JPS63154611A - Prehair rinse type hair treating agent composition - Google Patents
Prehair rinse type hair treating agent compositionInfo
- Publication number
- JPS63154611A JPS63154611A JP30103486A JP30103486A JPS63154611A JP S63154611 A JPS63154611 A JP S63154611A JP 30103486 A JP30103486 A JP 30103486A JP 30103486 A JP30103486 A JP 30103486A JP S63154611 A JPS63154611 A JP S63154611A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- treatment composition
- rinse type
- type hair
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 29
- 229920000642 polymer Polymers 0.000 claims abstract description 16
- 229920001577 copolymer Polymers 0.000 claims abstract description 6
- 229920001285 xanthan gum Polymers 0.000 claims abstract description 5
- 235000010493 xanthan gum Nutrition 0.000 claims abstract description 5
- 239000000230 xanthan gum Substances 0.000 claims abstract description 5
- 229940082509 xanthan gum Drugs 0.000 claims abstract description 5
- 150000004676 glycans Chemical class 0.000 claims abstract description 4
- 229920001282 polysaccharide Polymers 0.000 claims abstract description 4
- 239000005017 polysaccharide Substances 0.000 claims abstract description 4
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 claims abstract description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 3
- 235000017788 Cydonia oblonga Nutrition 0.000 claims abstract description 3
- 229920002581 Glucomannan Polymers 0.000 claims abstract description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims abstract description 3
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims abstract description 3
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims abstract description 3
- 229920000161 Locust bean gum Polymers 0.000 claims abstract description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 3
- 229940046240 glucomannan Drugs 0.000 claims abstract description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims abstract description 3
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims abstract description 3
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims abstract description 3
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims abstract description 3
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims abstract description 3
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims abstract description 3
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims abstract description 3
- 235000010420 locust bean gum Nutrition 0.000 claims abstract description 3
- 239000000711 locust bean gum Substances 0.000 claims abstract description 3
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims abstract description 3
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 claims abstract 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims abstract 2
- 238000011282 treatment Methods 0.000 claims description 23
- 229920006318 anionic polymer Polymers 0.000 claims description 13
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 7
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 7
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 7
- -1 loin Chemical compound 0.000 claims description 6
- 229920002567 Chondroitin Polymers 0.000 claims description 4
- 229920000045 Dermatan sulfate Polymers 0.000 claims description 4
- DLGJWSVWTWEWBJ-HGGSSLSASA-N chondroitin Chemical compound CC(O)=N[C@@H]1[C@H](O)O[C@H](CO)[C@H](O)[C@@H]1OC1[C@H](O)[C@H](O)C=C(C(O)=O)O1 DLGJWSVWTWEWBJ-HGGSSLSASA-N 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 229940094517 chondroitin 4-sulfate Drugs 0.000 claims description 3
- KXKPYJOVDUMHGS-OSRGNVMNSA-N chondroitin sulfate Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](OS(O)(=O)=O)[C@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](C(O)=O)O1 KXKPYJOVDUMHGS-OSRGNVMNSA-N 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 3
- 229920001059 synthetic polymer Polymers 0.000 claims description 3
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 claims description 2
- OEANUJAFZLQYOD-CXAZCLJRSA-N (2r,3s,4r,5r,6r)-6-[(2r,3r,4r,5r,6r)-5-acetamido-3-hydroxy-2-(hydroxymethyl)-6-methoxyoxan-4-yl]oxy-4,5-dihydroxy-3-methoxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](OC)O[C@H](CO)[C@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](OC)[C@H](C(O)=O)O1 OEANUJAFZLQYOD-CXAZCLJRSA-N 0.000 claims description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 244000215068 Acacia senegal Species 0.000 claims description 2
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims description 2
- 239000004375 Dextrin Substances 0.000 claims description 2
- 229920001353 Dextrin Polymers 0.000 claims description 2
- 229920002907 Guar gum Polymers 0.000 claims description 2
- 229920000084 Gum arabic Polymers 0.000 claims description 2
- 229920002971 Heparan sulfate Polymers 0.000 claims description 2
- 229920000288 Keratan sulfate Polymers 0.000 claims description 2
- 239000004373 Pullulan Substances 0.000 claims description 2
