[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

JPS6036189A - Thermal transfer film - Google Patents

Thermal transfer film

Info

Publication number
JPS6036189A
JPS6036189A JP58145213A JP14521383A JPS6036189A JP S6036189 A JPS6036189 A JP S6036189A JP 58145213 A JP58145213 A JP 58145213A JP 14521383 A JP14521383 A JP 14521383A JP S6036189 A JPS6036189 A JP S6036189A
Authority
JP
Japan
Prior art keywords
transfer film
ink
film
ink layer
thermal transfer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP58145213A
Other languages
Japanese (ja)
Inventor
Tadamitsu Nakayama
中山 忠光
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Resonac Corp
Original Assignee
Hitachi Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Chemical Co Ltd filed Critical Hitachi Chemical Co Ltd
Priority to JP58145213A priority Critical patent/JPS6036189A/en
Publication of JPS6036189A publication Critical patent/JPS6036189A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/382Contact thermal transfer or sublimation processes
    • B41M5/392Additives, other than colour forming substances, dyes or pigments, e.g. sensitisers, transfer promoting agents
    • B41M5/395Macromolecular additives, e.g. binders

Landscapes

  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Impression-Transfer Materials And Handling Thereof (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)

Abstract

PURPOSE:To contrive to reduce the number of time of replacing a thermal transfer film, by incorporating a crosslinked polymer in a heat-fusible ink layer of a thermal transfer film comprising the ink layer on a base film. CONSTITUTION:A low melting point resin, a coloring material and an optionally added softener are used as ink constituents, and further, a crosslinkable component is added thereto as the fourth constituent, and is crosslinked. Namely, the thermal transfer film comprises the base film 1 and the ink layer 2 as a basic structure, and the ink layer consists of a part 21 consisting of the low melting point resin, the coloring material and the optionally added softener and the crosslinked part 22. At the time of transferring, an ink 2 melted by the heat applied by a thermal head 3 is transferred onto a transfer recording paper 4, and is released from the transfer film, resulting in recording. In this case, since a part of the ink remains on the base film without being transferred, the transfer film can be used plural times for transferring. The low melting point resin may be a paraffin wax, a microcrystalline wax or the like, and any of heat-resistance films can be used as the base film.

Description

【発明の詳細な説明】 本発明は熱転写記録方式のプリンタやファクシミリで使
用さnゐmr規な熱転写フィルムに1列丁ゐ0 プリンタやファクシミリの記録方式の一つに熱転写記録
方式かあ/bOこf’LはA塾材フィルム上に熱苗融イ
ンク&’に設けた熱転写フィルムを晋インク(以Fイン
クと略丁)r被転写紙vc at写してhC録τ行なう
ものでめゐO 〃噌槌促米の熱転写フィルムはフラットな基材フィルム
上にバインダーと宕色刑とかりなるインク層を設けただ
けであゐ7jめ、′?にの懺ンよ欠点に’ffしてい々
0丁なわち1回の転写で記録部のインク層が基材フィル
ムvc残らず完全に転写してし互い、2I!21以上の
使用か出来ないいわゆめワンタイム品であり、記録コス
トが面いことおよび熱転写フィルムの父侯回献か増して
勺・間がか刀・すなどの欠点がめゐ0 そこで不発r!A省(グ上述の欠点v J’q’h消丁
べ(鋭慈倹討r皇ねに精米、インク成分として、低融点
慟脂、宥色創、必資ll′c応して除加丁ゐ仙く仕納の
他vc詔4の〕成分として架橋性成分荀h≦加し、力・
つ架槁丁ゐことにより、複数回転写を打力うことが出来
ゐとい9新7cな事笑忙見出し9本発明を児成するに至
った0 丁なわす、不発明は感熱ヘッド刀・らのカロ熱によって
熱、を融したインクη・インクj仁中に4+住丁ゐ架橋
性成分により一気に転写丁ゐことか妨けらfLs虐jV
rずつ扱転写紙上に転写丁ゐこと盆イ(倣と丁/8俵数
回使用司nヒl熱転写フィルムである0 不発明について図面忙用いてさらVc説明する0第1図
は不発明の熱転写フィルムの構造【ボ丁概略断面図、第
2図、第6図に使用状態?ボ丁概略岬r面図″′Cある
0 丁なVち、不発明の熱転与フィルムは第1凶のごトく″
基材フィルム1およびインクw12?r基不構造とし、
インク層は低融点仰脂、漕色炸」。
DETAILED DESCRIPTION OF THE INVENTION The present invention applies a thermal transfer recording method to one of the recording methods of printers and facsimiles. This f'L is for recording by copying the thermal transfer film provided on the A school material film with Shin ink (hereinafter referred to as F ink) on the transfer paper vc at. 〃The thermal transfer film of Sotsuchi-Sokumei is just a flat base film with an ink layer consisting of a binder and a sapphire layer. The ink layer in the recording area was completely transferred to the base film VC in one transfer, and the ink layer was completely transferred to the base film VC. It is a one-time product that cannot be used for more than 21 days, and has disadvantages such as high recording costs and the disadvantages of heat transfer film, such as the use of a knife, a knife, and a sword. Department A (g) The above-mentioned drawbacks v J'q'h Extinguisher (sharp rice polishing) As an ink ingredient, low melting point lard, softening scratches, necessary addition ll'c In addition to the cross-linking component (vc edict 4), a cross-linking component (x≦h≦) is added, and the force and
By using a holder, it is possible to perform multiple transfers. When the ink is melted by the heat generated by the heat generated by the ink, the cross-linking components prevent it from being transferred all at once.
Transfer paper onto transfer paper (copied and printed / 8 bales) Used several times using thermal transfer film. Structure of thermal transfer film Nogotoku”
Base film 1 and ink w12? The r group is unstructured,
The ink layer is a low-melting point, high-grade oil.

