KR100711244B1 - Aggregate coted with pearl pigment and building finishing material comprising it - Google Patents
Aggregate coted with pearl pigment and building finishing material comprising it Download PDFInfo
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- KR100711244B1 KR100711244B1 KR1020060075096A KR20060075096A KR100711244B1 KR 100711244 B1 KR100711244 B1 KR 100711244B1 KR 1020060075096 A KR1020060075096 A KR 1020060075096A KR 20060075096 A KR20060075096 A KR 20060075096A KR 100711244 B1 KR100711244 B1 KR 100711244B1
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/1092—Coating or impregnating with pigments or dyes
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/02—Agglomerated materials, e.g. artificial aggregates
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/02—Coverings or linings, e.g. for walls or ceilings of plastic materials hardening after applying, e.g. plaster
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- Pigments, Carbon Blacks, Or Wood Stains (AREA)
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Abstract
본 발명은 건축용 마감재에 관한 것으로, 보다 상세하게는 골재에 펄안료를 착색함으로써 펄의 특징인 다양한 귀금속성 색감과 진주빛 광택을 띄게 하여 골재의 단조로움을 보완한 펄안료가 코팅된 골재를 함유한 건축마감재에 관한 것이다.The present invention relates to a finishing material for building, and more specifically, to the pearl pigments on the aggregates, the pearl pigment coated aggregates that complement the monotony of the aggregates by making a variety of precious metallic colors and pearlescent luster characterized by pearl It is about a building finishing material.
본 발명은 용제 10∼20중량%, 수지 5∼15중량%, 펄안료 1∼5중량% 및 골재 65∼80중량%를 함유하는 것을 특징으로 하는 펄안료가 코팅된 골재를 제공한다. 또 본 발명은 펄안료가 코팅된 골재 70∼85중량% 및 접착바인더 15∼30중량%를 함유하는 것을 특징으로 하는 펄안료가 코팅된 골재를 함유한 건축마감재를 제공한다.The present invention provides a pearl pigment-coated aggregate comprising 10 to 20 wt% of a solvent, 5 to 15 wt% of a resin, 1 to 5 wt% of a pearl pigment, and 65 to 80 wt% of an aggregate. In another aspect, the present invention provides a building finishing material containing a pearl pigment-coated aggregate, characterized in that it contains 70 to 85% by weight of the aggregate coated with pearl pigment and 15 to 30% by weight of the adhesive binder.
본 발명에 의한 펄안료가 코팅된 골재 및 이를 함유한 마감재는 펄 특유의 귀금속성 색감과 진주빛 광택으로 인하여 심미적이며, 펄안료의 착색을 용이하고, 온풍에서도 건축마감재의 고화 건조가 신속하므로 경제적인 특징을 발휘할수 있는 골재 및 마감재를 제공하려는 것이다. The aggregates coated with pearl pigments according to the present invention and the finishing materials containing them are aesthetics due to the pearl's unique precious metal color and pearly luster, and are easy to color pearl pigments, and are quick to solidify drying of building finishes even in warm air. It is to provide aggregates and finishes that can exhibit the characteristics.
골재, 건축마감재, 펄안료 Aggregate, Building Finish, Pearl Pigment
Description
본 발명은 건축마감재에 관한 것으로, 보다 상세하게는 골재에 펄안료를 착색함으로써 펄의 특징인 다양한 귀금속성 색감과 진주빛 광택을 띄게 하여 골재의 단조로움을 보완한 펄안료가 코팅된 골재를 함유한 건축마감재에 관한 것이다.The present invention relates to a building finishing material, and more specifically, to the pearl pigments on the aggregate, the pearl pigment coated aggregates complementary to the monotony of the aggregates by exhibiting a variety of precious metallic colors and pearlescent luster characterized by pearl It is about a building finishing material.
종래에 건축용 자재로서 사용되고 있는 골재로는 통상적으로 규사, 백운석, 모래 등을 들 수 있고, 근래에 와서는 이들 골재에 여러 가지 첨가물, 예를 들어 몰타르, 폐조개껍질, 야자껍질 등을 첨가함으로써 내구성, 내열성, 내후성, 난연성을 강화한 마감재를 사용하고 있다. Conventional aggregates that are conventionally used as building materials include silica sand, dolomite, sand and the like. In recent years, durability is obtained by adding various additives, for example, mortar, shell clam shells, and coconut shells, to these aggregates. It is using finish material with enhanced heat resistance, weather resistance and flame retardancy.