- 229920001218 Pullulan Polymers 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 235000010489 acacia gum Nutrition 0.000 claims description 2
- 239000000205 acacia gum Substances 0.000 claims description 2
- 235000010418 carrageenan Nutrition 0.000 claims description 2
- 239000000679 carrageenan Substances 0.000 claims description 2
- 229920001525 carrageenan Polymers 0.000 claims description 2
- 229940113118 carrageenan Drugs 0.000 claims description 2
- 229940051593 dermatan sulfate Drugs 0.000 claims description 2
- 235000019425 dextrin Nutrition 0.000 claims description 2
- 235000010417 guar gum Nutrition 0.000 claims description 2
- 239000000665 guar gum Substances 0.000 claims description 2
- 229960002154 guar gum Drugs 0.000 claims description 2
- 229920000591 gum Polymers 0.000 claims description 2
- 229920002674 hyaluronan Polymers 0.000 claims description 2
- 229960003160 hyaluronic acid Drugs 0.000 claims description 2
- KXCLCNHUUKTANI-RBIYJLQWSA-N keratan Chemical compound CC(=O)N[C@@H]1[C@@H](O)C[C@@H](COS(O)(=O)=O)O[C@H]1O[C@@H]1[C@@H](O)[C@H](O[C@@H]2[C@H](O[C@@H](O[C@H]3[C@H]([C@@H](COS(O)(=O)=O)O[C@@H](O)[C@@H]3O)O)[C@H](NC(C)=O)[C@H]2O)COS(O)(=O)=O)O[C@H](COS(O)(=O)=O)[C@@H]1O KXCLCNHUUKTANI-RBIYJLQWSA-N 0.000 claims description 2
- 229940117841 methacrylic acid copolymer Drugs 0.000 claims description 2
- 229920003145 methacrylic acid copolymer Polymers 0.000 claims description 2
- 229920000609 methyl cellulose Polymers 0.000 claims description 2
- 239000001923 methylcellulose Substances 0.000 claims description 2
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 claims description 2
- 229920001277 pectin Polymers 0.000 claims description 2
- 239000001814 pectin Substances 0.000 claims description 2
- 235000010987 pectin Nutrition 0.000 claims description 2
- 229960000292 pectin Drugs 0.000 claims description 2
- 235000019423 pullulan Nutrition 0.000 claims description 2
- 235000010413 sodium alginate Nutrition 0.000 claims description 2
- 239000000661 sodium alginate Substances 0.000 claims description 2
- 229940005550 sodium alginate Drugs 0.000 claims description 2
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 2
- VFNGKCDDZUSWLR-UHFFFAOYSA-L disulfate(2-) Chemical compound [O-]S(=O)(=O)OS([O-])(=O)=O VFNGKCDDZUSWLR-UHFFFAOYSA-L 0.000 claims 2
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- AVJBPWGFOQAPRH-FWMKGIEWSA-L dermatan sulfate Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@H](OS([O-])(=O)=O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](C([O-])=O)O1 AVJBPWGFOQAPRH-FWMKGIEWSA-L 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 8
- 239000002453 shampoo Substances 0.000 abstract description 7
- 239000004615 ingredient Substances 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 3
- 125000000129 anionic group Chemical group 0.000 abstract 2
- 206010043268 Tension Diseases 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 9
- 238000011156 evaluation Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 6
- 239000002932 luster Substances 0.000 description 5
- 230000001953 sensory effect Effects 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000003676 hair preparation Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- VFNGKCDDZUSWLR-UHFFFAOYSA-N disulfuric acid Chemical compound OS(=O)(=O)OS(O)(=O)=O VFNGKCDDZUSWLR-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- FPJHWYCPAOPVIV-VOZMEZHOSA-N (2R,3S,4R,5R,6R)-6-[(2R,3R,4R,5R,6R)-5-acetamido-2-(hydroxymethyl)-6-methoxy-3-sulfooxyoxan-4-yl]oxy-4,5-dihydroxy-3-methoxyoxane-2-carboxylic acid Chemical compound CO[C@@H]1O[C@H](CO)[C@H](OS(O)(=O)=O)[C@H](O[C@@H]2O[C@H]([C@@H](OC)[C@H](O)[C@H]2O)C(O)=O)[C@H]1NC(C)=O FPJHWYCPAOPVIV-VOZMEZHOSA-N 0.000 description 1
- YLZOPXRUQYQQID-UHFFFAOYSA-N 3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]propan-1-one Chemical compound N1N=NC=2CN(CCC=21)CCC(=O)N1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F YLZOPXRUQYQQID-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- ZNOZWUKQPJXOIG-XSBHQQIPSA-L [(2r,3s,4r,5r,6s)-6-[[(1r,3s,4r,5r,8s)-3,4-dihydroxy-2,6-dioxabicyclo[3.2.1]octan-8-yl]oxy]-4-[[(1r,3r,4r,5r,8s)-8-[(2s,3r,4r,5r,6r)-3,4-dihydroxy-6-(hydroxymethyl)-5-sulfonatooxyoxan-2-yl]oxy-4-hydroxy-2,6-dioxabicyclo[3.2.1]octan-3-yl]oxy]-5-hydroxy-2-( Chemical compound O[C@@H]1[C@@H](O)[C@@H](OS([O-])(=O)=O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H]2OC[C@H]1O[C@H](O[C@H]1[C@H]([C@@H](CO)O[C@@H](O[C@@H]3[C@@H]4OC[C@H]3O[C@H](O)[C@@H]4O)[C@@H]1O)OS([O-])(=O)=O)[C@@H]2O ZNOZWUKQPJXOIG-XSBHQQIPSA-L 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000003766 combability Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 210000003128 head Anatomy 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229920000831 ionic polymer Polymers 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、ヘアリンス前に毛髪に塗布して用いるプレへ
アリンス型毛髪処理剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a pre-rinse type hair treatment composition that is applied to the hair before rinsing the hair.
