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JPS58176975A - 集積mos電界効果トランジスタ回路の製造方法 - Google Patents

集積mos電界効果トランジスタ回路の製造方法

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Publication number
JPS58176975A
JPS58176975A JP58052300A JP5230083A JPS58176975A JP S58176975 A JPS58176975 A JP S58176975A JP 58052300 A JP58052300 A JP 58052300A JP 5230083 A JP5230083 A JP 5230083A JP S58176975 A JPS58176975 A JP S58176975A
Authority
JP
Japan
Prior art keywords
layer
substrate
oxide film
silicon
silicide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP58052300A
Other languages
English (en)
Other versions
JPH0547979B2 (ja
Inventor
ウルリツヒ、シユワーベ
フランツ、ネツプル
コンラート、ヒーバー
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens Schuckertwerke AG
Siemens AG
Original Assignee
Siemens Schuckertwerke AG
Siemens AG
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Filing date
Publication date
Application filed by Siemens Schuckertwerke AG, Siemens AG filed Critical Siemens Schuckertwerke AG
Publication of JPS58176975A publication Critical patent/JPS58176975A/ja
Publication of JPH0547979B2 publication Critical patent/JPH0547979B2/ja
Granted legal-status Critical Current

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    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
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    • H01L21/28008Making conductor-insulator-semiconductor electrodes
    • H01L21/28017Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
    • H01L21/28026Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor
    • H01L21/28035Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor the final conductor layer next to the insulator being silicon, e.g. polysilicon, with or without impurities
    • H01L21/28044Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor the final conductor layer next to the insulator being silicon, e.g. polysilicon, with or without impurities the conductor comprising at least another non-silicon conductive layer
    • H01L21/28061Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor the final conductor layer next to the insulator being silicon, e.g. polysilicon, with or without impurities the conductor comprising at least another non-silicon conductive layer the conductor comprising a metal or metal silicide formed by deposition, e.g. sputter deposition, i.e. without a silicidation reaction
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    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/283Deposition of conductive or insulating materials for electrodes conducting electric current
    • H01L21/285Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
    • H01L21/28506Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers
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    • H01L21/28518Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic Table the conductive layers comprising silicides
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    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76838Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
    • H01L21/76877Filling of holes, grooves or trenches, e.g. vias, with conductive material
    • H01L21/76879Filling of holes, grooves or trenches, e.g. vias, with conductive material by selective deposition of conductive material in the vias, e.g. selective C.V.D. on semiconductor material, plating
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    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76838Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
    • H01L21/76886Modifying permanently or temporarily the pattern or the conductivity of conductive members, e.g. formation of alloys, reduction of contact resistances
    • H01L21/76889Modifying permanently or temporarily the pattern or the conductivity of conductive members, e.g. formation of alloys, reduction of contact resistances by forming silicides of refractory metals
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    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/41Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions
    • H01L29/417Electrodes ; Multistep manufacturing processes therefor characterised by their shape, relative sizes or dispositions carrying the current to be rectified, amplified or switched
    • H01L29/41725Source or drain electrodes for field effect devices
    • H01L29/41775Source or drain electrodes for field effect devices characterised by the proximity or the relative position of the source or drain electrode and the gate electrode, e.g. the source or drain electrode separated from the gate electrode by side-walls or spreading around or above the gate electrode
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    • H01L29/4925Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET the conductor material next to the insulator being a silicon layer, e.g. polysilicon doped with boron, phosphorus or nitrogen with a multiple layer structure, e.g. several silicon layers with different crystal structure or grain arrangement
    • H01L29/4933Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET the conductor material next to the insulator being a silicon layer, e.g. polysilicon doped with boron, phosphorus or nitrogen with a multiple layer structure, e.g. several silicon layers with different crystal structure or grain arrangement with a silicide layer contacting the silicon layer, e.g. Polycide gate
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    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
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    • H01L29/66409Unipolar field-effect transistors
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    • H01L29/66545Unipolar field-effect transistors with an insulated gate, i.e. MISFET using a dummy, i.e. replacement gate in a process wherein at least a part of the final gate is self aligned to the dummy gate

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  • Ceramic Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrodes Of Semiconductors (AREA)
  • Insulated Gate Type Field-Effect Transistor (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。

