KR101373644B1 - Apparatus for cleaning glass substrate and method for cleaning glass substrate - Google Patents

Abstract

Cleaning pressure is applied to the end surface 3a at an injection pressure necessary to scrape foreign matter present in the micro recesses of the polished end surface 3a of the glass substrate 3 and at an injection pressure that does not damage the glass substrate 3. Liquid injection means 5 for injecting the liquid 7 is provided. Preferably, the liquid injection means 5 is configured to directly contact the cleaning liquid 7 with the entire area of the polished end surface 3a of the glass substrate 3, and the injection pressure thereof is 9.8-24.5 MPa. Is set to.

Description

Glass substrate cleaning device and glass substrate cleaning method {APPARATUS FOR CLEANING GLASS SUBSTRATE AND METHOD FOR CLEANING GLASS SUBSTRATE}

The present invention relates to a glass substrate cleaning apparatus and a glass substrate cleaning method, and more particularly, to a technique for properly cleaning the polished end surface of the glass substrate.

As is already known, in the production of glass panels for various image display devices such as liquid crystal displays, plasma displays, electroluminescent displays, and field emission displays, a method in which a plurality of glass panels are made of one platelet glass is used. It leads to being adopted. And the platelet glass manufactured by glass makers etc. by this is the present state that large-formatization is being promoted.

At the end of the manufacturing process, these plated glasses are subjected to a polishing process on the end faces of the glass substrates that are rectangular and cut to a predetermined size, and then cleaned and dried to make the front and back surfaces of the glass substrates a clean surface. It is customary to obtain as a final product by performing the following. That is, since the cutout portion of the glass substrate is sharp, in such a state, even when subjected to the impact of the weak root, it causes distortion or damages other adjacent glass substrates at the time of conveyance. In order to avoid this, the above-mentioned grinding | polishing process (in many cases also serves as a chamfering process) is performed with respect to the cut end surface of a glass substrate. Moreover, since the platen glass for various image display apparatuses especially forms an electronic functional element etc. in the surface, it is required to maintain high cleanliness. In order to comply with such a request, the above-described cleaning treatment and drying treatment are performed on the glass substrate.

Next, a specific example of the above-described cleaning process and drying process of the glass substrate will be described. As shown in FIG. 6, first, a basket A capable of circulating the cleaning liquid (generally water is used) between inside and outside. In the interior, a plurality of glass substrates G are stored in parallel in a vertical position. Then, the basket A is immersed in hot water at about 80 ° C. stored in the cleaning tank B, and vibrated in the vertical direction or the like to remove dirt or detergent from the glass substrate G. Thereafter, the basket A is taken out from the washing tank B, transferred to the drying treatment position C, and blown with warm air onto the glass substrate G for drying.

As shown in FIG. 7, many foreign matters (particulates) P adhere to the glass substrate G which completed the above process, and it is in a state which cannot be easily removed, especially the front and back surfaces of the glass substrate G. FIG. In the peripheral portion H of one side in, the adhesion density of the foreign matter is high. This phenomenon is because when the cutting end surface at the four sides of the glass substrate G is subjected to a polishing process, the end surface is not a mirror surface but necessarily becomes a surface having minute unevenness. The glass powder and the abrasive powder are clogged in the inside, and they are soaked out at the time of the washing process, and are formed due to precipitation as fine particles P on the front and back surfaces of the glass substrate G during the drying process. Since the glass substrate G is held in a vertical position at the time of washing and drying, the fine particles P are concentrated on the peripheral portion H of one side existing at the upper end of the glass substrate G at that time. Will be attached.

This conclusion is obtained by carrying out the above-described washing and drying treatments in which the inventors have studied the window in the related art. In addition, the present inventors have tried to perform ultrasonic cleaning as the cleaning treatment, but even with this, the adhesion of the fine particles to the glass substrate can not be sufficiently eliminated, and a certain amount of glass powder from the end surface of the glass substrate is also observed. In order to remove the abrasive powder, a fundamental problem arises that it takes an unfairly long time and the productivity is very deteriorated.

