KR100991852B1 - Jam made of a flower of geranium - Google Patents
Jam made of a flower of geranium Download PDFInfo
- Publication number
- KR100991852B1 KR100991852B1 KR1020080036674A KR20080036674A KR100991852B1 KR 100991852 B1 KR100991852 B1 KR 100991852B1 KR 1020080036674 A KR1020080036674 A KR 1020080036674A KR 20080036674 A KR20080036674 A KR 20080036674A KR 100991852 B1 KR100991852 B1 KR 100991852B1
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- South Korea
- Prior art keywords
- geranium
- jam
- flower
- fruit
- sugar
- Prior art date
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L19/00—Products from fruits or vegetables; Preparation or treatment thereof
- A23L19/03—Products from fruits or vegetables; Preparation or treatment thereof consisting of whole pieces or fragments without mashing the original pieces
- A23L19/05—Stuffed or cored products; Multilayered or coated products; Binding or compressing of original pieces
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2200/00—Function of food ingredients
- A23V2200/30—Foods, ingredients or supplements having a functional effect on health
- A23V2200/326—Foods, ingredients or supplements having a functional effect on health having effect on cardiovascular health
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2200/00—Function of food ingredients
- A23V2200/30—Foods, ingredients or supplements having a functional effect on health
- A23V2200/328—Foods, ingredients or supplements having a functional effect on health having effect on glycaemic control and diabetes
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- Health & Medical Sciences (AREA)
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Polymers & Plastics (AREA)
- Jellies, Jams, And Syrups (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
Abstract
본 발명은 제라늄 꽃을 단독으로 또는 과일과 혼합하여 만들어지는 잼에 관한 것으로서, 제라늄 꽃과 설탕을 포함하며, 제라늄 꽃 1일 때 설탕 2~6의 중량비로 혼합된 조성물, 또는 과일을 더 포함하며, 상기 제라늄 꽃 1일 때 설탕 3~5, 과일 2~6의 중량비로 혼합된 조성물을 이용하여 제조된다.The present invention relates to a jam made by mixing geranium flowers alone or with a fruit, comprising a geranium flower and sugar, and further comprising a composition or fruit mixed with a weight ratio of sugar 2 to 6 when geranium flower 1 , When the geranium flower 1 is prepared using a composition mixed in a weight ratio of sugar 3-5, fruit 2-6.
제라늄, 잼 Geranium and jam
Description
본 발명은 제라늄 꽃을 단독으로 또는 과일과 혼합하여 만들어지는 잼에 관한 것으로서 제라늄의 다양한 기능성을 가지면서 손쉽게 식품으로 복용할 수 있으며 더더욱 과일과 혼합하여 만드는 경우 종래의 과일 잼에 제라늄의 기능성을 더할 뿐만 아니라 과일 잼의 맛, 향 등을 향상시킬 수 있는 잼에 관한 것이다.The present invention relates to a jam made by mixing geranium flower alone or with a fruit, and having various functionalities of geranium, can be easily taken as a food. Furthermore, when mixed with fruit, the functionality of geranium can be added to a conventional fruit jam. It also relates to jams that can improve the taste, aroma, and the like of fruit jams.
제라늄(Pelargonium inquinans Aiton)은 쥐손이과로 약 270여 종이 알려져 있다. 그중 80%가 아프리카 남부지역이 원산지이며, 세계적으로 가장 인기 있는 관상용 식물이기도 하다(James 등, 2004). Geranium (Pelargonium inquinans Aiton) is known as the rat family of about 270 species. 80% of them are native to southern Africa and are the most popular ornamental plants in the world (James et al., 2004).
제라늄류는 이뇨제, 지혈제, 강장제, 건위제, 항당뇨병, 지사제 등의 민간요법 치료제로 사용되어졌으며(Akdemir 등, 2001) 제라늄 꽃에서 6개의 안토시아닌(anthocyanin)과 14개의 플라보이노이드(flavonoid0가 함유되어 있는 것으로 보고되었다. 또한, 제라늄 방향유들이 특유한 냄새의 작용으로 식품에 첨가되어 항균활성을 갖는다고 알려져 있다(지, 2004). Geraniums have been used as a folk remedy for diuretics, hemostatics, tonics, stomachaches, antidiabetics, antidiabetics (Akdemir et al., 2001), and 6 ananthyanins and 14 flavonoids in geranium flowers. In addition, geranium fragrance oils are known to have antimicrobial activity by being added to foods under the action of peculiar odors (G, 2004).
그러나 상술한 바와 같이 다양한 기능성을 가진 제라늄을 손쉽게 섭취할 수 있는 식품이 아직 개발되지 않고 있다.However, as described above, foods that can easily consume geranium having various functionalities have not been developed yet.
잼(JAM)은 과일에 설탕을 넣고 끓여서 조린 점성이 강한 식품으로 고농도의 당분이 미생물의 성장발육을 저지하여 장기간 보존이 가능한 식품으로 토스트나 롤 같은 빵에 버터와 함께 발라서 간식이나 간단한 식사대용에 이용되고 있다.JAM is a viscous food that is boiled with sugar and boiled with fruit. Its high sugar content prevents the growth and growth of microorganisms, which can be preserved for a long time. It is applied to breads such as toast or roll with butter for snacks or snacks. It is used.
상기 잼에 사용되는 과일은 일정 이상의 응집력이 필요하기 때문에, 상기 응집제로 작용하는 펙틴과 구연산이 함유되어 있는 사과나 딸기, 포도 등을 사용하는데, 상기와 같은 펙틴이나 구연산이 함유되지 않는 과일은 잼의 재료로 사용될 수 없다.Since the fruit used in the jam requires a certain cohesion or higher, apples, strawberries, grapes, etc., which contain pectin and citric acid, which act as the coagulant, are used. Fruits that do not contain such pectin or citric acid are jams. Can not be used as a material.
