JPS6225187B2 - - Google Patents
Info
- Publication number
- JPS6225187B2 JPS6225187B2 JP56150112A JP15011281A JPS6225187B2 JP S6225187 B2 JPS6225187 B2 JP S6225187B2 JP 56150112 A JP56150112 A JP 56150112A JP 15011281 A JP15011281 A JP 15011281A JP S6225187 B2 JPS6225187 B2 JP S6225187B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- water
- resin
- monoethylenically unsaturated
- monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920005989 resin Polymers 0.000 claims description 82
- 239000011347 resin Substances 0.000 claims description 82
- -1 isocyanate compound Chemical class 0.000 claims description 67
- 239000002245 particle Substances 0.000 claims description 60
- 229920001225 polyester resin Polymers 0.000 claims description 57
- 239000004645 polyester resin Substances 0.000 claims description 57
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 56
- 229920006026 co-polymeric resin Polymers 0.000 claims description 45
- 239000000203 mixture Substances 0.000 claims description 41
- 239000000178 monomer Substances 0.000 claims description 33
- 239000012948 isocyanate Substances 0.000 claims description 30
- 229920001187 thermosetting polymer Polymers 0.000 claims description 18
- 239000008199 coating composition Substances 0.000 claims description 17
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 16
- YGSDEFSMJLZEOE-UHFFFAOYSA-N Salicylic acid Natural products OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 13
- 239000003431 cross linking reagent Substances 0.000 claims description 13
- 150000007965 phenolic acids Chemical class 0.000 claims description 13
- 239000004094 surface-active agent Substances 0.000 claims description 10
- 239000002562 thickening agent Substances 0.000 claims description 10
- 150000001735 carboxylic acids Chemical class 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 238000000576 coating method Methods 0.000 description 63
- 239000011248 coating agent Substances 0.000 description 59
- 239000003973 paint Substances 0.000 description 54
- 239000000243 solution Substances 0.000 description 40
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 39
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 31
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 26
- 238000006243 chemical reaction Methods 0.000 description 26
- 239000002904 solvent Substances 0.000 description 25
- 238000000034 method Methods 0.000 description 18
- 239000002253 acid Substances 0.000 description 16
- 239000006185 dispersion Substances 0.000 description 15
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 12
- 239000000049 pigment Substances 0.000 description 12
- 238000004132 cross linking Methods 0.000 description 11
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 10
- 239000002002 slurry Substances 0.000 description 10
- 229920000178 Acrylic resin Polymers 0.000 description 9
- 239000004925 Acrylic resin Substances 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 9
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 239000002585 base Substances 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 8
- 238000005260 corrosion Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 238000010422 painting Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 7
- 238000003860 storage Methods 0.000 description 7
- 238000003786 synthesis reaction Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 6
- 239000001361 adipic acid Substances 0.000 description 6
- 235000011037 adipic acid Nutrition 0.000 description 6
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 6
- 239000002981 blocking agent Substances 0.000 description 5
- 230000000903 blocking effect Effects 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- 235000019441 ethanol Nutrition 0.000 description 5
- 229940074391 gallic acid Drugs 0.000 description 5
- 235000004515 gallic acid Nutrition 0.000 description 5
- 239000005056 polyisocyanate Substances 0.000 description 5
- 229920001228 polyisocyanate Polymers 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- YQUVCSBJEUQKSH-UHFFFAOYSA-N 3,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C(O)=C1 YQUVCSBJEUQKSH-UHFFFAOYSA-N 0.000 description 4
- 229920000877 Melamine resin Polymers 0.000 description 4
- 239000004640 Melamine resin Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 239000003085 diluting agent Substances 0.000 description 4
- 229910001873 dinitrogen Inorganic materials 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000003822 epoxy resin Substances 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 239000010419 fine particle Substances 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 4
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 229920006243 acrylic copolymer Polymers 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000001723 curing Methods 0.000 description 3
- 238000010494 dissociation reaction Methods 0.000 description 3
- 230000005593 dissociations Effects 0.000 description 3
- 238000005886 esterification reaction Methods 0.000 description 3
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 3
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 230000001771 impaired effect Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000003505 polymerization initiator Substances 0.000 description 3
- 229910052573 porcelain Inorganic materials 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- RTTZISZSHSCFRH-UHFFFAOYSA-N 1,3-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=CC(CN=C=O)=C1 RTTZISZSHSCFRH-UHFFFAOYSA-N 0.000 description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- FZERHIULMFGESH-UHFFFAOYSA-N N-phenylacetamide Chemical compound CC(=O)NC1=CC=CC=C1 FZERHIULMFGESH-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 239000012975 dibutyltin dilaurate Substances 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical class OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000006266 etherification reaction Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 238000009775 high-speed stirring Methods 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pentâ4âenâ2âone Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
- 238000007665 sagging Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- MUTGBJKUEZFXGO-OLQVQODUSA-N (3as,7ar)-3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione Chemical compound C1CCC[C@@H]2C(=O)OC(=O)[C@@H]21 MUTGBJKUEZFXGO-OLQVQODUSA-N 0.000 description 1
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- VNMOIBZLSJDQEO-UHFFFAOYSA-N 1,10-diisocyanatodecane Chemical compound O=C=NCCCCCCCCCCN=C=O VNMOIBZLSJDQEO-UHFFFAOYSA-N 0.000 description 1
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- ZTNJGMFHJYGMDR-UHFFFAOYSA-N 1,2-diisocyanatoethane Chemical compound O=C=NCCN=C=O ZTNJGMFHJYGMDR-UHFFFAOYSA-N 0.000 description 1
- ZGDSDWSIFQBAJS-UHFFFAOYSA-N 1,2-diisocyanatopropane Chemical compound O=C=NC(C)CN=C=O ZGDSDWSIFQBAJS-UHFFFAOYSA-N 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- VGHSXKTVMPXHNG-UHFFFAOYSA-N 1,3-diisocyanatobenzene Chemical compound O=C=NC1=CC=CC(N=C=O)=C1 VGHSXKTVMPXHNG-UHFFFAOYSA-N 0.000 description 1
- OHLKMGYGBHFODF-UHFFFAOYSA-N 1,4-bis(isocyanatomethyl)benzene Chemical compound O=C=NCC1=CC=C(CN=C=O)C=C1 OHLKMGYGBHFODF-UHFFFAOYSA-N 0.000 description 1
- ALQLPWJFHRMHIU-UHFFFAOYSA-N 1,4-diisocyanatobenzene Chemical compound O=C=NC1=CC=C(N=C=O)C=C1 ALQLPWJFHRMHIU-UHFFFAOYSA-N 0.000 description 1
- OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 1
- SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 1
- ICLCCFKUSALICQ-UHFFFAOYSA-N 1-isocyanato-4-(4-isocyanato-3-methylphenyl)-2-methylbenzene Chemical compound C1=C(N=C=O)C(C)=CC(C=2C=C(C)C(N=C=O)=CC=2)=C1 ICLCCFKUSALICQ-UHFFFAOYSA-N 0.000 description 1
- WXTMDXOMEHJXQO-UHFFFAOYSA-N 2,5-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC(O)=CC=C1O WXTMDXOMEHJXQO-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 1
- QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- SXIFAEWFOJETOA-UHFFFAOYSA-N 4-hydroxy-butyl Chemical group [CH2]CCCO SXIFAEWFOJETOA-UHFFFAOYSA-N 0.000 description 1
- MWSKJDNQKGCKPA-UHFFFAOYSA-N 6-methyl-3a,4,5,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1CC(C)=CC2C(=O)OC(=O)C12 MWSKJDNQKGCKPA-UHFFFAOYSA-N 0.000 description 1
- KNDQHSIWLOJIGP-UHFFFAOYSA-N 826-62-0 Chemical compound C1C2C3C(=O)OC(=O)C3C1C=C2 KNDQHSIWLOJIGP-UHFFFAOYSA-N 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- WRQNANDWMGAFTP-UHFFFAOYSA-N Methylacetoacetic acid Chemical compound COC(=O)CC(C)=O WRQNANDWMGAFTP-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical class C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- MBHRHUJRKGNOKX-UHFFFAOYSA-N [(4,6-diamino-1,3,5-triazin-2-yl)amino]methanol Chemical class NC1=NC(N)=NC(NCO)=N1 MBHRHUJRKGNOKX-UHFFFAOYSA-N 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- 229960001413 acetanilide Drugs 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 235000012216 bentonite Nutrition 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- AOJOEFVRHOZDFN-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CC=C1 AOJOEFVRHOZDFN-UHFFFAOYSA-N 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- JBSLOWBPDRZSMB-BQYQJAHWSA-N dibutyl (e)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C\C(=O)OCCCC JBSLOWBPDRZSMB-BQYQJAHWSA-N 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- BEPAFCGSDWSTEL-UHFFFAOYSA-N dimethyl malonate Chemical compound COC(=O)CC(=O)OC BEPAFCGSDWSTEL-UHFFFAOYSA-N 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000009503 electrostatic coating Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 235000010944 ethyl methyl cellulose Nutrition 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 239000008131 herbal destillate Substances 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- TZMQHOJDDMFGQX-UHFFFAOYSA-N hexane-1,1,1-triol Chemical compound CCCCCC(O)(O)O TZMQHOJDDMFGQX-UHFFFAOYSA-N 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 229920003087 methylethyl cellulose Polymers 0.000 description 1
- VYKXQOYUCMREIS-UHFFFAOYSA-N methylhexahydrophthalic anhydride Chemical compound C1CCCC2C(=O)OC(=O)C21C VYKXQOYUCMREIS-UHFFFAOYSA-N 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- UTSYWKJYFPPRAP-UHFFFAOYSA-N n-(butoxymethyl)prop-2-enamide Chemical compound CCCCOCNC(=O)C=C UTSYWKJYFPPRAP-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- HRRDCWDFRIJIQZ-UHFFFAOYSA-N naphthalene-1,8-dicarboxylic acid Chemical compound C1=CC(C(O)=O)=C2C(C(=O)O)=CC=CC2=C1 HRRDCWDFRIJIQZ-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- RUOPINZRYMFPBF-UHFFFAOYSA-N pentane-1,3-diol Chemical compound CCC(O)CCO RUOPINZRYMFPBF-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- QIWKUEJZZCOPFV-UHFFFAOYSA-N phenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=CC=CC=C1 QIWKUEJZZCOPFV-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000003495 polar organic solvent Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007581 slurry coating method Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000007592 spray painting technique Methods 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tertâbutyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- AUHHYELHRWCWEZ-UHFFFAOYSA-N tetrachlorophthalic anhydride Chemical compound ClC1=C(Cl)C(Cl)=C2C(=O)OC(=O)C2=C1Cl AUHHYELHRWCWEZ-UHFFFAOYSA-N 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Description
æ¬çºæã¯åªããèé£æ§ãæãããã€çè³æºãäœ
å ¬å®³æ§ãæºè¶³ããæ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç©ã«
é¢ãããã®ã§ããã è¿å¹Žãå¡æãå¡è£ åéã«æŒãŠãçè³æºãçãšã
ã«ã®ãŒåã³ç°å¢åé¡ãéèŠãªããŒããšããŠãšãã
ãããããããã«é¢ããæ°èŠå¡æã®éçºãå¡è£ æ¹
æ³ã®æ¹è¯ãé²ããããŠãããç¹ã«ãå¡æã®åžéå€
ã§ããææ©æº¶åªã¯å¡è也ç¥éçšã§å€§æ°ã«æåºãã
ãããçè³æºãç°å¢ä¿å šã®ç¹ãã極ããŠç±ã ãã
åé¡ãšãããŠããããã®ãããªäºæ ãæ¹è¯ããã
ãå¡æäžã®ææ©æº¶åªãäœæžããåªåãè¡ãªããã
ãã®çµæãšããŠãã€ãœãªãããšç§°ãããé«äžæ®çº
åå¡æãé«ååéããªããŒãé極æ§ææ©æº¶åªïŒè
èªæç³»çåæ°ŽçŽ ïŒäžã«é«æ¿åºŠã«åæ£ããNAD
ïŒéæ°Žãã€ã¹ããŒã·ãšã³ïŒå¡æãåžéå€ã«æ°Žã䜿
çšããæ°Žç³»å¡æãåžéå€ãã®ãã®ãå šã䜿çšããª
ãç²äœå¡æãªã©ããã§ã«äžåžãããŠãããåŸã ã«
溶å€åå¡æã眮æãã€ã€ãããäžã§ãæ°Žç³»å¡æã«
ã€ããŠã¯åžéå€ãšããŠæ°Žã䜿çšããããç«çœçã®
å±éºããªãããšãåŸæ¥ã®å¡è£ è£ çœ®ããã®ãŸãŸæµçš
ã§ããããšãå¡è£ ç°å¢ãå¿«é©ã§ããããšãªã©ã®ç
ç±ããå¡æã®å°æ¥ç³»ãšããŠæ³šç®ãããŠããããã
ãæ°Žç³»å¡æã¯ãšãã«ã·ãšã³å¡æããã€ã¹ããŒã·ãš
ã³ïŒæ°Žåæ£åïŒå¡æã氎溶æ§å¡æãã¹ã©ãªãŒïŒæ³¥
挿ç¶ïŒå¡æçã«åé¡ã§ãããæ°Žç³»å¡æã«ã¯äžèšã®
ãããªå©ç¹ãããããåé¢æ¬ ç¹ãå€ãããã®ãã
ä»æ¥æº¶å€åå¡æãé§éããã«è³ã€ãŠããªãããã®
äž»ãªçç±ãšããŠã¯å¡è£ ç°å¢ãç¹ã«æž©åºŠã湿床ã«å·Š
å³ãããããèåãã€ãã«ããããšãå¡è也ç¥æ
ã«ã¯ããã¿ã¬ãããžãçã®å¡èæ¬ é¥ãçãããã
ããšãæ°Žã«å¯Ÿãã芪åæ§ãåäžãããããæš¹èäž
ã«èŠªæ°Žæ§åºã®å°å ¥ãåæ£å€ãçé¢æŽ»æ§å€çã®äœµçš
ã§å¡èã®èä¹ å質ãå£ãããšãªã©ãæããããã
ãã®ããçŸç¶ã§ã®æ°Žç³»å¡æã¯ãããã®æ°Žã«èµ·å ã
ãæ¬ é¥ãé€ãããããªãã®éã®ææ©æº¶åªã䜵çšã
ãŠããã®ãå®æ ã§ããçã®çè³æºãå ¬å®³å¯Ÿçå¡æ
ãšã¯äºãé£ãã ããã«å¯Ÿãã¹ã©ãªãŒç¶å¡æã¯ãã®ãããªæ°Žç³»å¡
æã®æ¬ é¥ãå æããæ°ããå¡æã§ããããã§ã«ç¹
å ¬æ48â52851å·ãç¹å ¬æ55â433å·ãªã©ã«è©³è¿°ã
ããŠããããã®ç¹åŸŽãç°¡åã«åèšãããšãã¹ã©ãª
ãŒç¶å¡æãšã¯æ°ŽãåªäœãšããŠïŒã80ÎŒçšåºŠã®ç²å
ç¶æš¹èãåºååæ¿åºŠãšããŠ10ã70ééïŒ ã®ç¯å²ã§
åæ£ãããå¡æã§ãããåŸã€ãŠæ®çºåãšããŠã¯åª
äœã§ããæ°Žã®ã¿ã§ãããããé«åºååæ¿åºŠã§å¡è£
ãå¯èœã§ãããåå¡ããåºæ¥ããããåŸæ¥ã®æº¶å€
åå¡æã®å¡è£ è£ çœ®ããã®ãŸãŸäœ¿çšã§ãããªã©æ°å€
ãã®å©ç¹ãæããåªããå¡æã§ããã äžè¬ã«ããã®ãããªã¹ã©ãªãŒç¶å¡æã«äœ¿çšãã
ãŠããæš¹èãšããŠã¯ãã¢ã¯ãªã«æš¹èãããªãšã¹ã
ã«æš¹èããšããã·æš¹èãã¢ã«ãããæš¹èãªã©ãç¥
ãããŠããããç¹ã«è²¯èµæã®å®å®æ§ãå¡èã®å¹³æ»
æ§ãä»äžãå€èŠ³ãªã©ããã¢ã¯ãªã«æš¹èããã³ããª
ãšã¹ãã«æš¹èã奜ãŸãããšãããŠãããåããã
ã«é²é£æ§ãªã©ãè£ãããã«ããšããã·æš¹èçã䜵
çšããããããå Žåãããããããããšããã·æš¹
èã䜵çšãããšãèåæ§ãæãªããããããäžå¡
ãå¡æçšæš¹èã®äžæåãšããŠäœ¿çšããã®ã¯å¥œãŸã
ããªãã äžæ¹ãå¡èã®èé£æ§ãåäžãããããã«ãããš
ããŒã«ã«ã«ãã³é žçã®åçš®å¡æã«é åããäŸãå€
ãããããã€ãç¥ãããŠãããäŸãã°R.N.