예들 들어 특허등록 제545530호 및 공개특허 제2005-37540호에는 몰타르 또는 야자껍질을 첨가한 마감재가 기재되어 있고, 공개특허 제2005-79963호에는 폐조개껍질을 첨가한 마감재가 기재되어 있다. 그러나 상기 발명들은 골재로서 단단하고 내열성, 내후성이 우수하며, 가공 정도에 따라 아주 부드러운 질감을 가져 우수한 건축자재로 사용되지만 색상이 단조롭다는 것이 단점이 있었다.For example, Patent Registration No. 545530 and Patent Publication Nos. 2005-37540 describe a finish added with mortar or palm peel, and Patent Publication No. 2005-79963 describes a finish added with waste shells. However, the above inventions have the disadvantages of being solid as aggregate, excellent in heat resistance and weather resistance, and having a very soft texture depending on the degree of processing, which is used as an excellent building material.
한편 상기 발명과 같은 단점을 보완하기 위하여, 금속산화물의 산화안료를 단순히 착색하는 방법이 알려져 있으나, 이렇게 단순히 착색하는 방법은 골재의 미세한 틈 사이에 산화안료를 침투시켜 안료를 부착시키는 것으로, 이는 색상이 단조로울 뿐 아니라 안료가 골재에 완전히 부착되지 못하여 골재 원래의 색상에 간섭을 받아 원하는 색상을 구현할 수 없다는 단점이 있었다. 따라서 일부 제한된 자재로만 사용되고 있었다. 이러한 산화안료로 코팅된 골재는 산화안료의 특성상 단순한 색상의 코팅에 불과하다. 또한 약 130∼700℃의 고온 가열상태에서 착색함에 따라 연료비와 시간이 낭비된다는 단점이 있었다.On the other hand, in order to make up for the disadvantages of the present invention, a method of simply coloring an oxide pigment of a metal oxide is known, but this simply coloring method is to penetrate an oxide pigment between fine gaps of aggregate to attach a pigment. In addition to being monotonous, there was a drawback that the pigment could not be completely attached to the aggregate and thus could not achieve the desired color due to interference with the original color of the aggregate. Therefore, it was used only with some limited materials. Aggregate coated with this oxide pigment is merely a coating of a simple color due to the nature of the pigment. In addition, there was a disadvantage in that fuel costs and time was wasted by coloring in a high temperature heating state of about 130 ~ 700 ℃.
따라서, 본 발명은 상기와 같은 문제점을 해결하기 위하여 이루어진 것으로서, 골재에 펄안료를 코팅함으로써 펄 특유의 귀금속성 색감과 진주빛 광택을 갖게 함으로서 일반 골재의 단조로움을 보완하는 것을 목적으로 한다. Therefore, the present invention has been made to solve the above problems, it is an object to complement the monotony of the general aggregate by having a pearl-specific noble metallic color and pearlescent luster by coating the pearl pigment on the aggregate.
또 본 발명은 휘발성이 강한 용제 및 고화 건조가 빠른 수지를 사용함으로써 펄안료의 착색을 용이하게 하고, 온풍에서도 고화 건조가 신속하게 이루어지도록 하는 것을 목적으로 한다. Moreover, an object of this invention is to make coloring of pearl pigment easy by using a highly volatile solvent and quick solidification resin, and to make solidification drying quick even in a warm air.
상기의 목적을 달성하기 위하여, 본 발명에 의한 펄안료가 코팅된 골재는 용제 10∼20중량%, 수지 5∼15중량%, 펄안료 1∼5중량% 및 골재 65∼80중량%를 함유하는 것을 특징으로 한다. 본 발명에서 사용되는 유기 용제로는 크실렌, 톨루엔, 메틸이소부틸 케톤, 메틸에틸 케톤 등을 들 수 있으며, 수지에 따라 2이상 혼합하여 사용할 수 있다. 수지로는 니트로셀룰로오스 수지 및 , 폴리이소시아네이트기를 갖는 우레탄 수지를 들 수 있다. In order to achieve the above object, the pearl pigment coated aggregate according to the present invention contains a solvent 10 to 20% by weight, resin 5 to 15% by weight, pearl pigment 1 to 5% by weight and aggregates 65 to 80% by weight It is characterized by. Examples of the organic solvent used in the present invention include xylene, toluene, methyl isobutyl ketone, methyl ethyl ketone, and the like, and may be used by mixing two or more according to the resin. Examples of the resin include a nitrocellulose resin and a urethane resin having a polyisocyanate group.