更に詳しくは、少なくとも一種以上の陰イオン性高分子
および少なくとも一種以上の非イオン性高分子を含有し
毛髪になめらかさ、しなやかさを与えながら、張り、こ
しをも付与することを特徴とするプレヘアリンス型毛髪
処理剤組成物に関する。More specifically, it is characterized by containing at least one kind of anionic polymer and at least one kind of nonionic polymer, which imparts smoothness and suppleness to the hair, as well as tension and stiffness. The present invention relates to a hair rinse type hair treatment composition.
［従来の技術］
従来シャンプーは、地肌や毛髪についた汚れを洗浄し清
潔にする機能を有するが、その反面幾つかの欠点が指摘
されてきている。それは、頭皮から分泌される皮脂成分
を過剰に除去するため毛髪の手触り感触、ブラシ、若し
くは櫛の通り、光沢、まとまりやすさ等が劣ることであ
る。[Prior Art] Conventional shampoos have the function of cleaning and cleaning dirt from the skin and hair, but on the other hand, several drawbacks have been pointed out. This is because the sebum components secreted from the scalp are removed excessively, so that the texture of the hair, the ability to brush or comb it, the shine, and the ease with which it is combed are deteriorated.
そのためシャンプー後の毛髪に、なめらかさ、しなやか
さ、光沢を回復させ櫛通りを良くする事を目的とした毛
髪化粧料としては、ヘアリンス、ヘアートリートメント
、ヘアーコンデショナー等の名称（以下、ヘアリンス剤
として総称する）のものが市販されている。 これら毛
髪化粧料には、主に、第４級アンモニウム塩が配合され
、更になめらかさ、しっとりさ、光沢を向上させる目的
で、油分やタンパク質等が添加されてきた。Therefore, hair cosmetics aimed at restoring smoothness, suppleness, and luster to hair after shampooing and making it easier to comb are known as hair rinses, hair treatments, hair conditioners, etc. (hereinafter collectively referred to as hair rinses). ) are commercially available. These hair cosmetics mainly contain quaternary ammonium salts, and oils, proteins, etc. have also been added for the purpose of improving smoothness, moisture, and gloss.
［発明が解決しようとする問題点コ
しかしながら、シャンプー後に従来のヘアリンス剤を使
用することにより、髪のしなやかさ、なめらかさ、光沢
を回復させ櫛通りをよくすることはできるが、その反面
、油っぽさ、べたつき等が現れ、更には仕上り感の重さ
から髪に張り、こしがなくなり自然な感じでのまとまり
やすさに難点があることが指摘されてきた。[Problems to be Solved by the Invention] However, by using a conventional hair rinse after shampooing, it is possible to restore the suppleness, smoothness, and luster of the hair and make it easier to comb, but on the other hand, it removes oil. It has been pointed out that hair tends to feel dry, sticky, etc., and that it has a heavy finish that causes it to stick to the hair, eliminates stiffness, and makes it difficult to manage hair naturally.