Faulknerçã«ãã€ãŠãæ€ç©æ²¹ãèèªé žãšã¹ã
ã«ãã¢ã«ããæš¹èãæ€ç©æ²¹å€æ§ãšããã·ãšã¹ãã«
æš¹èããããã¯æ€ç©æ²¹å€æ§ããªã¢ããæš¹èã«ãã«
ãã³ãŒã«ãããã¬ããŒã«ã没é£åé žãããã¯æ²¡é£
åé žãšã¹ãã«ãéå±ã¢ã«ã³ãã·ãã®ãããªè§Šåªã
çšããŠå°å ¥ããã溶å€ç³»â液åå¡æãéçºãããŠ
ãããïŒäŸãã°ãè±åœç¹èš±ç¬¬1045118å·ãç±³åœç¹èš±
第3304276å·ãå第3321320å·ãOil and Colour
Chemistâ²s Associationçºè¡ã®Journal of the Oil
and Colour Chemistâ²s Association第50å·»ã524
é ïŒ1967ïŒçãåç §ã®ããšãïŒãããããããã®
æš¹èã¯ãé«åºŠã®å¡èæ§èœãèŠæ±ãããåéã«ã¯é©
çšã§ããªãã€ãã ãšããã§ãæ¶æ©å€ãšããŠã¡ã©ãã³æš¹èãçšãã
å Žåãåèã«å¡è£ ãããšãçŒä»ãæã«çºæ³¡ïŒã¯
ãïŒãçãããããå¡è£ äœæ¥æ§ã®é¢ã«æ¬ ç¹ããã
åèåããããã«ã¯ãæ°åã«ãããå¡è£ ããå¿ èŠ
ããã€ãã æ¬çºæã¯ãããã®è«žåé¡ã解決ããããšãç®ç
ãšãããã®ã§ãããããªãã¡è²¯èµå®å®æ§ã«åªãã
äœæ¥å·ŸããããããçŒä»ãæã«ã¯ããªã©ã®æ¬ ç¹ã
ãªãããã«å æ²¢ãå¹³æ»æ§ãèè¬åæ§ãç¹ã«èé£æ§
è©ŠéšåŸã®ïŒæ¬¡å¯çæ§ãªã©ã«åªããå¡èæ§èœãæã
ãæ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç©ãæäŸãããã®ã§
ããã æ¬çºæã®äžæ æ§ã®éªšåã¯ãããªãšã¹ãã«æš¹èå
ã³ã¢ã¯ãªã«æš¹èã䜵çšããå©ç¹ã«å ãã該ããªãš
ã¹ãã«æš¹èã«ããšããŒã«ã«ã«ãã³é žãå°å ¥ããã
ãšã«ããåªããæ§èœãä»äžããããšã«ããããŸ
ããæ¬çºæã®å¥ã®æ æ§ã®éªšåã¯ãäžèšã®ç³»ã«å ã
ãŠãããã¯ã€ãœã·ã¢ããŒãååç©ãæ¶æ©å€ãšããŠ
䜵çšããããšã«ããäžèšã®å©ç¹ã«å ããŠã¬ã¿ã³æš¹
èãšããŠã®åªããæ§èœãä»äžããããšã«ãããã
ãªãã¡ãããªãšã¹ãã«æš¹èã®æããèæ°Žæ§ãè湿
æ§ãè沞氎æ§ãªã©ã®æ°Žã«é¢äžããæ§èœåã³ã¢ã¯ãª
ã«æš¹èã®æããåªããå¡èå€èŠ³ïŒå æ²¢ãèææã
è¡šé¢å¹³æ»æ§ïŒãªã©ã«å ããããšããŒã«ã«ã«ãã³é ž
ã®å°å ¥ã«ããããªãšã¹ãã«æš¹èã®æ§èœãšãããå¡©
æ°ŽåŽé§æ§è©ŠéšåŸã®ïŒæ¬¡å¯çæ§ãåäžããããŸããŠ
ã¬ã¿ã³æš¹èã®æããåªããèè¡ææ§ãèè¬åæ§ãª
ã©ãä»äžã§ããã ããã«ããªãšã¹ãã«æš¹èã«ã¢ã¯ãªã«æš¹èåã¯ã¢
ã¯ãªã«æš¹èãšã€ãœã·ã¢ããŒãååç©ãæ¶æ©ããã
ãããšã«ãã硬床ãšå¯ææ§ã®ãã©ã³ã¹ãé©åºŠã«ä¿
ãããå¡èãåŸãããšãå€æããã ãã®ããã«åªããç¹é·ã«å ããæ¬çºæçµæç©ã¯
çŒä»ä¹Ÿç¥æã®å¡èã®ãããŒæ§ãèããåäžãå¡è
å€èŠ³ãæ¹è¯ããå¹æãããã ããã«æ¬çºæçµæç©äžã«å«ãŸããããªãšã¹ãã«
æš¹èã¯æš¹èèªèº«ã®æ¥µæ§ãã¢ã¯ãªã«æš¹èãªã©ã«æ¯ã
é«ãããæ°Žãšã®èŠªåæ§ãããæ°Žäžã§ã®åæ£ç¶æ ã«
æŒãã貯èµå®å®æ§ãå¢é²ããããšããå¹æãã
ãã å³ã¡ãæ¬çºæã¯ã (1) (ã€) å€äŸ¡ããšããŒã«ã«ã«ãã³é žãïŒã15éé
ïŒ åå¿ããããæ°Žé žåºäŸ¡30ã300ã®ããªãšã¹
ãã«æš¹è âŠâŠ20ã90ééïŒ ãããã³ (ã) (i) αïŒÎ²âã¢ããšãã¬ã³æ§äžé£œåã«ã«ã
ã³é žã¢ããã®ïŒ®âã¢ã«ã³ãã·ã¡ãã«ååé
äœãšã (ii) åèš(i)以å€ã®Î±ïŒÎ²âã¢ããšãã¬ã³æ§äž
飜ååéäœã®ïŒçš®ãããã¯ïŒçš®ä»¥äžïŒäœ
ãããªã³é žåºå«æαïŒÎ²âã¢ããšãã¬ã³æ§
äžé£œååéäœãé€ãïŒãšã®åéäœæ··åç©ã
ãåŸãããæ¶æ©æ§å ±éåæš¹è
âŠâŠ80ã10ééïŒ ããæã埮ç²ç¶ã®ç±ç¡¬åæ§æš¹èç²åã該ç²å
ã«å¯ŸããŠ0.01ã5.0ééïŒ ã®çé¢æŽ»æ§å€å
ã³ïŒåã¯å¢ç²å€ãåã³å¿ èŠéã®æ°Žããæãæ°Ž
åæ£åç±ç¡¬åæ§è¢«èŠçµæç©ããªãã³ã« (2) (ã€) å€äŸ¡ããšããŒã«ã«ã«ãã³é žãïŒã15éé
ïŒ åå¿ããããæ°Žé žåºäŸ¡30ã300ã®ããªãšã¹
ãã«æš¹è âŠâŠ20ã90ééïŒ (ã) (a) (i) αïŒÎ²âã¢ããšãã¬ã³æ§äžé£œåã«
ã«ãã³é žã¢ããã®ïŒ®âã¢ã«ã³ãã·ã¡ãã«
ååéäœãšã (ii) åèš(i)以å€ã®Î±ïŒÎ²âã¢ããšãã¬ã³æ§
äžé£œååéäœã®ïŒçš®ãããã¯ïŒçš®ä»¥äž
ïŒäœãããªã³é žåºå«æαïŒÎ²âã¢ããšã
ã¬ã³æ§äžé£œååéäœãé€ãïŒ ãšã®åéäœæ··åç©ããåŸãããæ¶æ©æ§å ±éå
æš¹èãåã³ (b) ãããã¯ã€ãœã·ã¢ããŒãååç©ããæã
æ¶æ©å€æ··åç© âŠâŠ80ã10ééïŒ ããæã埮ç²ç¶ã®ç±ç¡¬åæ§æš¹èç²åã該ç²å
ã«å¯ŸããŠ0.01ã5.0ééïŒ ã®çé¢æŽ»æ§å€å
ã³ïŒåã¯å¢ç²å€ãåã³å¿ èŠéã®æ°Žããæãæ°Ž
åæ£åç±ç¡¬åæ§è¢«èŠçµæç©ã«é¢ããã æ¬çºæçµæç©ã«äœ¿çšããåèšããªãšã¹ãã«æš¹è
ã¯å€äŸ¡ããšããŒã«ã«ã«ãã³é žããã³å€äŸ¡ã«ã«ãã³
é žãããã«å¿ èŠã«å¿ããŠåèšå€äŸ¡ããšããŒã«ã«ã«
ãã³é žä»¥å€ã®äžäŸ¡ã®ã«ã«ãã³é žãšãå€äŸ¡ã¢ã«ã³ãŒ
ã«ãšããšã¹ãã«ååå¿ããããšã«ãã€ãŠåŸããã
ãã®ã§ããã該暹èã®ééå¹³åååéã¯2000ã
100000ã奜ãŸããã¯3000ã60000ã§ãããååé
ããã®ç¯å²ã«æºããªãå Žåã«ã¯ãã¹ã©ãªãŒå段é
ã§ç²åãå®å®ã«æ°Žäžã«åæ£ãããããšãå°é£ã§ã
ãã°ããã§ãªãå¡èæ§èœãç¹ã«æ©æ¢°çæ§èœãååŠ
çæ§èœãäœäžããã®ã§å¥œãŸãããªãããŸãååé
ããã®ç¯å²ãè¶ããå Žåã«ã¯äœµçšããã¢ã¯ãªã«æš¹
èããããã¯ã€ãœã·ã¢ããŒãååç©ãšã®çžæº¶æ§ã«
æ¬ ããããã«ãªãã°ããã§ãªããå¡èã®å¡è£ å€èŠ³
ãªã©ã«æ¯éãæ¥ããæãããããããªãšã¹ãã«æš¹
èã®æ°Žé žåºäŸ¡ã¯30ã300ãè©Šæ1gäžã«ååšããæ°Ž
é žåºã«å¯Ÿå¿ããã«ã«ããã·ã«åºãäžåããã«èŠã
ãæ°Žé žåã«ãªãŠã ã®ããªã°ã©ã æ°ïŒïŒæš¹èåºåå
å€ïŒä»¥äžåæ§ãã§ããã40ã200ã®ç¯å²ã奜ãŸã
ããæ°Žé žåºäŸ¡ããã®ç¯å²ã«æºããªãå Žåã«ã¯æ¶æ©
å¯åºŠãäœããŠæ¬æ¥ã®å¡èæ§èœãçºæ®ãåŸããç¹ã«
èæ°Žæ§ãè溶å€æ§ãèåæ§ãªã©ã®ïŒæ¬¡æ§èœãæªå
ããããŸããã®ç¯å²ãè¶ããå Žåã«ã¯ããªãšã¹ã
ã«æš¹èã«å¯Ÿããã¢ã¯ãªã«æš¹èããããã¯ã€ãœã·ã¢
ããŒãååç©ã®ç¡¬åæåã®æ¯çãå¢å€§ãããªãšã¹
ãã«æš¹èæ¬æ¥ã®æãŸããæ§èœãçºæ®åºæ¥ãªãã°ã
ãã§ãªããå¡èã®å¯ææ§ãå¯çæ§ãæãªãã æ¬çºæã®ããªãšã¹ãã«æš¹èã®åæã«éããã«ã«
ãã³é žæåãšããŠå€äŸ¡ããšããŒã«ã«ã«ãã³é žã䜿
çšããããšãå¿ é ã§ããã 該æåã¯ãããªãšã¹ãã«æš¹èæåäžïŒã15éé
ïŒ ã奜ãŸããã¯ïŒã10ééïŒ ã®å²åã§åå¿ããã
ããåèšç¯å²ã«æŒãŠã該æåãïŒééïŒ ã«æºããª
ãå Žåã«ã¯ãããªãšã¹ãã«æš¹èãåæããåŸãæ¶
æ©æ§å ±éåæš¹èãŸãã¯ãæ¶æ©æ§å ±éåæš¹èåã³ã
ããã¯ã€ãœã·ã¢ããŒãååç©ãçšããŠåœ¢æããå¡
èã®èé£æ§è©ŠéšåŸã®ïŒæ¬¡å¯çæ§ã®åäžå¹æãããŸ
ãåŸãããªããäžæ¹ãåèšæåã15ééïŒ ãè¶ã
ãŠäœ¿çšããããšãåŸããã硬åå¡èãèããªãã
ãŸãèåæ§ã®äœäžãèªããããããŸãã15ééïŒ
以å ã§å®è³ªçã«ååãªå¹æãåŸãããã®ã§ã15é
éïŒ ãèããè¶ããŠäœ¿çšããããšã¯çµæžçã«ã奜
ãŸãããªãã åèšå€äŸ¡ããšããŒã«ã«ã«ãã³é žãšããŠã¯ïŒïŒïŒ
âãžãªãã·å®æ¯éŠé žãïŒïŒïŒâãžãªãã·å®æ¯éŠ
é žãïŒïŒïŒâãžãªãã·å®æ¯éŠé žãïŒïŒïŒâãžãªã
ã·å®æ¯éŠé žãïŒïŒïŒâãžãªãã·å®æ¯éŠé žïŒããã
ã«ãããŠé žïŒãïŒïŒïŒâãžãªãã·å®æ¯éŠé žãïŒïŒ
ïŒïŒïŒâããªãªãã·å®æ¯éŠé žïŒæ²¡é£åé žïŒãïŒïŒ
ïŒïŒïŒâããªãªãã·å®æ¯éŠé žçãæãããããã
ããã¯ïŒçš®ãããã¯ïŒçš®ä»¥äžã®æ··åç©ãçšããŠã
ããã ãŸãå€äŸ¡ããšããŒã«ã«ã«ãã³é žä»¥å€ã®å€äŸ¡ã«ã«
ãã³é žããã³äžäŸ¡ã®ã«ã«ãã³é žãšããŠã¯ç¡æ°Žãã¿
ã«é žãã€ãœãã¿ã«é žããã¬ãã¿ã«é žããšã³ãã¡ã
ã¬ã³ããã©ãããç¡æ°Žãã¿ã«é žãããã©ãããç¡
æ°Žãã¿ã«é žãã¡ãã«ããã©ãããç¡æ°Žãã¿ã«é žã
ã¡ãã«ãããµãããç¡æ°Žãã¿ã«é žããããµããã
ç¡æ°Žãã¿ã«é žãç¡æ°Žããªã¡ããé žãã³ãã¯é žãã¢
ãžãã³é žãã¢ãŒã©ã€ã³é žãã»ããã³é žãã¯ãšã³
é žãé ç³é žããªã³ãŽé žãïŒïŒïŒâããã¿ãªã«é žç
ãå©çšåºæ¥ãããŸãåå¿èª¿æŽå€ãšããŠå®æ¯éŠé žã
ïœâïœããã«å®æ¯éŠé žãªã©ãå©çšããå Žåãã
ãããããã¯ïŒçš®ãããã¯ïŒçš®ä»¥äžã®æ··åç©ãçš
ããŠãããã 次ã«ãããªãšã¹ãã«æš¹èã®åæã«äœ¿çšããå€äŸ¡
ã¢ã«ã³ãŒã«ãšããŠã¯ãšãã¬ã³ã°ãªã³ãŒã«ããžãšã
ã«ã³ã°ãªã³ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ããã
ãã¬ã³ã°ãªã³ãŒã«ããžãããã¬ã³ã°ãªã³ãŒã«ãã
ãã¬ã³ã°ãªã³ãŒã«ãïŒïŒïŒâãã³ã¿ã³ãžãªãŒã«ã
ããªãã³ãã«ã°ãªã³ãŒã«ãïŒïŒïŒâãããµã³ãžãª
ãŒã«ãæ°ŽçŽ åãã¹ããšããŒã«ïŒ¡ãïŒïŒïŒâã·ã¯ã
ãããµã³ãžã¡ã¿ããŒã«ããã³ã¿ãšãªã¹ãªããŒã«ã
ã°ãªã»ãªã³ãããªã¡ãããŒã«ãããã³ãããªã¡ã
ããŒã«ãšã¿ã³çã®ä»ããªãããã¬ã³ã°ãªã³ãŒã«ã
ããªãšãã¬ã³ã°ãªã³ãŒã«çã®é«çŽã¢ã«ã³ãŒã«çã
å©çšã§ããããããã¯ãïŒçš®ãããã¯ïŒçš®ä»¥äžã®
æ··åç©ãšããŠäœ¿çšããããåãå¿ èŠã«å¿ããŠã«ãŒ
ãžãŠã©ãŒïŒ¥ïŒã·ãšã«ã»ã±ãã«ã«ç€Ÿè£œãåååïŒã
䜵çšãããã ãããã®æ§æåæã®çµåãã«ããå¡èã®æ§èœã
ããªãéæã«åœ±é¿ãåããã®ã§ç®æšãšããæ§èœã«
åèŽããåæã®æ§æãèæ ®ããå¿ èŠããããäŸã
ã°ãå¡èã®èæ°Žæ§ãèè¬åæ§ãªã©ãå¿ èŠãšããå Ž
åã¯ã€ãœãã¿ã«é žãããªãã³ãã«ã°ãªã³ãŒã«ç
ããå¡èã®èè¡ææ§ãèã¯ã©ãã¯æ§ãå¿ èŠãšãã
å Žåã¯ã¢ãžãã³é žãã»ããã³é žããžãããã¬ã³ã°
ãªã³ãŒã«çããä»ã®æš¹èãšã®çžæº¶æ§ãé«ãããã
ã«ã¯ç¡æ°Žãã¿ã«é žããããã¬ã³ã°ãªã³ãŒã«çãçš
ããããšãªã©ã¯ãã§ã«åšç¥ã§ãããããã«ãå¡è
ã«ç¹æ®ãªæ§èœäŸãã°é²çæ§ãä»äžããããããã©
ã¯ããç¡æ°Žãã¿ã«é žãåæãšããŠçšããããšãªã©
ãåºæ¥ãã ããªãšã¹ãã«æš¹èã®è£œæ³ã¯éåžžã®çž®ååå¿ã§ã
ã溶èæ³ãŸãã¯ãã·ããŒã«çã®å ±æ²žæº¶åªã䜿çšã
ãå ±æ²žæ³ãããã泚æãã¹ãããšã¯å¯çããçž®å
æ°Žãåºæ¥ãã ãæ©ãç³»å€ã«é€å»ããããšãšå ±æ²žã
ãŠåºãŠããã°ãªã³ãŒã«ãé«èœçã§ååããããå®
å šãšã¹ãã«åè£ çœ®ã®å®¹éã倧ããããããšããã
ã«ããªãšã¹ãã«ã®çè²ããããããäžæŽ»æ§ã¬ã¹ã
å°å ¥ããããšãªã©ã§ããããŸãããªãšã¹ãã«æš¹è
ã®é žäŸ¡ã¯50ïŒæš¹èïŒã°ã©ã ãäžåããã«å¿ èŠãªæ°Ž
é žåã«ãªãŠã ã®ããªã°ã©ã æ°ïŒæš¹èåºååïŒä»¥äž
ãšããããšãæãŸããã 次ã«æ¬çºæã«æŒããæ¶æ©æ§å ±éåæš¹èãæ§æã
ãαïŒÎ²âã¢ããšãã¬ã³æ§äžé£œååéäœæ··åç©ãš
ããŠã¯ãαïŒÎ²âã¢ããšãã¬ã³æ§äžé£œåã«ã«ãã³
é žã¢ããã®ïŒ®âã¢ã«ã³ãã·ã¡ãã«ååéäœãå¿ é
æåãšããŠäœ¿çšãããã該æåã¯ãããªãšã¹ãã«
æš¹èãšã®æ¶æ©åå¿ã«å¿ èŠã§ããã該æåã¯æ¶æ©æ§
å ±éåæš¹èäžïŒã30ééïŒ ã奜ãŸããã¯10ã25é
éïŒ ã®å²åã§åå¿ããããããšã奜ãŸããã該æ
åãïŒééïŒ ã«æºããªãå Žåã«ã¯ãããªãšã¹ãã«
æš¹èãšã®æ¶æ©åå¿ãäžååãšãªããå¡èã®è溶å€
æ§ãäœäžããããŸã30ééïŒ ãè¶ãããšæ¶æ©æ§å ±
éåæš¹èã®è£œé æã«ã²ã«åã䌎ããã奜ãŸãããª
ãã該æåã®å ·äœäŸãšããŠã¯ãâã¡ããã·ã¡ã
ã«ïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ãããâãšããã·ã¡ãã«
ïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ãããâïœâããããã·ã¡
ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ãããâã€ãœãããã
ã·ã¡ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ãããâïœâãã
ãã·ã¡ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ãããâsecâ
ãããã·ã¡ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ãããâïœ
âãããã·ã¡ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ãããâ
ã€ãœãããã·ã¡ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ãããç
ã®Î±ïŒÎ²âã¢ããšãã¬ã³æ§äžé£œåã«ã«ãã³é žã¢ã
ãã®ïŒ®âã¢ã«ã³ãã·ã¡ãã«åç©ïŒãããã¯ããã
ã®ïŒ®âã¡ãããŒã«åç©ãªã©ãæãããããããã¯
ïŒçš®ãããã¯ïŒçš®ä»¥äžã®æ··åç©ãšããŠçšããŠãã
ããæ¬çºæã«ãããŠã¯æ¶æ©æ§å ±éåæš¹èã®äžæå
ãšããŠÎ±ïŒÎ²âã¢ããšãã¬ã³æ§äžé£œåã«ã«ãã³é ž
ã0.5ã10ééïŒ ã®ç¯å²ã§äœ¿çšããŠãããã該å
éäœã¯æ¶æ©æ§å ±éåæš¹èãšããªãšã¹ãã«æš¹èãšã®
çžæº¶æ§ãåäžããããšãšãã«æ¶æ©åå¿ãä¿é²ãã
ãšããå¹æãæãããåèšç¯å²ã«ãããŠ0.5éé
ïŒ ã«æºããªãå Žåã¯ãã®å¹æã匱ããªããå10é
éïŒ ãè¶ãããšç¡¬åå¡èã®æ§èœãäœäžããããã
ã«ãªãã®ã§å¥œãŸãããªãã 該æåã®å ·äœäŸãšããŠã¯ãã¢ã¯ãªã«é žãã¡ã¿ã¯
ãªã«é žãã¯ããã³é žãã€ã¿ã³ã³é žããã¬ã€ã³é žã
ããã«é žçãæãããããããã¯ïŒçš®ãããã¯ã
ïŒçš®ä»¥äžã®æ··åç©ãšããŠçšããŠãããã æ¬çºæã«äœ¿çšãããæ¶æ©æ§å ±éåæš¹èã®åæãš
ããŠåèšä»¥å€ã®å ±éåæ§Î±ïŒÎ²âã¢ããšãã¬ã³æ§
äžé£œååéäœïŒäœãããªã³é žåºå«æαïŒÎ²âã¢ã
ãšãã¬ã³æ§äžé£œååéäœãé€ãïŒ60ã90ééïŒ ã®
å²åã§åå¿ããããããšã奜ãŸããã該æåã®å ·
äœäŸãšããŠã¯ãã¡ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒãããš
ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïœâãããã«ïŒã¡
ã¿ïŒã¢ã¯ãªã¬ãŒããã€ãœãããã«ïŒã¡ã¿ïŒã¢ã¯ãª
ã¬ãŒããïœâããã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããsec
âããã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïœâããã«ïŒã¡
ã¿ïŒã¢ã¯ãªã¬ãŒããã€ãœããã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬
ãŒããïœâããã·ã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïŒâ
ãšãã«ããã·ã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïœâãªã¯
ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã©ãŠãªã«ïŒã¡ã¿ïŒã¢
ã¯ãªã¬ãŒããããªãã·ã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒãã
ã¹ãã¢ãªã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒãçã®ã¢ã¯ãªã«é ž
åã¯ã¡ã¿ã¯ãªã«é žã®ã¢ã«ãã«ãšã¹ãã«é¡ïŒïŒâã
ãããã·ãšãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïŒâãã
ããã·ãããã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïŒâãã
ããã·ãããã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïŒâãã
ããã·ããã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïŒâããã
ãã·ããã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïŒâãããã
ã·ããã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïŒâããããã·
ãã³ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïŒâããããã·
ããã·ã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããããªãã³ãã«ã°
ãªã³ãŒã«ã¢ãïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïŒâããã
ã·âïŒâããããã·ãããã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒ
ããïŒâããããã·âïŒâããšãã«ãšãã«ïŒã¡
ã¿ïŒã¢ã¯ãªã¬ãŒããããªãããã¬ã³ã°ãªã³ãŒã«ã¢
ãïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã°ãªã»ãªã³ã¢ãïŒã¡
ã¿ïŒã¢ã¯ãªã¬ãŒãçã®Î±ïŒÎ²âã¢ããšãã¬ã³æ§äž
飜åã«ã«ãã³é žã®ããããã·ã¢ã«ãã«ãšã¹ãã«
é¡ïŒãã®ä»ïŒ®ïŒNâ²âãžã¡ãã«ã¢ãããšãã«ïŒã¡
ã¿ïŒã¢ã¯ãªã¬ãŒããã°ãªã·ãžã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬
ãŒããã·ã¯ãããã·ã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã
ãšãã«ã¡ã¿ã¢ã¯ãªã¬ãŒãããã³ãžã«ã¡ã¿ã¯ãªã¬ãŒ
ããããã«é žãžâããã«ãªã©ã®ããã«é žãžâã¢ã«
ãã«ãšã¹ãã«é¡ãã¹ãã¬ã³ãããã«ãã«ãšã³ãα
âã¡ãã«ã¹ãã¬ã³ãïŒã¡ã¿ïŒã¢ã¯ãªããããªã«ã
ããã«ã¢ã»ããŒãçã®åéäœãæãããããäžèš
åéäœã¯å¡æçµæç©ã®äœ¿çšç®çãçšå¡ã«å¿ããŠïŒ
çš®åã¯ïŒçš®ä»¥äžé©å®çµåããŠäœ¿çšããŠãå·®æ¯ããª
ãã æ¬çºæã®æ¶æ©æ§å ±éåæš¹èã¯éåžžã®æº¶æ¶²éåã«
ãã補é ãããã該溶液éåæ³ã«çšããããéå
溶åªãšããŠã¯æ°Žå¯æº¶æ§ãŸãã¯æ°Žæ··åæ§æº¶åªãçšã
ããããäŸãã°ã¡ãã«ã¢ã«ã³ãŒã«ããšãã«ã¢ã«ã³
ãŒã«ãã€ãœãããã«ã¢ã«ã³ãŒã«ãïœâãããã«ã¢
ã«ã³ãŒã«çã®ã¢ã«ã³ãŒã«é¡ïŒãšãã¬ã³ã°ãªã³ãŒã«
ã¢ãã¡ãã«ãšãŒãã«ããšãã¬ã³ã°ãªã³ãŒã«ã¢ããš
ãã«ãšãŒãã«ããšãã¬ã³ã°ãªã³ãŒã«ã¢ãããã«ãš
ãŒãã«ããšãã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«
ã¢ã»ããŒãçã®ãšãã¬ã³ã°ãªã³ãŒã«èªå°äœïŒãžãš
ãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«ããžãšãã¬
ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«ããžãšãã¬ã³ã°
ãªã³ãŒã«ã¢ãããã«ãšãŒãã«çã®ãžãšãã¬ã³ã°ãª
ã³ãŒã«èªå°äœïŒé ¢é žã¡ãã«ãé ¢é žãšãã«ãé ¢é žã
ãã«çã®ãšã¹ãã«é¡ïŒã¡ãã«ãšãã«ã±ãã³ãã¡ã
ã«ã€ãœããã«ã±ãã³çã®ã±ãã³é¡çã䜿çšãã
ãããããã®éå溶åªã¯ïŒçš®åã¯ïŒçš®ä»¥äžãé©å®
çµåããŠäœ¿çšããŠããããç¹ã«æ°Žã«å¯Ÿãã溶解床
ã20âã§10ã30ééïŒ çšåºŠã®ãã®ã奜ãŸããã ãŸãã䜿çšãããéåéå§å€ãšããŠã¯ãäŸãã°
ãã³ãŸã€ã«ããŒãªããµã€ããïœâããã«ããŒãã³
ãŸãšãŒããïœâããã«ãããããŒãªããµã€ããã¯
ã¡ã³ãããããŒãªããµã€ãããžâïœâããã«ããŒ
ãªããµã€ããïœâããã«ããŒãªã¯ããšãŒãçã®æ
æ©éé žåç©ãããã¯ã¢ãŸãã¹ã€ãœããããããª
ã«ãã¢ãŸãžã€ãœé ªé žãããªã«ãªã©ã®ã¢ãŸååç©ã
æããããããããã®éåéå§å€ã®ïŒçš®åã¯ïŒçš®
以äžãé©å®æ··åããŠäœ¿çšããŠããããå¿ èŠãªã
ã°ãååéã調æŽããããã«é£é移åå€ãäŸãã°
ããã·ã«ã¡ã«ã«ãã¿ã³ãããªã°ãªã³ãŒã«é žâïŒâ
ãšãã«ããã·ã«ãåå¡©åççŽ çã䜿çšããŠãã
ãã該æ¶æ©æ§å ±éåæš¹è補é æã®éå枩床ã¯çŽ50
ã150âãåå¿æéã¯çŽïŒã12æéã§ããããã®
é䜿çšãããéå溶åªã¯ãåèšæš¹è補é æã®äžæ®
çºåã10ã80ééïŒ ã奜ãŸããã¯35ã75ééïŒ ã«
ãªããããªç¯å²ã§äœ¿çšããã åãéåéå§å€ã®äœ¿çšéã¯ãæ¶æ©æ§å ±éåæš¹è
補é æã®äžæ®çºåã«å¯ŸããŠçŽ0.1ã15ééïŒ ã®ç¯
å²ã§ãããé£é移åå€ã¯åæã«çŽïŒãïŒééïŒ ã®
ç¯å²ã§çšããããšã奜ãŸããã æ¬çºæã®æ¶æ©æ§å ±éåæš¹èã®ééå¹³åååéã¯
10000ã100000奜ãŸããã¯20000ã80000ã®ç¯å²å
ã«ããããšã奜ãŸãããééå¹³åååéã10000
ã«æºããªãå Žåã¯ãå¡èæ§èœãååã§ãªããäžæ¹
ééå¹³åååéã100000ãè¶ããå Žåã¯ãå¹³æ»æ§
ãæãªãããããã«ãªãã 次ã«æ¬çºæã«äœ¿çšãããæ¶æ©å€æ··åç©ã®ïŒã€ã§
ãããããã¯ã€ãœã·ã¢ããŒãååç©ãšã¯ãïŒåå
äžã«ã€ãœã·ã¢ããŒãåºãïŒå以äžæããã€ãœã·ã¢
ããŒãååç©ã§ããããã®ã€ãœã·ã¢ããŒãåºã®å š
ãŠããããã¯å€ã§ãã¹ã¯ããããããã¯ã€ãœã·ã¢
ããŒãååç©ã§ããã 該ãããã¯ã€ãœã·ã¢ããŒãååç©ã¯ãããªãšã¹
ãã«æš¹èãšã®æ¶æ©åå¿ã«é¢äžãããŠã¬ã¿ã³æš¹èã®
ãã€èè¬åæ§ã®åªããŠããç¹ãä»äžããããšã«ç¹
城ãããã 該ãããã¯ã€ãœã·ã¢ããŒãååç©ã¯ãïŒååäž
ã«ïŒå以äžã®ã€ãœã·ã¢ããŒãåºãæããããªã€ãœ
ã·ã¢ããŒãååç©ãäŸãã°ããšãã¬ã³ãžã€ãœã·ã¢
ããŒãããããã¬ã³ãžã€ãœã·ã¢ããŒããããã©ã¡
ãã¬ã³ãžã€ãœã·ã¢ããŒãããããµã¡ãã¬ã³ãžã€ãœ
ã·ã¢ããŒãããã«ã¡ãã¬ã³ãžã€ãœã·ã¢ããŒããïœ
âããšãã¬ã³ãžã€ãœã·ã¢ããŒããïœâããšãã¬ã³
âãžã€ãœã·ã¢ããŒããïŒïŒïŒâããªã¬ã³âãžã€ãœ
ã·ã¢ããŒããïŒïŒïŒâããªã¬ã³âãžã€ãœã·ã¢ããŒ
ããïŒïŒïŒâãããã¬ã³âãžã€ãœã·ã¢ããŒãã
ïŒïŒ4â²ïŒ4â³âããªããšãã«ã¡ã¿ã³ããªã€ãœã·ã¢ã
ãŒããïŒïŒ4â²âãžããšãã«ã¡ã¿ã³âãžã€ãœã·ã¢ã
ãŒããïŒïŒ3â²âãžã¡ãã«âïŒïŒ4â²âãžããšãã¬ã³
âãžã€ãœã·ã¢ããŒããïœâãã·ãªã¬ã³âãžã€ãœã·
ã¢ããŒããïœâãã·ãªã¬ã³âãžã€ãœã·ã¢ããŒãã
ã€ãœããã³ãžã€ãœã·ã¢ããŒãããªãžã³ã€ãœã·ã¢ã
ãŒãçã®ããªã€ãœã·ã¢ããŒãåã³åèšã€ãœã·ã¢ã
ãŒãååç©ã®éå°ãšãããšãã°ãšãã¬ã³ã°ãªã³ãŒ
ã«ããããã¬ã³ã°ãªã³ãŒã«ãïŒïŒïŒâããã¬ã³ã°
ãªã³ãŒã«ãããªãã³ãã«ã°ãªã³ãŒã«ãïŒïŒïŒïŒïŒ
âããªã¡ãã«ïŒïŒïŒâãã³ã¿ã³ãžãªãŒã«ããããµ
ã¡ãã¬ã³ã°ãªã³ãŒã«ãã·ã¯ããããµã³ãžã¡ã¿ããŒ
ã«ãããªã¡ãããŒã«ãããã³ããããµã³ããªãªãŒ
ã«ãã°ãªã»ãªã³ããã³ã¿ãšãªã¹ãªããŒã«çã®äœå
åããªãªãŒã«ãšã®ä»å åå¿ã«ãã€ãŠåŸãããïŒå®
èœä»¥äžã®ããªã€ãœã·ã¢ããŒããããŠãŒã¬ããæ§é
ãæããããªã€ãœã·ã¢ããŒããã¢ããã¢ããŒãçµ
åãæããããªã€ãœã·ã¢ããŒãçããããã¯å€ã§
ãããã¯ããã€ãœã·ã¢ããŒãååç©ã§ããã 該ãããã¯å€ãšããŠã¯ãããšããŒã«ãã¯ã¬ãŸãŒ
ã«çã®ããšããŒã«ç³»ãã¡ã¿ããŒã«ããã³ãžã«ã¢ã«
ã³ãŒã«ããšãã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«
çã®ã¢ã«ã³ãŒã«ç³»ãã¢ã»ãé ¢é žã¡ãã«ãããã³é ž
ãžã¡ãã«çã®æŽ»æ§ã¡ãã¬ã³ç³»ãã¢ã»ãã¢ããªãã
é ¢é žã¢ããçã®é žã¢ããç³»ããã®ä»ã€ããç³»ãã¢
ãã³ç³»ãã€ãããŸãŒã«ç³»ãå°¿çŽ ç³»ãã«ã«ããã³é ž
å¡©ç³»ãã€ãã³ç³»ããªãã·ã ç³»ãã¡ã«ã«ãã¿ã³ç³»ã
äºç¡«é žå¡©ç³»ãã©ã¯ã¿ã ç³»çãããã æ¬çºæã®æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç©ã«æŒãŠ
ã¯ãåèšãããã¯ã€ãœã·ã¢ããŒãååç©äžã®ãã
ãã¯å€ã解é¢ãããšå¹æçãªæ¶æ©ãè¡ãªãããã®
ã§ãããã¯å€ã®è§£é¢æž©åºŠã¯100â以äžã®ãã®ã奜
ãŸããã æ¬çºæã®äžæ æ§ã«æŒãŠãå€äŸ¡ããšããŒã«ã«ã«ã
ã³é žãåå¿ãããããªãšã¹ãã«æš¹èãšæ¶æ©æ§å ±é
åæš¹èãšã®äœ¿çšéã¯ééæ¯ã§20ïŒ80ã90ïŒ10ïŒé
éïŒ ïŒã§ããã該ç¯å²ã«æŒãŠãæ¶æ©æ§å ±éåæš¹è
ã10ééïŒ ããå°ãªããªãã°å¡èã®æ¶æ©æ§ãäžè¶³
ãå¡èã®è溶å€æ§ãèè¬åæ§çãäœäžããåŸåãš
ãªããäžæ¹è©²æ¶æ©æ§å ±éåæš¹èã80ééïŒ ããå€
ããªãã°ãæ¬çºæã®ç¹åŸŽã§ããããªãšã¹ãã«æš¹è
ã®èé£æ§è©ŠéšåŸã®ïŒæ¬¡å¯çæ§åäžå¹æãä¹ãããª
ãããŸãããªãšã¹ãã«æš¹èéãå°ãªããªãããªãš
ã¹ãã«æš¹èã®ãã€å¯ææ§ãé¡æåæ£æ§ãªã©ãæãª
ãããã ãŸããæ¬çºæã®å¥ã®æ æ§ã«æŒãŠãå€äŸ¡ããšããŒ
ã«ã«ã«ãã³é žãåå¿ãããããªãšã¹ãã«æš¹èãšã
æ¶æ©æ§å ±éåæš¹èåã³ãããã¯ã€ãœã·ã¢ããŒãå
åç©ãããªãæ¶æ©å€æ··åç©ãšã®äœ¿çšéã¯ãééæ¯
ã§20ïŒ80ã90ïŒ10ïŒééïŒ ïŒã§ããã該ç¯å²ã«ã
ããŠæ¶æ©å€æ··åç©ã80ééïŒ ããå€ããªãã°åèš
æ¶æ©æ§å ±éåæš¹èãå€ããªã€ãå Žåãšåæ§ã®åŒå®³
ãçããã æ¬çºæã«æŒãŠæ¶æ©å€æ··åç©ã䜿çšããå Žåãæ¶
æ©åå¿ã¯ããªãšã¹ãã«æš¹èã®æ°Žé žåºãšãæ¶æ©å€æ··
åç©äžã®æ¶æ©æ§å ±éåæš¹èã®ïŒ®âã¢ã«ã³ãã·ã¡ã
ã«åºåã³ãããã¯ã€ãœã·ã¢ããŒãååç©äžã®ã€ãœ
ã·ã¢ããŒãåºã«ããè¡ãããã æ¶æ©å€æ··åç©äžã®æ¶æ©æ§å ±éåæš¹èãšãããã¯
ã€ãœã·ã¢ããŒãååç©ã®äœ¿çšå²åã¯äžèšã®ããã«
è¡ãã®ã奜ãŸããã ãæ¶æ©å€æ··åç©äœ¿çšéïŒéééšïŒãâãæ°Žé žåº
ã«å¯Ÿããã€ãœã·ã¢ããŒãåºã®åœéæ¯ã0.1ã1.2ã§
ãããããªãããã¯ã€ãœã·ã¢ããŒãååç©ã®äœ¿çš
éïŒéééšïŒãïŒãæ¶æ©æ§å ±éåæš¹è䜿çšéïŒéé
éšïŒãã§ãããããããããããã¯ã€ãœã·ã¢ããŒ
ãååç©ïŒæ¶æ©æ§å ±éåæš¹èïŒ0.1ïŒ99.9ã94ïŒ
ïŒïŒåºåœ¢åééæ¯ïŒã§è¡ãã®ã奜ãŸããã ãããã¯ã€ãœã·ã¢ããŒãååç©ã®äœ¿çšéãèã
ã倧ãããªãã°ãããªãšã¹ãã«æš¹èãšæ¶æ©æ§å ±é
åæš¹èãšã®åå¿ãä¹ãããªããæ¶æ©æ§å ±éåæš¹è
ã®ç¹åŸŽã§ããå¡èã®èé£æ§ãèæ°Žæ§çã®åäžå¹æ
ãä¹ãããªãã ãªãæ¬çºæã«äœ¿çšãããããªãšã¹ãã«æš¹èãšæ¶
æ©æ§å ±éåæš¹èãŸãã¯ããªãšã¹ãã«æš¹èãšæ¶æ©æ§
å ±éåæš¹èåã³ãããã¯ã€ãœã·ã¢ããŒãååç©ã
ããªãæ¶æ©å€æ··åç©ããåŸããã埮ç²ç¶ã®æš¹èç²
åã®è»å枩床ã¯ã30ã100âã®ãã®ã奜ãŸããã
æŽã«å¥œãŸããã¯40ã80âã§ãããè»å枩床ã30â
ããäœããªãã°å¡æã®è²¯èµå®å®æ§ãäœäžããåŸå
ã«ãªãããŸã100âããé«ããªãã°å¡èã®å¹³æ»æ§
çãäžè¶³ãããã奜ãŸãããªããå°æ¬çºæã«ãã
ãŠã¯å¿ èŠã«å¿ããŠããªãšã¹ãã«æš¹èãšãæ¶æ©æ§å ±
éåæš¹èåã¯æ¶æ©å€æ··åç©ãšã®æ¶æ©åå¿ãä¿é²ã
ãããã®å ¬ç¥ã®é žè§Šåªãããã«ãšããã·æš¹èãã»
ã«ããŒã¹ç³»æš¹èãã¢ããæš¹èãªã©ã®ïŒçš®ãããã¯
ïŒçš®ä»¥äžã®ä»ã®å¡è圢ææš¹èã®äœµçšãå¯èœã§ã
ãã 次ã«ãæ¬çºæã®æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç©ã®
補é æ¹æ³ã«ã€ããŠèª¬æããã該補é æ¹æ³ãšããŠåŸ
æ¥ã®ç²äœå¡æåã³ã¹ã©ãªãŒç¶å¡æã®è£œé ãªã©ã«çš
ããããŠããéåžžã®æ©æ¢°ç²ç æ³ãé©çšåºæ¥ããã
è»åç¹ãäœãå Žåã¯ãæš¹èç²åã®ç²çæ§ã倧ãã
ãç²æ«åããããšãå°é£ãšãªããåŸã€ãŠæ¬çºæã®
æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç©ã以äžã«è¿°ã¹ãåŠã
ç¹å¥ãªæ¹æ³ã«ãã€ãŠæå©ã«è£œé ããããšãåºæ¥
ãã å ããæå®éã®åèšããªãšã¹ãã«æš¹èãšãæ¶æ©
æ§å ±éåæš¹èåã¯æ¶æ©å€æ··åç©ãšãå¿ èŠã«å¿ã硬
å觊åªãä»ã®å¡è圢ææš¹èçãåèšæ°Žå¯æº¶æ§æº¶å€
åã¯æ°Žæ··åæ§æº¶å€ã«æº¶è§£ããŠæš¹è溶液ãšãããã
ã«å¿ èŠãªãã°é¡æãå ããç·Žååæ£ããŠé¡æåæ£
液ãšããã ãã®é䜿çšããã溶å€ã¯åèšæº¶æ¶²éåæ³ã«çšã
ãããéå溶åªãšåããã®ãçšãããããåãã®
䜿çšéã¯ãåèšæš¹è溶液ãããã¯é¡æåæ£æ¶²ã®äž
æ®çºåã30ã80ééïŒ ã®ç¯å²ã«ãªããããªéã§ã
ãã ã€ãã§ããã®æš¹è溶液ãŸãã¯é¡æåæ£æ¶²ããã
ã®äžã«å«ãŸããæ°Žå¯æº¶æ§æº¶å€åã¯æ°Žæ··åæ§æº¶å€ã®
ãã¹ãŠã溶解ããéã®æ°Žäžã«åŸ®ç²ç¶ã«ä¹³åããã
ãã®é䜿çšãããæ°Žã®éã¯ãåèšæš¹è溶液ããã
ã¯é¡æåæ£æ¶²ã®å°ããšãïŒåéïŒééïŒã§ããã
ä¹³ååŸã®ãéå·¥çšãèæ ®ããã°ãçŽ40åéïŒé
éïŒä»¥äžã奜ãŸããã ãŸãåèšæš¹è溶液ãŸãã¯é¡æåæ£æ¶²ã®ä¹³åã¯ã
æ¿ããæ¹æäžã«ããæ°Žäžã«åèšæº¶æ¶²åã¯åæ£æ¶²ã
滎äžãæ³šå ¥ãåŽé§çãè¡ãæ¹æ³ãæ°Žãšåèšæº¶æ¶²å
ã¯åæ£æ¶²ãã©ã€ã³ãããµãŒã§æ··åããæ¹æ³çã䜿
çšã§ãããããã®ææ¹æã«ããæ··å液ã®æž©åºŠãäž
æããæš¹èã®è»åã«ããæš¹èç²ååå¿ãåäœãªã
ãã¯äžäœåããç²å€§åããã®ãé²ãããã«ãæ··å
液ãå·åŽããŠæ¶²æž©ã30â以äžã«ä¿ã€ããšã奜ãŸã
ããåèšæ¹æãããã¯ã©ã€ã³ãããµãŒã§ã®æ··å
ã¯ãä¹³æ¿åŸ®ç²åäžã®æº¶å€ãæ°Žäžã«ç§»è¡ããæš¹èç²
åã圢æãããè¿è¡ããããããŠä¹³æ¿åŸ®ç²åäžã®
溶å€ãæ°Žäžã«æœåºãããæš¹èç²åãåŸããããã
ã®æš¹èç²åãéãŸãã¯é å¿åé¢çã«ããæ°Žâ溶
å€æ··åç©ãšåé¢ããããã«å¿ èŠãªãã°æ°ŽæŽåã³å
é¢ãå¿ èŠåæ°ç¹°ãè¿ããã¹ã©ãªãŒç¶ãªããã¯å«æ°Ž
ã±ãŒãç¶ã®æš¹èç²åãåŸãããã®ããã«ããŠã奜
ãŸããã¯ãå¹³åç²ååŸçŽïŒã200ÎŒã®éã®æš¹èç²
åãåŸããããã«ããã®ã¹ã©ãªãŒç¶ãªããã¯å«æ°Ž
ã±ãŒãç¶ã®æš¹èç²åã«çé¢æŽ»æ§å€åã³ïŒãŸãã¯å¢
ç²å€åã³æ°Žãå ããåŸãéåžžå¡æã®è£œé ã«çšãã
åæ£æ©ãäŸãã°ãµã³ããã«ãããŒã«ãã«ããã€ã¹
ããŒã¶ãŒããµã¹ãã€ã€ãŒãã«ãã»ã³ããªãŒãã«ç
ã§æš¹èç²åã埮ç²ç ããŠå¹³åç²ååŸãçŽïŒã50ÎŒ
ã®éã«èª¿æŽããã ããããŠåŸãããæ¬çºæã®æš¹èç²åã¯ãïŒåã®
ç²åäžã«ããªãšã¹ãã«æš¹èãšæ¶æ©æ§å ±éåæš¹èã
åã¯æ¶æ©æ§å ±éåæš¹èåã³ãããã¯ã€ãœã·ã¢ããŒ
ãååç©ãå«æãããã€ãŸãïŒåã®ç²åäžã«ãå
ç±ããããšã«ããçžäºã«åå¿ããåºãå³ã¡æ°Žé žåº
ãšïŒ®âã¢ã«ã³ãã·ã¡ãã«åºåã¯ãæ°Žé žåºãâã¢
ã«ã³ãã·ã¡ãã«åºåã³ã€ãœã·ã¢ããŒãåºãå¿ ãå«
æãããåŸã€ãŠæ¬çºæã®çµæç©ã¯å ç±ããããšã«
ãããæš¹èç²åäžã§ã®æ¶æ©åã³æš¹èç²ååå¿ã®æ¶
æ©åå¿ã§ãåªããæ§èœãæããå¡èãåŸãããã®
ã§ããã æ¬çºæã®æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç©ã¯åèšæš¹
èç²åãå¹³åç²ååŸãïŒã50ÎŒã®åŸ®ç²åç¶ã§åæ£
å«æããããšã奜ãŸãããå¹³åç²ååŸãïŒÎŒãã
å°ããå Žåã¯ç²ååå¿ã®åéæ§ã倧ãããªããå
å ç±æèæã«çºæ³¡ãæãçã®æ°Žæº¶æ§å¡æã«è¿ãæ§
質ããã³ãŠãããã奜ãŸãããªããåã50ÎŒãã
倧ããå Žåã¯è²¯èµäžã«æš¹èç²åãæ²æŸ±åéãæã
ãªããå¹³æ»ãªå¡é¢ãåŸãããªãããã«å¥œãŸãããª
ããç¹ã«å¹³åç²ååŸïŒã30ÎŒã®æš¹èç²åã«ãã貯
èµå®å®æ§ãåªããçºæ³¡ã®ãªãå¹³æ»ãªå¡èãäžãã
å¡æã圢æããæ¬çºæã«ã¯å¥œé©ã§ããããŸããæ¬
çºæã®çµæç©ã¯ãå¿ èŠã«ãã硬å觊åªãéåžžå¡æ
ã«äœ¿çšãããææ©ç³»ãç¡æ©ç³»ã®çè²åã³äœè³ªé¡
æãäžæé²éå€ãæµåå©å€ãæ¶æ³¡å€ãæ²æŸ±é²æ¢
å€ãé²åŸ®å€ãé²è å€çã®æ·»å å€ãåã³ä»ã®æ°Žæº¶æ§
æš¹èãããããŸã«ããšãã«ãžãšã³æš¹èçã®å¡è圢
ææš¹èçãå«ãããšãåºæ¥ããåè¿°ã®åŠããæš¹è
ç²åã®è»å枩床ã¯30ã100âã奜é©ã§ããããã
é¡æçå¡æäžã®å ç±æè枩床ã§æº¶èããªãæåã¯
æš¹èç²åäžã«50ééïŒ ä»¥äžã®éã§æ·»å ããããšã
奜ãŸããã æ¬çºæã§äœ¿çšããçé¢æŽ»æ§å€ãšããŠã¯ããããª
ã³ç³»çé¢æŽ»æ§å€ãã¢ããªã³ç³»çé¢æŽ»æ§å€ãã«ããª
ã³ç³»çé¢æŽ»æ§å€ãäž¡æ§çé¢æŽ»æ§å€ãªã©å ¬ç¥ã®ãã®
ã䜿çšå¯èœã§ããããããªã³ç³»çé¢æŽ»æ§å€ãšããŠ
ã¯äŸãã°ãœã«ãã¿ã³èèªé žãšã¹ãã«ãããªãªãã·
ãšãã¬ã³ãœã«ãã¿ã³èèªé žãšã¹ãã«ãããªãªãã·
ãšãã¬ã³ãœã«ãããŒã«èèªé žãšã¹ãã«ãããªãªã
ã·ãšãã¬ã³èèªé žãšã¹ãã«ãããªãªãã·ãšãã¬ã³
ã¢ã«ã³ãŒã«ãšãŒãã«ãã°ãªã»ãªã³èèªé žãšã¹ã
ã«ããããã¬ã³ã°ãªã³ãŒã«èèªé žãšã¹ãã«ãããª
ãªãã·ãšãã¬ã³ããã·æ²¹èªå°äœãããªãªãã·ãšã
ã¬ã³ã¢ã«ãã«ããšãã«ãšãŒãã«ãã¢ã«ãã«ãªã³é ž
ãšã¹ãã«ãããªãªãã·ãšãã¬ã³ãªã³é žãšã¹ãã«ã
ã¢ããªã³ç³»çé¢æŽ»æ§å€ãšããŠã¯ãã¢ã«ãã«ç¡«é žãš
ã¹ãã«å¡©ãããªãªãã·ãšãã¬ã³ã¢ã«ãã«ãšãŒãã«
ç¡«é žãšã¹ãã«å¡©ãã¢ã«ãã«ã¹ã«ãã³ãã¯é žå¡©ã
âã¢ã·ã«ãµã«ã³ã·ã³å¡©ãã«ããªã³ç³»çé¢æŽ»æ§å€ãš
ããŠã¯ç¬¬ïŒçŽã¢ã³ã¢ããŠã å¡©ãããªãžããŠã å¡©ãª
ã©ã䜿çšåºæ¥ãã æš¹èç²åã®åæ£å®å®æ§åã³å¡èæ§èœãªã©ã®ç¹ã
ãéã€ãªã³ç³»çé¢æŽ»æ§å€ã奜ãŸããç¹ã«HLBã
ïŒã18ã®ãã®ã奜é©ã§ããããŸãããããã®çé¢
掻æ§å€ã«ä»£ãããããã¯äœµçšããŠçšããåèšã®å¢
ç²å€ãšããŠã¯åŸæ¥æ°Žç³»æš¹èå¡æã«äœ¿çšãããŠãã
ãã®ãçšããããšãåºæ¥ãã ãããã¯äŸãã°ãã¡ãã«ã»ã«ããŒã¹ããšãã«ã»
ã«ããŒã¹ãããããã·ãšãã«ã»ã«ããŒã¹çã®ã»ã«
ããŒã¹ç³»æ°Žæº¶æ§æš¹èïŒããªããã«ã¢ã«ã³ãŒã«ïŒã
ãªãšãã¬ã³ã°ãªã³ãŒã«ãšãŒãã«ãããªãšãã¬ã³ãª
ããµã€ãçã®ããªãšãã¬ã³ç³»æ°Žæº¶æ§æš¹èïŒã¡ãã«
ããã«ãšãŒãã«ç¡æ°Žãã¬ã€ã³é žå ±éåäœããšãã¬
ã³ç¡æ°Žãã¬ã€ã³é žå ±éåäœãã¹ãã¬ã³ç¡æ°Žãã¬ã€
ã³é žå ±éåäœçã®ç¡æ°Žãã¬ã€ã³é žå ±éåäœç³»æ°Žæº¶
æ§æš¹èïŒã¢ã¯ãªã«é žç³»éåäœã®ã¢ã³ã¢ããŠã ãã¢
ãã³å¡©åã³ãããªãŠã å¡©ããã³ããã€ããããªã
ãã«ãããªãã³ãã¢ã«ã®ã³é žå¡©ãããªã¢ã¯ãªã«ã¢
ãã€ãåã³ãã®éšåå æ°Žå解ç©ãã«ãŒã€ã³åã³ãŒ
ã©ãã³çã®å€©ç¶ç£æ°Žæº¶æ§æš¹èãªã©ãæããããã äžèšçé¢æŽ»æ§å€åã³ïŒåã¯å¢ç²å€ã¯åŸ®ç²ç¶æš¹è
ç²åã«å¯ŸããŠ0.01ã5.0ééïŒ æ·»å ãããæ·»å é