또 본 발명에 의한 펄안료가 코팅된 골재를 함유한 건축마감재는 펄안료가 코팅된 골재 70∼85중량% 및 접착바인더 15∼30중량를 함유하는 것을 특징으로 한다. 상기 접착바인더는 물 35∼40중량%, 분산제 0.5∼1중량%, 아크릴계 바인더 50∼60중량%, 아크릴계 점증제 2∼5중량% 및 pH조정제 0.5∼1중량%를 함유한다. In addition, the building finishing material containing the pearl pigment-coated aggregate according to the present invention is characterized in that it contains 70 to 85% by weight of the pearl pigment-coated aggregate and 15 to 30 weight of the adhesive binder. The adhesive binder contains 35 to 40% by weight of water, 0.5 to 1% by weight of dispersant, 50 to 60% by weight of acrylic binder, 2 to 5% by weight of acrylic thickener and 0.5 to 1% by weight of pH adjuster.
펄안료가 코팅된 골재를 건축마감재로 사용하기 위하여는 접착을 위한 접착제로서 아크릴계 바인더를 주로 사용하고, 건축마감재의 용도에 따라 우레탄, 에폭시 등의 수지를 사용할 수도 있다.In order to use the pearl pigment coated aggregate as an architectural finishing material, an acrylic binder is mainly used as an adhesive for adhesion, and resins such as urethane and epoxy may be used depending on the purpose of the construction finishing material.
펄안료는 층상구조인 운모를 미분쇄하여 그 표면에 금속산화물을 얇게 코팅한 것으로, 빛을 받게 되면 반사, 굴절 및 투과 등에 의하여 펄과 같은 귀금속 색감과 진주빛 광택을 내는 안료이다. Pearl pigment is a thin powder coating of metal oxide on the surface of mica which is a layered structure, and when it receives light, it is a pigment that gives a pearly luster and precious metal color such as pearl by reflection, refraction and transmission.
펄안료는 금속산화물의 종류에 따라 간섭색을 갖거나 착색효과를 가지며, 산란, 반사 등의 효과로 유연한 광택성을 나타내며, 이러한 펄안료를 이용하여 착색한 골재는 빛을 받게 하면 반사와 굴절, 투과 등의 효과로 펄과 같은 특유의 귀금속성 색감과 진주빛 광택을 나타내는 펄 알갱이와 같은 조성물을 제공할 수 있게 된다.Pearl pigments have interference colors or coloring effects depending on the type of metal oxide, and they exhibit flexible glossiness due to scattering, reflection, etc., and aggregates colored using such pearl pigments are reflected, refracted, and transmitted when they receive light. It is possible to provide a composition such as pearl granules exhibiting a unique noble metallic color and pearly luster such as pearl by the effect of the.
또한 이러한 펄 특유의 귀금속성 색감과 진주빛 광택을 나나태는 펄알갱이 상태의 골재를 건축마감재 조성물로 사용하면 펄과 같은 특유의 귀금속성 색감과 진주빛 광택을 나타내는 펄 알갱이들로 결합된 건축마감재 조성물을 제공할 수 있다.In addition, when the pearl granules exhibiting pearl-like noble metallic colors and pearlescent luster are used as the building finishing composition, the architectural finishing materials combined with pearl grains exhibiting unique noble metallic colors such as pearl and pearlescent luster A composition can be provided.
펄안료의 입경은 사용되는 골재에 따라 다양하고 광범위하게 선택될 수 있고 골재의 크기보다 작으면 되지만, 바람직하게는 10~200㎛이다. The particle size of the pearl pigment may be selected in various ways depending on the aggregate used and may be smaller than the size of the aggregate, but is preferably 10 to 200 μm.
본 발명에 사용되는 분산제로는 알킬 4급 암모늄화합물과, 에틸렌 디아민 테트라아세트산, 니트릴로 트리아세트산 및 구연산 등의 유기 다가산이 바람직하다.The dispersant used in the present invention is preferably an alkyl quaternary ammonium compound and organic polyacids such as ethylene diamine tetraacetic acid, nitrilo triacetic acid and citric acid.
pH 조정제로는 구연산, 인산, 수산화나트륨, 수산화칼륨, 트리에탄올 아민 등을 사용할 수 있다. Citric acid, phosphoric acid, sodium hydroxide, potassium hydroxide, triethanol amine, etc. can be used as a pH adjuster.
점증제로는 폴리아크릴산, 양이온성 폴리머, 비이온성 폴리머, 셀룰로오스유도체 등을 사용할 수 있으나, 아크릴계 점증제가 바람직하다.As the thickener, a polyacrylic acid, a cationic polymer, a nonionic polymer, a cellulose derivative, or the like may be used, but an acrylic thickener is preferable.