本発明者らは、こうした事情にかんがみ、上記の欠点を
解決すべく鋭意研究を重ねた結果、シャンプー後ヘアリ
ンス剤を使用する前に、特定の陰イオン性高分子および
非イオン性高分子を有効成分として配合したプレヘアリ
ンス型毛髪処理剤組成物を毛髪に塗布し、その後ヘアリ
ンス剤で処理すれば、シャンプー後の髪に、しなやかさ
、なめらかさ、光沢更には櫛通りを回復させ、尚且つ、
油つぼさ、へたつき感がなく髪にはり、こしを与え、自
然な感じでのまとまりやすさが得られることを見いだし
この知見に基づいて本発明を完成するに至った。In view of these circumstances, the present inventors have conducted intensive research to solve the above-mentioned drawbacks, and as a result, we have found that specific anionic polymers and nonionic polymers can be effectively used before using a hair rinse after shampooing. By applying the pre-hair rinse type hair treatment composition formulated as an ingredient to the hair and then treating it with a hair rinse agent, the hair after shampooing can be restored to suppleness, smoothness, luster, and even combability.
It was discovered that hair was coated and stiffened without feeling oily or dry, and the hair was naturally manageable.Based on this knowledge, the present invention was completed.
［問題点を解決するための手段］
すなわち、本発明は、少なくとも一種以上の陰イオン性
高分子および少なくとも一種以上の非イオン性高分子を
含有することを特徴とするプレヘアリンス型毛髪処理剤
組成物を提供するものである。[Means for Solving the Problems] That is, the present invention provides a pre-hair rinse type hair treatment composition characterized by containing at least one kind of anionic polymer and at least one kind of nonionic polymer. It is something that provides something.
以下、本発明の構成について詳述する。Hereinafter, the configuration of the present invention will be explained in detail.
本発明に用いられる陰イオン性高分子は、キサンタンガ
ム、グルコマンナン、クインスシードガム、ローカスト
ビーンガム、アラビアガム、グアーガム、アルギン酸ソ
ーダ、カラギーナン（カッパー、ラムダ、アイオタ）、
ペクチン、ヒアルロン酸、コンドロイチン４硫酸、コン
ドロイチン８硫酸、デルマタン硫酸、コンドロイチン４
，８ジ硫酸、デルマタン４，８ジ硫酸、ケラタン硫酸、
又はヘパラン硫酸といった天然多糖類又はポリアクリル
酸ソーダ、カルボキシメチルセルロース、ビニールエー
テル／無水マレイン酸共重合物、アクリル酸エステル／
メタアクリル酸エステル／ダイアセトンアクリルアマイ
ド／アクリル酸／メタアクリル酸共重合物、又は架橋化
カルボキシビニールポリマーなどの合成高分子であり、
これらのうち一種又は二種以上が任意に選択されて用い
られる。The anionic polymers used in the present invention include xanthan gum, glucomannan, quince seed gum, locust bean gum, gum arabic, guar gum, sodium alginate, carrageenan (kappa, lambda, iota),
Pectin, hyaluronic acid, chondroitin 4 sulfate, chondroitin 8 sulfate, dermatan sulfate, chondroitin 4
,8 disulfuric acid, dermatan 4,8 disulfuric acid, keratan sulfate,
or natural polysaccharides such as heparan sulfate, sodium polyacrylate, carboxymethyl cellulose, vinyl ether/maleic anhydride copolymer, acrylic ester/
A synthetic polymer such as methacrylic acid ester/diacetone acrylamide/acrylic acid/methacrylic acid copolymer or crosslinked carboxyvinyl polymer,
One or more of these may be arbitrarily selected and used.
更にまた、本発明に用いられる非イオン性高分子は、ヒ
ドロキシエチルセルロース、ヒドロキシプロピルセルロ
ース、ヒドロキシプロピルメチルセルロース、ポリビニ
ールアルコール、ポリビニールピロリドン、ポリビニー
ルピロリドン／酢酸ビニール共重合、物、メチルセルロ
ース、デキストリン、ガラクタン又はプルランでありこ
れらのうち一種又は二種以上が任意に選択されて用いら
れる。Furthermore, the nonionic polymers used in the present invention include hydroxyethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, polyvinyl alcohol, polyvinylpyrrolidone, polyvinylpyrrolidone/vinyl acetate copolymer, methylcellulose, dextrin, and galactan. or pullulan, and one or more of these may be arbitrarily selected and used.