In addition, although not a technology related to the cleaning treatment, according to Patent Document 1 (see FIG. 3), a technique of spraying high pressure water from a high pressure spray nozzle in a step of polishing the end surface of the glass substrate by chamfering curb, and Similarly, in the polishing step, a technique is disclosed in which cutting water is supplied from the sprinkler of the sprinkling means to the peripheral edge of the glass substrate. Moreover, according to following patent document 2, the technique of chamfering the corner part of the liquid crystal panel cut out from a mother substrate (platelet glass) or a stick substrate by the ultra high pressure water sprayed from a water jet nozzle is disclosed.

Patent Document 1: Japanese Patent Application Laid-Open No. 8-12361

Patent Document 2: Japanese Patent Application Laid-Open No. 2002-292569

By the way, in recent years, the high definition of the display apparatus represented by a liquid crystal display advances, and accordingly, the cleanliness to a glass substrate (plate glass) is calculated | required more strictly. Nevertheless, as described above, when the fine particles P adhere to the peripheral portion H of one side of the glass substrate G and adhere to the strict requirements for cleanliness, the product value may decrease. In addition, it becomes unbearable for use and causes a problem of being treated as a defective product.

In addition, since the glass substrate is provided from the manufacturer to another display manufacturer or the like, washing and drying are performed again by the other manufacturer. Therefore, if foreign matter is still clogged in the minute recess of the polished end surface of the glass substrate, Not only the peripheral portion H of one side of the above-described glass substrate G, but also the fine particles adhere to the peripheral portion of the other side, causing the same problem.

Further, according to the technique disclosed in Patent Document 1, it can be expected that the high pressure water from the high pressure spray nozzle is supplied to the end surface during polishing of the glass substrate, but this high pressure water is described in paragraph [0019] of the document. As it is, it is injected to the grinding part of a chamfering grindstone, and is used for the clogging of the grinding part. Therefore, even if the high pressure water has reached the end face of the glass substrate once, for example, once it has reached the grinding part of the chamfering grindstone, the supply pressure of water to the end face becomes very small. For this reason, even if foreign matters such as glass powder or abrasive powder are clogged in the minute recesses of the end faces, it is impossible to scrape this foreign matter by the force of the water, and this does not lead to the problem of the fine particle adhesion.

In addition, in the technique disclosed in Patent Document 2, since the ultra high pressure water is injected into the corner portion from the surface side of the liquid crystal panel to the outside, the injection portion of the ultra high pressure water is substantially formed at the corner portion of the glass substrate. It is a surface and is not an end face. In addition, this technique is not intended to be a glass substrate but is intended for a liquid crystal panel, and in view of cutting off the corners of the liquid crystal panel, this also hardly leads to the above-mentioned problem of fine particle adhesion.

SUMMARY OF THE INVENTION The present invention has been made in view of the above circumstances, and it is a technical problem to clean the polished end surface of a glass substrate promptly and appropriately and to cope precisely with the problem of particle adhesion on the surface of a glass substrate especially.

In order to solve the above technical problem, the present invention provides a glass substrate cleaning apparatus for cleaning a polished end surface of a glass substrate with a cleaning liquid, wherein the cleaning liquid is present in the minute recess of the polished end surface of the glass substrate. It is characterized in that it is provided with the liquid injection means which injects with respect to the said end surface at the injection pressure which is necessary for scraping off a foreign material, and which does not damage a glass substrate.

Here, the "injection pressure necessary to scrape foreign matter present in the micro recesses of the end face" does not necessarily mean the spray pressure necessary to scrape all foreign matter present in all the micro recesses of the end face, It means that the injection pressure necessary to scrape a considerable amount of foreign matter present in a considerable number of micro recesses on the end surface is meant. In addition, the above-mentioned "injection pressure which does not damage the glass substrate" means the injection pressure which does not damage the edges of the end surface of the glass substrate, or cause breakage or distortion by causing an unreasonable deformation of the glass substrate. . In addition, water is often used as said "cleaning liquid."