必4iK応じて徐加丁ゐ軟化剤エリなる部分21と架橋
性l水分22とえりl/:1ものである。転写時には第
2図のCとく、感熱ヘッド6より加えら几た熱rCよっ
て浴融したインク2か仮転与紙4上に転写8nfC俊第
6凶のことく剥離さrして記録さ′i′L、勾か基材フ
ィルム上へインクの一部か転写式庇ずに残貿丁ゐために
複数回の転写に供丁ことが出釆るO 不発明ぼjコ・いて用いらn、ゐ結材フィルムとして(
グ耐熱性のi?I/bフィルムであnばよ(、処伸ポリ
ニスデル、ポリアミドイミド、ポリイミド、lとのグラ
スナックフィルムやコンデンサ租、グラシン厭などの紙
が挙げら几る0厚さは1.0〜20μmの他曲で適用出
量ゐ〇 薄い% tD It:i Hれや丁(、又、201ts
n以上では印字二ネルキーが大さく7i:り災用的では
ない0インク層に用いらnゐ低融点但j廟としてはパラ
フィンワックス、マイクロノリスタリノワックス、カル
ナウバワックス、セレシンワックス。
It is necessary to have a softening agent part 21, a crosslinkable water content 22, and a part part 1/:1 depending on the temperature. At the time of transfer, the ink 2 melted by the hot heat applied from the thermal head 6 is transferred onto the temporary transfer paper 4 as shown in C in FIG. 2, and the ink is peeled off and recorded. i'L, because some of the ink is transferred onto the base film without the transfer method, it may be necessary to transfer the ink multiple times. , As a binding material film (
Is it heat resistant? I/B films include paper such as processed polynisdel, polyamide-imide, polyimide, glass nac film, capacitor paper, glassine, etc. The thickness is 1.0 to 20 μm. Applicable output amount for other songs:
If the printing temperature is higher than n, the printing double key becomes large.

醸化ワックス、エステルワックス、ホリエテレンワック
ス、その他の大部ワックス、酋U〈ワックスなどが、5
言色チ■すとしてa刀−ボンプンソク。
Brewing wax, ester wax, polyester wax, and other waxes, such as 5
As for the word color, a sword - Bonpunsoku.

勺゛佛I駒・不斗1県(イ玖EO糾、來クキなとカリ刊
いらノ1−@。
勺゛Football I piece, Fudo 1 prefecture (Iku EO 糾, coming Kuki nato Kali publication Ira no 1-@.