또한, 상기 펙틴과 구연산과 같은 응집제는 응고와 함께 팽창하여 양이 늘어나게 되어 주원료의 투입량이 현저히 절감되지만 잼의 본래의 맛을 잃어버리게 되고, 맛을 보완하기 위해 식품첨가제를 주입하게 되며, 영양소도 부실해지게 된다.In addition, the flocculant such as pectin and citric acid is expanded with coagulation and the amount is increased, which significantly reduces the input amount of the main raw material, but loses the original taste of jam, and injects food additives to supplement the taste, and also nutrients It becomes insolvent.
따라서 맛을 보완하기 위한 식품첨가제를 별도로 사용하지 않으면서도 과일을 이용하여 만들어지는 종래의 잼의 맛, 향기, 기능성 등을 개선시켜 새로운 경쟁력을 가진 상품 개발이 요구되고 있으나 아직 개선이 되고 있지 않은 실정이다.Therefore, it is required to develop a new competitive product by improving the taste, aroma, and functionality of conventional jams made using fruits without using food additives to supplement the taste, but the situation has not been improved yet. to be.
따라서 본 발명이 해결하고자 하는 과제는 제라늄을 이용한 식품 및 종래의 과일 잼의 맛과 향기 등을 향상시킨 경쟁력을 가진 식품으로 변화시킬 수 있는 방법을 제공하는 것이다. Therefore, the problem to be solved by the present invention is to provide a method that can be changed to a food using geranium and a food having a competitive advantage to improve the taste and aroma of the conventional fruit jam.
상기 해결하고자 하는 과제를 달성하기 위하여, 본 발명은 제라늄 꽃과 설탕을 포함하며, 제라늄 꽃 1일 때 설탕 2~6의 중량비로 혼합된 조성물을 이용하여 제조되는 것을 특징으로 하는 제라늄 꽃 잼을 제공한다.In order to achieve the above object to be solved, the present invention comprises a geranium flower and sugar, when the
상술한 바와 같은 본 발명에 따른 제라늄 꽃 잼은 바람직하게는 과일을 더 포함하며, 중량비가 제라늄 꽃 1일 때 설탕 3~5, 과일 2~6로 혼합된 조성물을 이용하여 제조될 수 있다.Geranium flower jam according to the present invention as described above preferably further comprises a fruit, when the weight ratio of
상술한 바와 같은 본 발명에 사용되는 제라늄 꽃은 꽃을 수확하여 세척한 후 바로 사용할 수 있으며, 또한 세척한 꽃을 동결 건조하여 보관하고 있다고 사용할 수도 있다. 공급을 조절하기 위해서는 동결 건조하였다가 사용하는 것이 바람직할 수 있다. Geranium flowers used in the present invention as described above can be used immediately after harvesting and washing the flowers, it can also be used to store the washed flowers freeze-dried. It may be desirable to use lyophilization before use to control the feed.
상술한 바와 같은 본 발명에 따른 제라늄 꽃 잼을 제조하기 위한 조성물에 포함되는 과일은 본 발명이 속하는 기술분야에 알려진 과일, 즉 잼을 만들 수 있는 과일은 모두 특별한 제한이 없으나, 바람직하게는 오디, 사과, 포도, 딸기 및 귤로 이루어진 군에서 선택되는 어느 하나 이상이며, 오디, 사과, 포도, 딸기 및 귤 모 두를 포함하는 경우에는 이들이 동일한 중량비가 되도록 혼합하는 것이 바람직하다.Fruits included in the composition for producing a geranium flower jam according to the present invention as described above are all fruits known in the art to which the present invention pertains, that is, fruit that can make a jam, but preferably audio, At least one selected from the group consisting of apples, grapes, strawberries, and tangerines, and in the case of including all of audi, apples, grapes, strawberries, and tangerines, it is preferable to mix them in the same weight ratio.
상술한 바와 같은 본 발명에서 잼의 제조방법은 본 발명이 이전에 알려져 있는 방법들을 그대로 이용할 수 있으며, 특별한 제한은 없다.In the present invention as described above, the method of preparing jams can be used as it is known before the present invention, there is no particular limitation.
본 발명에 의하면, 안토시아닌과 플라보노이드계를 함유하고 있어 항산화작용, 심혈관계 질환 예방, 당뇨병, 이뇨제 등 여러 대사장애 조절 효능을 갖는 생리활성 등의 다양성 가능성을 가진 제라늄을 맛과 향이 뛰어나 손쉽고 거부감없이 섭취할 수 있는 식품으로 제공할 수 있다.According to the present invention, it contains an anthocyanin and a flavonoid system, and easily consumes geranium having a variety of physiological activities such as antioxidant activity, prevention of cardiovascular diseases, physiological activity having control effects of various metabolic disorders such as diabetes, diuretics, etc. Can be provided as food can.
또한 제라늄의 고유의 맛이 과일과 어우러져 잼의 풍미를 더욱 좋게 하여 기존의 과일 잼들과는 차별화할 수 있는 장점과 과일 잼을 제조하는데 응집력과 맛을 보완하기 위해 식품첨가제를 별도로 추가하지 않고 제라늄 꽃, 과일 및 설탕만으로 잼을 제조하여 잼에 첨가되는 제라늄 꽃과 과일의 본연의 맛을 느낄 수 있는 잼을 제공할 수 있는 장점 있다.In addition, the unique taste of geranium blends with the fruit to enhance the flavor of the jam, and differentiates it from the existing fruit jams, and makes fruit jam without adding food additives to supplement cohesion and taste. By producing jams with fruit and sugar only, the geranium flower added to the jam and the jam can feel the natural taste of the fruit.
이에 따라 제라늄을 재배하여 관상용뿐만 아니라 식용 꽃 또는 잼으로 제조하여 판매할 수 있어 농가소득의 증대할 수 있는 효과가 있다.Accordingly, it is possible to grow geranium and produce and sell not only ornamental flowers but also edible flowers or jams, thereby increasing farm household income.
이하 실시예를 통하여 본 발명을 실시를 위한 구체적인 내용을 설명하도록 한다.Through the following examples will be described in detail for the practice of the present invention.