According to this configuration, the cleaning liquid jetted from the liquid spraying means is supplied at an appropriate injection pressure to the polished end face of the glass substrate, thereby cleaning foreign matters such as glass powder and abrasive powder blocked in the minute recesses of the end face. It is scraped off by the liquid and washed off. Therefore, even after the cleaning treatment or the drying treatment for the purpose of cleaning the front and back surfaces of the glass substrate, for example, foreign matters ooze out from the end surfaces of the glass substrate, and precipitate on the front and back surfaces (particularly the surface), which is difficult to remove as fine particles. Attachment in a state is suppressed. In addition, since the cleaning liquid jetted from the liquid jetting means is prevented from being supplied to the end surface at an unreasonably high pressure damaging the glass substrate, the liquid crystal display glass substrate having a very thin thickness of about 0.5 to 0.7 mm, for example, There is no cause of unreasonable deformation leading to cracking or crushing, and the problem that the corner portion of the end face is cut off, for example, is caused by the jetting of the cleaning liquid. As a result, even in the current state of high definition display devices represented by liquid crystal displays, it is possible to comply with the strict requirements for the cleanliness of glass substrates (platelet glass) and to increase the product value and to reduce the probability of occurrence of defective products. As a result, the productivity can be greatly improved.

In this case, the liquid spraying means is preferably configured so that the cleaning liquid directly contacts the entire area of the polished end surface of the glass substrate.

In this case, the term "directly touching" means that the cleaning liquid is brought into contact with a member other than a glass substrate so as to exclude the contact with the end surface in a state in which the jet force is unduly weakened. In the case of contacting the guide member for adjusting the spraying direction of the cleaning liquid without weakening and spraying toward the end surface, or after joining the spray flows of the plurality of cleaning liquids without unduly weakening the force, When it makes contact, it is included in "it touches directly." In this case, since the cleaning liquid is hardly weakened until the cleaning liquid is ejected from the liquid spraying means and reaches the end surface of the glass substrate, the foreign material can be efficiently scraped off and the surface of the glass substrate can be efficiently removed. And adhesion of fine particles to the entire area of the back surface is suppressed.

Further, the liquid spraying means is based on a straight line parallel to the front and back surfaces of the glass substrate, from the outer side of the polished end surface of the glass substrate, in the plane orthogonal to the longitudinal direction of the side where the end surface is present. It is preferable that it is comprised so that the cleaning liquid may be inject | poured with respect to the said end surface in the range whose angle in the front and back direction is 0-70 degrees.

In this way, the direction of spraying the cleaning liquid on the end face of the glass substrate is not only from the outer side of the end face, but also is a straight line existing in the plane orthogonal to the longitudinal direction of the side where the end face is present. With respect to the straight line parallel to the front and back surface of, it has an angle of 0 to 70 ° in the front and back direction. If the angle exceeds 70 °, the impact force (pressure at the time of collision) when the cleaning liquid comes into contact with the end surface of the glass substrate becomes small, which may make it difficult to scrape off the foreign matter. Therefore, it is preferable that this angle shall be 70 degrees or less. Moreover, when this angle is 0-20 degrees, the impact force of the washing | cleaning liquid becomes large, and the scraping-off action of a foreign material becomes enough. However, in such an angle range, for example, a high-pressure cleaning liquid comes into direct contact with a fitting member, such as a rubber belt, which sandwiches and fixes the vicinity of the end surface of the glass substrate, so that the fitting supporting member contacts the cleaning liquid. Due to this, there is a high possibility of wear or damage and a relative positional shift between the glass substrate and the fitting support member, which causes the glass substrate to easily fall out. In view of such a matter, it is more preferable that said angle is 20-70 degrees.

Further, the liquid spraying means preferably includes a plurality of spray nozzles that spray the cleaning liquid from the surface side and the rear surface side of the glass substrate with respect to the polished end surface of the glass substrate.

In this case, the cleaning liquid is sprayed and supplied from the front side and the back side of the glass substrate to the end faces, respectively, by the plurality of injection nozzles, so that the foreign material scraping effect on the entire area of the end face can be easily and surely performed. It becomes possible to deal with the problem of microparticle adhesion more appropriately. In addition, it is very advantageous in avoiding the wear or damage of the fitting member and the relative misalignment of the glass substrate due to the direct contact of the high-pressure cleaning liquid with the fitting member such as the rubber belt described above.

In the above structure, it is preferable that the injection pressure of the cleaning liquid injected from the said liquid injection means is 9.8-24.5 Mpa.

That is, when the injection pressure of the cleaning liquid is less than 9.8 MPa, it is difficult to scrape a sufficient amount of foreign matter from inside the micro depressions of the end surface of the glass substrate, and there is a concern that the problem of fine particle adhesion still remains. On the other hand, when the injection pressure exceeds 24.5 MPa, when the thickness is 1 mm or less (about 0.5 to 0.7 mm), for example, as in the glass substrate of a liquid crystal display, uneven deformation occurs around the end surface of the glass substrate, Distortion may occur, or the periphery of the end surface may be cut off by the ultra high pressure cleaning liquid. Therefore, it is preferable that this injection pressure exists in said numerical range. In view of the above matters, the injection pressure is more preferably 14.7 to 24.5 MPa.