ã0.01ééïŒ ãããå°ãªããªãã°è²¯èµå®å®æ§ãå¡
è£ äœæ¥æ§çãæªããªããå5.0ééïŒ ãããå€ã
ãªãã°å¡èã®å¹³æ»æ§ãèæ°Žæ§çãæªããªãããæ¬
çºæã«é©ããªããªããåèšããå¢ç²å€ã®äžã§ãã«
ã«ããã·ã«åºå«æã¢ã¯ãªã«å ±éåäœã®ã¢ãã³å¡©
ã¯ãã¢ãã³ã®è±é¢ã«ããå¡èã®å ç±æèåŸæ°Žäžæº¶
æ§ã«ãªãå¡èã®èæ°Žæ§ãäœäžãããªãããæ¬çºæ
ã«ç¹ã«å¥œé©ã§ããã æ¬çºæã®è©²è¢«èŠçµæç©äžã®æ°ŽãšåŸ®ç²ç¶æš¹èç²å
ã®æ··åæ¯ã¯ãééã§90ã30ïŒ10ã70ã奜ãŸããã åèšã®æ··åæ¯ã«æŒãŠæš¹èç²åãåèšæ··åæ¯ãã
å°ãªãçµæã®ãšãã«ã¯ãå¡æã®åºåœ¢åæ¿åºŠãäœ
ãããã€äœç²åºŠã§ãããããäžåºŠã«éåžžã®å¡èã®
åããäŸãã°20ã80ÎŒã«å¡åžããå Žåå¡èã«ãã¬
çã®çŸè±¡ãçãããããé¿ããããã«ã¯æ°åã®é
ãå¡ããå¿ èŠã§ãããªã©å¡è£ äœæ¥æ§ã«åé¡ãçã
ãããã«ãªãã äžæ¹ãæš¹èç²åãåèšæ··åæ¯ããå€ãå Žåã«
ã¯ãå¡æ補é æã®æ¹æãç·Žåçã«ããåäžåãå°
é£ãšãªããåç²åºŠç¹æ§ãåçš®ã®å¡è£ æ³äŸãã°ã¹ã
ã¬ãŒå¡è£ ãéé»å¡è£ çã®é©æ£ç¹æ§ããå€ãããã
å¡è£ äœæ¥æ§ãæªãå®çšæ§ãäœäžããåŸåã«ãªã奜
ãŸãããªãã æ¬çºæã®æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç©ãå¡è£ ã
ãæ¹æ³ãšããŠã¯ããã±å¡ãã浞挬å¡è£ ãã¹ãã¬ãŒ
å¡è£ ãéé»å¡è£ ãã«ãŒãã³ãããŒã³ãŒããã·ã€ã¯
ãŒã³ãŒãåã³ããŒã«ã³ãŒãçã®åšç¥ã®åçš®å¡è£ æ¹
æ³ãçšããããšãåºæ¥ãã ãŸãã該被èŠçµæç©ã®å¡è£ åŸã®å ç±ç¡¬åã®æ¡ä»¶
ã¯ã該çµæç©äžã®æ¶æ©æ§å®èœåºã®å«æéãèåãª
ã©ã«ããç°ãªãããéåžž120ã200âã®æž©åºŠç¯å²ã®
é©åœãªæž©åºŠã§10ã40åå ç±åŠçããããšã«ãã硬
åå¡èãšããããšãåºæ¥ãã ããããŠåŸããã硬åå¡èã¯ãéå±è¡šé¢ãžã®å¯
çæ§ããèé£æ§è©ŠéšåŸã®ïŒæ¬¡å¯çæ§ã®ããããã
ã®ãšãªãããŸãããªãšã¹ãã«æš¹èã®ãã€å¯ææ§ã
é¡æåæ£æ§ãå¡èå€èŠ³ã®åªããŠããç¹ãšãæ¶æ©æ§
å ±éåæš¹èã®ãã€ç¡¬åºŠã®åªããŠããç¹ãåã³ãŠã¬
ã¿ã³æš¹èã®ãã€èè¬åæ§ã®åªããŠããç¹ãå Œãå
ããŠããããããé«æž©çŒä»æã«çããçºæ³¡ïŒã¯
ãïŒãªã©ã®ãªããåªããå¡èæ§èœãæããŠããã 以äžå®æœäŸã«ããæ¬çºæã説æãããå°ã
ãéšãåã¯ãïŒ ãã¯ãéééšãåã¯ãééïŒ ãã
è¡šããã ãããªãšã¹ãã«æš¹è溶液ã®è£œé æ¹æ³ã (1) ããªãšã¹ãã«æš¹èSPâïŒã®åæ 枩床èšãæ¹ææ©ãã¹ããŒãžã¬ã¹å°å ¥ç®¡ã枩床
å¶åŸ¡è£ 眮ãããŒã·ã€ã«ã³ã³ãã³ãµãŒãªã©ãè£ å
ããåå¿å®¹åšã«ç¡æ°Žãã¿ã«é ž394éšãã¢ãžãã³
é ž137éšããããã¬ã³ã°ãªã³ãŒã«96éšãããªã
ã³ãã«ã°ãªã³ãŒã«160éšãããªã¡ãããŒã«ãã
ãã³163éšãé åãçªçŽ ã¬ã¹ãæµããªããåå¿
枩床ã235âè¿ææž©ããïŒæéåå¿ç¶ç¶åŸãå
å¿æž©åºŠã190âãŸã§äžãããã®åŸæ²¡é£åé ž50éš
ãæ·»å ããæŽã«190âã§ïŒæéåå¿ãè¡ããé ž
䟡9.0ãæ°Žé žåºäŸ¡110ãééå¹³åååé9500ã®ã
ãªãšã¹ãã«æš¹èãåŸãããããã¡ãã«ãšãã«ã±
ãã³ã«æº¶è§£ãäžæ®çºå60ïŒ ã®æš¹è溶液ãšããã (2) ããªãšã¹ãã«æš¹èSPâïŒã®åæ åèš(1)ãšåæ§ã®ææ³ã«ããã€ãœãã¿ã«é ž215
éšãç¡æ°Žãã¿ã«é ž118éšãã¢ãžãã³é ž173éšãã
ãªãã³ãã«ã°ãªã³ãŒã«195éšããããã¬ã³ã°ãª
ã³ãŒã«52éšãïŒïŒïŒâãããµã³ãžãªãŒã«éš92
éšãããªã¡ãããŒã«ãããã³95éšãé åãçªçŽ
æ°æµäžã§235âã«ææž©ãã6.5æéåå¿ç¶ç¶åŸã
åå¿æž©åºŠã190âãŸã§äžãããã®åŸãïŒïŒïŒâ
ãžãªãã·å®æ¯éŠé žïŒãããã«ãããŠé žïŒ60éšã
æ·»å ããæŽã«190âã§2.5æéåå¿ãè¡ããé žäŸ¡
8.5ãæ°Žé žåºäŸ¡123ãééå¹³åååé13200ã®ã
ãªãšã¹ãã«æš¹èãåŸãããããã¡ãã«ãšãã«ã±
ãã³ã«æº¶è§£ãäžæ®çºå60ïŒ ã®æš¹è溶液ãšããã (3) ããªãšã¹ãã«æš¹èSPâïŒã®åæ åèš(1)ãšåæ§ã®ææ³ã«ããã€ãœãã¿ã«é ž200
éšãã¢ãžãã³é ž163éšãç¡æ°Žãã¿ã«é ž202éšãã
ãªãã³ãã«ã°ãªã³ãŒã«193éšããããã¬ã³ã°ãª
ã³ãŒã«74éšãããªã¡ãããŒã«ãããã³75éšãã
ãªã¡ãããŒã«ãšã¿ã³63éšãé åãçªçŽ ã¬ã¹äžã§
235âã«ææž©ãã8.5æéåå¿ç¶ç¶åŸãåå¿æž©åºŠ
ã195âãŸã§äžãããã®åŸæ²¡é£åé ž30éšãæ·»å
ããæŽã«195âã§ïŒæéåå¿ãè¡ããé žäŸ¡9.3ã
æ°Žé žåºäŸ¡89ãééå¹³åååé11300ã®ããªãšã¹
ãã«æš¹èãåŸãããããã¡ãã«ãšãã«ã±ãã³ã«
溶解ãäžæ®çºå60ïŒ ã®æš¹è溶液ãšããã (4) ããªãšã¹ãã«æš¹èSPâïŒã®åæ åèš(1)ãšåæ§ã®ææ³ã«ããç¡æ°Žãã¿ã«é ž203
éšãã¢ãžãã³é ž371éšããããã¬ã³ã°ãªã³ãŒã«
164éšããžãããã¬ã³ã°ãªã³ãŒã«131éšãããªã¡
ãããŒã«ãããã³131éšãé åãçªçŽ ã¬ã¹ãæµ
ããªããåå¿æž©åºŠã235âè¿ææž©ã7.5æéåå¿
ãç¶ããçµæãé žäŸ¡9.3ãæ°Žé žåºäŸ¡78ãééå¹³
åååé9200ã®ããªãšã¹ãã«æš¹èãåŸãããã
ãã¡ãã«ãšãã«ã±ãã³ã«æº¶è§£ããäžæ®çºå60ïŒ
ã®æš¹è溶液ãšããã ãæ¶æ©æ§å ±éåæš¹è溶液ã®è£œé æ¹æ³ã (1) æ¶æ©æ§å ±éåæš¹èAXâïŒã®åæ æ¹ææ©ã枩床èšã滎äžããŒããå·åŽç®¡ããã³
çªçŽ ã¬ã¹å°å ¥ç®¡ãåããåå¿å®¹åšã«ãã¡ãã«ãš
ãã«ã±ãã³340éšãå ¥ãã枩床ã80âã«äžãã
åŸãäžèšã®ã¢ãããŒããã³éå§å€æ··å液ãïŒæ
éã«ããã€ãŠæ»Žäžãããã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã
50éšãã¹ãã¬ã³150éšããšãã«ã¢ã¯ãªã¬ãŒã165
éšãâïœâãããã·ã¡ãã«ã¢ã¯ãªã«ã¢ãã
125éšãã¢ã¯ãªã«é ž10éšãã¢ãŸãã¹ã€ãœããã
ãããªã«10éšã 滎äžçµäºåŸã¢ãŸãã¹ã€ãœããããããªã«1.5
éšãè¿œå ããåå¿æž©åºŠ87âã«ææž©ãããåŸãïŒ
æéåå¿ãè¡ãªããé žäŸ¡12.0ãééå¹³åååé
38000ããã³äžæ®çºå58.4ïŒ ã®æš¹è溶液ãåŸã
ããæš¹èã®è»å枩床ã¯çŽ73ã75âã§ãã€ããã
ããAXâïŒãšããã (2) æ¶æ©æ§å ±éåæš¹èAXâïŒã®åæ åèšAXâïŒããåæãããšåæ§ãªåå¿å®¹åš
ã«ã¡ãã«ãšãã«ã±ãã³340éšãå ¥ãã枩床ã80
âã«äžããåŸãäžèšã®ã¢ãããŒããã³éå§å€æ··
å液ãïŒæéã«ããã€ãŠæ»Žäžãããã¡ãã«ã¡ã¿
ã¯ãªã¬ãŒã150éšãã¹ãã¬ã³65éšããšãã«ã¢ã¯
ãªã¬ãŒã175éšãâïœâãããã·ã¡ãã«ã¢ã¯
ãªã«ã¢ãã100éšãã¢ã¯ãªã«é ž10éšãã¢ãŸãã¹
ã€ãœããããããªã«10éšã 滎äžçµäºåŸãã¢ãŸãã¹ã€ãœããããããªã«
1.5éšãè¿œå ããåå¿æž©åºŠã87âã«ææž©ããã
åŸïŒæéåå¿ãè¡ãªããé žäŸ¡13.9ãééå¹³åå
åé42000ããã³äžæ®çºå59.0ïŒ ã®æš¹è溶液ã
åŸããæš¹èã®è»å枩床ã¯72ã75âã§ãã€ããã
ããAXâïŒãšããã ããããã¯ã€ãœã·ã¢ããŒãååç©ã®æº¶å€çœ®ææ¹
æ³ã çæ°Žæ§æº¶å€ãå«æãããããã¯ã€ãœã·ã¢ããŒã
ååç©ã䜿çšããå Žåãæš¹èç²åã圢æããå·¥çš
ã§ãä¹³æ¿åŸ®ç²åäžã®æº¶å€ãæ°Žäžã«æœåºãããã«æš¹
èç²åäžã«æ®åãããããæš¹èç²ååå¿ãåäœãª
ããã¯äžäœåããå®å®æ§ãæãªãããã®ã§å¥œãŸã
ããªããããã§äžèšã®æ¹æ³ã§ãããã¯ã€ãœã·ã¢ã
ãŒãååç©ã®æº¶å€çœ®æãè¡ã€ãŠæ¬çºæã«äŸããã ã¿ã±ããŒãâ820NSUãæŠç°è¬åå·¥æ¥(æ ª)補å
ååïŒNCOå«æé4.3ïŒ ãäžæ®çºå60ïŒ ïŒæº¶å€ïŒ
ã¹ãŒããŒãŸãŒã«1500ïŒé ¢é žããã«ïŒãã40âäžã®
ç空也ç¥æ©ã«å ¥ããïŒæ¥éç空也ç¥ãè¡ã€ãåŸ
ïŒäžæ®çºå92.6ïŒ ïŒãããã«ã¡ãã«ãšãã«ã±ãã³ã
å ããäžæ®çºå60ïŒ ã«åžéããŠNCOâãšã
ãã ãå®æœäŸ ïŒã ããªãšã¹ãã«æš¹è溶液ïŒSPâïŒïŒ50éšã«äºé ž
åãã¿ã³33.3éšãã¡ãã«ãšãã«ã±ãã³10éšãæµå
å©å€ïŒåååã¢ããããŒïŒã¢ã³ãµã³ã瀟補ïŒïŒéš
ãé åãç£è£œããããã«ã§10Ό以äžã«ãªãè¿ç·Žå
åæ£ãããã«ããŒã¹ã«ããã«ããªãšã¹ãã«æš¹è溶
液ïŒSPâïŒïŒã17éšãæ¶æ©æ§å ±éåæš¹èïŒAXâ
ïŒïŒã103éšé åãæ¹ææ··ååŸãããåäžãªå¡æ
溶液ãšããããããé«éæ¹æäžã«ããæ°Žæž©15âã®
æ°Ž3000éšäžã«æ»Žäžããé¡æåæ£æ¶²ãä¹³åãããšãš
ãã«æº¶å€ãæ°ŽäžãžæœåºããŠæš¹èç²åã圢æããã
ãã®åŸãéããã³æ°ŽæŽãç¹°ãè¿ããå¹³åç²ååŸ
çŽ100ÎŒãå«æ°ŽççŽ50ïŒ ã®æš¹èç²åå«æ°Žã±ãŒãã
åŸãããã®å«æ°Žã±ãŒã100éšã«ãããªã³ç³»çé¢æŽ»
æ§å€40ïŒ æ°Žæº¶æ¶²ïŒåååãšãã«ã²ã³930ãè±çã¢
ãã©ã¹ç€Ÿè£œãHLB15.1ïŒ0.5éšãã¢ã¯ãªã«é žç³»å ±
éåäœã®ã¢ã«ã«ãªå¡©å¢ç²å€10ïŒ æ°Žæº¶æ¶²ïŒéšãæ·»å
ãããµã³ããã«ã§åæ£ç·ŽåããŠæš¹èç²åã埮ç²ç
ããå¹³åç²ååŸ15ÎŒãPH7.6ã®ã¹ã©ãªãŒç¶å¡æã
åŸãã ãå®æœäŸ ïŒã ããªãšã¹ãã«æš¹è溶液ïŒSPâïŒïŒ50éšã«äºé ž
åãã¿ã³33.3éšãã¡ãã«ãšãã«ã±ãã³10éšãæµå
å©å€ïŒåååã¢ããããŒïŒã¢ã³ãµã³ã瀟補ïŒïŒéš
é åãç£è£œããããã«ã§10Ό以äžã«ãªããŸã§ç·Žå
åæ£ãããã«ããŒã¹ã«ããã«æ¶æ©æ§æš¹è溶液
ïŒAXâïŒïŒ120éšãå ãæ¹ææ··ååŸããããåäž
ãªå¡æ溶液ãšããããããé«éæ¹æäžã«ããæ°Žæž©
15âã®æ°ŽçŽ3000éšäžã«æ»Žäžãé¡æåæ£æ¶²ãä¹³åã
ããšãšãã«æº¶å€ãæ°ŽäžãžæœåºããŠæš¹èç²åã圢æ
ããã ãã®åŸéããã³æ°ŽæŽãç¹°ãè¿ããå¹³åç²ååŸ
130ÎŒãå«æ°ŽççŽ50ïŒ ã®æš¹èç²åå«æ°Žã±ãŒããåŸ
ãããã®å«æ°Žã±ãŒã100éšã«ãããªã³ç³»çé¢æŽ»æ§
å€40ïŒ æ°Žæº¶æ¶²ïŒåååãšãã«ã²ã³910è±çã¢ãã©
ã¹ç€Ÿè£œHLB12.2ïŒ0.6éšãå¢ç²å€ïŒããããã·ãš
ãã«ã»ã«ããŒã¹ïŒïŒ 氎溶液ïŒïŒéšãæ·»å ããããŒ
ã«ãã«ã§åæ£ç·Žåããæš¹èç²åã埮ç²ç ããŠå¹³å
ç²ååŸ17ÎŒãPH7.5ã®ã¹ã©ãªãŒç¶å¡æãåŸãã ãå®æœäŸ ïŒã ããªãšã¹ãã«æš¹è溶液ïŒSPâïŒïŒ50éšãäºé ž
åãã¿ã³33.3éšãã¡ãã«ãšãã«ã±ãã³10éšãæµå
å©å€ïŒåååã¢ããããŒïŒã¢ã³ãµã³ã瀟補ïŒïŒéš
ãé åãããããã«ã§10Ό以äžã«ãªããŸã§ç·Žåå
æ£ãããã«ããŒã¹ã«ããã«ããªãšã¹ãã«æš¹è溶液
ïŒSPâïŒïŒã8.5éšãæ¶æ©æ§å ±éåæš¹è溶液ïŒAX
âïŒïŒã110éšé åãæ¹ææ··ååŸããããåäžãª
å¡æ溶液ãšããã以äžå®æœäŸïŒãšåäžã®æ¹æ³ã§æš¹
èç²åã®å¹³åç²ååŸ14ÎŒãPH7.8ã®ã¹ã©ãªãŒç¶å¡
æãåŸãã ãå®æœäŸ ïŒã å®æœäŸïŒã®ãã«ããŒã¹ã«ããªãšã¹ãã«æš¹è溶液
ïŒSPâïŒïŒãããã«17.8éšãšæ¶æ©æ§å ±éåæš¹è溶
液ïŒAXâïŒïŒã69.6éšãããã«ãããã¯ã€ãœã·
ã¢ããŒãååç©ïŒNCOâïŒã31.2éšãããã³
解é¢è§ŠåªïŒãžããã«ãã³ãžã©ãŠã¬ãŒãïŒ0.4éšå
ãåäžãªå¡æ溶液ãšããããããå®æœäŸïŒã®æ¹æ³
ã«åŸã€ãŠæš¹èç²åã®å¹³åç²ååŸ12ÎŒãPH7.9ã®ã¹
ã©ãªãŒç¶å¡æãåŸãã ãå®æœäŸ ïŒã å®æœäŸïŒã®ãã«ããŒã¹ã«ããªãšã¹ãã«æš¹è溶液
ïŒSPâïŒïŒã25éšãæ¶æ©æ§å ±éåæš¹è溶液ïŒAX
âïŒïŒ50.8éšããããã¯ã€ãœã·ã¢ããŒãååç©
ïŒNCOâïŒã41.7éšãããã³è§£é¢è§ŠåªïŒãžãã
ã«ãã³ãžã©ãŠã¬ãŒãïŒ0.6éšãå ãåäžãªå¡æ溶
液ãšããããããå®æœäŸïŒã®ææ³ã«åŸã€ãŠæš¹èç²
åã®å¹³åç²ååŸ11ÎŒãPH8.0ã®ã¹ã©ãªãŒç¶å¡æã
åŸãã ãæ¯èŒäŸ ïŒã å®æœäŸïŒã®ãã«ããŒã¹é åããããªãšã¹ãã«æš¹
è溶液ïŒSPâïŒïŒ50éšã®ä»£æ¿ãšããŠããªãšã¹ã
ã«æš¹è溶液ïŒSPâïŒïŒ50éšãé åããŠç·Žååæ£
ãããã«ããŒã¹ã«ããã«ããªãšã¹ãã«æš¹è溶液
ïŒSPâïŒïŒã75éšãã¡ã©ãã³æš¹èïŒå¹³åçž®å床
2.5ããšãŒãã«å床2.5ããã³æ°Žå¯æº¶æ§æåïŒïŒ 以
äžã®ããã«åã¡ãããŒã«ã¡ã©ãã³æš¹èã®60ïŒ ã¡ã
ã«ãšãã«ã±ãã³æº¶æ¶²ïŒã41.7éšå ãåäžãªå¡æ溶
液ãšããããããå®æœäŸïŒãšåæ§ã®ææ³ã«ããã¹
ã©ãªãŒåããå¹³åç²åŸ16ÎŒãPH7.9ã®ã¹ã©ãªãŒç¶
å¡æãåŸãã ãæ¯èŒäŸ ïŒã æ¶æ©æ§å ±éåæš¹è溶液ïŒAXâïŒïŒã®ã¢ãããŒ
é åããâïœâãããã·ã¡ãã«ã¢ã¯ãªã«ã¢ãã
125éšã®ä»£æ¿ãšããŠïŒâããããã·ãšãã«ã¡ã¿ã¯
ãªã¬ãŒã125éšãé åããŠåŸãããã¢ã¯ãªã«å ±é
åæš¹è溶液ïŒæ°Žé žåºäŸ¡108ïŒ50éšã«äºé žåãã¿ã³
33.3éšãã¡ãã«ãšãã«ã±ãã³10éšãæµåå©å€ïŒå
ååã¢ããããŒïŒã¢ã³ãµã³ã瀟補ïŒïŒéšé åãç£
補ããããã«ã§10Ό以äžã«ãªãè¿ç·Žååæ£ããã
ã«ããŒã¹ã«ãããã«åèšã¢ã¯ãªã«å ±éåæš¹è溶液
ã75éšãšæ¯èŒäŸïŒã®ã¡ã©ãã³æš¹èã41.7éšå ãå
äžãªå¡æ溶液ãšããã ãããå®æœäŸïŒãšåæ§ã®ææ³ã«ããã¹ã©ãªãŒå
ãå¹³åç²åŸ19ÎŒãPH7.7ã®ã¹ã©ãªãŒç¶å¡æãåŸ
ãã 以äžã®åå®æœäŸããã³æ¯èŒäŸã§èª¿æŽããã¹ã©ãª
ãŒç¶å¡æããªã³é žäºéåŠçãæœãããã«éŒæ¿äžã«
ã¹ãã¬ãŒå¡è£ ããïŒåéã»ããã€ã³ã°ããåŸ90â
ã§10åéäºç±ããããã®åŸåæå®ã®æž©åºŠã§å ç±ä¹Ÿ
ç¥ããŠèå35ÎŒã®å¡èã圢æããã第ïŒè¡šã«å¡è
ã®å ç±ä¹Ÿç¥æ¡ä»¶ããã³ç©æ§è©Šéšçµæã瀺ãã
å ¬å®³æ§ãæºè¶³ããæ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç©ã«
é¢ãããã®ã§ããã è¿å¹Žãå¡æãå¡è£ åéã«æŒãŠãçè³æºãçãšã
ã«ã®ãŒåã³ç°å¢åé¡ãéèŠãªããŒããšããŠãšãã
ãããããããã«é¢ããæ°èŠå¡æã®éçºãå¡è£ æ¹
æ³ã®æ¹è¯ãé²ããããŠãããç¹ã«ãå¡æã®åžéå€
ã§ããææ©æº¶åªã¯å¡è也ç¥éçšã§å€§æ°ã«æåºãã
ãããçè³æºãç°å¢ä¿å šã®ç¹ãã極ããŠç±ã ãã
åé¡ãšãããŠããããã®ãããªäºæ ãæ¹è¯ããã
ãå¡æäžã®ææ©æº¶åªãäœæžããåªåãè¡ãªããã
ãã®çµæãšããŠãã€ãœãªãããšç§°ãããé«äžæ®çº
åå¡æãé«ååéããªããŒãé極æ§ææ©æº¶åªïŒè
èªæç³»çåæ°ŽçŽ ïŒäžã«é«æ¿åºŠã«åæ£ããNAD
ïŒéæ°Žãã€ã¹ããŒã·ãšã³ïŒå¡æãåžéå€ã«æ°Žã䜿
çšããæ°Žç³»å¡æãåžéå€ãã®ãã®ãå šã䜿çšããª
ãç²äœå¡æãªã©ããã§ã«äžåžãããŠãããåŸã ã«
溶å€åå¡æã眮æãã€ã€ãããäžã§ãæ°Žç³»å¡æã«
ã€ããŠã¯åžéå€ãšããŠæ°Žã䜿çšããããç«çœçã®
å±éºããªãããšãåŸæ¥ã®å¡è£ è£ çœ®ããã®ãŸãŸæµçš
ã§ããããšãå¡è£ ç°å¢ãå¿«é©ã§ããããšãªã©ã®ç
ç±ããå¡æã®å°æ¥ç³»ãšããŠæ³šç®ãããŠããããã
ãæ°Žç³»å¡æã¯ãšãã«ã·ãšã³å¡æããã€ã¹ããŒã·ãš
ã³ïŒæ°Žåæ£åïŒå¡æã氎溶æ§å¡æãã¹ã©ãªãŒïŒæ³¥
挿ç¶ïŒå¡æçã«åé¡ã§ãããæ°Žç³»å¡æã«ã¯äžèšã®
ãããªå©ç¹ãããããåé¢æ¬ ç¹ãå€ãããã®ãã
ä»æ¥æº¶å€åå¡æãé§éããã«è³ã€ãŠããªãããã®
äž»ãªçç±ãšããŠã¯å¡è£ ç°å¢ãç¹ã«æž©åºŠã湿床ã«å·Š
å³ãããããèåãã€ãã«ããããšãå¡è也ç¥æ
ã«ã¯ããã¿ã¬ãããžãçã®å¡èæ¬ é¥ãçãããã
ããšãæ°Žã«å¯Ÿãã芪åæ§ãåäžãããããæš¹èäž
ã«èŠªæ°Žæ§åºã®å°å ¥ãåæ£å€ãçé¢æŽ»æ§å€çã®äœµçš
ã§å¡èã®èä¹ å質ãå£ãããšãªã©ãæããããã
ãã®ããçŸç¶ã§ã®æ°Žç³»å¡æã¯ãããã®æ°Žã«èµ·å ã
ãæ¬ é¥ãé€ãããããªãã®éã®ææ©æº¶åªã䜵çšã
ãŠããã®ãå®æ ã§ããçã®çè³æºãå ¬å®³å¯Ÿçå¡æ
ãšã¯äºãé£ãã ããã«å¯Ÿãã¹ã©ãªãŒç¶å¡æã¯ãã®ãããªæ°Žç³»å¡
æã®æ¬ é¥ãå æããæ°ããå¡æã§ããããã§ã«ç¹
å ¬æ48â52851å·ãç¹å ¬æ55â433å·ãªã©ã«è©³è¿°ã
ããŠããããã®ç¹åŸŽãç°¡åã«åèšãããšãã¹ã©ãª
ãŒç¶å¡æãšã¯æ°ŽãåªäœãšããŠïŒã80ÎŒçšåºŠã®ç²å
ç¶æš¹èãåºååæ¿åºŠãšããŠ10ã70ééïŒ ã®ç¯å²ã§
åæ£ãããå¡æã§ãããåŸã€ãŠæ®çºåãšããŠã¯åª
äœã§ããæ°Žã®ã¿ã§ãããããé«åºååæ¿åºŠã§å¡è£
ãå¯èœã§ãããåå¡ããåºæ¥ããããåŸæ¥ã®æº¶å€
åå¡æã®å¡è£ è£ çœ®ããã®ãŸãŸäœ¿çšã§ãããªã©æ°å€
ãã®å©ç¹ãæããåªããå¡æã§ããã äžè¬ã«ããã®ãããªã¹ã©ãªãŒç¶å¡æã«äœ¿çšãã
ãŠããæš¹èãšããŠã¯ãã¢ã¯ãªã«æš¹èãããªãšã¹ã
ã«æš¹èããšããã·æš¹èãã¢ã«ãããæš¹èãªã©ãç¥
ãããŠããããç¹ã«è²¯èµæã®å®å®æ§ãå¡èã®å¹³æ»
æ§ãä»äžãå€èŠ³ãªã©ããã¢ã¯ãªã«æš¹èããã³ããª
ãšã¹ãã«æš¹èã奜ãŸãããšãããŠãããåããã
ã«é²é£æ§ãªã©ãè£ãããã«ããšããã·æš¹èçã䜵
çšããããããå Žåãããããããããšããã·æš¹
èã䜵çšãããšãèåæ§ãæãªããããããäžå¡
ãå¡æçšæš¹èã®äžæåãšããŠäœ¿çšããã®ã¯å¥œãŸã
ããªãã äžæ¹ãå¡èã®èé£æ§ãåäžãããããã«ãããš
ããŒã«ã«ã«ãã³é žçã®åçš®å¡æã«é åããäŸãå€
ãããããã€ãç¥ãããŠãããäŸãã°R.N.