又、心安に応じてcjJ納剤、油などの軟化炸」も併せ
て用いらn、ゐ〇 架橋性成分は架倫性ホリマーと必女に比、じて用いらn
ゐ朱横刑5俵偶成妹なとより選は11−7ζものからな
ゐ0 刀1\な・jリマーとしては架イ11!1点として水離
基、カルボキシル着、アミン基、ア(ドか、工小キシ基
などt臂する(メタ)アクリル敵エステル糸共里台体、
エチレン−I詳淑ビニル共爪付捧郡分鹸化物、エチレン
−酢酸ビニルー不飽オロ7fiik鈑共M8体、塩化ビ
ニル−酢酸ビニルーマレイン酸共厘合体、天然ゴム笈性
物、台底ゴム1性9勿1食性ポリウレタン、ポリエステ
ル、ポリエチレングリコール、フェノール側11t7−
 アルキルフェノール鶴J )IfT *尿素側脂、メ
ラミン4酊脂、エポキシ拉グ脂などかめる。刀・〃・φ
ポリマー甲の架橋点は、モノマーとして1%以上貧ひ必
愉があり、1%以下では架橋の幼果か侍らrl、7Zい
0朱wJ剤としては水酸基、カルボキシル萩、γξミノ
、アミド角+、 71との反^乙、に用いらn、ゐポリ
インシアネート、アルキルニーデル化メラミン仙庸、な
とやカルボキシル左、エポキシ詰の反応vchいら几る
ポリアミンなとが又、架橋触媒としては、ポリ1ソシア
イ・−ト、エホキシ佃)j目の反応のための塩基性触媒
、フェノール側+1i’j +アルキル;エノール佃脂
、尿糸樹脂、メラミン側+]Lff * エホキシ樹脂
の反応のπめのrR江触ム?などが埜けら′n/:I。
In addition, depending on your peace of mind, cjj delivery agents, softening explosives such as oil, etc. may also be used.
The selection is from 11-7ζ. Or, (meth)acrylic ester yarn Kyori base body, etc.
Ethylene-I detailed vinyl co-saponified product, ethylene-vinyl acetate-unsaturated aluminum 7fiik plate co-M8 body, vinyl chloride-vinyl acetate-maleic acid co-liquid, natural rubber core material, base rubber 1 Gender 9 Monoedible polyurethane, polyester, polyethylene glycol, phenol side 11t7-
Alkylphenol Tsuru J) IfT *Use urea fat, melamine 4 fat, epoxy fat, etc. Sword・〃・φ
The crosslinking points of the polymer A must be 1% or more as a monomer, and if it is less than 1%, the crosslinking points are young or samurai RL, and the 7Z, 0, and WJ agents are hydroxyl groups, carboxyl hagi, γξ mino, amide angle + In contrast to 71, polyincyanate, alkyl needled melamine, Natoya carboxyl, and polyamines that require epoxy-filled reactions are also used as crosslinking catalysts. Poly 1 socia-ite, epoxy resin) Basic catalyst for the j-th reaction, phenol side + 1i'j + alkyl; Enol Tsukuda fat, urine thread resin, melamine side +] Lff * π-th reaction of epoxy resin The rR Jiang touch? Such as Nokera'n/:I.

低融点側脂は60〜95ホふj都(以下部と略丁)、眉
色剤1rJ’5〜40郡、軟化剤は0〜20都、架痢任
ポリマー2〜20姉、架+8刑は架稿性ホリマー100
都に対して0〜10部、朱倫触には架倫剤100郁に対
して0〜100都が好ましい。着色六〇が5部以下では
印′:f−嫁度か低くなり、40帥以上では也写俊の被
転与租への定虐性が想い、軟化剤か20都以上でia印
字に枯瘤征か生じゐ揚台があゐ0朱千1断註ポリマーに
2都以下で龜仮叡回弘写忙ぜず、20都以上では印字エ
ネルギーが非7δVC大さくなめ0又、朱惧痢は朱怖性
ポリマーが目己朱倫憔の省什は不安であめが架倫注ホリ
マーに対し1U都以上では朱倫付ポリマーが架橋過剰と
なり卵子エイ・ルギーが大き(なゐ。架橋触媒は不安の
菊付もめ勾かb架橋All 100郡にメリして100
挿以上は触妹幼米刀ふ飽オ1L−b こ1し以上は不必
要であめ。
Low melting point fat is 60 to 95 years (hereinafter referred to as part and abbreviation), eyebrow coloring agent is 1rJ'5 to 40 groups, softening agent is 0 to 20 points, diaphragm polymer is 2 to 20 years old, rack + 8 times is a drafting Holimar 100
It is preferable to use 0 to 10 parts per volume, and 0 to 100 parts per 100 parts of Qianli agent for Zhu Linghang. If the coloring is 60 or less, the stamp':f-margin will be low, and if it is 40 or more, Yasha Shun's tyranny towards the transferred tax will be felt, and if it is a softener or 20 or more, the ia printing will be exhausted. If the printing energy is less than 2, the printing energy will be non-7δVC. In contrast to cross-linked polymers, polymers with cross-linking become over-crosslinked when the cross-linking polymer is over 1U, resulting in a large amount of energy.The cross-linking catalyst is Anxious Kikusuke Mome Gaka b Bridge All 100 County Meri 100
More than one insert is unnecessary.