In the above configuration, the distance from the injection port of the liquid spraying means to the polished end surface of the glass substrate is preferably 2 to 30 mm.

In this way, when the cleaning liquid jetted from the injection port of the liquid injection means reaches the end surface of the glass substrate, the jet diameter and the supply pressure of the cleaning liquid are maintained at an appropriate value. That is, if the distance is less than 2 mm, the fractionation diameter of the cleaning liquid becomes too thin, and there is a possibility that the scraping-off action of the foreign material over the entire area of the end surface becomes uneven, and the distance is 30 mm. If it exceeds, the cleaning liquid may become too large in diameter, and the supply pressure of the cleaning liquid at the time when it reaches the said end surface may become inadequate. Therefore, it is preferable that this distance exists in said numerical range.

Moreover, in the above structure, it is preferable that the said liquid injection means is a spray nozzle which consists of any one of hard ceramic, ruby, sapphire, and artificial diamond.

In other words, in the case of a metal injection nozzle, for example, a metal injection nozzle is injected from the injection port of the injection nozzle, the durability is very deteriorated because the injection hole around the injection port, in particular, the injection hole decreases due to wear or shortening. If the injection nozzle is made of or the like, such a situation does not occur and can withstand long-term use over a long time. In this regard, the life of the spray nozzle made of stainless steel is about 1 hour, about 48 hours when it is made of cemented carbide and about 3 months when it is made of hard ceramic.

A glass substrate cleaning apparatus having the above structure, further comprising a conveying means for conveying the glass substrate in a horizontal position in a horizontal position, and the liquid spray means conveying path of the glass substrate by the conveying means. You may arrange | position to both sides of the direction orthogonal to the conveyance direction in the case, respectively.

In this way, while the glass substrates are sequentially conveyed in a horizontal posture by the conveying means, the liquid spraying means are respectively applied to the polished end surfaces of the pair of sides existing on both sides in the direction orthogonal to the conveying direction of each glass substrate. The cleaning liquid is sprayed, and foreign matter is scraped off from the end faces of the two sides of each glass substrate. Therefore, the continuous processing is performed instead of the batch processing as in the case of performing ultrasonic cleaning on a large number of glass substrates, thereby reducing the time required for the cleaning of the end surfaces. It is also possible to carry out the same processing by providing a conveying means for conveying the glass substrate in the vertical direction in a vertical position.

In this case, the glass substrate is rotated 90 degrees horizontally during the conveyance path of the glass substrate, and the cleaning is performed from the liquid spraying means with respect to the polished end surface of the glass substrate before any horizontal turning and after the horizontal turning. The liquid may be configured to be injected.

In this case, before the glass substrate is rotated 90 ° horizontally, the cleaning liquid is sprayed onto the end faces of the two sides of the glass substrates sequentially conveyed by the conveying means as described above, and after the horizontal turning is performed in the same manner. By spraying the cleaning liquid on the end faces of the remaining two sides of the glass substrates sequentially conveyed by other conveying means, foreign matter can be scraped from the end faces of all four sides of the glass substrate. In this way, the scraping of foreign matter from the end faces of the four sides of the glass substrate is also performed by the continuous treatment.

Meanwhile, the method according to the present invention, which is designed to solve the above technical problem, is a glass substrate cleaning method for cleaning a polished end surface of a glass substrate with a cleaning liquid, wherein the cleaning liquid is applied to the polished end surface of the glass substrate. By spraying at a high pressure, it is characterized in that the foreign material existing in the micro recess of the end surface is scraped off.

According to this method, the problem of undesirably fine particles adhering to the front and back surfaces (especially the surface) of the glass substrate is eliminated. Therefore, even in the present situation in which high resolution of the display device represented by the liquid crystal display has progressed, the glass substrate (plate glass) In addition to being able to comply with the strict requirements for cleanliness, the product value can be increased, the probability of occurrence of defective products decreases, and the productivity is greatly improved.