Faulknerçã«ãã€ãŠãæ€ç©æ²¹ãèèªé žãšã¹ã
ã«ãã¢ã«ããæš¹èãæ€ç©æ²¹å€æ§ãšããã·ãšã¹ãã«
æš¹èããããã¯æ€ç©æ²¹å€æ§ããªã¢ããæš¹èã«ãã«
ãã³ãŒã«ãããã¬ããŒã«ã没é£åé žãããã¯æ²¡é£
åé žãšã¹ãã«ãéå±ã¢ã«ã³ãã·ãã®ãããªè§Šåªã
çšããŠå°å ¥ããã溶å€ç³»â液åå¡æãéçºãããŠ
ãããïŒäŸãã°ãè±åœç¹èš±ç¬¬1045118å·ãç±³åœç¹èš±
第3304276å·ãå第3321320å·ãOil and Colour
Chemistâ²s Associationçºè¡ã®Journal of the Oil
and Colour Chemistâ²s Association第50å·»ã524
é ïŒ1967ïŒçãåç §ã®ããšãïŒãããããããã®
æš¹èã¯ãé«åºŠã®å¡èæ§èœãèŠæ±ãããåéã«ã¯é©
çšã§ããªãã€ãã ãšããã§ãæ¶æ©å€ãšããŠã¡ã©ãã³æš¹èãçšãã
å Žåãåèã«å¡è£ ãããšãçŒä»ãæã«çºæ³¡ïŒã¯
ãïŒãçãããããå¡è£ äœæ¥æ§ã®é¢ã«æ¬ ç¹ããã
åèåããããã«ã¯ãæ°åã«ãããå¡è£ ããå¿ èŠ
ããã€ãã æ¬çºæã¯ãããã®è«žåé¡ã解決ããããšãç®ç
ãšãããã®ã§ãããããªãã¡è²¯èµå®å®æ§ã«åªãã
äœæ¥å·ŸããããããçŒä»ãæã«ã¯ããªã©ã®æ¬ ç¹ã
ãªãããã«å æ²¢ãå¹³æ»æ§ãèè¬åæ§ãç¹ã«èé£æ§
è©ŠéšåŸã®ïŒæ¬¡å¯çæ§ãªã©ã«åªããå¡èæ§èœãæã
ãæ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç©ãæäŸãããã®ã§
ããã æ¬çºæã®äžæ æ§ã®éªšåã¯ãããªãšã¹ãã«æš¹èå
ã³ã¢ã¯ãªã«æš¹èã䜵çšããå©ç¹ã«å ãã該ããªãš
ã¹ãã«æš¹èã«ããšããŒã«ã«ã«ãã³é žãå°å ¥ããã
ãšã«ããåªããæ§èœãä»äžããããšã«ããããŸ
ããæ¬çºæã®å¥ã®æ æ§ã®éªšåã¯ãäžèšã®ç³»ã«å ã
ãŠãããã¯ã€ãœã·ã¢ããŒãååç©ãæ¶æ©å€ãšããŠ
䜵çšããããšã«ããäžèšã®å©ç¹ã«å ããŠã¬ã¿ã³æš¹
èãšããŠã®åªããæ§èœãä»äžããããšã«ãããã
ãªãã¡ãããªãšã¹ãã«æš¹èã®æããèæ°Žæ§ãè湿
æ§ãè沞氎æ§ãªã©ã®æ°Žã«é¢äžããæ§èœåã³ã¢ã¯ãª
ã«æš¹èã®æããåªããå¡èå€èŠ³ïŒå æ²¢ãèææã
è¡šé¢å¹³æ»æ§ïŒãªã©ã«å ããããšããŒã«ã«ã«ãã³é ž
ã®å°å ¥ã«ããããªãšã¹ãã«æš¹èã®æ§èœãšãããå¡©
æ°ŽåŽé§æ§è©ŠéšåŸã®ïŒæ¬¡å¯çæ§ãåäžããããŸããŠ
ã¬ã¿ã³æš¹èã®æããåªããèè¡ææ§ãèè¬åæ§ãª
ã©ãä»äžã§ããã ããã«ããªãšã¹ãã«æš¹èã«ã¢ã¯ãªã«æš¹èåã¯ã¢
ã¯ãªã«æš¹èãšã€ãœã·ã¢ããŒãååç©ãæ¶æ©ããã
ãããšã«ãã硬床ãšå¯ææ§ã®ãã©ã³ã¹ãé©åºŠã«ä¿
ãããå¡èãåŸãããšãå€æããã ãã®ããã«åªããç¹é·ã«å ããæ¬çºæçµæç©ã¯
çŒä»ä¹Ÿç¥æã®å¡èã®ãããŒæ§ãèããåäžãå¡è
å€èŠ³ãæ¹è¯ããå¹æãããã ããã«æ¬çºæçµæç©äžã«å«ãŸããããªãšã¹ãã«
æš¹èã¯æš¹èèªèº«ã®æ¥µæ§ãã¢ã¯ãªã«æš¹èãªã©ã«æ¯ã
é«ãããæ°Žãšã®èŠªåæ§ãããæ°Žäžã§ã®åæ£ç¶æ ã«
æŒãã貯èµå®å®æ§ãå¢é²ããããšããå¹æãã
ãã å³ã¡ãæ¬çºæã¯ã (1) (ã€) å€äŸ¡ããšããŒã«ã«ã«ãã³é žãïŒã15éé
ïŒ åå¿ããããæ°Žé žåºäŸ¡30ã300ã®ããªãšã¹
ãã«æš¹è âŠâŠ20ã90ééïŒ ãããã³ (ã) (i) αïŒÎ²âã¢ããšãã¬ã³æ§äžé£œåã«ã«ã
ã³é žã¢ããã®ïŒ®âã¢ã«ã³ãã·ã¡ãã«ååé
äœãšã (ii) åèš(i)以å€ã®Î±ïŒÎ²âã¢ããšãã¬ã³æ§äž
飜ååéäœã®ïŒçš®ãããã¯ïŒçš®ä»¥äžïŒäœ
ãããªã³é žåºå«æαïŒÎ²âã¢ããšãã¬ã³æ§
äžé£œååéäœãé€ãïŒãšã®åéäœæ··åç©ã
ãåŸãããæ¶æ©æ§å ±éåæš¹è
âŠâŠ80ã10ééïŒ ããæã埮ç²ç¶ã®ç±ç¡¬åæ§æš¹èç²åã該ç²å
ã«å¯ŸããŠ0.01ã5.0ééïŒ ã®çé¢æŽ»æ§å€å
ã³ïŒåã¯å¢ç²å€ãåã³å¿ èŠéã®æ°Žããæãæ°Ž
åæ£åç±ç¡¬åæ§è¢«èŠçµæç©ããªãã³ã« (2) (ã€) å€äŸ¡ããšããŒã«ã«ã«ãã³é žãïŒã15éé
ïŒ åå¿ããããæ°Žé žåºäŸ¡30ã300ã®ããªãšã¹
ãã«æš¹è âŠâŠ20ã90ééïŒ (ã) (a) (i) αïŒÎ²âã¢ããšãã¬ã³æ§äžé£œåã«
ã«ãã³é žã¢ããã®ïŒ®âã¢ã«ã³ãã·ã¡ãã«
ååéäœãšã (ii) åèš(i)以å€ã®Î±ïŒÎ²âã¢ããšãã¬ã³æ§
äžé£œååéäœã®ïŒçš®ãããã¯ïŒçš®ä»¥äž
ïŒäœãããªã³é žåºå«æαïŒÎ²âã¢ããšã
ã¬ã³æ§äžé£œååéäœãé€ãïŒ ãšã®åéäœæ··åç©ããåŸãããæ¶æ©æ§å ±éå
æš¹èãåã³ (b) ãããã¯ã€ãœã·ã¢ããŒãååç©ããæã
æ¶æ©å€æ··åç© âŠâŠ80ã10ééïŒ ããæã埮ç²ç¶ã®ç±ç¡¬åæ§æš¹èç²åã該ç²å
ã«å¯ŸããŠ0.01ã5.0ééïŒ ã®çé¢æŽ»æ§å€å
ã³ïŒåã¯å¢ç²å€ãåã³å¿ èŠéã®æ°Žããæãæ°Ž
åæ£åç±ç¡¬åæ§è¢«èŠçµæç©ã«é¢ããã æ¬çºæçµæç©ã«äœ¿çšããåèšããªãšã¹ãã«æš¹è
ã¯å€äŸ¡ããšããŒã«ã«ã«ãã³é žããã³å€äŸ¡ã«ã«ãã³
é žãããã«å¿ èŠã«å¿ããŠåèšå€äŸ¡ããšããŒã«ã«ã«
ãã³é žä»¥å€ã®äžäŸ¡ã®ã«ã«ãã³é žãšãå€äŸ¡ã¢ã«ã³ãŒ
ã«ãšããšã¹ãã«ååå¿ããããšã«ãã€ãŠåŸããã
ãã®ã§ããã該暹èã®ééå¹³åååéã¯2000ã
100000ã奜ãŸããã¯3000ã60000ã§ãããååé
ããã®ç¯å²ã«æºããªãå Žåã«ã¯ãã¹ã©ãªãŒå段é
ã§ç²åãå®å®ã«æ°Žäžã«åæ£ãããããšãå°é£ã§ã
ãã°ããã§ãªãå¡èæ§èœãç¹ã«æ©æ¢°çæ§èœãååŠ
çæ§èœãäœäžããã®ã§å¥œãŸãããªãããŸãååé
ããã®ç¯å²ãè¶ããå Žåã«ã¯äœµçšããã¢ã¯ãªã«æš¹
èããããã¯ã€ãœã·ã¢ããŒãååç©ãšã®çžæº¶æ§ã«
æ¬ ããããã«ãªãã°ããã§ãªããå¡èã®å¡è£ å€èŠ³
ãªã©ã«æ¯éãæ¥ããæãããããããªãšã¹ãã«æš¹
èã®æ°Žé žåºäŸ¡ã¯30ã300ãè©Šæ1gäžã«ååšããæ°Ž
é žåºã«å¯Ÿå¿ããã«ã«ããã·ã«åºãäžåããã«èŠã
ãæ°Žé žåã«ãªãŠã ã®ããªã°ã©ã æ°ïŒïŒæš¹èåºåå
å€ïŒä»¥äžåæ§ãã§ããã40ã200ã®ç¯å²ã奜ãŸã
ããæ°Žé žåºäŸ¡ããã®ç¯å²ã«æºããªãå Žåã«ã¯æ¶æ©
å¯åºŠãäœããŠæ¬æ¥ã®å¡èæ§èœãçºæ®ãåŸããç¹ã«
èæ°Žæ§ãè溶å€æ§ãèåæ§ãªã©ã®ïŒæ¬¡æ§èœãæªå
ããããŸããã®ç¯å²ãè¶ããå Žåã«ã¯ããªãšã¹ã
ã«æš¹èã«å¯Ÿããã¢ã¯ãªã«æš¹èããããã¯ã€ãœã·ã¢
ããŒãååç©ã®ç¡¬åæåã®æ¯çãå¢å€§ãããªãšã¹
ãã«æš¹èæ¬æ¥ã®æãŸããæ§èœãçºæ®åºæ¥ãªãã°ã
ãã§ãªããå¡èã®å¯ææ§ãå¯çæ§ãæãªãã æ¬çºæã®ããªãšã¹ãã«æš¹èã®åæã«éããã«ã«
ãã³é žæåãšããŠå€äŸ¡ããšããŒã«ã«ã«ãã³é žã䜿
çšããããšãå¿ é ã§ããã 該æåã¯ãããªãšã¹ãã«æš¹èæåäžïŒã15éé
ïŒ ã奜ãŸããã¯ïŒã10ééïŒ ã®å²åã§åå¿ããã
ããåèšç¯å²ã«æŒãŠã該æåãïŒééïŒ ã«æºããª
ãå Žåã«ã¯ãããªãšã¹ãã«æš¹èãåæããåŸãæ¶
æ©æ§å ±éåæš¹èãŸãã¯ãæ¶æ©æ§å ±éåæš¹èåã³ã
ããã¯ã€ãœã·ã¢ããŒãååç©ãçšããŠåœ¢æããå¡
èã®èé£æ§è©ŠéšåŸã®ïŒæ¬¡å¯çæ§ã®åäžå¹æãããŸ
ãåŸãããªããäžæ¹ãåèšæåã15ééïŒ ãè¶ã
ãŠäœ¿çšããããšãåŸããã硬åå¡èãèããªãã
ãŸãèåæ§ã®äœäžãèªããããããŸãã15ééïŒ
以å ã§å®è³ªçã«ååãªå¹æãåŸãããã®ã§ã15é
éïŒ ãèããè¶ããŠäœ¿çšããããšã¯çµæžçã«ã奜
ãŸãããªãã åèšå€äŸ¡ããšããŒã«ã«ã«ãã³é žãšããŠã¯ïŒïŒïŒ
âãžãªãã·å®æ¯éŠé žãïŒïŒïŒâãžãªãã·å®æ¯éŠ
é žãïŒïŒïŒâãžãªãã·å®æ¯éŠé žãïŒïŒïŒâãžãªã
ã·å®æ¯éŠé žãïŒïŒïŒâãžãªãã·å®æ¯éŠé žïŒããã
ã«ãããŠé žïŒãïŒïŒïŒâãžãªãã·å®æ¯éŠé žãïŒïŒ
ïŒïŒïŒâããªãªãã·å®æ¯éŠé žïŒæ²¡é£åé žïŒãïŒïŒ
ïŒïŒïŒâããªãªãã·å®æ¯éŠé žçãæãããããã
ããã¯ïŒçš®ãããã¯ïŒçš®ä»¥äžã®æ··åç©ãçšããŠã
ããã ãŸãå€äŸ¡ããšããŒã«ã«ã«ãã³é žä»¥å€ã®å€äŸ¡ã«ã«
ãã³é žããã³äžäŸ¡ã®ã«ã«ãã³é žãšããŠã¯ç¡æ°Žãã¿
ã«é žãã€ãœãã¿ã«é žããã¬ãã¿ã«é žããšã³ãã¡ã
ã¬ã³ããã©ãããç¡æ°Žãã¿ã«é žãããã©ãããç¡
æ°Žãã¿ã«é žãã¡ãã«ããã©ãããç¡æ°Žãã¿ã«é žã
ã¡ãã«ãããµãããç¡æ°Žãã¿ã«é žããããµããã
ç¡æ°Žãã¿ã«é žãç¡æ°Žããªã¡ããé žãã³ãã¯é žãã¢
ãžãã³é žãã¢ãŒã©ã€ã³é žãã»ããã³é žãã¯ãšã³
é žãé ç³é žããªã³ãŽé žãïŒïŒïŒâããã¿ãªã«é žç
ãå©çšåºæ¥ãããŸãåå¿èª¿æŽå€ãšããŠå®æ¯éŠé žã
ïœâïœããã«å®æ¯éŠé žãªã©ãå©çšããå Žåãã
ãããããã¯ïŒçš®ãããã¯ïŒçš®ä»¥äžã®æ··åç©ãçš
ããŠãããã 次ã«ãããªãšã¹ãã«æš¹èã®åæã«äœ¿çšããå€äŸ¡
ã¢ã«ã³ãŒã«ãšããŠã¯ãšãã¬ã³ã°ãªã³ãŒã«ããžãšã
ã«ã³ã°ãªã³ãŒã«ãããªãšãã¬ã³ã°ãªã³ãŒã«ããã
ãã¬ã³ã°ãªã³ãŒã«ããžãããã¬ã³ã°ãªã³ãŒã«ãã
ãã¬ã³ã°ãªã³ãŒã«ãïŒïŒïŒâãã³ã¿ã³ãžãªãŒã«ã
ããªãã³ãã«ã°ãªã³ãŒã«ãïŒïŒïŒâãããµã³ãžãª
ãŒã«ãæ°ŽçŽ åãã¹ããšããŒã«ïŒ¡ãïŒïŒïŒâã·ã¯ã
ãããµã³ãžã¡ã¿ããŒã«ããã³ã¿ãšãªã¹ãªããŒã«ã
ã°ãªã»ãªã³ãããªã¡ãããŒã«ãããã³ãããªã¡ã
ããŒã«ãšã¿ã³çã®ä»ããªãããã¬ã³ã°ãªã³ãŒã«ã
ããªãšãã¬ã³ã°ãªã³ãŒã«çã®é«çŽã¢ã«ã³ãŒã«çã
å©çšã§ããããããã¯ãïŒçš®ãããã¯ïŒçš®ä»¥äžã®
æ··åç©ãšããŠäœ¿çšããããåãå¿ èŠã«å¿ããŠã«ãŒ
ãžãŠã©ãŒïŒ¥ïŒã·ãšã«ã»ã±ãã«ã«ç€Ÿè£œãåååïŒã
䜵çšãããã ãããã®æ§æåæã®çµåãã«ããå¡èã®æ§èœã
ããªãéæã«åœ±é¿ãåããã®ã§ç®æšãšããæ§èœã«
åèŽããåæã®æ§æãèæ ®ããå¿ èŠããããäŸã
ã°ãå¡èã®èæ°Žæ§ãèè¬åæ§ãªã©ãå¿ èŠãšããå Ž
åã¯ã€ãœãã¿ã«é žãããªãã³ãã«ã°ãªã³ãŒã«ç
ããå¡èã®èè¡ææ§ãèã¯ã©ãã¯æ§ãå¿ èŠãšãã
å Žåã¯ã¢ãžãã³é žãã»ããã³é žããžãããã¬ã³ã°
ãªã³ãŒã«çããä»ã®æš¹èãšã®çžæº¶æ§ãé«ãããã
ã«ã¯ç¡æ°Žãã¿ã«é žããããã¬ã³ã°ãªã³ãŒã«çãçš
ããããšãªã©ã¯ãã§ã«åšç¥ã§ãããããã«ãå¡è
ã«ç¹æ®ãªæ§èœäŸãã°é²çæ§ãä»äžããããããã©
ã¯ããç¡æ°Žãã¿ã«é žãåæãšããŠçšããããšãªã©
ãåºæ¥ãã ããªãšã¹ãã«æš¹èã®è£œæ³ã¯éåžžã®çž®ååå¿ã§ã
ã溶èæ³ãŸãã¯ãã·ããŒã«çã®å ±æ²žæº¶åªã䜿çšã
ãå ±æ²žæ³ãããã泚æãã¹ãããšã¯å¯çããçž®å
æ°Žãåºæ¥ãã ãæ©ãç³»å€ã«é€å»ããããšãšå ±æ²žã
ãŠåºãŠããã°ãªã³ãŒã«ãé«èœçã§ååããããå®
å šãšã¹ãã«åè£ çœ®ã®å®¹éã倧ããããããšããã
ã«ããªãšã¹ãã«ã®çè²ããããããäžæŽ»æ§ã¬ã¹ã
å°å ¥ããããšãªã©ã§ããããŸãããªãšã¹ãã«æš¹è
ã®é žäŸ¡ã¯50ïŒæš¹èïŒã°ã©ã ãäžåããã«å¿ èŠãªæ°Ž
é žåã«ãªãŠã ã®ããªã°ã©ã æ°ïŒæš¹èåºååïŒä»¥äž
ãšããããšãæãŸããã 次ã«æ¬çºæã«æŒããæ¶æ©æ§å ±éåæš¹èãæ§æã
ãαïŒÎ²âã¢ããšãã¬ã³æ§äžé£œååéäœæ··åç©ãš
ããŠã¯ãαïŒÎ²âã¢ããšãã¬ã³æ§äžé£œåã«ã«ãã³
é žã¢ããã®ïŒ®âã¢ã«ã³ãã·ã¡ãã«ååéäœãå¿ é
æåãšããŠäœ¿çšãããã該æåã¯ãããªãšã¹ãã«
æš¹èãšã®æ¶æ©åå¿ã«å¿ èŠã§ããã該æåã¯æ¶æ©æ§
å ±éåæš¹èäžïŒã30ééïŒ ã奜ãŸããã¯10ã25é
éïŒ ã®å²åã§åå¿ããããããšã奜ãŸããã該æ
åãïŒééïŒ ã«æºããªãå Žåã«ã¯ãããªãšã¹ãã«
æš¹èãšã®æ¶æ©åå¿ãäžååãšãªããå¡èã®è溶å€
æ§ãäœäžããããŸã30ééïŒ ãè¶ãããšæ¶æ©æ§å ±
éåæš¹èã®è£œé æã«ã²ã«åã䌎ããã奜ãŸãããª
ãã該æåã®å ·äœäŸãšããŠã¯ãâã¡ããã·ã¡ã
ã«ïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ãããâãšããã·ã¡ãã«
ïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ãããâïœâããããã·ã¡
ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ãããâã€ãœãããã
ã·ã¡ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ãããâïœâãã
ãã·ã¡ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ãããâsecâ
ãããã·ã¡ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ãããâïœ
âãããã·ã¡ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ãããâ
ã€ãœãããã·ã¡ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã«ã¢ãããç
ã®Î±ïŒÎ²âã¢ããšãã¬ã³æ§äžé£œåã«ã«ãã³é žã¢ã
ãã®ïŒ®âã¢ã«ã³ãã·ã¡ãã«åç©ïŒãããã¯ããã
ã®ïŒ®âã¡ãããŒã«åç©ãªã©ãæãããããããã¯
ïŒçš®ãããã¯ïŒçš®ä»¥äžã®æ··åç©ãšããŠçšããŠãã
ããæ¬çºæã«ãããŠã¯æ¶æ©æ§å ±éåæš¹èã®äžæå
ãšããŠÎ±ïŒÎ²âã¢ããšãã¬ã³æ§äžé£œåã«ã«ãã³é ž
ã0.5ã10ééïŒ ã®ç¯å²ã§äœ¿çšããŠãããã該å
éäœã¯æ¶æ©æ§å ±éåæš¹èãšããªãšã¹ãã«æš¹èãšã®
çžæº¶æ§ãåäžããããšãšãã«æ¶æ©åå¿ãä¿é²ãã
ãšããå¹æãæãããåèšç¯å²ã«ãããŠ0.5éé
ïŒ ã«æºããªãå Žåã¯ãã®å¹æã匱ããªããå10é
éïŒ ãè¶ãããšç¡¬åå¡èã®æ§èœãäœäžããããã
ã«ãªãã®ã§å¥œãŸãããªãã 該æåã®å ·äœäŸãšããŠã¯ãã¢ã¯ãªã«é žãã¡ã¿ã¯
ãªã«é žãã¯ããã³é žãã€ã¿ã³ã³é žããã¬ã€ã³é žã
ããã«é žçãæãããããããã¯ïŒçš®ãããã¯ã
ïŒçš®ä»¥äžã®æ··åç©ãšããŠçšããŠãããã æ¬çºæã«äœ¿çšãããæ¶æ©æ§å ±éåæš¹èã®åæãš
ããŠåèšä»¥å€ã®å ±éåæ§Î±ïŒÎ²âã¢ããšãã¬ã³æ§
äžé£œååéäœïŒäœãããªã³é žåºå«æαïŒÎ²âã¢ã
ãšãã¬ã³æ§äžé£œååéäœãé€ãïŒ60ã90ééïŒ ã®
å²åã§åå¿ããããããšã奜ãŸããã該æåã®å ·
äœäŸãšããŠã¯ãã¡ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒãããš
ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïœâãããã«ïŒã¡
ã¿ïŒã¢ã¯ãªã¬ãŒããã€ãœãããã«ïŒã¡ã¿ïŒã¢ã¯ãª
ã¬ãŒããïœâããã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããsec
âããã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïœâããã«ïŒã¡
ã¿ïŒã¢ã¯ãªã¬ãŒããã€ãœããã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬
ãŒããïœâããã·ã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïŒâ
ãšãã«ããã·ã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïœâãªã¯
ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã©ãŠãªã«ïŒã¡ã¿ïŒã¢
ã¯ãªã¬ãŒããããªãã·ã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒãã
ã¹ãã¢ãªã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒãçã®ã¢ã¯ãªã«é ž
åã¯ã¡ã¿ã¯ãªã«é žã®ã¢ã«ãã«ãšã¹ãã«é¡ïŒïŒâã
ãããã·ãšãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïŒâãã
ããã·ãããã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïŒâãã
ããã·ãããã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïŒâãã
ããã·ããã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïŒâããã
ãã·ããã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïŒâãããã
ã·ããã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïŒâããããã·
ãã³ãã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïŒâããããã·
ããã·ã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããããªãã³ãã«ã°
ãªã³ãŒã«ã¢ãïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããïŒâããã
ã·âïŒâããããã·ãããã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒ
ããïŒâããããã·âïŒâããšãã«ãšãã«ïŒã¡
ã¿ïŒã¢ã¯ãªã¬ãŒããããªãããã¬ã³ã°ãªã³ãŒã«ã¢
ãïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã°ãªã»ãªã³ã¢ãïŒã¡
ã¿ïŒã¢ã¯ãªã¬ãŒãçã®Î±ïŒÎ²âã¢ããšãã¬ã³æ§äž
飜åã«ã«ãã³é žã®ããããã·ã¢ã«ãã«ãšã¹ãã«
é¡ïŒãã®ä»ïŒ®ïŒNâ²âãžã¡ãã«ã¢ãããšãã«ïŒã¡
ã¿ïŒã¢ã¯ãªã¬ãŒããã°ãªã·ãžã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬
ãŒããã·ã¯ãããã·ã«ïŒã¡ã¿ïŒã¢ã¯ãªã¬ãŒããã
ãšãã«ã¡ã¿ã¢ã¯ãªã¬ãŒãããã³ãžã«ã¡ã¿ã¯ãªã¬ãŒ
ããããã«é žãžâããã«ãªã©ã®ããã«é žãžâã¢ã«
ãã«ãšã¹ãã«é¡ãã¹ãã¬ã³ãããã«ãã«ãšã³ãα
âã¡ãã«ã¹ãã¬ã³ãïŒã¡ã¿ïŒã¢ã¯ãªããããªã«ã
ããã«ã¢ã»ããŒãçã®åéäœãæãããããäžèš
åéäœã¯å¡æçµæç©ã®äœ¿çšç®çãçšå¡ã«å¿ããŠïŒ
çš®åã¯ïŒçš®ä»¥äžé©å®çµåããŠäœ¿çšããŠãå·®æ¯ããª
ãã æ¬çºæã®æ¶æ©æ§å ±éåæš¹èã¯éåžžã®æº¶æ¶²éåã«
ãã補é ãããã該溶液éåæ³ã«çšããããéå
溶åªãšããŠã¯æ°Žå¯æº¶æ§ãŸãã¯æ°Žæ··åæ§æº¶åªãçšã
ããããäŸãã°ã¡ãã«ã¢ã«ã³ãŒã«ããšãã«ã¢ã«ã³
ãŒã«ãã€ãœãããã«ã¢ã«ã³ãŒã«ãïœâãããã«ã¢
ã«ã³ãŒã«çã®ã¢ã«ã³ãŒã«é¡ïŒãšãã¬ã³ã°ãªã³ãŒã«
ã¢ãã¡ãã«ãšãŒãã«ããšãã¬ã³ã°ãªã³ãŒã«ã¢ããš
ãã«ãšãŒãã«ããšãã¬ã³ã°ãªã³ãŒã«ã¢ãããã«ãš
ãŒãã«ããšãã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«
ã¢ã»ããŒãçã®ãšãã¬ã³ã°ãªã³ãŒã«èªå°äœïŒãžãš
ãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«ããžãšãã¬
ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«ããžãšãã¬ã³ã°
ãªã³ãŒã«ã¢ãããã«ãšãŒãã«çã®ãžãšãã¬ã³ã°ãª
ã³ãŒã«èªå°äœïŒé ¢é žã¡ãã«ãé ¢é žãšãã«ãé ¢é žã
ãã«çã®ãšã¹ãã«é¡ïŒã¡ãã«ãšãã«ã±ãã³ãã¡ã
ã«ã€ãœããã«ã±ãã³çã®ã±ãã³é¡çã䜿çšãã
ãããããã®éå溶åªã¯ïŒçš®åã¯ïŒçš®ä»¥äžãé©å®
çµåããŠäœ¿çšããŠããããç¹ã«æ°Žã«å¯Ÿãã溶解床
ã20âã§10ã30ééïŒ çšåºŠã®ãã®ã奜ãŸããã ãŸãã䜿çšãããéåéå§å€ãšããŠã¯ãäŸãã°
ãã³ãŸã€ã«ããŒãªããµã€ããïœâããã«ããŒãã³
ãŸãšãŒããïœâããã«ãããããŒãªããµã€ããã¯
ã¡ã³ãããããŒãªããµã€ãããžâïœâããã«ããŒ
ãªããµã€ããïœâããã«ããŒãªã¯ããšãŒãçã®æ
æ©éé žåç©ãããã¯ã¢ãŸãã¹ã€ãœããããããª
ã«ãã¢ãŸãžã€ãœé ªé žãããªã«ãªã©ã®ã¢ãŸååç©ã
æããããããããã®éåéå§å€ã®ïŒçš®åã¯ïŒçš®
以äžãé©å®æ··åããŠäœ¿çšããŠããããå¿ èŠãªã
ã°ãååéã調æŽããããã«é£é移åå€ãäŸãã°
ããã·ã«ã¡ã«ã«ãã¿ã³ãããªã°ãªã³ãŒã«é žâïŒâ
ãšãã«ããã·ã«ãåå¡©åççŽ çã䜿çšããŠãã
ãã該æ¶æ©æ§å ±éåæš¹è補é æã®éå枩床ã¯çŽ50
ã150âãåå¿æéã¯çŽïŒã12æéã§ããããã®
é䜿çšãããéå溶åªã¯ãåèšæš¹è補é æã®äžæ®
çºåã10ã80ééïŒ ã奜ãŸããã¯35ã75ééïŒ ã«
ãªããããªç¯å²ã§äœ¿çšããã åãéåéå§å€ã®äœ¿çšéã¯ãæ¶æ©æ§å ±éåæš¹è
補é æã®äžæ®çºåã«å¯ŸããŠçŽ0.1ã15ééïŒ ã®ç¯
å²ã§ãããé£é移åå€ã¯åæã«çŽïŒãïŒééïŒ ã®
ç¯å²ã§çšããããšã奜ãŸããã æ¬çºæã®æ¶æ©æ§å ±éåæš¹èã®ééå¹³åååéã¯
10000ã100000奜ãŸããã¯20000ã80000ã®ç¯å²å
ã«ããããšã奜ãŸãããééå¹³åååéã10000
ã«æºããªãå Žåã¯ãå¡èæ§èœãååã§ãªããäžæ¹
ééå¹³åååéã100000ãè¶ããå Žåã¯ãå¹³æ»æ§
ãæãªãããããã«ãªãã 次ã«æ¬çºæã«äœ¿çšãããæ¶æ©å€æ··åç©ã®ïŒã€ã§
ãããããã¯ã€ãœã·ã¢ããŒãååç©ãšã¯ãïŒåå
äžã«ã€ãœã·ã¢ããŒãåºãïŒå以äžæããã€ãœã·ã¢
ããŒãååç©ã§ããããã®ã€ãœã·ã¢ããŒãåºã®å š
ãŠããããã¯å€ã§ãã¹ã¯ããããããã¯ã€ãœã·ã¢
ããŒãååç©ã§ããã 該ãããã¯ã€ãœã·ã¢ããŒãååç©ã¯ãããªãšã¹
ãã«æš¹èãšã®æ¶æ©åå¿ã«é¢äžãããŠã¬ã¿ã³æš¹èã®
ãã€èè¬åæ§ã®åªããŠããç¹ãä»äžããããšã«ç¹
城ãããã 該ãããã¯ã€ãœã·ã¢ããŒãååç©ã¯ãïŒååäž
ã«ïŒå以äžã®ã€ãœã·ã¢ããŒãåºãæããããªã€ãœ
ã·ã¢ããŒãååç©ãäŸãã°ããšãã¬ã³ãžã€ãœã·ã¢
ããŒãããããã¬ã³ãžã€ãœã·ã¢ããŒããããã©ã¡
ãã¬ã³ãžã€ãœã·ã¢ããŒãããããµã¡ãã¬ã³ãžã€ãœ
ã·ã¢ããŒãããã«ã¡ãã¬ã³ãžã€ãœã·ã¢ããŒããïœ
âããšãã¬ã³ãžã€ãœã·ã¢ããŒããïœâããšãã¬ã³
âãžã€ãœã·ã¢ããŒããïŒïŒïŒâããªã¬ã³âãžã€ãœ
ã·ã¢ããŒããïŒïŒïŒâããªã¬ã³âãžã€ãœã·ã¢ããŒ
ããïŒïŒïŒâãããã¬ã³âãžã€ãœã·ã¢ããŒãã
ïŒïŒ4â²ïŒ4â³âããªããšãã«ã¡ã¿ã³ããªã€ãœã·ã¢ã
ãŒããïŒïŒ4â²âãžããšãã«ã¡ã¿ã³âãžã€ãœã·ã¢ã
ãŒããïŒïŒ3â²âãžã¡ãã«âïŒïŒ4â²âãžããšãã¬ã³
âãžã€ãœã·ã¢ããŒããïœâãã·ãªã¬ã³âãžã€ãœã·
ã¢ããŒããïœâãã·ãªã¬ã³âãžã€ãœã·ã¢ããŒãã
ã€ãœããã³ãžã€ãœã·ã¢ããŒãããªãžã³ã€ãœã·ã¢ã
ãŒãçã®ããªã€ãœã·ã¢ããŒãåã³åèšã€ãœã·ã¢ã
ãŒãååç©ã®éå°ãšãããšãã°ãšãã¬ã³ã°ãªã³ãŒ
ã«ããããã¬ã³ã°ãªã³ãŒã«ãïŒïŒïŒâããã¬ã³ã°
ãªã³ãŒã«ãããªãã³ãã«ã°ãªã³ãŒã«ãïŒïŒïŒïŒïŒ
âããªã¡ãã«ïŒïŒïŒâãã³ã¿ã³ãžãªãŒã«ããããµ
ã¡ãã¬ã³ã°ãªã³ãŒã«ãã·ã¯ããããµã³ãžã¡ã¿ããŒ
ã«ãããªã¡ãããŒã«ãããã³ããããµã³ããªãªãŒ
ã«ãã°ãªã»ãªã³ããã³ã¿ãšãªã¹ãªããŒã«çã®äœå
åããªãªãŒã«ãšã®ä»å åå¿ã«ãã€ãŠåŸãããïŒå®
èœä»¥äžã®ããªã€ãœã·ã¢ããŒããããŠãŒã¬ããæ§é
ãæããããªã€ãœã·ã¢ããŒããã¢ããã¢ããŒãçµ
åãæããããªã€ãœã·ã¢ããŒãçããããã¯å€ã§
ãããã¯ããã€ãœã·ã¢ããŒãååç©ã§ããã 該ãããã¯å€ãšããŠã¯ãããšããŒã«ãã¯ã¬ãŸãŒ
ã«çã®ããšããŒã«ç³»ãã¡ã¿ããŒã«ããã³ãžã«ã¢ã«
ã³ãŒã«ããšãã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«
çã®ã¢ã«ã³ãŒã«ç³»ãã¢ã»ãé ¢é žã¡ãã«ãããã³é ž
ãžã¡ãã«çã®æŽ»æ§ã¡ãã¬ã³ç³»ãã¢ã»ãã¢ããªãã
é ¢é žã¢ããçã®é žã¢ããç³»ããã®ä»ã€ããç³»ãã¢
ãã³ç³»ãã€ãããŸãŒã«ç³»ãå°¿çŽ ç³»ãã«ã«ããã³é ž
å¡©ç³»ãã€ãã³ç³»ããªãã·ã ç³»ãã¡ã«ã«ãã¿ã³ç³»ã
äºç¡«é žå¡©ç³»ãã©ã¯ã¿ã ç³»çãããã æ¬çºæã®æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç©ã«æŒãŠ
ã¯ãåèšãããã¯ã€ãœã·ã¢ããŒãååç©äžã®ãã
ãã¯å€ã解é¢ãããšå¹æçãªæ¶æ©ãè¡ãªãããã®
ã§ãããã¯å€ã®è§£é¢æž©åºŠã¯100â以äžã®ãã®ã奜
ãŸããã æ¬çºæã®äžæ æ§ã«æŒãŠãå€äŸ¡ããšããŒã«ã«ã«ã
ã³é žãåå¿ãããããªãšã¹ãã«æš¹èãšæ¶æ©æ§å ±é
åæš¹èãšã®äœ¿çšéã¯ééæ¯ã§20ïŒ80ã90ïŒ10ïŒé
éïŒ ïŒã§ããã該ç¯å²ã«æŒãŠãæ¶æ©æ§å ±éåæš¹è
ã10ééïŒ ããå°ãªããªãã°å¡èã®æ¶æ©æ§ãäžè¶³
ãå¡èã®è溶å€æ§ãèè¬åæ§çãäœäžããåŸåãš
ãªããäžæ¹è©²æ¶æ©æ§å ±éåæš¹èã80ééïŒ ããå€
ããªãã°ãæ¬çºæã®ç¹åŸŽã§ããããªãšã¹ãã«æš¹è
ã®èé£æ§è©ŠéšåŸã®ïŒæ¬¡å¯çæ§åäžå¹æãä¹ãããª
ãããŸãããªãšã¹ãã«æš¹èéãå°ãªããªãããªãš
ã¹ãã«æš¹èã®ãã€å¯ææ§ãé¡æåæ£æ§ãªã©ãæãª
ãããã ãŸããæ¬çºæã®å¥ã®æ æ§ã«æŒãŠãå€äŸ¡ããšããŒ
ã«ã«ã«ãã³é žãåå¿ãããããªãšã¹ãã«æš¹èãšã
æ¶æ©æ§å ±éåæš¹èåã³ãããã¯ã€ãœã·ã¢ããŒãå
åç©ãããªãæ¶æ©å€æ··åç©ãšã®äœ¿çšéã¯ãééæ¯
ã§20ïŒ80ã90ïŒ10ïŒééïŒ ïŒã§ããã該ç¯å²ã«ã
ããŠæ¶æ©å€æ··åç©ã80ééïŒ ããå€ããªãã°åèš
æ¶æ©æ§å ±éåæš¹èãå€ããªã€ãå Žåãšåæ§ã®åŒå®³
ãçããã æ¬çºæã«æŒãŠæ¶æ©å€æ··åç©ã䜿çšããå Žåãæ¶
æ©åå¿ã¯ããªãšã¹ãã«æš¹èã®æ°Žé žåºãšãæ¶æ©å€æ··
åç©äžã®æ¶æ©æ§å ±éåæš¹èã®ïŒ®âã¢ã«ã³ãã·ã¡ã
ã«åºåã³ãããã¯ã€ãœã·ã¢ããŒãååç©äžã®ã€ãœ
ã·ã¢ããŒãåºã«ããè¡ãããã æ¶æ©å€æ··åç©äžã®æ¶æ©æ§å ±éåæš¹èãšãããã¯
ã€ãœã·ã¢ããŒãååç©ã®äœ¿çšå²åã¯äžèšã®ããã«
è¡ãã®ã奜ãŸããã ãæ¶æ©å€æ··åç©äœ¿çšéïŒéééšïŒãâãæ°Žé žåº
ã«å¯Ÿããã€ãœã·ã¢ããŒãåºã®åœéæ¯ã0.1ã1.2ã§
ãããããªãããã¯ã€ãœã·ã¢ããŒãååç©ã®äœ¿çš
éïŒéééšïŒãïŒãæ¶æ©æ§å ±éåæš¹è䜿çšéïŒéé
éšïŒãã§ãããããããããããã¯ã€ãœã·ã¢ããŒ
ãååç©ïŒæ¶æ©æ§å ±éåæš¹èïŒ0.1ïŒ99.9ã94ïŒ
ïŒïŒåºåœ¢åééæ¯ïŒã§è¡ãã®ã奜ãŸããã ãããã¯ã€ãœã·ã¢ããŒãååç©ã®äœ¿çšéãèã
ã倧ãããªãã°ãããªãšã¹ãã«æš¹èãšæ¶æ©æ§å ±é
åæš¹èãšã®åå¿ãä¹ãããªããæ¶æ©æ§å ±éåæš¹è
ã®ç¹åŸŽã§ããå¡èã®èé£æ§ãèæ°Žæ§çã®åäžå¹æ
ãä¹ãããªãã ãªãæ¬çºæã«äœ¿çšãããããªãšã¹ãã«æš¹èãšæ¶
æ©æ§å ±éåæš¹èãŸãã¯ããªãšã¹ãã«æš¹èãšæ¶æ©æ§
å ±éåæš¹èåã³ãããã¯ã€ãœã·ã¢ããŒãååç©ã
ããªãæ¶æ©å€æ··åç©ããåŸããã埮ç²ç¶ã®æš¹èç²
åã®è»å枩床ã¯ã30ã100âã®ãã®ã奜ãŸããã
æŽã«å¥œãŸããã¯40ã80âã§ãããè»å枩床ã30â
ããäœããªãã°å¡æã®è²¯èµå®å®æ§ãäœäžããåŸå
ã«ãªãããŸã100âããé«ããªãã°å¡èã®å¹³æ»æ§
çãäžè¶³ãããã奜ãŸãããªããå°æ¬çºæã«ãã
ãŠã¯å¿ èŠã«å¿ããŠããªãšã¹ãã«æš¹èãšãæ¶æ©æ§å ±
éåæš¹èåã¯æ¶æ©å€æ··åç©ãšã®æ¶æ©åå¿ãä¿é²ã
ãããã®å ¬ç¥ã®é žè§Šåªãããã«ãšããã·æš¹èãã»
ã«ããŒã¹ç³»æš¹èãã¢ããæš¹èãªã©ã®ïŒçš®ãããã¯
ïŒçš®ä»¥äžã®ä»ã®å¡è圢ææš¹èã®äœµçšãå¯èœã§ã
ãã 次ã«ãæ¬çºæã®æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç©ã®
補é æ¹æ³ã«ã€ããŠèª¬æããã該補é æ¹æ³ãšããŠåŸ
æ¥ã®ç²äœå¡æåã³ã¹ã©ãªãŒç¶å¡æã®è£œé ãªã©ã«çš
ããããŠããéåžžã®æ©æ¢°ç²ç æ³ãé©çšåºæ¥ããã
è»åç¹ãäœãå Žåã¯ãæš¹èç²åã®ç²çæ§ã倧ãã
ãç²æ«åããããšãå°é£ãšãªããåŸã€ãŠæ¬çºæã®
æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç©ã以äžã«è¿°ã¹ãåŠã
ç¹å¥ãªæ¹æ³ã«ãã€ãŠæå©ã«è£œé ããããšãåºæ¥
ãã å ããæå®éã®åèšããªãšã¹ãã«æš¹èãšãæ¶æ©
æ§å ±éåæš¹èåã¯æ¶æ©å€æ··åç©ãšãå¿ èŠã«å¿ã硬
å觊åªãä»ã®å¡è圢ææš¹èçãåèšæ°Žå¯æº¶æ§æº¶å€
åã¯æ°Žæ··åæ§æº¶å€ã«æº¶è§£ããŠæš¹è溶液ãšãããã
ã«å¿ èŠãªãã°é¡æãå ããç·Žååæ£ããŠé¡æåæ£
液ãšããã ãã®é䜿çšããã溶å€ã¯åèšæº¶æ¶²éåæ³ã«çšã
ãããéå溶åªãšåããã®ãçšãããããåãã®
䜿çšéã¯ãåèšæš¹è溶液ãããã¯é¡æåæ£æ¶²ã®äž
æ®çºåã30ã80ééïŒ ã®ç¯å²ã«ãªããããªéã§ã
ãã ã€ãã§ããã®æš¹è溶液ãŸãã¯é¡æåæ£æ¶²ããã
ã®äžã«å«ãŸããæ°Žå¯æº¶æ§æº¶å€åã¯æ°Žæ··åæ§æº¶å€ã®
ãã¹ãŠã溶解ããéã®æ°Žäžã«åŸ®ç²ç¶ã«ä¹³åããã
ãã®é䜿çšãããæ°Žã®éã¯ãåèšæš¹è溶液ããã
ã¯é¡æåæ£æ¶²ã®å°ããšãïŒåéïŒééïŒã§ããã
ä¹³ååŸã®ãéå·¥çšãèæ ®ããã°ãçŽ40åéïŒé
éïŒä»¥äžã奜ãŸããã ãŸãåèšæš¹è溶液ãŸãã¯é¡æåæ£æ¶²ã®ä¹³åã¯ã
æ¿ããæ¹æäžã«ããæ°Žäžã«åèšæº¶æ¶²åã¯åæ£æ¶²ã
滎äžãæ³šå ¥ãåŽé§çãè¡ãæ¹æ³ãæ°Žãšåèšæº¶æ¶²å
ã¯åæ£æ¶²ãã©ã€ã³ãããµãŒã§æ··åããæ¹æ³çã䜿
çšã§ãããããã®ææ¹æã«ããæ··å液ã®æž©åºŠãäž
æããæš¹èã®è»åã«ããæš¹èç²ååå¿ãåäœãªã
ãã¯äžäœåããç²å€§åããã®ãé²ãããã«ãæ··å