<실시예><Examples>
1. 실험 재료 및 분석 방법1. Experimental Materials and Analysis Methods
1) 실험재료1) Experimental material
본 실험에 사용된 실험재료는 제라늄(Pelargonium inquinans Aiton)으로 2006년 5월부터 8월 사이에 원광대학교 원예학과 화훼실습포장에서 재배되어 수확한 후 냉동보관하며 실험에 사용하였다. The experimental material used in this experiment was Pelargonium inquinans Aiton) were harvested and harvested from May-August 2006 in the Department of Horticulture, Wonkwang University.
2)일반성분2) general ingredient
시료의 일반성분은 동결 건조한 꽃잎을 AOAC 방법(1995)에 준하여 분석하였다. 즉, 수분함량은 105℃ 상압가열건조법으로, 조회분은 550℃ 직접회화법으로, 조지방은 자동 신속 지방추출장치(SX-6, Raypa Co, Spain)로, 조단백질은 자동 킬달분석장치(B-339, Buchi Co, Swiss)로, 조섬유는 Henneberg-stohmann 개량법으로 분석하였다. General components of the samples were analyzed by freeze-dried petals according to the AOAC method (1995). In other words, the moisture content is 105 ℃ atmospheric pressure drying method, the reference powder is 550 ℃ direct ignition method, crude fat is automatic rapid fat extraction device (SX-6, Raypa Co, Spain), crude protein is an automatic Kjeldahl analyzer (B- 339, Buchi Co, Swiss), crude fibers were analyzed by Henneberg-stohmann retrofit method.
3) 무기성분3) inorganic components
P 함량 분석은 Vanadate법으로 470nm에서 비색계(V-560, Jasco, Japan)를 사용하여 측정하였다. K, Ca, Mg, Na 및 K의 함량은 꽃을 동결 건조한 후 마쇄하여 0.5g씩 100mL 삼각플라스크에 넣고 H2SO4 1mL와 50% HClO4 10mL씩 첨가하여 차츰 온도를 올려 300~400℃에서 분해시켜 투명하게 되면 분해를 종료하고, 이 분해액을 100mL로 정용 여과(Whatman No. 5)한 여액을 원자흡수분광광도계(Spactra AA-220FS, Varian, Australia)를 이용하여 측정하였다.P content analysis was performed using a colorimeter (V-560, Jasco, Japan) at 470nm by Vanadate method. The contents of K, Ca, Mg, Na and K were freeze-dried and crushed, and then ground and put into 0.5
4) 비타민 C 분석4) Vitamin C Analysis
비타민 C의 함량은 2,6-dichlorophenolindophenol (DNP) 방법(AOAC, 1995)에 의해 형광광도계(Spectroflurometer, SFM-25, K?ntron, Italy)로 측정하였다. 동결건조 된 시료 2.5g을 시험관에 넣고 5% HPO3를 50mL 첨가하여 마쇄 후 여과(Whatman No. 5)하여 얻은 상징액 1mL씩 취하여 50% ethanol과 0.2%(2,6- dichlorophenolindophenol)에 녹인 3% thiourea 용액을 차례로 0.1mL씩 넣은 후 시험용액과 대조용액으로 나누어 시험용액에는 50% sodium acetate 용액을, 대조용액에는 50% sodium acetate 용액에 녹인 3% 용액을 각각 1mL씩 넣고 15분간 정치하였다. 15분간 방치 후 0.2% OPDA 용액을 5mL씩 첨가하여 35분간 암소에서 자창색의 형광물질인 guinoxaline을 형성시켜 2시간 이내에 여기(勵起) 파장 350nm, 형광파장 430nm로 측정하였다. The content of vitamin C was measured by a fluorophotometer (Spectroflurometer, SFM-25, Kntron, Italy) by the 2,6-dichlorophenolindophenol (DNP) method (AOAC, 1995). 2.5 g of the lyophilized sample was added to a test tube, and 50 mL of 5% HPO3 was added, followed by crushing (Whatman No. 5). 1 mL of the supernatant obtained was dissolved in 3% thiourea dissolved in 50% ethanol and 0.2% (2,6-dichlorophenolindophenol). 0.1 mL of the solution was added sequentially, and the test solution and the control solution were divided into 50% sodium acetate solution in the test solution and 1% of 3% solution dissolved in 50% sodium acetate solution in the control solution. After standing for 15 minutes, 5 mL of 0.2% OPDA solution was added to form guinoxaline, which is a purple-colored fluorescent substance in the dark for 35 minutes, and was measured at 350 nm of excitation wavelength and 430 nm of fluorescent wavelength within 2 hours.
5)유리당 분석5) free sugar analysis
유리당의 조성 및 함량은 Gancedo와 Luh(1986)의 방법에 준하여 분석하였다. 즉, 시료 3g을 취하여 70% methanol 15mL를 가한 후 시료 전 처리장치(Mars X, CEM Co., USA)로 75℃에서 1시간 동안 추출 여과하였다. 이 여과용액 10mL를 취하여 원심분리하고 상등액을 Sep-pak C18 cartridge를 통과시킨 후 0.2μm membrane filter로 여과하여 ELSD(Model 2000, Softa Co., USA)를 장착한 HPLC (NS-2004GP, Futecs Co., Korea)로 column은 Asahipak NH2P-504E (4.6mm×250mm), column 온도는 35℃, 이동상은 75% acetonitrile, 유속은 1.2mL/min의 조건으로 분석하였다.The composition and content of free sugars were analyzed according to the methods of Gancedo and Luh (1986). That is, 3 g of a sample was added, and 15 mL of 70% methanol was added, followed by extraction and filtering at 75 ° C. for 1 hour with a sample pretreatment device (Mars X, CEM Co., USA). 10 mL of this filtrate was taken and centrifuged. The supernatant was passed through a Sep-pak C18 cartridge and filtered through a 0.2 μm membrane filter, followed by HPLC (NS-2004GP, Futecs Co., USA) equipped with ELSD (Model 2000, Softa Co., USA). , Korea) were analyzed under the conditions of Asahipak NH2P-504E (4.6mm × 250mm), column temperature 35 ℃, mobile phase 75% acetonitrile, flow rate 1.2mL / min.
