JPS5695153A - Preparation of 3-isopropylamino-2-hydroxypropanol derivative - Google Patents
Preparation of 3-isopropylamino-2-hydroxypropanol derivativeInfo
- Publication number
- JPS5695153A JPS5695153A JP17155679A JP17155679A JPS5695153A JP S5695153 A JPS5695153 A JP S5695153A JP 17155679 A JP17155679 A JP 17155679A JP 17155679 A JP17155679 A JP 17155679A JP S5695153 A JPS5695153 A JP S5695153A
- Authority
- JP
- Japan
- Prior art keywords
- compound shown
- formula
- reacted
- give
- hydroxypropanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Indole Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pyrane Compounds (AREA)
Abstract
PURPOSE: To obtain the titled compound useful as a β-adrenergic neuronal blocking agent safely in high yield, by using 2,3-epoxypropanol-1 and 2,3-dihydropyran as starting materials by seven processes through the conversion of six novel intermediates, etc.
CONSTITUTION: 2,3-Epoxypropanol-1 is reacted with 2,3-dihydropyran, to give a compound shown by the formula I, which is reacted with benzyl-isopropylamine, to give a compound shown by the formula II. The compound shown by the formula II is reacted with a benzyldihalide in the presence of a base to give a reaction product, which is hydrolyzed in acidic conditions, to give a compound shown by the formula III. The compound shown by the formula III is reacted with dicyclohexylcarbodiimide, and reacted with a compound shown by the formula Ar-OH (Ar is 1-naphthyl or 4-indolyl) to form a compound shown by the formula IV, which is hydrolyzed to give the titled compound shown by the formula V. All the reaction intermediates are novel compounds.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP17155679A JPS5695153A (en) | 1979-12-28 | 1979-12-28 | Preparation of 3-isopropylamino-2-hydroxypropanol derivative |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP17155679A JPS5695153A (en) | 1979-12-28 | 1979-12-28 | Preparation of 3-isopropylamino-2-hydroxypropanol derivative |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP62190393A Division JPS6393752A (en) | 1987-07-31 | 1987-07-31 | 3-isopropylamino-2-hydroxy-1-propanol derivative |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5695153A true JPS5695153A (en) | 1981-08-01 |
JPS631937B2 JPS631937B2 (en) | 1988-01-14 |
Family
ID=15925312
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP17155679A Granted JPS5695153A (en) | 1979-12-28 | 1979-12-28 | Preparation of 3-isopropylamino-2-hydroxypropanol derivative |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5695153A (en) |
-
1979
- 1979-12-28 JP JP17155679A patent/JPS5695153A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS631937B2 (en) | 1988-01-14 |
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