液ãå·åŽããŠæ¶²æž©ã30â以äžã«ä¿ã€ããšã奜ãŸã
ããåèšæ¹æãããã¯ã©ã€ã³ãããµãŒã§ã®æ··å
ã¯ãä¹³æ¿åŸ®ç²åäžã®æº¶å€ãæ°Žäžã«ç§»è¡ããæš¹èç²
åã圢æãããè¿è¡ããããããŠä¹³æ¿åŸ®ç²åäžã®
溶å€ãæ°Žäžã«æœåºãããæš¹èç²åãåŸããããã
ã®æš¹èç²åãéãŸãã¯é å¿åé¢çã«ããæ°Žâ溶
å€æ··åç©ãšåé¢ããããã«å¿ èŠãªãã°æ°ŽæŽåã³å
é¢ãå¿ èŠåæ°ç¹°ãè¿ããã¹ã©ãªãŒç¶ãªããã¯å«æ°Ž
ã±ãŒãç¶ã®æš¹èç²åãåŸãããã®ããã«ããŠã奜
ãŸããã¯ãå¹³åç²ååŸçŽïŒã200ÎŒã®éã®æš¹èç²
åãåŸããããã«ããã®ã¹ã©ãªãŒç¶ãªããã¯å«æ°Ž
ã±ãŒãç¶ã®æš¹èç²åã«çé¢æŽ»æ§å€åã³ïŒãŸãã¯å¢
ç²å€åã³æ°Žãå ããåŸãéåžžå¡æã®è£œé ã«çšãã
åæ£æ©ãäŸãã°ãµã³ããã«ãããŒã«ãã«ããã€ã¹
ããŒã¶ãŒããµã¹ãã€ã€ãŒãã«ãã»ã³ããªãŒãã«ç
ã§æš¹èç²åã埮ç²ç ããŠå¹³åç²ååŸãçŽïŒã50ÎŒ
ã®éã«èª¿æŽããã ããããŠåŸãããæ¬çºæã®æš¹èç²åã¯ãïŒåã®
ç²åäžã«ããªãšã¹ãã«æš¹èãšæ¶æ©æ§å ±éåæš¹èã
åã¯æ¶æ©æ§å ±éåæš¹èåã³ãããã¯ã€ãœã·ã¢ããŒ
ãååç©ãå«æãããã€ãŸãïŒåã®ç²åäžã«ãå
ç±ããããšã«ããçžäºã«åå¿ããåºãå³ã¡æ°Žé žåº
ãšïŒ®âã¢ã«ã³ãã·ã¡ãã«åºåã¯ãæ°Žé žåºãâã¢
ã«ã³ãã·ã¡ãã«åºåã³ã€ãœã·ã¢ããŒãåºãå¿ ãå«
æãããåŸã€ãŠæ¬çºæã®çµæç©ã¯å ç±ããããšã«
ãããæš¹èç²åäžã§ã®æ¶æ©åã³æš¹èç²ååå¿ã®æ¶
æ©åå¿ã§ãåªããæ§èœãæããå¡èãåŸãããã®
ã§ããã æ¬çºæã®æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç©ã¯åèšæš¹
èç²åãå¹³åç²ååŸãïŒã50ÎŒã®åŸ®ç²åç¶ã§åæ£
å«æããããšã奜ãŸãããå¹³åç²ååŸãïŒÎŒãã
å°ããå Žåã¯ç²ååå¿ã®åéæ§ã倧ãããªããå
å ç±æèæã«çºæ³¡ãæãçã®æ°Žæº¶æ§å¡æã«è¿ãæ§
質ããã³ãŠãããã奜ãŸãããªããåã50ÎŒãã
倧ããå Žåã¯è²¯èµäžã«æš¹èç²åãæ²æŸ±åéãæã
ãªããå¹³æ»ãªå¡é¢ãåŸãããªãããã«å¥œãŸãããª
ããç¹ã«å¹³åç²ååŸïŒã30ÎŒã®æš¹èç²åã«ãã貯
èµå®å®æ§ãåªããçºæ³¡ã®ãªãå¹³æ»ãªå¡èãäžãã
å¡æã圢æããæ¬çºæã«ã¯å¥œé©ã§ããããŸããæ¬
çºæã®çµæç©ã¯ãå¿ èŠã«ãã硬å觊åªãéåžžå¡æ
ã«äœ¿çšãããææ©ç³»ãç¡æ©ç³»ã®çè²åã³äœè³ªé¡
æãäžæé²éå€ãæµåå©å€ãæ¶æ³¡å€ãæ²æŸ±é²æ¢
å€ãé²åŸ®å€ãé²è å€çã®æ·»å å€ãåã³ä»ã®æ°Žæº¶æ§
æš¹èãããããŸã«ããšãã«ãžãšã³æš¹èçã®å¡è圢
ææš¹èçãå«ãããšãåºæ¥ããåè¿°ã®åŠããæš¹è
ç²åã®è»å枩床ã¯30ã100âã奜é©ã§ããããã
é¡æçå¡æäžã®å ç±æè枩床ã§æº¶èããªãæåã¯
æš¹èç²åäžã«50ééïŒ ä»¥äžã®éã§æ·»å ããããšã
奜ãŸããã æ¬çºæã§äœ¿çšããçé¢æŽ»æ§å€ãšããŠã¯ããããª
ã³ç³»çé¢æŽ»æ§å€ãã¢ããªã³ç³»çé¢æŽ»æ§å€ãã«ããª
ã³ç³»çé¢æŽ»æ§å€ãäž¡æ§çé¢æŽ»æ§å€ãªã©å ¬ç¥ã®ãã®
ã䜿çšå¯èœã§ããããããªã³ç³»çé¢æŽ»æ§å€ãšããŠ
ã¯äŸãã°ãœã«ãã¿ã³èèªé žãšã¹ãã«ãããªãªãã·
ãšãã¬ã³ãœã«ãã¿ã³èèªé žãšã¹ãã«ãããªãªãã·
ãšãã¬ã³ãœã«ãããŒã«èèªé žãšã¹ãã«ãããªãªã
ã·ãšãã¬ã³èèªé žãšã¹ãã«ãããªãªãã·ãšãã¬ã³
ã¢ã«ã³ãŒã«ãšãŒãã«ãã°ãªã»ãªã³èèªé žãšã¹ã
ã«ããããã¬ã³ã°ãªã³ãŒã«èèªé žãšã¹ãã«ãããª
ãªãã·ãšãã¬ã³ããã·æ²¹èªå°äœãããªãªãã·ãšã
ã¬ã³ã¢ã«ãã«ããšãã«ãšãŒãã«ãã¢ã«ãã«ãªã³é ž
ãšã¹ãã«ãããªãªãã·ãšãã¬ã³ãªã³é žãšã¹ãã«ã
ã¢ããªã³ç³»çé¢æŽ»æ§å€ãšããŠã¯ãã¢ã«ãã«ç¡«é žãš
ã¹ãã«å¡©ãããªãªãã·ãšãã¬ã³ã¢ã«ãã«ãšãŒãã«
ç¡«é žãšã¹ãã«å¡©ãã¢ã«ãã«ã¹ã«ãã³ãã¯é žå¡©ã
âã¢ã·ã«ãµã«ã³ã·ã³å¡©ãã«ããªã³ç³»çé¢æŽ»æ§å€ãš
ããŠã¯ç¬¬ïŒçŽã¢ã³ã¢ããŠã å¡©ãããªãžããŠã å¡©ãª
ã©ã䜿çšåºæ¥ãã æš¹èç²åã®åæ£å®å®æ§åã³å¡èæ§èœãªã©ã®ç¹ã
ãéã€ãªã³ç³»çé¢æŽ»æ§å€ã奜ãŸããç¹ã«HLBã
ïŒã18ã®ãã®ã奜é©ã§ããããŸãããããã®çé¢
掻æ§å€ã«ä»£ãããããã¯äœµçšããŠçšããåèšã®å¢
ç²å€ãšããŠã¯åŸæ¥æ°Žç³»æš¹èå¡æã«äœ¿çšãããŠãã
ãã®ãçšããããšãåºæ¥ãã ãããã¯äŸãã°ãã¡ãã«ã»ã«ããŒã¹ããšãã«ã»
ã«ããŒã¹ãããããã·ãšãã«ã»ã«ããŒã¹çã®ã»ã«
ããŒã¹ç³»æ°Žæº¶æ§æš¹èïŒããªããã«ã¢ã«ã³ãŒã«ïŒã
ãªãšãã¬ã³ã°ãªã³ãŒã«ãšãŒãã«ãããªãšãã¬ã³ãª
ããµã€ãçã®ããªãšãã¬ã³ç³»æ°Žæº¶æ§æš¹èïŒã¡ãã«
ããã«ãšãŒãã«ç¡æ°Žãã¬ã€ã³é žå ±éåäœããšãã¬
ã³ç¡æ°Žãã¬ã€ã³é žå ±éåäœãã¹ãã¬ã³ç¡æ°Žãã¬ã€
ã³é žå ±éåäœçã®ç¡æ°Žãã¬ã€ã³é žå ±éåäœç³»æ°Žæº¶
æ§æš¹èïŒã¢ã¯ãªã«é žç³»éåäœã®ã¢ã³ã¢ããŠã ãã¢
ãã³å¡©åã³ãããªãŠã å¡©ããã³ããã€ããããªã
ãã«ãããªãã³ãã¢ã«ã®ã³é žå¡©ãããªã¢ã¯ãªã«ã¢
ãã€ãåã³ãã®éšåå æ°Žå解ç©ãã«ãŒã€ã³åã³ãŒ
ã©ãã³çã®å€©ç¶ç£æ°Žæº¶æ§æš¹èãªã©ãæããããã äžèšçé¢æŽ»æ§å€åã³ïŒåã¯å¢ç²å€ã¯åŸ®ç²ç¶æš¹è
ç²åã«å¯ŸããŠ0.01ã5.0ééïŒ æ·»å ãããæ·»å é
ã0.01ééïŒ ãããå°ãªããªãã°è²¯èµå®å®æ§ãå¡
è£ äœæ¥æ§çãæªããªããå5.0ééïŒ ãããå€ã
ãªãã°å¡èã®å¹³æ»æ§ãèæ°Žæ§çãæªããªãããæ¬
çºæã«é©ããªããªããåèšããå¢ç²å€ã®äžã§ãã«
ã«ããã·ã«åºå«æã¢ã¯ãªã«å ±éåäœã®ã¢ãã³å¡©
ã¯ãã¢ãã³ã®è±é¢ã«ããå¡èã®å ç±æèåŸæ°Žäžæº¶
æ§ã«ãªãå¡èã®èæ°Žæ§ãäœäžãããªãããæ¬çºæ
ã«ç¹ã«å¥œé©ã§ããã æ¬çºæã®è©²è¢«èŠçµæç©äžã®æ°ŽãšåŸ®ç²ç¶æš¹èç²å
ã®æ··åæ¯ã¯ãééã§90ã30ïŒ10ã70ã奜ãŸããã åèšã®æ··åæ¯ã«æŒãŠæš¹èç²åãåèšæ··åæ¯ãã
å°ãªãçµæã®ãšãã«ã¯ãå¡æã®åºåœ¢åæ¿åºŠãäœ
ãããã€äœç²åºŠã§ãããããäžåºŠã«éåžžã®å¡èã®
åããäŸãã°20ã80ÎŒã«å¡åžããå Žåå¡èã«ãã¬
çã®çŸè±¡ãçãããããé¿ããããã«ã¯æ°åã®é
ãå¡ããå¿ èŠã§ãããªã©å¡è£ äœæ¥æ§ã«åé¡ãçã
ãããã«ãªãã äžæ¹ãæš¹èç²åãåèšæ··åæ¯ããå€ãå Žåã«
ã¯ãå¡æ補é æã®æ¹æãç·Žåçã«ããåäžåãå°
é£ãšãªããåç²åºŠç¹æ§ãåçš®ã®å¡è£ æ³äŸãã°ã¹ã
ã¬ãŒå¡è£ ãéé»å¡è£ çã®é©æ£ç¹æ§ããå€ãããã
å¡è£ äœæ¥æ§ãæªãå®çšæ§ãäœäžããåŸåã«ãªã奜
ãŸãããªãã æ¬çºæã®æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç©ãå¡è£ ã
ãæ¹æ³ãšããŠã¯ããã±å¡ãã浞挬å¡è£ ãã¹ãã¬ãŒ
å¡è£ ãéé»å¡è£ ãã«ãŒãã³ãããŒã³ãŒããã·ã€ã¯
ãŒã³ãŒãåã³ããŒã«ã³ãŒãçã®åšç¥ã®åçš®å¡è£ æ¹
æ³ãçšããããšãåºæ¥ãã ãŸãã該被èŠçµæç©ã®å¡è£ åŸã®å ç±ç¡¬åã®æ¡ä»¶
ã¯ã該çµæç©äžã®æ¶æ©æ§å®èœåºã®å«æéãèåãª
ã©ã«ããç°ãªãããéåžž120ã200âã®æž©åºŠç¯å²ã®
é©åœãªæž©åºŠã§10ã40åå ç±åŠçããããšã«ãã硬
åå¡èãšããããšãåºæ¥ãã ããããŠåŸããã硬åå¡èã¯ãéå±è¡šé¢ãžã®å¯
çæ§ããèé£æ§è©ŠéšåŸã®ïŒæ¬¡å¯çæ§ã®ããããã
ã®ãšãªãããŸãããªãšã¹ãã«æš¹èã®ãã€å¯ææ§ã
é¡æåæ£æ§ãå¡èå€èŠ³ã®åªããŠããç¹ãšãæ¶æ©æ§
å ±éåæš¹èã®ãã€ç¡¬åºŠã®åªããŠããç¹ãåã³ãŠã¬
ã¿ã³æš¹èã®ãã€èè¬åæ§ã®åªããŠããç¹ãå Œãå
ããŠããããããé«æž©çŒä»æã«çããçºæ³¡ïŒã¯
ãïŒãªã©ã®ãªããåªããå¡èæ§èœãæããŠããã 以äžå®æœäŸã«ããæ¬çºæã説æãããå°ã
ãéšãåã¯ãïŒ ãã¯ãéééšãåã¯ãééïŒ ãã
è¡šããã ãããªãšã¹ãã«æš¹è溶液ã®è£œé æ¹æ³ã (1) ããªãšã¹ãã«æš¹èSPâïŒã®åæ 枩床èšãæ¹ææ©ãã¹ããŒãžã¬ã¹å°å ¥ç®¡ã枩床
å¶åŸ¡è£ 眮ãããŒã·ã€ã«ã³ã³ãã³ãµãŒãªã©ãè£ å
ããåå¿å®¹åšã«ç¡æ°Žãã¿ã«é ž394éšãã¢ãžãã³
é ž137éšããããã¬ã³ã°ãªã³ãŒã«96éšãããªã
ã³ãã«ã°ãªã³ãŒã«160éšãããªã¡ãããŒã«ãã
ãã³163éšãé åãçªçŽ ã¬ã¹ãæµããªããåå¿
枩床ã235âè¿ææž©ããïŒæéåå¿ç¶ç¶åŸãå
å¿æž©åºŠã190âãŸã§äžãããã®åŸæ²¡é£åé ž50éš
ãæ·»å ããæŽã«190âã§ïŒæéåå¿ãè¡ããé ž
䟡9.0ãæ°Žé žåºäŸ¡110ãééå¹³åååé9500ã®ã
ãªãšã¹ãã«æš¹èãåŸãããããã¡ãã«ãšãã«ã±
ãã³ã«æº¶è§£ãäžæ®çºå60ïŒ ã®æš¹è溶液ãšããã (2) ããªãšã¹ãã«æš¹èSPâïŒã®åæ åèš(1)ãšåæ§ã®ææ³ã«ããã€ãœãã¿ã«é ž215
éšãç¡æ°Žãã¿ã«é ž118éšãã¢ãžãã³é ž173éšãã
ãªãã³ãã«ã°ãªã³ãŒã«195éšããããã¬ã³ã°ãª
ã³ãŒã«52éšãïŒïŒïŒâãããµã³ãžãªãŒã«éš92
éšãããªã¡ãããŒã«ãããã³95éšãé åãçªçŽ
æ°æµäžã§235âã«ææž©ãã6.5æéåå¿ç¶ç¶åŸã
åå¿æž©åºŠã190âãŸã§äžãããã®åŸãïŒïŒïŒâ
ãžãªãã·å®æ¯éŠé žïŒãããã«ãããŠé žïŒ60éšã
æ·»å ããæŽã«190âã§2.5æéåå¿ãè¡ããé žäŸ¡
8.5ãæ°Žé žåºäŸ¡123ãééå¹³åååé13200ã®ã
ãªãšã¹ãã«æš¹èãåŸãããããã¡ãã«ãšãã«ã±
ãã³ã«æº¶è§£ãäžæ®çºå60ïŒ ã®æš¹è溶液ãšããã (3) ããªãšã¹ãã«æš¹èSPâïŒã®åæ åèš(1)ãšåæ§ã®ææ³ã«ããã€ãœãã¿ã«é ž200
éšãã¢ãžãã³é ž163éšãç¡æ°Žãã¿ã«é ž202éšãã
ãªãã³ãã«ã°ãªã³ãŒã«193éšããããã¬ã³ã°ãª
ã³ãŒã«74éšãããªã¡ãããŒã«ãããã³75éšãã
ãªã¡ãããŒã«ãšã¿ã³63éšãé åãçªçŽ ã¬ã¹äžã§
235âã«ææž©ãã8.5æéåå¿ç¶ç¶åŸãåå¿æž©åºŠ
ã195âãŸã§äžãããã®åŸæ²¡é£åé ž30éšãæ·»å
ããæŽã«195âã§ïŒæéåå¿ãè¡ããé žäŸ¡9.3ã
æ°Žé žåºäŸ¡89ãééå¹³åååé11300ã®ããªãšã¹
ãã«æš¹èãåŸãããããã¡ãã«ãšãã«ã±ãã³ã«
溶解ãäžæ®çºå60ïŒ ã®æš¹è溶液ãšããã (4) ããªãšã¹ãã«æš¹èSPâïŒã®åæ åèš(1)ãšåæ§ã®ææ³ã«ããç¡æ°Žãã¿ã«é ž203
éšãã¢ãžãã³é ž371éšããããã¬ã³ã°ãªã³ãŒã«
164éšããžãããã¬ã³ã°ãªã³ãŒã«131éšãããªã¡
ãããŒã«ãããã³131éšãé åãçªçŽ ã¬ã¹ãæµ
ããªããåå¿æž©åºŠã235âè¿ææž©ã7.5æéåå¿
ãç¶ããçµæãé žäŸ¡9.3ãæ°Žé žåºäŸ¡78ãééå¹³
åååé9200ã®ããªãšã¹ãã«æš¹èãåŸãããã
ãã¡ãã«ãšãã«ã±ãã³ã«æº¶è§£ããäžæ®çºå60ïŒ
ã®æš¹è溶液ãšããã ãæ¶æ©æ§å ±éåæš¹è溶液ã®è£œé æ¹æ³ã (1) æ¶æ©æ§å ±éåæš¹èAXâïŒã®åæ æ¹ææ©ã枩床èšã滎äžããŒããå·åŽç®¡ããã³
çªçŽ ã¬ã¹å°å ¥ç®¡ãåããåå¿å®¹åšã«ãã¡ãã«ãš
ãã«ã±ãã³340éšãå ¥ãã枩床ã80âã«äžãã
åŸãäžèšã®ã¢ãããŒããã³éå§å€æ··å液ãïŒæ
éã«ããã€ãŠæ»Žäžãããã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã
50éšãã¹ãã¬ã³150éšããšãã«ã¢ã¯ãªã¬ãŒã165
éšãâïœâãããã·ã¡ãã«ã¢ã¯ãªã«ã¢ãã
125éšãã¢ã¯ãªã«é ž10éšãã¢ãŸãã¹ã€ãœããã
ãããªã«10éšã 滎äžçµäºåŸã¢ãŸãã¹ã€ãœããããããªã«1.5
éšãè¿œå ããåå¿æž©åºŠ87âã«ææž©ãããåŸãïŒ
æéåå¿ãè¡ãªããé žäŸ¡12.0ãééå¹³åååé
38000ããã³äžæ®çºå58.4ïŒ ã®æš¹è溶液ãåŸã
ããæš¹èã®è»å枩床ã¯çŽ73ã75âã§ãã€ããã
ããAXâïŒãšããã (2) æ¶æ©æ§å ±éåæš¹èAXâïŒã®åæ åèšAXâïŒããåæãããšåæ§ãªåå¿å®¹åš
ã«ã¡ãã«ãšãã«ã±ãã³340éšãå ¥ãã枩床ã80
âã«äžããåŸãäžèšã®ã¢ãããŒããã³éå§å€æ··
å液ãïŒæéã«ããã€ãŠæ»Žäžãããã¡ãã«ã¡ã¿
ã¯ãªã¬ãŒã150éšãã¹ãã¬ã³65éšããšãã«ã¢ã¯
ãªã¬ãŒã175éšãâïœâãããã·ã¡ãã«ã¢ã¯
ãªã«ã¢ãã100éšãã¢ã¯ãªã«é ž10éšãã¢ãŸãã¹
ã€ãœããããããªã«10éšã 滎äžçµäºåŸãã¢ãŸãã¹ã€ãœããããããªã«
1.5éšãè¿œå ããåå¿æž©åºŠã87âã«ææž©ããã
åŸïŒæéåå¿ãè¡ãªããé žäŸ¡13.9ãééå¹³åå
åé42000ããã³äžæ®çºå59.0ïŒ ã®æš¹è溶液ã
åŸããæš¹èã®è»å枩床ã¯72ã75âã§ãã€ããã
ããAXâïŒãšããã ããããã¯ã€ãœã·ã¢ããŒãååç©ã®æº¶å€çœ®ææ¹
æ³ã çæ°Žæ§æº¶å€ãå«æãããããã¯ã€ãœã·ã¢ããŒã
ååç©ã䜿çšããå Žåãæš¹èç²åã圢æããå·¥çš
ã§ãä¹³æ¿åŸ®ç²åäžã®æº¶å€ãæ°Žäžã«æœåºãããã«æš¹
èç²åäžã«æ®åãããããæš¹èç²ååå¿ãåäœãª
ããã¯äžäœåããå®å®æ§ãæãªãããã®ã§å¥œãŸã
ããªããããã§äžèšã®æ¹æ³ã§ãããã¯ã€ãœã·ã¢ã
ãŒãååç©ã®æº¶å€çœ®æãè¡ã€ãŠæ¬çºæã«äŸããã ã¿ã±ããŒãâ820NSUãæŠç°è¬åå·¥æ¥(æ ª)補å
ååïŒNCOå«æé4.3ïŒ ãäžæ®çºå60ïŒ ïŒæº¶å€ïŒ
ã¹ãŒããŒãŸãŒã«1500ïŒé ¢é žããã«ïŒãã40âäžã®
ç空也ç¥æ©ã«å ¥ããïŒæ¥éç空也ç¥ãè¡ã€ãåŸ
ïŒäžæ®çºå92.6ïŒ ïŒãããã«ã¡ãã«ãšãã«ã±ãã³ã
å ããäžæ®çºå60ïŒ ã«åžéããŠNCOâãšã
ãã ãå®æœäŸ ïŒã ããªãšã¹ãã«æš¹è溶液ïŒSPâïŒïŒ50éšã«äºé ž
åãã¿ã³33.3éšãã¡ãã«ãšãã«ã±ãã³10éšãæµå
å©å€ïŒåååã¢ããããŒïŒã¢ã³ãµã³ã瀟補ïŒïŒéš
ãé åãç£è£œããããã«ã§10Ό以äžã«ãªãè¿ç·Žå
åæ£ãããã«ããŒã¹ã«ããã«ããªãšã¹ãã«æš¹è溶
液ïŒSPâïŒïŒã17éšãæ¶æ©æ§å ±éåæš¹èïŒAXâ
ïŒïŒã103éšé åãæ¹ææ··ååŸãããåäžãªå¡æ
溶液ãšããããããé«éæ¹æäžã«ããæ°Žæž©15âã®
æ°Ž3000éšäžã«æ»Žäžããé¡æåæ£æ¶²ãä¹³åãããšãš
ãã«æº¶å€ãæ°ŽäžãžæœåºããŠæš¹èç²åã圢æããã
ãã®åŸãéããã³æ°ŽæŽãç¹°ãè¿ããå¹³åç²ååŸ
çŽ100ÎŒãå«æ°ŽççŽ50ïŒ ã®æš¹èç²åå«æ°Žã±ãŒãã
åŸãããã®å«æ°Žã±ãŒã100éšã«ãããªã³ç³»çé¢æŽ»
æ§å€40ïŒ æ°Žæº¶æ¶²ïŒåååãšãã«ã²ã³930ãè±çã¢