本発明のプレヘアリンス型毛髪処理剤組成物において陰
イオン性高分子の配合量はプレヘアリンス型毛髪処理剤
組成物全量中の０．０１〜５重量％（以下、単に％と略
す）が好ましく、また非イオン性高分子は、０．０１〜
５％が好ましい。In the pre-hair rinse type hair treatment composition of the present invention, the blending amount of the anionic polymer is preferably 0.01 to 5% by weight (hereinafter simply abbreviated as %) based on the total amount of the pre-hair rinse type hair treatment composition. In addition, nonionic polymers range from 0.01 to
5% is preferred.
そして、両者においてこれより少ないと、本プレヘアリ
ンス型毛髪処理剤組成物を塗布後、ヘアリンス剤で処理
しても、しなやかさ、なめらかさ、光沢が発現しにくく
毛髪のはり、こしも満足されるものでない。又、これよ
り多いと毛髪がへたついたり、乾いた後でごねついたり
して好ましくない。If both are less than this, even if the pre-hair rinse type hair treatment composition is applied and then treated with a hair rinse agent, flexibility, smoothness, and luster will be difficult to develop, and the firmness and stiffness of the hair will also be unsatisfactory. It's not something. Moreover, if the amount is more than this, the hair will become untidy or sticky after drying, which is not preferable.
本発明において使用される陰イオン性高分子ならびに非
イオン性高分子を、仮にカチオン性界面活性剤を主成分
とするヘアリンス剤組成物中に併用配合しても本発明の
様な優れた効果は得られないばかりか、組成物中で凝集
物が生じたり、又経日で分離、沈澱が起こり安定性はき
わめて悪いものであった。Even if the anionic polymer and nonionic polymer used in the present invention are combined in a hair rinse composition containing a cationic surfactant as the main component, the excellent effects as in the present invention will not be obtained. Not only was this not possible, but the stability was extremely poor, with aggregates forming in the composition and separation and precipitation occurring over time.
本発明のプレヘアリンス型毛髪処理剤組成物には、上記
の必須成分に加えて配合組成物を完成させるための水を
要する他、毛髪化粧料に常用される成分や添加剤を配合
することも可能である。即ち、高級アルコール、シリコ
ーン油、流動パラフィン等の油分、プロピレングリコー
ル、グリセリン等の保湿剤、ＰＯＥ （ポリオキシエチ
レン；以下同じ）硬化ヒマシ油、ＰＯＥアルキルエーテ
ル等の非イオン性界面活性剤、クエン酸、乳酸等の有機
酸、塩化ナトリウム、塩化カリウム等の無機塩、香料、
色剤、防腐剤、キレート剤、紫外線吸収剤等を、本発明
の効果を損なわない範囲で適宜配合できる。In addition to the above-mentioned essential ingredients, the pre-hair rinse type hair treatment composition of the present invention requires water to complete the composition, and may also contain ingredients and additives commonly used in hair cosmetics. It is possible. In other words, oils such as higher alcohols, silicone oils, and liquid paraffin, humectants such as propylene glycol and glycerin, nonionic surfactants such as POE (polyoxyethylene; the same applies hereinafter) hydrogenated castor oil, and POE alkyl ethers, and citric acid. , organic acids such as lactic acid, inorganic salts such as sodium chloride and potassium chloride, fragrances,
Coloring agents, preservatives, chelating agents, ultraviolet absorbers, etc. may be appropriately added within the range that does not impair the effects of the present invention.
［実施例］
以下、実施例によって本発明を具体的に詳述するが、本
発明はこれらによって限定されるものではない。配合量
は重量％である。[Examples] Hereinafter, the present invention will be specifically explained in detail with reference to Examples, but the present invention is not limited thereto. The blending amount is in weight%.
実施例１〜１５、比較例１
非オン性高分子であるポリビニールピロリドンおよび本
発明の陰イオン性高分子を用いて、次に示すプレヘアリ
ンス型毛髪処理剤組成物を調整した。Examples 1 to 15, Comparative Example 1 The following pre-hair rinse type hair treatment compositions were prepared using polyvinyl pyrrolidone, which is a non-ionic polymer, and the anionic polymer of the present invention.
次に以下に示す方法により、洗髪後の髪の感触について
評価した。Next, the feel of the hair after washing was evaluated by the method shown below.
゛ ′のの触
女性パネル２０名によるＨａｌｆ−Ｈｅａｄ法（生類比
較法）にて比較判定した。Comparisons were made using the Half-Head method (organism comparison method) by a panel of 20 women.