In addition, the glass substrate cleaning method according to the present invention, which has been devised to solve the above technical problem, is subjected to a plurality of times of polishing processing using grinding wheels having different roughness on the end surface of the glass substrate, and then the glass. It is characterized by scraping off and cleaning off foreign matter in the micro recesses of the end face by spraying the cleaning liquid at a high pressure against the end face of the substrate.

According to this method, when the polishing process is performed a plurality of times on the end surface of the glass substrate, the total amount of foreign matter present in the minute recesses in the end surface is reduced as compared with the case where the polishing process is performed only once. As a result, the cleaning liquid is sprayed at a high pressure with respect to the end face of which the amount of the foreign material is reduced, thereby scraping the foreign material, so that the amount of the foreign material remaining on the end face is greatly reduced. Therefore, the problem of fine particle adhesion of the glass substrate can be solved more reliably. Moreover, it is preferable that the 1st grinding | polishing process also serves as chamfering process, and the 2nd or later grinding | polishing process may also serve as chamfering process.

According to the present invention as described above, the cleaning liquid sprayed from the liquid spraying means is supplied at an appropriate spray pressure to the polished end surface of the glass substrate, and foreign matter existing in the micro recesses of the end surface is scraped off and washed off. Since it is lost, foreign matter bleeds out from the said end surface of a glass substrate after that, it precipitates in the surface especially, and it adheres in the state which is difficult to remove as microparticles | fine-particles, if possible. In addition, since the cleaning liquid injected from the liquid spraying means is prevented from being injected and supplied to the end surface at an unreasonably high pressure damaging the glass substrate, the cleaning liquid is not caused to cause unreasonable deformation leading to cracking or crushing, and the cleaning liquid There is no problem that the corner part of the said end surface is cut off by the force of the injection of this. As a result, even in the current state of high resolution of the display device represented by the liquid crystal display, it is possible to meet the strict requirements for the cleanliness of the glass substrate (platelet glass), increase the product value, and increase the probability of occurrence of defective products. This drastically reduces productivity.

1 is a schematic plan view showing the overall configuration of a glass substrate cleaning apparatus according to an embodiment of the present invention.
Fig. 2 is an enlarged perspective view of a main portion showing a simplified portion of a glass substrate cleaning apparatus according to an embodiment of the present invention.
3 is an enlarged vertical front view showing the main portion of the glass substrate cleaning apparatus according to the embodiment of the present invention.
4 is an enlarged vertical front view showing the main part of the glass substrate cleaning apparatus according to another embodiment of the present invention.
5 is a graph showing the results of experiments on the adhesion of fine particles using the glass substrate cleaning device according to another embodiment of the present invention.
6 is a schematic view for explaining the procedures of the cleaning process and the drying process of a glass substrate that have been conventionally performed.
Fig. 7 is a front view showing a state of adhesion of fine particles to a glass substrate in the prior art.
DESCRIPTION OF THE REFERENCE NUMERALS (S)
1: glass substrate cleaning device 2A: conveying means (upstream conveying means)
2B: conveying means (downstream conveying means) 3: glass substrate
3a: end surface of glass substrate
4a: rough grindstone for rough first polishing
4b: Fine grindstone for fine second polishing
5: injection nozzle (liquid injection means) 6: rubber belt (fitting member)
7: washing water (cleaning liquid) L: straight
α: injection angle

EMBODIMENT OF THE INVENTION Hereinafter, embodiment of this invention is described with reference to an accompanying drawing.

First, based on the schematic plan view shown in FIG. 1, the whole structure of the glass substrate washing | cleaning apparatus which concerns on embodiment of this invention is demonstrated. As shown in the figure, the glass substrate cleaning apparatus (hereinafter simply referred to as a cleaning apparatus) 1 horizontally moves the glass substrate 3 in a horizontal position by the upstream conveying means 2A (the right side of the figure). Direction), and the glass substrate 3 is horizontally rotated 90 degrees by the turning means 2X adjacent to the downstream end thereof, and is also horizontally turned by the downstream conveying means 2B adjacent to the downstream side thereof. The glass substrate 3 afterwards is conveyed in the same direction in a horizontal position. In addition, the glass substrate 3 conveyed by these conveying means 2A, 2B becomes platelet glass for liquid crystal displays, and thickness is 0.7 mm.