インク層の厚ざに2〜20μfrlか好1しく2μm以
Fでは21!1白以呻の印字6吸か低トし、20μm以
上ではインクの1j手工不ルキーが多む「に心安とな々
0 次に実施例によ、!77本発明説明丁ゐQなお、部と表
わしたのは全て魚倉部T″あ々0実施例1 アクリル帥ブチル85部、アクリロニトリル10部、メ
タアクリル酸−2−ハイドロエテル5部にトルエン的媒
中″′C過酸化ベンゾイル2部ケ添加して力n熱血合ざ
ゼアクリル崎エステル系共Me体の架橋性ポリマーを得
ゐ。か刀・ゐポリマー固形分ioo都に対してポリイン
シアネート架橋剤(日本ポリウレタン裏コロネートし)
2.5sジプチル・チン・ジラウレート架礁触媒181
5葡硲加しfCもの〃・ら固形分として5部荀取v1エ
ステルワックス40都、カルナウバワックス20s1パ
ラフインワツクス2(1,カーボンブラック20都と混
合して一トルエンに分散し、一部醪解ぜせ厚さ6μmの
延伸ポリエステルフィルムの上に固形分で10μmnc
v8Lさに塗工し、扉熱乾燥して、架橋性ポリマーτ架
倫させ1本発明からなめ熱転写フィルム荀#た。
The thickness of the ink layer is preferably 2 to 20 μfrl, and if the thickness is 2 μm or more, printing of 21! 0 Next, according to the examples, !77 Description of the present invention D-Q Note that all parts are Uokurabe T''A0 Example 1 85 parts of butyl acrylic, 10 parts of acrylonitrile, 2 parts of methacrylic acid - Add 2 parts of benzoyl peroxide in a toluene medium to 5 parts of hydroether to obtain a crosslinkable polymer of acrylic acid ester co-Me type by combining with heat and heat. Polyincyanate crosslinking agent (Japanese polyurethane backing)
2.5s Diptyl Chin Dilaurate Fridge Catalyst 181
5 Added fC thing〃・5 parts as solid content, 40 parts of ester wax, 20 parts of carnauba wax, 2 parts of paraffin wax (1, mixed with 20 parts of carbon black, dispersed in 1 toluene, part 10 μm nc of solid content was melted on a stretched polyester film with a thickness of 6 μm.
The heat transfer film of the present invention was coated on V8L, dried under heat, and cross-linked with crosslinkable polymer τ.