미세한 펄안료를 휘발성이 강한 용제와, 접착성이 강하고, 고화 건조가 빠른 니트로셀룰로오스 수지 또는 폴리이소시아네이트기를 갖는 우레탄 수지에 혼합하여 골재의 미세한 틈에 침투시킴으로써, 수지의 접착력으로 부착된 펄안료로 인하여 펄 특유의 귀금속성 색감과 광택을 지닌 펄 알갱이와 같은 조성물이 생성된다.The fine pearl pigment is mixed with a highly volatile solvent, a strong adhesive and quick-drying nitrocellulose resin or a urethane resin having a polyisocyanate group to penetrate into fine gaps of the aggregate, thereby allowing the pearl pigment adhered to the adhesive strength of the resin. Compositions such as pearl granules with pearl-specific noble metallic colors and luster are produced.
또한 휘발성이 강한 용제와 고화 건조가 빠른 수지를 사용함으로써 약간의 온풍, 예를 들어 70∼100℃의 송풍에도 용제의 휘발성을 촉진하고, 이때 발생하는 열로 인한 상승작용에 의하여 가열하는 것과 같은 효과를 얻을 수 있고, 이로 인하여 고화 시간도 빨라져서 경제적인 효과도 얻을 수 있다.In addition, by using a highly volatile solvent and a fast solidifying resin, the solvent volatilization is promoted even in a slight warm air, for example, 70 to 100 ° C., and heated by synergy due to the heat generated. In this case, the solidification time can be accelerated, resulting in an economic effect.
이하에 본 발명을 실시예에 의하여 상세히 설명한다.Hereinafter, the present invention will be described in detail by way of examples.
(실시예 1)(Example 1)
혼합용기에 크실렌 17중량%와 니트로셀룰로오스 수지 10%를 혼합하여 약 10분 정도 교반한 후, 펄안료 3중량%를 혼합하여 약 10분 정도 교반한 다음, 다시 골 재 70중량%를 투입하여 15분 정도 교반하였다. 이후 70∼100℃의 온풍을 송풍하면서 10∼20분 정도 교반하여 펄안료가 코팅된 골재를 수득하였다.After mixing 17% by weight of xylene and 10% of nitrocellulose resin in the mixing vessel and stirring for about 10 minutes, 3% by weight of pearl pigment was mixed and stirred for about 10 minutes, and then 70% by weight of aggregate was added again. Stir for minutes. Thereafter, the mixture was stirred for 10 to 20 minutes while blowing a warm air of 70 to 100 ° C. to obtain an aggregate coated with pearl pigment.
(실시예 2) (Example 2)
혼합용기에 물 35중량%, 분산제 0.5중량%, 아크릴계 바인더 60중량%, 아크릴계 점증제 3중량%, pH조정제 1중량%를 혼합하여 접착바인더를 제조하였다. 수득된 접착바인더 20중량%에, 상기 실시예 1에서 제조된 펄안료가 코팅된 골재 80중량%를 혼합하여 건축마감재를 제조하였다. An adhesive binder was prepared by mixing 35% by weight of water, 0.5% by weight of a dispersant, 60% by weight of an acrylic binder, 3% by weight of an acrylic thickener, and 1% by weight of a pH adjuster. To 20% by weight of the obtained adhesive binder, 80% by weight of the aggregate coated with the pearl pigment prepared in Example 1 was mixed to prepare a building finishing material.
상기의 펄안료가 코팅된 골재는 펄안료의 종류에 따라 간섭색을 갖거나 착색효과를 가지며 빛의 산란과 반사등의 효과를 발휘하면서 유연한 광택성을 나타내게 된다.Aggregate coated with the pearl pigment has an interference color or a coloring effect according to the type of pearl pigment, and exhibits flexible gloss while exerting the effects of light scattering and reflection.
이와 같이 펄안료가 착색된 골재는 빛을 받게 되면 빛의 반사와 굴절, 투과등으로 펄과 유사하거나 같은 귀금속성의 색감과 진주빛의 광택을 나타내게 되고 이러한 골재를 이용한 건축물의 내외부는 아룸다움과 고급스러운 장식적효과를 더할 수 있다.As such, aggregates colored with pearl pigments exhibit noble metallic colors and pearlescent luster similar or similar to pearls due to reflection, refraction and transmission of light. The interior and exterior of the building using these aggregates are beautiful and luxurious. It can add decorative effect.
즉, 상기한 펄안료가 코팅된 골재를 접착바인더와 혼합하여 공지와 같이 건축물의 내외장 건축마감재로서 덫 칠하므로써 외벽에서 펄 특유의 질감 귀금속성의 색감과 광택을 표현함으로서 보다 고급스러운 장식효과와 미적인 건축물을 제공하게 되는 것이다.In other words, by mixing the above-mentioned pearl pigment-coated aggregate with an adhesive binder and trapping it as an interior and exterior building finishing material of a building as known, it expresses the color and luster of the texture of the precious metal of precious pearl on the exterior wall, so that a more luxurious decorative effect and aesthetic To provide architecture.