On the left and right both sides (both sides in the direction orthogonal to the conveying direction) in the conveying path of the upstream conveying means 2A, relative to the end faces 3a of both the left and right sides of the glass substrate 3 in order from the upstream side. A pair of coarse grindstones 4a for coarse first polishing, fine grindstones 4b for coarse second polishing, and polished end surfaces 3a on both sides of the glass substrate 3 Two pairs of liquid spraying means (spray nozzles) 5 for ejecting the washing water are arranged. In addition, the rough grindstone 4a, the fine grindstone 4b, and the injection nozzle 5 are similarly arrange | positioned at the left and right both sides in the conveyance path | route of the downstream conveying means 2B.

Therefore, with respect to each end surface 3a over the full length of the left and right sides of the glass substrate 3 conveyed by the upstream conveying means 2A, the abrasive grain 4a of the grain size of # 300- # 500 is provided. After the abrasive machining in two stages is performed by the fine grinding wheel 4b having the grain size of # 800 to # 4000, the washing water is sprayed and supplied twice from the injection nozzle 5. The same processing is also performed on each end surface 3a over the entire length of the remaining two sides of the glass substrate 3 conveyed by the downstream conveying means 2B.

Fig. 2 is a perspective view of a main part showing the peripheral configuration of the upstream conveying means 2A in detail (also the peripheral configuration of the downstream conveying means 2B), and for convenience, a pair of injection nozzles (left and right sides of the conveying path) Only 5) illustrates the deployed state. As shown in the figure, the glass substrate 3 is arrowed in a state where the glass substrate 3 is sandwiched from the top and bottom by a pair of band-shaped fastening members (rubber belts) 6 around the end surfaces 3a of both the left and right sides thereof, respectively. Direction, and the cleaning water 7 is sprayed by the spray nozzles 5 from the outer side regions of the left and right end surfaces 3a of the glass substrate 3 to the respective end surfaces 3a. Each is to be sprayed.

In detail, as shown in FIG. 3, the end surface 3a of the glass substrate 3 is chamfered by the above-mentioned two times grinding | polishing processes so that an end surface may form circular arc shape (convex arc shape). It is. Specifically, the end face 3a is shaped so as to have an approximately cross-sectional arc shape by the coarse grindstone 4a, and then the fine grindstone 4b is mainly used to reduce the surface roughness. And the end surface 3a of the glass substrate 3 is comprised so that the washing | cleaning water 7 from the injection nozzle 5 may directly contact, and the injection angle of the washing | cleaning water 7 is the said end surface 3a. ) Is set to 0 ° based on a straight line L existing in the plane (in plane parallel to the surface) orthogonal to the longitudinal direction of the existing side and parallel to the front and back surfaces of the glass substrate 3.

Further, the injection nozzle 5 is made of hard ceramic including the formation portion of the injection hole, and the injection pressure of the washing water 7 by the injection nozzle 5 is 9.8 to 24.5 MPa, preferably 14.7 to It is 24.5 Mpa, and the distance from the injection port of the injection nozzle 5 to the end surface 3a is set to 2-30 mm.

According to the washing | cleaning apparatus 1 equipped with the above structure, first, while the glass substrate 3 is conveyed by 2 A of upstream conveying means, the grinding | polishing process twice with respect to the end surface 3a of both left and right sides of the said upstream conveyance means. At this point in time, foreign matter such as glass powder or abrasive powder is clogged in the micro recesses of the end surfaces 3a thereof. Then, the glass substrate 3 is further transported to the downstream side, whereby the washing water 7 is injected from the jet nozzle 5 to the end face 3a at the above-mentioned predetermined pressure, whereby the end face 3a. Foreign matter in the micro recess of the scrape is scraped off. Such scraping-off action of the foreign material is performed twice on each of the end surfaces 3a of the left and right sides of the glass substrate 3, so that the foreign matter remaining in the micro recesses of the end surfaces 3a is very small. do.

In particular, in this embodiment, since the washing water 7 from the injection nozzle 5 is injected in the form of colliding with the end surface 3a of the glass substrate 3 directly from the front, the one injection nozzle 5 Even in this case, the washing water 7 is efficiently sprayed on the entire area of the end face 3a, so that a sufficient foreign material scraping effect can be obtained. In this case, however, since the washing water 7 directly touches the rubber belt 6, the relative position shift of the glass substrate 3 due to wear of the rubber belt 6 or deformation of the rubber belt 6 is caused. There is a risk of causing such problems.