すなわち、市販シャンプー１０ｇで１回洗髪し軽くすす
いだ後、同じシャンプー５ｇで２回目の洗髪をした。軽
くすすいだ後、頭髪の半分に本発明のプレヘアリンス型
毛髪処理剤組成物１０ｇを塗布し、もう半分は何もつけ
ない。２分後に、市販ヘアリンス剤を頭髪全部に塗布し
２分後、お湯で全てを洗い流す。その後、風乾し官能に
よって評価した。That is, after washing the hair once with 10 g of commercially available shampoo and rinsing lightly, the hair was washed a second time with 5 g of the same shampoo. After rinsing lightly, 10 g of the pre-hair rinse type hair treatment composition of the present invention is applied to half of the hair, and nothing is applied to the other half. After 2 minutes, apply a commercially available hair rinse to all of your hair, and after 2 minutes, rinse everything off with hot water. Thereafter, it was air-dried and evaluated by sensory evaluation.
評価は、「なめらかさ」「シなやかさ」「光沢」「毛髪
のはり、こし」「髪のまとまり易さ」の５項目について
実施した。The evaluation was carried out on five items: "smoothness", "flexibility", "gloss", "hair elasticity", "hair manageability".
官能評価は、本発明のプレヘアリンス型毛髪処理剤組成
物を塗布しない方を基準として一対比較によって以下の
５段階評価で行った。Sensory evaluation was performed on the following five-point scale based on pairwise comparison with reference to the one without application of the pre-hair rinse type hair treatment composition of the present invention.
評価点
＋２ 未使用に比して優れている
＋１ 未使用に比してやや優れている０ 未
使用と同程度
−１未使用に比してやや劣る
−２ 未使用に比して劣る
結果については、女性パネル２０名の平均評価点で示し
た。Evaluation score +2 Superior to unused +1 Slightly superior to unused 0 Same as unused -1 Slightly inferior to unused -2 For results inferior to unused, It is shown as the average evaluation score of 20 female panelists.
（効果）
表２かられかるように本発明例では、なめらかさ、しな
やかさ、光沢、毛髪のはり、こし、髪のまとまりやすさ
の全ての項目において、未使用に比較し、非常に優れて
いることがわかる。(Effects) As can be seen from Table 2, the examples of the present invention were extremely superior in all items of smoothness, suppleness, luster, hair firmness, strain, and ease of hair management compared to unused hair. I know that there is.
又、本発明に必須成分の一つである陰イオン性高分子を
配合しない比較例においては、効果が劣ることがわかる
。Moreover, it can be seen that the effect is inferior in the comparative example in which the anionic polymer, which is one of the essential components of the present invention, is not blended.
尚、陰イオン性高分子のなかでは、特に、キサンタンガ
ム、カッパーカラギーナン、コンドロイチン４硫酸が全
ての項目において、平均的に効果があった。Among the anionic polymers, xanthan gum, kappa carrageenan, and chondroitin 4-sulfate were particularly effective on average in all items.
（以下余白）
表１
表２
実施例１６〜２５
陰イオン性高分子であるキサンタンガムおよび本発明の
非イオン性高分子を用いて、次に示すプレヘアリンス型
毛髪処理剤組成物を調整した。(The following are blank spaces) Table 1 Table 2 Examples 16 to 25 Using xanthan gum, which is an anionic polymer, and the nonionic polymer of the present invention, the following pre-hair rinse type hair treatment composition was prepared.
次に以下に示す方法により、洗髪後の髪の感触について
評価した。Next, the feel of the hair after washing was evaluated by the method shown below.
゛ ′のの
パーマおよびヘアカラー処理を頻繁にしてい専門パネル
３０名によるＨａｌｆ−Ｈｅａｄ法（単頭比較法）にて
比較判定した。Comparisons were made using the Half-Head method (single head comparison method) by a panel of 30 experts who frequently undergo perm and hair color treatments.
すなわち、市販シャンプー１０ｇで１回洗髪し軽くすす
いだ後、同じシャンプー５ｇで２回目の洗髪をした。軽
くすすいだ後、頭髪の半分に本発明のプレヘアリンス型
毛髪処理剤組成物１．０ｇを塗布し、もう半分は、比較
例２の試料１．０ｇを塗布した。That is, after washing the hair once with 10 g of commercially available shampoo and rinsing lightly, the hair was washed a second time with 5 g of the same shampoo. After rinsing lightly, 1.0 g of the pre-hair rinse type hair treatment composition of the present invention was applied to half of the hair, and 1.0 g of the sample of Comparative Example 2 was applied to the other half.