6)구성 아미노산의 분석6) Analysis of constituent amino acids
구성 아미노산의 분석은 시료 2.5g을 시험관에 취하고 6N HCl 용액 15mL를 가하여 질소로 치환하고 밀봉한 후 110℃의 건조기에서 24시간 가수분해 하였다. 이어 감압 농축하고 구연산나트륨 완충용액(pH 5.3)으로 정용하여 0.2μm membrane filter로 여과한 후 아미노산 자동분석장치(Sykam S433, Germany)로 분석하였다. For analysis of the constituent amino acids, 2.5 g of the sample was taken in a test tube, 15 mL of 6N HCl solution was added thereto, replaced with nitrogen, sealed, and hydrolyzed in a dryer at 110 ° C. for 24 hours. Subsequently, the mixture was concentrated under reduced pressure, filtered with a 0.2 μm membrane filter, sodium citrate buffer (pH 5.3), and analyzed by an automatic amino acid analyzer (Sykam S433, Germany).
7) 지방산 분석7) Fatty Acid Analysis
시료의 총 지질은 Cho 등(2000)의 방법에 준하여 추출하였다. 즉, 시료에 chloroform : methanol (2 : 1, v/v) 혼합용액을 가하고 균질화 시킨 후 여과하였다. 잔사는 다시 chloroform : methanol (2 : 1, v/v) 혼합용액을 가하고 상기와 같은 방법으로 추출하였다. 이와 같은 조작을 3회 반복하여 얻은 여과액을 모두 합하여 분액 깔대기에 옮기고 소량의 증류수를 넣어 혼합한 후 하룻밤 방치하여 chloroform층을 분리하고 무수 Na2SO4으로 탈수시켜 여과하였다. 이어 여과액을 rotary vacuum evaporator로 40℃에서 감압 농축하여 용매를 제거한 후 총 지질을 얻었으며 -30℃의 냉동고에 보관하면서 분석용 시료로 사용하였다.Total lipids in the samples were extracted according to Cho et al. (2000). That is, chloroform: methanol (2: 1, v / v) mixed solution was added to the sample, homogenized and filtered. The residue was added to chloroform: methanol (2: 1, v / v) mixed solution and extracted in the same manner as above. The filtrates obtained by repeating the above three times were combined, transferred to a separatory funnel, mixed with a small amount of distilled water, left to stand overnight, the chloroform layer was separated, and dehydrated with
지방산 조성은 Metcalfe 등(1966)의 방법에 따라 지질을 methyl ester화 시킨 후 gas chromatography (6890N, Agilent technology, USA)로 분석하였다. 즉, 추출한 지질 0.2g에 0.5N NaOH/methanol 5 mL를 넣고 5분간 수욕상에서 가수분해 시킨 후 14% BF3-methanol 5mL를 가하여 2분간 가열하여 methyl ester화 시킨 다음 n-heptane으로 추출하여 지방산 분석용 시료로 사용하였다. 이때 GC의 분석조건은 column은 SP-2560 (100m×0.25mm, film thickness 0.20μm), detector는 FID (flame ionization detector)를 사용하였다. Column의 초기 온도는 140℃이었고 5분간 유지한 다음 4℃/min로 240℃까지 온도를 상승시켜 19분간 유지하였다.Fatty acid composition was analyzed by gas chromatography (6890N, Agilent technology, USA) after methyl esterification of lipids according to the method of Metcalfe et al. (1966). In other words, 5 g of 0.5N NaOH / methanol was added to 0.2 g of the extracted lipid, hydrolyzed in a water bath for 5 minutes, and 5% of 14% BF3-methanol was added thereto, heated for 2 minutes, methyl esterified, and extracted with n-heptane for fatty acid analysis. Used as a sample. The analysis conditions of GC were SP-2560 (100m × 0.25mm, film thickness 0.20μm) for the column and FID (flame ionization detector) for the detector. The initial temperature of the column was 140 ℃ and maintained for 5 minutes, then the temperature was raised to 240 ℃ at 4 ℃ / min and maintained for 19 minutes.
Injector와 detector의 온도는 260℃로 하였고 carrier gas는 N2를 사용하였 으며 유속은 0.8mL/min이었다. 각 지방산은 동일조건에서 표준지방산 methyl ester mixture (Sigma Chemical Co., USA)와 retention time을 비교하여 동정하였으며 함량은 각 peak의 면적을 상대적인 백분율로 나타내었다.The temperature of the injector and detector was 260 ℃, the carrier gas was N2, and the flow rate was 0.8mL / min. Each fatty acid was identified by comparing the retention time with the standard fatty acid methyl ester mixture (Sigma Chemical Co., USA) under the same conditions, and the content was expressed as a relative percentage of the area of each peak.
2. 제라늄 꽃 잼 제조2. Geranium Flower Jam Manufacturer
제라늄 잼 제조는 제라늄 1에 설탕을 3으로 혼합한 조성물, 제라늄에 과일(오디, 사과, 포도, 딸기, 귤 중 하나)과 설탕을 각각 1 : 4 : 3으로 혼합한 조성물 및 제라늄 2.5와 5종의 과일 2의 비율로 섞은 10과 설탕 7.5의 비율로 혼합한 조성물을 이용하여 잼을 제조하였다. 상기 레시피로 조제된 꽃과 과일을 믹서기로 갈아준 후 설탕을 혼합하여 넣고, 나무주걱으로 저어주면서 가스레인지의 중간 불에서 5분간, 약한 불로 15분간 걸죽한 상태까지 되도록 가열하였으며, 완성점(105℃)은 온도계로 측정하였고 제조된 제라늄 꽃 잼은 식기 전에 원형 유리용기(6×13cm)에 담아 90℃에서 8분간 살균하고 냉각하였다(이 등, 1994).Geranium jam production is a composition of a mixture of
3. 제라늄 꽃 잼 특성 조사3. Geranium Flower Jam Characteristic Investigation
제라늄 잼의 특성 조사는 제조 후 당도, 퍼짐성, 조직감, 색도와 관능 검사를 하였다.The geranium jam was examined for sugar, spread, texture, color and sensory properties after preparation.
