride generates electrons and holes by using a P-N junction structure of a compound semiconductor, and emits predetermined light by recombination thereof. Such a light emitting device is used in a backlight unit or a lighting device of a display device, and consumes only a few to one tenths of the power of a conventional light bulb or a fluorescent lamp. It is advantageous.
Such a light emitting device is generally composed of an N-type GaN layer, an active layer, and a P-type GaN layer formed on a substrate, and an N-type electrode and a P-type electrode connected to the N-type GaN layer and the P-type GaN layer, respectively. Here, the active layer is a region where electrons and holes are recombined, and is composed of a quantum well layer of InGaN and a barrier layer of GaN. In addition, the emission wavelength emitted from the light emitting diode is determined according to the type of the material forming the active layer.
The active layer may improve the GaN crystalline of the barrier layer by forming the barrier layer at a temperature higher than the temperature at which the quantum well layer is formed. However, phase separation of In of the quantum well layer occurs, thereby causing a defect of the quantum well layer. Such defects lower efficiency and electrical characteristics.
The present invention provides a light emitting device capable of preventing phase separation of a quantum well layer and improving the crystallinity of the barrier layer when forming the barrier layer after forming the quantum well layer and a method of manufacturing the same.
The present invention provides a light emitting device and a method of manufacturing the same, wherein a part of the barrier layer is formed at the same temperature as the quantum well layer and the rest of the barrier layer is formed at a temperature higher than the quantum well layer formation temperature.
In the light emitting device according to the aspect of the present invention, a first semiconductor layer, an active layer, and a second semiconductor layer are stacked on a substrate, and the active layer is formed by stacking a plurality of quantum well layers and barrier layers, and the quantum well layer and the A portion of the barrier layer in contact with the quantum well layer is formed at a first temperature, and the remainder of the barrier layer is formed at a second temperature higher than the first temperature.
The second temperature is maintained at a constant temperature, continuously rises or rises in stages.
The remainder of the barrier layer formed at the second temperature is the same or thicker than the portion of the barrier layer formed at the first temperature.
A method of manufacturing a light emitting device according to another aspect of the present invention includes the steps of forming a first semiconductor layer on a substrate; Forming a quantum well layer on the first semiconductor layer at a first temperature; Forming a portion of the barrier layer at the first temperature on the quantum well layer; Forming a remainder of the barrier layer at a second temperature higher than the first temperature; And forming a second semiconductor layer on the barrier layer.
The quantum well layer and the barrier layer are repeatedly formed a plurality of times.
The second temperature is maintained at a constant temperature, continuously raised or gradually increased.
The remainder of the barrier layer formed at the second temperature is the same or thicker than the portion of the barrier layer formed at the first temperature.
Embodiments of the present invention by stacking a plurality of quantum well layer and the barrier layer to form an active layer, forming a part of the barrier layer at the same temperature as the formation temperature of the quantum well layer, and forms the rest of the barrier layer at a higher temperature . That is, the barrier layer is formed at two different temperatures, wherein the first barrier layer on the quantum well layer is formed at the same temperature as the quantum well layer, and the second barrier layer on the first barrier layer is at a higher temperature than the first barrier layer. Form.
According to the present invention, phase separation of the quantum well layer can be prevented by forming a part of the barrier layer at the same temperature as the formation temperature of the quantum well layer. Therefore, defect generation in the quantum well layer can be suppressed, thereby improving efficiency and electrical characteristics. In addition, by forming the remainder of the barrier layer at a temperature higher than a portion of the barrier layer in contact with the quantum well layer, it is possible to improve the crystallinity of the barrier layer, thereby improving the brightness and electrical properties.
1 is a cross-sectional view of a light emitting device according to an embodiment of the present invention.
2 is a cross-sectional view of an active layer of a light emitting device according to an embodiment of the present invention.
3 to 5 are temperature recipe diagrams for forming an active layer according to embodiments of the present invention.
Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings. However, the present invention is not limited to the embodiments disclosed below, but may be implemented in various forms, and only the embodiments are intended to complete the disclosure of the present invention and to those skilled in the art. It is provided for complete information. In the drawings, the thickness is enlarged to clearly illustrate the various layers and regions, and the same reference numerals denote the same elements in the drawings.
1 is a cross-sectional view of a light emitting device according to an exemplary embodiment of the present invention, and FIG. 2 is a cross-sectional view of an active layer.
1 and 2, a light emitting device according to an exemplary embodiment may include a
The
The
The
As shown in FIG. 2, the
The second semiconductor layer 140 may be a semiconductor layer doped with P-type impurities, thereby supplying holes to the
The transparent electrode 150 is formed on the second semiconductor layer 140 so that power applied through the
The first and
As described above, in the light emitting device according to the exemplary embodiment, the
[Table 1] shows an embodiment of the present invention and a quantum well layer in which a part of the barrier layer is formed at the same first temperature as the formation temperature of the quantum well layer and the rest of the barrier layer is formed at a second temperature higher than the first temperature. The wavelength, brightness and electrical characteristics of the conventional comparative example forming the entire barrier layer at a second temperature higher than the formation temperature are compared. Here, the second temperature is 65 ° C higher than the formation temperature of the quantum well layer, and the barrier layer is formed of InGaN. In addition, the electrical characteristics were measured when the ratio of the light emitting device that is normally operating without being destroyed when applying an ESD of 2000V.
As shown in Table 1, compared with the embodiment, the wavelength shifts to the shorter wavelength. This is because phase separation of InGaN of InGaN occurs due to thermal damage due to high temperature growth, and accordingly, In is volatilized to decrease In content. In addition, it can be seen that the embodiment of the present invention is also excellent in brightness and electrical properties compared to the comparative example. This is because InGaN In (metallic In cluster) is generated by thermal damage due to high temperature growth, and the ESD characteristics are reduced by current concentration due to high resistance. In addition, the luminance characteristic is deteriorated due to an increase in the non-radiative recombination region.
Hereinafter, a method of manufacturing a light emitting device according to an embodiment of the present invention.
First, the
Subsequently, the
Subsequently, a
Subsequently, a
Subsequently, the second semiconductor layer 140 is formed on the
Subsequently, the transparent electrode 150 is formed on the second semiconductor layer 140. The transparent electrode 150 is formed in contact with the second semiconductor layer 140 to function as a reflective layer that reflects light while applying power to the second semiconductor layer 140. The transparent electrode 150 may be formed using a transparent conductive oxide such as indium tin oxide (ITO).
Subsequently, the transparent electrode 150, the second semiconductor layer 140, and the
In addition, the
Meanwhile, the embodiment forms the
Although the technical spirit of the present invention has been described in detail according to the above embodiment, it should be noted that the above embodiment is for the purpose of description and not for the purpose of limitation. It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit and scope of the invention.
110
130: active layer 131: quantum well layer
132a:
140: second semiconductor layer 150: transparent electrode
160, 170: first and second electrodes
Claims (8)
The active layer is formed by stacking a plurality of quantum well layers and barrier layers,
A portion of the barrier layer in contact with the quantum well layer and the quantum well layer is formed at a first temperature,
And a remainder of the barrier layer formed at a second temperature higher than the first temperature.