２分後に、市販ヘアリンス剤を頭髪全部に塗布し２分後
、お湯で全てを洗い流す。その後、風乾し官能によって
評価した。After 2 minutes, apply a commercially available hair rinse to all of your hair, and after 2 minutes, rinse everything off with hot water. Thereafter, it was air-dried and evaluated by sensory evaluation.
評価は、「なめらかさ」「シなやかさ」「光沢」「毛髪
のはり、こし」「髪のまとまり易さ」の５項目について
実施した。The evaluation was carried out on five items: "smoothness", "flexibility", "gloss", "hair elasticity and stiffness", and "hair manageability".
官能評価は、本発明のプレヘアリンス型毛髪処理剤組成
物を塗布しない方を基準として一対比較によって以下の
５段階評価で行った。Sensory evaluation was performed on the following five-point scale based on pairwise comparison with reference to the one without application of the pre-hair rinse type hair treatment composition of the present invention.
評価点
＋２ 比較例２に比してすぐれている＋１ 比較例
２に比してややすぐれている０ 比較例２と同程度
−１比較例２に比してやや劣る
−２ 比較例２に比して劣る
結果については、専門パネル８０名の平均評価点で示し
た。Evaluation score +2 Superior to Comparative Example 2 +1 Slightly superior to Comparative Example 2 0 Same as Comparative Example 2 -1 Slightly inferior to Comparative Example 2 -2 Compared to Comparative Example 2 Inferior results were indicated by the average score of 80 expert panelists.
（以下余白）
表３
（効果）
表４かられかるように本発明例では、なめらかさ、しな
やかさ、光沢、毛髪のはり、こし、髪のまとまりやすさ
の全ての項目において、未使用に比較し、非常に優れて
いることがわかる。(Leaving space below) Table 3 (Effects) As shown in Table 4, the inventive example was compared to unused hair in all items of smoothness, suppleness, gloss, hair elasticity, strain, and ease of hair management. and it turns out to be very good.
又、本発明に必須成分の一つである非イオン性高分子を
配合しない比較例においては、効果が劣ることがわかる
。Moreover, it can be seen that the effect is inferior in the comparative example in which the nonionic polymer, which is one of the essential components of the present invention, is not blended.
尚、非イオン性高分子のなかでは、特に、ポリビニール
アルコール、ポリビニールピロリドン、ポリビニールピ
ロリドン／酢酸ビニール共重合物が全ての項目において
、平均的に効果があった。Among the nonionic polymers, polyvinyl alcohol, polyvinyl pyrrolidone, and polyvinyl pyrrolidone/vinyl acetate copolymer were particularly effective on average in all items.
（以下余白）
表４
「発明の効果」
本発明のプレヘアリンス型毛髪処理剤組成物は従来のシ
ャンプーとヘアリンスの間に使用する。(The following is a blank space) Table 4 "Effects of the Invention" The pre-hair rinse type hair treatment composition of the present invention is used between a conventional shampoo and a hair rinse.
而して、髪になめらかさ、しなやかさを与えながら、張
り、こしをも賦与することができる。In this way, it is possible to impart tension and stiffness to the hair while giving smoothness and suppleness to the hair.
Claims (6)
なくとも一種以上の非イオン性高分子を含有することを
特徴とするプレヘアリンス型毛髪処理剤組成物。(1) A pre-hair rinse type hair treatment composition containing at least one kind of anionic polymer and at least one kind of nonionic polymer.
範囲第（１）項記載のプレヘアリンス型毛髪処理剤組成
物。(2) The pre-hair rinse type hair treatment composition according to claim (1), wherein the anionic polymer is a natural polysaccharide.
クインスシードガム、ローカストビーンガム、アラビア
ガム、グアーガム、アルギン酸ソーダ、カラギーナン（
カッパー、ラムダ、アイオタ）、ペクチン、ヒアルロン
酸、コンドロイチン４硫酸、コンドロイチン８硫酸、デ
ルマタン硫酸、コンドロイチン４，８ジ硫酸、デルマタ
ン４，８ジ硫酸、ケラタン硫酸又はヘパラン硫酸である
特許請求の範囲第（２）項記載のプレヘアリンス型毛髪
処理剤組成物。(3) Natural polysaccharides include xanthan gum, glucomannan,
Quince seed gum, locust bean gum, gum arabic, guar gum, sodium alginate, carrageenan (
Copper, lambda, iota), pectin, hyaluronic acid, chondroitin 4 sulfate, chondroitin 8 sulfate, dermatan sulfate, chondroitin 4,8 disulfate, dermatan 4,8 disulfate, keratan sulfate or heparan sulfate ( The pre-hair rinse type hair treatment composition according to item 2).