또한 상기 골재는 작은 모래크기에서부터 약 1cm내외의 자갈크기에 구성하여 건축물의 내외벽 마감재뿐만이 아니라 별도의 장식용 골재로도 이용 가능함을 물론이 다.In addition, the aggregate is composed of a gravel size of about 1cm from the small sand size can be used as a separate decorative aggregate as well as the interior and exterior wall finishing material of the building.
본 발명 종래의 금속산화물의 산화안료를 단순히 착색하는 방법에 의한 색상이 단조로움과 안료가 골재에 완전히 부착되지 못하여 골재 및 원래의 색상에 간섭을 받아 원하는 색상을 구현할 수 없다는 단점과 고온 가열상태에서 착색함에 따라 연료비와 시간이 낭비가 이루워지는 종래의 단점을 개선하여 골재에 펄안료를 착색함으로써 펄의 특징인 다양한 귀금속성 색감과 진주빛 광택을 띄게 하여 골재의 단조로움을 보완한 펄안료가 코팅된 골재를 함유한 건축마감재를 제공하되,According to the present invention, the color of the oxide pigment of the conventional metal oxide is simply colored and monochromatic and the pigment is not completely adhered to the aggregate, thereby preventing the desired color from being interfered with the aggregate and the original color. Pearl pigments that complement the monotony of aggregates by coloring pearl pigments on the aggregate by coloring the pearl pigments on the aggregates by improving the conventional disadvantage that waste of fuel cost and time by coloring. Provide building finishes containing coated aggregates,
크실렌, 니트로셀룰로오스 수지와 펄안료를 혼합교반하여 골재의 투입으로 코팅된 골재를 온풍으로건조하는 간단한 펄안료가 코팅된 골재를 수득하도록 함과,Mixing and stirring the xylene, nitrocellulose resin and the pearl pigment to obtain a simple pearl pigment coated aggregate for drying the coated aggregate with warm air by input of the aggregate,
상기의 골재에 물, 분산제, 아크릴계 바인더, 아크릴계 점증제, pH조정제를 혼합하여 구비되는 접착바인더를 혼합시켜 건축마감재를 얻을 수 있는 간편한 제조로 이루워지는 특징과 이러한 건축마감재를 이용하여 건축물의 내외벽에 도포함으로서 펄안료가 코팅된 골재 및 이를 함유한 마감재는 펄 특유의 귀금속성 색감과 진주빛 광택으로 인하여 심미감가 보다 고급스러운 건축물을 제공할 수 있고 시각적 효과를 더욱 증대하여 건축업계에서 새로운 장식효과를 가지는 골재 및 건축마감재를 제공할 수 있는 유용한 발명이다.The interior of the building using the building material and the characteristics made of a simple manufacturing can be obtained by mixing the adhesive binder provided by mixing the aggregate, water, dispersant, acrylic binder, acrylic thickener, pH adjuster to the aggregate. Aggregate coated with pearl pigment as a coating on the outer wall and finishing materials containing it can provide a more aesthetically pleasing construction with the pearl's unique precious metal color and pearlescent luster, and further enhance the visual effect to create new decoration in the construction industry. It is a useful invention that can provide aggregate and construction finishing materials having an effect.
Claims (5)
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| KR1020060075096A KR100711244B1 (en) | 2006-08-09 | 2006-08-09 | Aggregate coted with pearl pigment and building finishing material comprising it |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55125167A (en) | 1979-03-22 | 1980-09-26 | Umehiko:Kk | Production of wall covering material having metallic luster |
| JPS6259673A (en) | 1985-09-10 | 1987-03-16 | Shikoku Chem Corp | Production of wall surface finishing agent |
| JPH09176515A (en) * | 1995-12-25 | 1997-07-08 | Nippon Glass Fiber Co Ltd | Pearlescent pigment and synthetic resin composition mixed with the same |
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2006
- 2006-08-09 KR KR1020060075096A patent/KR100711244B1/en not_active IP Right Cessation
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55125167A (en) | 1979-03-22 | 1980-09-26 | Umehiko:Kk | Production of wall covering material having metallic luster |
| JPS6259673A (en) | 1985-09-10 | 1987-03-16 | Shikoku Chem Corp | Production of wall surface finishing agent |
| JPH09176515A (en) * | 1995-12-25 | 1997-07-08 | Nippon Glass Fiber Co Ltd | Pearlescent pigment and synthetic resin composition mixed with the same |
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