당도는 귤절당도계(Ataro, Japan)를 이용하였다. 잼의 퍼짐성은 300g의 병에 든 잼을 유리판 중심부에 놓은 직경 10cm의 상하부가 개방된 원통관을 위로 빼는 순간부터 2분경과 후에 퍼져 있는 상태를 중심으로부터 거리(cm)로 8군데서 동시에 측정한 평균값으로 하였다(박 등, 1994). The sugar content was used tangerine sugar meter (Ataro, Japan). The spread of jam is the average value measured at 8 places at the distance (cm) from the center of spreading two minutes after the top of the 10 cm diameter upper and lower portions of the jam in the center of the glass plate is placed at the center of the glass plate. (Pak et al., 1994).
색도는 Hunter colormeter(CR-300, Minolta, Japan)를 이용하여 L, a, b값을 측정하였으며, H V/C 값은 Munsell 표색계 변환법에 의하여 측정하였다. The chromaticity was measured by L, a, and b values using Hunter colormeter (CR-300, Minolta, Japan), and the H V / C values were measured by Munsell colorimeter conversion method.
조직감(rheological property)은 제조 후 냉장 보관된 잼을 직경 4.5cm 놀이 5.0cm의 비커에 4.5cm 높이로 잼을 채우고 수직형 원형의 adaptor를 사용하여 rheometer (model CR-100D, Sun SCI. Co. Japan)에서 강도, 경도, 항복치, 부착성과 젤강도를 측정하였다. 측정조건은 table speed: 120mm/min, load cell: 2kg, adaptor area 1.77cm2, 투입 깊이는 2.5cm로 하였다.Rheological properties were determined by filling the refrigerated jams with 4.5 cm high beakers 4.5 cm in diameter and using a vertical circular adaptor with a rheometer (model CR-100D, Sun SCI. Co. Japan). ), Strength, hardness, yield value, adhesion and gel strength were measured. The measurement conditions were table speed: 120 mm / min, load cell: 2 kg, adapter area 1.77 cm2, and feeding depth 2.5 cm.
소비자에 대한 제품의 관능적 품질을 평가하기 위하여 시중에서 판매되고 있는 잼과 비교하여 관능검사를 실시하였다. 관능평가는 훈련된 관능검사요원(20~30대) 10명을 대상으로 실시하였고 관능검사 시간은 오후 5시로 하였으며 각각의 잼을 똑같은 그릇에 담아서 제공하였다. 관능평가는 색, 단맛, 신맛, 향, 전체적인 기호도를 5점 평점법(Scoring test)으로 실시하였다.In order to evaluate the sensory quality of the product to the consumer, the sensory test was performed in comparison with the commercially available jams. The sensory evaluation was carried out for 10 trained sensory test personnel (20 ~ 30s). The sensory test time was 5pm and each jam was provided in the same bowl. Sensory evaluation was performed by five-point scoring test for color, sweetness, sourness, aroma, and overall preference.
4. 결과 및 고찰4. Results and Discussion
1)일반성분1) General Ingredient
제라늄의 일반성분을 분석한 결과는 도 1(table 1)과 같다. 전반적으로 수분은 8.5%, 조회분은 10.5%, 조지방은 1.1%, 조단백질은 18.8%, 조섬유는 8.3%, 탄수화물은 57.1% 수준이었다. 이러한 결과는 10여종의 자생 식용꽃을 대상으로 성분을 분석한 결과(전, 2000) 대부분의 꽃에서는 탄수화물(52.4~77.4%), 단백질(7.5~20.1%), 지방(1.8~7.5%), 회분(2.1~12.1%)순으로 나타났다고 보고하였는데 본 연구에서도 유사한 결과로 나타났다. The results of analyzing the general components of geranium are shown in Table 1 (table 1). Overall, water content was 8.5%, crude content 10.5%, crude fat 1.1%, crude protein 18.8%, crude fiber 8.3%, and carbohydrate 57.1%. The results of the analysis of 10 kinds of native edible flowers (previous 2000) showed that in most flowers, carbohydrate (52.4 ~ 77.4%), protein (7.5 ~ 20.1%), fat (1.8 ~ 7.5%), The results were reported in the order of ash (2.1 ~ 12.1%). Similar results were found in this study.
2) 무기질 함량2) mineral content
제라늄의 무기질 함량을 측정한 결과는 도 2(table 2)와 같다. 마그네슘은 85.7mg/100g, 칼슘은 55.4mg/100g, 나트륨은 20.5/100g, 철은 3.8mg/100g, 칼륨은 139.5mg/100g, 인은 470.2mg/100g이었다. 전(2000)은 진달래꽃, 아카시아꽃 등 8종의 식용꽃에 대한 영양성분을 분석한 결과 대부분의 꽃에서 Ca과 K의 함량이 높았고 특히 산수유꽃, 동백꽃 및 배꽃에는 Ca, 나팔나리에서는 Na, 칡꽃과 자색백합에서는 K, 달맞이꽃과 유채꽃에서는 Mg 함량이 많이 나타났다고 하였다. The result of measuring the mineral content of geranium is shown in Table 2 (table 2). Magnesium was 85.7 mg / 100 g, calcium was 55.4 mg / 100 g, sodium was 20.5 / 100 g, iron was 3.8 mg / 100 g, potassium was 139.5 mg / 100 g, and phosphorus was 470.2 mg / 100 g. Jeon (2000) analyzed the nutritional constituents of 8 kinds of edible flowers such as azalea and acacia, and the content of Ca and K was high in most of the flowers, especially Caustic, Camellia and Pear, Ca, Na, in the morning glory It was reported that K, and Evening Primrose and Rape blossoms showed a lot of Mg in purple lily.
본 연구에서도 제라늄은 P, K 및 Ca의 함량이 높아 인체에 유익한 무기성분을 많이 포함하고 있어서 우수한 무기원소의 공급원이자 건강에 좋은 요리 소재로 활용할 수 있을 것으로 생각된다.In this study, geranium is high in P, K and Ca and contains a lot of inorganic ingredients beneficial to the human body. Therefore, geranium is considered to be a good source of inorganic elements and a healthy cooking material.