Forming a quantum well layer on the first semiconductor layer at a first temperature;
Forming a portion of the barrier layer at the first temperature on the quantum well layer;
Forming a remainder of the barrier layer at a second temperature higher than the first temperature; And
Forming a second semiconductor layer on the barrier layer.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020120032953A KR20130110748A (en) | 2012-03-30 | 2012-03-30 | Light emitting device and method of manufacturing the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020120032953A KR20130110748A (en) | 2012-03-30 | 2012-03-30 | Light emitting device and method of manufacturing the same |
Publications (1)
Publication Number | Publication Date |
---|---|
KR20130110748A true KR20130110748A (en) | 2013-10-10 |
Family
ID=49632520
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020120032953A KR20130110748A (en) | 2012-03-30 | 2012-03-30 | Light emitting device and method of manufacturing the same |
Country Status (1)
Country | Link |
---|---|
KR (1) | KR20130110748A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103904171A (en) * | 2014-02-28 | 2014-07-02 | 华灿光电(苏州)有限公司 | Manufacturing method of epitaxial wafer of GaN-based light emitting diode |
CN115189232A (en) * | 2022-07-07 | 2022-10-14 | 西安唐晶量子科技有限公司 | Epitaxial wafer of semiconductor laser, preparation method of epitaxial wafer and semiconductor laser |
-
2012
- 2012-03-30 KR KR1020120032953A patent/KR20130110748A/en not_active Application Discontinuation
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103904171A (en) * | 2014-02-28 | 2014-07-02 | 华灿光电(苏州)有限公司 | Manufacturing method of epitaxial wafer of GaN-based light emitting diode |
CN115189232A (en) * | 2022-07-07 | 2022-10-14 | 西安唐晶量子科技有限公司 | Epitaxial wafer of semiconductor laser, preparation method of epitaxial wafer and semiconductor laser |
CN115189232B (en) * | 2022-07-07 | 2024-04-16 | 西安唐晶量子科技有限公司 | Epitaxial wafer of semiconductor laser, epitaxial wafer preparation method and semiconductor laser |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US8124990B2 (en) | Semiconductor light emitting device having an electron barrier layer between a plurality of active layers | |
TWI591851B (en) | Group iii nitride compound semiconductor light emitting device and production method thereof, and lamp | |
CN109119515B (en) | Light emitting diode epitaxial wafer and manufacturing method thereof | |
US9853182B2 (en) | Gallium nitride-based light emitting diode | |
TW201421739A (en) | Ultraviolet semiconductor light emitting element and method for manufacturing same | |
JP5554739B2 (en) | Manufacturing method of nitride semiconductor light emitting device | |
WO2011102450A1 (en) | Method of manufacture for a compound semiconductor light-emitting element | |
KR101903361B1 (en) | Nitride semiconductor light emitting device and manufacturing method thereof | |
KR20130022815A (en) | Nitride semiconductor light emitting device and manufacturing method thereof | |
JP5353821B2 (en) | SEMICONDUCTOR LIGHT EMITTING ELEMENT, ITS MANUFACTURING METHOD, LAMP, ELECTRONIC DEVICE, MECHANICAL DEVICE | |
KR100998234B1 (en) | Nitride semiconductor light emitting device and method for fabricating the same | |
KR20130110748A (en) | Light emitting device and method of manufacturing the same | |
JP5829014B2 (en) | Method for manufacturing compound semiconductor light emitting device | |
US9449815B2 (en) | Method of growing gallium nitride based semiconductor layers and method of fabricating light emitting device therewith | |
JP2008227103A (en) | GaN-BASED SEMICONDUCTOR LIGHT EMITTING ELEMENT | |
KR101239856B1 (en) | Light-emitting diode and Method of manufacturing the same | |
KR20150006162A (en) | Light emitting diode | |
JP2019117950A (en) | Electronic component | |
KR101387543B1 (en) | Nitride semiconductor light emitting device | |
KR20140147279A (en) | Light emitting diode and method of manufacturing the same | |
KR100608919B1 (en) | Light-emitting device and method of manufacturing the same | |
KR20150017103A (en) | Method of grawing electron blocking layer and method of fabricating nitride semiconductor device having the same | |
KR20130134671A (en) | Light emitting device and method of manufacturing the same | |
KR101720621B1 (en) | Light emitting device and method of manufacturing the same | |
JP2023178174A (en) | Light emitting element and method for manufacturing light emitting element |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
N231 | Notification of change of applicant | ||
WITN | Withdrawal due to no request for examination |