範囲第（１）項記載のプレヘアリンス型毛髪処理剤組成
物。(4) The pre-hair rinse type hair treatment composition according to claim (1), wherein the anionic polymer is a synthetic polymer.
メチルセルロース、ロース、メチルビニールエーテル／
無水マレイン酸共重合物、アクリル酸エステル／メタア
クリル酸エステル／ダイアセトンアクリルアマイド／ア
クリル酸／メタアクリル酸共重合物、又は架橋化カルボ
キシビニールポリマーである特許請求の範囲第（４）項
記載のプレヘアリンス型毛髪処理剤組成物。(5) Synthetic polymers include sodium polyacrylate, carboxymethyl cellulose, loin, methyl vinyl ether/
Claim 4, which is a maleic anhydride copolymer, an acrylic ester/methacrylic ester/diacetone acrylamide/acrylic acid/methacrylic acid copolymer, or a crosslinked carboxyvinyl polymer Pre-hair rinse type hair treatment composition.
、ヒドロキシプロピルセルロース、ヒドロキシプロピル
メチルセルロース、ポリビニールアルコールポリビニー
ルピロリドン、ポリビニールピロリドン／酢酸ビニール
共重合物、メチルセルロース、デキストリン、ガラクタ
ン又はプルランである特許請求の範囲第（１）項乃至第
（５）のいずれかに記載のプレヘアリンス型毛髪処理剤
組成物。(6) Claims in which the nonionic polymer is hydroxyethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, polyvinyl alcohol polyvinylpyrrolidone, polyvinylpyrrolidone/vinyl acetate copolymer, methylcellulose, dextrin, galactan, or pullulan. The pre-hair rinse type hair treatment composition according to any one of items (1) to (5).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30103486A JPH0751492B2 (en) | 1986-12-17 | 1986-12-17 | Pre-hair rinse type hair treatment composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30103486A JPH0751492B2 (en) | 1986-12-17 | 1986-12-17 | Pre-hair rinse type hair treatment composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63154611A true JPS63154611A (en) | 1988-06-27 |
| JPH0751492B2 JPH0751492B2 (en) | 1995-06-05 |
Family
ID=17892055
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP30103486A Expired - Fee Related JPH0751492B2 (en) | 1986-12-17 | 1986-12-17 | Pre-hair rinse type hair treatment composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0751492B2 (en) |
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|---|---|---|---|---|
| JP2006199648A (en) * | 2005-01-21 | 2006-08-03 | Dai Ichi Seiyaku Co Ltd | Composition for hair |
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| US11213470B2 (en) | 2015-11-24 | 2022-01-04 | L'oreal | Compositions for treating the hair |
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| US10555891B2 (en) | 2017-05-24 | 2020-02-11 | L'oreal | Methods for treating chemically treated hair |
| US11433011B2 (en) | 2017-05-24 | 2022-09-06 | L'oreal | Methods for treating chemically relaxed hair |
| US11596588B2 (en) | 2017-12-29 | 2023-03-07 | L'oreal | Compositions for altering the color of hair |
| US11975092B2 (en) | 2018-10-31 | 2024-05-07 | L'oreal | Hair treatment compositions, methods, and kits for treating hair |
| US11090249B2 (en) | 2018-10-31 | 2021-08-17 | L'oreal | Hair treatment compositions, methods, and kits for treating hair |
| US11419809B2 (en) | 2019-06-27 | 2022-08-23 | L'oreal | Hair treatment compositions and methods for treating hair |
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| US12036299B2 (en) | 2021-06-30 | 2024-07-16 | L'oreal | Compositions containing direct dyes for imparting color and tone to the hair |
| US12109289B2 (en) | 2021-06-30 | 2024-10-08 | L'oreal | Compositions for imparting color and tone to the hair |
| US12109287B2 (en) | 2022-07-31 | 2024-10-08 | L'oreal | Compositions and methods for altering the color of hair |
| US12144879B2 (en) | 2022-07-31 | 2024-11-19 | L'oreal | Compositions and methods for altering the color of hair |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0751492B2 (en) | 1995-06-05 |
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