3) 비타민 C와 총 폴리페놀 함량 분석3) Vitamin C and Total Polyphenol Content Analysis
제라늄의 비타민 C와 폴리페놀 함량을 분석한 결과는 도 3(table 3)과 같다. 일반적으로 비타민 C는 영양소로서의 기능 외에도 활성 산소의 제거를 도와주는 작용과 과산화물의 분해를 촉진하고 발암물질인 니트로사민의 생성을 막아주며, 간지질 과산화물을 저하시킨다. 그러므로 영양적인 면이나 기능적인 면에서 매우 중요한 요인으로 자리 잡고 있어 식품으로 가공 시 비타민 C 함량은 품질 지표의 하나가 될 만큼 중요하며, 물에도 쉽게 용출 된다(황 등, 2003). 천연물 중에는 아미노산, 아스코르브산, 카로티노이드, 플라보노이드, 페놀성 화합물은 식물계에 널리 분포되어 있는 2차 대사물의 하나로서 다양한 구조와 분자량을 가지며, phenolic hydroxyl기를 가지고 있기 때문에 생리활성 기능도 가진다. 일반적으로 황산화 활성을 가지고 있는 여러 물질들이 존재하고 있으며, 이중에는 페놀성물질이 강한 산 화방지 작용을 지니는 것으로 알려져 있다(Dugan, 1980).The results of analyzing the vitamin C and polyphenol content of geranium are shown in Table 3 (table 3). In general, vitamin C, in addition to its function as a nutrient, aids in the removal of free radicals, promotes the breakdown of peroxides, prevents the production of carcinogens nitrosamines, and lowers liver lipid peroxides. Therefore, it is very important in terms of nutritional and functional aspects, so vitamin C content is important enough to be one of the quality indicators when processed into food, and is easily dissolved in water (Hwang et al., 2003). Among natural products, amino acids, ascorbic acid, carotenoids, flavonoids, and phenolic compounds are secondary metabolites widely distributed in the plant system, and have various structures and molecular weights, and they also have physiologically active functions. In general, there are several substances that have sulfate activity, of which phenolic substances are known to have strong anti-oxidation effects (Dugan, 1980).
본 연구 결과 제라늄의 비타민 C 함량은 10.7mg/100g로 총 폴리페놀은 6.4mg/100g의 범위로 나타났다. 제라늄의 비타민 C함량은 박 등(2001)의 “식품성분표”에 나타난 원추리(39mg/100g), 민들레(28mg/100g), 국화(21mg/100g) 보다는 적은 경향을 보였지만 오이, 배 및 매실의 비타민 C 함량이 각각 8mg/100g, 4mg/100g, 6mg/100g 및 마 2.82mg/100g이라는 Shin(2004)의 보고에 비하면 높은 경향을 보였다. 따라서 오이, 배 및 매실에 비해 비타민 C의 함량이 높은 것으로 나타난 제라늄을 이용해 가공 식품화 한다면 관상용으로서의 역할 못지않게 식품영양학적 측면에서도 큰 의의가 있다고 생각된다. The results showed that geranium had a vitamin C content of 10.7mg / 100g and a total polyphenol range of 6.4mg / 100g. The vitamin C content of geranium tends to be less than that of conical (39mg / 100g), dandelion (28mg / 100g) and chrysanthemum (21mg / 100g) as shown in Park et al. (2001). Compared with Shin's (2004) report, vitamin C content of 8mg / 100g, 4mg / 100g, 6mg / 100g and hemp 2.82mg / 100g, respectively. Therefore, if processed food using geranium, which is shown to have a higher content of vitamin C than cucumbers, pears, and plums, it is considered to have great significance in terms of food nutrition as well as an ornamental role.
4) 총 유리당 분석4) Total Glass Sugar Analysis
제라늄의 유리당 함량을 분석한 결과는 도 4(table 4)와 같다. 전반적으로 fructose, glucose, sucrose 순이었으며 fructose는 94.1mg/g, glucose는 52.2mg/g, sucrose는 5.9mg/g으로 나타났다. 권 등(1995)의 아카시아꽃의 구성당은 fructose 75.23mg/g, sucrose 61.70mg/g 및 glucose 43.69mg/g이었다는 연구결과에 비해 제라늄의 경우는 fructose, glucose에서는 높은 수준임을 알 수 있었다. 일반적으로 식품에서의 당질은 fructose, glucose 및 maltose 등의 환원당과 sucrose 등과 같은 유리당이 존재하면서 주로 맛을 좌우하고, 영양성의 보강역할을 하므로 종류에 따라서는 기능성을 강화하기 위해 인위적으로 첨가하고 있다(Kim과 Kim, 2005). 따라서 유리당의 함량이 높은 제라늄은 관상적인 특성 외에 식품영양학적인 측면에서도 의의가 있어 제라늄 꽃의 이용증대를 위해서는 이 점을 활용하는 것도 좋을 것으로 생각된다.The result of analyzing the free sugar content of geranium is shown in Table 4 (table 4). In the order of fructose, glucose and sucrose, fructose was 94.1mg / g, glucose was 52.2mg / g and sucrose was 5.9mg / g. The composition of fructose 75.23mg / g, sucrose 61.70mg / g and glucose 43.69mg / g was higher in geranium than fructose and glucose. In general, sugars in foods are artificially added to enhance the functionality of the sugars, since the presence of reducing sugars such as fructose, glucose and maltose, and free sugars such as sucrose mainly influences the taste and enhances the nutritional properties. Kim and Kim, 2005). Therefore, geranium, which has a high content of free sugars, has significant significance in terms of food nutrition in addition to the coronary characteristics, so it may be good to use this point to increase the use of geranium flowers.