実施例2 架慟性成分としてアルキルフェノール僧脂(日立化成製
ヒタノール2084)1[1[]部のM E K m 
液VCJM化14−&架4m触71 1 D 815’
t&S刀口したものから固形分として5郡葡取り、エス
テルワックス40都、カルナウバワックス20部、ジオ
クチルフタレート10部、カーボンブラック20@と混
合してトルエンに分散し、一部浴解芒せ厚さ9μmの延
伸ポリエステルフィルム上に固形分で10μmの厚δに
m1し、カロ熱乾燥して架橋性ポリマーを架偏させ不発
明からなゐ熱転写フィルム荀得に0 比較例1 実施例1で侍に架橋性ポリマーの固形分5都tエステル
ワツクス40s、カルナラバソックス20s、パラフイ
ンワツクス20匍%カーボングラツク20部と混合して
トルエンに分散。
Example 2 M E K m of 1 [1 [] parts of alkylphenol resin (Hitanol 2084, manufactured by Hitachi Chemical) as a cross-resistance component.
Liquid VCJM 14-& 4m contact 71 1 D 815'
5 types of solids were taken from the T&S cut, mixed with 40 parts of ester wax, 20 parts of carnauba wax, 10 parts of dioctyl phthalate, and 20 parts of carbon black, dispersed in toluene, and partially thawed in a bath. The solid content was spread on a stretched polyester film of 9 μm to a thickness δ of 10 μm, and the cross-linkable polymer was cross-balanced by drying with heat to obtain a thermal transfer film without the invention.Comparative Example 1 Solid content of cross-linkable polymer: 5% T-Ester wax: 40s, Caruna Lavasox: 20s, paraffin wax: 20%, mixed with 20 parts of carbon grain and dispersed in toluene.

−it浴屑、!ぜ厚さ6μmの燵伸ポリエステルフィル
ム上に固形分で10μmの厚ぜに塗工し。
-It's bath waste! The solid content was coated to a thickness of 10 μm on a stretched polyester film with a thickness of 6 μm.

加熱乾保して、熱転写フィルム忙侍kO実施例1,2.
比軟例1で僧7′c泌転写フイ/L。
Heat and keep dry to make a thermal transfer film. Examples 1 and 2.
In example 1, monk 7'c secretion transfer phi/L.

ムtサーマルプリンターに装后して晋通厭を被転写風と
して核畝回転写を試みた。その結果を表1にボテ〇 なお表1Vcボ丁結果は印字σ度r反射鋲厖で表わした
がこの数1回が大きい程通切な印字がさ九ていることt
ボしている。
We loaded it onto a thermal printer and tried to transfer nuclear furrows using Jintong-hae as a transfer target. The results are shown in Table 1.Table 1Vc The results are expressed using the printing σ degree r reflective tack.
I'm bored.

表1 転写回数と印字数置 表1の実I追例で示すように本発明品は複叡回の印字か
Uf能であり。こILは比較19Nと比べて明ら刀・な
よシ11ンク層eこ架橋性成分t〃口えかつ架偏して1
9Jめて用IIヒとなっ7cものであ々Oyzオ、不発
明ばこ几ら実施セリeC眠建式tLoものではなくこの
発明の技術思想?!″逸脱しない範囲で糊々の変形がn
J雇でめゐ〇 4、図1IUo簡卑女睨明 図口11はいすn、も本発明の天〃10例’(1: 7
J<丁tので第1凶は熱転写フィルムの〜f’tIi1
図、扼2図−・よび第6図は使用状態〒示−j“模式1
τ)E間図でるなQ符号の説明 1、 基材フィルム 2 インク層 6 鉱恋ヘッド 46俵転与租
Table 1 Number of transfers and number of prints As shown in the additional example of Table 1, the product of the present invention has the ability to print multiple times. This IL clearly has a cross-linking component t, which is different from the comparison 19N.
Is this the technical idea of this invention, not the 9J first II Hi and the 7C one? ! ``Glue deformation within a range that does not deviate.
J Hireme 〇4, Figure 1 IUo simple female gaze figure mouth 11 is Isu n, also 10 examples of the present invention' (1: 7
Since J<dt, the first failure is ~f'tIi1 of the thermal transfer film
Figures 2 and 6 show the usage state.
τ) Explanation of the Q code in the E diagram 1. Base film 2. Ink layer 6. Mine head 46 bales.

Claims (1)

【特許請求の範囲】[Claims] 1、基材フィルム上に熱播融性インク層r設けてな/)
感熱転写フィルムにおいて、前記熱鹸融性インク層が架
槁妊几たポリマr宮肩丁ゐことt特徴と丁ゐ熱転写フィ
ルム。
1. A heat-melting ink layer is provided on the base film.
The heat-sensitive transfer film is characterized in that the heat-saponifiable ink layer is made of a cross-linked polymer.
JP58145213A 1983-08-09 1983-08-09 Thermal transfer film Pending JPS6036189A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58145213A JPS6036189A (en) 1983-08-09 1983-08-09 Thermal transfer film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58145213A JPS6036189A (en) 1983-08-09 1983-08-09 Thermal transfer film