Description

【発明の詳細な説明】 この発明はシリコンゲート技術による集積MO8電界効
果トランジスタ回路の製造方法に関する。この方法では
拡散領域が高融点金属ケイ化物層によって低抵抗にされ
て導体路として使用されるようになり、この金属ケイ化
物層はポリシリコン層が作られ又ソース・ドレン領域と
々る区域が形成された後にMO8構造が作られている半
導体基板表面に直接析出させる。
集積回路の構造寸法を縮小するには拡散領域の深さの低
減も必要となる。これによって層抵抗が著しく増大し、
n+型シリコン導体の場合遅延時間が長くなり又ソース
・ドレン直列抵抗が過大となり短チヤネルトランジスタ
の機能を阻害する。
これらの難点は拡散領域の自己整合形ケイ化物化によっ
て避けることができる。この工程段階において同時にポ
リシリコン−ゲートにもケイ化物が作られポリジッド・
ゲートとなる。これに対してケイ化白金を使用すること
は文献(Proceed i −ngs of IEM
D 81 、 paper A 28.2 、 p、 
647−650)に記載されている。このケイ化白金は
蒸着した白金とシリコン基板の間に反応にょうて作られ
る。この方法の欠点は次の4点である:(a)  ケイ
化物化する際シリコンが消費され、扁平な拡散領域では
基板への短絡が生ずる。
(b)  耐熱性が800C以下の温度に限定される。
(C)  拡散障壁を持つ高価な金属化装置が必要とな
り、又多重層に対するエツチングの問題が起る。
(d)  フッ化水素酸を含む化学薬品を使用する過程
とコンパチブルでない。
短絡の危険は白金とシリコンの混合物又は白金とタング
ステンの混合物の析出によって避けることができる。こ
れによって基板シリコンの消費を少くすることができる
(ただし白金・タングステンの場合は低温においてだけ
)。しかしこの場合は自己整合性が失われ、フォトリン
グラフィ過程が必要となる。
自己整合性の別法として選択的のタングステン析出法が
提案されているがこの場合続く過程が5ooc以下の温
度に限定され、これを越すとケイ化タングステンがシリ
コン消費を伴って形成される。これによって扁平な拡散
領域では基板短絡が起る。
この発明の目的は基板内に極めて扁平な拡散領域を持つ
超大規模集積回路において拡散領域の層抵抗の低減に金
属ケイ化物を使用する問題を解決しようとするものであ
って外部接触導体路面とケイ化金属面の間の絶縁分離酸
化膜の形成前に、熱分解に際してハロゲン化水素を分離
する反応ガスを使用してガス相からの選択析出によって
ケイ化金属層構造を作ることを提案する。ケイ化金属と
してタンタル、タングステン、チタンおよびモリブデン
のケイ化物を使用することもむの発明の枠内にある。
この発明の方法では基板内の拡散領域と、y リシリコ
ンゲート区域が高融点ケイ化物例えばケイ化タングステ
ンの選択析出によって自己整合式にケイ化物で覆われ、
それによって低抵抗(3Ω/口)となるためソース・ド
レン直列抵抗の低いMO8電界効果トランジスタの製作
が可能となる。
更にケイ化物の選択析出によりフォトリングラフ過程が
不必要となる。ケイ化タンタルを使用すると接着性が良
くなりケイ化タンタル・シIJ コン系は1000Cの
温度においても安定である。これによってこの発明の゛
方法はシリコンゲート技術における通常の金属化処理過
程とコンパチブルとなる。
次に第1図乃至第6図についてこの発明の特に有利な二
つの実施例を説明する。これらの図面はこの発明の特に
重要な工程段階においての処理物の断面構造を示すもの
で対応部分には同じ番号がつけである。
第1図乃至第4図はポリシリフン表面の酸化防止に窒化
物層が使用されているMO8電界効果トランジスタの製
作工程を示し、第5図と第6図はポリシリコンゲート電
極の形成後CVD酸化膜析出と異方性エツチングが行な