5) 구성아미노산의 분석5) Analysis of constituent amino acids
제라늄의 아미노산 조성을 분석한 결과 도 5(table 5)와 같다. 제라늄은 18종의 아미노산이 분리되었다. 필수 아미노산은 총 아미노산 함량을 기준하여 제라늄은 40% 이상 함유 되어 있었다. 필수 아미노산 중 leucine과 lysine은 각각 10.0mg/g 및 8.4mg/g으로 가장 많이 함유되어 있었다. 총 아미노산 중 신맛을 내는 glutamic acid은 23.8mg/g으로 가장 많이 나타났다. 한편, 권 등(1995)은 아미노산 조성은 맛과 향의 형성에 깊이 관여함으로서 품질과 깊은 관계가 있음을 지적하였으며, Konta(1991)는 대부분의 식용꽃의 경우 단백질의 함량 및 아미노산 조성이 우수하다고 하였는데, 본 연구 결과에서도 alanine, histdine, leucine, glycine 및 phenylalanine 등 단맛을 내는 아미노산 등이 포함되어 있어 식용꽃은 식품의 재료로서도 가치가 있는 것으로 판단되었다. As a result of analyzing the amino acid composition of geranium is shown in Figure 5 (table 5). Geranium has 18 amino acids isolated. Essential amino acids contained more than 40% geranium based on total amino acid content. Among the essential amino acids, leucine and lysine were the highest at 10.0mg / g and 8.4mg / g, respectively. Among the total amino acids, the sour glutamic acid was the highest at 23.8mg / g. On the other hand, Kwon et al. (1995) pointed out that amino acid composition is deeply related to quality by deeply involved in the formation of taste and aroma, and Konta (1991) found that most edible flowers have excellent protein content and amino acid composition. The results of this study also included sweet amino acids such as alanine, histdine, leucine, glycine, and phenylalanine, so that edible flowers were valuable as food ingredients.
6) 지방산 분석6) Fatty Acid Analysis
제라늄을 대상으로 지방산 조성을 분석한 결과 도 6(table 6)과 같다. 15종이 확인되었다. 포화지방산 중 myristic acid, palmitic acid, heptadecanoic acid 및 stearic acid은 확인되었으며, 이 중 palmitic acid가 가장 많이 포함되어 있었다. As a result of analyzing the fatty acid composition of the geranium as shown in Figure 6 (table 6). 15 species were identified. Among saturated fatty acids, myristic acid, palmitic acid, heptadecanoic acid and stearic acid were identified, among which palmitic acid was the most abundant.
7) 제라늄 꽃 잼의 종류별 색상7) Color by Type of Geranium Flower Jam
제라늄에 첨가되는 과일의 종류를 달리하여 제조한 제라늄 꽃 잼의 색도는 도 7(table 7) 및 도 8(Fig 1)과 같다. 김과 전(2001)의 딸기잼의 색도가 L값이 30.14, a값이 44.85, b값이 53.67로 실험결과와 비교하면 100% 제라늄 잼의 색도가 L값이 24.87, a값이 7.32, b값이 1.16로 딸기잼에 비해 밝기를 나타내는 L값은 다소 낮아졌으나 적색을 나타내는 a값과 황색을 나타내는 b값은 낮게 나타나 차이가 있었다. 본 실험에서 제라늄 잼의 L값은 포도를 첨가했을때 가장 낮아졌으나 a값은 가장 높게 나타났다. 이러한 색상의 차이는 각각의 첨가된 과일의 Flavonoid와 anthocyanin등의 색소의 영향 때문이라고 생각된다. The chromaticity of the geranium flower jam prepared by varying the kind of fruit added to the geranium is shown in Table 7 and 8 (Fig 1). Kim and Jeon (2001) showed that the strawberry jam had a L value of 30.14, an a value of 44.85, and a b value of 53.67. The 100% geranium jam had a L value of 24.87, a value of 7.32, and b. The value of 1.16 was slightly lower than that of strawberry jam, whereas the L value of brightness was slightly lower, but the b value of yellow and b value of yellow were lower. In this experiment, L value of geranium jam was the lowest when grape was added, but a value was the highest. This color difference is thought to be due to the influence of pigments such as Flavonoid and anthocyanin in each added fruit.
8) 제라늄 꽃 잼의 종류별 당도8) Sugar content by type of geranium flower jam
제라늄에 5가지 과일을 단일 또는 혼합하여 제조한 제라늄 꽃 잼의 당도를 조사한 결과는 도 9(table 8)와 같다. 과일을 혼합하지 않은 제라늄잼은 당도가 43.0±0.4로 가장 낮았으며 제라늄과 오디를 1:4로 혼합한 잼에서 당도가 68.0±0.0으로 가장 높게 나타났다. 현재 소비자의 식품에 대한 기호가 건강을 생각하여 저열량의 과일채소류 소비를 지향하고 있는 시점이다. 본 연구에서 사용한 제라늄은 anthocyanin과 flavonoid계를 함유하고 있기 때문에 항산화작용, 심혈관계 질환 예방, 당뇨병, 이뇨제등 여러 대사장애 조절 효능을 갖는 생리활성물질이 있는 것으로 밝혀졌고, 제라늄의 특유한 향으로 인하여 방부효과를 가지며(지, 2004) 제라늄의 고유의 맛이 과일과 어우러져 잼의 풍미를 더욱 좋게 하여 기존의 과일 잼들과는 차별화할 수 있는 장점이 있었다.As a result of examining the sugar content of geranium flower jam prepared by single or mixed five fruits in geranium is shown in Table 8 (table 8). Geranium jam with no fruit mixture had the lowest sugar content of 43.0 ± 0.4 and the highest sugar content was 68.0 ± 0.0 with jam containing 1: 4 of geranium and audi. At the present time, consumers' preference for food is toward low-calorie fruit vegetables in consideration of health. Geranium used in this study was found to contain anthocyanin and flavonoid-based bioactive substances with various metabolic disorders such as antioxidant activity, prevention of cardiovascular disease, diabetes, and diuretics. (Ji, 2004) Geranium's inherent taste, combined with the fruit to improve the flavor of the jam has the advantage that can be differentiated from the existing fruit jam.