When the glass substrate 3 is conveyed to the downstream end of the upstream conveying means 2A, the glass substrate 3 is rotated 90 degrees horizontally by the operation of the turning means 2X, and then by the downstream conveying means 2B. By being conveyed, also about the end surface 3a in the remaining two sides of the glass substrate 3, two times of grinding | polishing and scraping of the foreign material by two times of washing water are performed similarly to the above. As a result, with respect to all the end surfaces 3a of the four sides of the rectangular glass substrate 3, foreign substances remain in the micro recesses almost. This treatment is successively performed sequentially on the plurality of glass substrates 3. Therefore, even after the cleaning and drying treatments described above as shown in FIG. 6 are carried out, a large amount of foreign matters are ejected from the end surface 3a of the glass substrate 3 and an unreasonable amount of the front and back surfaces (particularly the surface). The occurrence probability of the situation where the fine particles adhere is reduced as much as possible.

4 illustrates a cleaning device according to another embodiment of the present invention. As shown in the figure, the cleaning device 1 has a front side and a back side of the glass substrate 3 for each of the washing water injection sites on the end surface 3a of each side of the glass substrate 3. It is configured so that the washing water is sprayed by a pair of spray nozzles 5 from. In detail, the washing water sprayed from the pair of spray nozzles 5 is configured to directly contact the end surface 3a of the glass substrate 3, and the spraying angle of the washing water 7 α) is based on a straight line L existing in the plane (in-plane parallel to the surface) orthogonal to the longitudinal direction of the side where the end face 3a is present and parallel to the front and back surfaces of the glass substrate 3, It is set to 20 to 70 degrees with respect to the front and back direction. Further, the pair of injection nozzles 5 are made of hard ceramic, the injection pressure of the washing water 7 is 9.8 to 24.5 MPa (preferably 14.7 to 24.5 MPa), and the respective injection nozzles 5 It is the same as that of embodiment mentioned above about the point whose distance from the injection port of () to the end surface 3a is 2-30 mm. In addition, also about the whole structure of the washing | cleaning apparatus 1, it is the same as that of embodiment mentioned previously shown in FIG.

According to such a structure, when the end surface of the glass substrate 3 is circular arc-shaped as shown in a figure, a pair of injection nozzles are carried out with respect to about half of the front side and half of the back surface side of the end surface 3a. Each of the washing waters 7 from (5) can be sprayed and supplied with an appropriate directionality. In addition, since the injection angle (alpha) of the washing | cleaning water 7 from a pair of injection nozzles 5 is set to 20-70 degree with respect to said straight line L, the washing water 7 Direct contact with the rubber belt 6 can be avoided, and the probability of occurrence of wear of the rubber belt 6 or relative positional shift of the glass substrate 3 is very low.

And the present inventors confirmed the effect at the time of washing | cleaning with the injection nozzle 5 about the end surface 3a of the four sides of the glass substrate 3 using the washing | cleaning apparatus 1 with such a structure. In order to do this, the experiment was shown below. In other words, when the polishing was performed by only the coarse grindstone 4a as the polishing treatment and when the polishing was performed by the coarse grindstone 4a and the fine grindstone 4b, the injection nozzles 5 were used. ) And the case where washing with the spray nozzle 5 was performed with the spray pressures of 4.9 MPa, 9.8 MPa, 14.7 MPa, and 19.6 MPa, respectively. In this comparison, after the respective treatments are performed on the end surface 3a of the glass substrate 3, the washing treatment and the drying treatment shown in Fig. 6 are executed, and the amount of fine particles deposited on the glass substrate 3 at that time. Were respectively detected. The comparison result is shown on the graph of FIG. In this graph, in the case where "no fine" is based only on the grindstone 4a which has been roughly processed, and "with fine" is based on both the grindstone 4a and the fine grindstone 4b which have been roughened, "No jet" means the case where washing with the injection nozzle 5 is not performed. In addition, the numerical value represented by "%" of a vertical axis | shaft is a share (number computed by the microscope determination) per unit area of the microparticles | fine-particles which mainly consist of glass in the front and back surface of the glass substrate 3, and is represented by "MPa". The numerical value shown is the injection pressure of the injection nozzle 5.