Publications (1)

Publication Number Publication Date
JPS6036189A true JPS6036189A (en) 1985-02-25

Family

ID=15379985

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58145213A Pending JPS6036189A (en) 1983-08-09 1983-08-09 Thermal transfer film

Country Status (1)

Country Link
JP (1) JPS6036189A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62275778A (en) * 1985-06-13 1987-11-30 Hitachi Chem Co Ltd Thermal transfer film
JPS6311364A (en) * 1986-07-02 1988-01-18 Mitsubishi Electric Corp Thermal transfer printing method
JPH0238094A (en) * 1988-07-28 1990-02-07 Dainichiseika Color & Chem Mfg Co Ltd Transfer sheet
JPH0248628A (en) * 1988-08-11 1990-02-19 Toshiba Corp Endoscopic device
WO1993001059A1 (en) * 1991-07-06 1993-01-21 Fujicopian Co., Ltd. Thermal transfer ink sheet withstanding repeated uses

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5539378A (en) * 1978-09-14 1980-03-19 Mitsubishi Electric Corp Heat-sensitive transcription recording material
JPS5539379A (en) * 1978-09-14 1980-03-19 Mitsubishi Electric Corp Heat-sensitive transcription recording material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5539378A (en) * 1978-09-14 1980-03-19 Mitsubishi Electric Corp Heat-sensitive transcription recording material
JPS5539379A (en) * 1978-09-14 1980-03-19 Mitsubishi Electric Corp Heat-sensitive transcription recording material

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62275778A (en) * 1985-06-13 1987-11-30 Hitachi Chem Co Ltd Thermal transfer film
JPS6311364A (en) * 1986-07-02 1988-01-18 Mitsubishi Electric Corp Thermal transfer printing method
JPH0546315B2 (en) * 1986-07-02 1993-07-13 Mitsubishi Electric Corp
JPH0238094A (en) * 1988-07-28 1990-02-07 Dainichiseika Color & Chem Mfg Co Ltd Transfer sheet
JPH0248628A (en) * 1988-08-11 1990-02-19 Toshiba Corp Endoscopic device
WO1993001059A1 (en) * 1991-07-06 1993-01-21 Fujicopian Co., Ltd. Thermal transfer ink sheet withstanding repeated uses
US5420613A (en) * 1991-07-06 1995-05-30 Fujicopian Co. Ltd. Indirect thermal transfer printing method with a multi-usable transfer ink sheet

Similar Documents

Publication Publication Date Title
JP2796434B2 (en) Applied absorbent thermal imageable laminated substrate
WO1991009742A1 (en) Thermosensitive stencil paper
JP2796435B2 (en) Laminated thermal imageable medium and method for producing the same
JPH0257799B2 (en)
JPS6036189A (en) Thermal transfer film
JPH0473390B2 (en)
US3922438A (en) Supercoated transfer elements and process for preparing and using same
JPH02590A (en) Dye carrier sheet for thermal transfer printing, manufacture thereof and composition for dye barrier used for manufacturing dye carrier sheet
JPS6040295A (en) Repeatedly usable thermal transfer material
JPS633994A (en) Thermal transfer recording medium
JP3246522B2 (en) Laminated substrate for sublimation type thermal transfer image receiving sheet
JPS6040297A (en) Repeatedly usable thermal transfer material
JPH05155191A (en) Material for id card
JPH10151870A (en) Thermal transcription sheet forming raised picture, method for forming raised picture, raised picture product
JP3171500B2 (en) Sublimation type thermal transfer image receiving medium
JP2001199171A (en) Thermal transfer recording medium
JP3035637B2 (en) Thermal transfer recording medium
US5599616A (en) Laminar imaging medium utilizing cross-linked borated polymeric binder
JPH10138639A (en) Device for forming protuberant image and method for forming protuberant image
JPS6040296A (en) Repeatedly usable thermal transfer material
JPH0952449A (en) Heat transfer sheet for forming raised image and image forming method used thereof
JP3195008B2 (en) Thermal transfer recording medium
JP3135091B2 (en) Thermal transfer sheet
JPH0342284A (en) Thermal transfer recording medium
JPH03205191A (en) Thermal transfer recording medium