ãã©ã¹ç€Ÿè£œãHLB15.1ïŒ0.5éšãã¢ã¯ãªã«é žç³»å ±
éåäœã®ã¢ã«ã«ãªå¡©å¢ç²å€10ïŒ æ°Žæº¶æ¶²ïŒéšãæ·»å
ãããµã³ããã«ã§åæ£ç·ŽåããŠæš¹èç²åã埮ç²ç
ããå¹³åç²ååŸ15ÎŒãPH7.6ã®ã¹ã©ãªãŒç¶å¡æã
åŸãã ãå®æœäŸ ïŒã ããªãšã¹ãã«æš¹è溶液ïŒSPâïŒïŒ50éšã«äºé ž
åãã¿ã³33.3éšãã¡ãã«ãšãã«ã±ãã³10éšãæµå
å©å€ïŒåååã¢ããããŒïŒã¢ã³ãµã³ã瀟補ïŒïŒéš
é åãç£è£œããããã«ã§10Ό以äžã«ãªããŸã§ç·Žå
åæ£ãããã«ããŒã¹ã«ããã«æ¶æ©æ§æš¹è溶液
ïŒAXâïŒïŒ120éšãå ãæ¹ææ··ååŸããããåäž
ãªå¡æ溶液ãšããããããé«éæ¹æäžã«ããæ°Žæž©
15âã®æ°ŽçŽ3000éšäžã«æ»Žäžãé¡æåæ£æ¶²ãä¹³åã
ããšãšãã«æº¶å€ãæ°ŽäžãžæœåºããŠæš¹èç²åã圢æ
ããã ãã®åŸéããã³æ°ŽæŽãç¹°ãè¿ããå¹³åç²ååŸ
130ÎŒãå«æ°ŽççŽ50ïŒ ã®æš¹èç²åå«æ°Žã±ãŒããåŸ
ãããã®å«æ°Žã±ãŒã100éšã«ãããªã³ç³»çé¢æŽ»æ§
å€40ïŒ æ°Žæº¶æ¶²ïŒåååãšãã«ã²ã³910è±çã¢ãã©
ã¹ç€Ÿè£œHLB12.2ïŒ0.6éšãå¢ç²å€ïŒããããã·ãš
ãã«ã»ã«ããŒã¹ïŒïŒ 氎溶液ïŒïŒéšãæ·»å ããããŒ
ã«ãã«ã§åæ£ç·Žåããæš¹èç²åã埮ç²ç ããŠå¹³å
ç²ååŸ17ÎŒãPH7.5ã®ã¹ã©ãªãŒç¶å¡æãåŸãã ãå®æœäŸ ïŒã ããªãšã¹ãã«æš¹è溶液ïŒSPâïŒïŒ50éšãäºé ž
åãã¿ã³33.3éšãã¡ãã«ãšãã«ã±ãã³10éšãæµå
å©å€ïŒåååã¢ããããŒïŒã¢ã³ãµã³ã瀟補ïŒïŒéš
ãé åãããããã«ã§10Ό以äžã«ãªããŸã§ç·Žåå
æ£ãããã«ããŒã¹ã«ããã«ããªãšã¹ãã«æš¹è溶液
ïŒSPâïŒïŒã8.5éšãæ¶æ©æ§å ±éåæš¹è溶液ïŒAX
âïŒïŒã110éšé åãæ¹ææ··ååŸããããåäžãª
å¡æ溶液ãšããã以äžå®æœäŸïŒãšåäžã®æ¹æ³ã§æš¹
èç²åã®å¹³åç²ååŸ14ÎŒãPH7.8ã®ã¹ã©ãªãŒç¶å¡
æãåŸãã ãå®æœäŸ ïŒã å®æœäŸïŒã®ãã«ããŒã¹ã«ããªãšã¹ãã«æš¹è溶液
ïŒSPâïŒïŒãããã«17.8éšãšæ¶æ©æ§å ±éåæš¹è溶
液ïŒAXâïŒïŒã69.6éšãããã«ãããã¯ã€ãœã·
ã¢ããŒãååç©ïŒNCOâïŒã31.2éšãããã³
解é¢è§ŠåªïŒãžããã«ãã³ãžã©ãŠã¬ãŒãïŒ0.4éšå
ãåäžãªå¡æ溶液ãšããããããå®æœäŸïŒã®æ¹æ³
ã«åŸã€ãŠæš¹èç²åã®å¹³åç²ååŸ12ÎŒãPH7.9ã®ã¹
ã©ãªãŒç¶å¡æãåŸãã ãå®æœäŸ ïŒã å®æœäŸïŒã®ãã«ããŒã¹ã«ããªãšã¹ãã«æš¹è溶液
ïŒSPâïŒïŒã25éšãæ¶æ©æ§å ±éåæš¹è溶液ïŒAX
âïŒïŒ50.8éšããããã¯ã€ãœã·ã¢ããŒãååç©
ïŒNCOâïŒã41.7éšãããã³è§£é¢è§ŠåªïŒãžãã
ã«ãã³ãžã©ãŠã¬ãŒãïŒ0.6éšãå ãåäžãªå¡æ溶
液ãšããããããå®æœäŸïŒã®ææ³ã«åŸã€ãŠæš¹èç²
åã®å¹³åç²ååŸ11ÎŒãPH8.0ã®ã¹ã©ãªãŒç¶å¡æã
åŸãã ãæ¯èŒäŸ ïŒã å®æœäŸïŒã®ãã«ããŒã¹é åããããªãšã¹ãã«æš¹
è溶液ïŒSPâïŒïŒ50éšã®ä»£æ¿ãšããŠããªãšã¹ã
ã«æš¹è溶液ïŒSPâïŒïŒ50éšãé åããŠç·Žååæ£
ãããã«ããŒã¹ã«ããã«ããªãšã¹ãã«æš¹è溶液
ïŒSPâïŒïŒã75éšãã¡ã©ãã³æš¹èïŒå¹³åçž®å床
2.5ããšãŒãã«å床2.5ããã³æ°Žå¯æº¶æ§æåïŒïŒ 以
äžã®ããã«åã¡ãããŒã«ã¡ã©ãã³æš¹èã®60ïŒ ã¡ã
ã«ãšãã«ã±ãã³æº¶æ¶²ïŒã41.7éšå ãåäžãªå¡æ溶
液ãšããããããå®æœäŸïŒãšåæ§ã®ææ³ã«ããã¹
ã©ãªãŒåããå¹³åç²åŸ16ÎŒãPH7.9ã®ã¹ã©ãªãŒç¶
å¡æãåŸãã ãæ¯èŒäŸ ïŒã æ¶æ©æ§å ±éåæš¹è溶液ïŒAXâïŒïŒã®ã¢ãããŒ
é åããâïœâãããã·ã¡ãã«ã¢ã¯ãªã«ã¢ãã
125éšã®ä»£æ¿ãšããŠïŒâããããã·ãšãã«ã¡ã¿ã¯
ãªã¬ãŒã125éšãé åããŠåŸãããã¢ã¯ãªã«å ±é
åæš¹è溶液ïŒæ°Žé žåºäŸ¡108ïŒ50éšã«äºé žåãã¿ã³
33.3éšãã¡ãã«ãšãã«ã±ãã³10éšãæµåå©å€ïŒå
ååã¢ããããŒïŒã¢ã³ãµã³ã瀟補ïŒïŒéšé åãç£
補ããããã«ã§10Ό以äžã«ãªãè¿ç·Žååæ£ããã
ã«ããŒã¹ã«ãããã«åèšã¢ã¯ãªã«å ±éåæš¹è溶液
ã75éšãšæ¯èŒäŸïŒã®ã¡ã©ãã³æš¹èã41.7éšå ãå
äžãªå¡æ溶液ãšããã ãããå®æœäŸïŒãšåæ§ã®ææ³ã«ããã¹ã©ãªãŒå
ãå¹³åç²åŸ19ÎŒãPH7.7ã®ã¹ã©ãªãŒç¶å¡æãåŸ
ãã 以äžã®åå®æœäŸããã³æ¯èŒäŸã§èª¿æŽããã¹ã©ãª
ãŒç¶å¡æããªã³é žäºéåŠçãæœãããã«éŒæ¿äžã«
ã¹ãã¬ãŒå¡è£ ããïŒåéã»ããã€ã³ã°ããåŸ90â
ã§10åéäºç±ããããã®åŸåæå®ã®æž©åºŠã§å ç±ä¹Ÿ
ç¥ããŠèå35ÎŒã®å¡èã圢æããã第ïŒè¡šã«å¡è
ã®å ç±ä¹Ÿç¥æ¡ä»¶ããã³ç©æ§è©Šéšçµæã瀺ãã
ãè¡šã
ãè¡šã
åèšæ¯èŒè©Šéšçµæè¡šããæãããªåŠããæ¬çºæ
ã®çµæç©ããåŸãããå¡èã¯å ç±ä¹Ÿç¥æã«çºæ³¡ã
ãããšããªããæŽã«æ¯èŒäŸçµæç©ããåŸãããå¡
èã«æ¯ããŠå¯çæ§ãå¯ææ§ãèè¡ææ§ãèè¬åæ§
ãåªãããšãšãã«ãèæ°Žæ§è©Šéšãè湿æ§è©ŠéšåŸã®
ïŒæ¬¡å¯çæ§ããã³èå¡©æ°ŽåŽé§æ§è©ŠéšåŸã®ïŒæ¬¡å¯ç
æ§ãç¹ã«åªãããã®ã§ãã€ãã
ã®çµæç©ããåŸãããå¡èã¯å ç±ä¹Ÿç¥æã«çºæ³¡ã
ãããšããªããæŽã«æ¯èŒäŸçµæç©ããåŸãããå¡
èã«æ¯ããŠå¯çæ§ãå¯ææ§ãèè¡ææ§ãèè¬åæ§
ãåªãããšãšãã«ãèæ°Žæ§è©Šéšãè湿æ§è©ŠéšåŸã®
ïŒæ¬¡å¯çæ§ããã³èå¡©æ°ŽåŽé§æ§è©ŠéšåŸã®ïŒæ¬¡å¯ç
æ§ãç¹ã«åªãããã®ã§ãã€ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ (ã€) å€äŸ¡ããšããŒã«ã«ã«ãã³é žãïŒã15éé
ïŒ åå¿ããããæ°Žé žåºäŸ¡30ã300ã®ããªãšã¹ã
ã«æš¹è âŠâŠ20ã90ééïŒ ãããã³ (ã) (i) αïŒÎ²âã¢ããšãã¬ã³æ§äžé£œåã«ã«ãã³
é žã¢ããã®ïŒ®âã¢ã«ã³ãã·ã¡ãã«ååéäœ
ãšã (ii) åèš(i)以å€ã®Î±ïŒÎ²âã¢ããšãã¬ã³æ§äžé£œ
ååéäœã®ïŒçš®ãããã¯ïŒçš®ä»¥äžïŒäœãããª
ã³é žåºå«æαïŒÎ²âã¢ããšãã¬ã³æ§äžé£œåå
éäœãé€ãïŒãšã®åéäœæ··åç©ããåŸããã
æ¶æ©æ§å ±éåæš¹è âŠâŠ80ã10ééïŒ ããæã埮ç²ç¶ã®ç±ç¡¬åæ§æš¹èç²åã該ç²åã«
察ããŠ0.01ã5.0ééïŒ ã®çé¢æŽ»æ§å€åã³ïŒå
ã¯å¢ç²å€ãåã³å¿ èŠéã®æ°Žããæãæ°Žåæ£åç±
硬åæ§è¢«èŠçµæç©ã ïŒ åèšæ¶æ©æ§å ±éåæš¹èãæ§æããåéäœæ··å
ç©ã¯ã (i) αïŒÎ²âã¢ããšãã¬ã³æ§äžé£œåã«ã«ãã³é žã¢
ããã®ïŒ®âã¢ã«ã³ãã·ã¡ãã«ååéäœ
âŠâŠïŒã30ééïŒ (ii) αïŒÎ²âã¢ããšãã¬ã³æ§äžé£œåã«ã«ãã³é ž
âŠâŠ0.5ã10ééïŒ (iii) åèš(i)åã³(ii)以å€ã®å ±éåæ§Î±ïŒÎ²âã¢ããš
ãã¬ã³æ§äžé£œååéäœ âŠâŠ60ã90ééïŒ ããæãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ°Žåæ£åç±
硬åæ§è¢«èŠçµæç©ã ïŒ (ã€) å€äŸ¡ããšããŒã«ã«ã«ãã³é žãïŒã15éé
ïŒ åå¿ããããæ°Žé žåºäŸ¡30ã300ããªãšã¹ãã«
æš¹è âŠâŠ20ã90ééïŒ (ã) (a) (i) αïŒÎ²âã¢ããšãã¬ã³æ§äžé£œåã«ã«
ãã³é žã¢ããã®ïŒ®âã¢ã«ã³ãã·ã¡ãã«åå
éäœãšã (ii) åèš(i)以å€ã®Î±ïŒÎ²âã¢ããšãã¬ã³æ§äž
飜ååéäœã®ïŒçš®ãããã¯ïŒçš®ä»¥äžïŒäœ
ãããªã³é žåºå«æαïŒÎ²âã¢ããšãã¬ã³æ§
äžé£œååéäœãé€ãïŒãšã®åéäœæ··åç©ã
ãåŸãããæ¶æ©æ§å ±éåæš¹èãåã³ (b) ãããã¯ã€ãœã·ã¢ããŒãååç©ããæãæ¶
æ©å€æ··åç© âŠâŠ80ã10ééïŒ ããæã埮ç²ç¶ã®ç±ç¡¬åæ§æš¹èç²åã該ç²åã«
察ããŠ0.01ã5.0ééïŒ ã®çé¢æŽ»æ§å€åã³ïŒå
ã¯å¢ç²å€ãåã³å¿ èŠéã®æ°Žããæãæ°Žåæ£åç±
硬åæ§è¢«èŠçµæç©ã ïŒ åèšæ¶æ©æ§å ±éåæš¹èãæ§æããåéäœæ··å
ç©ã¯ã (i) αïŒÎ²âã¢ããšãã¬ã³æ§äžé£œåã«ã«ãã³é žã¢
ããã®ïŒ®âã¢ã«ã³ãã·ã¡ãã«ååéäœ
âŠâŠïŒã30ééïŒ (ii) αïŒÎ²âã¢ããšãã¬ã³æ§äžé£œåã«ã«ãã³é ž
âŠâŠ0.5ã10ééïŒ (iii) åèš(i)åã³(ii)以å€ã®å ±éåæ§Î±ïŒÎ²âã¢ããš
ãã¬ã³æ§äžé£œååéäœ âŠâŠ60ã90ééïŒ ããæãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ°Žåæ£åç±
硬åæ§è¢«èŠçµæç©ã ïŒ åèšæ¶æ©æ§å ±éåæš¹èãšãããã¯ã€ãœã·ã¢ã
ãŒãååç©ã®åºååééæ¯ã¯99.9ïŒ0.1ïŒïŒïŒ94
ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®æ°Žåæ£åç±ç¡¬
åæ§è¢«èŠçµæç©ã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15011281A JPS5852366A (ja) | 1981-09-21 | 1981-09-21 | æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç© |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15011281A JPS5852366A (ja) | 1981-09-21 | 1981-09-21 | æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç© |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5852366A JPS5852366A (ja) | 1983-03-28 |
| JPS6225187B2 true JPS6225187B2 (ja) | 1987-06-02 |
Family
ID=15489745
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15011281A Granted JPS5852366A (ja) | 1981-09-21 | 1981-09-21 | æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç© |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5852366A (ja) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5865768A (ja) * | 1981-10-14 | 1983-04-19 | Dainippon Toryo Co Ltd | æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç© |
| JPS5865769A (ja) * | 1981-10-14 | 1983-04-19 | Dainippon Toryo Co Ltd | æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç© |
| JPH06220397A (ja) * | 1993-01-25 | 1994-08-09 | Mazda Motor Corp | äºæ¶²åãŠã¬ã¿ã³å¡æçµæç© |
| JP6022852B2 (ja) * | 2012-08-15 | 2016-11-09 | ãŠããã«æ ªåŒäŒç€Ÿ | ããªãšã¹ãã«æš¹èæ°Žæ§åæ£äœããã³ãã®è£œé æ¹æ³ |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5825383A (ja) * | 1981-08-05 | 1983-02-15 | Ishikawajima Harima Heavy Ind Co Ltd | ã³âã¯ã¹ä¹ŸåŒæ¶ç«èšåã«æŒããå·åŽã¬ã¹å¹èŸŒè£ 眮 |
| JPS6034991A (ja) * | 1983-06-15 | 1985-02-22 | ã¡ã«ã¯ããšã³ããã«ã ããâãã€ã³ã³âãã¬âããã | æ«ç«¯ã¢ããç°ãæããã¬ãã³é»å®³ç© |
-
1981
- 1981-09-21 JP JP15011281A patent/JPS5852366A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5825383A (ja) * | 1981-08-05 | 1983-02-15 | Ishikawajima Harima Heavy Ind Co Ltd | ã³âã¯ã¹ä¹ŸåŒæ¶ç«èšåã«æŒããå·åŽã¬ã¹å¹èŸŒè£ 眮 |
| JPS6034991A (ja) * | 1983-06-15 | 1985-02-22 | ã¡ã«ã¯ããšã³ããã«ã ããâãã€ã³ã³âãã¬âããã | æ«ç«¯ã¢ããç°ãæããã¬ãã³é»å®³ç© |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5852366A (ja) | 1983-03-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0980881B1 (de) | WÀssriges Beschichtungsmittel, dessen Herstellung und Verwendung fÌr Einbrennlacke | |
| JPS63193968A (ja) | æ°Žæ§è¢«èŠçµæç© | |
| DE69313014T2 (de) | WÀssrige OberflÀchenbeschichtungszusammensetzung | |
| JPH0812925A (ja) | æ°Žæ§å¡æçµæç©ããã³ãããçšããå¡è£ æ¹æ³ | |
| JPS6241543B2 (ja) | ||
| JPH10338719A (ja) | ãã£ã«ã 圢ææ§èŠªæ°Žæ§æš¹èããã³å¡æçµæç© | |
| JP4326690B2 (ja) | å€å±€ã®è¢«èŠã®è£œé æ¹æ³ | |
| AU665876B2 (en) | Two coat one bake coating method | |
| JPS6225187B2 (ja) | ||
| JPS598371B2 (ja) | ã¹ã©ãªâç¶å¡æã®èª¿è²æ¹æ³ | |
| JPS6225188B2 (ja) | ||
| JPS6225189B2 (ja) | ||
| JPS5833900B2 (ja) | æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç© | |
| JPS5950267B2 (ja) | æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç© | |
| JPH0252664B2 (ja) | ||
| JPH0252665B2 (ja) | ||
| JPS5825384B2 (ja) | æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç© | |
| JPS5952911B2 (ja) | æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç© | |
| JPS6034991B2 (ja) | æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç© | |
| JPS5830344B2 (ja) | æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç© | |
| JPS5825383B2 (ja) | æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç© | |
| JPS5825385B2 (ja) | æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç© | |
| JPH04213370A (ja) | å¡æçµæç©ããã³å¡è£ éŒæ¿ | |
| JPH0412301B2 (ja) | ||
| JPS6034989B2 (ja) | æ°Žåæ£åç±ç¡¬åæ§è¢«èŠçµæç© |