われる場合に第1図と第2図の構造が変化する情況を示
す。
第1図: (100)表面を持つ比抵抗2乃至500m
のpドープシリコン単結晶基板1の表面にLOCO8法
によってフィールド酸化膜区域2(厚さd。X=700
nm)と能動領域が区画される。
窒化物マスクを除去した後能動領域を酸化して厚さ4Q
nmのゲート酸化膜3を作る。その−ヒにCVD法によ
り厚さ500 nmのポリシリコン層4を全面的に析出
させリンをドープしてn+型とする。ポリシリコン層4
0表面に窒化シリコン層5を例えば100 nmの厚さ
に全面的に析出させる。
第2図:窒化シリコン層5とそつ下のポリシリコン層4
にポリシリコンゲート電極6に対応する構造を作り、続
いて構造形成に際して露出した単結晶基板表面とポリシ
リコン層側面に熱酸化によって新に酸化膜を形成させ、
高濃度ドープのぎりシリコン領域6の側面では厚さが2
00 nmでありその他 の単結晶領域8では5 Q 
nmであるように調節する。続いてヒ素イオンを注入し
て計ドープのソース・ドレン領域9を作る。
除去し、全面的の酸化物エツチングを行って酸化膜8を
全部除去する。続いてこの発明の重要な段階である選択
析出によりシリコンから成る表面区域6と9の上にケイ
化タンタル層1oを析出させる。その際ケイ化タンタル
は塩化水素を分離する反応混合ガスから゛気相析出によ
り析出する。その時の圧力、析出温度および反応ガスの
組成は、熱分解に際してハロゲン化水素が存在すること
により基板のシリコンから成る表面区域(6T 9 )
を除いてその他の区域(2,7)では結晶核が形成され
ないように選ぶ。塩化タンタルと水素とハロゲン化シラ
ン例えばジクロルシラン(S 1H2cJ21の混合比
率は1:10:2に、圧力は133Paに、基板温度は
850Cに調整する。ケイ化クンタル層10の成長速度
は100 n’m/醐、層の厚さは30 (l nm、
比面積抵抗は15乃至3Ω/口である。
第4図:ケイ化物の選択析出に続いてケイ化タンタル面
10と金属化面120間の絶縁分離酸化膜として作用す
る中間酸化膜11を析出させる。
これは例えばCVD法により層の厚さは11000nと
する。ケイ化タンタル(10)で覆われたn+型領領域
9b対する接触孔を食刻しA/!/Si構成の導体路1
2を公知の方法で作や。
第5図:この発明の方法の一つの変形として第1図のL
OCO8過程(フィールド酸化膜区域2の形成と能動領
域の区画)とゲート酸化膜3の形成が終った後CVD過
程によや厚さ500 nmのポリシリコン層を析出させ
、リンをドープしてポリシリコンゲート電極としての構
造を作る。ケート電極6で覆われていない基板表面部分
のゲート酸化膜を除去した後CVD法により酸化膜を全
面的に析出させ5i02層13を作る。
第6図:続いて5i02層13に異方性エツチングを施
し、その際高濃度にドープされたポリシリコンゲート電
極6の側面は酸化膜7で覆われたままにしておく。この
処理は例えば反応性のイオンエツチングによる。続いて
行なわれるn+ドープ単結晶ソース・ドレン領域9を作
るためのヒ素イオン注入は第2図の場合と同じである。
ケイ化タンタル層10の選択析出から金属化処理に至る
までの工程段階は第3図と第4図について説明した通り
に実施される。
【図面の簡単な説明】
第1図乃至第4図はこの発明の一つの実施例の種々の段
階においての処理物の断面構造を示し、第5図と第6図
は別の実施例において第1図と第2図に対応する断面構
造を示す。 1・・・基板、2・・・フィールド酸化膜区域、3・・
・ゲ−)l[tlll、4−・ポリシリコン層、5・・
・窒化シリコン層、6・・・ポリシリコンゲート電極、
9・・・ソース・ドレン領域。 FIGI FIG 2 FIG3 FIG 4 FIG 5 IG6