According to the graph, even when the grinding by the fine grindstone 4b is not carried out, when the injection pressure by the injection nozzle 5 is 9.8 MPa or more, good results are obtained with respect to fine particle adhesion, and when it is 14.7 MPa or more, even better results are obtained. Obtained. In addition, in the case where polishing by the fine grinding wheel 4b is performed, a very good result is obtained even when the example is a case where the injection pressure by the injection nozzle 5 is 14.7 MPa as compared with the case where it is not. . In the case where the cleaning by the spray nozzle 5 is not performed, good results could not be obtained regardless of whether or not polishing by the fine grindstone 4b is performed.

In addition, in this embodiment, although a pair of injection nozzles 5 are arrange | positioned for every one washing | cleaning water injection | pouring site | part in the edge 3a of each side of the glass substrate 3, three or more injection nozzles ( You may arrange | position 5), and when it does in this way, it is preferable to make it the injection angle (alpha) with respect to the said straight line L contain 0-20 degrees.

In addition, although the injection nozzle 5 which consists of hard ceramic was used in the above embodiment, you may use the injection nozzle which consists of ruby, sapphire, or artificial diamond instead.

Moreover, in the above embodiment, although the case where grinding | polishing by the rough grindstone 4a and the fine grindstone 4b was performed once each was illustrated, the several rough grindstone with different roughness and / or the several fine grindstone with different roughness are used. In this case, the polishing may be performed a plurality of times.

(Industrial applicability)

The glass substrate cleaning apparatus and the glass substrate cleaning method of the present invention include a glass substrate used for the production of glass panels for various image display devices such as liquid crystal displays, plasma displays, electroluminescent displays, field emission displays, and various electronic display functional elements. As a glass substrate used as a substrate for forming a thin film, it is suitable for cleaning a glass substrate where a high clean surface is required.

Claims (4)

In the glass substrate manufacturing process, a glass substrate cleaning apparatus which cleans an end surface extending in the polished straight line of the glass substrate with a cleaning liquid, targeting a single rectangular glass substrate,
The glass substrate is sandwiched by a band-shaped fitting member on both sides of the front and rear surfaces such that the edges of the polished end surface and the front and rear surfaces leading to the end surface are exposed.
And a liquid jetting means for spraying the cleaning liquid against the end face at an injection pressure necessary to thicken the foreign matter present in the minute recesses of the polished end surface of the glass substrate and not damaging the glass substrate.
The liquid ejecting means is configured to inject a cleaning liquid onto the end face toward the polished end face of the glass substrate,
And a spraying portion at which the cleaning liquid is injected from the liquid spraying means to the end surface is configured to move in a straight line along the longitudinal direction of the polished end surface of the glass substrate. In the glass substrate manufacturing process, a glass substrate cleaning method for cleaning a end surface extending in the polished straight line of the glass substrate with a cleaning liquid, targeting a single rectangular glass substrate,
In the state in which the glass substrate is sandwiched by the band-like fitting member on both sides of the front and rear so as to expose the edges of the polished end surface and the front and rear surfaces that follow the end surface,
When the cleaning liquid is sprayed at high pressure on the polished end surface of the glass substrate from the liquid ejecting means to scrape off the foreign matter present in the micro recess of the end surface.
The liquid ejecting means is directed toward the polished end surface of the glass substrate and injects a cleaning liquid onto the end surface.
And a spraying portion at which the cleaning liquid is sprayed onto the end surface from the liquid spraying means moves in a straight line along the longitudinal direction of the polished end surface of the glass substrate. In the glass substrate manufacturing process, a single rectangular glass substrate is subjected to a plurality of polishing operations using a grindstone having a different roughness on an end surface extending in a straight line of the glass substrate,
Then, in the glass substrate manufacturing process, in the state that the glass substrate is sandwiched by a band-like fitting member so as to expose the polished end surface and the edge portion of the front and rear surfaces subsequent to the end surface,
The liquid jetting means is directed toward the polished end face of the glass substrate and sprays the cleaning liquid at a high pressure on the end face.
The foreign substances in the micro recesses of the end surfaces are scraped off by moving the sprayed portion from which the cleaning liquid is sprayed to the end surface in a straight line along the longitudinal direction of the polished end surface of the glass substrate. A glass substrate cleaning method, characterized in that the washing off. The method of claim 1,
And moving the glass substrate to clean the end surface extending in the polished straight line of the glass substrate.

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