9) 제라늄 꽃 잼의 종류별 퍼짐성9) Spreadability by Type of Geranium Flower Jam
제라늄에 5가지 과일을 단일 또는 혼합하여 제조한 제라늄 꽃 잼의 퍼짐성을 조사한 결과 도 10(Fig 2)과 같다. 100% 제라늄과 제라늄에 바나나와 포도를 가각 첨가하여 만든 잼은 퍼짐성이 5∼6cm로 나타난 반면 제라늄에 딸기와 귤을 첨가한 잼은 퍼짐성이 7~8cm로 첨가한 과일의 종류에 따라 잼의 퍼짐성에는 약간 차이가 있음을 알수 있었다. 김과 전(2001)의 연구에 의하면 딸기잼 제조시 양파를 첨가하므로써 고형분의 함량이 증가하여 잼의 점도가 증가한다고 하였는데 이는 첨가물의 종류에 따라 차이가 있는 것으로 생각되어 앞으로 추가적인 연구를 해야 할 것으로 생각된다. As a result of investigating the spread of geranium flower jam prepared by single or mixed five fruits in geranium is shown in Figure 10 (Fig 2). Jam made by adding banana and grape to each 100% geranium and geranium showed spreadability of 5 ~ 6cm, while jam with strawberry and tangerine added to geranium showed spreading according to the kinds of fruits added with 7 ~ 8cm There was a slight difference. According to a study by Kim and Jeon (2001), the viscosity of jam increases due to the increase of solid content by adding onion when preparing strawberry jam, which is thought to be different depending on the types of additives. I think.
10) 제라늄 꽃 잼의 종류별 조직감10) Texture by type of geranium flower jam
제라늄에 5가지 과일을 단일 또는 혼합하여 제조한 제라늄 꽃 잼의 조직감을 조사한 결과는 도 11(table 9)과 같다. 제라늄 잼의 조직감 중 강도는 100% 제라늄잼에 비해 과일첨가시 커지는 경향을 보였다. 이는 과일에 함유되어있는 펙틴이 영향을 미친 것으로 생각되었다. 제라늄 잼의 경도와 부착성은 다소 높아진 것을 알 수 있었다. 시중에서 판매되고 있는 대부분의 잼은 제조시 응집력과 맛을 보완하기 위해 젤라틴과 같은 식품첨가제를 별도로 추가하여 잼을 제조하는 것이 일반적이다. 그러나 본 연구에서는 이와 같은 첨가물을 전혀 사용하지 않아도 제라늄 꽃과 과일에 포함되어 있는 펙틴 성분 때문에 잼 제조시 잼의 퍼짐성이나 조직감에는 아무런 문제가 없었다. 맛과 향 또한 제라늄 꽃과 과일이 가지고 있는 특징이 잘 나타나 기존의 잼들과는 차별화할 수 있었다.The results of examining the texture of geranium flower jam prepared by single or mixing five fruits in geranium are shown in Table 9 (table 9). The strength of the geranium jam texture tended to increase when the fruit was added compared to the 100% geranium jam. This was thought to be influenced by the pectin contained in the fruit. The hardness and adhesion of geranium jam were found to be somewhat higher. Most jams on the market are generally prepared by adding food additives, such as gelatin, to supplement cohesion and taste during manufacture. However, in this study, there was no problem in jam spreading or texture when making jams because of the pectin contained in geranium flowers and fruits even if these additives were not used at all. Taste and aroma also showed the characteristics of geranium flowers and fruits, so that they could be differentiated from existing jams.
11) 제라늄 꽃 잼11) Geranium Flower Jam 의of 종류별 관능평가 Sensory Evaluation by Type
제라늄에 5가지 과일을 단일 또는 혼합하여 제조한 제라늄 꽃 잼의 관능평가를 조사한 결과 도 12(table 10)와 같다. 제라늄 단독으로 만든 잼은 제라늄 고유 의 향과 맛이 남아있었지만 끝 맛이 약간 쓴 경향이 있었다. 그러나 과일을 첨가한 경우 이런 부분을 없앨 수 있었다. 본 실험에서는 제라늄에 포도를 혼합하여 만든 잼이 가장 높은 평가를 받았으나 제라늄에 귤, 딸기, 사과를 첨가하여 만든 잼도 높은 평가를 받았다.As a result of investigating the sensory evaluation of geranium flower jam prepared by single or mixed five fruits in geranium, it is shown in Table 10 (table 10). Jams made with geranium alone retained the inherent aroma and taste of geranium but tended to be slightly bitter. But if the fruit was added, this could be eliminated. In this experiment, jam made by mixing grapes with geranium received the highest rating, but jam made by adding tangerine, strawberry, and apple to geranium was also highly evaluated.
도 1은 제라늄의 일반성분을 분석한 결과이다.1 is a result of analyzing the general components of geranium.
도 2는 제라늄의 무기질 함량을 측정한 결과이다.Figure 2 is the result of measuring the mineral content of geranium.
도 3은 제라늄의 비타민 C와 폴리페놀 함량을 분석한 결과이다.Figure 3 is the result of analyzing the vitamin C and polyphenol content of geranium.
도 4는 제라늄의 유리당 함량을 분석한 결과이다4 is a result of analyzing the free sugar content of geranium
도 5는 제라늄의 아미노산 조성을 분석한 결과이다.5 is a result of analyzing the amino acid composition of geranium.
도 6은 제라늄을 대상으로 지방산 조성을 분석한 결과이다.6 is a result of analyzing the fatty acid composition of the geranium.
도 7 및 도 8은 제라늄 꽃 잼의 색도 조사한 결과이다.7 and 8 are the results of the color irradiation of the geranium flower jam.
도 9는 제라늄 꽃 잼의 당도를 조사한 결과이다.9 is a result of examining the sugar content of geranium flower jam.
도 10은 제라늄 꽃 잼의 퍼짐성을 조사한 결과이다. 10 is a result of investigating the spread of geranium flower jam.
도 11은 제라늄 꽃 잼의 조직감을 조사한 결과이다.11 is a result of examining the texture of geranium flower jam.
도 12는 제라늄 꽃 잼의 관능평가를 조사한 결과이다.12 is a result of examining the sensory evaluation of geranium flower jam.
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