Claims (1)

  1. 【特許請求の範囲】 1)拡散領域を低抵抗にする金属ケイ化物層が、外部接
    触導体路面と金属ケイ化物面の間に絶縁分離酸化膜の形
    成前に基板のシリコンから成る表面領域(6,9)の上
    にハロゲン化水素の分解に際して分裂する反応ガスを使
    用して選択的の析出によって作られることを特徴とする
    ポリシリコン層が完成しソース・ドレン領域が形成され
    た後に基板表面に直接析串した高融点金属ケイ化物の層
    により拡散領域を低抵抗として使用できるようにするシ
    リコンゲート技術による集積MO8電界効果トランジス
    タ回路の製造方法。 2)金属ケイ化物としてタンタル、タングステン、チタ
    ンおよびモリブデンのケイ化物が使用されることを特徴
    とする特許請求の範囲第1項記載の方法。 3)ケイ化物層の厚さが200乃至500 nmであり
    、その層抵抗がケイ化タンタルの場合l cm2当り1
    .5乃至3Ωに調整されることを特徴とする特許請求の
    範囲第1項又は第2項記載の方法。 4)次の工程・ (a)  能動トランジスタ領域を絶縁分離のための8
    102構造層(2)をLOCO8法又はイソプレーナ法
    と呼ばれる方法によってpドープされた半導体基板表面
    に作る、 (b)  IK出した基板表面を酸化してゲート酸化膜
    (3)を作る、 (C)  全面的にポリシリコン層(4)を析出させ、
    この層にn型ドーパントをドープしてn+型とし、これ
    にポリシリコンゲート電極(6)としての構造を作る、 (d)  ゲート電極で覆われない基板表面(8)のゲ
    ート酸化膜(3)を除去する、 (e)  ガス相から5L02層(13)を析出させる
    (CVD法)、 (1)  この酸化物層に異方性エツチングを施し、そ
    の際シリコンゲート電極の側面(7)が酸化物で覆われ
    たままにしておく、 (2) トランジスタ領域にヒ素イオンを注入しpドー
    プ基板内にn斗型にドープされた単結晶ソース・ドレン
    領域(9)を作る、 山)反応に際して塩化水素を分離する反応ガスを使用し
    てガス相からケイ化タンタルを析出させ、その際基板の
    シリコンから成る表面区域(6,9)だけにケイ化タン
    タルが沈積するようにする、 0)中間酸化膜として作用する絶縁層を析出させる、 (j)  基板のケイ化物化された部分に対する外部接
    触導体路のための接触孔区域を腐食する、 (k)  金属層を形成させ外部接触導体路構造をによ
    ることを特徴とする特許請求の範囲第1項乃至第3項の
    いずれかに記載の集積MO8電界効果トランジスタ回路
    の製造方法。 5)次の工程: (a)  pドープ半導体基板表面に能動トランジスタ
    領域を分離するための5i02構造層をLOCO8法又
    はイソプレーナ法と呼ハレる方法で作る、 (b)  p基板の露出表面を酸化してゲート酸化膜と
    する、 (C)  全面的にポリシリコン層を析出させ、この層
    にnドーパントをドープして?型とする、 (d)  窒化ンリコン層(5)を析出させ、この窒化
    シリコン層とポリシリコン層から成る二重層に構造を作
    る、 (e)  熱酸化を行ない、露出したシリコン表面に酸
    化膜を形成させ、高濃度ドープのポリシリコン層の側面
    に基板の単結晶部分(8)の酸化膜よりも厚い酸化膜を
    形成させる、(f)トランジスタ領域にヒ素イオン注入
    を実施しpドープ基板内にn+型にドープされたソース
    ・ドレン領域(9)を作る、 (g)窒化物層(5)を除去する、 (h)  基板上の酸化膜を全面的に腐食除去して基板
    の単結晶区域表面を露出させる、 (i)反応に際して塩化水素を分離する反応ガスを使用
    してガス相からケイ化タンタル層を析出させ、その際基
    板の礼すコンから成る表面部分だけにケイ化タンタルが
    沈積するようにする、 (」)中間酸化膜として作用する絶縁分離層を析出させ
    る、 [有]) 基板のケイ化物化されたシリコン区域に接触
    導体路のための接触孔区域を腐食する、。 (1)  外部接触導体路としての金属化面を設けこれ
    に構造を作る、 によることを特徴とする特許請求の範−間第1ンジスタ
    回路の製造方法。 6)基板として(1001表面を持ち比抵抗2乃至50
    Ωσにpドープされたシリコン単結晶板を使用すること
    を特徴とする特許請求の範囲第4項記載の方法。 7)工程段階(e)においてCVD法による酸化膜の厚
    さが100乃至]000nmに調整されることを特徴と
    する特許請求の範囲第4項記載の方法。 8)工程段階(e)において酸化膜の厚さが200 n
    m  に調整されることを特徴とする特許請求の範囲第
    5項記載の方法。 9)工程段階(h)において酸化膜の腐食が60nmの
    厚さとなるまで行なわれることを特徴とする特許請求の
    範囲第5項記載の方法。
JP58052300A 1982-03-30 1983-03-28 集積mos電界効果トランジスタ回路の製造方法 Granted JPS58176975A (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3211761.2 1982-03-30
DE19823211761 DE3211761A1 (de) 1982-03-30 1982-03-30 Verfahren zum herstellen von integrierten mos-feldeffekttransistorschaltungen in siliziumgate-technologie mit silizid beschichteten diffusionsgebieten als niederohmige leiterbahnen

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Publication Number Publication Date
JPS58176975A true JPS58176975A (ja) 1983-10-17
JPH0547979B2 JPH0547979B2 (ja) 1993-07-20

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EP (1) EP0090318B1 (ja)
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AT (1) ATE44115T1 (ja)
CA (1) CA1203642A (ja)
DE (1) DE3211761A1 (ja)

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EP0090318B1 (de) 1989-06-14
ATE44115T1 (de) 1989-06-15
EP0090318A2 (de) 1983-10-05
US4510670A (en) 1985-04-16
CA1203642A (en) 1986-04-22
EP0090318A3 (en) 1986-01-15
DE3211761C2 (ja) 1991-03-14
JPH0547979B2 (ja) 1993-07-20
DE3211761A1 (de) 1983-10-06

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